Construction and Building Materials: Bing Han, Ming-Hui Liu, Hui-Bing Xie, Yu-Ping Liu

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Construction and Building Materials 105 (2016) 189–195

Contents lists available at ScienceDirect

Construction and Building Materials


journal homepage: www.elsevier.com/locate/conbuildmat

A strength developing model of concrete under sustained loads


Bing Han a,b,⇑, Ming-Hui Liu a, Hui-Bing Xie a, Yu-Ping Liu c
a
School of Civil Engineering, Beijing Jiaotong University, Beijing, PR China
b
Key Laboratory of Transportation Infrastructure Safety and Risk Management, Ministry of Transportation, Beijing, PR China
c
Department of Civil and Environmental Engineering, University of Houston, Houston, TX, USA

h i g h l i g h t s

 Maximum past thickness in concrete was modified considering the effect of sustained load.
 Strength developing rules of concrete under sustained load were explored based on compressible packing model.
 Experiments were executed as a case study to suggest an available process to determine the parameters in the model.

a r t i c l e i n f o a b s t r a c t

Article history: The strength of concrete will be developed as the age increases. When a sustained load is applied on the
Received 17 July 2015 concrete, the development rules will be changed. Research on these rules is needed to estimate more
Received in revised form 11 November 2015 rationally the developing strength of concrete used in structures than those without considering the
Accepted 9 December 2015
action of sustained loads. In this paper, the development rule of compressive strength of concrete under
Available online 17 December 2015
sustained loads is explored. According to the mechanism assumption, a new model based on the
Compressible Packing Model (CPM) for concrete compressive strength is proposed. For calibrating the
Keywords:
model, experiments are carried out. Compressive strength of concrete were determined at four different
Concrete
Sustained load
ages and were compared with those of specimens without any sustained loads applied. Comparison of
Compressive strength the results by the model and by the experiments show the model presented in this paper can be suit
Compressible packing model for concrete strength development of concrete under sustained loading.
Ó 2015 Elsevier Ltd. All rights reserved.

1. Introduction flow of cement gel and the development of internal micro cracks.
Some researchers found sustained loading at high stress levels
It is common sense that concrete structures have to bear (lower than the compressive strength) may lead to concrete
sustained loads in their service stage, especially concrete in destruction, and the higher stress level is, the shorter time is
prestressed structures. As concrete ages, its strength will change. needed to failure [2]. Because of this, engineers thought that sus-
In fact, most of reported researches on the development of con- tained loads had negative effects on concrete strength, and con-
crete strength were based on the condition without sustained load crete strength was underestimated in practice. However, during
[1]. Although there are some studies that explore the aging charac- the service stage, concrete usually works in its elastic state, which
teristics of the concrete material itself without consideration of corresponds to stress lower than about 40% of the material com-
sustained load, the strength of concrete in a structure, which are pressive strength. Such a low stress is not enough to induce unsta-
very important to evaluate the true behavior of concrete struc- ble damage, which will decrease strength in concrete, and
tures, should be studied on the basis of sustained loading reversely, the concrete strength increases [3–7]. Nevertheless, all
conditions. of these studies have not given a clear mechanism on the strength-
Sustained loading may change the microstructure of concrete, ening effect of sustained loading on mechanical properties.
resulting in the change of the material performance. For example, In fact, concrete is a kind of mixture material with complicated
creep takes place under long-term loading because of the viscous mechanical performance and has significant time-dependent prop-
erties. To obtain a more rational description of concrete strength
development, lots of research on modeling has been done [8,9].
⇑ Corresponding author at: School of Civil Engineering, Beijing Jiaotong Mikulic et al. [10] classified all these models into three categories,
University, Beijing, PR China. i.e., (1) models that predict the concrete compression strength
E-mail address: bhan@bjtu.edu.cn (B. Han).

http://dx.doi.org/10.1016/j.conbuildmat.2015.12.067
0950-0618/Ó 2015 Elsevier Ltd. All rights reserved.
190 B. Han et al. / Construction and Building Materials 105 (2016) 189–195

based on its component; (2) models based on homogenous where qc is cement density (kg/m3); t stands for time (d); A is con-
assumptions, such as models based on maturity methods [11–14] stant related to cement properties; B and P are constant related to
and the degree of hydration concept [15]; and (3) models based fly-ash properties; p and q is constant related to aggregate type;
on composition and the age of concrete, such as the Exponential ceq is equivalent cement mass in concrete at a given age
Cement Model proposed by Popovics [16] in 1998 and the
Compressible Packing Model (CPM) proposed by De Larrard [17]
ceq ¼ c½1 þ Wðf a =cÞ ð4Þ
in 1999. Most of these models are semi-empirical and semi- where c refers to cement mass (kg); fa stands for fly-ash mass in unit
theoretical. volume of concrete (kg); W can be written as seen in Eq. (5)
  
