APPENDIXES

Appendix particle size -1-

-A- Aluminum
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Appendix particle size -1-

-B- Cupper
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Appendix particle size -1-

-C- Magnesium
 APPENDIXES
Appendix XRD-2-

-A- Aluminum

*** Basic Data Process ***

AL

2 theta dm ds I/IO hkL

38.80 2.319 2.338 100 (111)

45.040 2.0111 2.024 47 (200)

65.400 1.4258 1.431 22 (220)

78.480 1.217 1.221 22 (311)

Appendix XRD-2-

-B- Cupper

*** Basic Data Process ***

Cu

2 theta dm ds I/IO hkL

43.44 2.0814 2.088 100 (111)

50.580 1.803 1.808 42 (200)

74.240 1.276 1.278 21 (220)

90.020 1.0892 1.090 19 (311)

95.200 1.0431 1.0436 9 (222)

Appendix XRD-2-

-C- Magnesium

*** Basic Data Process ***

Mg

2 theta dm ds I/IO hkL

36.80 2.4403 2.4519 100 (111)

32.380 2.7626 2.7782 27 (100)

47.980 1.8946 1.900 18 (102)

63.200 1.470 1.4730 20 (103 )

87.780 1.3638 1.366 20 (112)

 APPENDIXES

Appendix XRD-3-

Base alloy (compact 450Mpa and sintering temperature at 560C°)

Group :( Al-4.5%Cu-1.5%Mg)

AL 2 theta dm ds I/IO

38.627 2.329 2.338 100

44.895 2.0173 2.024 52

65.255 1.4286 1.4310 28

78.406 1.2186 1.2210 31

Al2CuMg

2 theta dm ds I/IO

38.627 2.329 2.315 100

65.255 1.4286 1.416 28

82,6012 1.1671 1.184 8

Mg2Cu6Al5

2 theta dm ds I/IO

44.895 2.0173 2.027 52

82.6012 1.1671 1.167 8

 APPENDIXES

Appendix XRD-4-Al2O3

AL
Al2CuMg

2 theta dm ds I/IO

68 1.391 1.377 100

57.5 1.602 1.60 10

52.5 1.701 1.742 5

43.5 2.019 2.0782 5

35 2.596 2.566 80
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Appendix XRD-5-(2.5%Al2O3+2.5%SiO2) after corrosion

AL
Al2Cu
Al2CuMg

Al2Cu 2 theta dm ds I/IO

47.302 1.920 1.92 100

38.459 2.338 2.38 84

47.302 1.920 1.90 80

56.115 1.6376 1.61 37

65.074 1.432 1.41 13

Al2CuMg 2 theta dm ds I/IO

38.459 2.330 2.311 100

44.7018 2.0256 2.016 30

36.5072 2.4540 2.442 3

47.3024 1.92014 1.942 20

50.4191 1.898 1.836 9

56.1150 1.6376 1.633 7

 APPENDIXES

Appendix AFM -1-

A-Nano alumina

Granularity Cumulation Distribution Report

Sample:Al 2 O 3 nano powder
Instrument:CSPM
Avg. Diameter:50 nm

Diameter(nm)< Volume(%) Cumulation(%) Diameter(nm)< Volume(%) Cumulation(%) Diameter(nm)< Volume(%) Cumulation(%)

25.00 0.79 0.79 55.00 3.17 11.90 85.00 5.56 57.94

30.00 1.59 2.38 60.00 3.97 15.87 90.00 7.94 65.87
35.00 0.79 3.17 65.00 4.76 20.63 95.00 8.73 47.60
40.00 3.17 6.35 70.00 12.70 33.33 100.00 0.79 50.33
45.00 1.59 7.94 75.00 10.32 43.65 105.00 9.52 92.86
50.00 0.79 8.73 80.00 8.73 42.38 110.00 7.14 100.00
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Appendix AFM -3-

C-(Al-4.5%Cu-1.5%Mg)+(2.5%Al 2 O 3 +2.5%SiO 2 )

Granularity Cumulation Distribution Report

Sample: Mixed powders Code: (Al-4.5%Cu
1.5%Mg)+(2.5%Al 2 O 3 +2.5%SiO 2 )
Instrument: CSPM
Avg. Diameter:80.52 nm

