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VI–Chemistry (Vol–IV) Olympiad Class

Olympiad Work
Text Book
Book

CUQ
1. As per the modern periodic law the physical and chemical properties of elements
are periodic functions of their________.
1) Atomic weight 2) Electronic configuration
3) Density 4) Atomic size
2. Long form of periodic table has :
1) 8 horizontal columns & 8 vertical rows
2) 7 horizontal rows & 18 vertical columns
3) 10 horizontal columns and 14 vertical rows
4) 14 horizontal columns and 10 vertical rows
3. Elements of IVB and III B are called :
1) Normal elements 2) Transition elements
3) Alkaline earth metals 4) Alkali metals.
4. Father of modern periodic table is ________.
1) mendeleev 2) Dober neir 3) Mosley 4) Newland
5. Which of the following group contains coinage metals :
1) IB 2) II B 3) III B 4) IV B
6. The electronic configuration of Rb :
1) 2s1 2) 3s1 3) (Ar) 4s1 4) (Kr) 5s1
7. The II A group elements are called :
1) Alkali metals 2) Alkaline earth metals
3) Transition metals 4) Inner transition metals

Single Correct Choice Type:


1. Which atomic number out of the following can not be accommodated in the present
setup of the long form of the periodic table ?
1) 112 2)118 3) 120 4) 116
2. The 3d-transition series contains elements having atomic numbers ranging from
________.
1) 22 to 30 2) 21 to 29 3) 21 to 31 4) 19 to 29
3. The starting element in the incomplete period of long form of periodic table
is________.
1) Cs 2) Rn 3) Fr 4) Th

Narayana Group of Schools 29


Olympiad Class Work Book VI–Chemistry (Vol–IV)

4. The longest period in the periodic table is ________.


1) 3rd period 2) 6th period 3) 7th period 4) 5th period
5. The 3rd period of the periodic table contains:
1) 8 Elements 2) 32 Elements 3) 18 Elements 4) 19 Elements

6. The name of the element with atomic number 100 was adopted in honour of
1) Alfred Nobel 2) Enric Fermi
3) Dimitri Mendeleev 4) Albert Einstein
7. The long form of periodic table is nothing but just a graphical representation of
________principle
1) Pauli’s 2) Aufbau 3) Uncertainty 4) Wave mechanical
8. The atomic number of the element named after the scientist who introduced the
concepts of orbits or main energy levels :
1) 107 2) 108 3) 109 4) 110

9. Filling up of ‘f’ orbitals starts after with:


1) Actinium 2) Thorium 3) Ce 4) Lu
10. The 4th period of the periodic table contains:
1) 8 Elements 2) 32 Elements 3) 18 Elements 4) 19 Elements

11. The period that contain only gaseous elements is ________.


1) period-1 2) period-2 3) period-4 4) period-7

12. In a period, elements are arranged in strict sequence of:


1) Decreasing charge in the nucleus. 2) Constant changes in the nucleus.
3) Equal charge in the nucleus. 4) Increasing charge in the nucleus.

Multi Correct Choice Type:


13. Group 18 (or zero group) elements are also called as:
1) Inert gases 2) Rare gases 3) Noble gases 4) Inactive gases

30 Narayana Group of Schools


VI–Chemistry (Vol–IV) Olympiad Class
Olympiad Work
Text Book
Book

Comprehension Type:
Different groups having are general or special names For example O group elements
general name is Rare gases inert gases or Noble gasses
14. General name of IA group elements is _______.
1) Alkaline earth metals 2) Alkali metals
3) Boron family 4) Carbon family
15. General name IIA group elements is ________.
1) Alkaline earth metals 2) Alkali metals
3) Boron family 4) Carbon family
16. General name IIIA group elements is ________.
1) Alkaline earth metals 2) Alkali metals
3) Boron family 4) Carbon family
Matrix Match Type:
17. Column-I Column-II
Period number Nature of period
a) 4 p) Very long period
b) 3 q) Long period
c) 2 r) Short period
d) 1 s) Very short period
t) Incomplete period

Multi Correct Choice Type:


18. Among the following elements having same general electronic configuration is
ns 2
1) Ca 2) Sr 3) Be 4) Li
Statement Type:
19. Statement I : Atomic number is the number of protons in the nucleus of an atom.
Statement II : Atomic number is also equal to the number of electrons in a
neutral atom.
1) Both statement I and II are correct.
2) Both statement I and II are incorrect.
3) Statement I is correct and statement II is incorrect.
4) Statement I is incorrect and statement II is correct.

