CFD Modeling of Multiphase Reacting Flow in Blast Furnace Shaft With Layered Burden

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Applied Thermal Engineering 66 (2014) 298e308

Contents lists available at ScienceDirect

Applied Thermal Engineering


journal homepage: www.elsevier.com/locate/apthermeng

CFD modeling of multiphase reacting flow in blast furnace shaft with


layered burden
Dong Fu a, Yan Chen a, Yongfu Zhao b, John D’Alessio c, Kyle J. Ferron c, Chenn Q. Zhou a, *
a
Center for Innovation through Visualization and Simulation, Purdue University Calumet, 2200 169th Street, Hammond, IN 46323, USA
b
United States Steel Corporation, Research and Technology Center, 800 East Waterfront Drive, Munhall, PA 15120, USA
c
U.S. Steel Canada, Hamilton Works, 530 Gage Avenue North, Canada

h i g h l i g h t s g r a p h i c a l a b s t r a c t

 A novel methodology is proposed to


efficiently model the blast furnace
shaft with layered burden.
 The effects of layered burden on flow,
heat transfer, and chemical reactions
are considered in the model.
 The shape and location of the cohe-
sive zone is determined by an itera-
tive method.

a r t i c l e i n f o a b s t r a c t

Article history: The ironmaking blast furnace is a counter-current chemical reactor which includes the ascending gas
Received 15 November 2013 flow and the counter-current descending porous bed (burden). A Computational Fluid Dynamics (CFD)
Accepted 28 January 2014 model has been developed to simulate the multiphase reacting flow in blast furnace shaft. The gas flow
Available online 13 February 2014
dynamics, burden movement, chemical reactions, heat and mass transfer between the gas phase and
burden phase are included in the CFD model. The blast furnace burden consists of alternative layers of
Keywords:
iron ore and coke. A novel methodology is proposed to efficiently model the effects of alternative burden
Blast furnace
layer structure on gas flow, heat transfer, mass transfer and chemical reactions. Different reactions and
Shaft
Layered structure
heat transfer characteristics are applied for difference types of layer. In addition, the layered CFD model
Burden accurately predicts the Cohesive Zone (CZ) shape where the melting of solid burden taking place. The
CFD shape and location of the CZ are determined by an iterative method based on the ore temperature
distribution. The theoretical formation and the methodology of the CFD model are presented and the
model is applied to simulate industry blast furnaces. The proposed method can be applied to investigate
the blast furnace shaft process and other moving bed system with periodic burden structure
configuration.
Ó 2014 Elsevier Ltd. All rights reserved.

1. Introduction

The ironmaking blast furnace is regarded as the largest energy


consumption metallurgical reactors to produce iron. The blast
* Corresponding author. Tel.: þ1 219 989 2665. furnace is a counter-current moving bed reactor where the iron ore
E-mail addresses: dfu@purdue.edu, fudong1985@gmail.com (D. Fu), chen180@
purdue.edu (Y. Chen), yzhao@uss.com (Y. Zhao), JDAlessio@uss.com (J. D’Alessio),
and coke are charged from the top to form the burden and the hot
KJFerron@uss.com (K.J. Ferron), czhou@purduecal.edu (C.Q. Zhou). gas is generated at lower combustion zone. The blast furnace

http://dx.doi.org/10.1016/j.applthermaleng.2014.01.065
1359-4311/Ó 2014 Elsevier Ltd. All rights reserved.
D. Fu et al. / Applied Thermal Engineering 66 (2014) 298e308 299

efficiency is directly depended on the heat and mass transfer to the 2.2. Governing equations
ascending gas and descending burden. Due to the complicated
phenomenon and difficulties indirect measurement, numerical In the mathematical model, the ascending gas is described as
models have been applied to simulate and understand the multi- the gas phase and the descending burden is treated as the burden
phase reacting flow inside the blast furnace [1e15]. phase (ore and coke). The burden phase is defined as the gross bed,
In general, discrete and continuum models are the two major i.e. the combination of the solid and liquid [1,10]. As state in
approaches to model the blast furnace moving bed. The Discrete assumption 1, the governing equations for the gas phase are quasi-
Element Method (DEM) is applied to describe each individual ore steady state. The general transport equation for gas phase is given
and coke particle of the layered burden [14,15]. With coupling with as Eq. (1).
the CFD for the gas phase, such simulation reveals the detail of the
   
