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Sri Chaitanya IIT Academy Front Page 2021 Advance Pattern Paper - 2
Sri Chaitanya IIT Academy Front Page 2021 Advance Pattern Paper - 2
Please read the instruction carefully. You are allotted 5 minutes specifically for this purpose.
INSTRUCTIONS
GENERAL :
1. This sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.
2. The question paper CODE is printed on the left hand top corner of this sheet and the right hand top corner of
the back cover of this booklet.
3. Use the Optical Response Sheet (ORS) provided separately for answering the questions.
4. The ORS CODE is printed on its left part as well as the right part. Ensure that both these codes are identical
and same as that on the question paper booklet. If not, contact the invigilator.
5. Blank spaces are provided within this booklet for rough work.
6. Write your name and roll number in the space provided on the back cover of this booklet.
7. After breaking the seal of the booklet, verify that the booklet contains 32 pages and that all the 60 questions
along with the options are legible
8. The ORS consists of an original (top sheet) and its carbon-less copy (bottom sheet).
9. Darken the appropriate bubbles on the original by applying sufficient pressure. This will leave an impression at
the corresponding place on the carbon-less copy.
10. The original is machine-gradable and will be collected by the invigilator at the end of the examination.
11. You will be allowed to take away the carbon-less copy at the end of the examination.
13. Write your name, roll number and the name of the examination center and sign with pen in the space provided
for this purpose on the original. Do not write any of these details anywhere else. Darken the appropriate bubble
under each digit of your roll number
SYLLABUS
PHYSICS RAY-OPTICS : PLANE MIRRORS AND SPHERICAL MIRRORS SOUND
CHEMISTRY ALKYL HALIDES REAGENTS AND MECHANISM HYDROCARBONS
MATHEMATICS LIMITS INVERSE TRIGONOMETRY FUNCTIONS COMPLEX NUMBERS
JEE (ADVANCED) _2021 PI-TNTX_PAPER-II
PART-I PHYSICS
SECTION-I (Maximum Marks: 32)
f
1. A particle is dropped along the axis from a height on a concave mirror of focal length f
2
as shown in the figure. The acceleration due to gravity is g.
3
A) The maximum speed of the image is 3 fg
4
3. A particle revolves in clockwise direction (as seen from point A) in a circle C of radius 1
cm. It completes one revolution in 2 s. The axis of the circle and the principal axis of the
mirror M coincide. The radius of curvature of the mirror is 20 cm. Then the direction of
revolution (as seen from A) of the image of the particle and its speed is
A B
C
10 cm M
4. In the figure shown an observer O1 floats (static) on water surface with ears in air while
V
another observer O2 is moving upwards with constant velocity V1 in water. The
5
V
source moves down with constant velocity VS and emits sound of frequency f. The
5
velocity of sound in air is V and that is water is 4V. Select the incorrect option(s) for this
situation.
Vs V / 5
O1
V1 V / 5
O2
4V
A) The wavelength of the sound received by O1 is
5f
JEE (ADVANCED) _2021 PI-TNTX_PAPER-II
V
B) The wavelength of the sound received by O1 is
f
4V
C) The frequency of the sound received by O2 is
5
V
D) The wavelength of the sound received by O2 is
5f
5. Two plane mirrors M1 and M 2 are placed parallel to each other 20 cm apart. A luminous
small object O is placed between them at 5 cm from M1 .
A) The distances of the three nearest images from the mirror M1 are 5 cm, 35 cm and 45
cm.
B) The distances of the three nearest images from the mirror M 2 are 5 cm, 35 cm and 45
cm.
C) The distances of the three nearest images from the mirror M1 are 15 cm, 25 cm and 55
cm.
D) The distances of the three nearest images from the mirror M 2 are 15 cm, 25 cm and 55
cm.
6. Magnification due to a spherical mirror of small aperture is same numerically by placing
point size object at a distance of 10 cm or 20 cm from the mirror. Select the correct
option(s).
A) Getting same magnification is not possible for two different object distances
D) Distance between images in the two cases mentioned is four times the focal length.
JEE (ADVANCED) _2021 PI-TNTX_PAPER-II
SECTION-II (Maximum Marks: 18)
This section contains THREE (03) question stems.
There are TWO (02) questions corresponding to each question stem.
•The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the
on-screen virtual numeric keypad.
• If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.
The r.m.s. speed of hydrogen molecules at 27 C is v. Speed of sound in hydrogen is av. The
hydrogen gas is now heated to 927 C where the gas splits to atomic hydrogen. Speed of sound
at 927 is bv.
