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Front. Mech. Eng.

2017, 12(4): 490–509


DOI 10.1007/s11465-017-0484-4

REVIEW ARTICLE

Kwok Siong TEH

Additive direct-write microfabrication for MEMS: A review

© Higher Education Press and Springer-Verlag GmbH Germany 2017

Abstract Direct-write additive manufacturing refers to a technologies, it is possible to fabricate unsophisticated


rich and growing repertoire of well-established fabrication micrometer scale structures at adequate resolutions and
techniques that builds solid objects directly from compu- precisions using materials that range from polymers,
ter-generated solid models without elaborate intermediate metals, ceramics, to composites. In both academia and
fabrication steps. At the macroscale, direct-write techni- industry, direct-write additive manufacturing offers extra-
ques such as stereolithography, selective laser sintering, ordinary promises to revolutionize research and develop-
fused deposition modeling ink-jet printing, and laminated ment in microfabrication and MEMS technologies.
object manufacturing have significantly reduced concept- Importantly, direct-write additive manufacturing could
to-product lead time, enabled complex geometries, and appreciably augment current MEMS fabrication
importantly, has led to the renaissance in fabrication technologies, enable faster design-to-product cycle,
known as the maker movement. The technological empower new paradigms in MEMS designs, and critically,
premises of all direct-write additive manufacturing are encourage wider participation in MEMS research at
identical—converting computer generated three-dimen- institutions or for individuals with limited or no access to
sional models into layers of two-dimensional planes or cleanroom facilities. This article aims to provide a limited
slices, which are then reconstructed sequentially into three- review of the current landscape of direct-write additive
dimensional solid objects in a layer-by-layer format. The manufacturing techniques that are potentially applicable
key differences between the various additive manufactur- for MEMS microfabrication.
ing techniques are the means of creating the finished layers
and the ancillary processes that accompany them. While Keywords direct-write, additive manufacturing, micro-
still at its infancy, direct-write additive manufacturing fabrication, MEMS
techniques at the microscale have the potential to
significantly lower the barrier-of-entry—in terms of cost,
time and training—for the prototyping and fabrication of 1 Introduction
MEMS parts that have larger dimensions, high aspect
ratios, and complex shapes. In recent years, significant Microelectromechanical systems (MEMS) has been
advancements in materials chemistry, laser technology, around since the 1970s [1] and is a technology character-
heat and fluid modeling, and control systems have enabled ized by its extensive embeddedness in modern life.
additive manufacturing to achieve higher resolutions at the Modern MEMS include microgyroscope [2] used in a
micrometer and nanometer length scales to be a viable cell phone, digital light processor [3] in a projector, inkjet
technology for MEMS fabrication. Compared to traditional printer head [4], accelerometers [5,6] for automotive
MEMS processes that rely heavily on expensive equip- airbags, lab on a chip DNA diagnosis tool [7–9],
ment and time-consuming steps, direct-write additive automotive pressure sensor [10,11], radio frequency (RF)
manufacturing techniques allow for rapid design-to- MEMS [12], gas sensor [13], optoelectronics systems [14],
prototype realization by limiting or circumventing the and drug delivery [15]. The most common fabrication
need for cleanrooms, photolithography and extensive pathways for MEMS are characterized by planar fabrica-
training. With current direct-write additive manufacturing tion techniques that include surface micromachining [16–
18], bulk micromachining [19–21], and LIGA [22–27].
Received November 6, 2016; accepted August 9, 2017 These traditional MEMS fabrication techniques are pre-
Kwok Siong TEH ( ) ✉ mised on silicon fabrication technologies [28], which are
largely adopted from planar semiconductor integrated
School of Engineering, San Francisco State University, San Francisco,
CA 94132, USA circuits (IC) manufacturing technologies––ultra violet
E-mail: kwok.siong@gmail.com (UV) photolithography, wet/dry reactive ion etching,
Kwok Siong TEH. Additive direct-write microfabrication for MEMS: A review 491

chemical vapor deposition, metal deposition, wafer bond- circuits, the additional requirement for MEMS fabrication
ing, and packaging [28–33]. Each of these highly precise is the incorporation of larger-scale, high-aspect ratio
and specialized processes is typically accomplished by microstructures that are subjected to dynamic motions,
sophisticated equipment operated by highly trained mechanical stresses, and elastic deformations. For exam-
personnel in a class 1/100, dedicated MEMS cleanroom. ple, some routine MEMS structures include pressure
Oftentimes, patterning of MEMS devices necessitates sensing membranes [49,50] that are subjected to biaxial
multiple photolithographic steps, each of which is defined stresses, internal sensing microscale cantilevers [51] that
by a highly customized mask, making it both a critical and are subjected to bending stress, and scanning micromirror
costly procedure. In addition, the intractable challenges supports [52] that are subjected to torsional shear stress.
and limitations of planar manufacturing in making high- Similar to semiconductor IC fabrication, doped single
aspect ratio microstructures are becoming increasingly crystalline silicon or polycrystalline silicon (polysilicon)
apparent for larger and taller MEMS devices [34–37]. have been the mainstay structural materials used in MEMS
Aside from LIGA, wet etching, and deep reactive ion microfabrication, as their material properties (strength,
etching [28], the most common means to achieve high- conductivity, high resilience/no stress hysteresis), process
aspect ratio 3D MEMS structures and cavities is via wafer parameters (deposition, etching, bonding, packaging), and
bonding [38–40]. By stacking and laminating several robustness during fabrication are well established and can
wafers, cavities and through-thickness conduits can be be reliably predicted. From the perspective of production,
created via wafer bonding. Nevertheless, bonding process good process reproducibility, performance reliability and
depends critically on process parameters such as surface low unit cost also acted to cement silicon’s undisputed
preparation and temperature distribution, and could lead to dominance in MEMS microfabrication. Other non-struc-
interfacial and bulk defects [41–43]. To date, MEMS tural MEMS materials used include: (i) Insulation/
remain a high-barrier-of-entry technological field, making passivation: Silicon dioxide, silicon nitride, (ii) electrical
it a viable research area only to well-funded research conduction: Aluminium, (iii) sacrificial material: Silicon
institutions with cleanroom facilities, while limiting dioxide. Nevertheless, recent years have witnessed the
research participation by researchers at smaller institutions augmentation of the material repository to include,
with so such facilities. While pay-per-use foundry services importantly, silicon carbide [53–56], sapphire (crystalline
exist [44,45], the prototyping lead time is typically long–– aluminium oxide) [57], diamond [58,59], silicon germa-
e.g., 2 months for the Multi-User MEMS Processes nium [60], metal nanocomposites [61], soft materials [62],
(MUMPs), a commercial MEMS prototyping service and ceramics (lead zirconate titanate, barium strontium
offered by MEMSCAP [44]––making rapid design itera- titanate, aluminium nitride) [63–66].
tions virtually impossible and costly. Further, users are MEMS microfabrication leverages heavily semiconduc-
bound by a set of, understandably, strict design rules in tor IC fabrication technologies, which include: Photolitho-
order for the service to be catered to the widest spectrum of graphy, wet/dry etching, thin film deposition (chemical/
users at a reasonable cost, a reality that impedes creativity. physical vapor deposition, thermal oxidation), back-end
The confluence of these challenges creates a ripe process such as wafer dicing, wire bonding, hermetic
opportunity for the MEMS community to explore alter- packaging, and testing [28]. Major MEMS fabrication
native 3D microfabrication technologies that are at various techniques include surface micromachining, bulk micro-
stages of research and development. In particular, recent machining, and the LIGA technique. These days, due to
advancements in additive manufacturing have revolutio- the advent of deep reactive ion etch, the lines between
nized the product design process and significantly surface and bulk micromachining have blurred. Surface
shortened the design-prototype-product cycle as product micromachining is an adaptation of the complementary
prototyping can now be completed via the click of a button metal-oxide semiconductor (CMOS) process that has been
on a 3D printer, instead of having to go through the the mainstay of the semiconductor industry. Surface
traditionally long prototyping process that conventionally micromachining is fundamentally a thin film addition/
involves special metal fabrication techniques, skilled subtraction process that involves thin film deposition via
machinist, and logistics [46–48]. In light of these chemical/physical vapor deposition or thermal oxidation,
developments, the primary objective of this short review photolithographic patterning, and wet or dry etching to
is to provide a survey of the most relevant mask-less, produce the desired forms and shapes. Thin film deposition
direct-write additive manufacturing technologies that can on a silicon wafer typically takes place via one of three
potentially be added to the MEMS microfabrication routes: Physical vapor deposition (e.g., evaporation or
toolbox. sputtering of various metals or non-metals), chemical
vapor deposition (e.g., silicon dioxide, silicon nitrides,
silicon carbides), or thermal oxidation of silicon. Once
2 MEMS: Materials and processes deposition is completed, a photolithography step ensues,
where photoresist is first deposited via spin-coating, soft-
While both MEMS and semiconductors contain electronic baked, and patterned by means of exposing the photoresist
492 Front. Mech. Eng. 2017, 12(4): 490–509

