Test 4 - Enthuse (Score-1) - Paper-2 - 29-12-2020 (1

Time: 3 Hours Maximum Marks: 180
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Some Useful Data
Quantity Values
Constant of gravitation 6.67259 × 10–11 N-m2 kg–2
Speed of light in vacuum 2.99792458 × 108 m s –1
Avogadro constant 6.0221367 × 1023 mol–1
Gas constant 8.314510 JK–1-mol–1
Boltzmann constant 1.380658 × 10–23 JK–1
8.617385 × 10–5 eV K–1
Stefan-Boltzmann constant 5.67051 × 10–8 W m–2 - K–4
Wien’s displacement law constant 2.897756 × 10–3 m -K
Charge of proton 1.60217733 × 10–19 C
Mass of electron 9.1093897 × 10–31 kg
5.48579903 × 10–4 u
Mass of proton 1.6726231 × 10–27 kg
1.007276470 u
Permeability of vacuum 4 × 10–7 NA–2
Permittivity of vacuum 8.854187817 × 10–12 C2 N–1 m–2
Faraday constant 96485.3029 C mol–1
Planck constant 6.6260755 × 10–34 J-s
4.1356692 × 10–15 eV-s
JEE-ADVANCED
PART-I : PHYSICS
SECTION-I : One or More Options Correct Type
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE THAN ONE may be correct. You will be awarded 4 marks if all the
correct option(s) is/are chosen and zero mark if none of the option is chosen. For each correct answer
+1 mark will be awarded if no incorrect option is chosen. In all other cases minus two (–2) mark will be
awarded.
1. Consider an attractive force which is central but is inversely proportional to the first power of
distance. If such a particle is in circular orbit under such a force, which of the following statements
are correct
(A) v  r (B) v  r º (C) T  r (D) T  r º
2. Two projectile are thrown at the same time from two different points. The projectile thrown from
the origin has initial velocity 3iˆ  3 ˆj with respect to earth. The projectile has initial velocity
aiˆ  bˆj with respect to earth thrown from the point (10, 5). ( iˆ is a unit vector along horizontal, ĵ
along vertical). If the projectile collides after two second, then the
1
(A) value of ais -2 (B) value of a is
2
1
(C) value of b is (D) value of b is –2
2
3. A solid sphere moves at a terminal velocity of 20 m/s in air at a place where g = 9.8 m/s2. The
sphere is taken in a gravity free hall having air at the same pressure and pushed down at a speed of
20 m/s.
(A) Its initial acceleration will be 9.8 m/s2 downward
(B) Its initial acceleration will be 9.8 m/s2 upward
(C) The magnitude of acceleration will decrease as the time passes.
(D) It will eventually stop.
Nucleus Education-ENTHUSE All (Score–1)_29122020
4. A block P of mass 4 kg is placed on horizontal rough P

surface with coefficient of friction  = 0.6. And two B 4kg A
blocks R and Q of masses 2 kg and 4 kg connected with
the help of massless strings A and B respectively  = 0.6
passing over frictionless pulleys as shown, then
(g = 10m/s2) 4kg 2kg
Q R
(A) acceleration of block P is zero.
(B) tension in string A is 20 N.
(C) tension in string B is 40 N.
(D) contact force on block P is 20 5 N.
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1 1
JEE-ADVANCED
5. The temperature drop through a two layers furnace wall is 900ºC. Each layer is of equal area of
cross-section. Which of the following actions will result in lowering the temperature  of the
interface?
Inner Outer
layer layer
1000ºC 100ºC

(A) by increasing the thermal conductivity of outer layer
(B) by increasing the thermal conductivity of inner layer
(C) by increasing thickness of outer layer
(D) by increasing thickness of inner layer
6. A bimetallic strip is formed by two identical strips, one of copper and the other of brass. The
coefficients of linear expansion of the two metals are C and  B . On heating, the temperature of
the strip goes up by T and the strip bends to from an arc of radius of curvature R. Then R is
(A) proportional to T (B) inversely proportional to T
(C) proportional to  B  C (D) inversely proportional to  B  C
SECTION-II : Integer Value Correct Type

This section contains 8 questions. For each question, enter the correct numerical value (in decimal
notation, truncated / rounded off to the second decimal place; e.g. 6.25, 7.00, –0.33, –0.30, 30.27,
–127.30) using the mouse and the on screen virtual numeric keypad in the place designated to enter the
answer. You will be awarded 3 marks if correct numerical value is entered as answer. No negative
marks will be awarded for incorrect answers in this section.
7. A man of mass m = 60 kg is standing on weighing machine fixed on a triangular wedge of angle 
= 60º as shown in the figure. The wedge is moving up with an upward acceleration a = 2m/s 2. The
weight registered by machine is –
a


8. At a height 0.4m from the ground, the velocity of a projectile is, v  (6î  2 ĵ) m/s. The angle of
projection is: (g = 10 m/s2)
9. Two stones are projected with the same speed but making different angles with the horizontal.

