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Material Safety Data Sheet

WAXTREAT 16707 Page 1

Substance key: 000000811275 Revision Date: 13.02.2020


Version : 1 - 2 / RI Date of printing : 19.02.2020

1. PRODUCT AND COMPANY IDENTIFICATION

Trade name
WAXTREAT 16707
Material number: 315492
Substance name: Polymer mixture in aromatic solvent
Recommended use:
Industry sector : Oilfield
Type of use : Wax inhibitor
Supplier name/address/telephone no.:
PT Clariant Indonesia

Gatot Subroto Km. 4, Jl. Kalisabi No.1, Kec. Cibodas


Tangerang, Indonesia 15138, Indonesia
Telephone : +62 21 5538590
Information about the substance/preparation
Product Safety : Telephone: +61 3 8562 3300
Facsimile: +61 3 8562 3333
e-mail: SDS.SEAP@clariant.com
Emergency telephone number: 1800 643 555

2. HAZARDS IDENTIFICATION

GHS Classification
Flammable liquids : Category 3

Skin corrosion/irritation : Category 2

Serious eye damage/eye : Category 2A


irritation

Carcinogenicity : Category 2

Specific target organ toxicity - : Category 3 (Respiratory system, Central nervous system)
single exposure

Specific target organ toxicity - : Category 2 (Kidney, Liver, Central nervous system)
repeated exposure

Long-term (chronic) aquatic : Category 2


hazard

GHS label elements


Hazard pictograms :

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Material Safety Data Sheet

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Substance key: 000000811275 Revision Date: 13.02.2020


Version : 1 - 2 / RI Date of printing : 19.02.2020

Signal word : Warning

Hazard statements : H226 Flammable liquid and vapour.


H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H373 May cause damage to organs (Kidney, Liver, Central
nervous system) through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.

Precautionary statements :
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P210 Keep away from heat/ sparks/ open flames/ hot surfaces.
No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting
equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection.
Response:
P303 + P361 + P353 IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water/
shower.
P304 + P340 + P312 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Call a POISON CENTER/
doctor if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P332 + P313 If skin irritation occurs: Get medical advice/
attention.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
P362 + P364 Take off contaminated clothing and wash it before
reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or
alcohol-resistant foam to extinguish.
P391 Collect spillage.
Storage:

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Substance key: 000000811275 Revision Date: 13.02.2020


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P403 + P233 Store in a well-ventilated place. Keep container


tightly closed.
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

Other hazards which do not result in classification


No additional hazards are known except those derived from the labelling.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Components
Chemical name CAS-No. Concentration (% w/w)
Hydrocarbons, C10, aromatics, >1% 64742-94-5 >= 30 -< 60
naphthalene
Xylene 1330-20-7 >= 20 -< 30
Naphthalene (Amount coming from 91-20-3 >= 5 -<= 10
“Hydrocarbons, C10, aromatics, > 1%
naphthalene”)

4. FIRST AID MEASURES

General advice : Remove/ Take off immediately all contaminated clothing.


Get medical advice/ attention if you feel unwell.

If inhaled : If inhaled, remove to fresh air.


Get medical advice/ attention.

In case of skin contact : In case of contact, immediately flush skin with soap and plenty
of water.

In case of eye contact : In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.

If swallowed : If swallowed do not induce vomiting,seek medical advice and


show safety datasheet or label

Most important symptoms : No symptoms known currently.


and effects, both acute and No hazards known at this time.
delayed

Notes to physician : Treat symptomatically.

5. FIREFIGHTING MEASURES

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Suitable extinguishing media : Water spray jet


Alcohol-resistant foam
Dry powder
Carbon dioxide (CO2)

Unsuitable extinguishing : High volume water jet


media

Specific hazards during : In case of fires, hazardous combustion gases are formed:
firefighting Carbon monoxide (CO)
Carbon dioxide (CO2)

Specific extinguishing : Wear suitable protective equipment.


methods

Special protective equipment : Self-contained breathing apparatus


for firefighters

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Wear suitable protective equipment.


protective equipment and Ensure adequate ventilation.
emergency procedures

Environmental precautions : The product should not be allowed to enter drains, water
courses or the soil.

Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel,
containment and cleaning up acid binder, universal binder, sawdust).
Treat recovered material as described in the section "Disposal
considerations".

