CHEMISTRY

TARGET JEE 2022

DATE: 22.11.2020
CLASS : XI NSEC MM:240 Time: 120 min
NATIONAL STANDARD EXAMINATION IN CHEMISTRY
Date of Examination: 22nd November, 2020
Instructions to Candidates -
1. Use of mobile phones, smartphones, ipads during examination is STRICTLY PROHIBITED.
2. Make all the entries carefully in the space provided.
Incomplete/ incorrect/carelessly filled information may disqualify you.
3. Question paper has 80 multiple choice questions. Each question has four alternatives, out of which
only one is correct. Choose the correct alternative and fill appropriately.
4. A correct answer carries 3 marks whereas 1 mark will be deducted for each wrong answer.
5. Use of non-programmable calculator is allowed.
Answer sheets are evaluated using machine, hence CHANGE OF ENTRY IS NOT ALLOWED.
6. The answers/solutions to this question paper will be available on our website
|www.poojatutorials.com| Just after the completion of paper.

[SINGLE CORRECT CHOICE TYPE]

Q.1 to Q.80 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct. [+3, –1]

Q.1 Which starting material should be used to produce the compound shown below?

3O
? 
Zn  H 2O

(A) (B) (C) (D)

Q.2 A mixture of water and AgCl is shaken until a saturated solution is obtained. Now 100 ml of this solution
is mixed with 100 ml of 0.03 M.NaBr than -
[Ksp of AgCl and AgBr are 10–10 and 5×10–13 respectively. ]
(A) Yellow ppt of AgBr will not be obtained
(B) Yellow ppt of AgBr will not obtained
(C) both AgCl & AgBr will precipitate
(D) None of these

Q.3 The alkene ligand ( - C2R4) is both a ‘’ donor and a ‘’ acceptor , similar to the CO ligand in metal
carbonyls, and exhibits synergic bonding with metals. Correct order of C-C bond length in
K[PtCl3( - C2R4)] complexes in which R = H, F or CN is -
(A) H > F > CN (B) H > CN > F (C) CN > F > H (D) F > H > CN

Q.4 Arrange in order of decreasing reactivity in electrophilic addition

(I) Ph–CH = CH–COOH (II) p–NO2–C6H4–CH=CH–COOH
(III) p–MeO–C6H4–CH = CH–COOH (IV) p–Cl–C6H4–CH = CH–COOH
(A) II >I > IV > III (B) III > IV > I > II (C) III > I > IV > II (D) II > IV > I > III

XI_NSEC PAGE # 1
Q.5 An ammonia - ammonium chloride buffer has a pH value of 9 with [NH3] = 0.25. What will be the new
pH if 500 ml 0.1 M KOH is added to 200 ml buffer solution (Kb = 2 × 10–5) [log 2 = 0.3]
(A) 8.4 (B) 9.6 (C) 5.6 (D) 4.4

Q.6 Which of the following pairs of compounds can be stable while retaining the identity of each compound
in the pair over a period of time ?
(I) FeCl3, SnCl2 (II) HgCl2, SnCl2 (III) MgCl2, SnCl2 (IV) FeCl3, KI
(A) I only (B) I and III (C) III only (D) II and IV

Q.7 Identify the final major product of given reactions

( i ) B2 H 6 ,THF conc . H PO
   X  34  Y dil
. H
2SO 4
 Z (Major product)
(ii ) H 2O 2 / OH  

Z is :

(A) (B) (C) (D)

D
Q.8 For a reaction A nB the x (degree of dissociation) varies with in the above reaction
d
according to :

)45º
D
d

what will be the value of Kp if A is 25% dissociated at 5 atm pressure at equilibrium.

