All India Integrated Test Series: JEE (Advanced) - 2022

ALL INDIA INTEGRATED TEST SERIES
HALF COURSE TEST – II

JEE (Advanced)-2022
PAPER –1
TEST DATE: 16-05-2021
Time Allotted: 3 Hours Maximum Marks: 198
General Instructions:
 The test consists of total 54 questions.

 Each subject (PCM) has 18 questions.
 This question paper contains Three Parts.

 Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
 Each Part is further divided into Two Sections: Section-A & Section-C.
Section-A (01 – 06, 19 – 24, 37– 42) contains 18 multiple choice questions which have ONLY
ONE CORRECT ANSWER. Each question carries +3 marks for correct answer and –1 mark for
wrong answer.
Section-A (07 – 12, 25 – 30, 43 – 48) this section contains 18 multiple choice questions.
Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is (are)
correct answer(s).
For each question, choose the option(s) corresponding to (all) the correct answer(s)
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen:
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and
both of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is
a correct option;
Zero Marks : 0 If none of the options is chosen (i. e. the question is unanswered);
Negative Marks : 2 In all other cases.
Section-C (13 – 18, 31– 36, 49 – 54) contains 18 Numerical answer type questions with answer
XXXXX.XX and each question carries +4 marks for correct answer and 0 marks for wrong answer.
Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AIITS-HCT-II (Paper-1)-PCM-JEE(Advanced)/2022 2
Physics PART – I
SECTION – A
(One Options Correct Type)
This section contains 06 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
1. If position time graph of a particle is since curves as shown, what will be its velocity-time graph?
x
t
(A) (B) V
(C) (D) V
2. Same number of mole of an ideal gas is enclosed in two identical A B

thermally insulated chambers A and B shown in the figure.
Temperature of gas in each chamber is T where as walls of A and B
are at temperatures TA and TB respectively. If gas in the chamber A TB
TA
exerts more pressure on the wall than the pressure by the gas in the
chamber B, then
(A) TA < TB
(B) TA > TB
(C) TA = T B
(D) Can’t say
P
3. A monoatomic ideal gas undergoes a process consists of
n=1
concentric semi-circles on PV graph, starting from A(P0, V0) 2P0 n=2 Semi-circles
n=3
and ending at B(P0, 2V0). The point B is the common centre of
the PV semi circles. Let rn be the magnitude of radius of nth
circle. It is given that rn = 2/3 rn1, n  N. Find the magnitude P0
A B
of heat gained (or rejected) by the system in undergoing
whole process from A to B. Process is isobaric from (n-1)th to
nth circle. V
V0 2V0 3V0
 65  9 
(A)   P0 V0
 26 
4 
(B)   P0 V0
 2 
7  
(C)   P0 V0
 2 
 65  9 
(D)   P0 V0
 26 
3 AIITS-HCT-II (Paper-1)-PCM-JEE(Advanced)/2022
4. In the following diagrams three different liquids have been taken in three beakers and a ball make
of a material of specific gravity D remain in these three liquids as shown. If the three liquids X, Y,
Z have specific gravities Dx, Dy and Dz respectively, which of the following statement is correct?
Liquid X Liquid Y Liquid Z

(A) Dx > D y > D z
(B) Dz < D y > D x
(C) Dy > D x > D z
(D) Dx > D z > D y
5. A wooden block floats in a liquid with 40% of its volume inside the liquid. When the vessel
containing the liquid starts rising upwards with acceleration a = g/2, the percentage of volume
inside the liquid is
(A) 20%
(B) 60%
(C) 30%
(D) 40%
6. Two masses M and m are suspended together by a massless spring of force constant k. When
the masses are in equilibrium, M is removed without disturbing the system. The amplitude of
oscillation is:
Mg
(A)
k
mg
(B)
k
(C)
 M  m g
k
(D)
 M  m g
k
(One or More than one correct type)
This section contains 06 multiple choice questions. Each question has FOUR options (A), (B), (C) and
(D). ONE OR MORE THAN ONE of these four options is(are) correct.
7. A particle starts SHM at time t = 0. Its amplitude is A and angular frequency is  . At time t = 0 its
E
kinetic energy is . Assuming potential energy to be zero at mean position, the displacement
4
time equation of the particle can be written as:
(A) x  A cos  t   / 6 
(B) x  A sin t   / 3 
(C) x  A sin  t  2 / 3 
(D) x  A cos  t   / 6 
8. A ball of mass M is suspended from a bar of same mass with a light M
inextensible cord. The bar can slide on a frictionless slope of inclination.