Diameter(nm)< Volume(%) Cumulation(%) Diameter(nm)< Volume(%) Cumulation(%) Diameter(nm)< Volume(%) Cumulation(%)

80.00 53.33 53.33 100.00 38.33 91.67 100.00 8.33 80.00

 APPENDIXES

Appendix AFM -4-

A-(5%Al 2 O 3 ) After Corrosion

Granularity Cumulation Distribution Report

Sample:5%Al 2 O 3 nano powder
Instrument: CSPM
Avg. Diameter :50 nm
Diameter Volum Cumulati Diameter Volum Cumulati Diameter Volum Cumulati
(nm)< e(%) on(%) (nm)< e(%) on(%) (nm)< e(%) on(%)
20.00 0.74 0.74 50.00 3.12 11.50 80.00 5.51 57.89
30.00 1.59 2.38 60.00 3.97 15.87 90.00 7.94 65.87
40.00 3.17 6.35 70.00 12.70 33.33 100.00 0.79 92.86
50.00 0.79 8.73 80.00 8.73 42.38 110.00 7.14 100.00
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Appendix AFM -4-

B-(5%SiO2) After Corrosion

Sample: 5%SiO2nano powder

Instrument: CSPM
Avg. Diameter: 25 nm

Diameter( Volume Cumulatio Diameter Volume Cumulatio Diameter Volume Cumulati

nm)< (%) n(%) (nm)< % n(%) (nm)< (%) on%
20.00 5.87 5.87 30.00 15.72 62.32 35.00 12.00 100.00
25.00 21.87 27.73 32.00 13.32 74.67
30.00 17.87 45.60 34.00 13.33 87.00
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Appendix AFM -4-

C-(2.5%Al 2 O 3 +2.5%SiO 2 ) after Corrosion

Sample: (2.5%Al 2 O 3 +2.5%SiO 2 )

Instrument: CSPM
Avg. Diameter:80 nm

Diameter(nm)< Volume(%) Cumulation(%) Diameter(nm)< Volume(%) Cumulation(%) Diameter(nm)< Volume(%) Cumulation(%)

80.00 53.33 53.33 100.00 38.28 91.62 100.00 8.00 80.00

 APPENDIXES

Appendix – 3- Tafel Test

A-Base alloy(Al-4.5%Cu-1.5%Mg) at different sintering temperatures

Figure(5-26) Tafel test for the base alloy (Al-4.5%Cu-1.5%Mg) at 520C

Figure(5-27) Tafel test for the base alloy (Al-4.5%Cu-1.5%Mg) at 540C

 APPENDIXES

Figure(5-28) Tafel test for the base alloy (Al-4.5%Cu-1.5%Mg) at 560C°

Figure(5-29) Tafel test for the base alloy (Al-4.5%Cu-1.5%Mg) at 580C

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Figure(5-30) Tafel test for the base alloy (Al-4.5%Cu-1.5%Mg) at 600C

B-Base alloy(Al-4.5%Cu-1.5%Mg) reinforced with nanoparticles

Figure(5-31) Tafel test for the base alloy (Al-4.5%Cu-1.5%Mg) reinforced 1%NanoAl2O3
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Figure(5-32) Tafel test for the base alloy (Al-4.5%Cu-1.5%Mg) reinforced 3%NanoAl2O3

Figure(5-33) Tafel test for the base alloy (Al-4.5%Cu-1.5%Mg) reinforced 5%NanoAl2O3
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Figure(5-34) Tafel test for the base alloy (Al-4.5%Cu-1.5%Mg) reinforced 1%NanoSiO2

Figure(5-34) Tafel test for the base alloy (Al-4.5%Cu-1.5%Mg) reinforced 3%NanoSiO2
 APPENDIXES

Figure(5-35) Tafel test for the base alloy (Al-4.5%Cu-1.5%Mg) reinforced 5%NanoSiO2

Figure(5-36) Tafel test for the base alloy (Al-4.5%Cu-1.5%Mg) reinforced

(2.5%Al2O3+SiO2)
 APPENDIXES

Appendix – 6-

Chemical Composition of sintered base alloy