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Motion Aakash Test Series Unit Test 3 Solution
Motion Aakash Test Series Unit Test 3 Solution
Biology - Section A
1. Answer: C 2. Answer: C
Sol: Sol:
NCERT XIth Page No. 18 PPLO are the smallest free living prokaryotic
organisms or the cells, its size ranges from 0.1mm
to0.3mm. These organisms have the ability to live
without the presence of oxygen also.
3. Answer: B 4. Answer: C
Sol:
Multicellular fungi, filamentous algae
and protonema of mosses all show
multiplication by fragmentation.
Fragmentation is a form of asexual
reproduction where a fragment of the
parent breaks off and develops into an
entirely new but genetically identical
individual.
Thus right answer is C.
5. Answer: A 6. Answer: C
Sol:
R.H. Whittaker gave the five kingdom
system of Classification. It is based on
complexity of cell that means cell is
prokaryote or eukaryote. The five
kingdoms are monera, protista, fungi,
plantae and animalia. On the basis of
prokaryotes, monera is placed under it
and other kingdom is placed in
eukaryotes.
Hence, the correct answer is four
kingdom.
7. Answer: B 8. Answer: A
Sol: Sol:
A taxon is a unit of taxonomy group. It Binomial nomenclature is the biological
is usually known by a particular name system of naming the organisms in
and given a particular ranking. It is any which the name is composed of two
classificatory group, and there is a terms, where, the first term indicates
hierarchy of them: species, genus, the genus and the second term indicates
family, order, class, phylum, and the species of the organism.
kingdom.
Hence, the correct answer is Genus and
Genus comprises a group of related species.
species which has more characters in
common in comparison to species of
other genera.
Order being a higher category is the
assemblage of families which exhibit a
few similar characters.
The various grouping levels or ranks in
classification are known as taxonomic
categories.
Hence, the correct answer is
taxonomic group below the rank of
species.
9. Answer: D 10. Answer: A
Sol: Sol:
The essential features of an organism Psychiatry is the branch of medicine
that is the basis of modern taxonomic focused on the diagnosis, treatment and
studies are the structure of the cell, prevention of mental, emotional and
internal and external structure of the behavioral disorders.
organisms and ecological information
and developmental processes of the Psychology is the scientific study of the
organisms. So, the correct option is D mind and behaviour. Neurology is the
branch of medicine concerned with the
study and treatment of disorders of the
nervous system. Neuropsychiatry or
Organic Psychiatry is a branch of
medicine that deals with mental
disorders attributable to diseases of the
nervous system.
So Branch of science connected with
diagnosis, prevention and cure of
mental disorders is Psychiatry.
11. Answer: B 12. Answer: D
Sol:
Largest Botanical garden is in Kew
(England), Indian Botanical Garden is in
Howrah and National Botanical Research
Institute is in Lucknow. So, the correct
option is B.
13. Answer: B 14. Answer: D
Sol:
Taxonomical aids are means that help in
identification, naming and classification
of organisms. Example: zoological park,
herbarium and museum. Soil is not a
taxonomical aid because in soil the
outgrowth of organisms are shown. It
cannot preserve any specimen. So, the
correct option is B.
15. Answer: C 16. Answer: B
Sol: Sol:
Key is taxonomical aid used for Key is another taxonomical aid used for
identification of plants and animals identification of plants and animals
based on the similarities and based on the similarities and
dissimilarities. It is used in the dissimilarities. The keys are based on
preparation of flora, monographs etc. the contrasting characters generally in a
Flora contains the actual account of pair called couplet. Each statement in
habitat and distribution of plants of a the key is called a lead.
given area. Monographs contain
information on any one taxon. Hence, the correct answer is lead.
36. Answer: C
Sol:
Alga is a term that describes a large and
incredibly diverse group of eukaryotic,
photosynthetic lifeforms. These
organisms do not share a common
ancestor and hence, are not related to
each other (polyphyletic). Algae do have
a cell wall which consists of cellulose,
Galatians and mannans. Hence, algal
cell wall is composed of cellulose.