Their horizontal ranges are equal. The angle of projection of one is and the maximum height
3
reached by it is 102 m. Then the maximum height reached by the other in metre is -
2 2
JEE-ADVANCED
10. The diagram below shows rods of the same size of two different materials P and Q placed end to
end in thermal contact and heavily lagged at their sides. The outer ends of P and Q are kept at 0°C
and 100°C, respectively. The thermal conductivity of P is four times that of Q. What is the steady-
state temperature of the interface ?
0°C P Q 100°C
11. A charge of 5 C is given a displacement of 0.5 m, the work done in the process is 10 J. The
potential difference between the two points will be -
12. 45 gm of alcohol are needed to completely fill up a weight thermometer at 15ºC. Find the weight
of alcohol which will overflow when the weight thermometer is heated to 33ºC.
(Given a = 121 × 10–5 ºC–1)
13. At a certain distance from a point charge the electric field is 500 V/m and the potential is 3000 V.
What is the distance ?
14. Three rods made of the same material and having the same cross-section have been joined as
shown in the figure. Each rod is of the same length. The left and right ends are kept at 0°C and
90°C respectively. The temperature of the junction of the three rods will be –
90°C
0°C
90°C
SECTION-III : Matching List Type (4 × 4)(4 × 5)

This section contains 4 multiple choice questions, each having two matching lists. Choices for the
correct combination of elements from List-I and List-II are given as options (A), (B), (C) and (D), out of
which ONLY ONE is correct. You will be awarded 3 marks if only the correct option is chosen and zero
mark if none of the option is chosen. (–1) marks will be awarded for incorrect answers in this section.
3 3
JEE-ADVANCED
15. At any instant t = 0 a motorbike start from rest in a given direction, a car moving with constant
speed overtakes the motorbike at that instant when it is moving with a speed 40 m/s. Motor bike
accelerates uniformly till t = 18sand then move with constant speed and overtakes the car at t = 27
s.
List-I List-II
(P) The maximum speed of motorbike in m/s is (1) 240
(Q) The acceleration of motor bike in m/s2 is (2) 60
(R) The separation between can and bike at t = 18 s in m is (3) 10/3
(S) The maximum separation between car and bike in m (4) 180
before bike overtake the car is
(5) 200
Codes :
(A) P  2; Q  3; R  4; S  1 (B) P  3; Q  1; R  4; S  2
(C) P  4; Q  3; R  2; S  1 (D) P  1; Q  3; R  2; S  4
16. A cubical block is in a floating equilibrium in a liquid with half of its volume submerged as
shown in figure at temperature T.
S coefficient of linear expansion of block
L coefficient of volume expansion of liquid
S density of block at temperature T
L density of liquid at temperature T
List-I List-II
(P) The ratio of densities of solid and liquid at temperature (1) 1
T is 2
(Q) If the depth of the block submerged in the liquid does (2) 3
not change on increasing temperature then ratio of s
to L is
(R) If fraction submerged does not change on increasing (3) 2
temperature then the ratio of L to s is
(S) The ratio of Buoyant force to weight of body at (4) 1
temperature 2T is
(5)
Codes :
(A) P  2; Q  3; R  1; S  4 (B) P  4; Q  2; R  1; S  3
(C) P  1; Q  1; R  2; S  4 (D) P  3; Q  4; R  2; S  1
4 4
JEE-ADVANCED
17. 3 blocks are arranged as shown in figure. All the strings are massless and inextensible. All pulleys
are frictionless and massless. Co-efficient of friction between surfaces and blocks are 0.5. If the
blocks were initially at rest, then find (given tan 37° = 3/4)
1.2kg
2=0.5
2kg
1=0.5
37°
1kg
List-I List-II
(P) Tension in the string attached to 2 kg block (in N) (1) 7
(Q) Contact force by the surface on 1.2 kg (in N) (2) 10
2
(R) Acceleration of 1kg block (in m/s ) (3) 13
(S) Friction force on 2 kg block (in N) (4) 5
(5) zero
Codes :
(A) P  4; Q  3; R  6; S  1 (B) P  3; Q  2; R  4; S  1
(C) P  3; Q  1; R  2; S  4 (D) P  2; Q  3; R  4; S  1
18. Four large parallel identical conducing plates of area A are arranged as shown. The charges on
each plate are given in diagram and separation between plates is d. Surfaces of plates are
numbered (1), (2) ………….(8).
4Q Q 2Q 7Q
(1) (2) (3) (4) (5) (6) (7) (8)
d d d
List-I List-II
(P) The charge on surface (4) is (1) –3Q
(Q) The charge on surface (6) is (2) –2Q

(R) The charge on surface (2) is (3) 7Q
(S) The charge on surface (8) is (4) zero
(5) 5Q
Codes :
(A) P  2; Q  4; R  1; S  3 (B) P  5; Q  4; R  3; S  1
(C) P  1; Q  2; R  4; S  5 (D) P  2; Q  5; R  1; S  4
5 5
JEE-ADVANCED
PART-II : MATHEMATICS
awarded.
1 1
19. Let f be a real valued function and satisfies f(x) + f(y) =  x, y  R  {0} .
x y
 3(f(x))5  f (x) 
3
1  2 
If    dx  log    , then
2 1  (f(x)) 4
 2 3 
(A)    (B)  +  < 17

