Professional Documents
Culture Documents
26 Que With Sol
26 Que With Sol
26 Que With Sol
Please read the instructions carefully. You are allotted 5 minutes specifically for this
purpose.
Important Instructions:
1. The test is of 3 hours duration.
2. This test paper consists of 90 questions. Each subject (PCM) has 30 questions. The
maximum marks are 300.
3. This question paper contains Three Parts. Part-A is Physics, Part-B is Chemistry and
Part-C is Mathematics. Each part has only two sections: Section-A and Section-B.
4. Section – A : Attempt all questions.
6. Section-A (01 – 20) contains 20 multiple choice questions which have only one correct
answer. Each question carries +4 marks for correct answer and –1 mark for wrong
answer.
7. Section-B (01 – 10) contains 10 Numerical based questions with answer as numerical
value. Each question carries +4 marks for correct answer. There is no negative marking.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-2
PART – A (PHYSICS)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
E E
(A) (B)
R a b r R a b r
E E
(C) (D)
R a b r
R a b r
Q2. The rms speed of the molecules of Hydrogen, Oxygen and Carbondioxide at the same
temperature are VH , VO and VC respectively then:
(A) VC VO VH (B) VH VO VC
(C) VH VO VC (D) VH VO VC
Q3. In a Screw Gauge, fifth division of the circular scale coincides with the reference line when the
ratchet is closed. There are 50 divisions on the circular scale, and the main scale moves by 0.5
mm on a complete rotation. For a particular observation the reading on the main scale is 5 mm
and the 20th division of the circular scale coincides with reference line. Calculate the true reading.
(A) 5.25 mm (B) 5.15 mm
(C) 5.20 mm (D) 5.00 mm
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-3
Q4. The magnitude of vectors OA, OB and OC in
the
given
figure are equal. The direction of
y
OA OB OC with x-axis will be :-
(A) tan1
3 1 2 C
1 3 2 A
(B) tan1
1 3 2
45 30 x
1 3 2 O
60
(C) tan1
1 3 2
1 3 2
(D) tan1
3 1 2 B
1 3 2
Q5. The fractional change in the magnetic field intensity at a distance 'r' from centre on the axis of
current carrying coil of radius 'a' to the magnetic field intensity at the centre of the same coil is :
(Take r < a)
2 a2 2 r2
(A) (B)
3 r2 3 a2
3 a2 3 r2
(C) (D)
2 r2 2 a2
2.2V. r 0.6
Q7. An inductor coil stores 64 J of magnetic field energy and dissipates energy at the rate of 640 W
when a current of 8A is passed through it. If this coil is joined across an ideal battery, find the time
constant of the circuit in seconds :
(A) 0.8 (B) 0.2
(C) 0.125 (D) 0.4
Q8. If E, L, M and G denote the quantities as energy, angular momentum, mass and constant of
gravitation respectively, then the dimensions of P in the formula P EL2M5G2 are :-
(A) M0 L0 T 0 (B) M1 L1 T 2
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-4
Q9. A series LCR circuit driven by 300 V at a frequency of 50 Hz contains a resistance R 3k, an
inductor of inductive reactances XL 250 and an unknown capacitor. The value of
capacitance to maximize the average power should be :
(Take 2 10 )
(A) 400 F (B) 4 F
(C) 40 F (D) 25 F
Q11. In a photoelectric experiment ultraviolet light of wavelength 280 nm is used with lithium cathode
having work function 2.5 eV . If the wavelength of incident light is switched to 400 nm, find out
the change in the stopping potential. h 6.63 1034 Js,c 3 108 ms1
(A) 1.3 V (B) 1.1 V
(C) 0.6 V (D) 1.9 V
Q12. Car B overtakes another car A at a relative speed of 40 ms–1. How fast will the image of car B
appear to move in the mirror of focal length 10 cm fitted in car A, when the car B is 1.9 m away
from the car A?
(A) 0.1 ms 1 (B) 0.2ms 1
(C) 4ms1 (D) 40 ms1
Q13. An electric appliance supplies 6000 J/min heat to the system. If the system delivers a power of
90W. How long it would take to increase the internal energy by 2.5 × 103 J ?
