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Glacial Acetic Acid, 80%: Material Safety Data Sheet
Glacial Acetic Acid, 80%: Material Safety Data Sheet
Type of Use: This product is not intended for use in food applications.
Emergency Overview
This material is HAZARDOUS by OSHA Hazard Communication definition.
Signal Word
DANGER.
Hazards
Corrosive. Combustible liquid. In use, may form flammable/explosive vapor-air mixture. Severe irritant and corrosive to
the eyes, skin, and nose. High ingestion hazard - corrosive/irritant. Inhalation hazard.
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MSDS No.: BE9041
Variant: U.S.A.-EN
Material Safety Data Sheet Version No: 2.2
07/19/2007
Validation Date:
NFPA® HMIS®
2
Health 3
3 0 Flammability 2
Physic al Hazard 0
Physical State
Liquid above 20 C
Color
Clear, colorless.
Odor
Strong, acrid, vinegar odor.
Odor Threshold
0.074 ppm / (detectable) Odor is not an adequate warning of potentially hazardous ambient air concentrations.
Routes of Exposure
Eye. Inhalation. Skin.
Skin
Severe skin irritant. Causes skin burns.
Inhalation
Exposure to vapor may cause irritation of the eyes, nose, and respiratory tract. Inhalation may cause asthma-like
symptoms, including coughing, wheezing, tightness of chest, shortness of breath, and headache.
Eye
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MSDS No.: BE9041
Variant: U.S.A.-EN
Material Safety Data Sheet Version No: 2.2
07/19/2007
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Moderate to severe eye irritant. Eye contact can cause corneal burns.
Ingestion
May cause burns of the mouth, throat, esphagus and stomach. Signs and symptoms may include pain, nausea, vomiting,
diarrhea, dizziness, drowsiness, faintness, weakness, collapse and coma.
General
Take proper precautions to ensure your own health and safety before attempting rescue and providing first aid. For
specific information refer to the Emergency Overview in Section 2 of this MSDS., Assess rapidly and aggressively., Prompt
action is essential., Prolonged observation may be indicated.
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MSDS No.: BE9041
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Material Safety Data Sheet Version No: 2.2
07/19/2007
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Inhalation
Immediately remove victim to fresh air. If victim has stopped breathing, give artificial respiration, preferably
mouth-to-mouth. GET MEDICAL ATTENTION IMMEDIATELY.
Eye
Immediately flush eyes with plenty of cool water for at least 15 minutes. Do not permit victim to rub eyes. Get medical
attention immediately!
Ingestion
If swallowed, DO NOT INDUCE VOMITING. Obtain emergency room treatment immediately.
Note to Physician
Do not induce vomiting because of corrosive effects. There is no specific antidote. Assess airway if inhaled and/or
ingested. If ingested, cardiac and respiratory status must be continuously monitored. Assess extent and severity of tissue
injury by appropriate diagnostic studies and procedures. Vigorous anti-inflammatory/steroid treatment may be required at
first evidence of pulmonary/upper airway edema. Contact ophthalmologist immediately. Prolonged observation may be
indicated.
Flammable Properties
Classification
OSHA/NFPA Class II combustible liquid.
Flash Point
39 °C (102.2 °F) ASTM D-56 (Tag Closed Cup)
Auto-Ignition Temperature
463 °C (865.4 °F)
Extinguishing Media
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MSDS No.: BE9041
Variant: U.S.A.-EN
Material Safety Data Sheet Version No: 2.2
07/19/2007
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Protection of Firefighters
Protective Equipment/Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical
protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection.
Structural firefighters protective clothing will only provide limited protection.
Fire Fighting Guidance: Keep away from heat, sparks, open flame, or any ignition source. Vapors may travel long
distances along the ground before reaching a source of ignition and flashing back. Fire may produce irritating, corrosive
and/or toxic gases. Individuals should perform only those fire-fighting procedures for which they have been trained. Fire
fighters should wear self-contained breathing apparatus in the positive pressure mode with a full facepiece when there is a
possibility of exposure to smoke, fumes or hazardous decomposition products. Cool tanks and containers exposed to fire
with water. Blanket with alcohol-resistant foam. When fighting a fire, notify environmental authorities if liquid enters sewers
or public waters. Move containers from fire area if you can do it without risk. Fight fire from maximum distance or use
unmanned hose holders or monitor nozzles. Withdraw immediately in case of rising sound from venting safety devices or
discoloration of tank. Always stay away from tanks engulfed in fire. Dike fire control water for later disposal; do not scatter
material.
Hazardous Combustion Products: Thermal decomposition may generate carbon monoxide, carbon dioxide, and perhaps
other toxic vapors.
Release Response
Eliminate all sources of ignition. Wear appropriate respiratory protection and protective clothing as described in Section 8.
Turn off or remove all ignition sources. Contain spilled material. Transfer to secure containers. Where necessary, collect
using absorbent media. In the event of an uncontrolled release of this material, the user should determine if the release is
reportable under applicable laws and regulations. Runoff to sewer may create fire or explosion hazard. Prevent entry into
sewers, basements or confined areas; dike if needed.