(A) 0.25 (B) 0.33 (C) 0.30 (D) 0.35

Q.9 An excess of aqueous ammonia is added to three different flasks (Ft, F2, F3) containing aqueous solutions
of CuSO4, Fe2(SO4)3 and NiSO4 respectively. Which of the following is correct about this addition ?
I. A precipitate will be formed in all three flasks
II. Ammonia acts as a base as well as a ligand exchange reagent in F1 and F3
III. A soluble complex of NH3 and the metal ion is formed in F1 and F3
IV. A precipitate will be formed only in F2
(A) I only (B) IV only (C) II and IV (D) II, III and IV

Q.10 Two C4H6 isomers give the same C4H8O product with HgSO4 and dil. H2SO4. However, these isomers
give different C4H6Br4 products with excess bromine. What are these isomeric hydrocarbons?
(A) Cyclobutene and 1-butyne (B) 1, 2-butadiene and 1, 3-butadiene
(C) 2-butyne and cyclobutene (D) 2-butyne and 1-butyne

Q.11 Solubility of AgI in 0.05 M BaI2 solution is 1 x 10–15 M. The solubility of AgI in water is :
(A) 10–8 M (B) 5 x 10–8 (C) 10–7 M (D) 25 x 10–7

Q.12 Among the halides NCl3(I), PCl3(II) and AsCl3(III), more than one type of acid in aqueous solution is
formed with
(A) I, II and III (B) II only (C) I and II (D) II and III
XI_NSEC PAGE # 2
 ( i ) 2 CO 2 HgSO 4
HC  CH 2
CH3MgBr 
Q.13  (A)    (B) dil  (C) 
. H 2SO 4
 (D)

( ii ) HOH / H

O O
|| ||
(A) CH 3  C  COOH (B) CH 3  C  CH 3

O
O
|| CH—C
(C) HOOC  C  CH 2  COOH (D) O
CH—C
O
Q.14 The graph which will be representing all the equilibrium concentrations for the reaction
N2O4(g) 2NO2 (g) will be :
(the concentrations of N2O4 (g) and of NO2 (g) for which the following reaction will be at equilibrium will
lie on which of the following graphs)

(A) [NO2] (B) [NO2] (C) [NO2] (D) [NO2]

[N2O4]
[N2O4] [N2O4]
[N2O4]

Q.15 Which of the following metal nitrate produces gaseous product when reacts with KCN solution?
(A) Cu (NO3)2 (B)AgNO3 (C) Cd(NO3)2 (D) Pb(NO3)2

Q.16 Reaction (i) Cl

2  P (major) (ii)
Cl 2
 P2 (major)
500 C 1 CCl 4

(iii) N   P3 (major) (iv)

Chloro Succinimide HCl
 P4 (major)


(v) (i ) NaCl

 P (major)
( ii ) H O
2 5

Select the incorrect statement about products.(P1 to P5)

(A) P1 & P3 are identical (B) P4 & P5 are identical
(C) P2 is dihalide (D) P3 is a monohalide.

Q.17 Which of these reaction is correct ?

(A) Cl– +Br2  Br– +Cl2
NaOH Solution
(B) Mohr’s salt    NH3(g)
SO 3
(C) K2Cr2O7 solution 
 Green colour solution
Excess NaOH
(D) FeCl2 NaOH
 (ppt. coloured)     Soluble complex

XI_NSEC PAGE # 3
Q.18 The organic Product (P) of the given reaction is

alc
.KOH
 P



(A) (B) (C) (D)

Q.19 Compound which on heating produces paramagnetic acidic gas?

(A) Mg(NO3)2 (B) Fe2(SO4)3 (C) FeCO3 (D) HgC2O4

Q.20 At a temp, T, a compound AB4(g) dissociates as 2AB4(g) A2(g) + 4B2(g) with a degree of
dissociation x, which is small compared with unity. The expression of Kp in terms of x and total pressure
P is :
(A) 8P3x5 (B) 256P3x5 (C) 4Px2 (D) None of these.

Q.21 Which of the following combination does not liberate NH3 gas ?
(A) Heating of NH4ClO4 (B) Heating of NH4Cl
(C) (NH4)2CO3+NaOH (D) Li3N + H2O


H
H2 O A
Hg(OAc)2
H2O/NaBH4
B
Q.22
B2H6/THF
H2O2/NaOH
C

Select the correct statement about products A, B & C.