(A) 4.1 101 s (B) 2.4 103 s
(C) 2.5 101 s (D) 2.5 102 s
Q14. A particular hydrogen like ion emits radiation of frequency 2.92 1015 Hz when it makes transition
from n = 3 to n = 1. The frequency in Hz of radiation emitted in transition from n = 2 to n = 1 will
be :
(A) 2.46 1015 (B) 4.38 1015
(C) 6.57 1015 (D) 0.44 1015
Q15. The material filled between the plates of a parallel plate capacitor has resistivity 200 m . The
value of capacitance of the capacitor is 2 pF. If a potential difference of 40 V is applied across the
plates of the capacitor, then the value of leakage current flowing out of the capacitor is : (given
the value of relative permitivity of material is 50)
(A) 0.9 A (B) 9.0mA
(C) 9.0 A (D) 0.9mA
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-5
Q16. Two narrow bores of diameter 5.0 mm and 8.0 mm are joined together to form a U-shaped tube
open at both ends. If this U-tube contains water, what is the difference in the level of two limbs of
the tube.
[Take surface tension of water T = 7.3 × 10–2 Nm–1, angle of contact = 0, g = 10 ms–2 and density
of water = 1.0 × 103 kg m–3]
(A) 2.19 mm (B) 4.97 mm
(C) 5.34 mm (D) 3.62 mm
Q18. The initial mass of a rocket is 1000 kg. Calculate at what rate the fuel should be burnt so that the
rocket is given an acceleration of 20 ms 2 . The gases come out at a relative speed of 500ms1
with respect to the rocket :[Use g 10m / s 2 ]
(A) 500 kgs 1 (B) 10 kgs1
(C) 6.0 102 kg s 1 (D) 60kg s 1
Q19. Statement-I: By doping silicon semiconductor with pentavalent material, the electrons density
increases.
Statement-II: The n-type semiconductor has net negative charge.
In the light of the above statements, choose the most appropriate answer from the options given
below :
(A) Both Statement-I and Statement-II are true.
(B) Statement-I is true but Statement-II is false.
(C) Statement-I is false but Statement-II is true.
(D) Both Statement-I and Statement-II are false.
Q20. What equal length of an iron wire and a copper-nickel alloy wire, each of 2 mm diameter
connected parallel to give an equivalent resistance of 3 ?
(Given resistivities of iron and copper-nickel alloy wire are 12 cm and 51 cm respectively)
(A) 110 m (B) 90 m
(C) 82 m (D) 97 m
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-6
SECTION - B
(Numerical Answer Type)
This section contains 10 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded-off to the second
decimal place).
Q1. Two spherical balls having equal masses with radius of 5 cm each are thrown upwards along the
same vertical direction at an interval of 3s with the same initial velocity of 35 m/s, then these balls
collide at a height of .......... m. (Take g = 10 m/s2)
Q2. A source and a detector move away from each other in absence of wind with a speed of 20 m/s
with respect to the ground. If the detector detects a frequency of 1800 Hz of the sound coming
from the source, then the original frequency of source considering speed of sound in air 340 m/s
will be .....Hz.
Q5. White light is passed through a double slit and interference is observed on a screen 1.5 m away.
The separation between the slits is 0.3 mm. The first violet and red fringes are formed 2.0 mm
and 3.5 mm away from the central white fringes. The difference in wavelengths of red and voilet
light is ......... nm.
Q6. A soap bubble of radius 3 cm is formed inside the another soap bubble of radius 6 cm. The radius
of an equivalent soap bubble which has the same excess pressure as inside the smaller bubble
with respect to the atmospheric pressure is ______________________cm.
Q7. A uniform chain of length 3 meter and mass 3 kg overhangs a smooth table with 2 meter laying on
the table. If k is the kinetic energy of the chain in joule as it completely slips off the table, then the
2
value of k is ______________________(Take g = 10 m/s )
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-7
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-8
PART – B (CHEMISTRY)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
Q2. The correct options for the products A and B of the following reactions are
OH
OH OH OH OH
Br Br
A= , B= A= , B=
(A) (B)
Br Br Br Br
OH OH OH OH
Br Br Br Br Br Br
(C) A= , B= (D) A= , B=
Br
Br Br Br
Q3. What are the products formed in sequence when excess of CO2 is passed in slaked lime?
(A) Ca HCO3 2 , CaCO3 (B) CaO, CaCO3
(C) CaCO3 , Ca HCO3 2 (D) CaO, Ca HCO3 2
Q4. Which one of the following methods is most suitable for preparing deionized water?
(A) Permutit method (B) Synthetic resin method
(C) Calgon’s method (D) Clark’s method
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-9
(excess)
Br
Br
(A) (B)
Br
(C) Br (D)
Br Br
Q8. Which one of the following is correct for the adsorption of a gas at a given temperature on
a solid surface?