37. Answer: B 38. Answer: D
Sol: Sol:
Xerophytes are the plants that live in Chlorella is known as space alga. It is
dry habitats. They are adapted to used for the consumption of carbon
survive in an extremely limited water dioxide provided by the astronauts and
supply. Xerophytes can be seen in the production of oxygen in the
deserts. Pteridium is a xerophytes plant. spacecraft. The features which make the
The plant body of Pteridium is Chlorella, the space alga is given below:
sporophytic and it is differentiated in Chlorella can be grown very easily.
root, stem and leaves. Root and stem It is a very good source of food which is
are underground and leaves are aerial. rich in protein, nutrient.
Chlorella comprises a high amount of
Plants growing in aquatic environments iron and vitamins.
are known as hydrophytes. Hydrophytic
plants can be seen in freshwater bodies Ulva lactuca, also known by the
as well as in marine environments. common name sea lettuce, this is a
Hydrophytes show different adaptations small genus of marine and brackish
to survive in water. Mesophytes are water green algae. It is edible and is
plants that grow in typically average often called 'Sea Lettuce'. Species with
conditions. Mesophytes are the hollow, one-layered thalli were formerly
terrestrial plants that we encounter on a included in Enteromorpha, but it is
daily basis. They are adapted to an widely accepted now that such species
adequate or average supply of water. should be included in Ulva.
And also they are able to live in average
temperature conditions. A halophyte is a Chlamydomonas is a genus of green
salt-tolerant plant that grows in soil or algae consisting of about 150 species all
waters of high salinity, coming into unicellular flagellates, found in stagnant
contact with saline water through its water and on damp soil, in freshwater,
roots. seawater, and even in snow as "snow
algae".
Hence, the correct answer is Xerophyte
plant. Spirulina is a biomass of cyanobacteria
that can be consumed by humans and
animals. The three species are
Arthrospira platensis, A. fusiformis, and
A. maxima. Cultivated worldwide,
Arthrospira is used as a dietary
supplement or whole food.
39. Answer: A 40. Answer: A
Sol:
Rhodophyta (red algae) reproduces
asexually by either fragmentation or by
forming non-motile spores. Sexual
reproduction is oogamous. In oogamy,
female gamete is large and male
gamete is small and both are non-
motile. So, the correct option is A.
Sol:
The main plant body of the bryophyte is
haploid. It produces gametes, hence is
called a gametophyte. The sporophyte is
not free-living but attached to the
photosynthetic gametophyte and derives
nourishment from it. Some cells of the
sporophyte undergo reduction division
(meiosis) to produce haploid spores. So,
the correct option is A.
41. Answer: A 42. Answer: A
Sol: Sol:
Animals do not possess any sort of cell Viroids are infectious agents that consist
wall since animals always move, they only of naked RNA without any
are not static in one particular place, protective layer such as a protein
therefore they need to be flexible. coat. Viroids infect plants (but no other
Therefore, additional layer i.e. cell forms of life) and are replicated at the
wall is not required. The cell wall is a expense of the host cell. Viroid genomes
structural layer around types of the cell are small single-stranded circles of RNA
outside the cell membrane which that are only 250–400 bases long.
provides the cell with structural support Hence, viroids have single stranded RNA
and protection found in algae, fungi, not enclosed in protein coat.
plants, bacteria and archaea.
Ribosomes are minute particles with
associated proteins and RNA to
synthesise proteins and it can be found
floating in the cytoplasm or attached to
the endoplasmic reticulum.
Plasma membrane surrounds the cell
wall, which is composed of a
phospholipid bilayer arranged back to
back and covered in cholesterol and
protein molecule.
Mitochondria are rod-shaped organelles,
considered the power generators of the
cell which converts nutrients and oxygen
into ATP. They are not present in
bacteria. Hence, the correct answer is
cell wall.
43. Answer: A 44. Answer: C
Sol:
Chlorophyll is located within the
thylakoids membrane of the
chloroplast. It is found in all
photosynthetic organisms, including
green plants, cyanobacteria, and algae.
There are four types of chlorophyll i.e.
chlorophyll a, b, c, and d. Chlorophyll a
is found in all higher plants, algae and
cyanobacteria; chlorophyll b, found in
higher plants and
green algae; chlorophyll c, found in
diatoms, dinoflagellates and
brown algae; and chlorophyll d, found
only in red algae.
Hence, the correct answer is
Chlorophyll-a.
Sol:
Yellow-green algae or
the Xanthophyceae (Xanthophytes) are
an important group of heterokont algae.