7. HANDLING AND STORAGE

Advice on protection against : Observe the general rules of industrial fire protection
fire and explosion

Advice on safe handling : When used and handled appropriately no special measures
are needed

Further information on : Keep containers tightly closed in a cool, well-ventilated place.


storage conditions Handle and open container with care.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters


Components CAS-No. Value type Control Basis
(Form of parameters /

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Substance key: 000000811275 Revision Date: 13.02.2020


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exposure) Permissible
concentration
Naphthalene (Amount coming 91-20-3 NAB 10 ppm ID OEL
from “Hydrocarbons, C10,
aromatics, > 1% naphthalene”)
Further information: Adopted in Year 1996, Upper respiratory tract
irritation, Eye irritation, Eye irritation, Hematologic effects
PSD 15 ppm ID OEL
Further information: Adopted in Year 1996, Upper respiratory tract
irritation, Eye irritation, Eye irritation, Hematologic effects
TWA 10 ppm ACGIH
Biological occupational exposure limits
Components CAS-No. Control Biological Samplin Permissible Basis
parameters specimen g time concentratio
n
Xylene 1330-20-7 Methylhippu Urine End of 1.5 g/g ACGIH
ric acids shift (As creatinine BEI
soon as
possible
after
exposure
ceases)
Personal protective equipment
Respiratory protection : Use respiratory protection in case of insufficient exhaust
ventilation or prolonged exposure
Full mask, filter A
Full mask to standard DIN EN 136
Filter class 2
The use of filter apparatus presupposes that the environment
atmosphere contains at least 17% oxygen by volume, and
does not exceed the maximum gas concentration, usually
0.5% by volume. Relevant guidelines to be considered
include EN 136/141/143/371/372 as well as other national
regulations.
Applicable national Regulations must be observed. Take note
of the limitations regarding wear-time, in conjunction with the
Regulations for the use of Respiratory Protective Equipment.

Hand protection
Break through time : 480 min
Glove thickness : 0,7 mm
Remarks : Long-term exposure Impervious butyl rubber gloves

Break through time : 30 min


Glove thickness : 0,4 mm
For short-term exposure (splash protection): Nitrile rubber
gloves.

These types of protective gloves are offered by various


manufacturers. Please note the manufacturers´ detailed
statements, especially about the minimum thickness and the
minimum breakthrough time. Consider also the particular

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working conditions under which the gloves are being used.

Eye protection : Depending on the risk, wear sufficient eye protection (safety
glasses with side protection or goggles, and if necessary,
face shield.)

Protective measures : Observe the usual precautions for handling chemicals.

Hygiene measures : Wash hands before breaks and at the end of workday.
Use protective skin cream before handling the product.
Take off immediately all contaminated clothing and wash it
before reuse.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Colour : yellow to amber

Odour : aromatic

Odour Threshold : not tested.

pH : 7,43 (25 °C)


Concentration: 1 %

Melting point : not determined

Boiling point : 137 °C


Method: DIN 51751
Data relate to solvent

Flash point : 52 °C

Method: closed cup

Evaporation rate : not tested.

Self-ignition : Not applicable

Burning number : Not applicable

Upper explosion limit / upper : not tested.


flammability limit

Lower explosion limit / Lower : not tested.


flammability limit

Vapour pressure : ca. 8 hPa (20 °C)


Information refers to the main component.

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Relative vapour density : not tested.

Density : 0,880 g/cm3 (25 °C)


Method: DIN 51757

Bulk density : Not applicable

Solubility(ies)
Water solubility : insoluble

Solubility in other solvents : not tested.


Solvent: fat

Partition coefficient: n- : not determined


octanol/water

Auto-ignition temperature : not tested.

Decomposition temperature : not tested.

Viscosity
Viscosity, dynamic : 370 mPa.s ( 40 °C)

Viscosity, kinematic : ca. 420 mm2/s ( 40 °C)

Explosive properties : no data available

Oxidizing properties : Not applicable

Minimum ignition energy : not tested.

Particle size : Not applicable

10. STABILITY AND REACTIVITY

Reactivity : See section 10.3. "Possibility of hazardous reactions"

Chemical stability : Stable under normal conditions.

Possibility of hazardous : No dangerous reaction known under conditions of normal use.


reactions

Conditions to avoid : None known.

