Cossack - Summary Crude Oil Assay Report

Source of Sample Light Hydrocarbon Analysis Assay Summary / TBP Data

Reference: M17COS1 H2S* ppm wt - Gravity (°API) 48.8

Methane %wt 0.00 Sulphur (%wt) 0.03
Name: Cossack Ethane %wt 0.02
Propane %wt 0.64 Yield on Crude %wt %vol
Origin: Australia Isobutane %wt 0.64 Gas to C4 3.40 4.70
n-Butane %wt 2.03 Light Distillate to 149°C 35.70 38.85
Sample Date: 10/5/2016 Isopentane %wt 1.89 Kerosene 149 - 232°C 20.90 20.65
n-Pentane %wt 2.49 Gas Oil 232 - 369°C 25.70 23.45
Comments: Cyclopentane %wt 0.16 Vacuum Gas Oil 369°C - 550°C 12.65 11.05
C6 paraffins %wt 5.17 Residue above 550°C 1.65 1.30
C6 naphthenes %wt 2.98
Benzene %wt 0.03 Volume expansion: 0.4 per cent vol
*Dissolved in liquid on crude distributed across whole distillation

Cut Data Crude Distillates Residues

Light
Light Light Gas Heavy Vacuum Heavy Vacuum Gas
Naphtha Heavy Naphtha Kero Oil Gas Oil Gas Oil Oil AtRes VacRes
Start (°C API) IBP C5 95 149 175 232 342 369 509 550 369 509 550 585
End (°C API) FBP 95 149 175 232 342 369 509 550 585 FBP FBP FBP FBP

Yield on crude (% wt) 100 16.20 19.55 8.65 12.30 21.85 3.85 11.50 1.10 0.60 14.30 2.80 1.65 1.05
Yield on crude (% vol) 100 18.50 20.35 8.75 11.90 20.00 3.45 10.15 0.95 0.50 12.35 2.20 1.30 0.80
Density at 15°C (kg/litre) 0.7844 0.6810 0.7504 0.7710 0.8045 0.8539 0.8766 0.8879 0.9441 0.9767 0.9049 0.9829 1.0108 1.0319

Total Sulphur (% wt) 0.03 <0.001 0.001 0.001 0.002 0.032 0.097 0.095 0.184 0.25 0.13 0.277 0.34 0.393
Mercaptan Sulphur (ppm wt) 2 2 2 2 2 2 - - - - - - - -
Total Nitrogen (ppm wt) 180 0 0 0.1 0.3 13 150 600 2400 3300 1200 3800 4800 5600
Basic Nitrogen (ppm wt) 57.2 - - - - 9 56 205 570 840 371 1064 1398 1724
Acidity (mgKOH/g) 0.04 0.001 0.005 0.011 0.017 0.02 0.03 0.03 0.05 0.06 0.04 0.07 0.08 0.08

Viscosity at 20°C (cSt) 1.664 - - - - - - - - - - - - -

Viscosity at 30°C (cSt) 1.432 - - - - - - - - - - - - -
Viscosity at 40°C (cSt) 1.249 - - - 1.344 - - - - - - - - -
Viscosity at 50°C (cSt) 1.103 - - - - 2.734 7.065 - - - - - - -
Viscosity at 60°C (cSt) - - - - 1.043 - - 16.17 183.9 701.7 24.59 - - -
Viscosity at 100°C (cSt) - - - - - 1.299 2.552 5.653 31.45 82.04 7.724 136.3 542 7661
Viscosity at 120°C (cSt) - - - - - - - - - - 5.134 59.18 186.6 1683
Viscosity at 150°C (cSt) - - - - - - - - - - - 22.8 55.68 304.1

Paraffins (%wt) - 72.67 40.97 54.73 - - - - - - - - - -

Naphthenes (%wt) - 27.15 52.62 31.92 - - - - - - - - - -
Aromatics (%wt) - 0.18 6.41 13.36 - 27.9 - - - - - - - -
n-Paraffins (%wt) - 31.43 23.64 32.40 - - - - - - - - - -
Research Octane Number - 67 50 - - - - - - - - - - -

Smoke Point (mm) - - - - 24.9 16.2 - - - - - - - -

Aromatics (%vol) - - - - 15.3 24.1 - - - - - - - -
Naphthalenes (%wt) - - - - 1.56 10.59 - - - - - - - -

Pour Point (°C) -24 - - - - -15 18 39 - - 39 57 66 75

Cloud Point (°C) - - - - - -12 19 - - - - - - -
Freeze Point (°C) - - - - -46.0 -9.0 - - - - - - - -

Cetane Index ASTM D4737-90 - - - - 44.1 49.0 62.1 - - - - - - -

Refractive index at 70°C - - - - 1.4269 1.4526 1.4654 1.4757 1.5100 - - - - -
Aniline Point (°C) - - - - - - 82.6 94.3 101.8 102.8 - - - -

Wax (%wt) 6.0 - - - 0.0 5.6 25.8 29.4 20.0 15.6 26 14.2 10.2 7.1
Carbon Residue (%wt) 0.3 - - - - - - 0.02 1.76 5.81 2.27 11.6 18.2 25.4
Asphaltenes (%wt) 0.05 - - - - - - - - - 0.3 1.6 2.5 3.5

Vanadium (ppm wt) <2 - - - - - - - - - <1 4 6 9

Nickel (ppm wt) <2 - - - - - - - - - 3 14 23 35
Iron (ppm wt) <1 - - - - - - - - - 2 12 20 30

The information in this assay was prepared by BP Oil International Limited. It is for information purposes only and we are not soliciting or suggesting any action based upon it. While this material is based
upon information that we consider reliable, nevertheless it may not be accurate or applicable to the circumstances of any particular case. We cannot accept any liability for any loss arising from the use of this
information and any inaccuracies, errors or omissions in this assay.