Most live in fresh water, but some are
found in marine and soil habitats. They
vary from single-celled flagellates to
simple colonial and filamentous forms.
The members of chlorophyceae are
commonly called green algae. They are
usually grass green due to the
dominance of pigments chlorophyll a
and b.
The members of phaeophyceae or
brown algae possess chlorophyll a, c,
carotenoids and xanthophylls.
Rhodophyta are commonly called red
algae because of the predominance of
the red pigment, r-phycoerythrin in their
body. Hence, the correct pair is
Xanthophyta →Yellow - Green algae.
The size doesn't matter the thing which Moulting is the process by which the
is important to consider is that how the cockroach grows into the adult by series
oxygen is reaching the tissue for of the repeated shedding of the outer
providing them energy. Therefore, size skin. Therefore, it has nothing to do
is not playing part in the activity of with the phallic gland.
insects. Hence, Phallic gland is mainly associated
They are having open type of circulatory with the male reproductive system and
system. The circulatory system is not helps in formation of the
entrusted with the duty to deliver the spermatophores.
oxygen to the body. Therefore, open
type of circulatory system is not playing
part in the activity of insects.
They are having chitinous exoskeleton.
The exoskeleton is there to protect the
soft organ of the insect not for supplying
oxygen to the body tissue. Therefore,
chitinous exoskeleton is also not playing
part in the activity of insects.
Hence, Insects are comparatively more
active because 02 is directly to the
tissue with the help of the respiratory
system.
83. Answer: A 84. Answer: B
Sol: Sol:
Conglobate gland is found in a male Juvenile hormone is produced in
cockroach. the corpora allata of insects. The
main role of Juvenile hormone in
Phallic or conglobate gland is a white & immature insects is to inhibit the genes
bag-like gland which is situated ventral that promote development of adult
to the ejaculatory duct from 6th to 9th characteristics, causing the insect to
abdominal segments. Its anterior end is remain as nymph or larva. During the
broad & the posterior end is narrow last larval or nymphal instar, the corpora
tube-like. It opens outside by a long allatum becomes atrophied and stops
duct “Phallic aperture. Chitinous producing juvenile hormone.
structures associated with phallic
aperture and male genital pore called Prothoracic glands produce and release
“Phellomeres” or Gonapophysis.” Phallic ecdysteroids only after they have been
aperture presents on left phellomere. stimulated by another chemical
Male genital pore situated on Ventral messenger, prothoracicotropic hormone
phellomers. (PTTH). This compound is a peptide
hormone secreted by the corpora
The colleterial glands of insects are cardiaca, a pair of neurohemal organs
organs associated with the female located on the walls of the aorta just
genital apparatus. behind the brain.
Prostate glands and accessory glands Hence, the correct answer is corpora
are found in earthworm. The prostate allata.
glands secrete a fluid the prostatic fluid
and the secretion of accessory glands
probably help in uniting the two worms
during copulation.
The bulbourethral glands (also known
as Cowper's glands) are a pair of pea
shaped exocrine glands
located posterolateral to the
membranous urethra.
Hence, the correct answer is
conglobate gland.
85. Answer: C
Sol:
The central nervous system of
cockroach consists of the supra-
oesophageal ganglion or brain or
cerebral ganglion, sub- oesophageal
ganglion and the nerve cord.
In cockroach, usually compound eyes
are found. The compound eyes of
cockroach are a pair of large, sessile,
black, kidney-shaped structures situated
at the dorsolateral sides of the head
capsule. Each eye consists of about
2000 hexagonal ommatidia. With the
help of several ommatidia, a cockroach
can receive several images of an object,
and these several images are combine
by cerebral ganglion. This kind of vision
is known as mosaic vision with more
sensitivity but less resolution.
Biology - Section D
86. Answer: D
Sol:
The spontaneous interaction of the
molecules present in the early earth's
atmosphere formed more complex
organic molecules, such as amino acids,
sugars, fatty acids, and nitrogen bases -
the building blocks of life as we know it
today.
As these organic compounds
accumulated they formed an "organic
soup" in which additional reactions could
take place.
The energy needed to drive the
formation of these organic molecules
was derived from the sun's radiation,
electrical discharges in the form of
lightening, and heat from the cooling
earth.