2. Modeling strength development of loaded concrete fa
W ¼ Wmax 1  exp K p ð5Þ
c
Compressible Packing Model (CPM) proposed by De Larrard [17]
where Kp is activity coefficient reflecting strength contribution of
has a clear description concerning the composition of the concrete
fly-ash, and linear relation with lg t; Wmax is a coefficient related
material and can be conveniently used to develop a model of
to maximum mass of lime precipitation, and optimal value is sug-
concrete for a specific problem. This paper proposes a model for
gested as 1.10.
strength development of concrete under sustained loads on the
basis of CPM.
2.2. Modified CPM considering sustained load
2.1. Strength development model based on CPM
2.2.1. Modification for physical effects of sustained loads
Assuming concrete is a kind of binary mixture containing heavy, On the basis of the analysis above, concrete compaction caused
hard and inert aggregates spread randomly in a cement matrix, it is by sustained load mainly occurs in the cement matrix. As a result,
considered to be somewhat homogeneous. In such a composite the volume of the cement matrix is reduced, and the aggregate vol-
structure, the weakest position is located within the cement ume can be considered unchanged based on the assumption that
matrix, which should be the primary focus of attention. A strength aggregates are incompressible. Thus the aggregate content in a unit
development model for a hardened cement matrix is constructed concrete volume, g, will increase, inducing an MPT decrease.
by taking into account the effects of aggregate properties and the According to CPM, concrete can be seen as a stressed accumula-
topological structure of the aggregates. tion of dry aggregates injected into cement matrix in batches [17].
Hardened cement matrix is regarded as a kind of porous mate- The initial stress in the pressure system is called r0, as shown in
rial whose volume fraction will have an effect on compressive Fig. 2. It should be a constant depending on the characteristics of
strength [18]. De Larrard [17] found that there is more un- concrete itself and may also be related to the internal energy of
hydrated content in cement matrix with low water cement ratio, concrete at the loading age, or the strength of concrete or topolog-
and suggested a 28-day compressive strength model as follows ical properties between different components. When the accumu-
[17]: lation has no load action, the volume expands uniformly along the
 2:85 grid posed by the center of gravity of the aggregates during the
Vc process of injecting cement matrix, and MPT is formed at the junc-
f m ¼ 11:4Rc28 ð1Þ
Vc þ Vw þ Va tion point of two aggregates. The expansion coefficient is set as k.
where fm is the 28-day compressive strength of cement matrix cur- During the expansion, outside work acts on the system overcoming
ing hermetically (MPa); Rc28 is 28-day standard strength of cement r0, and the external work is set as W. The expansion coefficient
(MPa); Vc, Vw and Va stands for volume of cement, water and aggre- becomes k0 after the injection of cement matrix when stress is
gate, respectively (mm3). equal to afc0, and the maximum thickness of paste changes to MPT0 ,
A unified physical parameter named maximum paste thickness where k0 < k and MPT0 < MPT. During the process, outside work, W0 ,
(MPT) was proposed by De Larrard to take account for the acts on the system to overcome r0 + afc0. In Fig. 2, the comparison
maximum size and volume fraction of aggregates. Image in a dry of MPT formations in the two situations is shown.
accumulation of aggregates, the maximum stress should occur at Now take a coarse aggregate in the MPT as an example based on
junction points between aggregates [19]. If cement matrix is the spherical model in which aggregates are supposed to be in a
injected into the accumulation, the aggregates should spread shape of sphere. In an unstressed state, force on the coarse
evenly, and a layer of cement matrix would form between two aggregates is r0pd2/4 and the external forces do negative work
adjacent aggregates. The cement matrix layer is under high stress, to result in a displacement of MPT. In a stressed state, force on
i.e. MPT. The forming process of the MPT is shown as Fig. 1 [17]. the coarse aggregates is (r0 + afc0)pd2/4 and the negative work
MPT is written as leads a displacement of MPT0 .
rffiffiffiffiffi  Supposing the values of external work are the same regardless
g whether or not load is applied, that is W = W0 . The equivalence
MPT ¼ D 3 1 ð2Þ
g relation can be expressed as
where D is the maximum size of the aggregate (mm); g is volume of r0 p4d  MPT ¼ ðr0 þ af c0 Þ p4d  MPT 0
2 2

