WARNING - NEW EMERGENCY TELEPHONE NUMBER : +1-703-741-5970 

SAFETY DATA SHEET

Product: OLERIS® ESTEROL A Page: 1 / 6

SDS No.: 000658-001 (Version 1.0) Date 2018/04/11

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Substance name:
Fatty acids, C16-18 and C18-unsatd., Me esters
CAS-No.: 67762-38-3

Recommended use of the chemical and restrictions on use :

Use of the Substance/Mixture : Lubrification., Emulsifier, Additive, Lamp Oil

Company/Undertaking Identification:
Supplier ARKEMA - France
420 rue d’Estienne d'Orves
92705 Colombes Cedex, FRANCE
Telephone: +33(0)1 49 00 80 80
Telefax: +33(0)1 49 00 83 96
E-mail address: http://www.arkema.com

Emergency telephone number +65 31581074

[XXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXX See Emergency Number on the top of the page]

2. HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture:

Skin irritation, Category 3, H316

Additional information:
For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2. Label elements:

GHS-Labelling

Signal word: Warning

Hazard statements:
H316 : Causes mild skin irritation.

Precautionary statements:
Prevention:
P280 : Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.

2.3. Other hazards:

Potential health effects:

Irritation: Slightly irritating to skin.

Environmental Effects:
Readily biodegradable. Potentially bioaccumulable

Physical and chemical hazards:

At high temperature : Thermal decomposition into organic vapours forming explosive mixtures with air
Decomposition products: See chapter 10

3. COMPOSITION/INFORMATION ON INGREDIENTS

This product is a substance.

CAS-No.: 67762-38-3
1
: See chapter 14 for Proper Shipping Name

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4. FIRST AID MEASURES

4.1. Description of necessary first-aid measures:

General advice:
Take off immediately all contaminated clothing.

Inhalation:
Inhalation of vapours/mists Move to fresh air. Oxygen or artificial respiration if needed. In case of problems : Consult a physician.

Skin contact:
Wash immediately, abundantly and thoroughly with soap and water.

Eye contact:
Wash immediately, abundantly and thoroughly with water. If irritation persists, consult an ophthalmologist.

Ingestion:
In case of problems : Consult a doctor.

4.2. Most important symptoms/effects, acute and delayed: No data available.

4.3. Indication of immediate medical attention and special treatment needed, if necessary: No data available.

5. FIREFIGHTING MEASURES

5.1. Extinguishing media:

Suitable extinguishing media:

Foam, Dry powder, Carbon dioxide (CO2)

Unsuitable extinguishing media:

Water

5.2. Specific hazards arising from the chemical:

At high temperature :, Thermal decomposition into organic vapours forming explosive mixtures with air

5.3. Advice for firefighters:

Specific methods:
Ensure a system for the rapid emptying of containers. In case of fire nearby, remove exposed containers. Containers/tanks should be cooled
with water spray.

Special protective actions for fire-fighters:

In the event of fire, wear self-contained breathing apparatus.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures:

Avoid contact with the skin and the eyes.

6.2. Environmental precautions:

Do not release into the environment. Do not let product enter drains. Dam up with sand or inert earth (do not use combustible materials).

6.3. Methods and materials for containment and cleaning up:

Recovery:
Pump into a labelled inert emergency tank. Shovel into suitable container for disposal. Absorb the remainder with an inert absorbent material.
(do not use sawdust, prohibit the use of cloths or rags)

Elimination:
Destroy the product by incineration (in accordance with local and national regulations).

6.4. Reference to other sections: None.

7. HANDLING AND STORAGE

7.1. Precautions for safe handling:

Technical measures/Precautions:
Storage and handling precautions applicable to products: Liquid. Slightly irritating. viscous

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Provide appropriate exhaust ventilation at machinery. Provide showers, eye-baths.

Safe handling advice:

Clean up puddles of product immediately. Well ventilate empty vats and tanks before entering.

Hygiene measures:
Avoid contact with the skin and the eyes. When using do not eat, drink or smoke.
Wash hands after handling. Remove contaminated clothing and protective equipment before entering eating areas.

7.2. Conditions for safe storage, including any incompatibilities:

Keep tightly closed in a dry and cool place. Provide a catch-tank in a bunded area.

Keep in a dry, cool place. Store in closed containers, in a secure area to prevent container damage and subsequent spillage.

Do not store below: 5 °C, (to maintain the technical properties of the product).