Multi Correct Choice Type:


20. Among the following elements which belongs to chalcogens
1) S 2) Se 3) Te 4) As

Narayana Group of Schools 31


Olympiad Class Work Book VI–Chemistry (Vol–IV)

1) 3d series - electronic configuration.


4s1-2 3d1-10 [Sc(Z=21) to Zn (Z=30)]
2) 4d - series - electronic configuration.
5s1-2 4d1-10 [Y(Z=39) to Cd (Z=48)].
3) 5d- series - electronic configuration.
6s1-2 5d1-10 .[La (Z=57), Hf (Z=72) to Hg (Z=80)]
4) 6d - series - is an incomplete series.
 General characteristics of d-block elements are:
 They are hard, high melting metals showing variable oxidation states.
 They form coloured complexes and form ionic as well as covalent compounds.
 Most of them exhibit paramagnetism and possess catalytic properties.
 They form alloys and are good conductors of heat and electricity.
 (iv) f - block:

Definition: The elements in which the last electron enters the f-subshell of the
anti-penultimate (third to the outer most shell ) shell are called f- block elements.

(a) This block is placed separately at the bottom of the main periodic table.
(b) It consists of two series of elements placed at the bottom of the periodic table.
The elements of first series follow lanthanum and are called Lanthanides and
the elements of second series follow actinium and are called actinides.
(c) The general electronic configuration of these elements is (n-2)f 1-14(n-1) d 0-1
ns2, where ‘n’ represents the outermost shell, (n-1) represents the penultimate
shell and (n - 2) represents the anti penultimate shell.
 General characteristics of f-block elements are:
 They are hard and have high melting metals showing variable oxidation states.
 They form coloured complexes and have high densities.

CUQ
1. On the bases of electronic configuration, the elements are grouped in to _______
blocks.
1) 2 2) 4 3) 1 4) 3
2. The elements in which the last electron enters the s-subshell of their outermost
energy leve are called :
1) s-block 2) p–block 3) d–block 4) f–block

34 Narayana Group of Schools


VI–Chemistry (Vol–IV) Olympiad Class
Olympiad Work
Text Book
Book

3. The elements in which the last electron enters the p-subshell of their outermost
energy level are called :
1) s-block 2) p–block 3) d–block 4) f–block
4. The elements in which the last electron enters the d-subshell of their outermost
energy level are called :
1) s-block 2) p–block 3) d–block 4) f–block
5. The elements in which the last electron enters the f-subshell of their outermost
energy level are called :
1) p-block 2) s–block 3) f–block 4) d–block
6. s–block contains ––––––––– groups.
1) I B & II B 2) I A & IIA 3) IIIA & IV A 4) Only I A
7. The II A group elements are called:
1) Alkali metals 2) Alkaline earth metals
3) Transition metals 4) Inner transition metals
8. The atomicity of a noble gas is:
1) 2 2) 1 3) 4 4) 6
9. f–block elements are called :
1) Normal elements 2) Representative elements
3) Transition elements 4) Inner transition elements
10. The elements which are characterised by the outer shell electronic configuration
from ns1 to ns2 np5 are collectively called as:
1) Transition elements 2) Inner transition elements
3) Representative elements 4) Actinides

Single Correct Choice Type:


1. The elements whose outer electronic configuration vary from ns 2np 1 to ns2np 6
constitute?
1) s-Block of elements 2) p-Block of elements
3) d-Block of elements 4) f-Block ol elements
2. Elements which generally exhibit variable oxidation states and form coloured
ions are:
1) Metalloids 2) Transition elements
3) Non-metals 4) Gases
3. Lanthanides are group of elements in which the differentiating electron enters
into __________.
1) s-sublevel 2) d-sublevel 3) p-sublevel 4) f-sublevel