gas and particle behavior. However, it is computationally expensive !
V$ rg u g Bg ¼ V$ Gg VBg þ Sg (1)
due to the fact that blast furnace is a dense moving bed and the
transient simulation is needed for DEM model [15]. On the other For the solid phase, the diffusion term is zero because the
hand, the continuum approach assumes that the solid burden transport of the solid phase properties is solely by convection (the
behave like a continuum medium. The existing blast furnace con- movement of the burden). The general transport equation for
tinuum models [3e8,10,12,13] treat the layered burden as a ho- burden phase is given as Eq. (2). The detailed conservation equa-
mogenous mixture of coke and ore. Therefore, the effects of layer tions for gas phase and burden phase are expressed in Table 1. Two
thickness may not be reflected in the homogenous treatment for individual energy equations are used for the ore and coke due to the
the burden. Kuwabara et al. [11] developed a 1D model that takes heat transfer and reactions are different in coke and ore layer.
consideration of the layer structure and showed the effects of layer
structure on gas distribution. The model neglects the variation in !
V$ðrs u s Bs Þ ¼ Ss (2)
the furnace radius direction. In addition, the model assumed the
coke temperature and ore temperature is the same therefore used The gas flow through granular burden is described by Ergun
one energy equation for the combination of coke and ore. type equation [17]. The potential flow model is adopted to describe
The coke and ore are alternately charged into the blast furnace the burden movement [1,4,9,10]. The mass conservation equation
to form a layered burden. The layer thickness is ranged from 0.2 to and momentum equation for the gas phase are combined to solve
0.8 m. The layer structure of the burden maintains up to the CZ and the pressure in the Poisson type equation as Eq. (3). Then the ve-
liquid iron and coke co-exists below the CZ. Usually there are about locity is obtained by substituting the pressure into the momentum
30e60 layers of alternative coke layer and iron ore layer above the equation. Similarly, the same treatment is applied for the burden
cohesive in blast furnace. The layer structure of the burden is phase as Eq. (4). The coefficient Ks is the relative speed factor
important for furnace operation in the following aspects. First, the ranging from zero to unity.
permeability differs significantly in the coke layer and ore layer.
 
Second, different reactions are taken place for each type of layer, V$ rg Kg Vp ¼ mog
_ þ mcg
_ (3)
i.e., the reduction (FeyOx þ CO / Fe þ CO2) takes place in iron ore
layer and the coke gasification (C þ CO2 / 2CO) takes place in coke
layer. The reaction rates are directly related to the temperature of V$ðrs Ks Fs Þ ¼ mog
_  mcg
_ (4)
the individual layer. Pervious model assumed the ore and coke
share the same temperature. The heat transfer and reaction heat Because of the reaction heat and convective heat transfer differ
are also differs from coke layer and ore layer. At last, the ore layer in the coke layer and ore layer, two energy conservation equations
melts and becomes impermeable in the CZ so the coke layer is the are used, for coke and ore, respectively. The consideration of the
only path that the gas can flow through. Dong et al. [2] concluded burden structure on gas flow, heat transfer and chemical reactions
that the layered CZ treatment may provide a better overall picture are detailed in Section 2.4.
of steady blast furnace operation in terms of the permeability The boundary conditions are schematically shown in Fig. 1. At
prediction. the furnace top, the top gas pressure Ptop is set as a fixed value. The
burden velocity distribution vs(r) along the radius is specified. The
2. Model description gradient of the gas enthalpy Hg and species mass fraction Yi are
assumed to be zero at the top outlet. The enthalpy of the ore Ho,top
2.1. Model assumptions and simplifications and the enthalpy of the coke Hc,top are set according to the charging
material temperature. The concentrations of the burden Zo,j,top and
The following assumptions are made to derive the mathematic Zc,j,top along the radius are obtained by combining the burden dis-
model. tribution and total charge rate. At the furnace bottom, the gas ve-
locity, species mass fraction and gas enthalpy along the radius are
1. The quasi-steady state approximation is assumed for the mapped from the raceway model results [18]. The gradient of the
ascending gas phase due to the relative slow motion of the coke enthalpy, ore enthalpy and burden composition is set as zero.
burden to the gas. It takes about 5 h for the burden to decent At the furnace side wall, the heat loss from the furnace shell is
from the top to the bottom of the furnace but 2e3 s for the gas to specified via the convection boundary condition where Tg is the gas
flow from the bottom to the top [16]. temperature and TN is the cooling water temperature (300 K). The
2. The interface between the ore layer and coke layer is assumed effective heat transfer coefficient hg includes the convection be-
thin so that the mix layer is neglected. tween the hot gas and the refractory, the conduction within the
3. The layer structures remain until reaches the CZ lower refractory, the conduction within the stave cooler, and the con-
boundary. vection between the stave material and the cooling water. The
4. The layer volume maintains constant during burden actual value of hg is difficult to determine analytically due to the
descending. complicated gas flow pattern and the erosion profile of the re-
5. The particles are connected in point so that the heat conduction fractory. Therefore, hg value is adjusted until the calculated total
between burden particles is neglected. heat flux matches with the measured value. The gradient of all
300 D. Fu et al. / Applied Thermal Engineering 66 (2014) 298e308