to UV light via a photomask. The exposed photoresist is requirements drive the development of microscale direct-
next soaked in a developer to remove uncrosslinked write microfabrication processes that are essentially
photoresist, hard-baked, and is ready for the next step, scaled-down additive manufacturing processes.
etching. In surface micromachining, anisotropic etch is Presently, there exist myriads direct-write additive
achieved using reactive ions, whereas isotropic etch can be manufacturing techniques that could potentially lend
achieved either wet (e.g., hydrofluoric acid for silicon themselves to microfabrication [70–175]. These techni-
dioxide) or dry (e.g., xenon difluoride for silicon or ques are generally known as “3D printing” in layman’s
metals). For bulk micromachining, anisotropic silicon terms, though at the fundamental level, 3D printing is 2D
etching can be commonly achieved using potassium printing repeated layer by layer. We will review the basics
hydroxide (KOH), ethylenediamine pyrocatechol (EDP), of these additive direct-write techniques and their
tetramethylammonium hydroxide (TMAH), or deep reac- potentials for MEMS fabrication. The scope of this short
tive ion (DRIE) process to create deep cavities, thru-vias, review will be limited to the following additive direct-write
or moulds [67]. Subsequently, the thin film deposition, microfabrication techniques that already have or will likely
photholithography, and etching steps repeat, if necessary. have applications for MEMS: (i) Microstereolithography
Finally, for high-aspect ratio microstructures made of (µSL) which includes projection microstereolithography
metal, the LIGA process is generally used. LIGA is a (PmSL), two-photo polymerization (TPP), and continuous
German acronym for “Lithographie, Galvanoformung, liquid phase production (CLIP) [70–103], (ii) additive laser
Abformung”, which stands for lithography, electroplating, direct-write techniques, which encompasses laser micro-
and molding [68]. The key feature of a LIGA process is the sintering (LMS), laser-induced forward transfer process
use of (i) thick photoresist, (ii) x-ray or UV light for (LIFT), and laser-assisted chemical vapor deposition
exposure, (iii) electroplating process. The two major types (LCVD) [104–142], (iii) ink-/extrusion-based printing,
of LIGA processes, x-ray LIGA and UV LIGA, are with particular references to ink-jet printing, direct ink
distinguished by the exposure source used in the photo- writing (DIW), fused deposition modelling (FDM), multi-
lithography step. In x-ray LIGA, x-rays from a synchrotron jet modelling (MJM), electrohydrodynamic jet printing,
radiation source are used to expose thick photoresist such 3D electrospinning, and aerosol jet printing [143–175].
as polymethylmethacrylate (PMMA), an x-ray sensitive Table 1 provides an overview of the basic capabilities of
polymer [69]. For UV LIGA, a more accessible form of these techniques. These direct write techniques are at
LIGA that uses normal UV light, thick photoresist such as various stages of developments and each has specific
SU-8 is normally used. Prior to the deposition of ranges of process capabilities and therefore differing
photoresist, a conductive layer, such as nickel or copper, applicability towards MEMS. Other direct-write techni-
is deposited on the wafer. Upon exposure of the photoresist ques, including three-dimensional printing (3DP) and
to the light source, the photoresist is removed by means of focused ion-beam direct write (FIBDW) will not be
a photoresist developer. Subsequently, nickel or copper is included in this discussion and readers are referred to
electroplated in the empty cavities where exposed photo- other excellent articles for these techniques [98,175–180].
resist has been removed. Modern day LIGA process can At present, microfluidics system is the field in MEMS
achieve an aspect ratio (height/width) of 100. that is most amenable to direct write microfabrication
using these techniques due to its (i) structural simplicity,
simple/monolithic fabrication and therefore ease of
3 Additive direct-write microfabrication assembly and packaging, (ii) being less demanding about
processes materials choice and able to adapt to the prevailing,
common direct-write materials such as polymer, (iii)
While the current MEMS fabrication processes are generally large dimensions (tens to hundreds of mm),
relatively mature and well-established, there exists a which is the fabrication sweet spot for many existing
critical need for complementary MEMS fabrication direct-write techniques. Other MEMS structures such as
techniques that: (i) Can be fabricated at atmospheric microcantilevers, microbridges, microcoils, free-standing
environment and outside of a cleanroom environment structures have been successfully attempted at the larger
without the photolithography steps, (ii) are less process- (tens/hundreds of microns or millimeter) scale. When
intensive and cost-prohibitive for rapid and low-volume viewed as a collective group of microfabrication techni-
prototyping, (iii) can produce more sophisticated and free- ques, the aforementioned direct-write techniques still have
standing 3D structures without the need for sacrificial to overcome some universal bottlenecks and challenges
materials and elaborate etching processes. In addition, the compared to conventional MEMS fabrication techniques,
need for richer material choice other than silicon and such as: Lower resolution, higher surface roughness,
electroplated metals also call for alternative fabrication limited materials choice, need for post-fabrication proces-
technologies beyond surface micromachining, bulk micro- sing, new packaging requirements, and compatibility with
machining, and LIGA processes. Collectively, these current MEMS technologies. This short review will
Kwok Siong TEH. Additive direct-write microfabrication for MEMS: A review 493

