1. A solution has a pH of 3.6 will give ___ color if added with a drop of thymol blue.

A. red C. colorless
B. yellow D. blue
2. Yellowish gas
A. Cl2 C. CO2
B. N2 D. H2
3. Magnesium is obtained from
A. sea shells C. sea water
B. bentonite D. corals
4. What is the pH of natural rain water?
A. 7.0 - 8.3 C. 5.6 – 6.2
B. 2.4 – 3.4 D. 13
5. One sample of a solution with a pH of 10 is tested with phenolphthalein and another sample of this solution is tested
with litmus. In this solution the color of the litmus is
A. blue and the phenolphthalein is pink C. blue and the phenolphthalein is colorless
B. red and the phenolphthalein is pink D. red and the phenolphthalein is colorless
6. What volume of a 0.20 M NaOH solution is needed to exactly neutralize 40.0 milliliters of a 0.10 M H2SO4 solution?
A. 10.0 mL C. 40.0 mL
B. 20.0 mL D. 80.0 mL
7. What is the equivalent weight of a weak acid that requires 26.3 mL of 0.122 M KOH to neutralize 0.682 gram of the
acid?
A. 212 g/equi C. 147 g/equi
B. 4.70 g/equi D. 682 g/equi
8. If the solution X has a pH of 6 and solution Y has a hydronium ion concentration twice that of solution X, the
approximate pH of solution Y is
A. 12.0 C. 5.7
B. 3.0 D. 9.0
9. The pH of a solution is 6.38. Find the concentration of hydroxide ion in moles per liter.
A. 1.2 E-6 C. 2.4 E-6
B. 2.4E-8 D. 1.2 E-8
10. The hydrogen ion concentration of a solution is 5E-6 M. Find pOH.
A. 5.3 C. 4.8
B. 8.7 D. 9.2
11. Calculate the pH of a 0.030 M HCl solution.
A. 0.52 C. 3.00
B. 1.52 D. 3.51
12. What is the pH of a 0.30 M solution of benzoic acid, Ka = 6.6E-5?
A. 0.52 C. 4.7
B. 2.4 D. 4.2
13. Calculate the ionization constant for 0.1 M nitrous acid that is 6.5 % ionized.
A. 5.6 x 10-2 C. 4.5 x 10-6
B. 1.8 x 10-5 D. 1.8 x 10-5
14. A 0.0722 M acid has a pH of 3.11, what is the Ka of the acid?
A. 4.2 x 10 -6 C. 8.4 x 10 -7
B. 8.4 x 10 -6 D. 4.2 x 10 -7
15. Calculate the OH¯ in 0.1 molar ammonium hydroxide solution. Kb=1.8 E –5.
A. 1.34 E-2 C. 4.2 E-4
B. 1.34E-3 D. 4.2 E-2
16. . If 0.1 mole of solid NaOH is added to 1 liter of 0.125 M HAc solution, what is the final hydrogen ion concentration?
A. 1.5 E-4 M C. 5.9 E-4
B. 2.6 E-4 D. 4.6E-6 M
17. A 4.2% ionized 0.01 M ammonia solution is prepared from ammonium hydroxide. Calculate the pH.
A. 10.62 C. 8.55
B. 3.38 D. 5.45
E.
18. The percent ionization of a 0.20 M acetylsalicylic acid solution in the stomach where the pH is 1.00 is: (Ka of
acetylsalicylic acid = 3.0 × 10–4)
A. 3.8% C. 0.03%
B. 0.30% D. 0.0003%
19. What is the pH of a 0.10 M solution of NaHCO3? For H2CO3 at 25ºC, Ka1=4.5E-7 and Ka2=4.8E-11.
A. 8.34 C. 9.3
B. 7.1 D. 6.3
20. Calculate the pH of a 0.01 M NH4NO3 solution given Kb=1.6E-5 for NH3.
A. 2.4 C. 4.2
B. 3.6 D. 5.6
21. Find the hydrogen ion concentration in a solution containing 0.1 mole of HOCN and 0.1 mole of NaOCN per liter of
solution.
