12th - FLT-2 - Hints & Solution

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XII_JEE Main FULL LENGTH TEST-2 Date : 14-02-2021

Q.1 B
[Sol: In the reference frame of infinity, U = 0
E1 = –13.6 eV, K1 = 13.6 eV, U1 = –27.2 eV
E2 = –3.4 eV, K2 = 3.4 eV, U2 = – 6.8 eV
Now for U1 to be zero, we have to add 27.2 eV to U1.
Hence E2 = – 3.4 + 27.2 = 23.8 eV ]

Q.2 C
dU
[Sol: F  2Br  r0 
dr
K 2B
2   m1  m 2  ]
m reduced m1m 2
Q.3 C
0I R 2
[Sol: Magnetic flux through the loop A;   B r 2  r 2
2 2 3/ 2

2R x 
d  0 I R 2  r 2  3 dx 
Induced emf in the loop A;      5/ 2
2x
dt 2  2
 2
 dt 
 2R x 

3 0IR 2  r 2 v  x 
  5/ 2

2  R 2  x 2
  

d
Induced emf is maximum when 0
dx

2 R
R  x 2  5x 2  0 or x 
 ]
2

Q.4 D
Q.5 B
[Sol: Work done to rotate the ring is equal to work done to return the charge at its initial position. ]

Q.6 C
Kq Kq
[Sol: Potential of centre of sphere =  Vi 
r r
where Vi = potential due to induced charge at centre = 0 [ qi = 0 and all induced charges are
equidistance from centre]
Kq Kq
 potential at point P =   Vi (For conductor all points are equipotential)
r r1

q q 
 Vi  K    ]
 r r1 

XII_FLT-2 PAGE # 1
Q.7 D
4Q 2Q
[Sol: Slope of potential from x = 0 to x = d is  
2 0 A 0A

3Q
Slope of potential from x = d to x = 2d is 
0 A

2Q
Slope of potential from x = 2d to x = 3d is ]
0A
Q.8 C
V0
[Sol: Isotherm of maximum temperature has line AB as tangent on it at ]
2
Q.9 A
[Sol: The relative velocity of sound waves with respect to the walls is V  v.
(V  v)
Hence, the apparent frequency of the waves striking the surface of the wall is .

The number of positive crests striking per second is the same as frequency.
In three seconds, the number is [3(V  v)] / . ]
Q.10 A
2l dy
[Sol: y = 2A cos kx sin t (assuming t = 0, y = 0),   as P = B = B 2Ak sin kx sin t,
3 dx

B
Pmax  B(2A )k also v   2A = 2.5 cm. ]

Q.11 A
3v
[Sol: f
4(L  0.6r )

df 3v  1 dr  3v dr 8 dr dr 1
   2
 (0.6)  ;  2    0.6  ;  ;  m/s ]
dt 4  (L  0.6r ) dt  4  dt  3v  0.6 dt dt 72
Q.12 D
I 4I
[Sol. Current density :  = 2 2 r=
R  ( R / 2) 3R 2
2
R I
Current in smaller cylinder (if there were) : I1 =    = Magnetism
2 3
µ0 (I / 3)  µ0 I
For A : BA = Bwhole – cylinder – Bsmall – cylinder  BA = 0 =  
2(R / 2) 3R
For B : BB = Bwhole – cylinder – Bsmall – cylinder
µ0 (I  I / 3)(R / 2) µ0I
= 2 –0= ]
2R 3R
Q.13 B
XII_FLT-2 PAGE # 2
[Sol: In 8.5 sec
17 
 = t = = 4 +
4 4
A
2
t = 8.5 sec

45°
t = 0, 4, 8 sec

x=A
x=–A x=0
A
x=
2

A A 3
 Distance = 8A + A –  9A   27  cm ]
2 2 2
Q.14 A
dQ Pr 4
[Sol: 
dt 8 L
As capillaries are joined in series, so (dQ / dt ) will be same for each capillary..