 
(C) tan 1    sec1   (D) ( – ) is a prime number
5
dt

x
20. For 0 < x < 1, let g(x) = then
0
1 t2
  3
 0 g(x)dx  2 1
1
(A) (B) g'    2
 2 
 3 3 
(C) g    (D) g(x)  g( 1  x 2 ) 
 4 4 2
1
sin x
21. If I   dx , then-
0 1  x
  1  cos1 1  cos1
(A) I < (B) I  (C) I  (D) 1 
4 4 2 2
22. Let C1 and C2 be the graphs of y = x3 and y = 3x, x  [0, 1] respectively. Let C3 be the graph of a
Nucleus Education-(ENTHUSE-SCORE-I)_29122020
function y = f(x) in [0, 1], f(0) = 0. For a point P on C1, let the lines through P, parallel to the axes
meet C2 and C3 at Q and R respectively, (see figure). If f(x) is such that for every position of
P(on C1) the areas of shaded regions OPQ & ORP are equal, then
1
(A)  f (x)dx  
1 1
(B) f    
7 1
(C) f    
5
(D) f '(x) < 0 x(0, 1)
0 3  2 32  2 32
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JEE-ADVANCED
1
dy
23. Let y = f(x) & x  y   ydx , then which option(s) is/are true-
dx 0
(A) Solution of differential equation is family of concurrent lines.
(B) Solution of differential equation is family of parallel lines.
1
(C) If f(1) = 3, then  ydx  1
0
1
dy
(D)  4. ydx
dx 0
sin 2 2x dx
24.  sin 6 x  cos6x is equal to-
4 4 1
(A) tan 1(tan3x)  C (B) cot (cot 3x)  C
3 3
4 4
(C)  cot 1 (tan3x)  C (D)  cot 1 (cot 3x)  C
3 3
(where C is constant of integration)

25. A curve satisfying the differential equation (x2y2 – 1)dy + 2xy3dx = 0, is passing through the
points (1, 1) and (k, 2) then the value of k2 is equal to.
3 
  n  x 2
For n  N, if Lim x 2 
t t  1 dt 
n
26. then n is equal to
x  11
0
27. Let f : R  R be a function satisfying f "(x) = f '(x) + ex, f(0) = 0 and f '(0) = 1, then area bounded
by y = f(x) & x-axis in third quadrant is equal to
28. A Continuous function f : R  R satisfying the differential equation

2  f (t) 
x 2
f(x) = (1 + x ) 1   dt  then the value of |f(1)| is equal to-
 0 1 t 
2
dy 2x3  2xy  y
29. If solution of differential equation  is (x2 – y)a = bxy + C {C is arbitrary constant}
dx xx y
2
then a + b is equal to-
JEE-ADVANCED
30. Let a, b be real numbers. The functions f(x) = ax + b, g(x) = x + 1 satisfy
 (f(x))2 dx   f (x)g(x)dx .
1 1
1 1

1
Find the maximum value of (f(x))2 dx
1
31. If F  x   
x nx
n x n
 
dx, F e2  0, F  e   A  n2
2
Then A is equal to
32. If A denotes the area between the curve 2{y} = [x] + 1 for 0  y < 1 and the x-axis between
x2 – x  0, then A is equal to (where {·} and [·] are the fractional part and greatest integer
functions respectively)-

33. Match the list.
List-I List-II
(P) 2
3x 4  2x 2  1 (1) 1
If 
1 x4  x2 1
dx  m  n , then (m – n + 1) is
equal to
(Q) 2 (2) 4
x  2 x  2 x..... , then  (f (x) 1) dx is
2
If f(x) =
equal to
(R)  /2 (3) 8
ecos x 4I
If I  
0 e e
cos x sin x
dx , then

is equal to

(S) e (1  x)
x
1 (4) 12
If x
0
2
e 2x
dx  tan 1   , where  a is a solution of
n
8x = ex, then n is equal to
Codes :
(A) P  4; Q  2; R  1; S  3 (B) P  3; Q  2; R  1; S  4
(C) P  4; Q  1; R  2; S  3 (D) P  3; Q  2; R  1; S  3
JEE-ADVANCED
34. Match the list.
List-I List-II
(P) Area enclosed by the curve |x – 2| + |y + 1| = 1 is equal (1) 2
to
(Q) The order of differential equation whose general (2) 3
equation is y = c1sin3x + c2e2x + c3sin3x + c4sinx +
c5e2xc6 is equal to
(R) 2
1 x  1x  2 1  (3) 16
 2  x  x 2  dx is equal to
1/2 x
(S) 15  2  d2  (4) 0
  5
(x 1)  2 (sin x)  dx is equal to
2 0  dx 
Codes :
(A) P  2; Q  4; R  1; S  3
(B) P  2; Q  3; R  0; S  4
(C) P  1; Q  2; R  3; S  3
(D) P  1; Q  2; R  4; S  3
35. Match the list.
List-I List-II
(P) 5 (1) 

1
x  2 x  1dx
2
 [x] 
2
(Q) (2) 2
1 1  x 2 dx where [·] denotes greatest integer function
(R) 2
x nx (3) –1
 (1 x )
1/2
2 2
dx