aggregate in unit volume after spreading (mm3); g* is the aggregate ð6Þ


) MPT 0 ¼ r0 þra0 f MPT
volume before the cement matrix injected, also called stacking c0

density (mm3).
where r0 stands for initial stress in the accumulation and is a con-
Concrete strength development can be expressed by [17]
8 stant related to concrete properties (MPa); a = N/(fcAc); N refers to
  2:85 
>
> external force (N); fc refers to concrete compression strength at a
>
>
>
f cm ðtÞ ¼ 13:4R c28 A lgðt=28Þ þ 1 þ q wþa
c ceq ðtÞ MPT 0:13
given age (MPa); Ac refers to cross-section area of concrete member
< h   i
ð3Þ (mm2); fc0 is strength of concrete at the time of loading (MPa).
>
> ceq ðtÞ ¼ c 1 þ 1:1 1  exp ðB lg t þ PÞ fca
>
> Substitute Eqs. (6) into (3), and the physical effect of load on
>
: f ðtÞ ¼ pfcm ðtÞ strength development of concrete can be reflected by stress factor
c qfcm ðtÞþ1
[r0/(r0 + afc0)]0.13.
B. Han et al. / Construction and Building Materials 105 (2016) 189–195 191

Fig. 1. Formation process of MPT.

Fig. 2. Comparison of MPT formation progress under different stress conditions.

2.2.2. Modification for chemical effects of sustained loads degree of hydration of cement, cM, will be introduced into the
Since the extra hydration reaction caused by stress will develop impact factor of time of strength of concrete in the absence of
along with time, an impact factor of the extra hydration reflecting forces. Then
192 B. Han et al. / Construction and Building Materials 105 (2016) 189–195

 
t naphthalene-based superplasticizer were used to produce con-
dðtÞ ¼ cM þ A lg ð7Þ
28 crete. Fly ash was used to substitute 20% content of the cement.
Mix proportion is listed in Table 1.
where c is a parameter corresponding to degree of hydration and
related to properties of concrete and stress; M stands for degree 3.2. Specimen design
of hydration.
A model for calculating M is introduced here [15] To achieve the experimental objective, two types of specimens
8 kðtt 0 Þ were designed, namely loaded specimens for compression
>
> M ¼ ff28c ¼ b 1þkðtt
>
>
0
Þ
strength, un-loaded specimens for compression strength. The spec-
<
k ¼ A0 exp E imens for compression strength were 100  100  100 mm cubes.
RT ð8Þ
>
>
> b ¼ 1 þ ð28t0 Þk
1
All of loaded specimens were imposed with a load at an age of
>
: 7 days, and were tested for their compressive strength at the ages
of 14, 28, and 60 days. At the same time, the reference un-loaded
where f28 is concrete compression strength at age of 28 d (MPa); t0 specimens were tested after curing at 7, 14, 28, and 60 days. Totally
is the time when concrete strength starts to develop, t0 = 0 if t  t0 there are 7 groups of specimens with 3 specimens in each group.
(d); k is a rate constant related to cement hydration reaction; A0 is a The amount of the load imposed on the specimens was equal to
frequency factor related to intermolecular collisions during the 20% of the 7-day compressive strength of standard cured concrete.
chemical reaction and molecular activity involving in the hydration, The quantity and numbering of specimens are listed in Table 2.
A0 = e15.46 = 5,178,365; E is surface activation energy with a unit of Concrete cube compressive strength at 7 days was measured as
J/mol; R is the universal gas constant with a value of 8.341 J/mol K, 41.6 MPa, resulting in a sustained load of 8.32 MPa. Concrete prism
and E/R = 4978 K; T is curing temperature in unit of K; b is ratio of compressive strength at 7 days in the test was 32.5 MPa, so the
ultimate strength and 28-day strength, here t0 = 0. sustained load on the prism was 6.5 MPa.

2.2.3. Model establishment 3.3. Testing procedure


Taking above consideration of physical and chemical effects
into Eq. (3), compression strength development of concrete under In order to ensure applied loads were effective, special loading
sustained loads can be expressed as follows equipment was used as shown in Fig. 3. The device was designed

8  2:85  
>
 kðtt0 Þ  t
 
> f
> cm ðtÞ ¼ 13:4R c 1 þ 1
 þ A lg þ 1 þ q wþa
 r0 þra0 f  MPT 0:13
>
>
c28 28k 1þkðtt0 Þ 28 c ceq ðtÞ c0
>
>