Pr 4 P(r / 2) 4 P(r / 3) 4


Hence,  
8L 8(L / 2) 8(L / 3)
So, pressure difference across the ends of 2nd capillary
p  8P
and across the ends of 3rd capillary
p  27 P ]

Q.15 B
[Sol: h2 = constant ]

Q.16 A
[Sol: T ( R  r )  mgR ; 2mg  T  2ma ;
T  mg  ma
On solving, we get
 3 
 r  R 1   ]
 2(1  ) 
Q.17 D

XII_FLT-2 PAGE # 3
iB = 57°
57° 57°
µ=1

Sol. µ = 1.54 r= – 57° = 33°
r 2

Q.18 C

Q.19 B
1
T
[Sol:  100  5  100  0.8% ]
T 25

Q.20 C

SECTION: 2
[NUMERICAL TYPE]
Q.1 to Q.10 are "Numerical Type" questions. (Do Any FIVE) .There is NO NEGATIVE marking.
[5×4=20]
Q.1 72
h
[Sol: kx0h =  ( bdx )gx ( h  x )  kx0h
0

h
 h 2 h3 
= bg  ( hx  x 2 )dx  bg  h  
0  2 3

h3 bgh 2
 kx0h = bg  x0 =
6 6k

1 2 1 b 2 2 g 2 h 4 b 2 2 g 2 h 4
PE = kx 0  k  ]
2 2 36k 2 72k

Q.2 3
V l iR E0 R 10 5
[Sol: E  xl   l  E = R  R  r  L l  E  3  3V
L L h 5  4 1 5

Q.3 45
220 2
[Sol: 1
R 2  X c2

R 2  X C2  220  220  2

X c2  2  220 2  2202
 
X C  220
XII_FLT-2 PAGE # 4
Xc 220
tan    1
R 220
  450 ]

Q.4 240
 2 1  0  1 2  0
[Sol:  = R + R
v u 1 2

When u   V  f
1 .6 1 .5  1 .2 1 .6  1 .5
 
f  30  30
f = 240 cm ]

Q.5 21
E
Sol. B=
c

Q.6 10
2
I1 I max  I1  I 2 
Sol.  9
I 2 = ratio of slit width = 4 and I min  I1  I 2 

Q.7 5
Q.8 1
1
[Sol. WNA  WNG  WG  m BV 2  0 WPE
2
1
WNA  0  0  ( 2) (1) 2  0  1 ]
2
Q.9 7
Sol. From diagram

2A 6V 2

2
5A
A
10V
CE

5A 2

Current through ammeter


= (2 + 5) = 7A

Q.10 0.02

XII_FLT-2 PAGE # 5
XII JEE Main FLT-2 Date : 14-02-2021
CHEMISTRY
SECTION:1
[SINGLE CORRECT CHOICE TYPE]
Q.1 to Q.20 has four choices (1), (2), (3), (4) out of which ONLY ONE is correct.
Q.1 C

Q.2 B
Sol. (1) both are enantiomers (2) fliping is present
(3) both are enantiomers. (4) both are enantiomers

Q.3 B

Q.4 D

Q.5 D
[Sol. D is 2° amine ]

Q.6 A
Q.7 D
Q.8 A
Q.9 C
Cl

Sol. Na
/ether


Cl
Q.10 A
Q.11 C
Q.12 A
OMe
Sol. MeMgBr
  (excess
)  H2SO
4 
 +
O H 3O 
OH 
(P) (Major) (Minor)
(Q) (R)

Br2/CCl4 Br2/CCl4

Br Br

Br
Br

Q.13 C

XII PAGE # 1
Q.14 D

Q.15 B

PCl
[Sol. 5  Ph – C = N – CH3

H2O

Ph–C=N–CH3
|
OH

Ph–C–NH–CH3
||
O

Only anti group migrates during Beckmann rearrangement. ]

Q.16 C

Q.17 C
Q.18 D
CONH2
NH2
O H / Br2
[Sol:   ]
Hoffman bromamide degradation
D
D
Q.19 D
Q.20 C
Me
: O: OAlCl3

Sol. :O: AlCl


(para>ortho)
O O

Me Me

H OAlCl3 OH
O O
O O

XII PAGE # 2
SECTION:2
[NUMERICAL TYPE]
Q.1 to Q.10 are "Numerical Type" questions. There is NO NEGATIVE marking. [5×4=20]
Q.1 6
Q.2 96
Z.M 4  24 10 3
[Sol. Theoretical density = N .a 3 
A 6  10 23  ( 4  1010 ) 3
Z.M
Theoretical density d= N .a 3  2.5 × 103 kg/m3
A