examine the fundamental working principles, capabilities, through (i) photopolymerization or (ii) photocrosslinking
current technological landscape, and limitations of these of photosensitive monomers or oligomers (prepolymers).
direct write fabrication techniques as applied to MEMS. The layer-by-layer construction of 3D objects from a
photopolymer was first demonstrated by Hideo Kodama
3.1 Microstereolithography (mSL) from the Nagoya Municipal Industrial Research Institute in
1981. Three years later, Charles Hull formally coined the
Microstereolithography (mSL), similar to stereolithogra- term “stereolithography” (stereo = solid, lithography =
phy, is a direct-write 3D fabrication technique premised on printing) in a patent application and later founded 3D
photo-induced polymerization of a photopolymer by a Systems Inc., one of the leading additive manufacturing
finely focused rastering or stationary laser beam. At the companies. Building on stereolithography, Ikuta and
heart of mSL is photolithography using a scanning UV or Hirowatari developed the mSL process in 1993 that was
near-IR laser spot (~1 mm diameter) as the photonic energy capable of fabricating 3D microstructures with high aspect
source, instead of flood exposure as in conventional ratios and curved surfaces [73].
photolithography. The photopolymerization process in A typical mSL set up (Fig. 1(a)) is consist of (i) a laser
mSL occurs via one of two routes: (i) Single photon beam source and laser scan head (rastering or stationary),
polymerization at the UV wavelengths, or (ii) TPP or (ii) a liquid prepolymer bath, (iii) a height-adjustable
multi-photon polymerization at the near IR range using sample holder, and (iv) an x-y stage. The laser scan head,
femtosecond lasers [70–72]. During the mSL process, 3D sample holder, and x-y stage are controlled by a computer.
microstructures are fabricated in a layer-by-layer manner A computer software first deconstructs a user-input solid

Table 1 Summary of various direct-write fabrication techniques that are amenable to MEMS fabrication
Technique Minimum Layer Materials used Maximum Examples of References
line width thickness writing speed microstructures/
MEMS
Projection 0.5 mm 4 mm UV-curable photopolymer; 15–20 mm/h Microrods, suspended [74–76,86,96–100,102,119]
microstereolithography polymer-nanoparticle com- microbeams,
(PmSL) posites (e.g., silica, alumina, microcoils,
SiC, WC, PZT) microlenses,
micro-gripper,
microfluidics
Two-photon 50 nm 100 nm Photopolymers 10 mm/s Microrotors, microos- [71,81,85,99,101,103,116]
polymerization (TPP) cillator, microturbine,
microlenses
Continuous liquid 50 mm Continuous, UV-curable photopolymer 1000 mm/h Micropaddle with [89]
interface production layer-less (TMPTA, Sartomer undercut
(CLIP) (CN2920 & CN981))
Laser micro sintering 15 µm (metal) 1 mm Ag/Cu/Cr/Al/Mo/Ti/Ni 8 mm/h Microgears, [97,105–106,108–112]
(LMS) 50 mm (oxides) alloys, stainless steel 316L, Microsprings,
CoCr, tool steel, ceramics Free-standing walls,
(SiC), Nylon Microturbines
Laser-induced forward 0.5 mm 190 nm Ag, Au, Cr, Al, W, Cu, Ni, 1000 mm/s Microcantilevers, [114–116,119]
transfer (LIFT) Ge/Se, V microbridges
Laser-assisted chemical 0.5 mm 0.5 mm SiC, C, Al, B, BN, Mo 5 mm/s Microhelical springs, [119,131–132,142]
vapor deposition microsolenoids,
(LCVD) microcages
Ink-based printing 20 mm 20 mm UV curable ink 150 mm/s MEMS cantilever, RF [160,167]
antennas
Fused deposition 100 µm 32 mm Thermoplastic (ABS, PLA, 150 mm/s Microfluidics devices [146]
modelling (FDM) polypropylene)
Multi-jet modeling 25 mm 16 mm Thermoplastic (ABS, 150 mm/s Microfluidics devices [161,162]
(MJM) acrylonitrile)
3D electrospinning 2 µm 2 mm Polymers (PVDF, PVP, 90 mm/s Microgrids, [156–158]
PCL), polymer-nanotube microsupercapacitors
composite
Aerosol jet printing 10 µm 25 nm Ink (metallic, polymer, 200 mm/s Strain gage, gas [169,174–175]
semiconductor, sensors, antenna
nanoparticle)
494 Front. Mech. Eng. 2017, 12(4): 490–509

Fig. 1 (a) Set up of a projection microstereolithography system. (b) Micro matrix with suspended beam diameter of 5 mm. Scale bar: 200
mm. (c) High aspect-ratio micro rod array consists of 21  11 rods with the overall size of 2 mm  1 mm. Scale bar: 100 mm. The rod
diameter and height is of 30 mm and 1 mm, respectively. (d) Helical structures with the coil’s diameter of 500 mm and the filament’s
diameter of 130 mm. Scale bar: 200 mm. (e) 3D magnetic particle-polymer composite microfan with a diameter of 500 mm and height of
250 mm. (f)–(h) are silica nanoparticle-infused polymer (poly(hydroxyethylmethacrylate), pHEMA) nanocomposite. (f) Microfluidic chip.
Inset scale bar: 200 mm. (g) Micro-optical diffractive structure creating the optical projection pattern shown at the bottom (illuminated
with a green laser pointer). Scale bar: 100 mm. (h) Microlenses fabricated using greyscale lithography. Inset scale bar: 100 mm. (i) Metal-
coated photopolymer micro-grippers printed using microstereolithography, juxtaposed against a 20-pence British coin and (j) a sample
lateral displacement vs. applied potential at the micro-gripper tip. Figures are reprinted with permission from the following sources: (a)
and (d) from Ref. [77]; (b) and (c) from Ref. [74]; (e) from Ref. [78]; (f), (g), and (h) from Ref. [79]; (i) and (j) from Ref. [80]

