MATERIAT SAFETY DATA SHEET

Calcium Carbide

!. IDENTIFICATION OF THE SUBSTANCE/PREPAMNON AND OF THE

coMPANY/UNDERTAKING

Product name Calcium Carbide

Applications Production of Acetylene, desulfurizer in Metal lndustry

2. HAZARDSINDENTIFICATION

FIRE HAZARD: Contact with water, moist air, steam, acid, will
liberate extremely flammable gas (acetylene). The heat
generated can lead to ignition of the gas. ln contact with water
and moisture irritating calcium hydroxide is formed.
HEALTH RISK: Risk of serious damage to eyes. lrritating to
respiratory system and skin.
ENVIRONMENTAL RISK: The product is not classified as
environmentally hazardous according to criteria in current
legislation.
The product may cause elevation of pH. (Calcium Hydroxide).

3. COMPOSTTTON/TNFORMATION ON INGREDIENTS

EC No. CAS No. Content Classificatlon

200-843-3 75-20-7 65-80 %
215-138-9 1305-78-8 L7-32%
231-153-3 74r'r0-44-O <t%
23L-722-6 7744-34-9 <t%
etal alloys (si, Fe, etc) <LYo

Section 16 contains detailed classification phrases.

4.
lnhalation
lngestion
Skin
Eyes
5. FIRE.FIGHTINGMEASURES
Extinguishing media
Special fire fighting procedures
Specific hazards
Hazardous combustion products
Protective measures ln fire
6. ACCIDENTAL RETEASE MEASURES
Personal protection
Environmental protection
Spillcleanup methods
FIRSTAID MEASURES
Fresh air. lf respiratory problems, artificial respirationloxygen.
Rinse nose and mouth with water.
lmmediately give a couple of glasses of water or milk,
provided the victim is fully conscious. Do not induce vomiting.
Contact physician.
Remove contaminatedclothing. Wash skin thoroughly with
soap and water. Get medical attention if any discomfort
continues.
lmmediately flush with plenty of water for up to 15 minutes.
Remove any contact lenses and open eyes wide apart.
Do not use water as an extinguisher. Fire can be extinguished
using: Dry chemicals. Dry chemicals, sand, dolomite etc.
Do not use water on this product. lf not necessary do not
extinguish burning gas. Be aware of risk of fire re-starting, and
risk of explosion.
Contact with water liberates flammable gas. Water used for
fire extinguishing, which has been in contact with the product,
may cause irritation.
Fire creates: lrritant gases, fumes, smoke.
Firefighters exposed to combustion gases/decomposition
products should use a respiratory protective device.
Avoid direct contact with the product. Also refer to handling in
section 7 as wellas personal protective equipment in section 8.
Prevent release into drains and water courses.
Sweep up and place into an appropriate container (metal). Let
stand uncovered in a wellventilated dry area. Containers with
collected spillage must be properly labeled with correct
contents and hazard symbol. Wear necessary protective
equipment. Avoid contact with water. Avoid generation and
spreading of dust- For waste disposal, see section 13-
7. HANDLINGANDSTORAGE

Usage precautions Large quantities handled and stored in an inert atmosphere

(100 L). Prevent contact with water and moist air. Container
must be kept tightly closed. Provide good ventilation.
Avoid handling which leads to dust formation. Avoid direct
contact with the product if possible.
Storage precautions Store at moderate temperatures in dry, well-ventilated area.
Keep in original container. Keep containers tightly closed.
Specific use(s) Contact the supplier for additional information.

8. EXPOSURE CONTROLS/PERSONALPROTECTION

name CAS No. Reference LT Exp 8 Hrs ST Exp 15 Min Date

Ventilation Wellventilated area.

Respirators Use respiratory equipment with particle filter, type P2.
Protective gloves Use protective gloves made of: Rubber, neoprene or PVC.

Suitable gloves can be recommended by the glove supplier.

Eye proteetion Use tight fitting goggles if dust is generated.
Other Protection Wear suitable protective clothing as protection against
splashing or contamination. Use protective clothing, which
covers arms and legs.
Envircnmental exposure See section 6 and 7.
controls
Other exposure limits Phosphine: 0,14 mg/m3 (8 hrs), L,4mg/m3 (short term)

9. PHYSICALANDCHEMICATPROPERTIES

Appearance Solid Lumps. Powder, dust.

Colour Grey, Black.
Odour Characteristic. Phosphine
Physical data comments Flammability limit applies at normal pressure and temperature.
Solubility description Decomposes in water.
Boiling point ('C, interuall ca 2300
Density (g/cm3l t-L,2
Flammability limit (%l 2-82 (Acetylene)
10. STABITITYAND REACNVIW

Stability Chemicalstable product in normalconditions. See section 7.