<
k ¼ A0 exp E
h RT   i ð9Þ
>
>
>
> ceq ðtÞ ¼ c 1 þ 1:1 1  exp ðB lg t þ PÞ fca
>
>
>
: ðtÞ
f c ðtÞ ¼ qfpfcmcmðtÞþ1

in which, c, r0, p, q, A, B, and P is undetermined parameters, and according to the post-tensioned principle, i.e. a load was applied
can be obtained by regression according to experimental data. by a jack. When the load achieved the requirement, nuts on the
top of steel rods were tightened, and the concrete specimens were
pressured. For the case with unloading, the stress was adjusted
3. Experimental program
according to a pressure sensor and foil gauge adhered on the steel
rods. Three specimens for compressive strength can be loaded at
Experiments were designed to verify the effect of sustained load
the same time. Concrete blocks were placed between specimens
on the compression strength and provide data for regression of
and steel plates to avoid uneven stress.
coefficients in Eq. (9), referenced specimens without sustained
An important issue in loading is to avoid eccentricity. Speci-
loads applied were employed.
mens were laid on the horizontal bottom plate. It was necessary
that the bearing surface was parallel to the top surface when the
3.1. Mix design specimen was in the mold, and the centers of specimen, concrete
blocks, jack, and pressure sensor were made to coincide in a line
In the experiments, materials including ordinary Portland as accurately as possible. The middle plate was placed horizontally
cement (with 54.9 MPa of the 28-day standard compressive
strength), fly ash (classified as I in Chinese standard [20]), contin-
Table 2
uous grading macadam with diameters from 5 to 25 mm, medium
Quantity and numbering of specimens.
sand with diameters from 0.08 to 2.0 mm, as well as a kind of
Items of testing Stress level (%) Age Quantity
7d 14 d 28 d 60 d
Table 1
Mix proportion of concrete (kg/m3). Serial no.
fc 0 F0-I F0-II F0-III F0-IV 4  3 = 12
Cement Fly ash Sand Macadam Water Water reducing agent
20 – F2-II F2-III F2-IV 33=9
336 84 809 1029 162.5 2.4
Note: fc refer to concrete compressive strength.
B. Han et al. / Construction and Building Materials 105 (2016) 189–195 193

Fig. 3. Loading equipment.

and adjusted by a leveling instrument. When the test set-up for 3.4. Experimental results
specimens was complete, loads were imposed. First the specimens
were loaded slowly to 20% of the desired load. If the ratio of the dif- In Fig. 4 the experimental data of strength development of the
ference and the average value of the steel rods’ deformation were loaded and non-loaded specimens is shown. All of specimens’
greater than 10%, the specimens were unloaded and adjusted. strengths were increasing with time. For the non-loaded speci-
The specimens were reloaded, and the pressure sensor and foil mens, the strength for each of those at an age of 14 days, 28 days,
gauges were read at the same time to ensure uniform loading. and 60 days increases by 18.99%, 33.65%, and 42.55% when com-
When the indication of pressure sensor reached the desired value, pared to that at an age of 7 days, respectively. The development
the load was held and the strain of steel rods was recorded. After of strength before 28 days was rapid and then the strength devel-
that, the nuts on the middle plate were tightened. After about six opment continued but became slower. Comparatively, the strength
hours the stress was adjusted according to the reading of the foil for each of the loaded specimens at an age of 14 days, 28 days, and
gauges on steel rods if there was a stress relaxation. At the same 60 days increased by 21.39%, 37.02%, and 46.63% when compared
time, the reference unloaded specimens were removed from the to that at an age of 7 days.
water bath so that they had the same cured condition as the loaded As shown in Fig. 4, the strength of each of the loaded specimens
specimens. is higher than that of the corresponding non-loaded specimens.
The measuring method for compressive strength is based on the The strength of each of the loaded specimens at an age of 14 days,
Chinese standard [21]. The equipment used to execute the 28 days, and 60 days is 2.02%, 2.52%, 2.87% higher than that of the
mechanical test is electrohydraulic servo controlled pressure test- non-loaded specimens, respectively. Obviously, concrete under
ing machine. The maximum test pressure of the equipment is low stress level is strengthened slightly. This strengthening trend
1000 kN, and precision of the equipment is ±1%. Automatic loading is fast before the age of 28 days and becomes slow after that time.
was used to make sure the loading protocol was a continuous and It can be seen that this value would be astringent with increasing
uniform process, and the loading velocity was set as 0.5 MPa/s. the time, which agrees with reference [6].