This assay is © BP Oil International Limited. None of the material in this assay is to be incorporated or distributed in any work or publication in any form without the prior written consent of BP Oil International
Limited.
Cossack - TBP Data Summary

TBP Cut point API (°C) 50 55 60 65 70 75 80 85 90 95

Total distillate (%wt) 8.0 8.0 8.3 10.5 13.1 14.4 14.4 16.4 16.8 19.5
Total distillate (%vol) 10.5 10.5 10.7 13.4 16.4 17.7 17.8 19.8 20.3 23.2

TBP Cut point API (°C) 100 105 110 115 120 125 130 135 140 145
Total distillate (%wt) 22.1 26.7 27.1 27.6 30.0 32.1 34.3 35.7 36.8 38.5
Total distillate (%vol) 26.1 30.8 31.2 31.7 34.2 36.4 38.8 40.2 41.2 43.0

TBP Cut point API (°C) 150 155 160 165 170 175 180 185 190 195
Total distillate (%wt) 39.1 42.4 43.8 45.2 46.5 47.7 48.8 49.8 50.8 51.8
Total distillate (%vol) 43.6 47.1 48.5 49.8 51.1 52.3 53.4 54.4 55.4 56.3

TBP Cut point API (°C) 200 205 210 215 220 225 230 235 240 245
Total distillate (%wt) 52.8 53.8 54.9 56.0 57.1 58.3 59.5 60.7 61.9 63.1
Total distillate (%vol) 57.3 58.3 59.3 60.4 61.5 62.6 63.8 64.9 66.1 67.2

TBP Cut point API (°C) 250 255 260 265 270 275 280 285 290 295
Total distillate (%wt) 64.3 65.5 66.7 67.8 68.9 70.0 71.1 72.1 73.0 74.0
Total distillate (%vol) 68.3 69.4 70.5 71.5 72.5 73.5 74.5 75.4 76.3 77.1

TBP Cut point API (°C) 300 305 310 315 320 325 330 335 340 345
Total distillate (%wt) 74.9 75.8 76.7 77.5 78.4 79.2 80.0 80.8 81.5 82.3
Total distillate (%vol) 78.0 78.8 79.6 80.4 81.1 81.8 82.6 83.3 84.0 84.6

TBP Cut point API (°C) 350 355 360 365 370 375 380 385 390 395
Total distillate (%wt) 83.0 83.8 84.5 85.2 85.8 86.5 87.1 87.8 88.4 89.0
Total distillate (%vol) 85.3 85.9 86.6 87.2 87.8 88.4 88.9 89.5 90.0 90.6

TBP Cut point API (°C) 400 410 420 430 440 450 460 470 480 490
Total distillate (%wt) 89.5 90.6 91.6 92.6 93.4 94.2 94.9 95.5 96.0 96.5
Total distillate (%vol) 91.1 92.0 92.9 93.8 94.5 95.2 95.8 96.3 96.8 97.2

TBP Cut point API (°C) 500 510 520 525 530 540 550 600 650 700
Total distillate (%wt) 96.9 97.3 97.6 97.7 97.9 98.1 98.3 99.1 99.6 99.8
Total distillate (%vol) 97.5 97.8 98.1 98.2 98.3 98.5 98.7 99.4 99.7 99.9

The information in this assay was prepared by BP Oil International Limited. It is for information purposes only and we are not soliciting or suggesting any action
based upon it. While this material is based upon information that we consider reliable, nevertheless it may not be accurate or applicable to the circumstances of any
particular case. We cannot accept any liability for any loss arising from the use of this information and any inaccuracies, errors or omissions in this assay.

This assay is © BP Oil International Limited. None of the material in this assay is to be incorporated or distributed in any work or publication in any form without the
prior written consent of BP Oil International Limited.
TBP Cut point API (°C) Total distillate (%wt) Total distillate (%vol)
50 8 10.5
55 8 10.5 Total distillate (%vol)
60 8.3 10.7
800
65 10.5 13.4
70 13.1 16.4
75 14.4 17.7
80 14.4 17.8
85 16.4 19.8 700
90 16.8 20.3
95 19.5 23.2
100 22.1 26.1
105 26.7 30.8 600
110 27.1 31.2
115 27.6 31.7
120 30 34.2
125 32.1 36.4
130 34.3 38.8 500
135 35.7 40.2
140 36.8 41.2
145 38.5 43