87. Answer: D 88. Answer: B
Sol: Sol:
Protobionts are prebiotic chemical The primitive atmosphere of earth was
aggregates having one or more reducing atmosphere with little or no
properties of living systems. Process of oxygen but was rich in water vapour,
aggregation of organic molecules is carbon monoxide, carbon dioxide,
called coacervation. It produced three nitrogen, and hydrogen. The UV and
types of protobionts - coacervates, gamma radiations from Sun were the
microspheres and vesicles. Coacervates major sources of energy for chemo
are reversible emulsoid aggregates genesis as these radiations have energy
consisting of protein and polysaccharide quanta that can release electrons from
with some water. Coacervates, atoms resulting in formation of highly
Coacervation is a chemical method for reactive free radicals which in turn
producing polymer droplets combined to form early organic
in suspension based on the separation compounds. The ozone layer of present
of two liquid phases into one day atmosphere absorbs these UV and
concentrated colloidal phase. And gamma rays. Owing to immense long
without lipid membrane. A photocell is a lasting rainstorms, tremendous amount
resistor that changes resistance of lightening was generated. Lightening
depending on the amount of light provided energy for chemical reactions
incident on it. A photocell operates on between hydrogen and free oxygen,
semiconductor photoconductivity: the nitrogen and carbon to form water
energy of photons hitting the (present in form of superheated steam
semiconductor frees electrons to flow, due to high earth temperature),
decreasing the resistance. ammonia, methane and cyanides.
89. Answer: A 90. Answer: A
Sol:
In the present earth-life comes from
pre-existing life but in primitive earth
theory of abiogenesis says that life
originated from non-living entities.
synthesis or production of life from
something non-living.
Sol:
A.I.Oparin and JBS Haldane got the idea
from the new biochemistry that was
founded by F.G. Hopkins.
This theory was supported by Miller and
Urey in 1953.
ΔL/L
Stress= Force mg
∵ =
area area
Cross-section area of the wire
density x volume
2
= g( ) A = πR
area
2
⇒ S ∝ R
2
respectively. S1 and S2 be cross-section
We know that areas of circular holes and square.
E= × stress × = .
2
1 stress 1
S
2 Y 2 Y
v1 = √2 gy and v2 = √8 gy
Q2 = v2S2 = √8 gy L2
Q1 = Q2
∴ R = √
2
π
.L
At equilibrium,
Q1 Q2
=
t t
T1 k1 l2 +T2 k2 l1
T =
k1 l2 +k2 l1
L
= αΔt = − α20 T=
F
∴ [T] =
[F]
I [I]
length.
Therefore, the correct answer is (B)
Therefore, the correct answer is (B).
109. Answer: D 110. Answer: A
Sol: Sol:
Change in internal Energy As the liquid drop is falling through the
viscous fluid net force
DU = µCV DT DUµDT
Fnet = weight − Buoyancy − Fviscous
Therefore, the correct answer is (D)
According to stokes low the
instantaneous viscous force on the drop.
Fviscous = 6πnrv
h = 2s
bρg
cos (θ + α/2)
3
ℓ dg = ℓ g − 200
3
g ...(1)
3 3 2
ℓ − 200 = ℓ − 2ℓ
2
ℓ = 100
ℓ= 10 cm
Therefore, the correct answer is (B)
115. Answer: A 116. Answer: D
Sol:
According to equation of continuity
A1V1 = A2V2
A is the area of cross section and v
is corresponding velocity.
and Area ∝ (radius)
2
that end.
So, π(R 1)
2
V1 = 100π(R2 ) V2
2
−2
2 −2
2
9×10 0.05×10
( ) × 3 = 100( ) × V2
2 2
12
⇒ v2 = = 48 m/s.