Incompatible materials : not known

Hazardous decomposition : When handled and stored appropriately, no dangerous


products decomposition products are known

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11. TOXICOLOGICAL INFORMATION

Acute toxicity
Product:
Acute oral toxicity : Remarks: no data available

Acute inhalation toxicity : Acute toxicity estimate: > 20 mg/l


Exposure time: 4 h
Test atmosphere: vapour
Method: Calculation method

Acute dermal toxicity : Acute toxicity estimate: > 2.000 mg/kg


Method: Calculation method

Components:
Xylene:
Acute oral toxicity : LD50 (Rat, male and female): 3523 - > 4000 mg/kg
Method: EC Directive 92/69/EEC B.1 Acute Toxicity (Oral)
GLP: no

Assessment: The substance or mixture has no acute oral


toxicity

Acute inhalation toxicity : LC50 (Rat, male): 27,571 mg/l


Exposure time: 4 h
Test atmosphere: vapour
Method: Directive 67/548/EEC, Annex V, B.2.
GLP: No information available.
Assessment: The component/mixture is moderately toxic after
short term inhalation.

Acute dermal toxicity : Other (Rabbit, male): > 4.200 mg/kg


Method: Other
GLP: No information available.

Assessment: The component/mixture is moderately toxic after


single contact with skin.

Naphthalene (Amount coming from “Hydrocarbons, C10, aromatics, > 1% naphthalene”):


Acute oral toxicity : LD50 (Rat, male and female): 533 - 710 mg/kg
Method: OECD Test Guideline 401
GLP: No information available.

Acute inhalation toxicity : LC50 (Rat, male and female): > 0,4 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: OECD Test Guideline 403
GLP: yes
Assessment: The substance or mixture has no acute
inhalation toxicity

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Acute dermal toxicity : LD50 (Rat, male and female): > 16.000 mg/kg
Method: OECD Test Guideline 402
GLP: no

Skin corrosion/irritation
Product:
Remarks : no data available

Components:
Hydrocarbons, C10, aromatics, >1% naphthalene :
Result : Repeated exposure may cause skin dryness or cracking.

Xylene:
Species : Rabbit
Method : Other
Result : Irritating to skin.
GLP : No information available.

Naphthalene (Amount coming from “Hydrocarbons, C10, aromatics, > 1% naphthalene”):


Species : Rabbit
Exposure time : 24 h
Method : 16CFR1500.41
Result : No skin irritation
GLP : no

Serious eye damage/eye irritation


Product:
Remarks : no data available

Components:
Xylene:
Species : rabbit eye
Result : Irritating to eyes.
Method : Other
GLP : No information available.

Naphthalene (Amount coming from “Hydrocarbons, C10, aromatics, > 1% naphthalene”):


Species : Guinea pig
Result : No eye irritation
Exposure time : 24 h
Method : 16CFR1500.42
GLP : no

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Respiratory or skin sensitisation


Product:
Remarks : no data available

Components:
Xylene:
Test Type : Local lymph node assay (LLNA)
Exposure routes : Skin contact
Species : Mouse
Method : OECD Test Guideline 429
Result : Not a skin sensitizer.
GLP : No information available.

Naphthalene (Amount coming from “Hydrocarbons, C10, aromatics, > 1% naphthalene”):


Test Type : Maximisation Test
Exposure routes : Dermal
Species : Guinea pig
Method : OECD Test Guideline 406
Result : Not a skin sensitizer.
GLP : No information available.

Germ cell mutagenicity


Product:
Germ cell mutagenicity - : No information available.
Assessment

Components:
Xylene:
Genotoxicity in vitro : Test Type: sister chromatid exchange assay
Test system: Chinese hamster ovary cells
Concentration: 5 - 50 µg/ml
Metabolic activation: with and without metabolic activation
Method: Other
Result: negative
GLP: No information available.

Test Type: Chromosome aberration test in vitro


Test system: Chinese hamster ovary cells
Concentration: 15,1 - 100,5 µg/ml
Metabolic activation: with and without metabolic activation
Method: Directive 84/449/EEC, B.10
Result: negative
GLP: No information available.

Genotoxicity in vivo : Test Type: dominant lethal test


Species: Mouse (male and female)
Strain: Other
Application Route: Subcutaneous

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Exposure time: single injection


Dose: 1 ml/kg
Method: OECD Test Guideline 478
Result: negative
GLP: no

Germ cell mutagenicity - : It is concluded that the product is not mutagenic based on
Assessment evaluation of several mutagenicity tests.