Table 1
Governing equations for gas and burden phase.

Gas Burden

Ore Coke
! !
Mass V$ðrg ug Þ ¼ mog _
_ þ mcg V$ðrs us Þ ¼ mog
_  mcg
_
! !
Momentum Kg Vp ¼ ug Ks VFs ¼ us
 
r ju j 1
Kg ¼ ma þ C2 g 2 g
150ðjj dj Þ2 ε3j 3:5ð1ε Þ
a ¼ C2 ¼ ðj d Þε3j
ð1εj Þ2 j j j
  ! !
Energy ! k
V$ðrg ug Hg Þ ¼ V$ g;Cpeff VHg þ SgH V$ðro us Ho Þ ¼ SoH V$ðrc us Hc Þ ¼ ScH
! ! !
Chemical species V$ðrg ug Yi Þ ¼ V$ðDi; eff VYi Þ þ SgY;i V$ð us Zo;j Þ ¼ SoZ;j V$ð us Zc;j Þ ¼ ScZ;j

variables on the central axis are set to zero for the axisymmetric kinetically, a combination of reaction (3) and reaction (7) or a
configuration. combination of reaction (6) and reaction (8). The Boudouard reac-
tion going to the right is also known as the endothermic gasifica-
2.3. Chemical reactions and interphase exchange tion of carbon or the solution-loss reaction. The unreacted core
model [20] is utilized to model the coke reaction (7) and (8). Due to
The major chemical reactions in an ironmaking blast furnace are the high porosity of the coke particle, the diffusion resistance is
mainly gasesolid reactions as listed in Table 2. The following re- neglected. The flux decomposition reaction (8) is greatly dependent
actions, including nine gasesolid reactions and two phase trans- on the decomposition pressure. The unreacted core model is also
formations are considered in the model. Two models are included applied to the flux decomposition reaction [21].
in the CFD code for the indirect reduction reactions (1e6). The first The heat transfer between the gas and burden is described as Eq.
mode is the unreacted shrinking core (URC) model as the expres- (6) and the heat transfer coefficient proposed by Wakao et al. [22]
sion of single-pellet reaction kinetics [19]. The reduction of iron ore are used to account the porous bed effects on the heat transfer
proceeds via the successive steps Fe2O3 / Fe3O4 / FeO / Fe. The coefficient of a single particle. Rej is the particle Reynolds number
URC model assumes that the reduction of an iron oxide sphere based on particle diameter and superficial gas velocity.
occurs at the surface with the formation of an outer shell of metallic  
SgH ¼ n_ j hj Aj Tj  Tg (5)
iron. The shell grows in the radial direction until the entire oxide is
completely reduced to iron.
Blast furnace coke undergoes three main reactions in the shaft. hj dj 1=3
¼ 2 þ 1:1Re0:6
j Prg valid for 3 < Rej < 104 (6)
These are the Boudouard reaction (7), the wateregas reaction (8) kg
and the direct reduction reaction (C þ FeO / Fe þ CO) which is,

2.4. Burden layer structure consideration

The ore and coke is charged alternatively to form the layered


burden. The new layer will be charged as the burden slowly de-
scends due to the melting of reduced ore and consumption of the
coke in the lower part of the blast furnace. As the burden descents
and materials been recharged from the top. The layer structure
changes periodically during each charging cycle. At any fixed
location of the furnace, the descending of the burden follows the
periodical cycle from coke to ore then to coke again. This cycle
repeats in blast furnace because the top layer profile is the same
under a specific charging condition. Thus, the physical variable such
as temperature, composition and gas species at any specific loca-
tion will be also periodically changing with time. The average of the
transient periodical change for each physical variable in the blast
furnace shaft process can be obtained by averaging of the results

Table 2
Chemical reactions considered in the model.