model into hundreds of single cross-sectional layers via a and soaked in a solution to remove any support structures
process called slicing. The laser scan paths are then that were printed. Due to the point-by-point photopoly-
calculated and programmed for each cross-sectional slice. merization process, this process is time-consuming.
Next, as the laser spot scans across the adjustable platform
immersed in the photosensitive prepolymer, it polymerizes 3.1.1 Projection microstereolithography (PmSL)
the prepolymer on its scan path point-by-point and leaves
behind a solidified polymer pattern on the platform. The
platform is next lowered by a distance equal to the vertical Stampfl et al. [75] improved mSL further by integrating a
resolution of the stage, typically 0.1–0.2 mm but could be dynamic mask into a mSL system to create an advanced
as small as 0.1 mm [74], which essentially forms the version of mSL known as projection microstereolithogra-
thickness of each build layer. The laser scanning process phy (PmSL). In PmSL, either a (i) digital micromirror
repeats for the next layer. This process continues until the device (DMD) [74,75] or (ii) liquid crystal on silicon
object has been completely polymerized. Leading stereo- (LCoS) chip [76] is used as dynamic mask and a UV light
lithography companies such as Formlabs uses the inverted modulator. In a fashion similar to mSL, sliced 2D images
platform approach, where the sample holder is placed are digitized as a bitmap image, which is then transmitted
upside down and is fully immersed in a shallow bath of to the chip to be projected onto the polymer bath. As
photopolymer initially. A laser spot is scanned upward opposed to the point-by-point curing of photopolymers in
from below, toward the bottom of the UV-transparent mSL, PmSL is capable of layer-by-layer curing as each
polymer bath. After each layer is scanned, the sample micromirror in the DMD chip can be individually
holder is raised, followed by scanning of the next layer. addressed and therefore simultaneously projects light to
The finished product is removed from the sample holder different locations within the same layer of the polymer.
Kwok Siong TEH. Additive direct-write microfabrication for MEMS: A review 495

The switching time of the DMD is on the order of 20 ms be fabricated [83,84]. In addition, because of the non-linear
[74], significantly reduces fabrication time. The advantage absorption at longer wavelengths, the incoming photons
of using a dynamic mask includes: High display resolution, can travel deeper into the material and be confined once
high spatial resolution, fast switching speed, and therefore there, to fabricate microstructures of significantly higher
more precise control of exposure time. All these features aspect ratios compared to the LIGA process. The
combined to yield a high-resolution mSL system, capable advantages of TPP compared to conventional single
of producing a resolution of 5 mm [76] and parts having photon deep/extreme UV lithography are substantial:
between 1–10 µm of layer thicknesses [74], which makes it There is no need for vacuum, expensive optical lenses,
amenable to microstructures and MEMS fabrication. and special photopolymers to handle the damaging short-
Figures 1(b)–1(d) show the capability of PµSL, demon- wavelength UV lights. Maruo et al. [85] was able to
strating the fabrication of suspended microbeams (dia- fabricate microturbines, microgears, and micromanipula-
meter from 5 µm down to 0.6 µm), free-standing vertical tors using the TPP process. Using TPP, Nanoscribe GmbH
micro rod array (rod diameter = 30 mm, height = 1000 mm, (Germany) was able to produce polymer structure at tens to
aspect ratio = 1:33), micro coil array [74,77]. Figure 1(e) hundreds of nanometers at a minimum resolution of 120
illustrates a magnetic nanoparticle-infused photopolymer nm and a maximum vertical writing speed up to 100 µm/s
nanocomposite microfan, demonstrating the possibility of [71,83]. Figures 2(a)–2(c) show compound objective
fabricating magnetic microparts using this PmSL [78]. At lenses fabricated by Nanoscribe Photonic Professional
the moment, the main challenge of this technique being GT 3D Printer, where each doublet lens system has a
that only photopolymers can be used for direct writing. diameter of 120 µm and a height of 128 µm [87]. At
Zheng et al. [76] did demonstrate the promise of directly present, photopolymers such as SU-8, Ormocere, AZ MIR
writing oxide (e.g., Al2O3) nanoparticle-laden photopoly- 701, AZ 5214, AZ, 9260, and AZ 40XT have been used in
mer, as well as a two-step fabrication process for hollow this technique and they produce reliable results [88].
metallic structures (e.g., Ni) via electroless plating or
atomic layer deposition on a photopolymer structure 3.1.3 Continuous liquid interface production (CLIP)
directly written with PmSL. In 2017, Kotz et al. [79]
demonstrated the use of this technology to directly print Aside from its materials choice being limited to photo-
transparent fused silica glass microparts, by incorporating polymers, two major challenges of mSL are (i) the long
fused silica nanoparticles into a poly(hydroxyethylmetha- fabrication time arising from the inherently slow nature of
crylate) (pHEMA) matrix, as shown in Figs. 1(f)–1(h). point-by-point, serial processing in mSL, and (ii) the
Figure 1(i) shows a MEMS micro-gripper fabricated with presence of stepped interface between each print layers.
PmSL, followed by a sputter-coating process to obtain a Recently, a new commercial PmSL process known as CLIP
thin layer of platinum for thermal actuation of the micro- [89] enables continuous, layerless production of 3D
gripper [80]. Reasonable lateral displacements at the tip of microstructures (tens of mm) and mesostructures (up to
the grippers actuated at different applied potentials are 25 cm) at high speed––vertical extrusion speed of up to
shown in Fig. 1(j). 500 mm/h (or 140 µm/s), as shown in Figs. 2(d)–2(e).
Figure 2(d) shows a micropaddle having a stem diameter of
3.1.2 Two-photon polymerization (TPP) 50 mm, with undercuts fabricated directly without any
sacrificial layer or support structures. The key enabling
In general, the x-y resolution of parts made from mSL is technology in CLIP is an oxygen-permeable window (100
intimately tied to the laser spot size, which is around ten µm thick Teflon AF2400), which creates an oxygen-rich
micrometers [81]. To fabricate features down to the “dead zone” (20–30 mm) that inhibits photopolymerization
nanometer length scale, instead of using short-wavelength, within this zone. Photopolymerization could only occur
deep UV (DUV, l = 193 nm) or extreme UV (EUV, l = above the dead zone, allowing for continuous replenish-
13.5 nm) as in current UV lithography technology, mSL ment of prepolymer below the dead zone and at the
uses longer (UV-Vis to near-IR) wavelengths, but shorter- building surface. Instead of a layer-by-layer approach,
pulsed (typically femtosecond-pulsed) laser beam to CLIP is able to produce continuous, homogenous
initiate crosslinking [71]. Using a 150-femtosecond structures, as shown in Fig. 2(e). Materials that can be
titanium sapphire laser, Kawata et al. [82] demonstrated printed via a CLIP process include soft elastic materials,
a sub-diffraction-limit spatial resolution of 120 nm, ceramics, and biological materials [89]. As a newly
enabling the fabrication of a micro-bull that measures 10 developed stereolithography process, CLIP is capable of
µm long and 7 µm high. The non-linear absorption at these rapidly printing mesoscale objects, and to some extent,
wavelengths spatially confines non-zero exposure to the microscale structures in the tens and hundreds of
focal volume (i.e., the volume where the laser is focused micrometers. It could be suitable as both a prototyping
on), known as voxel, while suppressing exposure to and a mass production tool for predominately larger scale
adjacent volume. This enables free-standing structures to polymer MEMS applications, such as microfluidics for
496 Front. Mech. Eng. 2017, 12(4): 490–509