Observed density 2.4 103


% occupancy = Ideal density × 100  × 100 = 96 % Ans.]
2.5  103
Q.3 2
OH

Sol. (a) OMDM


 

O
CN C=NMgX 
(b) CH
3MgBr
 CH3 H3O

OH O
Hg 2 
(c) 
H 3O 

(d) B
2 H 6 / THF
 
H 2 O 2 / OH ¯ OH

Q.4 6

Q.5 5
[Sol. H3PO3  2H+ + HPO 32 rH = ?
2H+ + OH—  2H2O rH = –55.84 × 2 = –111.68
–106.68 = ionH – 55.84 × 2
ionH = 5 kJ/mol ]

Q.6 4

Sol. OH
 2-H
N NMe2

XII PAGE # 3
Br Me
Me

HBr

Br Br
Q.7 2
Q.8 8
1.055
[Sol. × x ×18 = (1.055 – 0.695)  x=8 Ans. ]
24  254  18x

Q.9 3
Sol. (III), (IV), (VI)

(III) O (Reductive ozonolysis)


CHO

(IV) (Hoffmann alkene is major due to sterically hindered base)

(VI) (Pyrolysis of ester yields Hoffmann alkene.)

Q.10 0.33
[Sol. PM = dRT
dRT 6.25  0.08  278
Mmix =   139
P 1

M PCl5  M mix 208.5  139


=  = 0.5
M mix (n  1) 139(2  1)

2 0 .5 2 0.25 1
KP= 2
( PT )  2
  ]
1  1  (0.5) 0.75 3

XII PAGE # 4
FLT-2 (MATHEMATICS) 14.02.2021 CLASS: XII

PART-A
[SINGLE CORRECT CHOICE TYPE]
Q.1 to Q.20 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
Q.1 B
[Sol: Lim f (x) = 0  continuous
x 0
but LHD = – 1 and RHD = 1 ]

Q.2 A
[Sol: Let y = f (x) = x3 – 12x and y = – a
For f(x) = – a to have exactly one real root, we must have
– a > 16 or – a < – 16  a  ( – , – 16)  (16, )

y
y = f(x)
16

O x
–2 2

Ans.
– 16

Alternate: Let f(x) = x3 – 12x + a


f '(x) = 3x2 – 12 = 3(x + 2) (x – 2)
 The equation f(x) = 0 has exactly one real root, if f (– 2) f (2) > 0
 (16 + a) (– 16 + a) > 0  (a – 16) (a + 16) > 0
 a  ( – , – 16)  (16, )
Y Y

O (0,0)
x=2 X
x= –2
X
x= –2 O (0,0) x=2
OR

Two possible graph of f(x). Ans. ]


Page # 1
Q.3 D
1 a
2 4
[Sol: A(a) = 2   (1  x 
)  a dx =
3
(1 – a)3/2
0

4
 A(0) =
3
y

y=a
(– 1, 0) (1, 0)
× × a
O 1 a

3
1 4 12 A ( 0)
and A   =    = 2 2. ]
2 3 2 1
A 
2
Q.4 A
[Sol: p q pq pVq ~(p V q) ( p  q )  (~ ( p V q ))
T F F T F F
F T F T F F
T T T T F F
F F F F T F ]

Q.5 A
[Sol: Use L'Hospital's rule

(tan 1 x ) x 2  1
Lim ;
x  x

 x2 1 
Lim = . Ans. ]
2 x  x 2

Q.6 D
[Sol. Since, root mean square  arithmetic mean
n n
 x i2  xi
i 1 i 1
400 80
  =   n  16
n n n n
Hence, possible value of n = 18. ]
Q.7 D
(n  1)2  n 1 1 
[Sol: Tn = =1+   
n (n  1)  n n 1

 1  120
 S10 = 10 + 1   = Ans. ]
 11  11

Page # 2
Q.8 B
2
3 2 9
2    2· 1
 2  2   2    2     4  4 16
[Sol: = 2 = = =–7 ]
( ) 2     1
2 1
  16
4
Q.9 B

a1 b1
a2
a3 b2
[Sol: Let b1 < b2 < b3 < b4
a4 b3
a5
a6 b4

 N = 6C3 · (3!) = 20 × 6 = 120 ]