A car moving towards a vertical wall with a speed of 20 m s 1 sounds a horn of frequency
765 Hz . The wall is moving away from the car such that their relative velocity of separation is
20 m s 1 . Also, there is a wind that is blowing in the direction from car towards the wall at a
speed of 20 m s 1 . The speed of sound in still air is 340 m s 1 . The wavelength of sound
waves returning towards the car after reflection from the wall is . The frequency of the echo of
the horn received by the driver of the car is f.
A) Circular B) Parabolic
C) Elliptical D) Hyperbolic
14. What is the height of the bottom-most part of the lit portion of the wall above the level of
road?
A) 2 m B) 7.5 m
C) 9 m D) 12 m
JEE (ADVANCED) _2021 PI-TNTX_PAPER-II
PARAGRAPH-II FOR QUESTION NOS. 15-16
16. In the resultant wave formed after reflection, the maximum and minimum values of
particle speeds in medium are
17. As shown in the fig two loudspeakers are located at point A and B. Both are vibrating in
phase at a frequency 100 Hz and P1 8 W and P2 18 W are their respective
powers. Point C lies on a line joining two loudspeakers at a distance of d1 from A and
d2 1.5 m from B. Assume that loudspeakers behave like isotropic point sources. When
both the speakers are switched on, then find the intensity (in W / m2 ) at point C?
[Velocity of sound 300 ms1 ]
P1 P2
A C B
d1 d2
18. In the given arrangement, a source is placed at the fixed end of the spring with spring
constant100 N m1 . Receiver is attached to the moving end of the spring, which in turn
is connected to a box of mass 4 kg. The block oscillates horizontally with an amplitude of
oscillation 2 m. If the source emits a frequency of 990 Hz then frequency bandwidth
received by the receiver is 10n Hz. Find the value of n. [speed of sound 330 m s 1 ]
19. A square ABCD of side 1 mm is kept at distance 15 cm in front of the concave mirror as
shown in the figure. Edge AD is along the optical axis. The focal length of the mirror is 10
cm. The length of the perimeter of its image will be approximately x mm. Find the value of
x 4.
B C
A D
15cm
JEE (ADVANCED) _2021 PI-TNTX_PAPER-II
PART-II CHEMISTRY
SECTION-I (Maximum Marks: 32)
20.
A) B) C) D)
21. Which of the following reaction will go faster if the concentration of the reagent is
increased?
H Br Br
A) CH 3 O
B) CH 3 S
Br
Acetone
KI
A)
B)
C)
D)
t Bu O K
A) CH3 CH 2 CH CH3
|
Br
CH3CH 2 O K
B) CH3 CH 2 CH CH3
|
F
CH3
OH
C) CH3 CH 2 CH N CH3
|
CH3
CH3
OH
D) CH3 CH 2 CH CH3
|
S(CH3 )2
JEE (ADVANCED) _2021 PI-TNTX_PAPER-II
24. Which of following will give syn-elimination on heating?
CH3
|
C) CH3CH 2CH 2 O C S CH3 D) CH3CH 2CH 2 N O
|| |
S CH3
A) B)
C) D)
JEE (ADVANCED) _2021 PI-TNTX_PAPER-II
SECTION-II (Maximum Marks: 18)
This section contains THREE (03) question stems.
There are TWO (02) questions corresponding to each question stem.
• The answer to each question is a NUMERICAL VALUE.
•For each question, enter the correct numerical value corresponding to the answer in the designated place using the mouse and the
on-screen virtual numeric keypad.
•If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
•Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks: 0 In all other cases.
26. Find the molar mass of E and divide it by the difference in the positions of the
substituents.
(i) Among them, the number of structures that give symmetrical compounds on reductive
ozonolysis are x .
(ii) The number of products obtained on doing bromination in CCl4 of the compounds in (I)
are y .
(iii) The number of compounds in (I) whose products of reductive ozonolysis give enol as the
major form in equilibria are z .
30. Report x .
31. Report z /y .
JEE (ADVANCED) _2021 PI-TNTX_PAPER-II
Two isomeric alkynes A and B have molecular formula C8H14 . A on treatment with ammonical
AgNO3 solution forms a white precipitate while B on similar treatment formed no precipitate.
Also both A and B are chiral and hydrogenation of either A or B with H2 / Pt gives the same
achiral hydrocarbon C C8H18 . Treatment of A with HgSO4 / H2SO4 (aq) gives D(C8H16O) as
major product while similar treatment of B, mixture of D and E in comparable amounts are
formed.