Naphthalene (Amount coming from “Hydrocarbons, C10, aromatics, > 1% naphthalene”):


Genotoxicity in vitro : Test Type: Other
Test system: human lymphoblastoid cells
Concentration: 40 µg/ml
Metabolic activation: without
Method: Other
Result: negative
GLP: No information available.

Test Type: Ames test


Test system: Salmonella typhimurium
Concentration: 0,3 - 100 µg/plate
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
GLP: No information available.

Test Type: Chromosome aberration test in vitro


Test system: Chinese hamster ovary cells
Concentration: 15 - 112,5 µg/ml
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 473
Result: Positive only in the test with metabolic activation
GLP: yes

Genotoxicity in vivo : Test Type: Micronucleus test


Species: Mouse (male and female)
Strain: CD1
Cell type: Bone marrow cells
Application Route: Intraperitoneal injection
Exposure time: single treatment
Dose: 250-500-1000-3000-5000 mg/kg
Method: Other
Result: negative
GLP: yes

Test Type: Micronucleus test


Species: Rat (male)
Strain: Sprague-Dawley
Cell type: Liver cells
Application Route: oral (gavage)
Exposure time: single treatment
Dose: 600-1000-1600 mg/kg
Method: OECD Test Guideline 486

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Result: negative
GLP: yes

Germ cell mutagenicity - : In vitro tests did not show mutagenic effects, In vivo tests did
Assessment not show mutagenic effects

Carcinogenicity
Product:
Carcinogenicity - : No information available.
Assessment

Components:
Hydrocarbons, C10, aromatics, >1% naphthalene :
Carcinogenicity - : Suspected human carcinogens
Assessment

Xylene:
Carcinogenicity - : Animal testing did not show any carcinogenic effects.
Assessment

Naphthalene (Amount coming from “Hydrocarbons, C10, aromatics, > 1% naphthalene”):


Carcinogenicity - : Limited evidence of a carcinogenic effect.
Assessment

Reproductive toxicity
Product:
Reproductive toxicity - : No information available.
Assessment No information available.

Components:
Xylene:
Effects on fertility : Test Type: Two-generation study
Species: Rat, male and female
Application Route: Inhalation
Dose: 25 - 100 - 500 ppm
Duration of Single Treatment: 6 h
General Toxicity - Parent: NOAEL: >= 2,171 mg/l
General Toxicity F1: NOAEL: >= 2,171 mg/l
General Toxicity F2: NOAEL: >= 2,171 mg/l
Method: Other
GLP: No information available.
Remarks: By analogy with a product of similar composition

Effects on foetal : Test Type: Two-generation study


development Species: Rat
Application Route: Inhalation
Dose: 100 - 500 - 1000 ppm

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Developmental Toxicity: NOAEL: 342 mg/kg body weight


Method: OPPTS 870.3800
GLP: No information available.
Remarks: Based on available data, the classification criteria
are not met.

Reproductive toxicity - : Classification as "toxic for reproduction" is not justifiable.


Assessment Classification as "teratogenic" is not justifiable.

Naphthalene (Amount coming from “Hydrocarbons, C10, aromatics, > 1% naphthalene”):


Effects on fertility : Test Type: Pre-/postnatal development
Species: Rat, female
Strain: Sprague-Dawley
Application Route: oral (gavage)
Dose: 50 - 150 - 450 mg/kg
General Toxicity F1: NOAEL: 150 mg/kg body weight
Method: Other
GLP: yes

Test Type: Fertility


Species: Rat, male and female
Strain: Sprague-Dawley
Application Route: Inhalation
Dose: 11 - 52 - 304 mg/m3
Duration of Single Treatment: 6 h
Frequency of Treatment: 5 days/week
General Toxicity - Parent: NOAEL: 0,306 mg/kg body weight
Method: Other
GLP: yes

Effects on foetal : Species: Rat


development Strain: Sprague-Dawley
Application Route: oral (gavage)
Dose: 50 - 150 - 450 mg/kg
Teratogenicity: NOAEL: 150 mg/kg body weight
Method: OECD Test Guideline 414
GLP: yes

Reproductive toxicity - : No evidence of adverse effects on sexual function and fertility,


Assessment or on development, based on animal experiments.