Conditionsto avoid
Materialto avoid
Hazardous decomp. Product
Do not store in damp conditions or areas of high humidity.
Avoid contact with water. Flammable gas is generated in
contact with water. Avoid handling which leads to dust
formation. Avoid contact with acids and oxidizing substances.
Avoid heat, flames and other sources of ignition.
Acids. Oxidizing agent.
Acetylene Calcium hydroxide, phosphine.

11. TOXICOLOGICAL INFORMATION

lnhalation Dust irritates the respiratory system, and may cause coughing
and difficulties in breathing. May cause damage to mucous
membranes in nose, throat, lungs and bronchial system.
lngestion lngestion may cause severe irritation of the mouth, the
oesophagus and the gastrointestinal tract. May have a
corrosive effect on the digestive canal.
Skin Dust has an irritating effect on moist skin. Prolonged or
repeated exposure may cause severe irritation. Prolonged
contact may cause corrosion.
Eyes Risk of serious damage to eye. Dust in the eyes causes risk or
permanent eye damage. lmmediate first aid is necessary.
Health warnings According to the manufacturer the product does not contain
any CMR substances.

T2. ECOLOGICAT INFORMATION

Ecotoxicity
Mobility
Bioaccumulative potential
Perslstence and degradability
Other adYerse effects
The product may affect the acidity (pH-factor) in water with
risk of harmful effects to aquatic organisms.
The product reacts with water and willgenerate heat.
The product is not classified as a potential bioaccumulate.
Calcium carbide: log Pow < 0
Applies to the following component: Calcium carbide;
Decomposes on contact with water to acetylene and calcium
hydroxide.
Calcium oxide; readily biodegradable- Decomposes on contact
with water to calcium hydroxide.
Not known.
 MPONENT: Calcium Oxide
LC 50,96 Hrs, Fish mg/l: 1070 (Cyprinus carpio)
EC 50,48 Hrs, Daphnia, mg/l: 159,6

13. DISPOSAL CONSIDERATIONS

GeneraUcleaning Reuse if possible. Discarded product (incl. Contaminated

packaging) and related waste may constitute dangerous waste
in accordance with the Waste Ordinance. Contact an approved
waste disposal company for disposal instructions. The
packaging should be collected for reuse. Let stand outdoors.
Let Calcium carbide slowly react with moisture in the air to
calcium hydroxide. Do not add water. Acetylene and calcium
hydroxide is formed. Calcium hydroxide to destruction.
Disposalmethods Collect in marked containers and deliver to approved depot.
Contact specialist disposal companies.
Waste class Allocation of EWC code to be based on the source generating
the waste. Proposed EWC code: 10 08 wastes from other non-
ferrous thermal metallurgy 10 08 10* dross and skimmings
that are flammable or emit, upon contact with water,
flammable gases in dangerous quantities.

14. TRANSPORT INFORMATION

Proper shipping name (nationall CALCIUM CARBIDE MIXTURE

Proper shipping name (international) CALCIUM CARBIDE MIXTURE
ROAD TRANSPORT (ADR):
UN no. Road 7402
ADR class no. 4.3
Classification code W2
ADR packing group It

Road transport notes Tunnel restriction code (D/E)

RAILTRANSPORT (RtD|:
RID class no. 4.3
RID packinggroup ll
SEA TRANSPORT {|MDG}:
UN no. sea L40Z
IMDG class 4.3
!MDG packinggroup 1t

EMS no. F-G, S.N

Marine pollutant No.
ArR TRANSPORT (IATA-DGR / ICAO-TI):
UN no., air L4A2
tATA/lCAo class 4.3
IATA/ICAO packing group lt

15. REGUIATORY INFORMATION

Symbol(sl

Contains Calcium carbide

Calcium Oxide
Risk phrases R-15 Contact with water liberates highly flammable gases.
R-37/38 lrritating to respiratory system and skin.
R-41 Risk of serious damage to eye.
Safety phrases S-7/8 Keep container tightly closed and dry
5-26 ln case of contact with eyes, rinse immediately with
plenty of water and seek medical advice.
5-36137139 Wear suitable protective clothing gloves and
eyefface protection.
S-43 ln case of fire, use dry sand. Do not use water.
EU directives Ec 127 2 I 2oo8 (cLP) EC L9o7 I 2006 ( Reach)

15. OTHERINFORMANON

Explanations to R-phrases in section 3 R-15 Contact with water liberates highly flammable gases. R-
37138 lrritating to respiratory system and skin. R-41 Risk of
serious damage to eye.
lssued by EMDEKT UTAMA, lndonesia
Date of issue 2AL7-A6-20
Signature BC

Disclaimer The information in this safety data sheet is in accordance with

EC regulation L9O7/20o16 and is largely based on information
from the manufacturer/supplier and presupposes that the
product is used within the specified area of application.