PEAR A AMINA'TYONS COUNCIL | it General Coriificate of Education Advanced Level 1 E92 NOVEMIER 2005 SESSION {hour 15 minutes ‘Cendlidases anewer on the question payer, ‘ional materialy Data Booklet ‘Mathematical Tables Yor Cale ptt te our 15 minutes ICTIONS TO CANDIDATES ‘ite your nams, Cone number and candidate number in the spaces at the top ofthis page. awor all questions, answers in spaces provided on the question paper, | INFORMATION Porc AsNpATES The mamber of marks is wisn in brackets [J at the end of question or paxt question, . printed pages ond { blanic page, | pyright: Zimbabwe Schoo! Examinations Council, N2005, {BiesEC M2005 {Tara over1 at Curves A, B and C represent plois of p ageinst pV for nitrogen, ammonia and neon, but not in that order. (pis the pressure and V is the volume of the gas). @ b) (e) A gas reason gas, * meason c Ba reason sora N2o0s [6] [Total : 6] For Examiaer’s Useb The boiling points of three amines are given below. amine boiling poiay?C I (Ca 4 | (CH):NH 7 | cum | 10 (a). Explain the difference in these boiling points. (b) Write an equition to explain why a solution of CH; is basic eee (©). “Use dot-and-cross diagrams to describe bonding in @ aluminium oxide, (i) | BCINFA, gies nzcos + ee eer ae 2) + fa] + {Total :7} (furn over |4 The table below shows data which o: an be used to determine the lattice enthalpy of franeium,chloride, FrCl, enthalpy change energy/kImol' atomisation of flancium set atomisation of chlorine +1220 Wonisation of fancium "| =403 1* electron affinity of chlorine ~ 345 a) Construct an energy cycle using the above data. 2] Ab)” Determine value for the lattice enthalpy of FrCl 11) «© -- Explain why the latti¢e enthalpy of rubidium ehloride, RbCl is more ih exothertric than that of francium chloride, [Total : 5} 91802 N200s For Examiner Usefay (b) () State and explain trietly the wend in vetntility of Group VII elements: Chlorine. gas is bubbled through a mixture of aqueous so and sodium bromide, ether is then.added and two izamiscible layers weer: obtained. @ (ii) | (iii) Deserive any colour change observed. ee SSeS eC HEEL) ‘Write cn equation for the reaction occurring, . : Sanne Explain the presence of the two layers. tt) State’an industrial use of a chlorine contsiming substance. The chlorides of tin and lead can be formed by heating solderterral of tin and lead) in dry chlorine. if @ di): A) fFotal : 7] ‘Write valancéd equations for the seactions.that take place. Suggest, with the ail of an equationwhy it is not possible to form the chloride of tin using aqueous elibrine, - 98972 N200 For Examiner's Use(b) <6 Explain the trend in boiling points of the tetrachlorides of Group TV elements, [3] (otal: 8} Concentrated nitric acid.is a source of an electrophile used in nitration of metliyl benzene. (a) (b) © What isan clectophile? Give an examnple of an electrophile and suggest a reaction from which if can be generated. ft) Give the reagents and.conditions necessary 1o convert methyibenzene into ethyl benzoate. + ; senna . oe (4) [Total : 8] 91897 Nau0s For [Examiner UseProp 1—ene, CH)CHNMH,, isa highly Gammable gas. f) (by (ce) “Wha type of intermolecular and intramolecular interaotions exist in this Molecule? 1 Intermolecular” 2 Intraraolecular 2 G) Draw a displayed formula of prop-I-ene, showing bond angles, Label one o - bond and one pi-bond in the displayed formula in (b)(j). Deseribe in terns of orbital overlap, the formation-of a a-bond and a pi-bond in prop-L-ene. 19 nau 14) balanced equation for the complete combustion of prop-I-ene. [1] [Total : 7] | For Examiner's Use.