No. Reaction Rate Ref.

Indirect reduction 1 3Fe2O3(s) þ CO(g) / 2Fe3O4(s) þ CO2(g) R1 [19]


of iron oxide 2 Fe3O4(s) þ CO(g) / 3FeO(s) þ CO2(g) R2 [19]
by CO 3 FeO(s) þ CO(g) / Fe(s) þ CO2(g) R3 [19]
Indirect reduction 4 3Fe2O3(s) þ H2(g) / 2Fe3O4(s) þ H2O(g) R4 [19]
of iron oxide 5 Fe3O4(s) þ H2(g) / 3FeO(s) þ H2O(g) R5 [19]
by H2 6 FeO(s) þ H2 (g) / Fe(s) þ H2O(g) R6 [19]
Coke reaction 7 CO2 þ C / 2CO R7 [20]
8 H2O(g) þ C / CO þ H2 R8 [20]
Flux 9 MeCO3(s) / MeO(s) þ CO2(g) R9 [21]
decomposition (Me ¼ Ca, Mg)
Fig. 1. Boundary conditions.
D. Fu et al. / Applied Thermal Engineering 66 (2014) 298e308 301

from a number of steady state cases. The detail development of the Table 3
method is reported previously [23]. For each steady state case, the Source term Sg configuration for gas phase.

layer structure of coke and ore is prescribed beforehand of the CFD Bg Ore cell Coke cell
calculation. The layer structure is predicted by the burden distri- Gas momentum
!
ug ; p do,jo,eo dc,jc,ec
bution model published elsewhere [24]. The CFD cell is divided into Gas enthalpy Hg SgH ¼ n_ o ho Ao ðTo  Tg Þ SgH ¼ n_ c hc Ac ðTc  Tg Þ
four types depending upon the layer structure as shown in Fig. 2. If Gas Species Yi SgS; CO ¼ n_ o ðR1 þ R2 þ R3 Þ SgS;CO ¼ 2n_ c R7 þ n_ c R8
the space of the grid is occupied by the coke layer, the type of grid is SgS; CO2 ¼ n_ o ðR1 þ R2 þ R3 Þ SgS; CO2 ¼ n_ c R7

