Clase 20220526 FQ

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Transformations fisicas de sustain

ciaspuras
fast → forma de la materia uniform in
composition quimica y
estado

tisico
solid ,
liquid , gas
↓ equilibria

/
vaioslipos fluid
:L
agua
p

solid ↳ punto critics ☒ = 0


••
Jvm
gas = 0

.
avni

punto tiple
tinea de equilibria : Dtots = 0 tot : total

BtrsG =
0 tis : transition

estabilidaddefases :

G =
GCT , p ,
n )

ᵈG=
(¥)p,nᵈT (Yp ) ,nᵈP (En ) ,pᵈ
+ + "
,

T
-
-

-
S V

µ potential quimioo (¥n )


:
µ
=

,
,p

sustancias
paras
:

µ
=

Gm Energia de Gibbs molar a


Ty
p definidas
di fuentes fasesde A
ACN →
Acp) X
, P :

→ ntaneo
<

{
< ◦ → →
µ, µ,
Atrscm espontaneo MX
Mp >
0 → no →
>

↓ =
0 →
equilibria →
up
=

Ma
Btrs µ Mp Ma
= -

lafase ma's istable a


Typ definidas tiene menor
potential
qvimiw

§

f-

MOI

dp
C§±,)p C§pm_)
Gmctip ) =
IT +

,
MCT, p )
= -

Sm DT +
Vm dp
Dependenceadd potential quimiw con T
y p


temperature
= -

Sm dt

6¥)p
÷!
=
. sm > ◦

ds
¥ dog ¥
=
= =

dkreciente la
is con
temperature

1T¥ )p =

CF ) -1,1¥.jp 9¥
-
=
=
-

,
,
también céncava hacia
<
abajo
0 →

t
n

"
,

said
i H
i :

i i gas liquid
This Teb
T

(IF)p =
Sm → sélido liquid
-
-

gas
-

small ) < Smlliq ) <


Smcgas )

presién
µ
=
Vmdp (Tdefinida)
P= Fm
Vm
(Ipt ) sordid liquid gas
-
= -

Vmlso't )
,
<
Vmcliq ) <
Vmcgas )


glhlalmente
""
%
• ""
" " " °
" " " °

" liquid liquid


gas gas

P2 >
pi

Ttr -11-2 T
Transition de fase : en el equilibria
A- (a) =
Alf )
Btrs Gm =
0

Btrsu 0
=

µ Smdt +
Vmdp
Mp
-
= =

Ma 0
-

Smp dtt
Vmp dp
-

C -

Sma DT +
Vma dp ) =
0

-
(
sp
-
sa) DT + ( Vp
-

Va ) dp =
0

( Up Va ) dp ( sa ) DT
sp
=
-
-

¥ Dtrssm
duration
%¥÷ de
Clapeyron
=


twain general aplicaparawalquier
,

transition defase
Transition liquid -

vapor

Alliq) 7- Acgas )

dp_ =
Dtrsm =
bvapSm_ =
Dvapltm
DT Dtrsvm Dvapvm Tbvapvm

Bvapsm
tvqptm
=

bvapvm =
Vmcgas) -

Vmlliq ) ≈
Vmcgas )
Vmcgass >>
Vmcliq )

¥ DFFI-g.si
=

gas ideal →
Vm gas ] =
RI
p

da
AaP¥T
=

dip
f off

=

tfbvaptm 1,2
DT

po To

si
Bvapltm es constante
ewaoion
tvapytm ( ¥ %)
In de Clausius
ftp.
-
- -

Clapeyron
ebullition
royal
de referenda
To , po :
punt , punto de

1bar

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