Page No.

Date:

thexmod pce PSoceAR 1a

Cndmge jn pxessuze and Nolume tare plale
Cl
AConstant TOmpedeturIs callad satherma
PD eS Fos Sucha pmcegs oYmst

ha poss1le when Me sstRm is10.

odthoymal Contaut aithit environm
amd the tramsfer o heat faom he system
is ext melyslow,so that thermaequlilum
S mauotined
though out the change
Ag:nelHng et fce at Comranftemp4rathar
Boyle's Raw un be Cpplled tu sothernd
ohenee equeahn ot stak frs isatherma
PDcep pV= Constan
considler c tdeal 2aA underaoina
isothemal éxpansion lett V bethe
Initalolumeqnd Ve_be the nal dume
ThR w k done in_an inknnesimally
9mau eapansîpa is 2ven by L
w =Pdv
- Th tota wst done dusinghe expansion
tDm ví to Vp Ve n be obtained by
W dw=Pdv
'PV=nps

V
n ey =n£I lo3
MRTo V. 1ogY)
W-nRT 0 .V
AIc +0 s oL of hemoelyna micss
AV+W
 Page No.

EDate: /
=
O So thevmal pm em T 0 AVO

-Q=w
W= nRT lo VE
V
Thus i lotherma pateen hea trangtered
O J4s is Completely tonvehed i eA=
done ie fos ex pånsion o qa)
Pi

f+ B
V

2 sobarie pzocest A Process in which psesU

of the System maios constant is talUed as
isobasic pnces
Boilins at water at Constant pressUse

an sobasic padces3
Ap=oo
f s isobosic prmcass_p-bons
is
but AU, W Q none dt thee ZD
Cosidey an îdeal oas undeygoìnq
espansion a oNtanf_pYIsUe
yolume
tout.
Hal vo1ume qnd temyp
tet vLTi be_he ini
ag ctod VA an T be the Hoal vol ume
AMtemp epechvely
The wrMC do ne cung thipansion isven by
W= pdv PCVe-Vj): mp
W nfdf =nR(TP- T) -OD
in esna ener
also chane
also
A
A nCydr =nly CTf-Tr)
 veren
Page No.

Date /201

Ae o first law d-hey mudynamio

Av+W
nyCTfT:) NRTP-T:)

ntey+RIETA-1:9-
nCpmCp Tp-Tr)
CS here p= CtR sp.heaut a
Co ndpsessue
Thus by keepina pregsyzt Co stTn
heat Suppled ispasty used t
OCpase thetemperafure Qne
Dastly to do the wk dusing
eaPanson
B

V
 yereen
Page No.

Date /201

Sochoxic profess A process 1A

hich Volume System
the
OmuinS Constant Called isochuri
PrOCesS.
nisoc hosic chame 16 wok i
done byhe System dn he
nVi Ament
rors ocnosic pucess V: Const AV=o
m me 1S aw ot thes mo dynamis-
AV+W
=AVAy + PAV
=AU+ O
hus dusinq ISochoric change all the
he Supplieed is u Sed only to
nreateintesnal eeroy ottne
SyStemn ie to rise its temp only

e HeaHoq d 4as 'n 4 Constn volume

Contauoes
fos soc honiproce»y öV=0
W-PAV=o AU W
Av to e AV
= AU ncy AT|
A

V
 Everpee
Page No.

/201
(Date

SHdda bab protusi_A Pro cessin

C Michneithex beoutenters 1atD
he Sy Stem,noY heatleavey o m
TA System ` Called evo adabahd

t aollabaHC chomge = 0
Heat tranfex to,o om sttstenm
1S pre vented e ither by josulattag
h e sy Stem oo m its environment
aY by cerssynq Out the change
apicly So fhaF there is n o time far
amy exchanae heat.
e pumctusinq 4n nkiaked balloon
Y a tye
A/cto SF qw dt thez amudynamla

AU= -W
e h e n syctem eNPands adtabaticadly
w i s positve AUK negatne,
theoexnal enésGY Sysem decreoe
ieqns h e
m sy stem Coor doun.
&when SYstem e ompe Sses odluabuhicl,
wk negaive A U is Pasibe,

the 1tesnal eneY oSySem

cceae,1f Mee)SFe Sysem
 Paga No.

Data /201

PrVi= PeVa Const C

f r d i a b a h i c poress Pu':Cont

Wh :(p_s called spheat

ToHo
tOnen3ystemUndee o 0e aduabah'k
changeis temp. 2 iatevnal ener
dso change AV=-W
The voIK
VP
cconm W is
w edv_
PVec
VA V r

dv

-+1V1

V
- V7-JV

C
Y-

C
Ve -

Pe Ve

-Y
P Ve PrV= -Y
-T