“coke cell”. Same rule is applied to “ore cell”. The “free space cell” þn_ f R9

type is assigned for the space above the top burden layer to SgS; H2 ¼ n_ o ðR4 þ R5 þ R6 Þ SgS; H2 ¼ n_ c R8
SgS; H2 O ¼ n_ o ðR4 þ R5 þ R6 Þ SgS; H2 O ¼ n_ c R8
calculate the mixing of the top gas. The cells between two different
types of layer are “interface cell”. A certain percentage of ore and
coke and ore are co-exists in the “interface cell” as the layer process can be approximated by averaging multiple steady state
boundary passes through the cell. The interface between the free cases with fixed burden configurations [23]. The equation for the
space cell and the bed cell is not considered because only one layer average value is given in Eq. (7) where n is the total number of
of such interface exists in a furnace. The error caused by the cases. Similar averaging method has also been used in blast furnace
simplification is considered to be negligible. shaft modeling [2]. The average of two cases (Case 1 and 2) will be
The conservation equations for the gas and burden phase are compared with the average of four cases (Case 1, 2, 3 and 4). If the
solved in the cell system with the type of cell prescribed. The effects difference is larger than the defined criteria, divide one charging
of the layer structure are reflected in the source term settings of cycle into more snaps (run Case 5, 6 then averaging Case 1e6 and so
conservation equations for different cell type. The detail source on) until a case number independent solution is obtained.
term settings are given in Table 3. Different layer properties such as
particle size, shape factor and porosity are used in the Ergun type 1 Xn
B ¼  B n ¼ 2; 4; 6; 8; . (7)
momentum equation for ore cell and coke cell respectively. Simi- n i¼1 i
larly, the source terms associated with gas enthalpy and species will
be also cell type dependent. The species source term associated
B ¼ p; u; v; Tg ; To ; Tc ; Zj ; Yi ; etc:
with iron ore reactions is only activated in the “ore cell” and those
with coke reaction only activated in the “coke cell”. The source term
of the burden enthalpy and composition for different types of grid
is set accordingly for different governing equations. An example for
2.5. Calculation procedures
such configuration is given in Table 4. The treatment for source
term is applied both chemically and thermally. The top boundary is
The calculation flowchart is shown in Fig. 4. The shape and
set as the inlet for burden phase with the time averaged value for
position of the CZ is updated with each iteration, i.e., constant
burden composition. The bottom boundary is set as the gas inlet
temperature for upper boundary and local liquidus temperature for
with the velocity and composition from raceway. Essentially, the
the lower boundary, until the previous and current positions of
steady state conservation equations for both gas and burden are
both boundaries are within the difference of less than a mesh size.
solved. The heat and mass exchanges between the two phases are
determined by the type of cell that forms the layer structure. In this
manner, the effects of the layer structure are explicated considered 3. Results and discussion
in this model.
The grid is set as a fixed layer configuration for the steady state 3.1. Simulation condition
case. In order to consider the layer descending effects, the changing
cycle has been equally divided into a number of snaps. Case 1 and The baseline case used geometry from an industrial blast
Case 2 equally divide the cycle into two parts. Case 3 and Case 4 furnace. Operating data is listed in Table 5. The properties for the
further divide the cycle into four parts. The corresponding burden coke layer and ore layer are given in Table 6. The effective heat
configurations of the four cases are shown in Fig. 3. More cases will transfer coefficient for wall heat loss hg is set to be 100 W/(m2 s). The
be added by the similar principle. The source term configuration relative speed factor Ks is assumed to be linearly changing from 0.8
changes correspondingly to the burden structure of each case. to 1.0 from the furnace center to the wall due to the fact the coke is
Average value of the variables distributions of the periodical mostly consumed in the raceway which is closer to the furnace wall.

Fig. 2. Types of CFD grid.


302 D. Fu et al. / Applied Thermal Engineering 66 (2014) 298e308

Table 4
Source term Ss configuration for solid burden phase.

Bs Ore cell Coke cell

Ore enthalpy Ho SoH ¼ n_ o ho Ao ðTg  To Þ  n_ o ðR1 H1 þ R2 H2 þ R3 H3 þ R4 H4 þ R5 H5 þ R6 H6 þ R9 H9 Þ SoH ¼ 0


Coke enthalpy Hc ScH ¼ 0 ScH ¼ n_ c hc Ac ðTg  Tc Þ  n_ c R7 H7  n_ c R8 H8
Burden composition Zj SsZ; Fe2 O3 ¼ n_ o ðR1 þ R4 Þ SsZ; Fe2 O3 ¼ 0
SsZ; Fe3 O4 ¼ n_ o ðR2 þ R5  R1  R4 Þ SsZ; Fe3 O4 ¼ 0
SsZ; FeO ¼ n_ o ðR3 þ R6 Þ SsZ,FeO ¼ 0
SsZ,c ¼ 0 SsZ; c ¼ n_ c R7  n_ c R8

Fig. 3. Layered burden configurations.

