Concept Strengthening Sheet (CSS-07) Based On AIATS-07 (TYM) - Chemistry

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TYM Based on

AIATS-07

Corporate Office: Aakash Tower, 8, Pusa Road, New Delhi-110005, Ph.011-47623456

CONCEPT STRENGTHENING SHEET


CSS-07
CHEMISTRY
AIATS – 07 – TYM – Q.52 (1) 1050 J (2) 990 J
Topic: (Mole Concept and Molar Masses) (3) –990 J (4) –1050 J
Which of the following contains maximum
number of atoms?
(1) 2 mol of H2 (2) 22 g of CO2
(3) 44.8 L of O2 at STP (4) 27 mL of H2O

Practice Questions:

1. 5 L of an ideal gas at a pressure of 20 atm


expands isothermally into a vacuum until its
total volume is 8 L. The work done in the
Practice Questions:
expansion is
1. Which of the following has maximum number of
atoms? (1) Zero (2) – 60 L-atm

(1) 48 g of O (3) 60 L-atm (4) – 20 L-atm

(2) 48 g of O2 2. 2 mol of an ideal gas is allowed to expand


isothermally and reversibly from 10 m 3 to 20 m3
(3) 48 g of O3
at 300 K. The work done in the expansion
(4) All have same number of atoms process is
2. Total number of atoms present in 0.1 mol of (1) – 1449.5 J (2) – 3446.5 J
K2Cr2O7 is
(3) – 4228 J (4) 3446.5 J
(1) 1.1 NA (2) 11 NA
3. Under isothermal conditions, a gas at 300 K
(3) NA (4) 0.11 NA
expand from 0.1 L to 0.5 L against a constant
3. If 5.6 L of a gas (X) weighs 11 g, then the gas(X) external pressure of 5 bar. The work done by
could be the gas is (given that 1 L–bar = 100 J)
(1) O2 (2) CO2 (1) 200 J (2) – 200 J
(3) C2H6 (4) SO2
(3) – 100 J (4) 100 J
4. Total number of atoms of hydrogen present in
AIATS – 07 – TYM – Q.59
44.8 L of C2H6 is
Topic: (Molecular Orbital Theory)
(1) 8NA (2) 1.2 NA
During which of the following changes, the bond
(3) 12 NA (4) 2 NA order increases and the magnetic properties
changes?
AIATS – 07 – TYM – Q.64  
(1) H2  H2 (2) N2  N2
Topic: (Reversible and Irreversible Process)
 
An ideal gas expands isothermally at 25°C from (3) O2  O2 (4) C2  C2
10–4 m3 to 10–2 m3 against a constant external
pressure of 105 Nm–2. The heat exchanged in
the process is

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CSS-07 Chemistry

2. Consider the following carbocations

Practice Questions:
1. Paramagnetic species among the following is Correct order of stability of the given
(1) CN– (2) N2 carbocations is
(3) H2 (4) H
2 (1) III > II > I > IV (2) III > I > II > IV

2. During conversion of O2 to O2– , the incoming (3) I > III > II > IV (4) I > II > III > IV
electron is added to
3. Least stable carbocation among the following is
(1)  orbital (2) * orbital

(3)  orbital (4) * orbital (1) (2)


3. During which of the following changes, the bond
order increases?

(1) H2  H+2 (2) C2  C+2 (3) (4)

(3) B2  B2– (4) N2  N2–


4. Most stable carbocation among the following is
4. In which of the following conversions, the
magnetic behaviour does not gets changed? (1)
(1) O2  O+2 (2) N2  N+2
(2)
(3) H2  H2– 4) Li2  Li+2

AIATS – 07 – TYM – Q.79 (3)

Topic: Intermediate: Carbocation


Most stable cation among the following is (4)

AIATS – 07 – TYM – Q.83


(1) (2)
Topic: Reactions of Alkynes
Consider the following reaction sequence,

(3) (4) Major product (B) is

(1)

(2)

Practice Questions:
(3)
1. Most stable carbocation among the following is

 (4)
(1) CH3 (2)

(3) (4)

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CSS-07 Chemistry

Practice Questions:
1. Consider the following reaction sequence,

CH3–CH2–CC–CH2–CH3 + H2O 


H2SO 4
A


Isomerisation
B Practice Questions:
Major product (B) is 1. The number of angular nodes and radial nodes
in 4s orbital are

(1) (1) 0 and 1, respectively

(2) 0 and 3, respectively


(2)
(3) 1 and 0, respectively

(3) (4) 4 and 0, respectively

2. How many electrons may be filled in orbital for


(4) which n = 4 and l = 2?