Fig. 2 (a) A compound objective lens (blue) fabricated directly on an optical fiber (red) inserted within a 27-gauge needle. (b) Scanning
electron microscope images of a doublet lenses printed with a 90° piece cut out to provide a better view of the different lenses. Scale bar:
20 µm. (c) An Omnivision 5647 CMOS image sensor with doublet lenses (inset). The CMOS-chip has a pixel size of 1.4 µm 1.4 µm.
Reprinted with permission from Ref. [87]. (d)–(e) Microfabrication with the continuous liquid interface production (CLIP) technique. (d)
Micropaddles with stems 50 mm in diameter. (e) The CLIP process enables fast print speeds and layerless part construction. Reprinted with
permission from Ref. [89]

bioMEMS. For MEMS applications that require high high-energy laser beam (e.g., continuous wave CO2 or Nd:
stiffness and good long-term reliability (e.g., acceler- YAG lasers, 400 W, focused down to a 50–300 μm spot
ometer), further improvements in materials systems other size [105]) scans the surface of a powder bed that is packed
than photopolymers, higher resolutions, lower-temperature with metal powders and selectively sinters or melts the top
packaging process that does not degrade the material are layer of powders along its path. The sintering process fuses
expected before this technique can become an integral the powders to form a solid part based on a predetermined
MEMS fabrication technique. pattern generated from a computer-generated solid model.
To date, mSL has been applied in a limited manner in the After a single pass of laser beam, the bed is lowered and a
fabrication of micromachines [93], microturbines [85], roller spreads an even layer of fresh powders over the
microgears [85], micromanipulators [85], microfluidic entire bed. During an SLS process, the part being made is
systems [94], and optical waveguides [95]. Some of the supported in a bed of powders and is lowered in a stepwise
key limitations are the direct write materials choice since manner. As such, an SLS process does not require support
only photopolymers can be reliably used for fabrication structure while fabricating complex, overhanging struc-
presently, compatibility and reliability of current materials tures. A variant of the SLS process is known as selective
with traditional MEMS decives and packaging techniques, laser melting (SLM) when the temperature is high enough
and minimum resolution. While the resolution of mSL is to melt the powders to form a liquid phase [106]. The
comparable to current MEMS fabrication needs, but powders used are commonly metals (Ag, Al, Cu, Mo,
without the stringent process requirements such as stainless steel) or polymers, however, ceramics (alumina,
photomasks and cleanroom facilities, limited materials silicon carbide and lead zirconate titanate (PZT)) can also
choice will likely be the bottleneck that this technology be processed using SLS [98,107].
will have to surmount to be fully adopted in the MEMS Laser micro sintering (LMS) is a modified SLS process
field. to improve fabrication resolution down to 10 mm range and
was pioneered by the Laser Institute Mittelsachsen in 2003
[108]. The distinguishing features of the LMS process are
3.2 Additive laser direct-write techniques its use of (i) 1–2-micron or submicron-sized powder to
fabricate ceramic or metallic microscale components for
3.2.1 Laser micro sintering (LMS) greater resolutions [109], and (ii) q-switched laser pulses
(e.g., Nd:YAG, 1064 nm wavelength, 180 ns pulse
Selective laser sintering (SLS) is powder metallurgy duration, 25 mm laser spot size), which can yield
technique that was originally developed in the early significantly higher intensity and fluency compared to
1980s by Deckard and Beaman to create casting patterns continuous wave lasers [106]. The present minimum
out of plastic powder [104]. In a typical SLS system, a achievable resolutions for metal and oxide ceramics are
Kwok Siong TEH. Additive direct-write microfabrication for MEMS: A review 497