(A) H 0, S 0 (B) H 0, S 0
(C) H 0, S 0 (D) H 0, S 0
Q9. Among the following compounds I-IV, which one forms a yellow precipitate on reacting
sequentially with (i) NaOH (ii) dil. HNO3 (iii) AgNO3?
Cl Cl Br Cl
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-10
Q10. The conversion of hydroxyapatite occurs due to presence of F ions in water. The correct
formula of hydroxyapatite is:
(A) Ca3 PO 4 2 .CaF2 (B) 3Ca3 PO 4 2 .Ca OH2
Q11. The correct sequential addition of reagents in the preparation of 3-nitrobenzoic acid from
benzene is:
(A) Br2 / AlBr3 ,HNO3 / H2 SO4 ,Mg / ether,CO2 ,H3 O
(B) Br2 / AlBr3 ,HNO3 / H2SO 4 ,NaCN,H3 O
(C) HNO3 / H2SO4 ,Br2 / AlBr3 ,Mg / ether,CO2 ,H3 O
(D) Br2 / AlBr3 ,NaCN,H3O ,HNO3 / H2 SO4
Q13. Which one of the following when dissolved in water gives coloured solution in nitrogen
atmosphere?
(A) Cu2CI2 (B) ZnCI2
(C) AgCI (D) CuCI2
Q15. Excess of isobutane on reaction with Br2 in presence of light at 125°C gives which one of the
following, as the major product?
CH3
CH3 CH CH2Br
(A) (B) CH3 C Br
CH2Br
CH3
Br
CH3 CH CH2Br
(C) (D) CH3 C CH2 Br
CH3
CH3
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-11
Q17. The major products formed in the following reaction sequence A and B are :
O
Br2
CH3 A+B
KOH
O
(A) A= C CBr3 , B = CHO
Br HO
O O
(B) A= C CH3 , B = C CH3
Br HO
O
(C) A= C ,B= CHBr3
OK
O O
A= C CH2 Br , B = C CH2 OH
(D)
Br Br
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-12
SOCl2, CH3OH
H2N Major
N product
H
CO 2CH3 CO 2CH3
(A) (B)
NH2 HCl NH2 HCl
N N
H HCl H
COCl Cl CO 2CH3
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-13
SECTION - B
(Numerical Answer Type)
This section contains 10 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded-off to the second
decimal place).
Q1. The Born-Haber cycle for KCl is evaluated with the following data:
f H for KCl 436.7kJmol1; subH for K 89.2kJmol1 ;
ionizationH for K 419.0kJmol1; electrongainH for Cl(g) 348.6kJmol1;
bondH for Cl2 243.0kJmol1
The magnitude of lattice enthalpy of KCl in kJ mol–1 is _______ (Nearest integer)
Q2. Of the following four aqueous solutions, total number of those solutions whose freezing point is
lower than that of 0.10 M C2H5OH is ________
(Integer answer)
(A) 0.10M Ba3 PO 4 2
(B) 0.10MNa2 SO4
(C) 0.10 M KCI
(D) 0.10 M Li3PO4
Q3. The ratio of number of water molecules in Mohr's salt and potash alum is ____ × 10–1
(Integer answer)
Q4. The following data was obtained for chemical reaction given below at 975 K.
2NO(g) + 2H2(g) N2(g) 2H2 O(g)
NO H2 Rate
1 1
molL molL molL1s1
(A) 8 10 5 8 105 7 109
(B) 24 105 8 105 2.1 10 8
(C) 24 105 32 10 5 8.4 108
The order of the reaction with respect to NO is _______. [Integer answer]
–
Q5. The OH concentration in a mixture of 5.0 mL of 0.0504 M NH4Cl and 2 mL of 0.0210 M NH3
–6
solution is x × 10 M. The value of x is _______. (Nearest integer)
[Given K w 1 10 14 and K b 1.8 105 ]
Q6. An aqueous KCl solution of density 1.2 g mL–1 has a molality of 3.30 mol kg–1. The molarity of the
solution in mol L–1 is ________ (Nearest integer)
[Molar mass of KCl = 74.5]
Q7. The total number of negative charge in the tetrapeptide, Gly-Glu-Asp-Tyr, at pH 12.5 will be
_______. (Integer answer)
2+
Q8. The number of 4f electrons in the ground state electronic configuration of Gd is _____.