(S) 2x (4) 0
 sin x 
0 
dx
(5) 
4
Codes :
(A) P  2; Q  1; R  3; S  4 (B) P  2; Q  3; R  4; S  1
(C) P  3; Q  2; R  4; S  5 (D) P  5; Q  2; R  4; S  1
JEE-ADVANCED
36. Match the list. [D.I., AUC, D.E.(E)]
List-I List-II
(P) Let f(x) be the anti derivative of (1) 5
  
2
If g(x)  tan x  x  x tan x and f    , then
2
4 2
 6   
 2 f   4   is equal to
  
(Q) log x  elog b x  log x (2) 1
If  dx  log x .log  log x   C then  b  3
x
is equal to
(R) If y= f(x) be a curve passes through the point (1, 2) and satisfies (3) 2
dy 2x y
the differential equation  , then f  2  is equal to
dx x 2  1
(S) Area inclosed between the curves y  ex  2 and the lines x = 0 (4) 3
and x  log e 4 is equal to
(5) 4
Codes :
(A) P  4; Q  5; R  2; S  1
(B) P  3; Q  2; R  5; S  1
(C) P  4; Q  5; R  1; S  2
(D) P  5; Q  4; R  3; S  2
JEE-ADVANCED
PART-III : CHEMISTRY
awarded.
37. Amphoteric oxide(s) of Mn is/are :
(A) MnO2 (B) Mn3O4 (C) Mn2O7 (D) MnO
38. Which of the following ether can be produced by Williamson ether synthesis in good yield:
OCH3 OPh
(A) (B) (C) (D) O

O
39. In the given question Ka values of five weak acids are given Ka for HA = 10–8, HB = 10–6,
HC = 2×10–8, HD = 10–10, HE = 10–4
Select the CORRECT statement(s) as per the information.
Given : log2 = 0.3
(A) Among NaA, NaB, NaC, NaD and NaE, the NaD is most extensively hydrolysed.
(B) Among NaA, NaB, NaC, NaD and NaE, the NaB is most extensively hydrolysed.
(C) pH of 0.1 M aqueous solution of NaB is approximately 9.5.
(D) 0.1 M solution of HE and 0.01 M solution of HB are isohydric (same value of pH) to each
other.
40. Which of the following metal carbonate is/are thermally stable ?

(A) Na2CO3 (B) MgCO3 (C) K2CO3 (D) Rb2CO3
41. A chemist allows some pure (2S, 3R)-3-Bromo-2,3-diphenyl pentane to react with a solution of
sodium ethoxide (NaOC2H5) in ethanol. The product is two alkenes : P (cis-trans mixture) & Q, a
single pure isomer. Under the same condition, (2S, 3S)-3-Bromo-2,3-diphenyl pentane gives two
alkenes, P(cis-trans mixture) & R. On catalytic hydrogenation P, Q & R all produces S. Then
select CORRECT option(s) :
(A) Configuration of compound R is ‘Trans’ & ‘E’.
(B) Configuration at chiral center in P can be both ‘R’& ‘S’.
(C) Formation of P, Q & R involves bimolecular elimination reaction.
(D) IUPAC name of compound S is ‘2,3-diphenyl pentane’.
JEE-ADVANCED
42. For the reaction
2ClF3(g) Cl2(g) + 3F2(g)
1
log Keq v/s (where temperature is in K) curve is obtained as following
T
Which of the following change will increase the concentration of Cl2 in an equilibrium mixture of
Cl2, F2 & ClF3:
Log Keq
1
T
(A) Addition of inert gas at constant pressure
(B) Increase in temperature at constant volume
(C) Addition of catalyst at equilibrium
(D) Removal of F2(g) at equilibrium

43. Find the number of longest Cr–O bonds in Cr2O72
44. A solution of pure (S)-2-iodobuane ([] = +15.90°) in acetone is allowed to react with radioactive
iodide, 131I. The specific rotation of recovered iodobutane mixture is found to be +15.582°. In
this classical SN2 mechanism, the % of (R)-2-iodobutane in final product mixture is :
45. 500 ml of 0.01 M AgNO3 is mixed with 250 ml each of NaBr and NaCl, each having molarity
0.02 M each. Find equilibrium concentration of Br– (moles/L).
Given: KSP (AgBr) = 5 × 10–13 ; KSP (AgCl) = 10–10.
–y
[If your answer is x × 10 then fill x.]
46. The oxidation number of Mn in the product of alkaline oxidative fusion of MnO2 is :
47. Monochlorination reaction of following enantiomeric pure compound takes place in 1.0 mol of
Cl2/hv. Then total chiral products obtained are:
CH3
H Cl Cl2/hv
H CH3 1.0 mole
CH3
JEE-ADVANCED
48. The equilibrium constant of a reaction A2(g) + B2(g) 2AB(g) at 100°C is 4. If a one litre
flask containing one mole of A2(g) is connected to a 2.0 L flask containing two mole of B2(g),
how many moles of AB will be formed at 373 K.
49. Percentage of gold in 14 carat gold is :
50. In the following reaction, position of Br & Methyl in IUPAC name of major product is x & y
respectively then find the value of y/x :
HBr/CCl4
(1equivalent)