0.25
Ap vp = Aq vq
vp aq
=
vq ap
2
vp π(rq )
= 2
vq
π(rp )
2
−2
vp (2×10 )
= 2
vq −2
(10 )
vp
= 4
vq
Hence, vp = 4 × vq
V =
2r g
(d − p)
gn
V = √2gh 2
2
v1 r1 r
= ( ) = ( )
The taken to reach at point in
v2 r2 2r
2 2(H−h) V2 = 4V
So H − t = 12 gt t = √ g
2(H−h)
= √2gh× √ g
= 2√(H − h) h
Sol:
Let mass of hot water = m kg
mass of cold water = (20 – m) kg
Heat taken by cold water
= (20 − m) × 1 × (35 − 10)
⇒ 65m = (20 − m) × 25
⇒ 90m = 500
500
⇒ m = = 5 .56 kg
90
dt
∵ w = JQ
cooling, and w = mv
2
and Q = mL + ms (θ − θ2 )
1
2
80+70
2
− 25α Rate of cooling R1 mv
2
∴ = [mL + ms (θ1 − θ2 )]
2
60+50
2
− 25α Rate of cooling R2 ∴
mv
2
= mL + ms (475 − 25)
2
R1 α50; R2 α30
R1 5
=
R2 3
5 5
t2 = t1 = × 6
3 3
i. e. = 10
R1 t2 5
∴ = = min
R2 t1 3
T2
η = 1 −
T1
dt
=
σA
ms
(T
4
− T )
4
0
formed and dx is going to form. Now, solve using data given in the
question
2
t Lp ρ R ρLR
⇒ ∫ dt = ∫ x(R − x)dx =
0 KRθ 0 6Kθ
12
10
= k (56 − T0)
8
10
= k (46 − T0)
3 56–T0
=
2 46–T0
T0 = 26
Sol:
Here,
Initial temperature (Ti)= 100ºC
Final temperature (Tb)= 90ºC
Temperature of surrounding
(T0)=constant
t = 20 min
According to newton's law of cooling
(100−90)
= K [95 − To ]
20
1
K =
2(95−To )
In second condition:
Initial temperature (Ti)= 110ºC
Final temperature (Tb)= 100ºC
Time taken for cooling is t Acc to
newton's law of cooling
(110−100)
(110+100)
1
= [ − To ]
2(95−To ) 2
10 1
= (105 − To )
t 2(95−To )
20(95−To )
t =
(105−To )
λmoon
=
Tmoon
Tsun
So, now from stefan's law
4
5000×10
–10
Tmoon E ∝ T ⇒ E' = 16E
⇒ –6
=
100×10 6000
⇒ Tmoon = 30K
For triatomic
CP
γ = 1. 33 =
Cv
–1
= 0.4 =
ΔW γ–1 3 2
= = 5
ΔQ γ 5
3
Q= 5W
∵ Vrms = √
3 RT Pressure does not have any effect on
the kinetic energy of the molecule. Gas
M
πM
colliding to the walls of the container.
∴
Vrms
= √
3π
The kinetic energy of the molecule is
directly proportional to the temperature.
Vavg 8
135. Answer: C
Sol:
Critical temperature of gas is given by
TC = 8a
27 Rb
136. Answer: A
Sol:
We know that-
Pv = nRT =
m
M
RT At Constant Volume.
P
m ∝
T
Hence, m 1 > m2
5 h 1 2
D = d P0 + ρg = P0 + ρV
4 2 2 1
⇒ V1 = √hg ...(1)
h 1 2
P0 + ρgh + (2ρ)g = P0 + (2ρ)V
2 2 2
⇒ V2 = √2 hg
Pf Tf
=
Pi Ti
1.004 = T+1
1.004T = T + 1
0.004 T = 1
1
T =
0.004
T = 250oC
141. Answer: D 142. Answer: A
Sol: Sol:
We know that Isometric Process is a constant volume
1 gm
process.
No. of moles =
4 gm / mole
1
dQ = dU + dW
= mole
4
dW = 0
ΔQ = ΔU + ΔW
dQ = dU
NA K B
CV = − ∫
2
f 3 1
Q = nRΔT = × KB NaΔT
2 2 4
3
= NaKB (T2 − T1 ) + 0
8
3
= NaKB (T2 − T1 )
8
T= T =
n1 T1 +n2 T2
n1 +n2
V =
M
r
=
mass
density
So
P
1
V
1
P
2
V
2 m γ
T1 + T2 P( ) = constant
T=
RT RT
1 2 r
P V P V
1 1 2 2
+
RT
1
RT
2 P
(r)
γ = constant ..........(I)
T=
T1 T2 (P1 V1 +P2 V2 )
P1 V1 T2 +P2 V2 T1
Initial state : presure & density (P, r)
Finals tate :
1 1 3
(P , r ) & γ =
2
From equation
1
P P
γ
= γ
1
(r) (r )
1 1 γ
r p
⇒ = ( )
r p
γ 3 15
1 1 1
P r P
⇒ = ( ) = (32) 2 ⇒ = (2) 2
P r P
η2 = 1 −
T '2
d = m/v
T '1
v ∝ 1/d
Given:-
γ γ
1 1
T2 T'2
p1 [ ] = p2 [ ]
= d1 d2
T1 T'1
−γ −γ
100 T
= p1 d1 = p2 d2
500 900
100
T = × 900
500
= 180 K
Therefore, the correct answer is (C)
147. Answer: A 148. Answer: A
Sol: Sol:
Given : Mass of ice = 100 gm (at 0ºC) Ivory ball will rise to a greater height
after striking the floor. This is because
Temperature of bucket = 50ºC ivory ball is more elastic than the wet
We know that S =
ΔQ
=
mL clay ball. Therefore ivory ball will regain
T T
its original shape immediately after the
Let initial entropy be S1 and final collision only if it has more energy after
entropy be S2 collision.