(A) A is a primary alcohol (B) B is a secondary alcohol
(C) C is a tertiary alcohol (D) A & C are secondary alcohol

Q.23 The value of kp for the reaction at 270C

Br2(l) + Cl2(g) 2BrCl(g)
is ‘1 atm’. At equilibrium in a closed container partial pressure of BrCl gas is 0.1 atm and at this temperature
the vapour pressure of Br2(l) is also 0.1 atm. Then what will be minimum moles of Br2(l) to be added to
1 mole of Cl2 , initially, to get above equilibrium situation :
10 5 15
(A) moles (B) moles (C) moles (D) 2 moles
6 6 6
Q.24 Consider the following sequence of reactions :
CH 3COOH
M2+ (aq.) NH
4     Q Followed
Cl ( s )  ( NH 4 ) 2 CO 3 sol.        R
by addition of ( NH ) C O
4 2 2 4

Which of the following cation can form ppt. Q but does not form ppt. ‘R’ ?
(A) Mg2+(aq.) (B) Ca2+(aq.) (C) Sr2+(aq.) (D) Ba2+(aq.)

XI_NSEC PAGE # 4
 OH Baeyer 's
Q.25 conc
 . H 2SO 4
 Possible Product(s)    Total Product(s)
 reagent

Find out the total number of products.

(A) 6 (B) 5 (C) 4 (D) 8

Q.26 Find the pH(initial pH – final pH) when 100 ml 0.01 M HCl is added in a solution containing 0.1
m moles of NaHCO3 solution of negligible volume ( k a 1  10 7 , k a 2 10 11 for H2CO3) :
(A) 6 + 2 log3 (B) 6 – log3 (C) 6 + 2log2 (D) 6 – 2log3

Q.27 Which metal sulphide is soluble in excess NH3 solution ?

(A) ZnS (B) MnS (C) FeS (D) Cr2S3

Q.28 (
i ) Hg ( OCOCH 3 ) 2 .H 2O
     SOCl 2  NaI
 / acetone
 (Y)
( ii ) NaBH / OH ¯
4

Y is :
I
I

(A) (B) I (C) (D)

I

Q.29 A sample of gas is compressed from an initial volume of 2v0 to v0 using three different processes.
First : Using reversible isothermal
Second : Using reversible adiabatic
Third : Using irreversible adiabatic under a constant external pressure then
(A) Final temperature of gas will be highest at the end of third process.
(B) Final temperature of gas will be highest at the end of second process.
(C) Enthalpy change of sample will be highest in isothermal process. (magnitude wise)
(D) Final pressure of gas will be highest at the end of second process.

Q.30 I– (aq.) + MnO4–(aq.)  X + Mn2+ (aq.)

Neutral or
I– (aq.) + MnO4–(aq.) Weakly
 
OH 
Y + MnO2
MnO4–(aq) + Mn2+(aq) ZnSO  Z + 4H
4
+

Products X, Y and Z respectively:

(A) I2, IO3–, MnO2 (B) IO3–, I2, MnO2 (C) I2, IO3–, MnO42– (D) IO3–, I2, MnO42–

Q.31 What will be major product of the following reaction ?

HBr
 / 40C


Br
Br
(A) (B) (C) (D)
Br
XI_NSEC PAGE # 5
Br
Q.32 A liquid which is confined inside an adiabatic piston is suddenly taken from state 1 to state 2 by a single
stage process. If the piston comes to rest at point 2 as shown.Then the enthalpy change for the process
will be :

2  P0 V0 3  P0 V0
(A) H =  1
(B) H =  1
(C) H = –P0 V0 (D) None of these
Q.33 Select the incorrect match :
(A) Fe3+ +[Fe(CN)6]4–  Blue colour ppt.
(B) Fe3+ + [Fe(CN)6]3–  Red brown colouration
(C) Fe2+ +[Fe(CN)6]3–  Blue colour ppt.
(D) Fe2+ + [Fe(CN)6]4–  Red brown colouration

Q.34 Br / H 2O / NaCl

2   

Which product can not form during above reaction?

CH3 CH3
OH Br
Br Br
(A) H + en (B) H + en

CH3 CH3
Cl OH
Br Cl
(C) + en (D) H + en
H

Q.35 Equilibrium concentration of B if initial moles of 'A' , 'B', and 'C' are 8, 16 & 16 respectively in 1 litre
container, is Given : A(g) + 3 B(g)  C (g) ; KC = 109 M–3
(A) (8/27) × 10–3 M (B) (2/27) × 10–3 M (C) 2 × 103 M (D) 2× 10–3 M