[Atomic number of Gd = 64]
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-14
Q10. AB3 is an interhalogen T-shaped molecule. The number of lone pairs of electrons on A is
_______. (Integer answer)
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-15
PART – C (MATHEMATICS)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
cos x
Q1. The sum of solutions of the equation tan2x , x , , is:
1 sin x 2 2 4 4
(A) (B)
15 10
11
7
(C) (D) 30
30
1 x
Q2. Let f x cos 2 tan1 sin cot 1 , 0 x 1. Then:
x
2 2 2 2
(A) 1 x f ' x 2 f x 0 (B) 1 x f ' x 2 f x 0
2 2 2 2
(C) 1 x f ' x 2 f x 0 (D) 1 x f ' x 2 f x 0
Q3. Out of all the patients in a hospital 89% are found to be suffering from heart ailment and 98% are
suffering from lungs infection. If K% of them are suffering from both ailments, then K can not
belong to the set:
(A) 80, 83, 86, 89 (B) 84,87,90,93
(C) 84,86,88,90 (D) 79, 81, 83, 85
z 1
Q4. The equation arg represents a circle with:
z 1 4
(A) centre at (0, 1) and radius 2 (B) centre at (0, 1) and radius 2
(C) centre at (0, –1) and radius 2 (D) centre at (0, 0) and radius 2
Q5. Let 0, . If the system of linear equations.
2
1 cos x sin y 4 sin3 z 0
2 2
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-16
1 2 22 2100
Q7. The sum of the series 2 4 .... 100 when x 2 is:
x 1 x 1 x 1 x2 1
2100 2101
(A) 1 (B) 1
4100 1 4101 1
2100 2101
(C) 1 (D) 1
4101 1 4101 1
20
20 20
Q8. If Cr is the co-efficient of x r in the expansion of 1 x , then the value of r 2 20Cr is equal
r 0
to
(A) 380 218 (B) 420 218
(C) 420 219 (D) 380 219
1 2
5 5 1 0 T 2021 T
Q9. If A ,B , i 1, and Q A BA , then the inverse of the matrix AQ A is
2 1 i 1
5 5
equal to
1
2021
1 0 5
(A) (B)
2021i 1 1
2021
5
1 0 1 2021 i
(C) (D)
2021 i 1 0 1
1
1/2
x 1 2 x 1 2
2
Q10. The value of 2 dx is:
1 x 1 x 1
2
(A) loge 16 (B) 2loge 16
(C) loge 4
(D) 4loge 3 2 2
x2 y 2
Q11. On the ellipse 1 let P be a point in the second quadrant such that the tangent at P to
8 4
the ellipse is perpendicular to the line x 2y 0 . Let S and S’ be the foci of the ellipse and e be
its eccentricity. If A is the area of the triangle SPS’ then, the value of 5 e2 . A is:
(A) 24 (B) 6
(C) 12 (D) 14
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-17
Q12. Let A and B be independent events such that P (A) = p, P(B) = 2p. The largest value of p, for
5
which P (exactly one of A, B occurs) , is:
9
5 2
(A) (B)
12 9
4 1
(C) (D)
9 3
Q13. If a line along a chord of the circle 4x 2 4y 2 120x 675 0 , passes through the point (–30, 0)
and is tangent to the parabola y 2 30x, then the length of this chord is:
(A) 7 (B) 5
(C) 5 3 (D) 3 5
Q14. If the truth value of the Boolean expression p q q r ~ r p q is false, then the
truth values of the statements p, q, r respectively can be:
(A) F T F (B) F F T
(C) T F F (D) T F T
Q15. The mean and standard deviation of 20 observations were calculated as 10 and 2.5 respectively.
It was found that by mistake one data value was taken as 25 instead of 35. If and are the
mean and standard deviation respectively for correct data, then , is:
(A) (11, 25) (B) (11, 26)
(C) (10.5, 26) (D) (10.5, 25)
Q16. Let ABC be a triangle with A (–3, 1) and ACB , 0 . If the equation of the median
2
through B is 2x y 3 0 and the equation of angle bisector of C is 7x 4y 1 0 , then tan is
equal to:
4 3
(A) (B)
3 4
1
(C) (D) 2
2
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-18
Q19. If the sum of an infinite GP a,ar,ar 2 ,ar 3 ,...... is 15 and the sum of the squares of its each term is
150, then the sum of ar 2 ,ar 4 , ar 6 ,.... is:
1 25
(A) (B)
2 2
5 9
(C) (D)
2 2
1 2n1 n2
Q20. The value of lim
n n
2 2 is:
r 0 n 4r
1 1
(A) tan1 4 (B) tan1 2
4 2
1
(C) tan1 4 (D) tan1 4
2
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-19
SECTION - B
(Numerical Answer Type)
This section contains 10 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded-off to the second
decimal place).