Initially they are kept motionless and released from the position shown. Then 
just after the release: M
2g sin 
(A) Acceleration of the bar is
1  sin 2 
2g
(B) Acceleration of the ball is
 cosec2  1
 1  sin 2  
(C) Tension in the cord is Mg  
 cos  
2
 cos 2  
(D) Tension in the cord is Mg  
 1  sin  
2
9. A particle is rotating in a conical pendulum with help of a string of length  as

 
shown in the figure. The speed of the particle is constant and angle  is also
constant with time. It can be said that
(A) Angular momentum of the particle about the point of suspension is not constant.
(B) Only the direction of angular momentum of the particle about the point of suspension is
constant.
(C) Only the magnitude of angular momentum about the point of suspension is constant.
(D) Net torque on the particle about the point of suspension is zero.
10. Inside a uniform spherical shell

(A) The gravitational potential is zero
(B) The gravitational field is zero
(C) The gravitational potential is same everywhere
(D) The gravitational field is the same everywhere.
V3
11. Two moles of a monatomic ideal gas undergoes a thermodynamic process = constant, if the
T2
temperature is raised by 300K then:
(A) Work done by the gas is 400 R
(B) Change in internal energy is 900 R
(C) Molar heat capacity of the gas for the process is 13R/6
(D) Molar heat capacity of the gas for the process is 3R/2
12. Two whistles A and B each have a frequency of 500 Hz. A is stationary and B is moving towards
the right (away from A) at a speed of 50 m/s. an observer is between the two whistles moving
towards the right with a speed of 25 m/s. The velocity of sound in air is 350 m/s. Assume there is
no wind. Then which of the following statements are true
(A) The apparent frequency of whistle B as heard by person at A is 444 Hz (approximately).
(B) The apparent frequency of whistle B as heard by the observer is 469 Hz (approximately)
(C) The difference in the apparent frequencies of A and B as heard by the observer is 4.5 Hz
(approximately).
(D) The apparent frequencies of the whistles of each other as heard by A and B are the
same.
SECTION – C
(Numerical Answer Type)
This section contains 06 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded-off to the second
decimal place; e.g. XXXXX.XX).
13. A pipe in the form of a half ring of radius r is placed on a horizontal C

surface as shown in figure. If is displaced through, a small quantity,
and then released. Assuming that it rolls without sliding determine the G
period of oscillations (in sec)
(Given r  10 /1.14m, g  10 m / s 2 ,   3.14 )
14. A wooden bar (10 kg) is placed on a smooth floor with its
both ends fixed (Fig. A). A gradual increasing force at
midpoint of it can break it at mid point when its value is F1 .
F1 F2
Now another identical bar is placed on the smooth floor with
two blocks (5kg) attached at the two ends. The maximum
force that can be applied without breaking it at midpoint is F2 .
Fig.A Fig.B
F
Then find the value of 2 .
F1
15. Pipe A has length twice the pipe B. Pipe A has both ends open & pipe B has one end open. If a
sound wave of same frequency was sent in both pipes. Which least harmonic of pipe A have a
frequency that matches with resonance frequency of pipe B.
16. A projectile is projected with velocity 10 m/s at angle 37°. Find out the distance of the point
where it lands from ground. Co-efficient of restitution for collision is 0.5. [Take the value of g =
10 m/s2]. (in m)
17. Two particles are performing circular motion in concentric circles of radii 10 m and 5m each, in
opposite sense. Velocities of the particles are 200 m/s and 79 m/s respectively. Find out the
angular velocity of line joining them, when they are farthest apart. (in red/sec)
18.
15 m/s
F ?
Water enters steadily in a U-shaped tube of uniform cross-section area as shown in figure. Find
out the magnitude of force F that is needed to keep the tube in equilibrium. (In N)
[Density of water = 1000 Kg/m3, cross-section area of the tube = 1 cm2]
Chemistry PART – II
SECTION – A
19. Why does raising the pressure of a fixed mass of gaseous reactants at a constant temperature
cause an increase in the rate of reaction?
(A) More collisions occur per second when the pressure is increased.
(B) More molecules have energy greater than the activation energy at the higher pressure.
(C) Raising the pressure lowers the activation energy.
(D) All are correct
20. 4-chloroaniline is a pale yellow solid which in an important building block used for the production
of pesticides, drugs and dyestuffs.
Cl NH2
4-chloroaniline
Which of the following shows a suitable starting compound and sequence of steps to produce a
good yield of 4-chloroaniline?
Starting compound Step 1 Step 2
(A) Conc. HNO3, conc. H2SO4 Sn, conc. HCl following by NaOH
Cl (aq.)
(B) Dil. HNO3 LiAlH4

