COLLE STON H£ORY MEAN EREC PArH

Mean Eree path is de fined as avemg

distance raLYelledb a molecule
beE tuoa Collision s
Eoreg
Iwilial
MeAn freR path dtdztd3|

NENO ofmolecules
VEVolumeo container
*
Na density a particleg

Collision_cliam eter (o)

I t the closegt dis tancebet the

Cen bTes of tuo molecules toking art in-
Collisionn.

b o t h paviele aire
Sam Ehen 2TN

Collisian frequency
t 1sthe mo OF Coisions ta Ka place
 per second Pe nit gaS
rse f role.iuls
TV

]Area Ja-2

hitially we LS Sume tha_except 1 -

pasticleall therPa1 ticles are
Tes
Molecule on the left males to
ght iEh Average elocituVa
Two identical malecuwes willgust_
touch each other when distance sepente
there centre o nasS S O

Thu a moving molecWe il coli

with0 ther moletules only ithere

CentreotmoS5 come within a dis tanc
o Erormits own Cen tre
 The ua atit is Iinoen aYen of
co510.n o55 5ectio

Theena mo cyinder can

dis tance toeltea by ime talkem

Vay d d Vay 1)
length of ynder

Valum Cylinder Ccan be giuen as

Vay A-t
No f molculesIn h e cylinder
Can be talculetc na

cen s
to mdtw N A Vol
cylinder- N Jo-Vau A t
inc c other roolerules a r e a t resE
illDe eqa
therefore n o oF Tno (u3
to nDOF Cotli_ionsY9ade thS-
one Partic1e

No o Collsipns

Per pxtidle
when Romon.n9 a
 We Kmoco that allparticles are n
thevefove insteack
oF CeTag veloc
of p a r t i c l e we ghald
Use ree
15 aSsume d hot/an n
atie
Nekecity t C l l i c l e u I n each
molec ules
Avexa,
othey only perpendicula.

Thereforein 2Vavgem shau

he replaced by Urelo Vow
Thusefore ro o cellisianspeT particie
1o Nyav AtE

Mean Eree poth Distence travelled_

No of Collsiob

Vavg A E-
2 o N Va t

N euN
Totalno efE bA mgle cula.r clisi ons
pes n1 e.Y UE volume is
aiven D 1OY Colision equn
Zu ZN*)

pLni 1m prr L t y o t

2
)
PV=n RT PV N x RT
NA

PNA
at Const pie charls la vAT

aa onst ieBes lau P

0Y V

Hence 7S V Les & A

ab ont V Chcu-sa 5k
PorT
Pin reas then
Taedso incoss
Samea extond hence -leores ct
T
Dependenc af Z

N 2N Vav
N Vav
Va

N RT
NA

Dependenct of z44
714 2 Vava

Vaa(N

oie
tYT collig10n5
 The dffvs bn cacFie t f n icleal g
feortisnal t ts mtan

h
retpath men sxek
B t abs
s elute
tempeTak ure of an ickca
JasS-
ned4 timS its pres Staeis ncseesce
2tine9 ASa1e Su the diffSian cefide
the dffusianLnefiient
o Enis_4
iocceaSes timeS thevalue a t S
Cntrgex).

PJERI
 e Flass A B hve quavalume
1K 8 at K
6co
mantainti a t 3o0
ontains a gas Bho antaual mat-
oF RH4 8 assume both behav
declly
Fimd: 1)F las Ks having Jeteyno- 0f msls
mal

i) tind Elask m uhirh P3Suris l .

1R3oo

PN 2B

ini) ElasK i n twhich avg yeloctty-of mdt

N)Pind Flosk w t h astater voltt at nf

afaEn s3sume callisian dua
End las Cath Aeaker u o
MolarKineiic
o laBk tsilh highex
neL nea ialue of total

Fnclo 1n Lyhich 2
4axe

-2 N* Navg
N xT P