Avoid uncontrolled releases of this material. Where spills are possible, a comprehensive spill response plan should be
developed and implemented.
Handling
Keep container tightly closed when not in use. Carefully vent any internal pressure before removing closure. Do not
handle near heat, sparks, or flame. Avoid contact with incompatible agents. Use only with adequate ventilation/personal
protection. Avoid contact with eyes, skin and clothing. Do not enter storage area unless adequately ventilated. Metal
containers involved in the transfer of this material should be grounded and bonded. Acid or caustic must be transferred
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MSDS No.: BE9041
Variant: U.S.A.-EN
Material Safety Data Sheet Version No: 2.2
07/19/2007
Validation Date:
Storage
Protect container against physical damage. Detatched or outside storage is preferred. Inside storage should be in an
NFPA approved flammable liquids storage room or cabinet. All ignition sources should be eliminated. Electrical
installations should be in accordance with Article 501 of the National Electrical Code. NFPA 30, Flammable and
Combustible Liquids Code, should be followed for all storage and handling. Consul t local fire codes for additional storage
information. Do not use or store without examining material compatibilities. Flammable materials should be stored in a
separate safety storage cabinet or room. Store so fire extinguishing media can be applied to all containers from a safe
distance/protected location. Keep containers tightly closed when not in use and store in a well -ventilated area. Isolate
incompatible materials such as oxidizers. Containers should be clearly labeled. Metal containers used to store this
material should be grounded. Containers must be properly grounded before beginning transfer. All equipment must
conform to applicable electrical code.
Engineering Controls
Engineering controls, preferably enclosed systems, should be used whenever feasible to maintain exposures below
acceptable criteria. When such controls are not feasible, or sufficient to achieve full conformance, other engineering
controls such as local exhaust ventilation should be used.
Personal Protection
Inhalation A respiratory protection program that meets OSHA's 29 CFR 1910.134 or ANSI Z88.2 requirements must be
followed whenever workplace conditions warrant respirator use. Where engineering controls are not feasible or sufficient
to achieve full conformance with exposure limits (Section 8), use NIOSH approved respiratory protection equipment.
Respirators should be selected based on the form and concentration of contaminant in air and in accordance with OSHA
(29 CFR 1910.134).
Skin Wear chemical resistant gloves such as: Butyl rubber. or Viton(TM). When skin contact is possible, protective
clothing including gloves, apron, sleeves, boots, head and face protection should be worn. The equipment must be
cleaned thoroughly after each use.
Eye Wear safety glasses meeting the specifications of OSHA 29CFR 1910.133 / ANSI Standard Z87.1 where no contact
with the eye is anticipated. Chemical safety goggles meeting the specifications of OSHA 29CFR 1910.133 / ANSI Standard
Z87.1 should be worn whenever there is the possibility of splashing or other contact with the eyes.
Additional Remarks
Selection of appropriate personal protective equipment should be based on an evaluation of the performance
characteristics of the protective equipment relative to the task(s) to be performed, conditions present, duration of use, and
the hazards and/or potential hazards that may be encountered during use. Emergency eye wash fountains and safety
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MSDS No.: BE9041
Variant: U.S.A.-EN
Material Safety Data Sheet Version No: 2.2
07/19/2007
Validation Date:
Odor Threshold: 0.074 ppm (detectable) Odor is not an adequate warning of potentially hazardous ambient air
concentrations.
pH: < 2
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MSDS No.: BE9041
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Material Safety Data Sheet Version No: 2.2
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Chemical Stability
Stable.
Conditions to Avoid
Heat, sparks, open flame, other ignition sources, and oxidizing conditions.
Substances to Avoid
Chromic acid. Nitric acid. Sodium peroxide Carbonates. Hydroxides. Phosphates Corrosive to some metals. Potentially
violent reaction with acetaldehyde and acetic anhydride. Ignites on contact with potassium -tert-butoxide.
Decomposition Products
Not expected to decompose under normal conditions.
Hazardous Polymerization
Not expected to occur.
PRODUCT INFORMATION
Product Summary
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COMPONENT INFORMATION
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Material Safety Data Sheet Version No: 2.2
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Skin Contact Liquid may be absorbed through the skin. Acetic acid may be harmful by the dermal route of exposure. Acetic
acid may cause skin burns and subsequent respiratory difficulty and fatigue. Very high exposures to animals caused
hemoglobinuria: however, these effects have not been reported following accidental human skin expos ure.
Irritation
Skin Causes skin burns. Concentrations as low as 25% have caused severe irritation in animals. Skin studies performed
on human subjects found that a 10% solution was only slightly irritating.
Eye Liquid causes eye burns. Based on limited animal testing and human reports of eye splashes involving dilute liquid,
contact with a 3 % solution of acetic acid may cause slight ocular irritation while a 10 % solution may cause permanent
damage. Exposure to 25-50 ppm acetic acid vapor causes intolerable eye irritation and tearing in most individuals.
Acetic acid is mildly irritating to the eyes at an airborne concentration of 10 ppm.