Cl
(C) Cl2, AlCl3 Sn, conc. HCl following by NaOH

NO 2 (aq.)
(D) LiAlH4 Cl2 in CCl4

NO 2
21. High-energy irradiation in the stratosphere produces radicals from chlorofluoroalkanes, commonly
known as CFCs.
Which radical could result from this irradiation of CHFClCF2Cl?

(A) CHFCl C FCl

(B) C HClCF2Cl

(C) C HFCF2Cl

(D) C FClCF2Cl
22. The bar chart shows the melting points of a series of consecutive elements arranged in order of
increasing atomic number. The elements sodium to chlorine form part of this series. Which bar
represents sodium?
(A) A = Na
(B) B = Na
(C) C = Na
(D) D = Na
23. Incomplete combustion of 20 cm3 of a gaseous hydrocarbon gave carbon dioxide and carbon
monoxide in a 6:1 ratio, as well as water vapour. It was found that the carbon dioxide took up a
volume of 51.4 cm3 whereas the water vapour took up a volume of 80 cm3. All gas volumes are
measured at the same temperature and pressure. What is the molecular formula of the
hydrocarbon?
(A) C2 H4
(B) C2 H6
(C) C3 H 6
(D) C3 H 8
24. The reaction of hydrogen peroxide with iodide ions in acidic solution can be monitored by an initial
rate method.
H 2O2  aq   2 H   aq   2 I   aq  
 2 H 2O  l   I 2  aq 
The following results were obtained for a series of experiments with different volumes of each
regent used.
Experiment Volume of H2O2 Volume of H+ Volume of I- Volume of Time taken / s
number (aq.)/cm3 (aq.) / cm3 (aq.) / cm3 water / cm3
1 40 40 20 0 33
2 20 40 20 20 66
3 40 20 30 10 22
4 20 40 30 10 44
What could be the mechanism of this reaction?
(A) H O  H  
2 2  H O  OH   fast 
2
 