15 and 50 mm, respectively, at a minimum layer thickness consists primarily of a pulsed UV laser source, a donor
of 1 mm and up to an aspect ratio of 1:25 [98,106]. Metal substrate, and a receiving substrate, as shown in Fig. 4(a)
powder that can be employed in a LMS process include: [114]. The donor substrate, also known as the “ribbon”, is
Al, Ag, Cu, Mo, Ti, W, nichrome 80/20, stainless steels typically made up of a laser-transparent substrate (e.g., a
(316L), and WCu alloys. In addition, ceramic powders glass slide) coated with a 1–20 mm thick solid film (metal,
such as alumina, silica, and silicon-rich silicon carbide can polymer, ceramic, or composite), complex fluids (ink or
also be sintered. Figure 3 illustrates several metal and high-viscosity nanopaste, sol-gel), or even cell cultures
ceramic microcomponents fabricated with LMS. These [119]. The laser beam used are usually ultrashort pulsed
include (i) tungsten microcoil (coil diameter = 300 mm) laser with t < 100 picoseconds––generally in the femto-
(Figs. 3(a) and 3(b)), (ii) coiled tungsten ligament (Figs. 3 seconds (fs-LIFT)––so as to minimize the heat-affected
(c) and 3(d)), (iii) silicon-rich silicon carbide (SiSiC) zone and the melt zone––which could otherwise cause
microturbine, and (iv) “nichrome 80/20” valve [98,109]. oxidation and irreversible phase changes [119]. During the
Other sub-millimeter microstructures that can be fabricated LIFT process, the donor substrate is irradiated by a pulsed
with LMS include a micro sintered gearbox, a microturbine laser beam from the backside of the donor substrate. The
for a turbo charger, and 60 mm-thick free-standing wall donor material absorbs the laser energy, which rapidly
[105]. As can be seen, the textures and surface finish of the elevates the local pressure and eventually causes the
microstructures are relatively coarse (surface roughness ejection of a liquid microdroplet onto a receiver substrate
~ 35 mm), due to two reasons. First, local inconsistencies in approximately between 25–75 mm away. The deposited
the compactness of powder bed, plus the fact that film generally is 30 mm in diameter, with a line width as
compactness of powder decreases with smaller powder fine as 2 mm [120]. Figures 4(b)–4(e) show some basic
size, result in limited heat conduction, reduced wetting microstructures that can be fabricated via the LIFT process
between particles, and lower sintered material density. using silver nanopaste [121]. As seen from Figs. 4(c)–4(e),
Second, the recoil pressure of the expanding plasma plume the LIFT technique is able to fabricate high-aspect ratio
during laser irradiation suppresses the eruption of a melt structures by stacking 20 individual voxels to create a 75
pool, pushes the melt downward locally, and subsequently mm tall microstructure (Fig. 4 (e)). This technique makes
causes undulation on the surface, a phenomenon known as possible the deposition of a wide range of mainly metals,
the condensing effect [105]. In addition, the smaller-sized including: Chromium, tungsten, gold, nickel, aluminium,
powders (typically < 2 mm), due to their larger surface copper, Ge/Se, vanadium, nichrome, and BaTiO 3
area-to-volume ratios, tend to (i) react more actively in the [116,119,120]. The minimum resolution for metal fs-
presence of humidity and oxygen and bring about a LIFT is as low as 0.5 µm and maximum writing speed is up
massive exothermic reaction, and (ii) form agglomerates to 1000 mm/s. Birnbaum et al. [114] demonstrated the
readily. To use even finer powders for fabricating smaller fabrication of free-standing microbridges (Fig. 4(f)) and
parts, vacuum/oxygen-free, shielding environment, and microcantilevers (Fig. 4(g)), each about 460 nm thick,
special powder handling measures are required to make using silver nanoink as the donor material, followed by
micro and nanoparts with good structural integrity and machining via a focused ion beam (FIB). The as-deposited
high degree of densification. For microfabrication with wet Ag ink was subsequently cured in air for one hour at
significantly smaller surface roughness, this technique still 250 °C. To date, a good understanding of the influences of
requires improvements in terms of finer nanoparticle size, parameters such as optimal laser pulses, laser-material
better powder compacting mechanism, optimization of interaction, and film adhesion mechanism have greatly
laser-nanomaterial interaction, and the presence of oxida- improved the quality of films deposited via LIFT.
tion-shielding mechanism. With increasing ability in Massively parallel LIFT process has also been demon-
fabricating micron-size parts, LMS is a promising strated, where a DMD is used as a dynamic mask to shape
technique for the microfabrication of monolithic and the laser beam, such that one single laser pulse can
free-standing metal and ceramic MEMS components. generate an entire grid pattern [122]. The key limitations at
the moment include: (i) Low resolution and simple
3.2.2 Laser-induced forward transfer (LIFT) geometry, (ii) shrinkage upon sintering when donor
material is ink or complex fluid, (iii) porosity of as-
Laser induced forward transfer (LIFT) is a direct-write deposited material, (iv) limited aspect ratio, as micro-
laser additive technology that has promising potential as a structures of high aspect ratios would require multiple
complementary technique to conventional planar MEMS passes to fabricate. This said, compatibility of this
fabrication technologies. LIFT was first introduced by technique with a wide range of donor materials, atmo-
Bohandy et al. [113] in 1986 and was further developed by spheric-condition operation capability, and the stability
other workers into matrix-assisted pulsed laser evaporation and accessibility of ultrashort-pulsed laser make this
(MAPLE), a variant of LIFT [114–118]. A LIFT system technique suitable for MEMS fabrication.
498 Front. Mech. Eng. 2017, 12(4): 490–509

Fig. 3 (a)–(d) 3D microparts produced by an LMS process using q-switched laser pulses and in an oxygen-free, shield gas environment.
(a), (b) Bihelical tungsten coil, 300 mm in wire diameter. Scale bar: 700 µm. (c) Coiled tungsten ligament (35 mm width, 300 mm height).
Scale bar: 400 µm. (d) Top view of coiled tungsten ligament in (c). Scale bar: 200 µm. (e) Microturbine of SiSiC (diameter = 6 mm, blade
thickness = 500 mm). (f) Detail of a valve generated under ambient conditions from 10 mm sinter layers of a 10 mm grained nickel-
chromium alloy powder (nichrome 80/20). Reprinted with permission from Refs. [98,109]

3.2.3 Laser chemical vapor deposition (LCVD) the substrate is determined by several parameters: (i) Laser
beam spot size, (ii) laser energy density, (iii) laser
Laser chemical vapor deposition (LCVD) process is a wavelength, and (iv) substrate thermal properties. LCVD
versatile additive laser direct-write microfabrication tech- can have resolution of 500 nm, deposition rate of up to 80–
nique capable of depositing a wide range of materials and 100 µm/s [98], and at a writing speed of 0.1–5 mm/s
produce parts with complex geometries [127–130]. LCVD, [119,132]. To date, LCVD has predominantly been used to
together with laser chemical-assisted etching (LCAE), a produce thin films and as a means for repairing metallic
subtractive technology that is not discussed in this review, interconnects. Microstructures that have been fabricated
are two high-resolution laser-materials processing techni- via this method include carbon microhelical springs (Fig.
ques [117,129]. A LCVD process typically occurs in a 5) [133], microsolenoids [134], alumina 3D photonic
vacuum chamber where a precursor gas is decomposed by microparts [132], and microcages [135]. Growth of carbon
a scanning laser beam into its byproduct that subsequently nanotubes has also been demonstrated by this method
deposits on the substrate. There are two primary laser- [119,136]. The disadvantage of the LCVD process is its
assisted mechanisms through which LCVD occurs: (i) long process time and need for vacuum, however, its
Pyrolytic LCVD, where the precursor gas does not absorb distinguishing feature as far as MEMS fabrication is
the laser energy but is thermally decomposed by the laser concerned, would be its ability to selectively deposit
heat on the substrate surface, (ii) photolytic LCVD, in materials on surfaces that are not planar [133,137]. To this
which the photon energy is absorbed by the precursor end, LCVD could be a versatile, niche technique for free-
gas––cleaving the chemical bond and leaving behind form microfabrication.
deposits on the substrate. The laser used in LCVD can be
focused down to 1 μm spot size. The precursor gases for 3.3 Ink-based and extrusion-based printing
metal deposition are generally metal-organic precursors,
such as carbonyls, alkyls, halides, and oxyhalides, whereas Ink-based, extrusion-based, or a hybrid of ink/extrusion-
for semiconductor deposition, hydrides, alkyls, or alkyl based printings, broadly speaking, belong to a group of
halides are typically used. A large group of materials–– layer-by-layer manufacturing techniques that collectively
including silicon carbide, carbon, alumina, boron, boron represent various technologies that perform the following
nitride, molybdenum, titanium, tin, lead, platinum, zinc, tasks: (i) Deposition of liquid or semisolid droplets on a
cadmium––have been successfully deposited on various surface, either directly from a liquid feedstock or via
substrates such as silicon, tungsten, zirconia, alumina, and melting of a solid feedstock, (ii) solidification of the
graphite [117,131]. The resolution of solid deposited on droplets via solvent evaporation, phase transformation,
Kwok Siong TEH. Additive direct-write microfabrication for MEMS: A review 499

