Qualitative Analysis

1 . Qualitative analysis
-

technique to identity
-
cation + anion present in solution
-

by analyzing its physical + chemical properties

2. QA

v v

Physical Chemical
1
green
~,
""
✗ "" "" e

-
: %,
÷ -

water
1 K¥
-

- - -

" / limewater
'
1010115 :
green ( Fe ) Residue ,
.
.
.
'

)
'

insoluble ( CO,
"
Solubility after heating black :
'
- i
: : -

t
* It could also be 14103 salt .
limewater -1111771
cloudy
.
This salt decomposes to
Confirmatory test for cations produce carbon dioxide
4
gal ( Fe CO, or CUCO , )
-
Potassium hexacycinofeiate .

Residue is black 1141031

↳
( It → Iron till dark blue Test for cation
☒ Precipitate
:
2
↳ ( THI →
Iron (Il )
-
Potassium thiocyanate .
NH , ✗ precipitate
iron LIII blood ted
"
↳ → .
Fe →
green
solution Fe
"
→ brown
- Nessler reagent Cu
"
→ blue
↳ Nltyt → brown precipitate .

My
"
(a
"
,
A- 13-1,2174 ,
,

"
pb
Charge It
}
↳ :
✗ soluble
in excess
has
" "
↳ inn,

3 Test for anion :

first
"
•
(0 , always comes

Acid + Metal 10,

" - > Salt 1- Water + CO ,
I
add dilute acid

Test for anion

✗ Pb
v v
✓ A"
( 1- ✗ Pb
>
NO ,
-

g v
1- ✗ C"
✗ Hg "

✓ Ba
soy ✓
✓
"
Test for ( 03 Test for (Oz
"

Test for
"
103
i
add dilute nitric .
add dilute sulphuric
acid -
add dilute acid

no reaction hydrochloric acid reaction

no
✓
no reaction ✓

AICI , -1317g NO, '

3Ag( I + AHN 0,1
3 V
T J g- add
F
so ,
Alison, -1313442
'

Fesoy .

sol Sol into 5

g- . add concentrated Hzsoy
Sol Sol
down the wall of slanted
→Bash, -1211-14 , test tube .

5
g-
insol Sol