132/2-Mock Examination 2022

PRESIDENT’S OFFICE
REGIONAL ADMINISTRATION AND LOCAL GOVERNMENT
ADVANCED CERTIFICATE OF SECONDARY EDUCATION EXAMINATION
MOCK EXAMINATION SOUTHERN ZONE
(MTWARA AND LINDI )

132/2 CHEMISTRY 2
(For Both School and Private Candidates)

Time: 3 Hours Friday, 04th February, 2022 p.m.

Instructions

1. This paper consists of six (6) questions.

2. Answer only five (5) questions.

3. Each question carries twenty (20) marks.

4. Mathematical tables and Non programable calculators may be used.

5. Cellular phones and any unauthorized materials are not allowed in the examination
room.

6. Write your Examination Number on every page of your answer booklet(s).

7. For calculations you may use the following constants:

• Universal gas constant,R= 8.314JK−1 mol−1 or 0.0821K−1 atm mol−1 K−1 dm3
• Standard temperature =273K
• Standard pressure =1atm =760mmHg =1.0 × 105 Nm−2
• 1Faraday= 96500Cmol−1
• GMV=22.4dm3
• 1Litre=1dm3 = 1000cm3
• Velocity of light,C=3.0 × 108 m/s
• Atomic masses:Ag= 108, Cl= 35.5, Mn= 55, Fe= 56, I= 127

This paper consists of Five (5) printed pages.

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132/2-Mock Examination 2022

1. (a) (i) What is ideal solution. (01 mark)

(ii) Ideal solution differ from non-ideal solution by four areas, by using four
points give factors contributes to ideal solution formation. (04 marks)
(iii) By using well labelled diagram show that Acetone and Ethanol mixture form
a non-ideal solutions. (05 marks)
(b) When 0.7dm3 of an aqueous solution containing 6g of a solute B per litre was
shaken with 200cm3 of heptanol, 3.21g of the solute B was extracted. Assuming
the molecular state of the solute remained the same in both solvents, Calculate:
(i) Value of distribution coefficient. (03 mark)
(ii) Mass of the solute B which remained in the aqueous solution after a further
shaking with 200cm3 of heptanol. (03 marks)
(c) (i) What is steam distillation?. (01 mark)
(ii) Chlorobenzene which is insoluble in water is steam distilled at 98◦ C and
atmospheric pressure of 101300Pa. A sample of steam distillate contains
247g of chlorobenzene for every 16g of H2 O. Calculate the vapour pressure
of water and chlorobenzene at 98◦ C. (03 marks)

2. (a) Define the following terms as applied in chemistry

(i) Electric double layer (01 21 marks)
(ii) Electrode potential (01 21 marks)
(iii) Salt Bridge. (01 21 marks)
(b) (i) Differentiate between Kohlrausch law and Ostwald dilution law.
(02 marks)
(ii) Give five application of electrochemical series in life of chemistry.
(02 21 marks)
i−1
(iii) Show the relationship between weak electrolyte and α = .
v−1
(02 marks)
(c) (i) During supplying of food to students with silver tray it observed some silver
particles were plated out from silver tray. How many grams of silver could
be plated out on a serving tray by electrolysis of a solution silver +1 for a
period of 8 hours at a passed current of 8.35amphere.
(04 marks)
(ii) What mass of NH4 Cl must be added to 0.5L of 1molL−1 NH3 solution to
yield a solution with a PH of 9.0. Assume that no change in volume with
Kb of 1.8 × 10−5 . (03 marks)

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(d) Give two components of buffer solution. (02 marks)

3. (a) Explain the following concepts:-

(i) Is there any reaction for which the rate does not change with the initial
concentrations of the reactants?. (02 marks)
(ii) A lump of coal burns at a moderate rate in air while coal dust burns
explosively. (02 marks)
(iii) liquid bromide reacts slowly as compared to bromine vapour. (02 marks)
(iv) The energy of activation determine its rate. (02 marks)
(b) (i) What is half life of the reaction. (01 mark)
(ii) Consider the following reaction
H2(g) + I2(g) −→ 2HI(g) .
If the rate constant K at 310◦ C and 420◦ C is 1.3 × 10−3 dm−3 mol−1 s−1 and
6.3 × 10−2 dm−3 mol−1 s−1 respectively, What is the activation energy Ea for
the reaction?. (04 marks)
(c) The following table contains data which were collected at 298K for the
reaction.
4H2 + 2NO2(g) −→ 4H2 O(l) + N2(g) .

