ey The Rate Law: The Method of Initial Rate Question 1: Determine the rate law and calculate the rate constant for the reaction based on the following experimental data: F; (g) + 2ClO, (g) ——> 2FCIO,(g) Rate= k[F,}"[Cl0,]” oo pan #9 $a! tn sa Se 200 Pe K(020) Peat Zax ao aa? Beate T= hensz Ke 129 301" 3.0.20 0.010 24% 107 os TD & (2a >ne/ Boo.) & at? @ Sey. ‘ Rae gamete KS Don rate = KF eM] Rote! s L215" i Lopy (0.010 = ae a 20) o (b) For reds: L2K10°. 2K (a0} y fansde R(a2ed) 7 ELA Ey [DS Question 2; Determine the rate law and calculate the rate constant for the reaction based on the following experimental data: 5,05 (aq) + 3 (agp—>. 280 (aq) + Iz (aq) Rate =k [S,0,"]"[]” Exp | initia | 2x i gue ?lis.0f]| 0 | |..# | 208) 0 [Rate (Mis) | ny. Zax 0 4 land (207) 1 1% 1 | 0.08 | 0.034) 2.2x 104 netez: sen iet 4 2 [omy C207” / 2 0.08 | 0.017) L1x104 Ze (2? #7 427 = age 3 | 0.16 | 0.017) 22x 104 © pry pete KEES EI fexx, #3 ¢ 2s = fale 34 22015 Ke4D Ho ale at peed ID 2 2 (2727 77% 2.2% ite hla92(202) 2.2 x57 2 (0.90274) m 0.081 (M" Ke oe QO roc axn BLEThe Rate Law: The Method of Initial Rate Question 3: For the reaction: BrO; (aq) + 5 Br (aq) + 6H” (ag) 2 3Br,(l) + 3 H,O) Determine: rxn. orders for reactants; overall rxn. order; rate constant k. ‘The Results from Four Experiments to Study the Reaction BrOs"(ag) + 5Br7 (ag) + GH*(aq) > 3Br(!) + 34,01) Rate = BrOs}*[Br]}"[H*P Sa en at ea Contention Concrtaton Concent "hil aoe eee ard nae Experiment (molt) (mot) fmol) (mmol -s) . 1 0.10 0.10 010 80x 107 ee 0.20 0.10 010 1.6 x 107} 3 0.20 0.20 010 3.2.x 1073} 4 0.10 0.10 0.20 32 x 107] 2 Bom #2 €/ Bun wo % # 32. n0% knee)’ aes 0 Ab IGF = Ble: 2 (0s0y (31 20 = (2) => mel 32 5 15? 7) Salar Pon. Pete ber S HE THT BOK = se farsfiiasy? (oi0 = ea Orcler=/4 V2 = * | 4 4NO,(g) + O,(g) (a) Using the integrated rate law, verify that the rate law is 1* order in [N,O,}; (b) Calculate the value of the rate constant k. slpe sei ae tac wana 0 5f4.920% 18° 0 0.1000 reel we 8.940 x ae 50 0.0707 3.689 200 216.930 XS 7 4382 200 216.930 «o> si aS 5075 400 co 100 f 0.0500 “io 200 300400 Time(s) 6920x157 200 0.0250 wf 0025 | ony LnfWoc) ve Bove Ep oGpe go 400 0,00625 rs is contort a gph 6 @ Straight Gone G Ben. pate =k LW.05))' Sines Gofnlss] vo. tome te 0 leigh, rote Bours IL Orcler sm [Nr 95], fine shoe = -k = -E.930xX)F= Den. Pele = 6.730. )33L1205]" Question 5: Using data from question # 4: 2N,05(@) > 4NO, (g) + 0; (@) (©) Caleulate [N,O,] at 150 seconds after the start of the reaction. For /3t Order xn: [A]. [A], € (6950x1715) QQ b= 150 sec; in a, ee: é ok op Ke E920! LOB9S 8 =IE0 =(0 ca a ite aH ” 905636 1700 (M0 c]e50 * 2 ===Half Life of 1" Order Reaction Question 6: A certain 1* order reaction has a half-life of 20.0 minutes. (t %) a) Calculate the rate constant for this reaction; b) How much time is required for this reaction to be 75% complete. (a) ty- 2623 200. 0673 w= AOBIF cin] & K = = ef\ (8) OB [erdy IS% Compete > 28% () oe te ° tonhel reatenlt concen Traber, a 7 @ 622 E% (asx & LA) Pernees 2514 | 2- ¢ Le 2x 20.0 b2 Y0.0 wer Question 7: A first order reaction is 35% complete at the end of 55 minutes, What is the value of k? @ E288 min E548 HE feactent (B) rermaiirs. oe, Taje = 6S LAI, ¢ Ch]e - 065 joo [A]o But (Ale, EX° shen, €n “le, Ale) »& CPle lade wp -/04308) 2 -K(SS) F 124Question 8: For a reaction aA > Products, [A], = 5.0 M, and the first two half- lives are 25 and 50 minutes, respectively. ; : im {é ae 25 rn Eh (e),2 80" a) Write the rate law for this reaction. b) Calculate k, c) Calculate [A] at /=525 minutes. (® srnce the Second hulf-Epe 's ae he pot fal Cpe, this i. gd order cancthom Peale = K [ay* () fore ozone reaction: se L B= th Ten eee) (2nke ” - ko 20x18" [07 ‘mio! —= és) f okt + 2 [Alle 1, a (29x1F S25) + ae 2424 0.20 fae 5 Le t4 Gi: 02 0.2509 Pale nsQuestion 9: Consider the reaction aA > Products. [A]p = 1.0 Mand k= 1.0 x 10%, Calculate [A] after 30.0 seconds have passed, assuming the reaction is: (a) zer0 order; (b) first order; (¢) second order (0) 20 Dele Bx: [aly =-kt + Calo [Ale= -G.0x162)-(329 + (40 Che = 080410 CA = C27 C2) Jot ardee 2° [AR [Aly 7 (al; cs (10). 097 B49 Pe CAI = 029% pe ktet (6) Bf Orde Bi: a : (lo HL = (0x69 (30.0) + ds [Ale Ls 30470 (le = 73 (¢ ) da 246Question 10: For the reaction: A + 2B > 2C, the following data were collected: [Alo Blo Run. Rate a! 020M 0.10 0.300 mol/L min man a? 050M 030M —0,360molLmin = Baye K CA]. FO) 3 080M 030M 1.44 mol/L min a) Determine the rate law expression for the reaction. b) What is the expected reaction rate if [AJp = 0.50 M, and [B]p = 0.80 M? ©) Assuming the initial rate is given in terms of production of C, what is the initial rate of change in concentration A in the first experiment? 4) Assuming the initial rate is given in terms of production of C, what is the initial rate of change in concentration B in the first experiment? ( amas, 1M KAOONOAT 42 16" Be #2 FH ag9 K (082) (ay? me#3 ao Pink — a3bo = 932) (039)” 12.2825) (3)" Bxn ts 0.300 (0.20) {e.12)” Ee Gylo0ven =” 9718) wo hihs 2 O% Be 272.8% -2 See eueuey eo (9 Etzcling ko (HD e301) = K (22000) mo “(or 0.390 19 = x (a00to00') K 2 2378 re vn /@.0100") — fate for (Ah-2500 $ [6 ]o=2. 80" 2302 o- pate - (0 345) (0.2 8)? ele OO as Are ices, (0-0)~