TBP, °C
150 39.1 43.6 400
155 42.4 47.1
160 43.8 48.5
165 45.2 49.8
170 46.5 51.1
300
175 47.7 52.3
180 48.8 53.4
185 49.8 54.4
190 50.8 55.4
195 51.8 56.3 200
200 52.8 57.3
205 53.8 58.3
210 54.9 59.3
215 56 60.4 100
220 57.1 61.5
225 58.3 62.6
230 59.5 63.8
235 60.7 64.9
0
240 61.9 66.1 0 10 20 30 40
245 63.1 67.2
250 64.3 68.3 %
255 65.5 69.4
260 66.7 70.5
265 67.8 71.5
270 68.9 72.5
275 70 73.5
280 71.1 74.5
285 72.1 75.4
290 73 76.3
295 74 77.1
300 74.9 78
305 75.8 78.8
310 76.7 79.6
315 77.5 80.4
320 78.4 81.1
325 79.2 81.8
330 80 82.6
335 80.8 83.3
340 81.5 84
345 82.3 84.6
350 83 85.3
355 83.8 85.9
360 84.5 86.6
365 85.2 87.2
370 85.8 87.8
375 86.5 88.4
380 87.1 88.9
385 87.8 89.5
390 88.4 90
395 89 90.6
400 89.5 91.1
410 90.6 92
420 91.6 92.9
430 92.6 93.8
440 93.4 94.5
450 94.2 95.2
460 94.9 95.8
470 95.5 96.3
480 96 96.8
490 96.5 97.2
500 96.9 97.5
510 97.3 97.8
520 97.6 98.1
525 97.7 98.2
530 97.9 98.3
540 98.1 98.5
550 98.3 98.7
600 99.1 99.4
650 99.6 99.7
700 99.8 99.9
Total distillate (%vol) Total distillate (%wt) %V %W TBP, °C SG
10.5 8.0 50 0.5976
16.4 13.1 70 0.6780
26.1 22.1 100 0.7278
34.2 30.0 105 0.7650
43.0 38.5 145 0.7577
49.8 45.2 165 0.7729
60.4 56.0 215 0.7992
69.4 65.5 255 0.8280
78.0 74.9 300 0.8574
84.0 81.5 340 0.8628
92 90.6 410 0.8923
98.1 97.6 520 0.9001

SG = 0.7844

20 30 40 50 60 70 80 90 100

% Dest.
VABP
Pendiente de la Curva ASTM
%en Vol Temp ºC Temp ºf
T10 190.83 375.494 SL 0.6021
T30 196.29 385.322
T50 204.12 399.416
T70 210.95 411.71
T90 217.59 423.662

VABP ºc 203.956

VABP ºf 399.1208 p60 0.7844 g/cm3

WABP ºf 400.05046514775 pw60 0.99907 g/cm3
MABP ºf 394.16504792184 SG 0.785130171
MeABP ºf 395.98053394736
MeABP ºR 855.65053394736
MABP ºR 853.83504792184
Kuop 12.091786630973

Masa Molecular Punto de anilina

exp 0.0053207328729 PA 612.9017542 ºR
M 161.73845946633

indicie de refraccion Temperatura Pseudocritica

exp 6.6103708608063 exp 0.533663379
i 0.2623343050537 Tpc 1186.737268 ºR
n 1.4376657814177

Presion Pseudocritica
exp 0.003458155
Ppc 301.3286636 psia

Analisis Cuantitativo

d20 0.7813130340216

Método n.d.m

V -0.0240219226631 < 0
W -0.028245983352 < 0 %S 0.03

%Ca 5.3333418166571
Ra 0.0991784988037
%Cr 28.545211285449
Rt 0.7233099315696
%Cn 23.211869468792
%Cp 71.454788714552
Rn 0.6241314327659

Representacion del crudo en diagrama generalizado

K
TBP, °C %V Acumulado %Vol medio SG 60/60 Tm ºC Tm ºR 10
16.9 0
50 10.5 5.25 0.5976 33.45 551.88 0.820253739
70 16.4 13.45 0.6780 60 599.67 0.843278008
100 26.1 21.25 0.7278 85 644.67 0.863864884
105 34.2 30.15 0.7650 102.5 676.17 0.877711859
145 43.0 38.6 0.7577 125 716.67 0.894897047
165 49.8 46.4 0.7729 155 770.67 0.916831412
215 60.4 55.1 0.7992 190 833.67 0.941162738
255 69.4 64.9 0.8280 235 914.67 0.970706963
300 78.0 73.7 0.8574 277.5 991.17 0.997047961
340 84.0 81 0.8628 320 1067.67 1.022066169
410 92 88 0.8923 375 1166.67 1.052727602
520 98.1 95.05 0.9001 465 1328.67 1.099357752

500 600 700 800 900 1000 1100 1200 1300 140
0.5

0.6

0.7
p60/60

0.8

0.9

1.1

1.2

T(R)
 1.1

1.2

T(R)

%V Acumulado SG 60/60 %Vol medio SG 60/60 %V AcumuladTBP, °C

0 0.5976 0 0.55 0 16.9
10.5 0.5976 5.25 0.597638095 10.5 50
10.5 0.6780 13.1 0.678040678 16.4 70
16.4 0.6780 20.8 0.727793814 26.1 100 0.9000
16.4 0.7278 28.3 0.765032099 34.2 105
26.1 0.7278 39.8 0.757659091 43.0 145
26.1 0.7650 46.4 0.772864706 49.8 165
34.2 0.7650 55.1 0.7992 60.4 215
34.2 0.7577 65.2 0.827977778 69.4 255
43.0 0.7577 71.75 0.857367442 78.0 300 0.8500
43.0 0.7729 82.45 0.86284 84.0 340
49.8 0.7729 86.4 0.892255 92 410
49.8 0.7992 95.06 0.900131148 98.1 520
60.4 0.7992 98.1 0.903
60.4 0.8280
69.4 0.8280
0.8000
69.4 0.8574
78.0 0.8574
78.0 0.8628
84.0 0.8628
84.0 0.8923
92 0.8923
92 0.9001 0.7500
98.1 0.9001