OH  2 I  H  
 H 2O  I 2  slow 
(B) H 2O2  I    H 2O  IO   slow 
H   IO    I   I 2  H 2O  fast 
HIO  H   I    I 2  H 2O  fast 
(C) 2 H   2 I  
 2 HI  fast 
2 HI  H 2O2   I 2  2 H 2O  slow 
(D) H 2O2  I   H  
 H 2O  HIO  fast 
 I 2  2 H 2O  slow 
HIO  I  
OH   H  
 H 2O  fast 
25. The value of the ionic product of water, Kw, varies with temperature.
Temperature/°C Kw/mol2 dm-6
25 1.0×10-14
62 1.0×10-13
Which of the following statement is correct?
(A) The ionic dissociation of water is an endothermic process.
(B) Water is a neutral liquid at 62°C.
(C) pH<7 at 62°C for water
(D) pH>7 at 62°C for water
26. Which of the following has the same value as the standard enthalpy change of formation, H f ,
of carbon monoxide?
(A) H combustion  C , graphite   H combustion  CO 
(B) H f   CO2   H combustion  CO 
1
(C) H  f  CO2 
2
1
(D) H Combustion  CO2 
2
27. The radius and charge of each of the six ions are shown below.
Ion J L M 2 X Y Z2 
Radius/nm 0.14 0.18 0.15 0.14 0.18 0.15
The ionic solids JX, LY and MZ are of the same lattice type. Which of the following statement are
correct?
(A) The melting point increases in the order LY<JX<MZ
(B) The numerical value of hydration energy of X is smaller than that of Z2 
(C)
2
The solution containing M ions is more acidic than the solution containing J  ions.
(D) The lattice energy of JX salt is highest among the given ionic solids.
28. In which of the following pairs are the members, I and II,
Stereoisomers of each other, and the overall dipole moment of I is larger than that of II?
I II
(A) O 2N NO2 O 2N H
H H H NO2
(B) H3C H H3C Br
Br Cl H Cl
(C) Br Br
Br H Br H
Br Cl
H Cl H Br
(D) Cl Cl Cl H
H H H Cl
29. The numerical value of the solubility product of nickel (II) carbonate is 6.6×10-9 while that of silver
carbonate is 2.1×10-11 at 25°C
Which of the following statements is/are FALSE?
(A) Addition of silver nitrate increases the solubility of silver carbonate
(B) The solubility of silver carbonate is higher than the solubility of nickel (II) carbonate.
(C) Addition of nitric acid to a solution containing nickel (II) carbonate increases the solubility
product of nickel (II) carbonate.
(D) Nickel (II) carbonate precipitates first when sodium carbonate is added to a solution
containing equal concentrations of nickel (II) and silver ions.
2
30. Polythionates are a series of sulfur-oxo anions with the general formula Sn O 6 , where n>2 . A
2
simple example is tetrathionate ion, S4 O 6 .
(A) If n=2, average oxidation state of sulphur =3
(B) If n=4, average oxidation state of sulphur =2.5
(C) If n=3, averageoxidation state of sulphur =10/3
(D) If n=5, average oxidation state of sulphur =6
SECTION – C
31. At constant pressure what would be the percentage decrease in the density of an ideal gas for a
10% increase in temperature?
32. 200 mL of 0.5 N solution of acidified KMnO 4 was mixed with 300 mL of 0.6 N FeC2O4 solution and
the mixture is gently heated for complete reaction according to the following equation.
MnO 4  FeC2O 4  H  Mn2   Fe3   CO2  H2O
What volume (in L) of CO2 gas is produced at STP in the reaction?
33. The percentage ionic character of a bond having 1.275 A0 as its length and 1.03 D its dipole
moment will be
34. How many of the following statements is/are correct?

h
(1) The orbital angular momentum for a d-electron is 6 .
2
(2) The number of orbitals in a shell with principal quantum number n is 2n 2 .
 1
(3) The set of quantum numbers for the last unpaired electron of Cl atom can be 3 ,1,1,  
 2 
(4) The ratio of energy in the first Bohr orbit of H – atom to the electron in the first excited
state of Be3+ is 1:4.
(5) The electronic configuration of Co ends with 3d74s2.
(6) The order of energy of subshells in a given principle quantum level for an H-atom are
ns<np<nd<.
(7) in silver atom (at.no. 47), 23 electrons have a spin of one type and 24 electrons have a
spin of opposite type.
35. In the compound Na2 [B4O5(OH)4]8H2O, if the

(i) number of BOB bonds is a
(ii) number of BB bonds is b
(iii) number of sp2 hybridized B atom is “c”
Calculate the value of a+ b+ c.
36. In 1869 Ladenburg suggested a structure for benzene, C6H6, in which one hydrogen atom is
attached to each carbon atom.
A compound C6H4Cl2 could be formed with the same carbon skeleton as the Ladenburg structure.
How many structural isomers would this compound have?
Mathematics PART – III
SECTION – A
n
37. Given that sin3 x. sin 3x   c m cos mx, c n  0, is an identity. The value of n is
m0
(A) 2
(B) 4
(C) 6
(D) cannot be calculated
38. If the sum of first 100 terms of an arithmetic progression is -1 and the sum of the even terms lying
in first 100 terms is 1, then
13
(A) common difference is
50
7
(B) common difference is
50
151
(C) first term is
50
149
(D) first term is
50
39. If the focus of midpoints of portions of tangents intercepted between coordinate axes of hyperbola
x2 y2  9
  1is 2  2   , then ( + ) is equal to
16 9 x y
(A) 14
(B) 16
(C) 18
(D) 20
40. Seven different lecturers are to deliver lectures in seven periods of a class on a particular day. A,
B and C are three of the lectures. The number of ways in which a routine for the day can be made
such that A delivers his lecture before B and B before C, is :
(A) 210
(B) 420
(C) 840
(D) None of these
41. If |zi|2 and z1 = 5 + 3i, (where i  1) , then the maximum value of |iz+z1| is:
(A) 2  31
(B) 7
(C) 31  2
(D) 31  2
r 1 A B C
42. If in triangle ABC,  , then the value of tan  tan  tan  is equal to:
r1 2 2 2 2
(A) 2
1
(B)
2
(C) 1
(D) None of these

