JEE Main 2022 June Session 1 Shift-1 (DT 27-06-2022) Chemistry

JEE (Main)
PAPER-1 (B.E./B. TECH.)
2022
COMPUTER BASED TEST (CBT)
Memory Based Questions & Solutions
Date: 27 June, 2022 (SHIFT-1) | TIME : (9.00 a.m. to 12.00 p.m)
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Duration: 3 Hours | Max. Marks: 300
SUBJECT: CHEMISTRY
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| JEE MAIN-2022 | DATE : 27-06-2022 (SHIFT-1) | PAPER-1 | MEMORY BASED | CHEMISTRY
PART : CHEMISTRY
1. When white phosphorus react with conc. NaOH product formed are.
(1) PH3 & NaH2PO2 (2) PH3, Na3PO4 (3) PH3, & Na2HPO3 (4) NaH2PO2, Na3PO4
Ans. (1)
Sol. P4(white) + NaOH  PH3 + NaH2PO2
2. Statement-I: O2– and Mg2+ have equal radii

Statement-II: They are isoelectric
(1) Both Statement-I & Statement-II are True.
(2) Both Statement-I & Statement-II are False.
(3) Statement-I is True while Statement-II is False.
(4) Statement-I is False while Statement-II is True.
Ans. (4)
Sol. ion O2– Mg2+
No. of e– 10 10
Z 8 12
Order of ionic size  O2– > Mg2+
3. Which of the following complex have maximum value of crystal field splitting energy.
(1) [Co(CN)6]3– (2) [Cu(NH3)4]2+ (3) [Co(H2O)6]2+ (4) [Ti(H2O)6]3+
Ans. (2)
Sol. Complex Hybridisation
(1) [Co(CN)6]3– d2sp3
(2) [Cu(CN)4]2+ dsp2
(3) [Co(H2O)6]2+ sp3d2
(4) [Ti(H2O)6]3+ d2sp3
sp = 1.3 0
4. When acidified KMnO4 reacts with oxalic acid gives a manganese product. Find the magnetic moment
(spin only) of Mn in this product.
(Report your answer to nearest integer)
Ans. (6)
Sol. 2MnO4– + 5C2O42– + 16H+ Mn2+ + 10CO2 + 8H2O
2+ = 3d5
25Mn
No. of unpaired electron = 5

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(spin only) = √𝑛(𝑛 + 2)BM
= √5(5 + 2)
= √35
= 5.916
Ans. 6
5. 2 gram of non-volatile solute dissolve in each 200 gram of two different solvents A and B and have same
molality. It ratio of Kb of solvent A and B is 1 : 8 & the ratio of elevation in boiling point is x : y, then value
of y is ______.
Ans. (8)
Sol. Tb = Kb × m
(𝑇𝑏 )𝐼 (𝐾 ) 1 𝑥
(𝑇𝑏 )𝐼𝐼
= (𝐾 𝑏) 𝐼 = =
𝑏 𝐼𝐼 8 𝑦
So y = 8
6. S1 : At 20ºC molality of KCl solution is 'X' m, on decreasing temperature to –10ºC molality remain
unchanged.
S2 : On changing temperature mass remain unchanged.
(1) Both S1 & S2 are ture (2) Both S1 & S2 are false
(3) S1 is ture & S2 is false (4) S1 is false & S2 is true
Ans. (1)
Sol. Molality & mass are temperature independent so on changing temperature molality & mass remain
unchanged.
7. What product are obtained in following reaction, H2SO4 + BaO2  Product.

(1) H2 + O2 (2) H2O (3) BaSO4 + H2O2 (4) H2SO8 + H2O2
Ans. (3)
Sol. BaO2.8H2O(s) + H2SO4(aq)  BaSO4(s) + H2O2(aq) + 8H2O(l)
8. Two element A & B form two different compound A2B & AB3. If 0.15 mole of both compound have equal
weight then what is the ratio of molar mass of A & B.
Ans. (2)
Sol. Let molar mass of A is a
B is b
again  0.15 [2a + b] = 0.15 [a + 3b]
𝑎 2
a = 2b  ( ) =
𝑏 1

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9. Match the following.

List-I List-II
(i) Si(CH3)4 (a) Silane
(ii) Si(CH3)2(OH)2 (b) 2D silicone
(iii) Si(CH3)(OH)3 (c) Chain silicone
(iv) Si(CH3)3(OH) (d) Dimeric silicone
I II III IV
(1) a c b d
(2) a b c d
(3) a d b c
(4) d c b a
Ans. (1)
Sol. (i) Si(CH3)4 Silane
(ii) Si(CH3)2(OH)2 Chain silicone
(iii) Si(CH3)(OH)3 2D silicone
(iv) Si(CH3)3(OH) Dimeric silicone
10. 2 mole of NOCl taken in 1 L of closed container it dissociate into NO & Cl2 gas
2NOCl ⇌ 2NO + Cl2
At equilibrium if 0.4 mole of NO are obtained then value of Kc is ____×10–4
Ans. (125)
Sol. 2NOCl ⇌ 2NO + Cl2
Initially 2 mole 0 0
At equilibrium (2 – 0.4) 0.4 0.2
= 1.6
(𝑁𝑂)2 (𝐶𝑙2 ) (0.4)2 (0.2)
Kc = (𝑁𝑂𝐶𝑙)2
= (1.6)2
= 0.0125
= 125×10–4
Ans. = 125
11. The limiting molar conductivites of Nal, NaNO 3, and AgNO3 are 12.7 S m2 mole–2, 12 S m2 mole–2
and 13.3 S m2 mole–2 respectively (all at 25ºC). The limiting molar conductivity of AgI at this temperature
is :
Ans 14