Q1. A wire of length 36 m is cut into two pieces, one of the pieces is bent to form a square and the
other is bent to form a circle. If the sum of the areas of the two figures is minimum, and the
4
circumference of the circle is k (meter), then 1 k is equal to_________ .
2 1 2
Q2. The sum of all integral values of k k 0 for which the equation in x has no real
x 1 x 2 k
roots, is ______________
x 1 y 3 z 4
Q5. Let the line L be the projection of the line in the plane x 2y z 3 . If d is
2 1 2
the distance of the point (0, 0, 6) from L, then d2 is equal to ______________.
d2 y
Q6. If y y x is an implicit function of x such that loge x y 4xy, then at x 0 is equal to
dx 2
Q7. The locus of a point which moves such that the sum of squares of its distances from the points (0,
0), (1, 0), (0, 1), (1, 1) is 18 units, is a circle of diameter d. Then d2 is equal to _____.
1 i 3
Q8. Let z , i 1 . Then the value of
2
3 3 3 3
1 1 1 1
21 z z 2 2 z 3 3 ..... z 21 21 is ________.
z z z z
a sin 2 x 1 , for x 0
Q9. Let a,b R,b 0 . Define a function f x
tan2x sin2x , for x 0
bx3
If f is continuous at x 0 , then 10 ab is equal to ______________
Q10. The number of three digit even numbers, formed by the digits 0, 1, 3, 4, 6, 7 if the repetition of
digits is not allowed, is _____________,
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-20
FIITJEE
KEYS to JEE (Main)-2021
PART – A (PHYSICS)
SECTION - A
1. D 2. B 3. B 4. C
5. D 6. A 7. B 8. A
9. B 10. B 11. A 12. A
13. D 14. A 15. D 16. A
17. B 18. D 19. B 20. D
SECTION - B
1. 50 2. 2025 3. 52 4. 1
5. 300 6. 2 7. 40 8. 354
9. 2 10. 1
PART – B (CHEMISTRY)
SECTION - A
1. B 2. B 3. C 4. B
5. C 6. D 7. A 8. C
9. B 10. B 11. C 12. B
13. D 14. A 15. B 16. D
17. C 18. C 19. C 20. B
SECTION - B
1. 718 2. 4 3. 5 4. 1
5. 3 6. 3 7. 4 8. 7
9. 3 10. 2
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-21
PART – C (MATHEMATICS)
SECTION - A
1. D 2. A 3. D 4. B
5. B 6. B 7. B 8. B
9. C 10. A 11. B 12. A
13. D 14. C 15. C 16. A
17. A 18. A 19. A 20. D
SECTION – B
1. 36 2. 66 3. 27 4. 136
5. 26 6. 40 7. 16 8. 13
9. 14 10. 52
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-22
FIITJEE
Solutions to JEE (Main)-2021
PART – A (PHYSICS)
SECTION – A
3RT
Sol2. Vrms
M
1
Vrms at constant T
M
1 1 1
VH : VO : VCo2 : :
1 16 44
1 1
1: :
4 2 11
VH VO VCo2
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-23
OB cos60 ˆi sin 60 ˆj
OC cos 45 ˆi sin 45 ˆj
OA OB OC
cos 30 ˆi sin30 ˆj cos 60 ˆi sin 60 ˆj cos 45 ˆi sin 45 ˆj
3 1 1 1 3 1 ˆ
2 2 ˆi j
2 2 2 2
1 3 2
2 2 2 1 3 2
tan
3 1 2 1 3 2
2 2 2
0NIa2
Sol5. Baxis 3/ 2
2 a2 r 2
0NI
Bcent
2a
B centre Baxis
Fractional change
Bcentre
Baxis
1
Bcentre
0NIa2
3
2 a2 r 2 2
1
0NI
2a
a3
1 3
3 r2 2
a 1 2
a
3
r2 2
1 1 2
a
3r 2
1 1 2 r a
2a
3r 2
2a 2
4 12 6 8
Sol6. Re q 0.6 12 6 8
4
4 12 6 8
4 12 6 8
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-24
48
3
0.6 14
48
3
14
0.6
144 / 14
90
14
0.6 1.6
2.2
2
v2 2.2V
P 2.2W
Re q 2.2
1 2
Sol7. UB LI ………(i)
2
PR I2R
2
640 8 R
R 10
1 2
from (i) 64 L 8
2
L 2H
L 2
I 0.2 sec ond
R 10
Sol10. Inside a uniform spherical shell, electric field is zero every where & electric potential is constant
but not zero, every where
hc
Sol11. W eV1
1
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-25
hc
W eV2
2
1 1
hc e V1 V2
1 2
hc 1 1
V1 V2
e 1 2
1 1
12400 1 & 2 are taken in A
2800 4000
4.4 3.1
1.3 V
V I1M V O1M
19
1
2
40 0.1m / s
19
U 6000
Sol13. 90
t 60
10J
U 2.5 103
t 2.5 102 sec ond
10 10
1 1 8
Sol14. hf1 R 2 2 R
1 3 9
1 1 3
hf2 R 2 2 R
1 2 4
f1 8 / 9 32
f2 3 / 4 27
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-26
27
f2 f1
32
27
2.92 1015
32
15
2.46 10 Hz
dq q0 t /
I e
dt
k A d
CR 0 d
d A
k 0
q0 t
I e
k0
q0 2 10 12 40
Imax
k 0 200 50 8.85 1012
0.9mA
Sol16. PB PA gh
2T 2T
P0 P0 gh
r2 r1 A
1 1 B
2T
h r1 r2
g
1 1
2 7 3 102 3
3
2.5 10 4 10
1000 10
2.19 103 m
2.19mm
Sol17.