Narayana Group of Schools 35


Olympiad Class Work Book VI–Chemistry (Vol–IV)

4. The atomic numbers of Lanthanides are from __________.


1) 58 to 71 2) 90 to 103 3) 21 to 30 4) 39 to 48
5. In the long form of periodic table all non-metals are placed in__________.
1) s - block 2) p - block 3) d - block 4) f - block
6. Lanthanum belongs to ...... group.
1) III B 2) II B 3) IV B 4) II A
7. In the long form of periodic table inert gases are _________ group.
1) 15 2) 16 3) 18 4)19
8. The last lanthanide is:
1) La 2) Ce 3) Th 4) Lu

9. Elements with atomic numbers 9, 17, 35, 53 are collectively known as:
1) Chalcogens 2) Halogens 3) Lanthanides 4) Rare gases
10. In iron atom (z=26), the differentiating electron enters……..sublevel.
1) 4d 2) 3d 3) 4p 4) 5p
11. Ce — 58 is a member of :
1) s - block 2) p - block 3) d - block 4) f - block

12. In the transition elements, the incoming electron occupies (n–1)d sub level in
preference to__________.
1) np 2) ns 3) (n–1)d 4) (n+1)s
13. The element with the electronic configuration [Xe]4f7 5d1 6s2 lies in the:
1) s-Block 2) d-Block 3) f-Block 4) p-Block

14. The fourteen elements collectively placed in group 3 (or IIIB) and 7 th period are
called:
1) d-Block elements 2) p-Block elements
3) s-Block elements 4) Actinides
15. Atoms with three of their outer most orbits incompletely filled with electrons are
present in __________.
1) Lanthanides 2) Representative elements
3) s - block elements 4) Transitional elements

36 Narayana Group of Schools


VI–Chemistry (Vol–IV) Olympiad Class
Olympiad Work
Text Book
Book

16. First transitional series is present in __________.


1) Third period 2) Fifth period 3) Fourth period 4) Sixth period

Multi Correct Choice Type:


17. The atomic number of the following represents the element in the d-block?
1) Z= 40 2) Z = 74 3) Z = 45 4) Z = 49
Comprehension Type:
This classification is based on the type of atomic orbital to which a differentiating
(last) electron enters. On the bases of electronic configuration, the elements are
grouped into four blocks. They are :
i) s-block elements ii) p-block elements
iii) d-block elements iv) f-block elements
18. Which of the following is/are the characterstics of the s - block elements?
1) Highly electro positive 2) Non - metallic
3) Acidic nature 4) All the above
19. Which of the following is/are the characterstics of the p - block elements?
1) Highly electro negative 2) Metals
3) Highly malleable 4) All the above
20. The elements whose atoms have outer most and penultimate shells incomplete
are called:
1) s-Block elements 2) p-Block elements
3) d-Block elements 4) f-Block elements
Matrix Match Type:
21. Column-I Column-II
a) First transition series p) Incomplete series
b) Second transition series q) 5d1-9 6s1-2
c) Third transition series r) 4d1-9 5s1-2
d) Fourth transition series s) 3d1-9 4s1-2
t) 6d series
Integer type:
22. How many groups are occupied by p-block elements in long form of periodic table?

Narayana Group of Schools 37


Olympiad Class Work Book VI–Chemistry (Vol–IV)

Multi Correct Choice Type:


23. Which of the following are correct statements for d-block elements?
1) 3d series electronic configuration is 3d1-10 4s1-2
2) 4d - series electronic configuration is 4d1-10 5s1-2
3) 5d - series electronic configuration is 5d1-10 6s1-2.
4) All d–block elements diamagnetic

Multi Correct Choice Type:


24. Identify the characterstics of d - block elements:
1) Variable Oxidation states 2) Forms alloys
3) Formed coloured complexes 4) Bad conductors