51. Match the following :
List-I List-II
(P) pKb of X (Ka of HX = 10–6)
–
(1) 6.9
(Q) pH of 10–8 M HCl (2) 8
(R) pH of 10–2 M acetic acid solution (Take Ka fo (3) 10.7
acetic acid = 1.6×10–5)
(S) pOH of a solution obtained by mixing equal (4) 3.4
volumes of solution with pH 3 and 5.
Code:
(A) P2; Q1; R3; S4 (B) P1; Q2; R4; S3
(C) P2; Q4; R1; S3 (D) P2; Q1; R4; S3
52. Match the following :
List-I List-II
(Compounds) (Use of compounds)
(P) Magnesium hydroxide (1) As a purgative
(Q) Barium sulphate (2) As a fertilizer
(R) Magnesium sulphate (3) As a constituent of sorrel cement
(S) Calcium cyanamide (4) As a constituent of lithopone
Code :
(A) P; Q; R; S  (B) P; Q; R; S
(C) P; Q; R; S (D) P; Q; R; S
JEE-ADVANCED
53. The compound shown below has three different types of acidic groups X, Y, Z. Which of the
following groups will reacts with given conditions to give product:
COOH
HO (X)
(Z)
OH
(Y)
List-I List-II
(Conditions) (Group reacts)
(P) 1 equivalent NaH & 1 equivalent CH3–I (1) Only X
(Q) 2 equivalent NaH & 2 equivalent CH3–I (2) Only Y
(R) 3 equivalent NaH & 2 equivalent CH3–I (3) Only Z
(S) 2 equivalent NaH & 1 equivalent CH3–I (4) Only X & Y
(5) Only Y & Z
Code :
(A) P-1; Q-4; R-4; S-1 (B) P-2; Q-4; R-5; S-1
(C) P-1; Q-5; R-4; S-2 (D) P-1; Q-4; R-5; S-2
54. For the given endothermic reaction

A(g) 2 B(g)
The variation in concentration due to different changes is plotted. In column II various changes are
given and you are supposed to match the entries in column-I with possible changes the system
have undergone. Neglect the slope of change in concentration when system approaches
equilibrium.
Assume that changes are carried out very fast.
Concentration
effect effect effect effect

I II III IV
Time
List-I List-II
(P) Effect-I (1) Addition of inert gas at constant pressure
(Q) Effect-II (2) Decrease in total equilibrium pressure by changing volume.
(R) Effect-III (3) Decreases in temperature at constant volume
(S) Effect-IV (4) Addition of B only at constant volume
(5) Addition of inert gas at constant volume
Code:
(A) P2; Q5; R1,5; S3 (B) P3; Q5; R1,5; S3
(C) P4; Q5; R1,2; S3 (D) P2; Q4; R1,5; S3
JEE-ADVANCED
ANSWER KEY & SOLUTION
PART-I : PHYSICS
1. BC 2. AC 3. BCD 4. ABCD 5. AD 6. BD 7. 360.00
8. 30.00 9. 34.00 10. 20.00 11. 2.00 12. 0.96 13. 6.00 14. 60.00
15. A 16. C 17. A 18. A
19. CD 20. BCD 21. AD 22. ABD 23. ACD 24. ABC 25. 0.75
26. 4.00 27. 1.00 28. 6.00 29. 4.00 30. 3.67 31. 0.25 32. 0.50
33. A 34. D 35. B 36. C
37. AB 38. AD 39. AC 40. ACD 41. ACD 42. BD 43. 2.00
44. 1.00 45. 2.49 or 2.50 46. 6.00 47. 4.00 48. 1.34 49. 58.33
50. 0.33 51. D 52. B 53. D 54. C
SOLUTION | PART-I : PHYSICS | ENTHUSE-ALL_SCORE-1

1. (B,C)
K
Sol. F
r
where K is proportionally constant.
mV 2  K
 i.e., V  r 0
r r
2r 2r
T  i.e., T r .
V K
So choices (a) and (d) are wrong and choices (b) and (c) are correct.
2. (A,C)

Sol. v AB  3  aiˆ  3  b ˆj (10,5)
  vAB B
a AB  o
3  a 2  10 and 3  b 2  5 A
(0,0)
1
a = –2 and b =
2
15 15
JEE-ADVANCED
3. (B,C,D)
4. (A,B,C,D)
Sol. Friction maximum = 24 N
So net applied force on P is less than fmax.
Hence acceleration is zeroand TA = 20 N, TB = 40 N
Contact force  N 2   f   40  20  20 5 N
2 2 2
5. (A,D)
900
Sol. H  rate of heat flow  …(1)
li l
 0
Ki A K 0 A
Hli
Now, 1000    …(2)
Ki A
 