A B X Y Z
1 1 0 0 0
1 0 0 1 0
0 1 1 0 0
0 0 1 1 1
dm
Sol18. Vre mg Fext
dt
dm
500 1000 10 1000 20
dt
dm
60k g / s
dt
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-27
Sol19. Pentavalent materials have more electrons and so electron density increase. But overall
semiconductor is neutral
R1 R 2
Sol20. 3
R1 R 2
1 2
A A
3
1 2
A A
3A 1 1
1 2
2
3 2 103 12 51 10 6 102
4
12 106 10 2 51 10 6 102
97m
SECTION - B
Sol1. y1 y 2
1 2 1 2
35t gt 35 t 3 g t 3
2 2
1
35 3 g t t 3 3
2
10
105 3 2t 3
2
t5
1
y1 35 5 10 52
2
50m
340 20
Sol2. f' f0
340 20
320
1800 f0
360
f0 2025Hz
2 2
5r 13r x y z
Sol3. Ixx ' Iyy ' M Izz ' M
2 2 13r / 2
36r 2 M 25r 2 Mr 2 169Mr 2 3r
M M
12 4 2 4
52Mr 2 r 5r
2 2
z'
x' y'
Assuming circular portion to be disc
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-28
4T P0
Sol6. p1 p2 …(1) r2
r1 P2
4T
p2 p0 …(2) P1
r2
1 1 r1
(1) + (2), p1 p0 4T
r1 r2
4T 1 1
4T
req r1 r2
r1 r2 36
reg 2cm
r1 r2 3 6
3 1
Sol7. x 3 g 2 1 g 2 K
mass
length
9 1
g K
2 2
3
10 4 K
3
K 40 J
2I
Sol8. P P radiation pressure
C
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-29
21 2
0E 0 C
C2
0E02
2
8.85 10 12 200
354 109 N / m2
Sol10. kx
2
3.14
1.57x 1.57
2 2
x 1cm
PART – B (CHEMISTRY)
SECTION - A
Sol1. Bakelite formed by the condensation reaction of phenol with formaldehyde and it is a
thermosetting polymer/ plastics.
Sol2. CS2 is non- polar, non- ionisable solvent and produce only para substituted compound due to the
production of less Br ion, while H2O itself a polar solvent and produce sufficient concentration of
Br to attack on ortho and para position.
st
Sol3. Ca OH2 CO 2 CaCO3 H2O ( 1 step of reaction)
nd
CaCO3 H2 O CO2 Ca HCO3 2 ( 2 step of reaction)
Sol4. De-ionised water means dissolved mineral free water which is prepared by synthetic resin
method. Where cation exchanged by H+ and anion exchanged by OH of resin.
Sol5. Statement I is true because methyl orange indicator has pH range (3.2 to 4.2) which is suitable
for buffer produced by strong acid and weak base.
Statement II is false because phenolphthalein has pH range (8.4 to 10.2) and only suitable for
equivalence point above than 7, In this case pH increased by the addition of NaOH on acetic
acid.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-30
Sol6.
Br
HBr Br
(excess) (stable) (Unstable) (More stable product)
Sol7. According to Bohr’s model, velocity of electron increases according to atomic number (z).
z
Ve ( z = Atomic number and n = number of shell / principal quantum number)
n
Similarly, velocity of electron decreases according to number of shell ( i.e principal quantum
number).