Fig. 4 (a) Schematic of a laser-induced forward transfer (LIFT) process. (b)–(e) Microstructures fabricated by a LIFT process, and cured
at 70 °C, 1 h. (b) A 5 mm-thick rectangular voxel crossing a 100 µm wide silicon channel. Scale bar: 50 µm. (c) Multilayer scaffold
structure. Scale bar: 20 µm. (d) A high aspect ratio micro pyramid (100 mm  100 mm  60 mm). Scale bar: 20 µm. (e) High aspect ratio
micro pillars made by stacking 20 individual voxels of 30 mm  30 mm area, each 3.75 mm thick. Scale bar: 40 µm. (f) FIB machined
microbridge, thickness = 460 nm. Inset depicts the machined area(s). (g) FIB machined cantilever, thickness = 460 nm. Dynamic
responses of (h) the microcantilever and (i) doubly clamped microbridge as measured by laser vibrometry. Reprinted with permission from
Refs. [114,115]

crystallization, or polymer cross-linking, and (iii) bonding 3.3.1 Ink-jet printing


of the deposited material within the present layer and with
previous layers [143,144]. This printing technology can be Figure 6(a) shows the printing of microelectronics
classified into two broad categories, based on whether the components using ink-jet printing [147]. The inks that
feedstock materials are (i) melted or (ii) not melted prior to are used in the process shown contain both metallic (Ag
extrusion or dispensing. Techniques in the first category nanoparticle ink) and non-metallic (poly[(vinylidenefluor-
(melted feedstock) include fused deposition modelling ide-co-trifluoroethylene)]) [P(VDF-TrFE)] components.
(FDM), multi-jet modeling (MJM), precise extrusion As demonstrated in the example, the ink could be in one
manufacturing (PEM), precision extrusion deposition or more of the following forms: Photo-monomers,
(PED), 3D fiber deposition [98], and melt electrospinning colloidal suspension, nanoparticle-filled solution, or sol-
[145]. Techniques in the second category (solution feed- gel in organic or inorganic solvents. The simplest and most
stock) include: Inkjet printing [146,147], direct ink writing prevalent ink-dispensing technique uses either a thermal
(DIW) [148–152], robocasting [153], 3D bioplotting, actuator or a piezoelectric actuator to expel the droplets
extrusion freeform fabrication (EFF) [153], aqueous onto a surface. During inkjet printing, droplets can be
based extrusion fabrication (ABEF) [154], electrohydro- created either as discrete droplets when required (a drop-
dynamic jetting [155,156], 3D electrospinning [157,158], on-demand (DoD) technique) or in a continuous stream (a
and aerosol jet printing [168]. Several of these techniques continuous inkjet (CIJ) technique) with the unused liquid
that are of particular relevance to microfabrication will be being recycled. Among the two, DoD is more applicable
discussed below. for microfabrication as it allows for more control over the
500 Front. Mech. Eng. 2017, 12(4): 490–509

Fig. 5 (a) A selection of the different carbon micro-springs fabricated using LCVD. Scale bar: 1 mm. (b) Modulus of elasticity of
LCVD-deposited carbon as a function of laser power (LP) and ethylene pressure. (c), (d) SEM photos of two springs deposited at 400 mW
laser power and 50 kPa ethylene. (c) Spring deposited at a translation speed of 0.5 mm/s and having a deposition rate of 6.75 mm/s and a
wire diameter of 67 mm. Scale bar: 100 mm. (d) Spring deposited at a translation speed of 1.0 mm/s and having a deposition rate of 7.18 mm/
s and a wire diameter of 75 mm. Scale bar: 200 mm. Reprinted with permission from Ref. [133]

dispensing of the material (in the form of discrete droplets Silver lines (3–5 µm diameter) and silver helical coils (500
with predetermined volume), and importantly, the volume µm coil diameter) have been demonstrated with this
dispensed. Currently, commercial inkjet printers such as method at a writing speed of 500 µm/s on polyethylene
Fuji Dimatix material printer are able to print at high terapthalate (PET) substrate. Mechanical testing of the
micrometer scales. Figure 6(b) shows an ink-printed coils demonstrated high linear elastic strain of up to 50%.
microbattery interdigitated fingers. Inorganic inks made The success of these ink-jet printing technologies
of LiFePO4 (LFP) and Li4Ti5O12 (LTO) are printed with a [148,152] are significant to the field of MEMS as they
30 µm nozzle onto Au electrodes on a glass substrate. The demonstrate the possibility of using ink-based direct write
printed line width is between 30–50 µm. The as-printed technique to fabricate both mechanically robust free-
battery demonstrates a high areal energy density of 9.7 standing microstructures (and with overhangs) and the
J/cm2 at a power density of 2.7 mW/cm2 [148]. Using ink- energy source (microbattery) that power these microstruc-
based printing, Lessing et al. [160] fabricated a cantilever- tures.
based MEMS deflection sensor by printing reactive carbon
ink on omniphobic, C10F-treated Canson Vellum paper 3.3.2 Fused deposition modelling and multi-jet modelling
using a Fuji Dimatix material printer. The line width of the
carbon ink electrodes is approximately 800 µm. Figures 6 Extrusion-based additive manufacturing is most promi-
(c)–6(e) show the work by Lewis et al. [152] in the field of nently represented by fused deposition modelling (FDM)
direct ink writing (DIW), a laser-assisted ink-jet printing and multi-jet modelling (MJM), both of which have been
technique. In this work, silver nanoparticle ink is being the most well-developed commercially among the additive
dispensed by a syringe pump onto a receiver substrate, and fabrication technologies. Working in similar fashion as ink
is immediately irradiated by an 808-nm IR laser (100 µm jet printing, except with an extrusion system that heats and
spot size). The laser annealing process solidifies and melts the print materials that are usually thermoplastics
densifies the silver nanoparticles. Diameters of printed such as polylactic acid (PLA) and acrylonitrile butadiene
silver wire vary from < 1 to 20 µm depending on the styrene (ABS), FDM has become prevalent at the
nozzle diameter, extrusion pressure, and printing speed. macroscale for rapid prototyping and production purposes.
Kwok Siong TEH. Additive direct-write microfabrication for MEMS: A review 501