SG
0.7000

0.6500

0.6000
 0.6000

0.5500
0

MeABP
%Vol medio SG 60/60 Tm ºC MeABP K M I
0 0.55 0
5.25 0.5976380952381 33.45 551.88 13.72492392 66.83706997 0.211601789
13.1 0.6780406779661 60 599.67 12.43698254 81.79893369 0.230875646
20.8 0.727793814433 85 644.67 11.86963762 93.55900043 0.244618216
28.3 0.7650320987654 102.5 676.17 11.47287624 101.1664025 0.255510949
39.8 0.7576590909091 125 716.67 11.81134177 113.7163296 0.253794482
46.4 0.7728647058824 155 770.67 11.86276725 130.7258297 0.258518294
55.1 0.7992 190 833.67 11.77631054 151.8919331 0.26630353
65.2 0.8279777777778 235 914.67 11.7238287 182.5620676 0.274564313
71.75 0.8573674418605 277.5 991.17 11.62917918 214.7048507 0.282683526
82.45 0.86284 320 1067.67 11.84537306 255.6175632 0.283336305
86.4 0.892255 375 1166.67 11.79850606 312.1931234 0.290187464
95.06 0.900131147541 465 1328.67 12.21330641 440.6846308 0.288853144
98.1 0.903 ….

500 14
1
450
13.5 0.9
400
13 0.8
350
0.7
12.5
300
0.6
250 12
0.5
200
11.5 0.4
150
11 0.3
100
0.2
10.5
50
0.1
0 10
0 10 20 30 40 50 60 70 80 90 100 0
0 10 20 30
200
11.5 0.4
150
11 0.3
100
0.2
10.5
50
0.1
0 10
0 10 20 30 40 50 60 70 80 90 100 0
0 10 20 30
ln Dw -0.07293081 Dw 0.9296651477
ln Dm 1.600548938 Dm 4.9557520782
ln Dme 1.144307526 Dme 3.1402660526

Presion de Vapor Factor Acéntrico

T 830.7160874 ºR Pr* Err:502

w Err:502
T'b Err:502 ºR

X Err:502 < 0.0013

logP* Err:502
P* Err:502 mmHg

F 0.97067524

T'b Err:502

Metodo n.d.PA

PA 67.35097456
%Ca 11.26460502
%Cn 25.63115648
%Cr 36.8957615
%Cp 63.1042385
 K
11 12 13

0.745685217 0.683544782 0.630964414

0.766616371 0.702731673 0.64867539
0.785331712 0.719887403 0.664511449
0.797919872 0.731426549 0.675162968
0.81354277 0.745747539 0.688382344
0.833483102 0.764026177 0.705254932
0.855602489 0.784302282 0.723971337
0.882460876 0.808922469 0.746697664
0.906407237 0.830873301 0.76695997
0.929151063 0.851721808 0.786204746
0.957025093 0.877273002 0.809790463
0.999416138 0.91613146 0.845659809

1200 1300 1400

K=10
K=11
K=12
K=13
K del crudo
 Curva continua de densidad

0.9000 516.9

0.8500

416.9

0.8000

316.9
0.7500
SG

0.7000
216.9

0.6500

116.9

0.6000
 116.9

0.6000

0.5500 16.9
0 20 40 60 80 100 120

%V

n PA

1.343571238 668.3036915
1.378600594 592.6665252
1.404101722 568.4722917
1.424643567 553.6718126
1.421386697 578.1239656
1.430368072 589.3707494
1.445297315 594.1711857
1.461316478 602.2538992
1.477245554 606.9479827
1.478534365 624.3741942
1.492135398 631.1137415
1.489475731 660.1532293

1400

1200

1000

800

600

400

200

0
0 10 20 30 40 50 60 70 80 90 100
 600

400

200

0
0 10 20 30 40 50 60 70 80 90 100
516.9

416.9

316.9

Escalonada
%Medios
TBP

216.9

116.9
 116.9

16.9
100 120
Trabajo Practico Nº3

Temperatura de Corte Separacion Gap (Fijado)

ASTM Celsius ASTM ºF
NAFTA 170 338 D1 N(L-P) - JP1 40
JP1 240 464 D2 JP1-GOL 10
GAS OIL (liv) 290 554 D3 GOL-GOP 8
GAS OIL (Pes) 340 644 D4 GOP- CR 4

ASTM 100%
TBP 100% ASTM 95% ASTM 5% TBP 0% Tcorte
(ºF)
D1 338 359.3 331.92 349.555
D2 464 487.6 454.76 371.92 339.81 463.61
D3 554 585.1 544.58 464.76 439.62 559.56
D4 644 687.5 635.64 552.58 534.02 657.555
Residuo 639.64 627.61

600

500

400

300

200

100

0
0.0 10.0 20.0 30.0 40.0 50.0 60.0 70.0 80.0 90.0 100.0

Rendimiento Relativo % Rendimientos Acumulado %

0 0
D1 52 52
D2 14 66
D3 11 77
D4 8.5 85.5
Residuo 14.5 100

Extension de las curvas para cada corte

D1 D2
TºC Ideal TºC Real TºC Ideal
0 0 20 20 52 0 176.4194444
5.2 10 35 35 53.4 10 180
15.6 30 68 68 56.2 30 194
26 50 100 100 59 50 208
36.4 70 114 114 61.8 70 219
46.8 90 158 158 64.6 90 230
52 100 176.4194444 181.83333333 66 100 239.7833333

350
X Y
84.65 342

340

400
330
350

320 300

250
310
200

150
300
100

290 50

0
280 0 10 20 30 40 50 60

270
70.0 72.0 74.0 76.0 78.0 80.0 82.0 84.0 86.0 88.0 90.0 Curva real TBP

400

350

300

250

200

150

100
 300

250

200

150

100

50

0
0 10 20 30 40 50 60 7

EJERCICIO Nº2: Determinación de las propiedades de los cortes comerciales

Estimacion de la MeABP

Método analítico, empleando las curvas TBP-ASTM extendidas para cada corte.