3.5. Discussion

Development of concrete mechanical properties under sus-


tained loads, coupling hydration, creep and damage, is a complex
process. While a force is applied to concrete, its physical and chem-
ical characteristics in microstructure will change. Differing from
effects of high stress levels (more than 70% compressive strength)
that induces unstable damage, one of the low level stress effects on
concrete would make it solid and dense [22], and mechanical prop-
erties of concrete are enhanced. The denser concrete and micro
cracks in concrete under sustained loads co-exists [5]. According
to the experiments, the solidification effect overwhelms the dam-
age effect from the point of view of low level stress, so the strength
increases.
The enhancement could be explained from the changes of phys-
ical concrete microstructure and chemical hydration when con-
crete is under stress. First, from a physical point of view, stresses
promote concrete solidified. Since aggregates are hard to compress,
the effect mainly occurs in cement mortar. Shah and Chandra [5]
Fig. 4. Comparison of compressive strength development of concrete under found strength enhanced effect of concrete came from the
different loading conditions. secondary adhesive strength of cement gel, which is caused by
194 B. Han et al. / Construction and Building Materials 105 (2016) 189–195

reducing distance between the aggregates due to the solidification.


Wittmann [23] also corroborated to this viewpoint, and he
believed the bond between cement particles will increase with act-
ing force growing proportionally. Second, from a point of view of
chemistry, stresses propel cement hydration process. As known,
once the stress and temperature were given, solubility of a kind
of solid in water should be limited to a certain concentration.
Un-hydrated cement accelerates to dissolve into water due to
stress action, and this generates a supplement process to hydration
[6], inducing strength increase. To prove that stresses promote
hydration, Coutinho [6] studied loaded and non-loaded concrete
by thermogravimetric analysis and X-ray diffraction, and found
that when heating the concrete to 600 °C, loaded concrete had
higher weightlessness rate, which means chemical-bonded water
content in cement matrix under sustained load was higher than
that without imposed stress, and a higher peak value of Ca(OH)2
diffracted wave was observed, i.e. higher content of free Ca(OH)2
was present in the concrete under stress [6]. All the evidences have
illustrated that hydratable content in concrete under sustained Fig. 6. Fitting p and q by using calculating values of concrete matrix strength and
experimental data of compressive strength.
load is higher than that without stress, and stresses provide an
extra ‘maturity’ to concrete.
corresponding aggregate fraction must be obtained. The parameter
4. Parameter fitting g can be calculated by the mix proportion of the concrete, but g⁄
cannot be calculated directly by CPM because the residual packing
4.1. Coefficients A, B, P density of each aggregate fraction is unknown. A simplified for-
mula [24] is used to calculate g⁄. For crushed aggregate
The strength of the cement matrix in an unstressed state will be  0:19
Dmin
fitted first. The related parameters are A, B and P. Test data of g  ¼ 1  0:45 ð10Þ
strength varying with age in an unstressed state is used. The 28- Dmax
day activity coefficient is 0.5 for fly ash [17]; therefore, only A
in which Dmin and Dmax are the minimum and maximum grain size
and B need to be determined.
(mm), respectively.
To ensure only A and B are unknown in the fitting formula, rel-
The strength of the concrete matrix can now be achieved. The
ative strength is used to offset the effects of factors p and q on the
coefficient p and q are fit in a nonlinear approach; according to
aggregate properties. Here the influence of the aggregate on the
experimental data, the fitted values are p = 1.33533, q = 0.00771
concrete strength is supposed to be linear. The regression values
(Adj. R2 = 0.99851), respectively. The fitted curve is as shown in
of A, B, and P are A = 0.12201, B = 2.75883, P = 0.5  B lg 28 (Adj.
Fig. 6.
R2 = 0.91807), respectively.
The regressive curve is as shown in Fig. 5.
4.3. Coefficients r0, c
4.2. Coefficients p, q
Lastly, the formula for compression strength development of
The formula for compression strength of concrete in an concrete under sustained load was fit with the stress related coef-
unstressed state is fitted in which p and q are involved. Prior to ficients r0 and c. On the condition that coefficients mentioned
calculating the strength of the concrete matrix, the MPT above are known, the least square method can be used to fit the

Fig. 5. Fitting curve of relative compression strength of concrete under sustained Fig. 7. Fitting curve of compressive strength development formula of concrete
load. under sustained load.
B. Han et al. / Construction and Building Materials 105 (2016) 189–195 195

Table 3 51078027). And all of authors are appreciated to the valuable sug-
Comparison of calculated values by model and tested results of strength. gestions provided by Prof Mo Y.L., University of Houston, USA.
Stress ratio Age Calculated values Tested results Error
(%) (day) (MPa) (MPa) (%) References
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The authors would like to gratefully acknowledge the financial
support of National Science Foundation of China (Grant No.

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