STOT - single exposure


Product:
Remarks : no data available

Components:
Hydrocarbons, C10, aromatics, >1% naphthalene :
Target Organs : Central nervous system
Assessment : May cause drowsiness or dizziness.

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Xylene:
Exposure routes : Inhalation
Assessment : May cause respiratory irritation.

Naphthalene (Amount coming from “Hydrocarbons, C10, aromatics, > 1% naphthalene”):


Assessment : The substance or mixture is not classified as specific target
organ toxicant, single exposure.

STOT - repeated exposure


Product:
Remarks : no data available

Components:
Xylene:
Target Organs : Kidney, Liver, Central nervous system
Assessment : May cause damage to organs through prolonged or repeated
exposure.

Naphthalene (Amount coming from “Hydrocarbons, C10, aromatics, > 1% naphthalene”):


Assessment : The substance or mixture is not classified as specific target
organ toxicant, repeated exposure.

Repeated dose toxicity


Product:
Remarks : no data available

Components:
Xylene:
Species : Rat, male and female
NOAEL : 250 mg/kg
Application Route : oral (gavage)
Exposure time : 103 w
Number of exposures : Once daily (5 days/week).
Dose : 250 - 500 mg/kg
Control Group : yes
Method : Other
GLP : No information available.

Species : Rat, male and female


NOAEL : 150 mg/kg
LOAEL : 150 mg/kg
Application Route : oral (gavage)
Exposure time : 90 d
Number of exposures : once daily
Dose : 150 - 750 - 1500 mg/kg
Control Group : yes
Method : OECD Test Guideline 408

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GLP : No information available.

Species : Rat, male


NOAEL : >= 3,515 mg/l
Application Route : Inhalation
Exposure time : 13 w
Number of exposures : 6 hours/day, 5 days/week
Dose : 781 - 1996 - 3515 mg/m3
Control Group : yes
Method : Other
GLP : No information available.

Application Route : Skin contact


Remarks : This information is not available.

Naphthalene (Amount coming from “Hydrocarbons, C10, aromatics, > 1% naphthalene”):


Species : Rat, male and female
NOAEL : 100 mg/kg
Application Route : oral (gavage)
Exposure time : 13 w
Number of exposures : daily, 5 d per w
Dose : 25 - 50 - 100 - 200 - 400 mg/k
Control Group : yes
Method : OECD Test Guideline 408
GLP : no

Species : Rat, male and female


LOAEL : 0,011 mg/l
Application Route : Inhalation
Exposure time : 13 w
Number of exposures : 6 h/d, 5d per w
Dose : 11 -51 - 306 mg/m3
Control Group : yes
Method : OECD Test Guideline 413
GLP : yes

Species : Rat, male and female


NOAEL : 1.000 mg/kg
Application Route : Skin contact
Exposure time : 13 w
Number of exposures : 5 d per week
Dose : 100 - 300 - 1000 mg/kg
Control Group : yes
Method : OECD Test Guideline 411
GLP : yes

Aspiration toxicity
Product:
no data available

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Components:
Hydrocarbons, C10, aromatics, >1% naphthalene :
May be fatal if swallowed and enters airways.

Xylene:
May be fatal if swallowed and enters airways.

Naphthalene (Amount coming from “Hydrocarbons, C10, aromatics, > 1% naphthalene”):


No aspiration toxicity classification

12. ECOLOGICAL INFORMATION

Ecotoxicity
Product:
Toxicity to fish :
Remarks: no data available

Toxicity to daphnia and other :


aquatic invertebrates Remarks: no data available

Toxicity to algae/aquatic :
plants Remarks: no data available

Toxicity to microorganisms : Remarks: no data available

Components:
Hydrocarbons, C10, aromatics, >1% naphthalene :
Toxicity to fish : LL50 (Oncorhynchus mykiss (rainbow trout)): 2 - 5 mg/l
End point: mortality
Exposure time: 96 h
Test Type: semi-static test
Method: OECD Test Guideline 203

Toxicity to daphnia and other : EL50 (Daphnia magna (Water flea)): 3 - 10 mg/l
aquatic invertebrates End point: Immobilization
Exposure time: 48 h
Test Type: static test
Method: OECD Test Guideline 202