D1 D2
ASTM ºc ASTM ºc
T10 59.84 T10 190.83
T30 77.91 T30 196.29
T50 99.88 T50 204.12
T70 109.06 T70 210.95
T90 150.72 T90 217.59

MeABP ºf 197.79976058 MeABP ºf 395.9805339

MeABP ºc 92.1109781 202.2114077

Estimacion de la densidad: Por integración analítica de los datos de densidades del reporte de laboratorio

Corte
%V SG Nafta
10.5 0.5976380952 6.2752 Kerosene
16.4 0.678040678 4.00044 Gas oil L
26.1 0.7277938144 7.0596 Gas oil P
34.2 0.7650320988 6.19676 Residuo
43 0.7576590909 6.6674
49.8 0.7728647059 5.25548 SG crudo
52 0.7992 1.75824
60.4 0.7992 6.71328
 66 0.8279777778 4.636675556
69.4 0.8279777778 2.815124444
77 0.8573674419 6.515992558
78 0.8573674419 0.857367442
84 0.86284 5.17704
85.5 0.892255 1.3383825
92 0.892255
98.1 0.9001311475
Crudo 0.7851301711

Estimación de las propiedades con la curva de densidades instantaneas

Curva de densidad
0.9
Densidad Inst D1
Column N Column N
D2 Column N
Column N D3
Column Q Column Q
0.85
D4 Column Q
Column Q TBP

0.8

0.75
SG

0.7

0.65

0.6

0.55
0 10 20 30 40 50 60 70 80

%V
 0.55
0 10 20 30 40 50 60 70 80

%V

Metodo con las curvas MID%

1 1400

0.95 1300

0.9 1200

0.85 1100

0.8 1000
SG 60/60

0.75 900

0.7 800

0.65 700

0.6 600

0.55 500

0.5 400
0 10 20 30 40 50 60 70 80 90 100

%V

Estimar el valor de K y M para cada corte:

Método MID %

Corte MeABP º R SG K M Exponencial

D1 668 0.76 11.50213768 99.05399879 0.00523497
D2 863 0.81 11.75398809 162.5338934 0.004528289
D3 990 0.855 11.6567894 214.5236773 0.003839957
D4 1055 0.86 11.83729221 248.8172445 0.003993126

Balance de Materia

Producto m3/h ρ(kg/m3) kg/h lb/h mol/h

 Producto m3/h ρ(kg/m3) kg/h lb/h mol/h
Nafta D1 258.3543625 714.97138074 184715.9753 407228.9908 1899712.659
Kerosene D2 69.55694375 809.95714978 56338.14391 124204.3383 353268.5467
Gas oil L D3 54.65188438 847.49446034 46317.16926 102111.8724 232029.9869
Gas oil Pesado D4 42.23100156 866.58038203 36596.55747 80681.59314 149828.5984
Residuo B 72.04112031 912.67005474 65749.77322 144953.4278 439265.4007
Crudo 496.8353125 784.4 389717.6191 859180.2224 3074105.191

75000 BOPD 1Barril =

496.8353125 m3/h 1lb =
M crudo =

ρ60 Agua 999.07 kg/m3

 Tcorte ºc TBP 100% ºc TBP 0% ºc
176.4194444 176.4194444 181.8333333
239.7833333 239.7833333 253.1111111 171.0055556
293.0888889 293.0888889 307.2777778 226.4555556
347.5305556 347.5305556 364.1666667 278.9

0 100
 D3 D4
TºC Real TºC Ideal TºC Real TºC Ideal
171.0055556 66 0 239.7833333 226.4555556 77 0 293.0888889
180 67.1 10 247 247 77.85 10 300
194 69.3 30 256 256 79.55 30 310
208 71.5 50 265 265 81.25 50 318
219 73.7 70 275 275 82.95 70 330
230 75.9 90 288 288 84.65 90 342
253.1111111 77 100 293.0888889 307.2777778 85.5 100 347.5305556

Curva ideal TBP VERIFICADO

D1
ASTM
0 20 55.08
10 35 59.84
30 68 77.91
D1 50 100 99.88
D2 70 114 109.06
D3 90 158 150.72
D4 100 181.8333333 170.06

VERIF 170,06-170
<5,5

20 30 40 50 60 70 80 90 100
D3
ASTM
0 226.4555556 243.12
urva real TBP 10 247 251.11
30 256 254.06
50 265 258.57
70 275 264.65
90 288 272.94
100 307.2777778 289.98

D1
D2
D3
D4
 D1
D2
D3
D4 Curva real ASTM
400

350

300
20 30 40 50 60 70 80 90 100
250

200

150

100

50

0
0 10 20 30 40 50 60 70

D3 D4 Estimar el valor de K y M p
ASTM ºc ASTM ºc
T10 251.11 T10 301.64
T30 254.06 T30 305.06
T50 258.57 T50 308.95
T70 264.65 T70 316.55
T90 272.94 T90 324

MeABP ºf 498.0191285 MeABP ºf 589.8855369

258.8995158 309.9364094

e laboratorio

Rendimiento Densidad
Acumulado
52 0.715636923
66 0.810711111
77 0.848283364
85.5 0.867387052
100 0.913519628