S1 = 80 × 100
{L = Latent Therefore, the correct answer is (A)
0+273
Heat = 80 cal/gm}
8000
∴ S1 = cal /K
273
Now,
S2 = 80 × 100
273+5
S2 = 8000
323
cal/K
∴ S2 = 8000
323
cal/K
Change in entropy Δ S = S2 – S1
Δ S= (
8000
323
–
8000
273
)
4
ρav
2
Total force = 3
4
ρav
2
net pressure = 3
4
ρav
2
As we know pressure =
Force
Area
So, Force =
ρgh fσgh
× hσ =
2 2
= = = 0.1233
2 −1
Λm 48.15 S cm mol
0 −1
2
Λm 390.5 S cm mol
Ka = =
2 0.001028 mol L ×(0.1233)
cα
m (BaCl2 )
= λ
∘
2+
+ 2λ ∘
Θ
= 240.6 S cm2 = 2.71 V
Ba Cl
mol-1
Λ
∘
m (NH4 Cl)
= λ ∘
NH
⊕ + λ
∘
Cl
Θ
= 129.8 S cm2
4
mol-1
Λ
∘
m (NH4 OH)
= Λ ∘
m (NH4 Cl)
+ 1
2
Λ
∘
m [Ba (OH) ]
– 1
2
2
∘
Λ
m [BaCl2 )
= 129.8 + 1
2
(457.6) – 1
2
(240.6)
m(AgBr)
= λ ∘
Ag
⊕
+ λ ∘
Br
Θ
Ag(S)|Ag+||Cu+2|Cu(S)
o
E = SRP(C) – SRP(A)
= 62 + 78 = 140.0 S cm2 mol-1 cell
o
E = y– x
Λ ∘
m (AgBr)
= Λ m (AgBr)
= κ×1000
S
cell
140.0 S cm2 mol–1 =
−7 3
8.5×10 ×10
S =
–7 3
8.5 ×10 ×10
140.0
= 0.06 × 10-4 mol L–1
= 0.06 × 10-4 × Mw(AgBr)
= 0.06 × 10-4 × 188 g L–1
= 1.128 × 10–3 g L–1
Ksp of AgBr = S2M2 = (0.06×10–4)2
= 3.6 × 10–11 mol2 L–2
157. Answer: A 158. Answer: C
Sol:
Reducing power ∝
SRP
1
o
E =– 0 .14 +0 .44
cell
o
E = +0 .30 V
cell
SRP
SRP
Unit of K ohm–1 cm–1
o
E = 1 .25– 0 .68
cell
= 0.67 V
(B) II, III
o
E = 1 .25– (−1 .25)
cell
o
E = 2.50 V
cell
(C) III, IV
o
E = 0.68 + 1.25
cell
= 1.93 V
(D) I, II
o
E = 1.25– (0.74)
cell
= 1.49 V
167. Answer: A 168. Answer: B
Sol: Sol:
Cr+3 + 3e– Cr (1) Potential is a relative terms i.e. it is
always measured with respect to a
Cr+3 + e– Cr+2 (2) reference. In electrochemistry,
Target Equation Hdyrogen is taken to be the reference to
measure the potential and hence to
Cr+2 + 2e– Cr form a basis for comparision with all
other electrode reactions, hydrogen's
ΔG º = ΔGº – ΔGº 1 2 standard electrode potential is declared
– 2 × FEº = +3 × Fx 0.74 – 1 × Fx 0.40 to be zero volts at all temperatyures.