(1) 2 (2) 6
2.
(3) 10 (4) 14
In above given reaction which one of the
3. For 4d subshell, maximum possible value of ml
following acts as catalyst? is
(1) Mercurous ion (2) Mercuric ion
(1) 1 (2) 3
(3) (4)
(3) 2 (4) 10
3. 4. The angular momentum of an electron in 's'
orbital is equal to
Major product [A] is a/an
(1) Aldehyde (2) Ketone (1) 0h (2) 6h

(3) Alcohol (4) Carboxylic acid (3) 2h (4) 2 3h

4. AIATS – 07 – TYM – Q.76

(1) Toluene Topic: Salts of Oxoacids


Which of the following compounds decomposes
(2) Acetylene to give corresponding nitrite?
(3) Benzene (1) LiNO3 (2) NaNO3
(3) Mg(NO3)2 (4) Ba(NO3)2
(4) Anti-aromatic compound
AIATS – 07 – TYM – Q.54
Topic: Quantum Numbers
Incorrect statement among the following is
(1) Energy of 2s orbital of hydrogen atom is
greater than that of 2s orbital of lithium atom Practice Questions:

(2) For hydrogen atom, the maximum number 1. Most stable carbonate is
of degenerate orbitals in the third energy (1) BeCO3 (2) MgCO3
level is 9
(3) CaCO3 (4) BaCO3
(3) Mathematically, Heisenberg’s uncertainty
2. On heating, which of the following releases
h
principle is expressed as x  px  CO2(g) most easily?
4
(1) Li2CO3 (2) Na2CO3
(4) For any subshell, maximum possible value
of ml is 2(l + 1) (3) Rb2CO3 (4) K2CO3

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CSS-07 Chemistry


3. LiNO3   Li2O + [A] + [B]  Practice Questions:

(g) (g) 1. Consider the given reaction as balanced


equation in acidic medium

NaNO3   NaNO2 + [C] (g)
Cr2O72– + 6Fe2  xH  6Fe3  yCr 3  zH2O
[B] and [C] are same gas  (aq) (aq) (aq) (aq) (l)

Choose the correct option regarding gases (A), Coefficients x, y and z respectively are
(B) and [C]
(1) 14, 2 and 7 (2) 14,1 and 7
(1) [C] = O2, [B] = NO2
(3) 7, 2 and 14 (4) 14, 2 and 6
(2) [B] = [C] = NO2
2. Consider the given reaction as balanced
(3) [A] = NO2, [B] = O2 equation in basic medium
(4) [A] = O2, [B] = NO2
4. In which of the following options, the order of
arrangement does not agree with the variation The coefficient a, b and c respectively are
of property indicated against it?
(1) 6, 3 and 2 (2) 12, 4 and 2
(1) LiH > NaH > KH > RbH > CsH [Thermal stability]

(2) Li2CO3 < Na2CO3 < K2CO3 < Rb2CO3 [Thermal stability]
(3) 6, 2 and 4 (4) 3, 2 and 4

(3) BeSO4 < MgSO4 < CaSO4 < SrSO4 [Solubility in water] I2 + 2S2O3–2  2I– + S 4O –2
3. 6

(4) BeO > MgO > CaO > SrO [Lattice Energy] (aq) (aq) (aq) (aq)
AIATS – 07 – TYM – Q.71
Valency factor of S2O3–2 in the above reaction
Topic: Balancing of Redox Reactions
is
Consider the given reaction as balanced
equation in acidic medium (1) 2 (2) 1
(3) 0.5 (4) 1.5
aCr2O72 (aq)  bSO32 (aq)  cH (aq)  xCr 3 (aq)  ySO24 (aq)
 zH2O(l) 4. Consider the given reaction as balanced
The coefficients a, b and c respectively are equation in basic medium
(1) 1, 3 and 8 (2) 2, 3 and 8
(3) 2, 6 and 4 (4) 1, 3 and 4
The coefficients a, b and c respectively are
(1) 1, 1 and 2 (2) 2, 1 and 1
(3) 2, 2 and 1 (4) 1 ,2 and 1


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CSS-07 Chemistry

Based on
AIATS-07 (TYM)

Corporate Office: Aakash Tower, 8, Pusa Road, New Delhi-110005, Ph.011-47623456

CONCEPT STRENGTHENING SHEET


CSS-07(CHEMISTRY)
Answer Key

AIATS – 07 – TYM – Q.52 AIATS – 07 – TYM – Q.83


Topic: Mole Concept and Molar masses Topic: Alkynes Reaction
1. (4) 1. (3)
2. (1) 2. (2)
3. (2) 3. (2)
4. (3) 4. (3)
AIATS – 07 – TYM – Q.64
AIATS – 07 – TYM – Q.54
Topic: (Reversible and Irreversible Process)
Topic: Quantum Numbers
1. (1)
1. (2)
2. (2)
2. (1)
3. (2)
3. (3)
AIATS – 07 – TYM – Q.59 4. (1)
Topic: Molecular Orbital Theory AIATS – 07 – TYM – Q.76
1. (4)
Topic: Salts of Oxoacids
2. (4)
3. (3) 1. (4)
4. (1) 2. (1)
3. (3)
AIATS – 07 – TYM – Q.79 4. (3)
Topic: Intermediate: Carbocation AIATS – 07 – TYM – Q.71
1. (2)
2. (2) Topic: Balancing of Redox Reactions
3. (1) 1. (1)
4. (2) 2. (3)
3. (2)
4. (2)

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