0.7844
 Nafta

516.9 52 0
52 2
0 0.71
52 0.71
18.1 0
18.1 0.71
18.1 76
416.9
100 76
SG 0.71
MeABP ºc 76

316.9
Kerosene JP1

66 0
66 2
52 0.81
216.9 66 0.81
58.9 0
58.9 0.81
58.9 208
100 208
SG 0.81
MeABP ºc 208
116.9

16.9
60 70 80 90 100
 16.9
60 70 80 90 100

1400

1300 Nafta GOL

1200 52 0 77 0
52 1 77 1
V medio 26 V medio 71.5
1100
26 0 71.5 0
26 0.76 71.5 0.855
1000 26 668 71.5 990
100 668 100 990
MeABP ºF

SG 0.76 SG 0.855
900
MeABP ºc 97.96 MeABP ºc 276.85

800

700 Kerosene JP1 GOP

66 0 85.5 0
600
66 1 85.5 1
V medio 59 V medio 81.25
500 59 0 81.25 0
59 0.81 81.25 0.86
400
59 863 81.25 1055
80 90 100 100 863 100 1055
SG 0.81 SG 0.86
MeABP ºc 206.29 MeABP ºc 312.96

%s/c %s/c Acum

 %s/c %s/c Acum
52 52
14 66
11 77
8.5 85.5
14.5 100
100 100

0.1589873 m3
0.4535924 kg
126.7743278
TºC Real
278.9
300
310
318
330
342
364.1666667

D2
ASTM
171.0055556 188.79
180 190.83
194 196.29
208 204.12
219 210.95
230 217.59
253.1111111 236.59

D4
ASTM
278.9 293.25
300 301.64
310 305.06
318 308.95
330 316.55
342 324
364.1666667 342.53
 D1
D2
D3
D4

0 50 60 70 80 90 100

timar el valor de K y M para cada corte:

Método analítico

Corte
MeABP º R SG K M Exponencial
D1 657.4697606 0.715636923 12.15064095 97.23363922 0.007074835
D2 855.6505339 0.810711111 11.71024595 159.4768185 0.004471663
D3 957.6891285 0.848283364 11.61985127 199.6171697 0.003875032
D4 1049.555537 0.867387052 11.71625656 244.2561558 0.003780941
GOL

77 0
77 2
66 0.85
77 0.85
70.2 0
70.2 0.85
70.2 259
100 259
SG 0.85
MeABP ºc 259

GOP

85.5 0
85.5 2
77 0.867
85.5 0.867
83 0
83 0.867
83 333
100 333
SG 0.867
MeABP ºc 333
 V
X Y
100 548

TBP Residuo

520

470
ºC

420

370

320
80.0 82.0 84.0 86.0 88.0 90.0 92.0 94.0 96.0 98.0 100.0
%V

TBP 0% [ºf] TBP 100%[ºf] DT ºf T corte ºf

GOLV 315.6 870 150 795
GOPV 720 1010 160 930
OF 850 1036.5 956.5

Cortes X (redimiento) Y (Temp)

GOLV 0 795
51 795
51 0
GOPV 0 930
80 930
80 0
OF 0 956.5
85 956.5
85 0

GOLV GOPV OF
%Vext %V orig Temp ºF %V orig Temp ºF %V orig Temp ºF
0 0 315.6 51 720 80 850
10 5.1 670 53.9 805 80.5 934
30 15.3 695 59.7 833 81.5 939
 50 25.5 715 65.5 860 82.5 944
70 35.7 740 71.3 888 83.5 949
90 45.9 770 77.1 916 84.5 954
100 51 870 80 1010 85 1036.5

TBP ºf EFV atm 760 mmHg

%V Temp ºf Temp ºC K ºC ºf
0 315.6 157.55555556 666.87 393.72 740.70
10 685.4 363 674.17 401.02 753.84
30 726.8 386 693.33 420.18 788.32
50 788 420 708.68 435.53 815.96
70 881.6 472 717.95 444.80 832.64
90 980.6 527 726.19 453.04 847.48
100 1018.4 548 732.53 459.38 858.88

EFV 760mmHg
1000.00
900.00
800.00
700.00
600.00
500.00
ºF

400.00
300.00
200.00
100.00
0.00
0 10 20 30 40 50 60 70 80 90 100

%V

Diagrama de Fases
1/T
10% 30% 50% 70% 90%
0.00133 0.00127 0.00123 0.00120 0.00118 2.88081
0.00212 0.00200 0.00190 0.00185 0.00181 1.00000

Marcador
X Y
0.0012 2
 TºF P mmHg
833.3333333 100

B 72.0411203125 m3/h 65749.77322 kg/h

Cortes
GOLV GOPV OF
VABP 718 ºF 860.4 ºF 944 ºF
SL 1.25 1.3875 0.25
MeABP 1177.67 ºR 1320.07 ºR 1403.67 ºR
K 11.9009918961 11.9009919 11.9009919
SG 0.887342694 0.921755691 0.940817051
M 321.223863651 425.4490986 499.7265445
exp -5.5623301089 -5.61475707 -5.63321266

Balance

Caudal Vol 36.7409713594 m3/h 20.89192489 m3/h 3.602056016 m3/h

Caudal Masico32601.8325062 kg/h 19257.25066 kg/h 3388.875719 kg/h
Flujo molar 101.492560782 molkg/h 45.26334813 molkg/h 6.781460292 molkg/h