Packaging material:
Recommended: Ordinary steel

7.3. Specific end use(s): None.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters:

Exposure Limit Values Not relevant

8.2. Exposure controls:

General protective measures: Ensure sufficient air exchange and/or exhaust in work areas

Personal protective equipment:

Hand protection: Gloves (synthetic rubber, plastic materials)
Eye/face protection: Safety glasses
Skin and body protection: Non-skid boots.

Environmental exposure controls:

See chapter 6

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance:
Physical state (20°C): liquid
Colour: light yellow
Odour: slight
Olfactory threshold: Not relevant
pH: No data available.
Freezing point : 6.3 °C (OECD Test Guideline 102)
Freezing point : 6.3 °C (OECD Test Guideline 102)
Boiling point/boiling range : 354.3 °C (OECD Test Guideline 103)
Flash point: closed cup: 173 °C (ISO 3679)
Evaporation rate: No data available.
Flammability (solid, gas):
Flammability: Not applicable
Vapour pressure: 3.6 hPa , at 20 °C (NF T 20-048)
4.2 hPa , at 25 °C (NF T 20-048)
0.00048 hPa , at 25 °C ((D.S.C.))
Vapour density: No data available.
Relative density (Water=1): 0.8881 at 20 °C (OECD Test Guideline 109)
Water solubility: < 0.023 mg/l insoluble at 20 °C (OECD Test Guideline 105)
Partition coefficient: n-octanol/water: log Kow : = 6.2 , at 25 °C (OECD Test Guideline 117)
Auto-ignition temperature: 261 °C (Standard NF T 20 037 - DIN 51794)
Decomposition temperature: No data available.
Viscosity, dynamic: 6.1 mPa.s , at 20 °C
Explosive properties:

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Explosivity: Not relevant (due to its chemical structure)

Oxidizing properties: Not relevant (due to its chemical structure)

9.2. Other data: None.

10. STABILITY AND REACTIVITY

10.1. Reactivity: No data available.

10.2. Chemical stability:

The product is stable under normal handling and storage conditions.
After a long cooling period, possible formation of :, Crystals of methyl esters of saturated fatty acids

10.3. Possibility of hazardous reactions:

None reasonably foreseeable.

10.4. Conditions to avoid:

Temperatures below 5 °C
(to maintain the technical properties of the product).

10.5. Incompatible materials to avoid: No data available.

10.6. Hazardous decomposition products:

At high temperature :, Thermal decomposition into organic vapours forming explosive mixtures with air

11. TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects:

Acute toxicity:

Ingestion: Slightly harmful by ingestion

• In animals : No mortality/Rat: 2000 mg/kg bw

Dermal: Slightly harmful in contact with skin

• In animals : No mortality/Rat: 2000 mg/kg bw

Local effects ( Corrosion / Irritation / Serious eye damage ):

Skin contact: Slightly irritating to skin.

• In animals : Mild skin irritation (After semi-occlusive contact, Rabbit, Exposure time: 4 h)

Eye contact: Not irritating to the eyes.

• In animals : Slightly or not irritating to eyes (Rabbit)

Respiratory or skin sensitisation:

Inhalation: No data available.

Skin contact: Not a skin sensitizer

• In animals : No skin allergy was observed (Guinea pig)

CMR effects :

Mutagenicity: According to available experimental data: Not genotoxic

In vitro
Ames test in vitro: Inactive (Method: OECD Test Guideline 471)
In vitro chromosomal abnormality test on human lymphocytes: Inactive (Method: OECD Test Guideline
473)
In vitro gene mutations test on mammalian cells: Inactive (Method: OECD Test Guideline 476)

In vivo
Micronucleus test in vivo mouse: Inactive

Carcinogenicity: No data available.

Reproductive toxicity:

Fertility:

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• In animals : Absence of toxic effects on fertility

NOAEL ( Parental toxicity ): 1,000 mg/kg bw/day
NOAEL ( Fertility ): 1,000 mg/kg bw/day
NOAEL ( Developmental Toxicity ): 1000 mg/kg bw/day
(Method: OECD Test Guideline 422, Rat, By oral route)

Specific target organ toxicity :

Single exposure : No data available.

Repeated exposure: No specific toxic effects to rats

• In animals : By oral route: No adverse effect has been observed in chronic toxicity tests.
NOAEL= 1000mg/kg bw/day (Method: OECD Test Guideline 422, Rat)

Aspiration hazard: No data available.

