Analytical Chemistry MCQs: TYBSC SEM III

1] Gravimetric Analysis
1. If the solubility of calcium fluoride in water is S moles per litre, its solubil is
given by
(a) 2S (b) 2S2
(b) 4S3 (d) 4S2

2. Correct representation of solubility product of Ca3(PO4)2 is

a) [Ca2+][PO3-4]2- (b) [Ca2+][PO3-]
(c) [Ca] [PO4] (d) none of these

3. Dimethyl glyoxime is a reagent specific for the metal ion.

(a) AI (b) Ni
(b) Fe (d) Cu

4. The solubility product expression for Hg2Cl2 is

(a) [Hg2+] [Cl-] (b) [Hg2+2][Cl-]2-
c. [Hg2+2][2Cl-] (d) [Hg+1 [CI]

5. A solution is called saturated if

(a) ionic product < solubility product.
(b) ionic product > solubility product
(c) ionic product = solubility product.
(d) none of these

6. Solubility of alcohol in water is due to

(a) ionic bonding
(b) covalent bonding
(c) Metallic bonding
(d) Hydrogen bonding

7. Precipitation takes place when the product of concentration of ions

(a) Exceeds their solubility product
(b) Is less than their solubility product
(c) Equal to their solubility product
(d) None of these

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 Analytical Chemistry MCQs: TYBSC SEM III
8. The solubility product Ksp of sparingly soluble Ag2CrO4 is 4*10-12. The molar
solubility of the salt is
(a) 1.0*10-4 moles/lit
(b) 2.0*10-4 moles/lit
(c) 1.0*10-5 moles/lit
(d) 1.2*10-12 moles/lit

9. Solubility product of AgCl is 1.44*10-4 moles/lit at 373K. The solubility of the

AgCl is boiling of water will be….
(a) 0.72*10-4 moles/lit
(b) 0.72*10-2 moles/lit
(c) 1.20*10-2 moles/lit
(d)1.20*10-4 moles/lit

10. Precipitation takes place when the ionic product…

(a) Is zero
(b) Exceeds the solubilty product
(c) Equal to solubilty product
(d) Is less than the solubility product

11. The electomotive force is expressed In the unit of …..

(a) Ohm
(b) Volt
(c) Ampere
(d) Colulomb

12. If the cell can provide electrical energy to an external system, it is called as
(a) Galvanic cell
(b) Electrolytic cell
(c) Concentration cell
(d) Chemical cell

13. The current per unit area of electrode surface is known as….
(a) Current efficiency
(b) Current yield
(c) Current density
(d) None of these

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 Analytical Chemistry MCQs: TYBSC SEM III
14. The applied voltage is just sufficient to overcome to back emf due to polarization
is known as….
(a) Back emf
(b) Overvoltage
(c) Applied potential
(d) Decomposition potential

15. The copper is determined in strongly acid solution by electronegativity at a

potential not exceeding by….
(a) One volt
(b) Two volt
(c) Three volt
(d) Four volt

16. When the ionic concentration is reduced to one-ten-thousandth of its initial value,
for divalent ion, the potential is altered by…
(a) 0.236 volts
(b) 0.118 volts
(c) 0.079 volts
(d) 0.100 volts

17. The quantitative separation of metals is possible only when the applied potential
should be greater than….
(a) Cathode overvoltage
(b) Back emf
(c) Decomposition potential
(d) System potential

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 Analytical Chemistry MCQs: TYBSC SEM III
2] Thermal Methods of Analysis
1. Which is not method of thermogravimatric analysis?
(a) TGA
(b) DTA
(c) DSC
(d) DPP

2. TGA is used to find….

(a) Weight loss
(b) Mass
(c) Volume
(d) Both (a) and (b)

3. DTA is used to find….

(a) Temperature difference
(b) Mass
(c) Volume
(d) None of these

4. Thermometric titrations are carried out under ……..conditions.

(a) Adiabatic
(b) Isothermal
(c) Isobaric
(d) Vaccum

5. Temperature difference between sample and ….in DTA is measured using…

(a) Thermister
(b) Thermocouple
(c) Voltmeter
(d) Ameter

6. Which of the following when heated gives CO2 at 14000C

(a) CaCO3
(b) BaCO3
(c) MgCO3
(d) NaNO3

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 Analytical Chemistry MCQs: TYBSC SEM III
7. TGA graph is
(a) Mass Versus Temperature
(b) Temperature Versus Mass
(c) Volume Versus Temperature
(d) Delta T Versus Temperature

8. DTA graph is…

(a) Temp Versus Delta T
(b) Mass Versus Temperature
(c) Delta T Versus Temperature
(d) None of these

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 Analytical Chemistry MCQs: TYBSC SEM III
3] Spectrophotometry
1. What is the wavelength range for ultravolient spectrum?
(a) 570-590 nm
(b) 620-760 nm
(c) 400 nm
(d) 450-500 nm

