4/15/22, 9:17 AM Paper Preview

12TH  Marks : 45

LAKSHYA INSTITUTE PATHANKOT

 
SUBJECT : CHEMISTRY

CHEMTEST01  Time (mm:ss) : 60:00

TEST

 
 
1. 0

Sodium crystallizes in a bcc cubic lattice with the cell edge, 1.86A . What is the radius of sodium atom?

2. An element crystallizes in fcc lattice having edge length 400 pm. Calculate the maximum diameter of atom which can be placed in interstitial site without distorting the structure.

3. A metallic element crystallizes into a lattice containing a sequence of layers of ABABAB…… Any packing of layers leaves out voids in the lattice. What percentage of this lattice is
empty space?

4. 0

The edge length of unit cell of a metal having molecular weight 75g/mol is 5 A which crystallizes in cubic lattice. If the density is 2 g/cc then find the radius of metal atom.

(NA = 6 × 10
23
) . Give the answer in pm.

5. 0

A metal crystallizes into two cubic phases, face centred cubic (fcc) and body centred cubic (bcc), whose unit cell lengths are 3.5 and 3.0 A , respectively , Calculate the ratio of
densities of fcc and bcc.

6. Chromium metal crystallizes with a body centred cubic lattice. The length of the unit edge is found to be 287 pm. Calculate the atomic radius. What would be the density of
chromium in g/cm3?

7. An element germanium crystallises in bcc type crystal structure with edge

of unit cell 288 pm and the density of the element is 7.2 g cm-3.
Calculate the number of atoms present in 52g of the crystalline element.

Also calculate atomic mass of the element.

8. An element has a cubic unit cell made up of faces as shown below:

Co-ordination number of a lattice point in the above solid is

9. At 1000C, copper (Cu) has FCC unit cell structure with cell edge length of x Å. The approximate density of Cu (in g cm-3) at this temperature is y/x3. Find y.

[Atomic Mass of Cu = 63.55u]

10. Fe0.95O can be due to presence of iron in +2 and +3 oxidation numbers.

Then % of iron present in +3 oxidation state will be

om

11. A newly synthesised copper complex with molecular formula C11H29N5B2Cu (molar mass = 316.5 g mol-1) is found to crystallise in the orthorhombic system with following
parameters. Thus, the number of molecules of the complex per unit cell is …….

t.c
en

)
ssm

te+
ma
bo
Ro
se

by
red
as

we
bo

(po

12. ‘A’ and ‘B’ crystallises in such a way that ‘B’ is present at the corners of the cube as well as on the faces of the cube. If ‘A’ occupies all tetrahedral void then formula of unit cell is Ax By
and value of x + y is
ro

13. In NaCl structure, Cl- ions have ccp arrangement and Na+ ions occupy all the octahedral sites. The total number of Na+ and Cl- ions per unit cell is _______.

14. Atoms of element A from hcp arrangement and those of element B occupy 2/3rd of tetrahedral voids. The total number of A and B per formula unit is _____.

15. In hexagonal close packing, the difference in the number of tetrahedral and octahedral voids in a unit cell is ______.

END

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