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Additives, Fillers, Reinforcements
Additives, Fillers, Reinforcements
Additives, Fillers, Reinforcements
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1) Carbon or graphite fibers:
2) Glass fibers
3) Calcium Carbonate
4) Talcum (Talc) or Magnesium Hydroxide
Plastics Additives
Content
2) Additives
2.1 Anti Counterfieting
2.2 Antimicrobials / Biostabilisers
2.3 Antioxidants
2.4 Antistatic Agents
2.5 Biodegradable Plasticisers
2.6 Blowing Agents
2.7 External Lubricants
2.8 Fillers/Extenders
2.9 Flame Retardants
2.10 Fragrances
2.11 Heat Stabilisers
2.12 Impact Modifiers
2.13 Internal Lubricants
2.14 Light Stabilisers
2.15 Pigments
2.16 Plasticisers
2.17 Process Aids
2.18 Reinforcements
Every activity in modern life is influenced by plastics and many depend entirely on plastics products. Imagine cars without
synthetic bumper, dashboards, steering wheels and switches; medicine without plastic hypodermic syringes and artificial hip
joints. And what about telecommunications, dependent on plastic telephones, circuit boards and cable insulation. Our
entertainment and leisure relies on the unique combination of characteristics offered by plastics in sports equipment and
clothing, CDs, video and audio tape, television and cinema - indeed you wouldn't be able to read this over the internet
without plastics!
All these plastics products are made from the essential polymer mixed with a complex blend of materials known collectively
as additives. Without additives, plastics would not work, but with them they can be made safer, cleaner, tougher and more
colourful. Additives cost money, of course, but by reducing production costs and making products last longer, they help us to
save money and conserve the world's precious raw material reserves. In fact, our world to day would be a lot less safe, a lot
more expensive and a great deal duller without the additives that turn basic polymers in to useful plastics.
2. Additives
Function:
There are a number of ways manufacturers and brand owners can combat counterfeiting by employing one of several or
indeed multilayer anti-counterfeiting technologies. Optical brighteners absorb ultraviolet and violet light then re-emit this
energy at a higher wavelength, normally as a blue glow.
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2.2 Antimicrobials/Biostabilisers
Function:
Help prevent deterioration of plastic materials where part of the material might be susceptible to microbiological attack.
Such attacks can cause staining, discolouration, odour and loss of aesthetics but more importantly, loss of electrical
insulating properties, hygiene and overall loss of mechanical properties in the material.
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2.3 Antioxidants
Function:
Help prevent "oxidation", the polymer reacting with oxygen. Oxidation can cause loss of impact strength, elongation, surface
cracks and discolouration. Antioxidants help prevent thermal oxidation reactions when plastics are processed at high
temperatures and light-assisted oxidation when plastics are exposed to UV light.
Function:
Help to prevent the build up of static electric charge. Plastics are generally insulating and so have the capacity to build up
static charges on the surface which greatly disturb processing procedures and can be an issue for hygiene and aesthetics.
Function:
Used to make plastics softer and more flexible and to enhance the degradability of the product.
Function:
Form gases in the plastic to produce a foam material. The blowing agents form gases by breaking down on heating at a pre-
determined temperature and form a foam structure within the plastic's polymer matrix.
Function:
To prevent damage to plastics or the mould during processing. Applied to the material or directly to the machine to allow
processing without damage.
2.8 Fillers/Extenders
Function:
Natural substances used to improve strength and lower the cost of the material. Usually mineral-based, fillers/extenders
literally increase the overall "bulk" of the plastic.
Function:
To prevent ignition or spread of flame in plastic material. Plastics see substantial use in critical construction, electrical and
transport applications which have to meet fire safety standards either by mandatory regulations or voluntary standards.
Flame retardants are added to plastics to meet these requirements.
2.10 Fragrances
Function:
Fragrances and deodorants for plastics are used in a variety of applications and arer products for the home.
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Function:
To prevent decomposition of the polymer during processing. Processing usually results in temperatures well above 180 deg
celsius, which without the addition of heat stabilisers would result in the plastic material literally falling apart
Function:
Enables plastic products to absorb shocks and resist impact without cracking. Particularly relevant for polyvinyl chloride
(PVC), polystyrene (PS) and polypropylene (PP) materials.
Function:
Used to improve processability of plastics by increasing the flowability. Internal lubricants improve the melt flow of material
by lowering the viscosity and heat dissipation (also see Processing Aids)
Function:
Used to inhibit the reactions in plastics which cause undesirable chemical degradation from exposure to UV light.