Toxicity to algae/aquatic : EL50 (Pseudokirchneriella subcapitata (green algae)): > 1 - <


plants 3 mg/l
End point: Biomass
Exposure time: 72 h
Test Type: static test
Method: OECD Test Guideline 201

Toxicity to fish (Chronic : NOELR (Oncorhynchus mykiss (rainbow trout)): 0,487 mg/l
toxicity) Exposure time: 28 d
Method: Other

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Remarks: Estimated value

Toxicity to daphnia and other : NOELR (Daphnia magna (Water flea)): 0,851 mg/l
aquatic invertebrates Exposure time: 21 d
(Chronic toxicity) Method: Other

Ecotoxicology Assessment
Chronic aquatic toxicity : Toxic to aquatic life with long lasting effects.

Xylene:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 2,6 mg/l
Exposure time: 96 h
Test Type: semi-static test
Analytical monitoring: yes
Method: OECD Test Guideline 203
GLP: No information available.
Remarks: By analogy with a product of similar composition

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): ca. 1 mg/l
aquatic invertebrates Exposure time: 24 h
Test Type: static test
Analytical monitoring: yes
Method: OECD Test Guideline 202
GLP: No information available.
Remarks: By analogy with a product of similar composition

Toxicity to algae/aquatic : EC50 (Pseudokirchneriella subcapitata (microalgae)): 4,36


plants mg/l
End point: Growth rate
Exposure time: 73 h
Test Type: static test
Analytical monitoring: yes
Method: OECD Test Guideline 201
GLP: yes
Remarks: By analogy with a product of similar composition

EC50 (Pseudokirchneriella subcapitata (green algae)): 2,2


mg/l
End point: Biomass
Exposure time: 73 h
Test Type: static test
Analytical monitoring: yes
Method: OECD Test Guideline 201
GLP: yes
Remarks: By analogy with a product of similar composition

NOEC (Pseudokirchneriella subcapitata (green algae)): 0,44


mg/l
Exposure time: 73 h
Test Type: static test
Analytical monitoring: yes
Method: OECD Test Guideline 201

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GLP: yes
Remarks: By analogy with a product of similar composition

Toxicity to fish (Chronic : NOEC (Oncorhynchus mykiss (rainbow trout)): > 1,3 mg/l
toxicity) Exposure time: 56 d
Test Type: flow-through test
Analytical monitoring: yes
Method: Other
GLP: no

Toxicity to daphnia and other : NOEC (Freshwater insects): 0,96 - 1,17 mg/l
aquatic invertebrates End point: Reproduction rate
(Chronic toxicity) Exposure time: 7 d
Test Type: semi-static test
Analytical monitoring: yes
Method: Other
GLP: no
Remarks: By analogy with a product of similar composition

Toxicity to microorganisms : EC50 (Nitrosomonas sp.): 96 mg/l


Exposure time: 24 h
Test Type: static test
Analytical monitoring: no
Method: Other
GLP: No information available.
Remarks: By analogy with a product of similar composition
The details of the toxic effect relate to the nominal
concentration.

EC50 (activated sludge, domestic): > 157 mg/l


End point: Bacteria toxicity (respiration inhibition)
Exposure time: 3 h
Test Type: static test
Analytical monitoring: no
Method: OECD Test Guideline 209
GLP: yes
Remarks: By analogy with a product of similar composition
The details of the toxic effect relate to the nominal
concentration.

Toxicity to soil dwelling : Remarks: Not applicable


organisms

Plant toxicity : EC50: ca. > 1 mg/kg


>1 milligram per kilogram
Exposure time: 14 d
End point: Growth
Species: Lactuca sativa (lettuce)
Analytical monitoring: yes
Method: OECD Guide-line 208
GLP: No information available.
Remarks: By analogy with a product of similar composition

Sediment toxicity : Remarks: Not applicable

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Toxicity to terrestrial : Remarks: Not applicable


organisms

Ecotoxicology Assessment
Chronic aquatic toxicity : Harmful to aquatic life with long lasting effects.

Naphthalene (Amount coming from “Hydrocarbons, C10, aromatics, > 1% naphthalene”):


Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 1,6 mg/l
Exposure time: 96 h
Test Type: flow-through test
Analytical monitoring: yes
Method: OECD Test Guideline 203
GLP: No information available.