3.2. Results of shaft CFD simulation

The simulation was conducted using the in-house developed


code by FORTRAN language. The cases in the paper are 2D
axisymmetric since the furnace condition is assumed symmetric
about the central axis. The gas streamline in Fig. 5(a) illustrations
the zigzag flow pattern caused by the difference in porosity of the
coke and ore layer. The ore layered inside CZ possesses a much
lower porosity due to the fusion of the iron ore burden. The ore
layer inside CZ has a porosity of 0.1 and it is observed that the CZ
the ore layers become virtually impermeable thus forcing the
ascending gas to pass through the coke slits present between the
ore layers. The gas temperature with its isothermal lines in Fig. 5(b)
is similar to the coke temperature distribution in Fig. 5(c). The ore
temperature with its isothermal lines is shown in Fig. 5(d). Because
only coke exists in the center of the furnace, the ore temperature in
the center is not available. The isothermal lines of the coke and ore
temperature are presented ranging from 400 K to 1200 K. The low
temperature thermal reserve zone (TRZ) is observed from 800 K to
1000 K.
Fig. 6 shows the volume fractions of the major gas species with
the isothermal lines of the gas temperature. In Fig. 6(a), the CO
volume fraction is high around the CZ due to the direct reduction,
solution loss and the water gas reaction. As the gas ascends, the
indirect reduction occurs and CO is gradually consumed. On the
other hand, the distribution of CO2 is correspondingly followed the
distribution of CO as a product of the CO reactions as shown in
Fig. 6(b). In Fig. 6(c), the H2 is mostly consumed in the high tem-
perature region near the vicinity of CZ upper boundary due to the
fact that H2 is more active to for FeO reduction when the temper-
Fig. 4. Flowchart of the solution procedure. ature is higher than 1100 K. The H2O vapor also increases drastically
D. Fu et al. / Applied Thermal Engineering 66 (2014) 298e308 303

Table 5 in the furnace top due to the water evaporation from the ore and
Operation data. coke.
Productivity (MTHM/day) 4993 Fig. 9 shows the stepwise reduction process of the iron oxides to
PCI rate (kg/MTHM) 67 hot metal. The isothermal line of the ore temperature is presented
Ore rate (kg/MTHM) 1501 ranging from 400 K to 1200 K (CZ upper boundary) with an interval
Flux rate (kg/MTHM)* 112
Top absolute pressure (Pa) 1.70  105
of 100 K. The CZ lower boundary liquidus temperature is found to
Averaging bosh gas temperature (K) 2300 be approximately the value of 1673 K. The reduction of hematite
(Fe2O3) took place at the upper part of the BF and it is completed
transformed to magnetite (Fe3O4) above 800 K. The wustite (FeO) is
starting to generate from 800 K and it is not reduced until near the
CZ. Below the CZ, almost all the wustite has been converted to
melted iron (Fig. 7).
Table 6
The detailed gas and burden information in the middle of the
Layer properties.
furnace (location is indicated in Fig. 9) is select to illustrate the
Coke layer dc ¼ 0.050 m features of layered burden treatment. The gas temperature and
ec ¼ 0.36
streamline are shown in Fig. 8(a) and (b) for Case 1 and Case 2,
jc ¼ 0.8
Ore layer do ¼ 0.012 m
respectively. The figures reflect the realistic gas temperature when
eo ¼ 0.45, eo ¼ 0.10 (inside CZ) the burden moves to such position because of the relative slow
jo ¼ 1.0 burden descending speed. For the gas phase, the heat transfer takes
place in both coke layer and ore layer. A continues distribution of
temperature for the gas is observe. In Fig. 8(c) and (d), the coke
temperature gradually increases throughout the coke layer. How-
ever, the isothermal lines are almost vertical inside the ore layer,

Fig. 5. Results of case 1: (a) gas streamline, (b) gas temperature, (c) coke temperature, (d) ore temperature.

Fig. 6. Gas species distributions of case 1: (a) CO, (b) CO2, (c) H2, (d) H2O.
304 D. Fu et al. / Applied Thermal Engineering 66 (2014) 298e308

Fig. 7. Burden composition: (a) Fe2O3, (b) Fe3O4, (c) FeO, (d) Fe.

indicating that the value maintains unchanged from the boundary shown in Fig. 9(b), the effects of the layered burden on temperature
between ore layer and coke layer until the next coke layer. are further evidenced in the gas, ore and coke temperature plotted
Conversely, the ore temperature increases during the ore layer and along the vertical line. The ore temperature reaches the gas tem-
maintains during the coke layer as shown in Fig. 8(e) and Fig. 8(f). perature very quickly due to the small size. Notable temperature
Fig. 9(a) is colored by the gas temperature and a vertical line at the difference between the coke and gas is observed. The difference is
3 m radius position is selected as the location for plotting data. As increased as the coke descending to the lower level of the furnace.

Fig. 8. Temperature distributions: (a) Case 1, gas, (b) Case 2, gas, (c) Case 1, coke, (d) Case 2, coke, (e) Case 1, ore, (f) Case 2, ore.
D. Fu et al. / Applied Thermal Engineering 66 (2014) 298e308 305

Fig. 9. Case 1 result: (a) gas temperature distribution and the location of the vertical line (b) Plot of gas, ore, and coke temperature along the vertical line.

