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TH ND: System Surroundings Universe Universe
TH ND: System Surroundings Universe Universe
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II. Problem Solving. Given the equation, calculate the standard free energy change. Answer what
is being asked.
____11-15. N2(g)+3H2(g) --->2NH3(g)
If ΔH = -92.2kJ and ΔS= -0.1987kJ/K, what is ΔG for the reaction at 475°C and at 5°C? Provide the
answer in kJ. In each case, is the reaction spontaneous?
____16-20. The enthalpy and entropy change of a reaction are -3.9 kJ/mole and +56.6 J/mole K
respectively at 25°C. What is the free energy change in kJ/mole? Is this reaction always spontaneous,
never spontaneous or does it depend on the temperature?
____21-25. When 1.50 mol CO2 and 1.50 mol H2 are placed in a 3.00-L container at 395 °C, the following
reaction occurs: CO2 (g) + H2 (g) CO (g) + H2O (g). If Kc = 0.802, what are the concentrations of each
substance in the equilibrium mixture?
Approved:
____1. H2O
____2. OH-
____3. NH3
____4. NH4+
____5. NH2-
____6. Who developed definitions of acids and bases based on the compounds' abilities to either donate or
accept protons (H+ions)?
A. Johannes Nicolaus Brønsted C. Svante Arrhenius
B. Gilbert Newton Lewis D. Thomas Marcus Highry
____7. Which of the following is CORRECT on the following statement?
I. In Bronsted-Lowry acids are defined as proton acceptors.
II. In Bronsted-Lowry acids are defined as proton donors
III. A Brønsted-Lowry base is a proton (hydrogen ion) acceptor.
A. I only C. III only
B. II only D. II and III
____8. In the equation , Which compound is considered
as the conjugate base?
A. C2H5NH2 C. C2H5NH3+
B. H2O D. OH-
____9. In number 8, which compound is considered as the conjugate acid?
A. C2H5NH2 C. C2H5NH3+
B. H2O D. OH-
____10. It is said to be Arrhenius acid if it is any species that can increase the concentration of H+ in
aqueous solution.
A. True C. Unrelated
B. False D. Maybe
II. Identification. Write the word/group of words being described in each statement.
_______________________11. This is a solution composed of a weak acid and its conjugate base that can be
used to stabilize the pH of a solution.
_______________________12. This is equal to the negative logarithm of the concentration of H+ ions in
solution.
_______________________13. These solutions are also termed as ALKALINE.
_______________________14. The __________________ equation was developed for relating the pH to the
bicarbonate buffer system of the blood.
_______________________15. A low pKa value indicate a stronger acid. That is, the ___________ value
indicates the acid more fully dissociates in water.
II. Problem Solving. Given the equation, calculate for the missing items. WRITE YOUR ANSWERS
AT THE BACK PAGE.
16-20. In an acidic solution with a pH of 3.4, 65% of the acid is ionized. What is the pKa of the acid?
21-25. What is the pH of a buffer solution that is 0.25 M in NH3 and 0.44 M in NH4Cl with 5.30 pKb?
Prepared by: Checked: Noted:
Approved:
Approved:
B. Hg2+ was reduced; N2H4 was oxidized D. Hg2+ was reduced; N2H4 was reduced
____21. When two dissimilar metals make electrical contact in the presence of a/an _______, the rate at
which corrosion occurs depends on the difference in their corrosive tendencies.
A. ion C. neutron
B. electrolyte D. electron
____22. Corrosion is the electrochemical _________ of a metal because of its chemical reaction with the
surrounding environment.
A. accumulation C. assimilation
B. generation D. deterioration
____23. Stainless steels have higher corrosion resistance because of __________.
A. their passive Layer C. their high amounts of chromium
B. their positive potential D. A and C
____24. Which of the following statements is FALSE?
A. Oxidation occurs at the anode.
B. Reduction occurs at the cathode.
C. All electrochemical reactions involve the transfer of electrons.
D. All voltaic (galvanic) cells involve the use of electricity to initiate
nonspontaneous chemical reactions.
____25. Which among the choices is the best example in making a simple fuel cell?
A. lead storage battery
B. Daniell cell
C. H2−O2 cell
D. Lechlanche cell
Approved: