TM

HYDROCARBON
DPP - 1
JEE [MAIN + ADV.] DIVISION

HCl
1. Me  CH  CH  CH  Ph 
 W
|
Et
W is

(A) Me  CH  CH 2  CH  Ph (B) Me  CH  CH  CH 2  Ph
| | | |
Et Cl Et Cl

(C) Me  CH  CH  CH 2 (D) Cl  CH  CH  CH 2  Ph
| | | | |
Cl Et Ph Et Me

2. HCOOK + CH3COOK Electrolys

  is  Product obtained is/are:
(A) H2 (B) CH3—CH3
(C) CH4 (D) all the above

3. HBr
 Major product.

Br
Br
(A) (B)

Br
(C) (D)

Br

4. Successive alkanes differ by

(A) CH2 (B) CH
(C) CH3 (D) C2H4

5. An alkene is formed from a carbocation by

(A) Elimination of a H+ ion (B) Elimination of H– ion
(C) Addition of a H+ ion (D) Addition of a H– ion.

6. Which fo the following species is not electrohilic in nature :

(A) BH3 (B) H3O+
 
(C) NO (D) Cl
2

7. Which of the following species is an electrophile

(A) RNH (B) SO
2 3
(C) NO (D) ROH
3

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8. Which of the following acts as a nucleophile ?

(A) NO2 (B) :CCl
2



(C) NH2 (D) CH3

9. Give reactivity order towards EAR.

(i) (ii)

(iii) (iv)

(A) (i) > (ii) > (iii) > (iv) (B) (iv) > (iii) > (ii) > (i)
(C) (ii) > (iv) > (i) > (iii) (D) (iii) > (ii) > (iv) > (i)

10. Correct reactivity order for EAR of following compounds is

ph–CH=CH2 Ph2C = CH–CH3 CH2–CH–NO2

(I) (II) (III) (IV)

(A) IV > I > II > III (B) III > II > I > IV
(C) II > III > i > IV (D) II > III > IV > I

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 TM
HYDROCARBON
DPP - 1
JEE [MAIN + ADV.] DIVISION

HINT & SOLUTIONS

1. A


Me–CH–CH=CH–Ph Me–CH–CH2–CH–Ph
Et Et

H–Cl Cl

Me–CH–CH2–CH–Ph
Markwonikoff’s addition Et Cl

2. D

H–C–O + CH 3–C–O + 2 K
O O
at – e at
– e anod
anod

HCOOK + CH3COOK Electrolys

  is
 H–C–O H–C–O
O O
– CO2 – CO2
H CH3
combination
If H + H H2 ; If H + CH3 CH4
FR combination

If CH3+ CH3 CH3 –CH3 ]

FR combination

3. C


H  
Br

4. A
Successive members differ in mass by an extra methylene bridge (–CH2–unit) inserted in the chain option A is
a correct answer.

5. A
In Elimination raaction after leaving the leaving group carbocation are formed.

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6. B
Electron defincient species are knowns electrophiles. Among the given, H3O+ has lone pair of
electrons for donation, so it is not electron deficient and hence, not an elecrophile.

7. B
Sulphur trioxide SO3 is an electrophile. It can accept a pair of electron from nucleophile.
H2O , NH3 and C2H5OH are nucleophiles. They have lone pairs of electrons on heteroatom (N or O)
which can be easily donated to a suitable heteroatom.
The SO3 (an electrophile) reacts with H2O (a nucleophile) to form sulphuric acid H2SO4 .
SO3 + H2O  H2SO4

8. C
Negative charge species act as a necleophile.

9. C
EAR + (M) effect

10. B
Stability of carbocation + (M,H,I)

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