Fig. 10. Distribution along the vertical line: (a) ore temperature (b) average ore temperature (c) CO (d) average CO.

In reality, any specific location inside coke layer or ore layer distribution in blast furnace shaft. The ore temperature with
should has continuous temperature change as it is descending. opposite burden configurations (Case 1 and Case 2) and their
Averaging of multiple cases result with different burden structure average is plotted in Fig. 10(a). Case 1 and Case 2 with another two
in one charging cycle is adopted to obtain the average variable cases (Case 3 and 4) equally divided one charging cycle into four

Fig. 11. Distribution in the CZ region: (a) CO (b) CO2.


306 D. Fu et al. / Applied Thermal Engineering 66 (2014) 298e308

Fig. 12. CO distribution along vertical line at radius 3 m: (a) in whole shaft (b) near CZ region.

snaps. Fig. 10(b) shows that the average of Case 1 and Case 2 is 4. Conclusion
comparable with the average of Case 3 and Case 4 and also the
average of all four cases. The CO is consumed in ore layer but A CFD model has been developed to simulate the ascending gas
slightly increased in coke layer due to mixing as shown in Fig. 10(c). flow and the counter-current descending porous bed for iron-
Similar to the average of temperatures, the same conclusion is making blast furnace shaft by considering the layer structure of the
reached for averaging the CO distribution provided by Fig. 10(d). burden thermally and chemically. The model proposed to consider
The distributions of the CO and CO2 near the CZ are examined the layer structure of the burden is to solve the conservation
closely in Fig. 11. The CO from the raceway combustion is consumed equations for the gas and burden phase in the cell system with the
in the melting ore layer and regenerated in coke layer by the solution type of cell prescribed. The effects of the layer structure are re-
loss and water gas reaction due to the high temperature. The CO flected in the source term settings of conservation equations for
distribution at 3 m radius along the entire blast furnace shaft is different cell type. Essentially, the steady state conservation equa-
shown in Fig. 12(a). The magnitude of the oscillation of CO volume tions for both gas and burden are solved. The heat and mass ex-
fraction inside the CZ is much larger than that above the CZ. The changes between the two phases are determined by the type of cell
oscillation inside the CZ is detailed in Fig. 12(b). The average CO that forms the layer structure. In this manner, the effects of the
distribution above CZ is smooth comparing to the distribution inside layer structure are explicated considered in this model.
CZ as shown in Fig. 13(a). Fig. 13(b) shows the oscillation inside CZ is It has been concluded that on one hand, each steady state case
smoothed by involving more cases in the average. Each case reflects reflects the quasi steady state distribution for gas phase under that
the quasi steady state distribution for gas phase including the spe- specify layer structure. In addition, each steady state case also
cies, velocity, and pressure and temperature distribution under that predicts the global blast furnace performance such as top gas
specific burden structure. The average results from multiple steady composition, pressure drop and coke rate due to the number of
state cases represent the averaged value of the periodical change for layers in a blast furnace is large. On the other hand, the descending
both the gas phase and burden phase. Despite the difference in layer cycle of the layer is considered by the averaging of multiple cases
structure of the four cases which causes the local distribution differs with different layer structure in one charging cycle. Therefore, the
from case to case, the overall CO distributions are similar for all the averaged local distribution over time can be obtained by averaging
four cases as shown in Fig. 14. The top gas composition, total coke multiple such cases. The model was applied to simulate an industry
rate, total pressure drop is also similar as listed in Table 7. Good blast furnace. Good agreements have been found by comparing the
agreements have been found by comparing the predicated value predicated value with the plant measurement. The proposed
with the plant measurement. It has been found that each steady method can be applied to investigate the blast furnace shaft process
state case also predicts the global blast furnace performance due to and other moving bed system with periodic burden structure
the number of layers in a blast furnace is large. configuration.

Fig. 13. Average CO distribution along vertical line at radius 3 m: (a) in whole shaft (b) near CZ region.
D. Fu et al. / Applied Thermal Engineering 66 (2014) 298e308 307

Fig. 14. Distribution in the CZ region: (a) Case 1 (b) Case 2 (a) Case 3 (b) Case 4.