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Sol. Given 𝜆∞ 2
𝑚 (NaI) = 12.7 S m mole
–2
𝜆∞ 2
𝑚 (AgNO3) = 13.3 S m mole
–2
𝜆∞ 2
𝑚 (NaNO3) = 12 S m mole
–2
𝑚 (AgI) = 𝜆𝑚 (AgNO3) + 𝜆𝑚 (NaI) – 𝜆𝑚 (NaNO3)

𝜆∞ ∞ ∞ ∞
= 13.3 +12.7–12
= 14 S m2 mole–2
12. Find % of Fe2+ in Fe0 .93O. [Report your answer to nearest integer]
Ans. (85)
Sol. Fe0.93O
+2 +3
x (0.93–x)
2x + 3 (0.93 – x) = 2
2x + 0.93 × 3 – 3x = 2
2.79 – 2 = x
x = 0.79
0.79
% of Fe2+ = × 100 = 84.94%
0.93
Ans = 85
13. Identify correct match using Column I & Column II

Column I Column II
(i) Spontaneous process (a) Isothermal and isobaric process
(ii) Hºr (b) H < 0
(iii) T = 0, P = 0 (c) G < 0
(iv) Exothermic process (d)(Bond energy of reactant) – (Bond energy of product)
I II III IV I II III IV
(1) c d a b (2) b a c d
(3) d b c d (4) a d b c
Ans. (1)
Sol. (i) For spontaneous process G < 0
(ii) For exothermic process H < 0
(iii) For isotnermal process T < 0
For isobaric process P < 0

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14. Column I Column II

(i) Gold (Au) (a) SO2
(ii) Blister Copper (b) NaOH
(iii) Al2O3 (c) NaCN
(iv) Froth stabilizer (d) Aniline
Correct matching is
(1*) c a b d (2) a b c d
(3) b c d a (4) c b a d
Sol. Theory based
15. Identify the correct products in following reaction

BeCl2 + LiAlC4  Product.
(1) Be, LiAlC4 NCl (2) BeH2, LiCl, AlCl3 (3) AlH3, BeH2 HCl (4) Be, AlCl3, LiCl
Ans (2)
Sol. 2BeCl2 + LiAlC4 2BeH2 + LiCl+ AlCl3
16. Column I Column I

Compound Shape
(i) BF3 (a) T-Shape
(ii) SF4 (b) Square planar
(iii) XeF4 (c) See - saw
(iv) ClF3 (d) Trigonal planar
Correct matching is
(1) d c b a (2) a b c d
(3) d a c d (4) b c d a
Ans (1)
Sol. (i) BF3 (a) Trigonal planer
(ii) SF4 (b) See - saw
(iii) XeF4 (c) Square planer
(iv) ClF3 (d) T–shape
(i) (ii) (iii) (iv)
F F F
Xe
B F F
F F
(Trigonal planar) (See-saw) (Square planar) (T-shape)

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17. 0.76 gram mixture of H2 and O2 occupy 2000 cm3 of volume at 300K and 105 Pascal pressure, then molar
ratio of Hydrogen and oxygen is
Sol. For mixture.
PV = nRT
1
1 × 2 = nTotal × ×300
12
24
nTotal = = 0.08Mole
300
nH2 + nO2 = 0.08

(i) WH2 + WO2 = 0.76
WH2 WO2
(ii) + = 0.08
2 32
16W H2 + W O2 = 0.08 × 32 ;
0.08×32−0.76
WH2 = ( ) = 0.12 ; WO2 = 0.64
15
0.12 0.64
So nH2 = = 0.06 ; nO2 = = 0.02
2 32
Ans = 3
18. Uncertainty in position of a moving particle is 10–7 m and uncertainty velocity is 2.4 × 10–24 m/sec, then
mass of particle is [X] × 10–5 Kg value of X is___ . [Report your answer to nearest integer]
Sol. According to Heisenberg uncertainty
Principle
𝑏
x × P 
4𝜋
6.62×10–34
 10–7 × m.V =
4×3.14
6.62×10–34
 10–7 × m × 2.4 × 10–24 =
4×3.14
M = 0.2196 × 10–3Kg
= 21.96 × 10–5kg Ans = 22
19. Which of the following combination gives Benzaldehyde.