Q.10 A
B A 1 1 1
[Sol: P(A) · P   = P(B) · P    × = P(B) ×
A B 4 2 4

1 1 1  A  P(A  B) 1  P(A  B)
 P(B) = ; P(A) = and P(A  B) = ;  P  B  = =
2 4 8   P ( B) 1  P(B)

1 1 1
1    
=  2 4 8 = 3 ]
1 4
1
2
Q.11 A

[Sol: OP = 2cos 30º = 3 P (X, Y)


2
 OP2 = 3 30°
 X2 + Y2 = 3 ] O(0, 0) 2

Q.12 B
h
[Sol:  Line is (y – k) = (x – h)
k

 3
P  2, 
 2

P (h, k)
h
k m' =
3  h m=h k
   k = (2 – h)
2  k O
L

Page # 3
3k 3y
 – k2 = – 2h + h2  + 2x = x2 + y2  2x2 + 2y2 – 4x – 3y = 0
2 2

Q.13 B
[Sol. 6C p4 (1 – p)2 = 6C p5 (1 – p)
4 5
 15 (1 – p) = 6p
1 p 2
 =
p 5
6
C2 p 2 (1  p) 4 15 (1  p) 3 2 3
Now, 6 3 3 =
 =  = . Ans.]
C3 p (1  p) 20 p 4 5 10
Q.14 D
c c c( x  iy)
[Sol. We have u + iv = z   u + iv = (x + iy) +  u + iv = (x + iy) + 2
z x  iy x  y2
 u + iv = x(1 + c) + i(1 – c)y (using x2 + y2 = 1)
u2 v2
Hence  = x2 + y2 = 1, which is an ellipse. Ans.]
(1  c) 2 (1  c) 2

Q.15 A
[Sol. D = (8P)2 – 4 (p – 2) = 4(16p2 – p + 2)  D > 0
(A) f (x) = x2 – 8px + p – 2
1 1
f (1) < 0  –7p – 1 < 0  p >
7
and f (0) > 0  p > 2
 p  (2, ) ]

Q.16 C
[Sol: L1 through Point A (1, 1, 1) and dir <1, 1, 1>
L2 through point B (1, – 1, 0) and dir <1, – 1,– 1>
0 2 1
1 1 1 2 1
 S·D = 1 1  1 = = ]
2 2 2
440
Q.17 C
[Sol. Given
(z2 + 1) (z2 + z + 1) = z2
z4 + z3 + 2z2 + 2 + 1 = z2
z4 + z3 + z2 + z + 1 = 0
z5 – 1 = 0
z5 = 1
z100 = 1
Hence value is 6 × 6 = 36. ]

Page # 4
Q.18 C
1
  1  2   n   n
[Sol: L = Lim  1  1  .....1   
n    n  n   n  

1 n  r 1
 ln L = Lim l n 1
   =  ln (1  x ) dx

n  n r 1  n 
0

4
 ln L = 2ln 2 – 1  L = ]
e
Q.19 D

 cos 10 3 

 2  sin 10  2

 2 
[Sol:  + =
1
2 cos 10 sin 10 
2

cos(60  10)
  + = 4 · =4
sin 20
2 sin 25 cos 60
and  ·  = =1
cos 65
 x2 – 4x + 1 = 0
 = 16 – 4 = 12 (Not perfect square) ]

Q.20 C
c c
[Sol: Let u = , so du = 2 dx ,
x x
c c c
f (x ) u f (u )   x 2  f (u )
so  dx =  du =  du
1
x c
c  c  c
u

c c c
f (x ) f (x ) f (u )
Therefore,  dx =  dx +  du = 3 +3 = 6 Ans. ]
1
x x u
1 c

[NUMERICAL TYPE]
Q.1 to Q.10 are "Numerical Type" questions. (Do any FIVE) [10×4=40]
Q.1 12
[Sol: From the first radical sign
x2 + y2  16 i.e. interior of a circle with circle (0, 0) and radius 4.
From the 2nd radical sign y  |x|
3
i.e. th of the circle
4

