Professional Documents
Culture Documents
Pr-124 - Ghs Msds (Eng)
Pr-124 - Ghs Msds (Eng)
Pr-124 - Ghs Msds (Eng)
1. IDENTIFICATION
A. Product name
- PR-124
2. HAZARD IDENTIFICATION
A. GHS Classification
- Flammable liquids : Category2
- Skin corrosion/irritation : Category2
- Skin sensitization : Category1
- Carcinogenicity : Category2
- Reproductive toxicity : Category2
- Specific target organ toxicity(Single exposure) : Category3(Narcotic effects)
- Specific target organ toxicity(Repeated exposure) : Category2
- Aspiration hazard : Category1
○ Signal words
- Danger
○ Hazard statements
- H225 Highly flammable liquid and vapour
2/9
3. COMPOSITION/INFORMATION ON INGREDIENTS
B. Skin contact
- Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
- Wash contaminated clothing thoroughly before re-using.
- Get medical attention immediately.
- Go to the hospital immediately if symptoms(flare, irritate) occur.
- Wash thoroughly after handling.
C. Inhalation contact
- When exposed to large amounts of steam and mist, move to fresh air.
- Take specific treatment if needed.
- Get medical attention immediately.
- If breathing is stopped or irregular, give artificial respiration and supply oxygen.
D. Ingestion contact
- Please be advised by doctor whether induction of vomit is demanded or not.
- Rinse your mouth with water immediately.
- Get medical attention immediately.
- If swallowed, large amounts of water to drink and do not induce vomiting.
E. Delayed and immediate effects and also chronic effects from short and long term exposure
- Not available
F. Notes to physician
- Notify medical personnel of contaminated situations and have them take appropriate protective measures.
- If exposed or concerned, get medical attention/advice.
5. FIREFIGHTING MEASURES
A. Suitable (Unsuitable) extinguishing media
- Dry chemical, carbon dioxide, regular foam extinguishing agent, spray
- Avoid use of water jet for extinguishing
B. Environmental precautions
- Prevent runoff and contact with waterways, drains or sewers.
- If large amounts have been spilled, inform the relevant authorities.
B. Engineering controls
5/9
- Business owner is recommended to maintain below recommended exposure limits for the working place with general exhaust of
gas/vapour/mist/fume.
A. Appearance
- Appearance Liquid(Viscous liquid)
- Color Not available
B. Odor Not available
C. Odor threshold Not available
D. pH Not available
E. Melting point/Freezing point Not available
F. Initial Boiling Point/Boiling Ranges 56.1 ℃
G. Flash point 30 ℃
H. Evaporation rate Not available
I. Flammability(solid, gas) Not available
J. Upper/Lower Flammability or explosive limits Not available
K. Vapour pressure Not available
L. Solubility Not available
M. Vapour density Not available
N. Specific gravity(Relative density) Not available
O. Partition coefficient of n-octanol/water Not available
P. Autoignition temperature Not available
Q. Decomposition temperature Not available
R. Viscosity Not available
S. Molecular weight Not available
C. Conditions to avoid
- Avoid contact with incompatible materials and condition.
- Avoid : Accumulation of electrostatic charges, Heating, Flames and hot surfaces
- Avoid contact with heat, sparks, flame or other ignition sources.
6/9
D. Incompatible materials
- Not available
B. Delayed and immediate effects and also chronic effects from short and long term exposure
○ Acute toxicity
* Oral
- Product (ATEmix) : 2000mg/kg < ATEmix <= 5000mg/kg
- [Methyl Ethyl Ketone] : LD50 2737 ㎎/㎏ Rat (RTECS, ChemIDPlus)
- [Toluene] : LD50 5580 ㎎/㎏ Rat (EU Method B.1) (ECHA)
- [Acetone] : LD50 = 5280 ㎎/㎏ Rat (EHC(1990), SIDS(1997))
- [Cyclohexanone] : LD50 1890 ㎎/㎏ Rat (ECHA)
* Dermal
- Product (ATEmix) : >5000mg/kg
- [Methyl Ethyl Ketone] : LD50 6480 ㎎/㎏ rabbit (RTECS, ChemIDPlus)
- [Toluene] : LD50 >5000 ㎎/㎏ Rabbit (ECHA)
- [Acetone] : LD50 = 12870 ㎎/㎏ rabbit (EHC(1990), PATTY(1994), SIDS(1997))
- [Cyclohexanone] : LD50 1000 ㎎/㎏ Rabbit (HSDB, AIHA)
* Inhalation
- Product (ATEmix) : 20.0mg/L < ATEmix <= 50.0mg/L
- [Methyl Ethyl Ketone] : Vapor LC50 32 ㎎/ℓ 4 hr Mouse (RTECS)
- [Toluene] : LC50 >20 ㎎/ℓ Rat (OECD TG 403) (ECHA)
- [Acetone] : LC50 = 76 mg/L/4hr Rat (SIDS)
- [Cyclohexanone] : LC50 >6.2 ㎎/ℓ/4 hr Rat (ECHA)
○ Skin corrosion/irritation
- Causes skin irritation
○ Serious eye damage/irritation
- Not available
○ Respiratory sensitization
- Not available
○ Skin sensitization
- May cause an allergic skin reaction
○ Carcinogenicity
* IARC
- [Toluene] : Group 3
- [polyurethane] : Group 3
- [Cyclohexanone] : Group 3
* OSHA
- Not available
* ACGIH
- [Toluene] : A4
- [Acetone] : A4
- [Cyclohexanone] : A3
* NTP
- Not available
7/9
* EU CLP
- Not available
○ Germ cell mutagenicity
- Not available
○ Reproductive toxicity
- Suspected of damaging fertility or the unborn child
○ STOT-single exposure
- May cause drowsiness and dizziness.
○ STOT-repeated exposure
- May cause damage to organs through prolonged or repeated exposure
○ Aspiration hazard
- May be fatal if swallowed and enters airways
C. Bioaccumulative potential
○ Bioaccumulative potential
- Not available
○ Biodegradation
- [Methyl Ethyl Ketone] : 98 % 28 day (OECD TG 301D)
- [Toluene] : 80 % 20 day (Readily biodegradable) (ECHA)
- [Acetone] : 62% 5 day (OECD TG 301B)(ECHA)
- [Cyclohexanone] : 90 ~ 100 % 28 day (ECHA)
D. Mobility in soil
- [Cyclohexanone] : Koc 15.15
C. Hazard Class
-3
E. Marine pollutant
- Not applicable
- [Toluene] : Applicable
○ Rotterdam Convention listed ingredients
- Not applicable
○ Stockholm Convention listed ingredients
- Not applicable
○ Montreal Protocol listed ingredients
- Not applicable
B. Issue date
- 2020-05-25
D. Other
- This SDS is prepared according to the Globally Harmonized System (GHS).