A. 2E-4 M C. 1.5 E-6 M
B. 2 E-5 M D. 1.5 E-3 M
22. Calculate the pH of an aqueous buffer solution which contains 0.100 mol/L NH3 and 0.200 mol/L NH4Cl.
A. 9 C. 7.0
B. 8.5 D. 10
23. What is the pH of a solution containing 0.01 M acetic acid and 0.01 M sodium acetate?
A. 9.26 C. 3.25
B. 4.74 D. 10.75
24. What is the pH of a saturated solution of Mg(OH)2? Ksp = 1.2 E-11
A. 3.5 C. 10.9
B. 10.1 D. 10.5
25. The solubility of BaSO4 in water is 0.00092 gram per 100 mL. Find the value of Ksp for BaSO4.
A. 1.5E-9 C. 1.5E-7
B. 1.5 E-8 D. 1.5E-6
26. Silver chromate, Ag2CrO4, is soluble to the extent of 0.0259 mole per liter. Calculate the solubility product constant.
A. 1.9E-12 C. 1.9E-10
B. 1.9 E-11 D. 1.9E-9
27. Calculate the solubility of SrSO4 in grams per 100 mL of solution from its solubility product constant, Ksp=7.6E-7.
A. 0.016 g/100mL C. 0.152 g/100 mL
B. 0.202 g/100 mL D. 0.406 g/100 mL
28. The solubility product of PbI2 is 7.9 E-9. What is the molar solubility of PbI2 in distilled water?
A. 2.0E-3 C. 5.0E-4
B. 1.25E-3 D. 8.9E-5
29. The solubility of gold(III) nitrate is 1.0E-4 g/L. What is the solubility product of AuCl3?
A. 1.0E-16 C. 1.2E-26
B. 2.7E-15 D. 3.2E-25
30. The Ksp of AgCl is 1.0E-10, and the Ksp of AgI is 8.3E-17. A solution is 0.100 M in I- and Cl-. What is the molarity of
iodide ions when AgCl just starts to precipitate?
A. 1.0E-5 C. 8.3E-7
B. 9.1E-9 D. 8.3E-8
31. In a titration, 2.7 cm3 of 0.100 mol dm-3 sodium hydroxide, NaOH, solution is added to 25.0 cm3 of 0.125 mol dm-3
benzoic acid, C6H5COOH, solution. Calculate the pH of the resulting solution given that the pKa of benzoic acid is 4.19.
A. 3.13 C. 7.45
B. 4.12 D. 9.12
32. What volume of 0.125 M H2SO4 is required to neutralize 2.50 g of Ca(OH)2?
A. 54 mL C. 135 mL
B. 270 mL D. 0.170 mL
33. Vinegar is an aqueous solution of acetic acid. A 5 ml sample ofa particular vinegar requires 26.90 mL of 0.175 M
NaOH for its titration. What is the molarity of acetic acid in the vinegar?
A. 0.52 C. 0.94
B. 1.04 D. 0.47
E.
34. What H+ is needed to dissolve completely 0.0010 mole of AgCN in 1 liter solution. KHCN = 4E-10 and KspofAgCN =
1.6E-14
A. 0.00026 M C. 0.000026 M
B. 0.026 M D. 0.26 M
35. A 25 ml sample of 0.025 M HBr is mixed with 25.0 ml of 0.023 M KOH. What is the pH of the resulting mixture?
A. 1.00 C. 7.00
B. 3.00 D. 11.00
36. A student is titrating 50 ml of 0.2 N HClsolution with a solution of 0.2 N KOH. He accidentally adds one ml too much
titrant. What is the pH of the resulting solution?
A. 10.3 C. 2.7
B. 11.3 D. 7.3
37. A 0.3991 g of an unknown containing chloride is dissolved and precipitated with 43.98 ml of excess 0.1056 M AgNO3.
A sintered glass crucible weighing 23.4101 g is used to filter out the resulting AgCl. The new weight of the dried crucible
is 23.9622 g. Compute % Cl in the sample.