2.15 Pigments
Function:
Tiny particles used to create a particular colour.
2.16 Plasticisers
Function:
Used to make plastics softer and more flexible.
Function:
Used to improve processability of plastics by increasing the flowability. Internal lubricants improve the melt flow of
material by lowering the viscosity and heat dissipation (Also see Internal Lubricants) High-polymeric processing aids also
improve flowability of PVC compounds.
2.18 Reinforcements
Function:
Used to reinforce or improve tensile strength, flexural strength and stiffness of the material. Often fibre-based.
3.1) Additives Make Plastics Easier To Process
Process aids become liquid during the moulding process and form
a liquid around colour particles so that they mix better. Other
additives make the individual polymer particles adhere more to
each other inside the tube so that they melt quicker. This means
that the moulding temperature can be lower which saves energy
and prevents or minimises heat damage to the plastics.
Pigments are tiny particles which have to be evenly mixed into the
polymer in its molten state. Colourists specialise in scientifically
devising shades suitable for all types of situations. Through a
skilful manipulation of additives, plastics components can be
colour matched with parts made from other materials such as
wood, metal and fabrics, cars radios and kitchen appliances all use
this technique.
Different pigment formulations co-ordinate plastics with other
materials, as in the Land Rover Discovery (BASF).
Fashion is a word that not only covers clothes and accessories, but
also includes, tableware, kitchenware and office equipment. In all
these areas, pigments enable plastics to offer an endlessly variable
palette of colours, as vivid as any other media. Colour in plastics
also has many non-decorative functions. It can be used to cut down
light to protect the contents of a package, for example in medicine
bottles. It can be used as an important danger signal. Often it is
used simply to protect and conceal, as in dashboards, machine
housings and pipes. To make an opaque moulding, pigments are
chosen that absorb or scatter light very well. The most common,
cost-effective way of creating solid colour is to use carbon black or
titanium dioxide. Carbon black absorbs light, whereas titanium
dioxide, with its high refractive index, scatters light, producing a
very high level of whiteness and brightness. It is part of a range of
inorganic pigments and is mixed with other colours to create pastel
shades. Organic pigments are also good for making bright colours.
There are two vacuum cleaners in a shop. They both look attractive
and offer the same attachments, but one is on special offer.
Unknown to the customer, the cheaper appliance has been made
from plastics components that contain no additives. Does this
make any difference? What are additives for anyway? Is the
cheaper machine better value?
Most people are probably not aware that all our major plastics are
similar in composition to natural polymers such as wood, wool,
silk or cotton. They are all based on organic molecules which can
catch fire and burn. In some cases this is not a problem, but in
other situations it could mean life or death. the building materials
that are used to construct our homes, schools and public buildings
must be protected against fire by law, which means they must nor
ignite or spread flame. Depending on the type of plastics material
and the likely hazard, there are many FLAME RETARDANT
additives available to help satisfy this requirement.
Tough crash helmets and colour coded occurred regularly when
pulleys overheated, causing serious warning lights are produced
with additives (Shell).
Many natural materials decay with age - even granite erodes over
the years. In the world of plastics measures are being taken to
protect products from the effects of time. In extending the life and
service of plastics, the unseen protection given by additives can
result in materials which lead to new products for even more
demanding situations. Imagine the conditions that plastics are
subjected to - heat light, electric current, water weathering, cold,
and knocks and kicks of continual use in the home, office factory
or field. Effectiveness is critical.
Cars are good examples. The next time you are out in a car, take a
look at the exterior and interior and under the bonnet. Not only will
you find more components than ever before made of plastics, but
many of them - from bumpers and wheel trim to steering wheels
and door panels - have to endure long exposure to the elements, as
well as flying stones, scrapes, knocks and wear. Look at the engine
with its plastics mouldings, cables and tubes. Conditions are tough,
temperatures are high, yet plastics components still have to - and
do - work effectively. In all these cases the longer life additives are
silently at work.
Non-fading pigments will help these Spectrum stadium seats to
hold their colour for many years (Hille).
We all tend to think that plastics consume energy. In fact plastics
actually help to save energy in many different ways. For example
plastics in cars save European motorists some six billion litres of
fuel per year. This is because plastics have replaced heavier metal
parts and inspired designers to create wind-cheating aero-dynamic
shapes that cut down on fuel consumption. Without additives to
give plastics strength and durability, this would not be possible.