 900  l 900
or   1000    i  1000 
 li  l0  Ki A l K
1 0 i
 Ki A K 0 A  K0 li
Now, we can see that  can be decreased by increasing thermal conductivity of outer layer ( K 0 )
and thickness of inner layer li  .
6. (B,D)
l
Sol. R
 B  C t
7. (360.00)
8. (30.00)
Sol. 2 = u 2 sin 2   2hg
or 4 = u2 sin2 – 2 (0. 4) (10)
or u2sin2 = 12
or u sin  = 2 3
and u cos  = 6
1
 tan  = or  = 30º
3
2
u sin  6
u cos 
16 16
JEE-ADVANCED
9. (34.00)
Sol. Since both projectiles have equal range, thus angle of projection of second is (90 – ).
H1
 = tan2 60º
H2
 H2 = H1/3 = 34 m
10. (20.00)
4K(T – 0)
Sol. = K(100 – T)
L L
11. (2.00)
12. (0.96)
13. (6.00)
14. (60.00)
Sol.  =1 + 2 =
KA (T – 0) KA (90 – T) KA (90 – T)
= +
L L L
15. (A)
Sol. Let maximum speed of motorbike = v
40  27  27  9v
1
2
v = 60 m/s
60 10
So acceleration of motorbike  
18 3
Maximum separation = shaded area
1 1
  40  OD   40  12  240
2 2
1
Separation at t  18  240   20  6 = 180
2
v(m/s)
Motorbike
B C
v
40m/s A Car
t(s)
O D 18 27
17 17
JEE-ADVANCED
16. (C)
v v 
Sol. mg   L g , v s g   L g ,  s  L
2 2 2
mg  v'  L g , mg  Ax L g
… (i)
when temperature is raised by T, mg  A' x' L g … (ii)
From (i) and (ii) A L  A'' L
L
A L  A1  2 s T 
1   L T
s 's
 L  2 s for fraction inside the liquid to be same 
L 'L
s  1   L T 
 s  L  3 s
L L 1  3 s T 
17. (A)
Sol. Friction force between blocks and surfaces is sufficient to prevent motion of blocks.
T0 = 1 g = 10 N
2T = T0
T=5N
N2 = 1.2 g = 12 N
f2 = T = 5 N (<2N2 = 6N)
N2
T
f2
1.2 g
Contact force between 1.2 kg and surface
= 12 2  52  13 N
T  f1  2g sin 37
3
f1  2 10   5 = 7 N
5
1
T
f1
2g sin37°
2g cos 37°
18 18
JEE-ADVANCED
18. (A)
Sol. Charge distribution shown in diagram
7Q
7Q –3Q –2Q 0
+3Q 2Q 0
19 19
JEE-ADVANCED
19. [C,D]
Sol. We have
 3 1  3 1
 3  7  3
3
 5  x x 
 2  x 1x  dx  2  1 1  dx
 1 4   x2  x6 
 x   
80
1 729
dt   1 1 
=
2 
15 t
 Put,  x 2  x 6   t 
   
64
1  210 
= log    = 10,  = 7
2  37 
20. [B,C,D]
Sol. g(x) = sin–1x.
21. [A,D]
sin x sin x 1
Sol. as  
2 1 x 1 x2
11 1
1 1 
 
22
sin xdx  I  
0 1 x
2
dx 
2
(1  cos1)  I 
4
22. [A,B,D]
Let P(, 3)
Sol.
 3
 y
 (x  f(x))dx    y   dy
3 1/3
0 0 3
 3  2
 – f() = 
3
   3
 3 
f() = 5 – 23  f(x) = x5 – 2x3
1
1 1 1
(A)  (x5  2x3 )dx    
0 6 2 3
(B) f      
1 1 1 7
 2  32 4 32
(D) f '(x) = x2(5x2 – 6) < 0 x(0, 1)
JEE-ADVANCED
23. A,C,D]
1
Sol. Let  ydx  k
0
I.F. = e  x 
1
dy y k dy y k  dx 1
    
dx x x dx x x x
1
y k 1
Solution is   · dx y = – k + cx k =  ydx
x x x 0
1
cx 2 c
k = – kx + k = – k +  c = 4k  y = k(4x – 1)
2 0
2
1
(C) f(1) = 3  3 = k(4 – 1)  k = 1 =  ydx
0
1
dy
(D) y = k(4x – 1)   4k  4 ydx
dx 0
24. [A,B,C]
4sin 2 x cos2 xdx
Sol.  sin6 x  cos6 x
tan 2 x sec2 xdx
= 4 Put tan3x = t
1  tan 6 x
3tan2xsec2xdx = dt
  1 
  cot 1 x  0

 tan 1 (tan3x)  C = cot   3   C
4 dt 4 4 1 x
=   tan 1 x   
3 1 t 
 tan x    x  0 
2
3 3  1 1
 
cot
 x 
4 
cot (cot 3x)  C or tan 1 (tan3x)  C    cot 1(tan3x)   C
4 1 4
=
3 3 3 2 
4 1
=– cot (tan3x)  C
3
25. [0.75]
Sol. y2(x2dy + 2xyzdx) – dy = 0
dy 1
d(x2y) – 0  x2 y + =c=2
y2 y
1 3
2k2 + = 2 4K2 = 3  k2 = = 0.75
2 4
JEE-ADVANCED
26. [4.00]

x
t n t  1 dt    2 2 2
Sol. Let L = Lim 0
   (using Lopital's rule)  n = 4.
x 3
n    2n  3 2n  3 1
x2
27. [1.00]
df '(x)
Sol.  f '(x)(1)  ex
dx
If = e–x
0
f '(x)e–x = x +  f(x) = xex  A   xexdx  1