R9 single particle flux decomposition, mol CO2/s


Sg source term of general transport equation for the gas
Table 7
phase, variety
Comparison with plant measurement.
SgC source term of continuity equation for the gas phase,
Measurement Case 1 Case 2 Case 3 Case 4 kg/(m3 bed s)
Top gas CO2% 22.18 22.46 22.91 22.51 22.86 Sgu, Sgv source term of momentum equation for the gas phase,
Top gas CO% 23.88 24.23 24.07 24.41 24.24 N/m3
Top gas H2% 6.33 6.50 6.36 6.44 6.30 SgY,i source term of species equation for the gas phase,
Top gas N2% 47.62 46.81 46.66 46.65 46.60
CO gas utilization 48.15 48.11 48.77 47.97 48.54
kg/(m3 bed s)
Pressure drop (Pa) 162,716 175,127 178,574 175,127 168,922 Ss Source term of general transport equation for the solid
Coke rate (kg/MTHM) 412 408 411 411 413 phase, variety
SgH source term of energy equation for the gas phase, W/m3
SoH source term of energy equation for the solid iron ore,
Acknowledgements W/m3
ScH source term of energy equation for the solid coke, W/m3
This research was supported by the American Iron and Steel SsZ,j source term of composition equation for the solid phase,
Institute (AISI) and the U.S. Department of Energy (DOE) under j ¼ o (ore), j ¼ c (coke), mol/(m3 bed s)
Award No. DE-FG36-07GO17041. The authors would like to thank Tj burden temperature, j ¼ o (ore), j ¼ c (coke), K
the support from the collaborators at ArcelorMittal-USA, Arce- TOB type of burden, e
lorMittal-Dofasco, SeverStal, US Steel, US Steel e Stelco Inc., and Yi gas species mass fraction,e
Union Gas. The authors would like to thank all the help from the Zj burden composition concentration, j ¼ o (ore), j ¼ c
students and staffs of CIVS. (coke), mol/m3 bed
dj particle diameter, j ¼ o (ore), j ¼ c (coke), m
hj Heat transfer coefficient, j ¼ o (ore), j ¼ c (coke), w/(m2 K)
Nomenclature hg Effective heat transfer coefficient for wall heat loss,
Aj surface area of a single particle, j ¼ o (ore), j ¼ c (coke), m2 w/(m2 K)
Cp gas heat capacity, J/(kg K) k gas thermal conductivity, W/(m K)
Di gas species diffusivity, m2/s n_ j number density of burden, j ¼ o (ore), j ¼ c (coke),
Hg gas enthalpy, J/kg 1/m3 bed
Ho ore enthalpy, J/kg tcyc the time for the burden to move in one periodic cycle of
Hc coke enthalpy, J/kg layers, s.
!
H1, H4 heat of reaction of Fe2O3 reduction by CO and H2, J/mol ug gas superficial velocity vector, m/s
H2, H5 heat of reaction of Fe3O4 reduction by CO and H2, J/mol
H3, H6 heat of reaction of FeO reduction by CO and H2, J/mol
H7, H8 heat of reaction of coke gasification by CO2 and H2O, J/mol Greek
H9 heat of reaction of flux decomposition, J/mol rg gas density, kg/m3 bed
Ks relative speed factor for burden descending, e ro ore bulk density, kg/m3 bed
R1, R4 single particle Fe2O3 reduction rate by CO and H2, mol rc coke bulk density, kg/m3 bed
CO/s or mol H2/s Bg general variable for gas phase, variety
R2, R5 single particle Fe3O4 reduction rate by CO and H2, mol Bs general variable for solid phase, variety
CO/s or mol H2/s εj burden porosity, j ¼ o (ore), j ¼ c (coke), e
R3, R6 single particle FeO reduction rate by CO and H2, mol CO/s Gg diffusion coefficient of general transport equation for the
or mol H2/s gas phase, variety
R7, R8 single particle coke gasification by CO2 and H2O, mol m gas viscosity, kg/(s m)
CO2/s or mol H2/s jj particle shape factor, j ¼ o (ore), j ¼ c (coke), e
308 D. Fu et al. / Applied Thermal Engineering 66 (2014) 298e308

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