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 2,16 mg/l
aquatic invertebrates Exposure time: 48 h
Test Type: static test
Analytical monitoring: yes
Method: OECD Test Guideline 202
GLP: no
Remarks: The details of the toxic effect relate to the nominal
concentration.

Toxicity to algae/aquatic : NOEC (Lemna gibba G3 (gibbous duckweed)): >= 16 mg/l


plants End point: Growth rate
Exposure time: 8 d
Test Type: static test
Analytical monitoring: yes
Method: Other
GLP: No information available.

Toxicity to fish (Chronic : NOEC (Oncorhynchus kisutch (coho salmon)): ca. 0,37 mg/l
toxicity) Exposure time: 40 d
Test Type: flow-through test
Analytical monitoring: yes
Method: Other
GLP: No information available.

Toxicity to daphnia and other : NOEC (Daphnia pulex (Water flea)): 0,59 mg/l
aquatic invertebrates End point: Reproduction rate
(Chronic toxicity) Exposure time: 125 d
Test Type: static test
Analytical monitoring: yes
Method: Other
GLP: No information available.

Toxicity to microorganisms : IC50 (Bacteria): 29 mg/l


End point: Growth rate
Exposure time: 24 h
Test Type: aquatic
Analytical monitoring: no data available

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Method: Other
GLP: No information available.
Remarks: The details of the toxic effect relate to the nominal
concentration.

Sediment toxicity : Remarks: Not applicable

Ecotoxicology Assessment
Acute aquatic toxicity : Very toxic to aquatic life.

Chronic aquatic toxicity : Very toxic to aquatic life with long lasting effects.

Persistence and degradability


Product:
Biodegradability : Remarks: no data available

Components:
Hydrocarbons, C10, aromatics, >1% naphthalene :
Biodegradability : aerobic
Inoculum: activated sludge
Result: Inherently biodegradable.
Method: OECD Test Guideline 301F

Xylene:
Biodegradability : aerobic
Inoculum: activated sludge, non-adapted
Concentration: 41 mg/l
BOD in % of theoretical OD
Result: Readily biodegradable.
Biodegradation: 87,8 %
Exposure time: 28 d
Method: OECD Test Guideline 301F
GLP: yes

Naphthalene (Amount coming from “Hydrocarbons, C10, aromatics, > 1% naphthalene”):


Biodegradability : aerobic
Inoculum: activated sludge, non-adapted
Concentration: 30 ppm
BOD in % of theoretical OD
Result: Not biodegradable
Biodegradation: ca. 0 %
Exposure time: 28 d
Method: OECD Test Guideline 302C
GLP: no

aerobic
Inoculum: Other
Concentration: 0,15 mg/l
BOD in % of theoretical OD

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Result: Readily biodegradable.


Biodegradation: 99,9 %
Exposure time: 15 d
Method: Other
GLP: No information available.

Physico-chemical : Remarks: Biodegradable


removability

Bioaccumulative potential
Product:
Bioaccumulation : Remarks: no data available

Components:
Xylene:
Bioaccumulation : Species: Oncorhynchus mykiss (rainbow trout)
Bioconcentration factor (BCF): 7,2 - 25,9
Exposure time: 56 d
Concentration: 0,36 - 0,74 mg/l
Method: Other
GLP: No information available.

Naphthalene (Amount coming from “Hydrocarbons, C10, aromatics, > 1% naphthalene”):


Bioaccumulation : Species: Cyprinus carpio (Carp)
Bioconcentration factor (BCF): 36,5 - 168
Exposure time: 56 d
Concentration: 0,15 mg/l
Method: OECD Test Guideline 305
GLP: no
Remarks: Does not significantly accumulate in organisms.

Mobility in soil
Product:
Distribution among : Remarks: no data available
environmental compartments

Components:
Xylene:
Distribution among : Adsorption/Soil
environmental compartments Medium: water - soil
log Koc: 2,73
Method: OECD Test Guideline 121

Naphthalene (Amount coming from “Hydrocarbons, C10, aromatics, > 1% naphthalene”):


Distribution among : Adsorption/Soil
environmental compartments Medium: water - soil
Koc: ca. 664

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Method: Other

Other adverse effects


Product:
Results of PBT and vPvB : Remarks: no data available
assessment

Additional ecological : no data available


information

Components:
Xylene:
Environmental fate and : not available
pathways

Results of PBT and vPvB : The substance is not identified as a PBT or as a vPvB
assessment substance.