Q.36 Select the ion exchange reaction, which proceeds to forward direction in aqueous medium :
(A) 2AgCl + CaF2 Aqueous
  2AgF + CaCl2
Aqueous
(B) BaSO4+2NaOH    Ba(OH)2 + Na2SO4
(C) Pb (NO3) 2 + 2CH 3COONa Aqueous
  Pb(OAc)2 + 2NaNO3
(D) Na2CrO4+ BaCl2 Aqueous
 BaCrO4+ 2NaCl

XI_NSEC PAGE # 6
 O O
PhMgBr CH3MgBr
Q.37 
H/ H
2O
  Product
(1eq.) (1eq.)
O
The product formed in the reaction is :
OH OH O O
|| ||
(A) Me Ph (B) Me — C — C — Ph

O
OH O O
| || ||
(C) Me  C  COOH (D) Ph — C — C — O — Me
|
Ph
Q.38 The percentage of acetic acid molecules are unionised in 5 × 10–8M-CH3COOH solution at 25°C?
Ka of CH3COOH = 1.6 × 10–5.(Take 4.25  2.06 ) [ multiply your answer with 1000]
(A) 0.2 (B) 0.4 (C) 0.8 (D) 0.5

Q.39 Which of the following combination of reagents does not undergo redox reaction in aqueous medium?
(A) SnCl2 +HgCl2 (B) CuSO4 +KCN (C) Pb(CH3COO)2 + KI (D) Ag2O + SO2

Q.40 Which of the following is the correct order of decarboxylation of following carboxylic acids using soda
lime?

(A) > > >

(B) > > >

(C) > > >

(D) > > >

Q.41 N2 and H2 are taken in 1 : 3 molar ratio in a closed vessel to attain the following equilibrium
P
N2(g) + 3H2(g) 2NH3(g) . Find kp for reaction at total pressure of 2p if PN2 at equilibrium is
3

1 4 4 P2
(A) 3 P 2 (B) 3 P 2 (C) 3 (D) none

XI_NSEC PAGE # 7
Q.42 Sodium salt solution + AgNO3 soln.  Coloured precipitate.
If coloured precipitate is soluble in both dil. HNO3 and excess conc. NH3 solution then which of the
following anion is present in the salt solution ?
(A) S2–(aq.) (B) I–(aq.) (C) PO43– (aq.) (D) Br–(aq.)

Mg / Ether 
Q.43 Br   D/D 2O
 Major product
Br
Major product is.........

(A) D (B) OD (C) OD (D) D

D OD D OD

Q.44 The solubility of C6H5 NH3+Cl¯ would be highest, among the following solvents, in :
(A) Acidic buffer of pH = 3 (B) basic buffer of pH = 10
(C) neutral buffer of pH = 7 (D) pure water

Q.45 Select the correct match:

Anions Separated by reagent
(A) CO32–, SO32– BaCl2
(B) CO32–, HCO3– CaCl2
(C) SO32–, SO42– (CH3COO)2Pb
(D) Cl–, Br– AgNO3
O
||
( i ) CH 3MgBr (1eq.) Ph COO H
Q.46 HC  CH     (
i ) CH 3MgBr (1eq.)
  (
i ) Sia 2 B H
     

( ii ) CH I3 ( ii ) EtI ( ii ) CH 3COOH
Final product is
H Et H 3C Et
C C + en C C + en
(A) (B)
H3 C O H H O H

CH3 CH3
H OH H H
+ en + en
(C) H OH (D) H OH
Et Et

Q.47 KSP of Al(OH)3 = 10–15 M. At what PH does 1 × 10–3 M Al3+ precipitate on the addition of buffer of
NH4Cl and NH4OH reaction KSPAl(OH) = 10–15.
3
(A) 10 (B) 5 (C) 4 (D) None of these

Q.48 Mg3N2 (s) + H2O R .T . P + Q 

Excess 'Q' gas does not form coloured complex with
(A) Ni2+ (aq.) (B) Zn2+ (aq.) (C) Cr3+ (aq) (D) Cu2+ (aq)

XI_NSEC PAGE # 8
 O
|| 
Q.49 Me  C  O  CH 2  CH 2  N H 3 NaOH
 Q
Q is:
O O
|| ||
(A) Me  C  O  CH 2  CH 2  NH 2 (B) Me  C  NH  CH 2  CH 2  OH