Prediction of block, group, period of an element based on electronic


configuration
i. Prediction of block
If differentiating electron enters into
a) s-subshell  s-block
b) p-subshell  p-block
c) d-subshell  d-block
d) f-subshell  f-block
ii. Prediction of period
Maximum value of principal quantum number in the given electronic configuration
of an element indicates the period of that particular element
Example: Scandium- 1s 2 2s 2 2 p 6 3s 2 3 p 6 4s 2 3d 1
Here maximum principal quantum number = 4
Hence period = 4
iii. Prediction of group
For s-block elements
Group number = No of valence electrons
Example: Calcium- 1s 2 2s 2 2 p 6 3s 2 3 p 6 4s 2

38 Narayana Group of Schools


Olympiad Class Work Book VI–Chemistry (Vol–IV)

PERIODIC CLASSIFICATION

KEY & SOLUTIONS


WORKSHEET -1 KEY
CUQ:
1) 4 2) 3 3) 4 4) 2
5) 3 6) 3 7) 1
JEE MAIN AND ADVANCED:
1) 1 2) 3 3) 3 4) 3
5) 1 6) 4 7) 3 8) 1,3
9) 4 10) 2 11) 1 12) 3
13) a-r;b-s;c-p;d-t 14) 23.0 15) 1 16) 1
17) 2
WORKSHEET -2 KEY
CUQ:
1) 1 2) 1 3) 3 4) 2
5) 1 6) 4 7) 2
JEE MAIN AND ADVANCED:
1) 4 2) 1 3) 1 4) 3
5) 2 6) 4 7) 2 8) 1
9) 1,2,3,4 10) 3 11) 3 12) 4 13) 3
14) a-q; b-r; c-s; d-p 15) 35.5 16) 1,3 17) 1
18) a-q; b-s; c-p; d-r
WORKSHEET -3 KEY
CUQ:
1) 1 2) 1 3) 1 4) 2
5) 4 6) 4 7) 1 8) 3
JEE MAIN AND ADVANCED:
1) 1 2) 1 3) 2 4) 4
5) 1 6) 3 7) 1 8) 1
9) 2 10) 1,4 11) 1 12) 4
13) 4 14) 4 15) a-r; b-p; c-s; d-q 16) 69.9
17)1,2,3 18) 3 19) 1 20) 1,4
WORKSHEET -4 KEY
CUQ:
1) 2 2) 2 3) 2 4) 3
5) 1 6) 4 7) 2

44 Narayana Group of Schools


VI–Chemistry (Vol–IV) Olympiad Class
Olympiad Work
Text Book
Book

JEE MAIN AND ADVANCED:


1) 3 2) 2 3) 3 4) 2
5) 1 6) 2 7) 2 8) 1
9) 3 10) 3 11) 1 12) 4
13) 1,2,3,4 14) 2 15) 1 16) 3
17) a - q, b -r, c -r, d -s 18) 1,2,3,4 19) 1
20) 1,2,3
WORKSHEET -5 KEY

CUQ:

1) 2 2) 1 3) 2 4) 3
5) 3 6) 2 7) 2 8) 2
9) 4 10) 3
JEE MAIN AND ADVANCED:
1) 2 2) 2 3) 4 4) 1
5) 2 6) 1 7) 3 8) 4
9) 2 10) 2 11) 4 12) 2
13) 3 14) 4 15) 1 16) 3
17) 1,2,3 18) 1 19) 1 20) 3
21) a-s; b-r; c-q; d-p, t 22) 6 23) 1,2,3
24) 1,2,3
WORKSHEET -6 KEY
CUQ:
1) 2 2) 4 3) 1 4) 2
5) 2
JEE MAIN AND ADVANCED:
1) 2 2) 1 3) 1 4) 2
5) 4 6) 4 7) 2 8) 4
9) 4 10) 2 11) 3 12) 1
13) 1 14) 3 15) 1, 2 16) 1,2,3
17) 2 18) 1 19) 4
20) a - p, b -q, c -s, d -r 21) 1,2,3,4 22) 1,2
23) a -r; b -q; c -p; d -p

Narayana Group of Schools 45

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