A) B)
C) D)
Compound which rotates the plane polarised light is known as optically active compound. On
the basis of direction of rotation, two forms of an optically active compounds are termed as
dextro and laevo rotatory. The two are termed as enantiomers. If we have a 1 : 1 mixture of d
and l isomers of a given chiral compound, optical rotation of such mixture is zero. Such a
mixture is optically inactive and is called a racemic modification.
The net specific rotation of any mixture of the d and l isomers of a given chiral
compound is equal to the weighted average of the rotations due to both the isomers.
Mathematically, it can be expressed as:
Where f d and fl are fractions of d and l isomers respectively and ad , al are their specific
rotations.
34. The pure d isomer of certain chiral compound has d 55 . A non racemic mixture of
25
this compound has a net d 11 . What is the fraction of this isomer in mixture?
25
A) 0.40 B) 0.60
C) 0.30 D) 0.70
35. What is the enantiomeric excess in any pure sample of an optically active substance?
A) 50% B) 100%
36. How many of the following undergo solvolysis reaction faster than benzyl chloride?
37. For the isomeric alkenes corresponding to molecular formula C4H8 , how many products
are formed by addition of Br2 in CCl4 .
38. If a pure enantiomer of 5-bromo-2-hexene is treated with Br2 CCl4 , how many
different tribromides would be formed?
JEE (ADVANCED) _2021 PI-TNTX_PAPER-II
PART-III MATHEMATICS
SECTION-I (Maximum Marks: 32)
A) B) | /
C) 2 / 12 D) 3
x2
a a x 2 2
A) a 2 B) a 1
1 1
C) L D) L
64 32
JEE (ADVANCED) _2021 PI-TNTX_PAPER-II
41. Let z1, z2 , z3 be complex numbers such that | z1 | | z2 | | z3 | 1and
z12 z22 z32
1, then value of | z1 z2 z3 | can be
z2 z3 z3 z1 z1z2
A) 1 B) 2 C) 3 D) 4
42.
If f ( x) sin 1 x 2 ln x [ x] cot 1
1
1 2x
2
then (Note: [k] and {k} denotes the
greatest integer and fractional part functions of k respectively)
13
C) range of f ( x) is ,
4 8
A) a b c 1 B) a b c 2
3
C) f (1) D) f (1) 1
4
x2 1 1 2 x 2
44. If sum of solutions of the equation cos 2 1
tan 2 is then
x 1 x 1 3
A) is equal to 2
B) | x 5 | | x 4 | has 2 distinct solutions
C) is equal to 5
D) | x 10 | | x 7 | has no solution
JEE (ADVANCED) _2021 PI-TNTX_PAPER-II
SECTION-II (Maximum Marks: 18)
Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.
b cos(2cos1 x sin 1 x)
1
46. If a 2 26 / 51, then 2 is equal to
b
2 2
Let cos i sin and and .
2 4 3 5 6
7 7
48. The value of is equal to
4
JEE (ADVANCED) _2021 PI-TNTX_PAPER-II
Question Stem for Question Nos. 49-50
Question Stem
1 1 (1 ax)
Consider the limit lim exists, finite and has the value equal to l (where a,
x 0 x3 1 x (1 bx)
b are real constants), then:
b
50. The value of is equal to
l
JEE (ADVANCED) _2021 PI-TNTX_PAPER-II
SECTION-III (Maximum Marks: 12)
• This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
• For each question, choose the option corresponding to the correct answer.
• Answer to each question will be evaluated according to the following marking scheme:
For √
A circular arc of radius 1 subtends an angle of radian as shown in figure. The centre of the
circle is and the point is the intersection of two tangent lines at and . Let ( ) be the
area of and ( ) be the area of shaded region.
T ( x)
53. lim is
x 0 x 3
A) B)
C) D)
S ( x)
54. lim is
x 0 x
A) 0 B)
C) 2 D) 2
JEE (ADVANCED) _2021 PI-TNTX_PAPER-II
SECTION-IV (Maximum Marks: 12)
This section contains THREE (03) questions.
• The answer to each question is a NON-NEGATIVE INTEGER.
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual numeric keypad
in the place designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.
2x 1 1 2 x 1
55. Let x1, x2 , x3 be the solutions of tan 1 tan
1
2tan x 1 where
x 1 x 1
x1 x2 x3 , then is equal to
56. If the range of function
( ) ( √ ) ( ) √ is , ) then find the
value of