12. ECOLOGICAL INFORMATION

12.1. Acute toxicity :

Fish: No effect up to the limit of solubility

LC50, 96 h (Danio rerio (zebra fish)) : > 0.26 mg/l (Method: OECD Test Guideline 203, pH: 7.7)

Aquatic invertebrates: No effect up to the limit of solubility

LR50, 48 h (Daphnia magna (Water flea)) : > 5 mg/l (Method: OECD Test Guideline 202, pH: 7.8,
Immobilization)

Aquatic plants: No effect up to the limit of solubility

EC50, 72 h (Pseudokirchneriella subcapitata) : > 0.131 mg/l (Method: OECD Test Guideline 201,
growth rate inhibition)

Aquatic toxicity / Long term toxicity:

Aquatic plants: NOEC r, 72 h (Pseudokirchneriella subcapitata) : > 1 mg/l (Method: OECD Test Guideline 201, growth
rate inhibition)

12.2. Persistence and degradability :

Biodegradation (In water): Readily biodegradable

75 % after 28 d (Method: OECD Test Guideline 301 B)

Photodegradation (In air):

Direct photolysis (Half-life) : 1.7 h

12.3. Bioaccumulative potential :

Bioaccumulation: Potentially bioaccumulable.
Partition coefficient: n-octanol/water: log Kow : = 6.2 , at 25 °C (Method: OECD Test Guideline 117)

12.4. Mobility in soil - Distribution among environmental compartments:

Distribution among environmental compartments :

Water: 11.5 %
Air: 0.3 %
Soil: 1.6 %
sediment: 86.6 %

Vapor pressure: 3.6 hPa, 20 °C, (Method: NF T 20-048)

4.2 hPa, 25 °C, (Method: NF T 20-048)
0.00048 hPa, 25 °C, (Method: (D.S.C.))

Absorption / desorption: log Koc: 5.6 ( Method: OECD Test Guideline 121 )

12.5. Results of PBT and vPvB assessment :

According to REACH regulation, annex XIII, the substance does not meet PBT and vPvB criteria.

12.6. Other adverse effects: None known.

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13. DISPOSAL CONSIDERATIONS

13.1. Waste treatment:

Disposal of product: Do not dispose of waste into sewer. Destroy the product by incineration (in accordance with local and
national regulations).

Disposal of packaging: Do not release into the environment. Destroy packaging by incineration at an approved waste disposal
site. In accordance with local and national regulations.

14. TRANSPORT INFORMATION

Not classified as dangerous in the meaning of transport regulations.

15. REGULATORY INFORMATION

Not listed Stockholm Convention on Persistent Organic Pollutants (POPs)

Not listed Montreal Protocol. Substances that Deplete the Ozone Layer, as amended
Not listed Kyoto Protocol to the United Nations Framework Convention on Climate Change,
Annex A, Greenhouse Gases
Not listed Rotterdam Convention on the Prior Informed Consent (PIC) Procedure for Certain
Hazardous Chemicals and Pesticides in International Trade
Not listed International Chemical Weapons Convention (CWC) Schedules of Toxic Chemicals
and Precursors

INVENTORIES:
EINECS: Conforms to
TSCA: Conforms to
DSL: All components of this product are on the Canadian DSL
IECSC (CN): Conforms to
ENCS (JP): Conforms to
ISHL (JP): Conforms to
KECI (KR): Conforms to
PICCS (PH): Conforms to
AICS: Conforms to
NZIOC: Conforms to

16. OTHER INFORMATION

Full text of H, EUH-phrases referred to under sections 2 and 3

H316 Causes mild skin irritation.

Update:

Safety datasheet sections which have been updated: Type:

Product name Revisions
15 Inventories Additions

Thesaurus:
NOAEL : No Observed Adverse Effect Level (NOAEL)
LOAEL : Lowest Observed Adverse Effect Level (LOAEL)
bw : Body weight
food : oral feed
dw : Dry weight

This information applies to the PRODUCT AS SUCH and conforming to specifications of ARKEMA. In case of formulations or mixtures, it is
necessary to ascertain that a new danger will not appear. The information contained is based on our knowledge of the product, at the date of
publishing and it is given quite sincerely. Users are advised of possible additional hazards when the product is used in applications for which it
was not intended. This sheet shall only be used and reproduced for prevention and security purposes. The references to legislative, regulatory
and codes of practice documents cannot be considered as exhaustive. It is the responsibility of the person receiving the product to refer to the
totality of the official documents concerning the use, the possession and the handling of the product. It is also the responsibility of the handlers of
the product to pass on to any subsequent persons who will come into contact with the product (usage, storage, cleaning of containers, other
processes) the totality of the information contained within this safety data sheet and necessary for safety at work, the protection of health and the
protection of environment.

NB: In this document the numerical separator of the thousands is the "." (point), the decimal separator is "," (comma).

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