43. The points (2, 3), (0, 2), (4, 5) and (0, t) are concyclic if the value of t is
(A) 1
(B) 2
(C) 17
(D) 3
The equation of four circles are  x  a    y  a   a2 . The radius of the circle touching all the
2 2
44.
four circles is
(A)  2 1 a
(B) 2 2a
(C)  2  1 a
(D) 2  2  a
45. If the equation of the parabola is x2 + y2 – 2xy + 4x – 2y + 1= 0, then
(A) Axis is 2x – 2y + 3 = 0
5
(B) Tangent at vertex is 2x  2y   0
4
 1 11 
(C) Vertex is   , 
 8 8
 3 15 
(D) Focus is  , 
8 8 
46. Let us consider all complex numbers satisfying |z25i|15. Among all these complex numbers:
(A) complex number with least argument is tan1(3/4)
1
(B) complex number with maximum argument is   tan (3 / 4)
(C) complex number with at least magnitude is 10
(D) complex number with maximum magnitude is 40
n
47. For n  N, let S(k)  r
r 0
k n
( Cr )2 , then
2n
(A) S(0)  Cn
1 2n
(B) S(1)  ( Cn )
2
2n
(C) S(0)  Cn1
n 2n
(D) S(1)  ( Cn )
2
48. The number of ways of arranging seven persons (having A, B, C and D among them) in a row so
that A, B, C and D are always in order A-B-C-D(not necessarily together is:
(A) 210
(B) 5040
(C) 6× 7C4
(D) 7P
3
SECTION – C
49. If a, b, c are distinct integers and   1 is a cube root of unity and if minimum value of
1
a  b  c2  a  b2  c is 144  n , then the value of n must be equal to
The coefficient of x2009 in the expansion of (1  x) (1  x  x 2 )2007 is ……

2008
50.
51. The number of solutions of 2 loge 2x = loge(7x – 2 – 2x2) is
52. Let normals are drawn to the parabola y2 = 8x from any point on the line y = -4. If the locus of
vertices of triangle formed by the corresponding tangents is (x – ) (y – ) = c, then the value of
 –  + c is ____
 x  2  2x  3   x  6 
2 3
53. The number of integral values of x satisfying  0 is __________

 x  5
4
54. If  be the minimum value of y  (sin x  cosec x) 2  (cos x  sec x) 2  (tan x  cot x) 2 where
x  R . Find   6

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ALL INDIA INTEGRATED TEST SERIES

HALF COURSE TEST – II

 The test consists of total 54 questions.

 This question paper contains Three Parts.

2. Same number of mole of an ideal gas is enclosed in two identical A B

Liquid X Liquid Y Liquid Z

8. A ball of mass M is suspended from a bar of same mass with a light M

inextensible cord. The bar can slide on a frictionless slope of inclination.

9. A particle is rotating in a conical pendulum with help of a string of length  as

10. Inside a uniform spherical shell

13. A pipe in the form of a half ring of radius r is placed on a horizontal C

(B) Dil. HNO3 LiAlH4

(C) Cl2, AlCl3 Sn, conc. HCl following by NaOH

(D) LiAlH4 Cl2 in CCl4

(B) H3C H H3C Br

34. How many of the following statements is/are correct?

(5) The electronic configuration of Co ends with 3d74s2.

35. In the compound Na2 [B4O5(OH)4]8H2O, if the

Mathematics PART – III

(One or More than one correct type)

The coefficient of x2009 in the expansion of (1  x) (1  x  x 2 )2007 is ……

51. The number of solutions of 2 loge 2x = loge(7x – 2 – 2x2) is

53. The number of integral values of x satisfying  0 is __________

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