28. [6.00]
f (x) x 2
f (t) (1  x 2 )f '(x)  2x,f(x) f 2 (x)
Sol.  1  dt  
1 x2 0 1 t
2
(1  x)2 1 x2
dy  2x  1 dt 2x
  2 
.y  y2 Let –  t   t 1
dx  1  x  y dx 1  x 2
1 x3 3(1  x 2 )
So, solution is  (1 + x ) =
2
+ x + c but f(0) = 1 c = – 1 y = f(x) = – 2
y 3 x  3x  3
f(1) = – 6 |f(1)| = 6
29. [4.00]
Sol. (x2 – y)dy + xdy = 2x(x2 – y)dx – ydx
(x2 – y) (dy – 2xdx) = – (ydx + xdy)
  (x2  y)d(x2  y)   d(xy)
(x 2  y)2
  xy  k
2
(x2 – y)2 = 2xy + 2k
30. [3.67]
 
1 1
Sol. Given (ax b)2 dx = (ax  b)(x 1)dx
1 1
  (a 2x2  b2 )dx   (ax2  b)dx

1
1 1
a 2

 b2  = 2   b  a2 – a + 3(b2 – b) = c
9
 2
3  3 
JEE-ADVANCED
2 2
 1  1
a  2  b  2 
()  a 2  a    3 b2  b    1 
1 1     1
 4  4 1 1
3
1 1 1
a = + cos and b = + sin
2 2 3
 a2 
Now  (f(x)) dx =   b2 
1
2
2
1
3 
1 
 4  cos   cos  1 1 2
2
sin  
= 2   sin   
 3 4 3 3 
 
2 1 3 
=   cos2   cos    sin 2   3sin  
3 4 4 
2
3

2  cos   3sin  
–2 –2
0 4
= 0 8/3
1
8
  (f(x)) dx  3
2
max. value of
1
31. (0.25)
n n x
Sol.  x nx
dx put n n x t
 n  n x   2t
1 1
F(x)   2t dt  . dx  2dt
n x 2x
  C
2
dx
 t2  C   2dt  F x   n n x
x nx
put x  e2  C  0
 
2
1  1 1
 F  x    n n x   F  e    n2  A   0.25
2
2  4 4
JEE-ADVANCED
32. [0.50]
Sol. 2{y} = [x] + 1 ...(1)
 0y<1 {y} = y  (1) 2y = [x] + 1
0  [x] + 1 < 2 – 1  [x] < 1

but [x] is an integer [x] = – 1 – 1  x < 0
[x] = 0 0  x< 1
when x  [–1, 0) y = 0
1 1
when x  [0, 1) y = Area =
2 2
33. (A)
2
3x 5  2x 3  x
Sol. (P) 
1 x6  x4  x2
dx
Let x6 + x4 + x2 = t
(3x5 + 2x3 + x2) = t
14
1 dt
2
3 t
 14  3
m – n + 1 = 12
(Q) y= x  2y y2 – 2y + 1 = x + 1
2
y–1=± x  1 y = 1 + x  1  (f(x) – 1)2 = x + 1   (f (x) 1)2 dx
0
2
=  (x  1)dx  4 .
(R) use king property, we get

 4I
I=  =1
4 
eL = 1

e x (1  x)
(S) 0 (xex )2 1 dx
let xe–x = t dt = (e–x – xe–x) dx

dt  1 x  1 
 t 2  1   tan ex 0  tan e  tan 8
1
JEE-ADVANCED
34. (D)
Sol. (P) Using shifting of origin, required area is area bounded by curve |x| + |y| = 1
which is a square of side 2
Area = 2
B(0, 1)
C O A(1, 0)
(Q) Given curve can be rewritten as y = Asinx + Bsin3x + C.e2x

So, order = 3
1 x1t  2 1 
2
1
(R) I   2  x  2  dx , put x 
1/2 x  x  t
 1 2  1 
1/2 1
x
  t2
2
t
 t 2  t   t 2 dt 
  
2
1 t 1  1
I    2 t  t 2  2  dt
1/2 t  t 
I = – I I = 0
15  2 



(S)  ((x  1)(sin 5
x)') 0  2x(sin 5x)'dx 
2 0 
15  

 2x(sin x)0   2 sin xdx 
5  5
=
2 0 
/2
15 4.2
= .2.2  sin5 xdx  30  16
2 0 5.3
JEE-ADVANCED
35. (B)
5 5
Sol. (A) 
t
x  2 x 1 dx  
t
x 1 1 dx
   
2 5
  1  x 1 dx  x 1 1 dx
t 2
2  x  1 2  x 1
x/2 2 3/2 5
 x  x
3 3
t 2
 2   16 2 
  2  1  0     5   2 
 3  3 3 
12
 2  2
3
2
  x  0
 1 
1 2
 1 
(B) 1 1  x2  1 1  x2  0
dx  dx   0 dx  1 1  x 2  dx
0
   1 dx  0  0  1
1
2
x nx 1 1
(C) I  dx Put x   dx   dt
t/2 1  x  2 2 t t2
t/2
1 nt t 4  1 
I 
t t  t 2  12  t 2 
dt
2
 I  1
 I0
y=2x/