A. 37.56% C. 34.22%
B. 47.82% D. 27.33%
38. How many drops of 0.1 M HNO3 solution are required to neutralize 15 drops of 0.2 M Ba(OH)2 solution?
A. 40 C. 60
B. 50 D. 70
39. A sample of Rochelle salt (KNaC4H4O6.4H2O), after ignition to convert it to the double carbonate, is titrated with
H2SO4, using methyl orange as an indicator. From the following data calculate the percentage purity of the sample : wt.
of sample= 0.9500g; H2SO4 used = 43.65 mL; NaOH used = 1.72 mL; 1.000 mL H2SO4 = 1.064 mL of 0.1321 N NaOH.
A. 50.70% C. 87.76%
B. 58.90% D. 95.50%
40. A sample of crude ammonium salt weighing 1.00 g is treated with hot KOH solution. The NH3 liberated is collected in
50.0 mL of 0.5000 N acid, and the excess acid requires 3.12 mL of 0.2000 N NaOH for neutralization. Calculate the
percentage ammonia in the sample.
A. 41.25% C. 49.0%
B. 45.5% D. 52.0%
41. In the analysis of a 2.00-g sample of lime by titration with H2SO4, what must be the normality of the acid so that the
percentage of Ca may be found by dividing the net volume of the acid by 4?
A. 0.15 N C. 0.25 N
B. 0.20 N D. 0.30 N
42. A mixture contains Na2CO3, NaOH, and inert matter. A sample weighing 1.500 g requires 28.85 mL of 0.5000 N HCl
to reach a phenolphthalein end point, and an additional 23.85 mL to reach a methyl orange end point. What is the
percentage of NaOH in the sample?
A. 84.27% C. 20.56%
B. 50.68% D. 6.67%
43. In standardizing a solution of HCl, it is found that 47.26 ml of the acid are equivalent to 1.216 g of pure Na2CO3.
What is the normality of the acid?
A. 0.4855N C. 0.5020 N
B. 0.3540 N D. 0.3902 N
44. A mixture of Na2CO3 and BaCO3 weighing 0.2000 g requires 30.00 ml of 0.1000N acid for complete neutralization.
What is the percentage of Na2CO3 in the sample?
A. 55.7% C. 50.5%
B. 44.3% D. 49.5%
45. What is the normality of a solution of KOH if 45.18 mL are required to neutralize 0.300 g of pure oxalic acid
(H2C2O4.H2O)?
A. 0.1053 C. 0.2135
B. 0.1153 D. 0.3125
46. How many milliliters of 0.01000 N Ba(OH)2 are theoretically required to titrate 0.03000 g of H3AsO4 to the
formation of Ba(H2AsO4)2?
A. 16.4 mL C. 18.9 mL
B. 17.6 mL D. 21.14 mL
47. A 1 gram sample of impure K2CO3 is taken for analysis. The solution of the dissolved sample required 58.10 ml of
0.14 N HCl. However, 0.65 ml of NaOH was used for back titration ( 1mlHCl is equivalent to 2.60 ml NaOH). Calculate the
purity of the sample expressed as percent K2O.
A. 38.14% C. 34.4%
B. 40.23% D. 42.1%
48. A super phosphate fertilizer was analyzed for phosphorus. A 0.5414 gram sample produce 0.1277 g of Mg2P2O7
residue upon ignition of the magnesium ammonium phosphate precipitate. The percentage of P2O5 present in the
sample is
A. 20.5% C. 15.04%
B. 18.20% D. 14.02%
49. A sample of impure cuprite Cu2O contains 66.6% copper. What is the percentage of pure Cu2O in the sample?
A. 45% C. 65%
B. 55% D. 75%
50. A sample of polystyrene prepared by heating styrene with tribromobenzoyl peroxide in the absence of air has the
formula Br3C6H3(C8H8)N. The number n varies with the conditions of preparation. One sample of polystyrene prepared
in this manner was found to contain 10.46% bromine. What is the value of N?
A. 19
B. 18
C. 17
D. 16