Page # 5
y

x
O

3
Required area = (·16) = 12Ans. ]
4
Q.2 120
15 15 15 15
ar Cr (15)! (r  1)! (15  r  1)!
[Sol: r· a r 1
=  r · 15 C r 1
=  r · (15  r )! r! × (15)!
r 1 r 1 r 1

15
15 16
=  (16  r) = (1 + 2 + 3 + ...... + 15) = = 120. ]
2
r 1

Q.3 32
1
9 6 3 6 3
[Sol:   (x  x  x ) (2x  3x  6) 3 dx
1
=  ( x 8  x 5  x 2 ) ( 2 x 9  3x 6  6 x 3 ) 3 dx
Let 2x9 + 3x6 + 6x3 = t  18(x8 + x5 + x2)dx = dt
t1 / 3 1 t4/3 1 4/3
 I=  18 dt = · +C = t +C
18 4 / 3 24
4
 AB = 24 × = 32 Ans. ]
3
Q.4 125
3
[Sol: y = 5  x2 3
 
2

dy 3 2 1 
dx
=
2
5  x   3 , x
23
13 

dy
dx M (1, 8) = 5 1 = – 2
When x = 1, y = 8
tangent is y – 8 = – 2(x – 1) 2x + y = 10
length of intercept = 100  25 = 125  N = 125 Ans.]

Q.5 2
 sin  cos   sin   cos 
[Sol: PT · P =  cos  sin   cos  sin  
  

1 0  1 2018
 P T · P = 0 1  = I  PT · (Q)2018 · P = A2018 = 0 1  ]
  

Page # 6
Q.6 2
[Sol. cc1 = r + r1
cc2 = r + r2 c1 r1 r2 c2
cc1 – cc2 = r1 – r2
r1 r2
 Locus of c is hyperbola with foci c1 and c2
 2ae = c1c2 = r1 + r2 and r1 – r2 = 2a r r

r1  r2 c
 = 2
r1  r2
 e2 = 2 ]

Q.7 48

 0  
 
[Sol. A =  0 
  0 
 

Number of skew symmetric matrices = 3! × 8 = 48. Ans.


[ As, diagonal element must be 0 and conjugate pair elements are additive inverse of each other
in skew-symmetric matrix. ]
Aliter: 1 can be put by 6 ways
– 1 can be put by 1 way
2 can be put by 4 ways
– 2 can be put by 1 way
3 can be put by 2 ways
– 3 can be put by 1 way
 Number of skew symmetric matrices = 6 × 1 × 4 × 1 × 2 × 1 = 48. Ans.]

Q.8 58
[Sol: Since, both the planes are parallel
P1 : 4x – 6y + 12z + 10 = 0
P2 : 4x – 6y + 12z + d = 0
b = – 6, c = 12
d  10
Now, =3
2 4  9  36
| d – 10 | = 42  d = 52 or – 32
 P2 is 4x – 6y + 12z + 52 = 0
or 4x – 6y + 12z – 32 = 0
 Point (–3, 0, –1) is lying between planes P1 and P2
 On substituting the point in the equation of the planes both expressions must be of opposite sign.
From P1 :
4 × (–3) – 6 × 0 + 12 (–1) + 10= –ve
From P2 :
4 × (–3) – 6 × 0 + 12 (–1) + 52 = +ve
 d must be 52
Hence, (b + c + d) = – 6 + 12 + 52 = 58 ]

Page # 7
Q.9 2
Sol. Let k (x) = f(x) f (x)
 k (x) = (f (x))2 + f (x) · f (x)
 Given k (x) = k (x)
k ' (x )
 1
k(x )
Integrating we get
k(x) = ex
k(x) e–x = 1
Let G(x) = e–x f (x) f  (x)
Now G(2) = G(4) = 0 [ f (2) = f(4) = 0]
Also using Rolle's theorem
f  (c) = 0 for C  (2, 4)
 G(c) = 0 for C  (2, 4)
 G(2) = G(c) = G(4) = 0
 G  (x) has at least 2 zeroes in (2, 4) ]

Q.10 3
y ( x 3 )  x 3dy  x3 
Sol.de = dx  d   = dx
y2  y
 

x3
=x+C  8=2+C  C=6
y

x3
y = f(x) =  f(3) = 3.
x6

Page # 8

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