(C) (D) MeCOONa + HOCH2CH2NH2

Q.50 In the redox reaction

a CrCl3 + b H2O2 + c NaOH  2 Na2CrO4 + x NaCl + y H2O
Find the value of a, b, c in the given equation :
(A) a = 2, b = 3, c = 10 (B) a = 1, b = 2, c = 8
(C) a = 2, b = 2, c = 8 (D) a = 2, b = 3, c = 4

Q.51 Which of the following pair of cations can be separated by excess NaOH solution ?
(A) Fe3+ (aq.), Zn2+ (aq.) (B) Mn2+ (aq), Cd2+ (aq)
(C) Mg2+ (aq.), Hg2+ (aq) (D) Al3+ (aq.), Cr3+ (aq)

Q.52 Which is B in the sequence of reaction HBr

 A (
i ) Mg / ether
  B
40C
( ii ) CO 2 / H 3 O

(A) (B) (C) (D)

Q.53 2gm of an impure mixture of MgCO3 was dissolved in 50 ml of 0.8 M HCl. The excess of acid required
20 ml of 0.2M NaOH for complete neutralization. The percentage of MgCO3 in the sample will be
(A) 7.56 % (B) 37.8 % (C) 75.6 % (D) None of these

Q.54 (NH4)2Cr2O7 on heating liberates a gas. The same gas will be obtained by:
(A) Heating NH4NO2 (B) Heating NH4NO3
(C) Heating (NH4)2SO4 (D) Treating Mg3N2 with H2O

Q.55 Among the following compounds which liberate two equivalent of CO2  gas on oxidative ozonolysis
followed by heating ?

(A) (B) (C) (D)

Q.56 What mass of H2(g) is needed to reduce 192 gm of MoO3 to metal? [At. wt. of Mo = 96]
(A) 8 gm (B) 16 gm (C) 32 gm (D) None of these

XI_NSEC PAGE # 9
Q.57 If salt Q undergoes redox reaction with H2S in acidic medium then which of the following species can
not be possible product?
(A) MnO42– (aq.) (B) S (C) MnO2 (D) Both (A) and (C)

H O Mg HCHO
Q.58 + MeMgCl 3  A HBr
 B  C  
D
Et 2O H 3O

D is :

(A) (B) (C) (D)

Q.59 A2Ox is oxidised to AO3¯ by MnO4¯ in acidic medium. If 1.5 × 10–3 mole of A2Ox requires 40 ml of
0.03 M-KMnO4 solution in acidic medium. Which of the following statement(s) is/are correct?
(A) The value of "x" = 1
(B) The value of "x" = 3
(C) Empirical formula of oxide is AO3.
(D) Empirical formula of oxide is A2O.

2 
Cr2 O 7 / H
Q.60 Metal sulphate (A) Heat
 Oxide (B) + Gas (C) + Gas (D)   Green solution
Na
2O2
 E
Excess Yellow
solution

Compound A, B, C, D and E are respectively :

(A) ZnSO4, ZnO, SO3, SO2, Na2CrO4
(B) A12(SO4)3, A12O3, SO3, SO2, Na2CrO4
(C) CuSO4, CuO, SO3, SO2, Na2CrO4
(D) FeSO4, Fe2O3, SO3, SO2, Na2CrO4

Q.61 X2Sn + water  X(OH)n  + Y Z

(Gas) (Black ppt.)
Then (X) cation cannot be
(A) Fe3+ (B) Al3+ (C) Cr3+ (D) Mg2+

XI_NSEC PAGE # 10
 Paragaph for Q.62 & Q.63

Q.62 When H2S gas was passed into filtrate (P), a coloured precipitate was obtained, then cation present in
the filtrate is :
(A) Zna+(aq.) (B) Cr3+(aq.) (C)Al3+(aq.) (D) Pb 2+(aq.)

Q.63 Precipitate (Q) was treated with dil. HCl and coloured solution was obtained. On passing H2S gas into
this solution no precipitate was obtained but colour of the solution changes, then cation present in the
precipitate (Q) can be identified by :
(A) Na2S2O3 solution (B) KI + Starch
(C) K4[Fe(CN)6] (D) All

NH 4 Cl
Q.64 (A) Na
CrCl3 NH 2 O2
(B) Lead
(C)
4 OH H 2 O Acetate

In this reaction sequence, the compound (C) is:

(A) Na2CrO4 (B) Na2Cr2O7 (C) Cr(OH)3 (D) PbCrO4

Q.65 Which of the following is not paramagnetic ?