Calculo de la zona flash

Pzf 35 mmHg dato

Tzf 595 ºF dato (Se puede modificar la temperatura, inicia desde 695ºF )

Diagrama de fases
3.00000
2.80000
2.60000 10% 30% 50% 70% 90%
2.40000
2.20000
Log(P)

2.00000
1.80000
1.60000
1.40000
1.20000
1.00000
0.00100 0.00120 0.00140 0.00160 0.00180 0.00200
1/T

Phc 25.1188643151 mmHg

 Fraccion Molar del Hidrocarburo

Xhc 0.7176818376

Despejo nt

nt 60.397777495 molkg/h
n1 18.263825894 molkg/h
n2 42.133951601 molkg/h
nt>n1

OverFlash

TBP ºf EFV atm 760 mmHg

%V Temp ºf Temp ºC K ºC ºf
0 850 454.44444444 778.57 505.42 941.75
10 934 501.11111111 778.81 505.66 942.19
30 939 503.88888889 779.30 506.15 943.06
50 944 506.66666667 779.78 506.63 943.94
70 949 509.44444444 780.27 507.12 944.82
90 954 512.22222222 780.76 507.61 945.69
100 1036.5 558.05555556 765.89 492.74 918.93

Diagrama de fases OF
3
2.8
2.6 0%
2.4
2.2
Log(P)

2
1.8
1.6
1.4
1.2
1
0.001 0.0011 0.0012 0.0013 0.0014 0.00
1/T
 1/T Marcador
0.00106185428 2.8808135923 log(760) X Y
0.00157198216 1 log(10) 0.001474926 1.347293649

TºF P mmHg
678 22.24813696

tof 678 ºF

Residuo extendida TBP

900
GOLV + GOPV
%Vext %V orig Temp ºF 800
0 0 315.6
10 8 690 700
30 24 715
50 40 760

T ºF
600
70 56 812
90 72 890 500
100 80 1010
400

300
Marcador 0 10 20 30 40 50
X Y
%V
72 890

EFV atm 760 mmHg

K ºC ºf
665.52 392.37 738.26
669.16 396.01 744.81
679.42 406.27 763.29
685.87 412.72 774.89
691.01 417.86 784.15
698.29 425.14 797.26
701.93 428.78 803.81

Diagrama de fase GOPV+GOLV

1.35

1.3
100%
1.25

1.2
Log(P)

1.15

1.1

1.05
 1.3
100%
1.25

1.2

Log(P)
1.15

1.1

1.05

1
0.00125 0.00135 0.00145 0.00155 0.00165 0.00175 0.00185
1/T

1/T Marcador
0.00124407509 2.8808135923 log(760) X Y
0.00194380234 1 log(10) 0.001821494 1.327424185

TºF P mmHg
Tl 549 21.25319295

Pent 31 mmHg 0.5994408 psia Tzf 595

Psal 30 mmHg 0.580104 psia Tof 678
Tl 549

Entrada H
Entrada=suma(corriente*entalpia
GOLV 32601.8325062 kg/h 71874.7374 lb/h 470.69 BTU/lb
GOPV 19257.2506639 kg/h 42454.97041 lb/h 486.445 BTU/lb
OF 3388.8757189 kg/h 7471.192066 lb/h 511.47 BTU/lb
H20 1087.15999491 kg/h 2396.777516 lb/h 1334.08 BTU/lb

kg 2.20462262 lb

Salida
Salida=suma(corriente*entalpia)
GOLV 32601.8325062 kg/h 71874.7374 lb/h 461.2936295 BTU/lb
GOPV 19257.2506639 kg/h 42454.97041 lb/h 471.3146756 BTU/lb
OF 3388.8757189 kg/h 7471.192066 lb/h 452.4210549 BTU/lb
H20 1087.15999491 kg/h 2396.777516 lb/h 1312.1 BTU/lb
 Tr1 577.5 ºF
EFV atm 760 mmHg
htr1 387.665 BTU/lb
K ºC ºf
Q 1811566.31686 BTU/h 722.67 449.52 841.13

Reflujo 21656.5850838 lb/h

50.9028815756 mollb/h
23.0891587131 molkg/h 1/T
0.001188877 2.880813592
0.001828028 1
Xhc 0.73767793973
Phc 19.179626433 mmHg

Pt 26 mmHg

Diagrama de fases GOPV

1.4
1.38
0%
1.36
1.34
1.32
Log(P)

1.3
1.28
1.26
1.24
1.22
1.2
0.0017 0.00171 0.00172 0.00173 0.00174
1/T

Verificacion de Trl Diagrama de

1.5

Pt 30 mmHg
1.45
Xhc 0.7376779397
Phc 22.130338192 mmHg
1.4
Log(P)

1.35

1.3

1.25

1.2
0.00175 0.00176 0.00177 0.00178 0.00179
 Log(P)
1.35

1.3

1.25

1.2
0.00175 0.00176 0.00177 0.00178 0.00179

El nuevo valor de Tl es: 550.75 ºF

Al comparar este nuevo valor de Tl con el obtenido anteriormente se

aprecia que la diferencia de temperaturas es despreciable; el cálculo
finaliza en este aqui.
 Vacio

Residuo %V TºC ideal TºF ideal %V TºF

0 315.6
85.5 0 352 665.6 5 665.6
86.95 10 363 685.4 10 685.4
89.85 30 386 726.8 30 726.8
92.75 50 420 788 50 788
95.65 70 472 881.6 70 881.6
98.55 90 527 980.6 90 980.6
100 100 548 1018.4 100 1018.4