Sol10. Hydroxyapatite is the calcium minerals whose molecular formula is 3Ca3(PO4)2. Ca(OH)2 or
Ca10(PO4)6(OH)2. During contact with water dissolved F ion, hydroxyapatite converted into
3Ca3(PO4)2. CaF2 .
Sol11.
NO 2 NO 2
HNO3 Br2
H2SO4 AlBr3
Br
Mg / ether
NO 2 NO 2 NO 2
CO2
+
H3O
COOH C O MgBr MgBr
3-Nitrobenzoic Acid
O
Sol12. Molar conductivity measured at infinite dilution is called limiting molar conductivity. Hence at
infinite dilution stage, both strong electrolyte (KCl) and weak electrolyte (CH3COOH) have
identical value of conductivity. Therefore statement –I is false.
Statement-II is also false because molar conductivity increases by the decreasing the
concentration of electrolyte.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-31
Sol15.
Br2 / h
+
free radical path Br
Br (Major)
Isobutane (Minor)
Sol16. In Frenkel defect, cations are inserted in neighbouring site, therefore statement-I is correct,
because vacancy developed by missing cations and interstitial sites are equal. Statement II is
false because F-centre developed by metal excess defect due to anion vacancies.
Sol17.
O
O
(A) (B)
Sol18. Statement-I is true, because metal reduced by decreasing G in Elligham diagram but statement-
II is false, Ellingham diagram is G vs temperature graph has no relation with S.
Sol19. Reactivity order of halogens and inter halogens are F2 ClF Cl2 and ClF forms HOCl and HF
after the reaction with water.
Sol20.
O
O
+
SOCl2 C Cl HCl
C OH
NH2
NH2 N
N O
H
H O C Cl
CH3OH
C OCH3
NH3Cl
N
NH3Cl
N H
H
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-32
SECTION – B
Sol1.
1 Cl
K(s) 2 2(g) KCl(s) ; Hf°
° 1
Hsub sub H°BDE
2
K(g) Cl(g)
°
HLE
°
H IE -e H°EA +e
K(g) Cl(g)
1 0
H0f H0sub HIE
0
HBDE
2
0
HEA HLE
0
1 0
436.7 89.2 419 243 348.6 HLE
2
0
OR HLE 89.2 419 121.5 348.6 436.7kJmol1
Lattice energy = 717.8
Ans. = 718 (Nearest integer)
Sol2. All the solution have higher ion production with respect to 0.1M C2H5OH i.e 0.1 M Ba3(PO4)2,
0.1M Na2SO4, 0.1 M KCl and 0.1 M Li3PO4. Hence all have lowered freezing point than 0.1 M
C2H5OH (which is non- ionisable in aqueous medium).
Ans.= 4
a b
Sol4. If Rate K NO H2
a 5 b
Case I 7 109 K 8 105 8 10
5 a 5 b
Case II 2.1 10 8 K 24 10 8 10
a
7 101 1
Therefore,
2.1 3
1 a
1 1
or a 1
3 3
Ans. = 1
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-33
OH NH4
Here, Kb
NH4OH
OH 0.0504 5
1.8 10 5
0.0210 2
1.8 10 5 0.0210 2
OH 0.3 105 M
0.0504 5
OH 3 106 M
x3
Ans. = 3
Sol6. KCl solution has molality (m) = 3.3, [ Means 3.3 mol of KCl dissolved in 1 kg of solvent]
Total mass of solution = mass of solute + mass of solvent
= 3.3 74.5 1000gm
= 1245.85gm
Mass 1245.85
Volume of solution = = 1038.20ml
density 1.2
moles 1000 3.3 1000
M 3.17M
V(ml) 1038.2
Ans. = 3 (Nearest integer)
Sol9. Except electron gain enthalpy all the physical properties like sublimation enthalpy, ionization
enthalpy and hydration energy affected the value of reduction potential.
Ans. =3
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-34
Sol10. For AB3 interhalogen compound, which is T- shaped, only two lone pair electrons are available
on central atom.