Therefore, the correct answer is (B)
– 2Eº = 2.22 – 0.40
Eº = – 0.91 V
169. Answer: A 170. Answer: B
Sol: Sol:
SRP Δ H= Δ U + PΔV [PV = nRΔT]
Z>Y>X Δ H = nCvΔT + nRΔT ΔU = nCvΔT
⇒ Z will oxidize both Δ H = nΔT(Cv + R)
∴ ΔH = nCp ΔT
n = 1 (given)
Δ H = CpΔT ...(1)
Δ H= 5
2
RΔT
2
X2 +
3
2
Y2 → XY3 ΔH = −30 kJ ΔH = 4 Kcal/mol
ΔS = SXY3 −
1
2
SX2 −
3
2
SY2 ΔS = 10 cal mol–1 K–1
= 50 −
1
× 60 −
3
× 40
at. equilibrium. ΔG < 0
2 2
T > ΔH
> 4000
> 400 K
= 50 - 30 - 60 ΔS 10
= - 40
For equilibrium, ΔG = 0
T= ΔH
ΔS
=
−30×1000
40
= 750 K
175. Answer: B 176. Answer: D
Sol: Sol:
At equilibrium At constant temperature and pressure
ΔH = ΔU + ΔnRT
ΔG = 0 ⇒ Δn = nP–nR ⇒ 2 – 4 = – 2
∴ΔH < ΔU
If Δ Gsystem > 0, the process is non
spontaneous Therefore, the correct answer is (D)
If Δ Gsystem < 0, the process is
spontaneous
Therefore, the correct answer is (B)
177. Answer: D 178. Answer: A
Sol: Sol:
we know, ΔG = ΔH − TΔS Δ S Vap. = 186.5
373
⇒ 0.5KJ/mole/K.
TΔS = ΔH − ΔG
Therefore, the correct answer is (A)
ΔH−ΔG
ΔS =
T
V1
Δn = 2 − 3 = − 1 = 2.303 × 1 × 8.314 × 10
7
× 298 log
20
10
ΔU = −1366.5 + 1×8.31×300
1000
7
= 298 × 10 × 8.314 × 2.303 log 2.
ΔU = − 1364
181. Answer: A 182. Answer: C
Sol: Sol:
Δng = (6 + 3) – (0 + 7.5)
o −1 −1
ΔSreaction = −215 .2 JK Mol
Δng = 1.5
ΔH - ΔE =1.5 × 3.3 × 300 = 3.74 kJ
Therefore, the correct answer is (B)
185. Answer: D
Sol:
If Δng = 0 ⇒ ΔH = ΔE
Case–I = ∆ng = 2 – 1 –1 = 0
Case–II = ∆ng = 0 – 0 = 0
Case–III = ∆ng = 1 – 1 = 0
Case–IV = ∆ng = 2 – 3 – 1 = –2 ≠ 0
Therefore, option D is correct.
Chemistry - Section B
186. Answer: D
Sol:
Moving top to bottom in a group size
increases in groups, Cs has maximum
size
In group 17 F being on the top in group
have smallest size
Hence CsF have lowest anion to cation
size ratio
187. Answer: C 188. Answer: B
Sol: Sol:
As we know, electron affinity decrease ΔH = −(– 46 × 2) = 92 .0 kJ mol
−1
Zeff
(1) Zeff ∝
1
Atomic size
Atomic size
2
involve to removal of 2nd electron due
IP = 2X−Y to it has attain noble gas configuration.
Therefore lots of energy require for 2nd
Therefore the correct answer is (B) ionization energy
Therefore, the correct answer is (C)
199. Answer: B 200. Answer: C
Sol: Sol:
Electron affinity: Energy released by The electron affinity of an atom or
addition of an electron to an isolated molecule is defined as the amount of
gaseous element. energy released when an electron is
added to an atom to form a negative
7N ; 1S2 2S2 2P3 Half filled configuration ion.
(stable)
2 2 4 So, Electron affinity for both O2– and S2–
8O : 1S 2S 2P are less than zero.
6C : 1S1 2S2 2P2 Therefore, the correct answer is (C)
1 2 1
5B : 1S 2S 2P
Therefore N- has least electron affinity.
Therefore the correct answer is (B)