(A) S2– (B)N2– (C) O2– (D)NO

Q.66 A sample of water from a river was analysed for the presence of metal ions and the observation were
recorded as given below

The water sample is likely to contain

(A) Ba2+ (B) Cu2+ (C) Li+ (D) Mg2+
Q.67 The gaseous product obtained on reaction of BF3 with LiH is
(A) HF (B) H2 (C) B2H6 (D) F2
Q68. Which of the following elements will exhibit photoelectric effect with light of the longest wavelength ?
(A) K (B) Rb (C) Mg (D) Ca
Q.69 If the radius of the hydrogen atom is 53 pm, the radius of the He+ ion is close to
(A) 75 pm (B) 38 pm (C) 106 pm (D) 27 pm

XI_NSEC PAGE # 11
Q.70 In which of the following, all the bond lengths are not the same?
I. IF4+ II. BF4– III. SF4 IV. TeCl4
(A) I, II, IV (B) II, III, IV (C) I, III, IV (D) I, II, III

Q.71 Among the following, the reaction/s that can be classified as oxidation-reduction is/are
I. Cr2O72–(aq) + 2OH–(aq)  2CrO42– + H2O (1)
II. SiCl4(l) + 2Mg(s)  2MgCl2(l) + Si(s)
III. 6C12(1) + 12KOH(l)  2KC1O3 (s) + 10 KC1 + 6H2O (1)
IV. 2H2O2  2H2O (1) + O2 (g)
(A) I and IV (B) I, II and III (C) II, III and IV (D) IV only

Q.72 Among the following pairs, the one in which both compounds as pure liquids can show significant auto
ionization is
(A) H2O and H2S (B) BrF3 and ICl3 (C) PF5 and PCl5 (D) HF and HCl

Q.73 Which one of the following is not used as a monomer for the synthesis of a high molecular weight silicone
polymer ?
(A) MeSiCl3 (B)Me2SiCl2 (C)Me3SiCl (D)PbSiCl3

Q.74 Which of the following is a strong oxidising agent ?

(A) AlCl3 (B) TlCl3 (C) NF3 (D) PCl3

Q.75 An orbital among the following that has two radial nodes and two angular nodes is
(A) 3d (B) 4p (C) 4f (D)5d

Q.76 The C-O bond length is the shortest in

(A) [Cr(CO)6] (B) [Mo(CO)6] (C) [Mn(CO)6]+ (D) [V(CO)6]–

Q.77 There is mixture of Cu(II) chloride and Fe(Il) sulphate. The best way to separate the metal ions from this
mixture in qualitative analysis is:
(A) hydrogen sulphide in acidic medium, where only Cu(II) sulphide will be precipitated
(B) ammonium hydroxide buffer, where only Fe(II) hydroxide will be precipitated
(C) hydrogen sulphide in acidic medium, where only Fe(II) sulphide will be precipitated
(D) ammonium hydroxide buffer, where only Cu(II) hydroxide will be precipitated

Q.78 A colourless water soluble solid ‘X’ on heating gives equimolar quantities of Y and Z. Y gives dense
white fumes HCl and Z does so with NH3. Y gives brown precipitate with Nessler’s reagent and Z gives
white precipitate with nitrates of Ag+, Pb2+ and Hg+ ‘X’ is-
(A) NH4Cl (B) NH4NO3 (C) NH4NO2 (D) FeSO4

XI_NSEC PAGE # 12
Q.79

Identify salt (A) satisfying above chemical property:

(A)Cu(NO3)2 (B)NaNO3 (C) AgNO3 (D) Pb(NO3)2

Q.80 A coloured solution known to contain two metal ions, was treated with excess cold sodium hydroxide
solution. When filtered a whitish solid, slowly changing to brown, was retained on the filter paper and a
colourless solution collected as the filtrate. Dropwise addition of hydrochloric acid to the filtrate produced
a white ppt. which dissolved in excess acid. Treatment of the residue on filter paper with a solution of
strong oxidiser produced a reddish-violet solution. Indicate any pairs of ions:
(A) Zn2+ and Mn2+ ions (B) Ni2+ and Fe3+ ions
(C) CO2+ and Mg2+ ions (D) Fe2+ and Zn2+ ions

XI_NSEC PAGE # 13