B
A B
B
Ans. = 2
PART – C (MATHEMATICS)
SECTION - A
Sol1. Given equation
cos x 2 sin x cos x
1 sin x cos2 x sin2 x
1 x
Sol2. f(x) ,0 x 1 (on simplification)
1 x
2
f '(x) 2
1 x
2 2
1 x f ' x 2 f x
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-35
Sol3. 89 k k 98 k x 100 H L
87 k 89
89-k K 98-k
Sol5. 0
1
sin3
2
but 0
2
70o
Sol6. r planes
3
n1,n2 0
4
Where required plane P is
1 x 2 y 3 z 1 6 0
2x y 2z 5 0
1 2101
Sol7. S
100 2
x 1 x2
1
2101
For x 2, S 1
4101 1
20
20
Sol8. 1 x 20 Cr x r
r 0
Sol9. AA T A T A I
2021
A A TBA AT
2021 1 0
B 2021 I P I 2021P
2021i 1
1 1 0
B 2021
2021i 1
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-36
0 0
where P
i 0
1
1
2 2
16x 2
Sol10. I dx
2 2
2
1 x 1
1
2
4x
2 dx
0 1 x
4ln2
xx1 yy1
Sol11. TP : 1,
8 4
x2 y2
where 1 1 1 ……….(i)
8 4
given : slope = 2
x1 4y1 .………(ii)
8 2
(i) & (ii) P ,
3 3
1
e
2
4
A ar PSS '
3
5 e A 6
2
5
Sol12. P 2P 2 2P 2P 2
9 p-2p2 2p2 2p-2p2
5 1
P ,
12 3
P
15
Sol13. P t 2 ,15t
2 D
C 15,0
Q
Q 30,0 C O N
PQ is the common tangent
PN
tan
QN
15t
t 15 2
30 t
2
t2
1
Tangent = y x 30
2
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-37
Sol14.
p q r pq qr A p q q r B ~ r A B C pq A B C
F T F T F F T F F T
F F T F T F F F F T
T F F T T T T T F F
T F T T T T F F F F
Sol15. X 200
x 2 2125
For new data
x 200 25 35 210
x 10.5
x 2 2725
2725 2
2 10.5 26
20
A(-3,1)
Sol16. Line BM : 2x y 3 M 0,3
Line CD : 7x 4y 1 C 3,5
M (t,3-2t)
Mirror image of A 3, 1 in the line D
13 11
CD is , and it will lie on BC.
5 5 B C(2t+3,5-4t)
Slope of AC is 2/3
Slope of BC is 18.
2
18
3 4
tan
2
3
1 18
3
where ACB
dy sec 2 x
Sol17. y tan x
dx tan x
IF tan x
Solution : y tan x x tan x C
lim xy 1 C 1
x 0
For x ,y
4 4
Sol18. a.b c
b.c a
b. b
2
b 2
a a2
Sol19. 15, 150
1 r 1 r2
1 ar 2 1
r , a 12 2
5 1 r 2
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-38
SECTION - B
Sol1. Side of square = a
Radius of circle = r
Given : 4a 2r 36
S a 2 r 2
2
r 2 9r 81
4
ds 18
0r
dr 4
Sol2. Equation : 2x 2 6 k x 4 3k 0
D 0 64 2 k 64 2
Sum of integral values of K is 1+2+3+….+11 = 66
4
3x 3x 2
6 dx 27
2
2 4
3x 2 3x
6 x 2,4
4 2 x
-2 4
15
Sol4. LHS = r r!
r 1
15
r 1 1 r! r 1! r!
r 1
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-39
2 (3,-1,2) M
R 75 (7,1,5)= R
1950
d2 26
75
Sol6. ln x y 4xy
dy 4xy 4y 2 1
,
dx 1 4x 2 4xy
d2 y
1 4x 2 4xy 4y 4xy ' 8yy ' 4xy 4y 2 1 8x 4y 4xy '
dx 2
1 4x 2 4xy
2
For x 0, y 1
dy d2 y
3, 2 40
dx dx
2 2 2 2
Sol7. x 2 y 2 x 1 y 2 x 2 y 1 x 1 y 1 18
7
x2 y2 x y 0
2
1 1 7
r2 4
4 4 2
21 3
1 3 3
Sol8.
k 1 z
S 21 zk k zk zk
8 Re zk
1
(As z 1 z )
z
21 21
k
S 2 cosk 6 cos 21
k 1 k 1 3
2 1 6Re 2 3 21
Where e
i 2 /6
1 1
2 1 6 1 21
2 2
8 21 13
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.
JEE-MAIN-2021 (26th August-First Shift)-PCM-40
Sol9.
f 0 f 0 a
1
sin2x 1
cos 2x 4
f 0 lim
x 0 bx 3 b
ab 4 10 ab 14
4 x 5 =20
4 x 2 =8
3 x 4 x 2 =24
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.