Fig. 6 (a1)–(a6) Process flow for manufacturing all inkjet-printed piezoelectric polymer actuators. Electrodes and piezoelectric P(VDF-
TrFE) layers are printed and sintered/tempered subsequently. (a7) Cross-sectional SEM image of layer sandwich. (a8) Cantilever and (a9)
membrane samples mounted. Reprinted with permission from Ref. [147]. (b) Direct ink writing (DIW) techniques developed by Lewis
et al. [152] showing an SEM image of lithium-ion microbatteries printed from LiFePO4 (LFP) and Li4Ti5O12 (LTO) inks, respectively. (c)
Free-form ink printing of hemispherical spiral from silver paste and immediately post-annealed by IR laser. Reprinted with permission
from [149]. (d1)–(d7) 500 µm diameter helical coil going through large extension (strain = 150% in tension) and compression (strain =
–50%). (e) A force-extension curve for an 800-mm-tall helix exhibits a linear-elastic behavior up to 50% strain. Reprinted with permission
from Ref. [152]
502 Front. Mech. Eng. 2017, 12(4): 490–509

Fig. 7 (a) Microfluidics components printed from a ProJet 3000HD 3D printer (3D Systems) based on the extrusion-based fused
deposition modeling process. (a1) Fluidic capacitor, (a2) fluidic diode, (a3) fluidic transistor, and (a4) fluidic enhanced gain transistors.
Reprinted with permission from Ref. [162]. (b1) Molds for microelectronics components that are printed using ProJet 3000HD 3D printer.
Once printed, the inner conduits are filled with conductive silver paste to create an embedded conductive structure. (b2) Microelectronics
components after the liquid metal paste filling and curing, including a resistor, an inductor, a capacitor, and an LC tank. (b3) An exposed 4-
turn solenoid coil. Reprinted with permission from Ref. [146]

A variety of resolutions exists for FDM, however, due to electrohydrodynamic (EHD) jet printing [156], 3D elec-
the viscoelastic properties of polymer melts, it is difficult to trospinning [157,158], and aerosol jet printing [159]
produce resolutions that are less than 16 mm––the techniques, as shown in Fig. 8. Electrohydrodynamic jet
minimum layer thickness for a state-of-the-art commercial printing and electrospinning are in fact the same type of
FDM printer such as Stratasys Objet Eden 260VS printer. process, in that both are fundamentally electrostatic-based
In the x-y plane, FDM printers are capable of 100 mm jet or droplet printing system. An EHD jet printing or
minimum resolution. There has been a concerted effort to electrospinning set up typically consists of (i) high voltage
improve the minimal resolution of the extruded part. Due source (with or without a pulse modulator), (ii) syringe
to the viscoelastic behaviour of molten thermoplastic, pump, (iii) ground collector. During EHD jet printing or
practical size of the extrusion nozzle is generally above 0.2 electrospinning, high voltage (on the order of 1–20 kV) is
mm so as to avoid clogging and excessive pressure applied to a polymer or conductive ink solution, which are
required to dispense. As for MJM, a layer-by-layer inkjet dispensed from a syringe pump and accelerated toward the
deposition technique that is followed by a photocuring ground collector. The solution could form a fiber or a series
process, the minimum achievable layer thickness is of droplets, depending on if the voltage is continuous or
currently at 16 µm for ProJet 3500HD Plus [161]. As far pulsed. Among the two, electrospinning has existed for a
as microfabrication is concerned, FDM and MJM are used long time (since 1930s) and is a technique used in the
predominantly in creating microfluidics channels and fabrication of non-woven polymeric fabrics where high
components, and moulds for microelectronics components voltage is used to draw polymer solution into randomly
[146,162], as shown in Fig. 7, due to the limit on resolution aligned and non-woven nano/microscale polymer fibers on
and materials compatibility. Improvements are still needed the ground collector. Due to residual like charges on the
in this technique to make it feasible for microfabrication electrospun fibers, strong electrostatic repulsion between
for conventional MEMS devices as it becomes increas- fibers made it impossible to fabricate 3D structures using
ingly difficult to achieve uniformity and consistency in electrospinning. Recent advances in the field enable
feature size as the dimension becomes smaller. complete removal of these charges on the fibers and
allow the fabrication of polymeric or polymer-nanoparticle
3.3.3 Electrohydrodynamic printing, 3D electrospinning composite three-dimensional micro and mesoscale struc-
and aerosol jet printing tures as shown in Fig. 8 [156,157]. At the moment, 3D
microstructures fabricated from these techniques are
Several nascent ink/extrusion-based or hybrid printing limited to relatively simple geometries due to the fiber-
technologies that have the potential to be applied toward by-fiber stacking mechanism. Free-standing structures
micro and mesoscale 3D and MEMS construction include (without overhangs) can be fabricated, however, materials
Kwok Siong TEH. Additive direct-write microfabrication for MEMS: A review 503

Fig. 8 (a) Schematic setup of the 3D electrospinning process and a close-up schematic of stacked 2 µm-fibers made of polyvinylidene
difluoride (PVDF). (b) SEM image of a 10-layer, 3D grid structure constructed on a paper substrate, fabricated at a writing speed of 10
mm/s. (c) SEM image showing the magnified image of the crossover area (white box) of the grid in (b). (d) An optical photo showing a
whole grid structure held by a tweezer after being physically detached from the paper substrate. Reprinted with permission from Ref.
[157]. (e), (f) Multilayered 3D grid structure fabricated by an electrohydrodynamic jet printing technique using polycaprolactone (PCL).
Reprinted with permission from Ref. [156]. (g) An aerosol jet printing system. Reprinted with permission from Ref. [159]
504 Front. Mech. Eng. 2017, 12(4): 490–509

choice is limited to polymer or polymer-nanocomposites at direct-write MEMS fabrication technologies. Seeing how
the moment. These techniques could be used to comple- macroscale additive manufacturing has revolutionized
ment conventional MEMS fabrication in the localized product design practices in the industry, reduced concept-
deposition of dielectric materials and soft, polymeric or to-production lead time, and enabled more creativity in
polymer nanocomposite materials, at highly targeted design work, it is easy to imagine how direct-write
locations where a ground could be established. The microfabrication could benefit the MEMS community.
challenge remains that high electrostatic potential and/or Importantly, direct-write additive manufacturing could
elevated temperature (melting temperature of polymer) remarkably expand MEMS fabrication technologies,
have to be maintained during the process. accelerate design-to-product cycle, enable more creativity
Finally, a relatively new commercial inkjet printing in MEMS designs, and critically, empower wider partici-
technology, aerosol jet printing (AJP), aerosol (nanopar- pation in MEMS research by lowering the barrier-of-entry
ticle ink) jet is focused and directed toward a receiving into the field.
substrate to form a dot or a line, which if repeatedly many
times, allows the building up of a microstructure. AJP was Conflict of interest The author declares that he does not have conflict of
also known as maskless mesoscale materials deposition interests nor financial interests in the work presented herein.
(M3D) and was formerly developed by Optomec [169]. A
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