2. Colorimetry is concerned with the region of the spectrum

(a) Ultravoilet
(b) Visible
(c) Infrared
(d) X-rays

3. If wavelegth is 0.5 micrometer, how much the frequency and wavelength of the
radiation……
(a) 1016 cps and 107 cm-1
(b) 107 cps and 1016 cm-1
(c) 6*1016 cps and 2*107 cm-1
(d) 2*107 cps and 6*1016 cm-1

4. Beer’s law gives the relationship between

(a) Absorbance and path length
(b) Absorbance and transmittance
(c) Absorbance and extinction coefficient
(d) Absorbance and concentration

5. Which radiation source is used for UV spectrophotometer?

(a) Tungsten lamp
(b) Hydrogen lamp
(c) Carbon arc
(d) None of these

6. In order to prepare an interference filter, which material is used to give the thin
layer on a plate of glass?
(a) ZnF2
(b) CuF2
(c) BF3

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 Analytical Chemistry MCQs: TYBSC SEM III
(d) MgF2

7. The dynodes are the used in the detector…

(a) Photovoltaic cell
(b) Phototubes
(c) Photomultipliertubes
(d) None of these

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 Analytical Chemistry MCQs: TYBSC SEM III
4] Polorography
1. Concentration is directlyu proportional to
(a) Redisual current
(b) Migration current
(c) Difusion current
(d) Limiting current

2. In polorogram half wave potential is independent of

(a) Current
(b) Concentration
(c) Voltage
(d) Pressure

3. In polorogram qualitative analysis is identify by

(a) Diffusion current
(b) Limiting current
(c) Half wave potential
(d) Residual current

4. In polorometer quantitative analysis is indentify

(a) Diffusion current
(b) Limiting current
(c) Half wave potential
(d) Residual current

5. Mecury pool is
(a) Indicator electrode
(b) Reference electrode
(c) Cathodic electrode
(d) All of the above

6. Reference electrode is
(a) Non polarize
(b) Constant
(c) Both
(d) None of these

7. The curve formed by plotting graph between applied voltage versus current is
(a) Polarogram
(b) Half wave potential
(c) Both
(d) none of these

8. DME (dropping mercury electrode) in polarogram is act as

(a) Anode
(b) Cathode
(c) Renewable eletrode
(d) Both (b) and (c)

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 Analytical Chemistry MCQs: TYBSC SEM III
9. Each drop of DME (Dropping Mercury Electrode) has life time of
(a) 3 seconds
(b) 2-5 seconds
(c) 3-5 seconds
(d) 1-2 seconds

10. Current flows in the absence of depolarisor (supporting electrolyte)

(a) Difusion current
(b) Residual current
(c) Limiting current
(d) Migration current

11. Polorography is used to

(a) Electromagnetic technique
(b) Electrolytic technique
(c) Electronic technique
(d) Magnetic technique

12. DME is
(a) Indicator electrode
(b) Refence electrode
(c) Non-polarize electode
(d) None of these

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 Analytical Chemistry MCQs: TYBSC SEM III
5] Atomic Absorption Spectroscopy
1. In AAS procedure, the species that absorb light is…
(a) Ground state atoms
(b) Excited atoms
(c) Boh ground and excited state atoms
(d) None of these

2. The main function of flame unit is….

(a) To form most of solution
(b) To form ground state atoms
(c) To form excited atoms
(d) Desolvation

3. Hollow cathode lamp produces…

(a) Broad spectrum
(b) Decrete spectrum
(c) Atomic spectrum
(d) None of these

4. Light signal is converted into an electrical signal by a device called..

(a) Diffraction grating
(b) Electromic intergrator
(c) Hollow cathode lamp
(d) Photomultiplier tube

5. Difraction grating is used for

(a) Increase of intensity of light
(b) Decrease of intensity of light
(c) Isolation of different wavelengths
(d) None of these

6. Premix type of burner produces

(a) Turbulent flame
(b) Laminar flame
(c) Reducing flame
(d) Violent flame

7. Releasing agent is used to solvethe problem of ….

(a) Ionisation
(b) Stable background formation
(c) Spectral interference
(d) Background absorption

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 Analytical Chemistry MCQs: TYBSC SEM III
6] Flame Emission Spectroscopy
1. Flame photometry deals with the measurement of
(a) Absorption
(b) Emission
(c) Absorbance
(d) Transmittance

2. Flame is used in FES for

(a) Excitation of atoms
(b) Ionisation of atoms
(c) Formations of atoms
(d) Vaporisations of solvent

3. The loss of light due to radiation is saved by using…

(a) Silits
(b) Filters
(c) Reflector
(d) Detector

4. Slits are used to..

(a) Save light
(b) Block certain lines
(c) Direct the light
(d) To incraese of light

5. Photomultiplier tube is used as a

(a) Detector
(b) Read out device
(c) Atomizer
(d) Wavelegth isolator

6. Which one of the following is thebest wavelength isolator?

(a) Absorption filter
(b) Prism
(c) Diffraction grafting
(d) None of these

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