Balance

Residuo extendida TBP

1050 GOLV
950 GOLP
OF
850 Residuo
750 Crudo
Reducido
650
T ºF

550

450

350

250
0 10 20 30 40 50 60 70 80 90 100
%V

Marcador
X Y
84.5 954
 Correlacion de Maxwell y Bonnel
EFV a 10 mmHg

Q F T`b Temp K Temp ºc Temp ºf

0.00 2.70 666.18 510.89 237.74 459.92
0.00 2.77 673.45 517.16 244.01 471.22
0.00 2.94 692.57 533.71 260.56 501.00
0.00 3.08 707.89 547.06 273.91 525.03
0.00 3.16 717.13 555.15 282.00 539.60
0.00 3.24 725.36 562.38 289.23 552.61
0.00 3.29 731.67 567.94 294.79 562.62

EFV 10mmHg
600.00

500.00

400.00

300.00
ºF

200.00

100.00

0.00
0 10 20 30 40 50 60 70 80 90 100

%V

Diagrama de Fase del crudo Reducido

3.00000
Log(760) 2.80000
Log(10)
2.60000 10% 30% 50% 70%
2.40000
2.20000
Log P

2.00000 0 2.880813592
1.80000 0.0025 2.880813592
1.60000
1.40000
1.20000
1.00000
0.00100 0.00120 0.00140 0.00160 0.00180 0
 2.20000

Log P
2.00000
1.80000
1.60000
1.40000
1.20000
1.00000
0.00100 0.00120 0.00140 0.00160 0.00180 0
1/T

Residuo de fondo

1547.131879 R MeABP = a VABP por ser SL<2%

11.9009919 K = K de la alimentacion
0.971835186
655.4989804
-5.6461364

10.80616805 m3/h
10501.81433 kg/h
16.02109941 molkg/h

atura, inicia desde 695ºF )

Marcador
X Y
0.001680672 1.4

30% 50% 70% 90%

TºF P mmHg
595 25.11886432

0.00180 0.00200 0.00220

 nt: moles de agua
nhc: moles de hidrocarburo vaporizado

Correlacion de Maxwell y Bonnel

EFV a 10 mmHg

Q F T`b Temp K Temp ºc Temp ºf

0.002 3.71 777.61 608.78 335.63 636.14
0.002 3.71 777.85 609.00 335.85 636.53
0.002 3.72 778.34 609.44 336.29 637.32
0.002 3.72 778.82 609.87 336.72 638.10
0.002 3.72 779.31 610.31 337.16 638.89
0.002 3.73 779.79 610.74 337.59 639.67
0.002 3.59 764.96 597.47 324.32 615.77

Kup 11.9009919

OF

0%

0.0014 0.0015 0.0016

Fraccion Molar del Hidrocarburo

Xhc 0.717681838
Phc 22.24813696 mmHg
 Pt 31 mmHg

Residuo extendida TBP

20 30 40 50 60 70 80
%V

Correlacion de Maxwell y Bonnel

EFV a 10 mmHg

Q F T`b Temp K Temp ºc Temp ºf

0.00 2.69 664.82 509.72 236.57 457.83
0.00 2.72 668.45 512.84 239.69 463.45
0.00 2.82 678.69 521.68 248.53 479.36
0.00 2.87 685.12 527.25 254.10 489.38
0.00 2.92 690.26 531.70 258.55 497.39
0.00 2.99 697.52 538.02 264.87 508.76
0.00 3.02 701.15 541.18 268.03 514.46

Fraccion Molar del Hidrocarburo

00% Xhc 0.708439765

Phc 21.25319295 mmHg

Pt 30 mmHg
00%

0.00175 0.00185

VABP
SL
MeABP
K
SG
ºF M
ºF exp
ºF

Entrada=suma(corriente*entalpia)
61501511.78 BTU/h

Salida=suma(corriente*entalpia)
59689945.47 BTU/h
 Correlacion de Maxwell y Bonnel
EFV a 10 mmHg

Q F T`b Temp K Temp ºc Temp ºf

0.00 3.21 721.84 559.28 286.13 547.04

Marcador
log(760) X Y
log(10) 0.001731602 1.282840144

TºF P mmHg
577.5 19.17962643

GOPV

0%

0.00173 0.00174 0.00175

Diagrama de fases GOLV+GOPV

Marcador
X Y
0.001815706 1.344988051
100%

TºF P mmHg
550.75 22.13033819

0.00176 0.00177 0.00178 0.00179 0.0018 0.00181 0.00182 0.00183 0.00184 0.00185
1/T
0.00176 0.00177 0.00178 0.00179 0.0018 0.00181 0.00182 0.00183 0.00184 0.00185
1/T
 Autores:
Suyo Matías
Viveros Lautaro

Balance de Materia

Flujo Vol
m3/h
%SC acum %SC
51 51 36.74097136
80 29 20.89192489
85 5 3.602056016
100 15 10.80616805
100 72.04112031

0.001952262

0.001955991
 0.001983461

K= 11.9009919

ucido

30% 50% 70% 90%

0.00180 0.00200 0.00220

0.00180 0.00200 0.00220
0.001952262

0.001955991

0.001983461

K= 11.9009919
0.001952262

0.001955991

0.001983461

K= 11.9009919
 GOLV+GOPV
773.4 ºF
2.5 ln Dme 2.414798382 Dme 11.18751453
1221.882485 ºR
11.9009919 MeABP 762.2124855
0.898310868
350.8977873
-5.58162978