O
C CH3 CrO3,(CH3CO)2O
O–CH3 NaBH4
(A) PCC (B)
O O
C 1.SOCl2, Pyridine C NaBH4
OH OH
(C) 2.H2,Pd, BaSO4 (D)
(1) A and B (B) B and C (C) A and D (D) C and D

Ans. (2)

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20. Statement-I: In Hofmann rearrangement reaction alkyl group shift from carbonyl carbon atom to nitrogen
atom.
Statement-II: In alkyl shift, the group get shifted to the electron deficient carbon atom.
(1) Both Statement-I & Statement-II are True. (2) Both Statement-I & Statement-II are False.
(3) Statement-I is True while Statement-II is False. (4) Statement-I is False while Statement-II is True.
Ans. (1)
21. A mixture of organic compound A and B on reductive ozonolysis

O3
(A)
Zn,H2O
Glyoxal,ethanedicarbaldehyde
O3 & 5-oxohexanal
(B)
Zn,H2O
Gives the product glyoxal, ethanedicarbaldehyde and 5-oxohexanal. The compound A and B are :
(1) (2) (3) (4)
Ans. (1)
22. L-Isomer of an organic compound with molecular formula C4H8O4, gives +ve Tollen’s reagent test.
On treatment with bromine water gives optically active isomer but on treatment with conc. HNO3 it gives
optically inactive isomer. The correct figure of compound is :
CHO CHO CHO CHO

HO H H OH HO H H OH
(1) HO H (2) H OH (3) H OH (4) HO H
CH2OH CH2OH CH2OH CH2OH
Ans. (1)
23. The correct match of the polymers given in Column-I with their uses in Column-II is
Column – I Column – II
(A) Bakelite (i) Water pipe
(B) Polyvinyl Chloride (ii) Electric Switches
(C) Polystyrene (iii) TV Cabinet
(D) Glyptal (iv) Paint and Lacquers
(1) (A)-(ii), (B)-(i), (C)-(iv), (D)-(iii) (2*) (A)-(ii), (B)-(i), (C)-(iii), (D)-(iv)
(3) (A)-(i), (B)-(ii), (C)-(iii), (D)-(iv) (4) (A)-(ii), (B)-(iii), (C)-(i), (D)-(iv)
Ans. (2)

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24. Statement-I: Classical fog is reducing smog and found in cold and humid region.
Statement-II: Photo chemical smog is oxidising and consist of oxidising agent as oxides of nitrogen
nitrogen oxides, Volatile Organic Compounds (VOCs), tropospheric ozone, and PAN (peroxyacetyl
nitrate)
(1) Both Statement-I & Statement-II are True. (2) Both Statement-I & Statement-II are False.
(3) Statement-I is True while Statement-II is False.(4) Statement-I is False while Statement-II is True.
Ans. (1)
25. Total number of isomers of dimethylcyclopentane is (including stereoisomers)

Ans. (7)
Sol.
RR,RS and SS RR,RS and SS = 7
26. Structure of separating funnel is
(1) (2) (3) (4)
Ans. (1)
27. Major product of the given reaction is
F
PhS–Na+
DMF
NO2
SPh SPh I I
F F SPh F
(1) (2) (3) (4)
PhS
NO2 NO2 NO2 NO2
Ans. (2)

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28. The correct match of the compounds given in Column – I with their uses in Column – II
Column – I Column – II
– +
(A) CH3(CH2)10CH2OSO3Na (i) Toothpaste
)
(B) ) CH3(CH2)16COO(CH2CH2O)nCH2CH2OH (ii) Dish Washer
+
CH3
| –
(C) CH3(CH2)15–N–CH3 Br (iii) Hair conditioner
|
CH3
(D) C17H35COONa (iv) Soap

(1*) (A)-(i), (B)-(ii), (C)-(iii), (D)-(iv) (2) (A)-(ii), (B)-(iii), (C)-(iv), (D)-(i)
(3) (A)-(i), (B)-(iv), (C)-(iii), (D)-(ii) (4) (A)-(iv), (B)-(iii), (C)-(i), (D)-(ii)
Ans. (1)

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JEE Main 2022 June Session 1 Shift-1 (DT 27-06-2022) Chemistry

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JEE Main 2022 June Session 1 Shift-1 (DT 27-06-2022) Chemistry

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JEE (Main)

PAPER-1 (B.E./B. TECH.)

Duration: 3 Hours | Max. Marks: 300

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2. Statement-I: O2– and Mg2+ have equal radii

No. of unpaired electron = 5

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(spin only) = √𝑛(𝑛 + 2)BM

7. What product are obtained in following reaction, H2SO4 + BaO2  Product.

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9. Match the following.

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𝑚 (AgI) = 𝜆𝑚 (AgNO3) + 𝜆𝑚 (NaI) – 𝜆𝑚 (NaNO3)

13. Identify correct match using Column I & Column II

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14. Column I Column II

15. Identify the correct products in following reaction

16. Column I Column I

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nH2 + nO2 = 0.08

19. Which of the following combination gives Benzaldehyde.

(1) A and B (B) B and C (C) A and D (D) C and D

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21. A mixture of organic compound A and B on reductive ozonolysis

(1) (2) (3) (4)

CHO CHO CHO CHO

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25. Total number of isomers of dimethylcyclopentane is (including stereoisomers)

(1) (2) (3) (4)

27. Major product of the given reaction is

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(D) C17H35COONa (iv) Soap

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