TM ISOMERISM DPP - 2

[MEDICAL DIVISION]

1. Which is optically active molecule :-

(A) C6H5 C OH (B) CH3 CH C2H5 (C) C6H5 CH OH (D) C6H5 CH CH3
O OH H CH3

2. The following two compounds are

and

(A) Enantiomers (B) Diastereomers (C) Identical (D) Epimers

3. The pair of structures represents :-

Me Me
H Me H H

H H H H
Cl CH2Cl

(A) Enantiomers (B) Position isomers (C) Conformers (D) None

4. Increasing order of stability among the three main conformation (i.e. eclipse, anti, gauche) of
ethylene glycol is :
(A) Eclipse, gauche, anti (B) Gauche, eclipse, anti
(C) Eclipse, anti, gauche (D) Anti, gauche, eclipse

5. Which one of the following is a meso–compound.

(A) (B) (C) (D)

6. Which of the following compounds can exist both as a cis pair of enantiomers and a trans pair
of eantiomers -
(A) CH3CHClCH = CH2 (B) CH3CHClCH = CHCH3
(C) CH2 = CH – CHOHCH = CH2 (D) CH2 = CH – CHClCH = C(CH3)2

7. How many isomers of C5H11OH will be primary alcohols :–

(A) 2 (B) 3 (C) 4 (D) 6
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8. Number of structural isomers of C6H14 is -
(A) 3 (B) 4 (C) 5 (D) 6

9. Which of the following compounds is a meso compound -

H Cl Br Cl Cl Cl H Cl

(A) (B) (C) (D)

Cl H H H H H Br H

10. The most stable conformation of 2, 3-dimethylbutane is -

CH3 CH3 CH3 H3C H

CH3 CH3 H H3C CH3
H
(A) (B) (C) CH3 (D) H3C CH3
CH3 H CH3 H H
H CH3
CH3 CH3 H

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