2x y =sin 
(D)  sin x 
0 
dx y  2x / 
/2 
 2x   2x 
  sin x    dx      sin x  dx
0   /2  
/2 x
x2 x2 
  cos x    cos x 
 0
 /2
2
JEE-ADVANCED
36. [C]
Sol. (P) f (x)   tan x  x  x tan 2 dx  x(tan x  x)  C
f (x) x.f 1 (x)
    
2
f (x)  f  x   F     f   
 4 4 2
log  e log bx  log x log  e log bx 

(Q)  log x
.
x
dx   x
dx
e
put elog bx  t  dx  dt
x
1 1
  log t dt  t  log t 1  C
e e
 log b log  elog b x  1  C
log blog  log bx   C
 b 1
 y   x 2  1 dx  ny  n  x  1  C ...........(1)
dy 2x 2
(R)
It passes through (1, 2)

 n2  n2  C  C  0
 (1)  ny  n  x 2 1  y  f  x   x 2 1  f  2  5
(S) Required area
n2 n4
  e  2 dx   e  2 dx  1
x x
0 n2
O
(ln4,0)
(ln2,0)
JEE-ADVANCED
37. (A,B)
Sol. MnO  Basic
Mn2O7  Acidic
 All the other oxide of Mn are amphoteric.
38. (A,D)
39. (A,C)
Sol. (A) Anion of weak acid hydrolysis more then that of anion of strong acid.
1
(C) pH = [pKw + pKa + logC]
2
1
= [14 + 6 + 1]
2
= 9.5
40. (A,C,D)
Sol. All the alkali metal carbonates (expect Li2CO3) are thermally statble.
41. (A,C,D)
42. (B,D)
43. (2.00)
O O
O
Sol. O Cr Cr O
– –
O O
Cr – O Bond  2
Cr = O Bond  6
44. (1.00)
45. 2.49 or 2.50

Sol. [AgNO3]0 = 0.05 mole / L
[NaBr]0 = 0.005 mole / L
[NaCl]0 = 0.005 mole / L
Assume : AgNO3 + NaBr  AgBr (s) + NaNO3
0.005 0.005 0.005
0.005 moles of solid AgBr in presence of 0.005 moles of [Cl–]
AgBr (s) + Cl–  AgCl(s) + Br–
(5 × 10–3 –x) x
Ksp (AgCl)
= (5 × 10–3) =  
X
3 
Ksp (AgCl)  5 10  x 
x  25 × 10–6 M
= 2.5 × 10–5
JEE-ADVANCED
46. (6.00)
Sol. The product obtained is K2MnO4 hence, the oxidation number of Mn in the product of alkaline
oxidative fusion of MnO2 is 6.
47. (4.00)
48. (1.34)
4x 2
Sol. K= =4  2x(moles of AB) = 1.34
(1  x)(2  x)
49. (58.33)
Sol. 24 carat = 100% gold
100
% of gold in 14 carat = × 14 = 58.33
24
50. (0.33)
51. (D)
52. (B)
53. (D)
54. (C)
QUESTION PAPER FORMAT AND MARKING SCHEME
19. The question paper has three parts: Physics, Mathematics and Chemistry.
20. Each part has three sections as detailed in the following table:
NAME OF THE CANDIDATE :_____________________________________________
ROLL NO. :_______________________
I have read all the instructions I have verified the identity, name and roll number
and shall abide by them of the candidate.
_______________________ ____________________________
Signature of the Candidate Signature of the invigilator

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Time: 3 Hours Maximum Marks: 180

READ THE INSTRUCTIONS CAREFULLY

DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR.

Name of the Candidate Form Number

I have verified all the information filled in by the Candidate.

Signature of the Candidate Signature of the invigilator

CHOOSE WISE TO RISE

4. A block P of mass 4 kg is placed on horizontal rough P

SECTION-II : Integer Value Correct Type

SECTION-III : Matching List Type (4 × 4)(4 × 5)

(1) (2) (3) (4) (5) (6) (7) (8)

(Q) The charge on surface (6) is (2) –2Q

SECTION-II : Integer Value Correct Type

28. A Continuous function f : R  R satisfying the differential equation

then a + b is equal to-

SECTION-III : Matching List Type (4 × 4)(4 × 5)

35. Match the list.

(A) (B) (C) (D) O

40. Which of the following metal carbonate is/are thermally stable ?

SECTION-II : Integer Value Correct Type

this classical SN2 mechanism, the % of (R)-2-iodobutane in final product mixture is :

49. Percentage of gold in 14 carat gold is :

SECTION-III : Matching List Type (4 × 4)(4 × 5)

52. Match the following :

54. For the given endothermic reaction

effect effect effect effect

SOLUTION | PART-I : PHYSICS | ENTHUSE-ALL_SCORE-1

  (a 2x2  b2 )dx   (ax2  b)dx

0  [x] + 1 < 2 – 1  [x] < 1

(R) use king property, we get

(Q) Given curve can be rewritten as y = Asinx + Bsin3x + C.e2x

log  e log bx  log x log  e log bx 

It passes through (1, 2)

45. 2.49 or 2.50

NAME OF THE CANDIDATE :_____________________________________________

ROLL NO. :_______________________

and shall abide by them of the candidate.

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