[H2 ] [NO2 ] Rate(mols)−1

0.7 0.42 0.41
0.7 0.84 0.82
1.4 0.84 0.82
(i) Write down the rate expression for the reaction. (03 marks)
(ii) Calculate the order of the reaction with respect to each reactant and write
the overall order of reaction. (04 marks)

4. (a) (i) Describe four features of coordination compounds. (04 marks)

(ii) Differentiate between charged complex from neutral complex. (02 marks)
(iii) How Ambidentante ligand differ from Monodentate ligand with example.
(02 marks)
(b) Give explanations and equation when possible from the following observations.
(i) Sodium metal is very soft compared with magnesium metal. (01 mark)
(ii) Silicon tetrachloride (SiCl4 ) can be hydrolysed by water, but carbon
tetrachloride (CCl4 ) can not be hydrolysed. (01 mark)
(iii) Aluminium metal does not react hot water or steam. (01 mark)

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(iv) F2 and Cl2 exists as gases, Br2 exist in the liquid form and I2 exist as solid.
(01 mark)
(v) lithium nitrate is decomposed thermally completely but potassium nitrate
decomposed only partially. (01 mark)
(c) Briefly explain the extraction of aluminium from its principal ore, bauxite
(Al2 O3 .2H2 O) by Bayer’s Method. (07 marks)
5. (a) (i) What is a nucleophilic addition reaction. (01 12 marks)
(ii) Describe the mechanism of nucleophilic addition reaction to a carbonyl
compound. (03 marks)
(iii) Explain why ethanal are more reactive than acetone towards nucleophilic
addition reaction. (02 21 marks)
(b) Complete the following chemical reactions:
O
Warm
(i) CH3 C CH CH + H2 N OH −−−→ (01 12 marks)
2 3
O
(ii) CH3 C CH CH + 3I2 + 4NaOH −→ (01 12 marks)
2 3
O
C H
Zn/Hg
(iii) + [H] −−−−−→. (01 12 marks)
conc.HCl
O
C H
(iv) + 2[Ag(NH3 )2 ] −→ (01 12 marks)
O
Dry
(v) CH3 CH2 CH2 C CH + CH3 CH2 MgBr −−−→ (01 12 marks)
3 Ether
(c) An unknown ester E was found to have molecular formula C5 H10 O2 . When E
was hydrolysed with water in the presence of mineral acid, it produced
carboxylic acid F with alcohol G. The treatment of G with SOCl2 gave an
alkyl chloride H. When H was treated with KCN, a product I was formed
which on hydrolysis with water and acid produced carboxylic acid F.
(i) Use this information to deduce the structure and name of the original ester.
(02 marks)
(ii) Identify F to I and write all chemical reactions involved. (06 marks)
6. (a) An organic compound C2 H4 O gives red precipitate when warmed with Fehling’s
solution. It also undergo aldol condensation in the presence of NaOH.

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(i) Write structure and IUPAC name of the compound. (01 mark)
(ii) What is the state of hybridization of the carbon atoms in the compound.
(01 mark)
(iii) Write all reactions involved in the compound. (02 21 marks)
(b) Show how the following conversion may be achieved.
OH O
C CH3
(i) −→ (01 12 marks)
NH2

(ii) CH3 CH2 CH2 CH3 −→ (01 12 marks)

O
(iii) CH3 CH2 C OH −→ CH3 CH2 CH2 NH2 (01 12 marks)
C N OH
(iv) HC CH −→ H (01 12 marks)

CH2 CH3 NH2

(v) −→ (01 12 marks)
(c) An ester A (C4 H8 O2 ), on treatment with excess methyl magnesium chloride
followed by acidification, gives an alcohol B as the sole organic product.
Alcohol B, on oxidation with NaOCl followed by acidification, gives acetic
acid.
(i) Deduce the structure of A and B. (02 marks)
(ii) Show all reactions involved. (03 marks)

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