Additional ecological : Do not allow to enter ground water, waterways or waste water.
information

Naphthalene (Amount coming from “Hydrocarbons, C10, aromatics, > 1% naphthalene”):


Environmental fate and : not available
pathways

Results of PBT and vPvB : The substance is not identified as a PBT or as a vPvB
assessment substance.

Additional ecological : Do not allow to enter ground water, waterways or waste water.
information

13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Product should be taken to a suitable and authorized waste
disposal site in accordance with relevant regulations and if
necessary after consultation with the waste disposal operator
and/or the competent Authorities

Contaminated packaging : Packaging that cannot be cleaned should be disposed of as


product waste

14. TRANSPORT INFORMATION

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IATA
Proper shipping name: Flammable liquid, n.o.s.
Class: 3
Packing group: III
UN/ID number: UN 1993
Primary risk: 3
Remarks Shipment permitted
Hazard inducer(s): Xylene
Aromatic hydrocarbons
IMDG
Proper shipping name: Flammable liquid, n.o.s.
Class: 3
Packing group: III
UN no. UN 1993
Primary risk: 3
Remarks Shipment permitted
Hazard inducer(s): Xylene
Aromatic hydrocarbons
Hazard inducer/Marine Aromatic hydrocarbons
pollutant:
Marine pollutant: Marine Pollutant
EmS : F-E S-E

15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or


mixture
Apart from the data/regulations specified in this chapter, no further information is available
concerning safety, health and environmental protection.

Minister of Industry Regulation No. 23/M-IND/PER/4/2013 concerning the Revision of


Minister of Industry Regulation No. 87/M-IND/PER/9/2009 concerning Globally Harmonized
System of Classification and Labelling of Chemicals.
Regulation of the Minister of Hea lth No. 472 of 1996 on the Safeguarding of Substances
Hazardous to Health
Hazardous substances that must be registered : Not applicable

Government Regulation No. 74 of 2001 on the Management of Hazardous and Toxic


Substances
Hazardous substances approved for use : Not applicable

Prohibited substances : Not applicable

Restricted substances : Not applicable

Regulation of the Minister of Trade No. 44 of 2009 on Procurement, Distribution and


Supervision of Hazardous Materials
Type of Hazardous Materials Restricted to Import, : Not applicable
Distribution and Supervision

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16. OTHER INFORMATION

Further information
Other information : Observe national and local legal requirements

Date format : yyyy/mm/dd

Full text of other abbreviations


ACGIH : USA. ACGIH Threshold Limit Values (TLV)
ACGIH BEI : ACGIH - Biological Exposure Indices (BEI)
ID OEL : Indonesia. Occupational Exposure Limits

ACGIH / TWA : 8-hour, time-weighted average


ID OEL / NAB : Long term exposure limit
ID OEL / PSD : Short term exposure limit

AICS - Australian Inventory of Chemical Substances; ANTT - National Agency for Transport by
Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for
Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with
x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized
System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer;
IATA - International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory
concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing
Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50
- Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test
population (Median Lethal Dose); MARPOL - International Convention for the Prevention of
Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No
Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level;
NOELR - No Observable Effect Loading Rate; NOM - Official Mexican Norm; NTP - National
Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for
Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution
Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines
Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity
Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the
Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals;
SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan
Chemical Substance Inventory; TDG - Transportation of Dangerous Goods; TSCA - Toxic
Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations
Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very
Bioaccumulative; WHMIS - Workplace Hazardous Materials Information System

This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Clariant makes no warranties, express
or implied, as to the information's accuracy, adequacy, sufficiency or freedom from defect and

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assumes no liability in connection with any use of this information. Any user of this product is
responsible for determining the suitability of Clariant's products for its particular application.
Nothing included in this information waives any of Clariant's General Terms and Conditions of
Sale, which control unless it agrees otherwise in writing. Any existing intellectual/industrial
property rights must be observed. Due to possible changes in our products and applicable
national and international regulations and laws, the status of our products could change. Material
Safety Data Sheets providing safety precautions, that should be observed when handling or
storing Clariant products, are available upon request and are provided in compliance with
applicable law. You should obtain and review the applicable Material Safety Data Sheet
information before handling any of these products. For additional information, please contact
Clariant.

ID / EN

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