Sensitization
Does not induce skin sensitization. Unlikely to cause respiratory sensitization. An asthma-like reactive airways dysfunction
syndrome (RADS) has been reported following exposure to high concentrations; however, the pathogenesis of this
condition is unknown.
Reproductive Effects
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MSDS No.: BE9041
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Material Safety Data Sheet Version No: 2.2
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Developmental Effects
Acetic acid did not cause maternal toxicity, fetal toxicity, or developmental abnormalities in animals receiving up to 1600
mg 5% acetic acid/kg bwt/day by the oral route during gestation. A temporary increase i n preweaning body weights and
decrease in activity level in an open field test were observed in male offspring of female rats administered 0.0052 M acetic
acid in drinking water during lactation. While exposure to acetic anhydride (which readily hydrolyze s to form acetic acid)
did cause fetotoxicity in an inhalation screening study in rats, effects were only observed at 100 ppm, an exposure
concentration causing severe respiratory irritation and maternal toxicity. No embryotoxic/fetotoxic or teratogenic e ffects
were observed in the offspring of mice receiving up to 1000 mg/kg bwt sodium acetate by the oral route.
Genetic Toxicity
No evidence of genotoxicity was noted for acetic acid, sodium acetate, or acetic anhydride (which readily hydrolyzes to
form acetic acid) when tested in standard bacterial in vitro test systems. Positive results with acetic acid but not sodium
acetate in the chromosome aberration assay and equivocal results with acetic anhydride in the mouse lymphoma assay i n
the absence of activation may be due to acidification of the culture medium and not true mutagenicity. In a single study,
acetic acid did induce very slight, dose-related increases in sister chromatid exchanges in the absence of activation at a pH
approaching neutral. No in vivo genetic toxicity data are available for acetic acid. However, no increase in frequency of
micronuclei was observed in the bone marrow of rats exposed by inhalation to 20 ppm of acetic anhydride for 90 days.
Carcinogenicity
In controlled animal studies, long-term dermal or oral administration of acetic acid alone did not induce tumors. However,
following initiation with a known carcinogen, acetic acid did act as a weak promoter by increasing t he number of benign
tumors progressing to carcinomas at the site of contact in rats treated orally and mice treated dermally. Acetic acid is not
classified as a carcinogen by any recognized authoritative body. Although repeated exposure to acetic acid ha s been
linked to increased risk of chronic respiratory symptoms and declines in pulmonary function, there have been no published
reports of cancer by the inhalation route in exposed humans. In addition, there have been no reports of cancer from long
term consumption of acetic acid for food preservation or preparation at concentrations approaching 10 %.
PRODUCT INFORMATION
Ecotoxicity
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MSDS No.: BE9041
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Material Safety Data Sheet Version No: 2.2
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COMPONENT INFORMATION
Ecotoxicity
Toxicity to microorganisms
EC50 / 5 HOURS Sewage sludge > 5,000 mg/l
Summary: Low toxicity to bacteria.
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MSDS No.: BE9041
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Material Safety Data Sheet Version No: 2.2
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Mobility
Transport between environmental compartments: Based on water solubility, partition coefficient and vapor pressure, this
substance is expected to have high mobility and be partitioned mainly into the atmospheric and water compartments
Information provided in this material safety data sheet applies to the product as manufactured. Processing, use and
contamination may render this information inappropriate for the material requiring disposal. State and local laws, and
regulations may differ from federal requirements, and requirements may change or be re -interpreted. It is the
responsibility for the waste generator to characterize waste streams relative to the pertinent regulatory provisions to
ensure that applicable requirements are reviewed and met.
Special Requirements
If you reformulate or further process this material, you should consider re -evaluation of the regulatory status of the
components listed in the composition section of this sheet, based on final composition of your product.
ID No. UN2789
Hazard Class 8
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MSDS No.: BE9041
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Material Safety Data Sheet Version No: 2.2
07/19/2007
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Regulatory Status
Country Inventory
Australia AICS X
Canada DSL X X = All components are included or are otherwis e
Canada NDSL exempt from inclusion on this inventory.
China IECS X
European Union EINECS X
European Union ELINCS
European Union NLP C = Contact Lyondell/Equistar by e-mail at
Japan ENCS X product.safety@lyondell.com or
Korea ECL X product.safety@equistarchem.com for additional
Philippines PICCS X infor mation.
United States TSCA X
If identified components of this product are listed under the TSCA 12(b) Export Notification rule, they will be listed below.
SARA 302/304
This material contains a component(s) with known CAS numbers classified as hazardous substances subject to the
reporting of CERCLA (40 CFR 302) and/or to the release reporting requirements of SARA (Section 302) bas ed on
reportable quantities (RQs).
Component RQ
Acetic Acid / CAS# 64-19-7. 5,000 lbs
SARA 311/312
SARA 313
This material does not contain any chemical components with known CAS numbers that exceed the De Minimis rep orting
levels established by SARA Title III, Section 313 and 40 CFR 372.
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MSDS No.: BE9041
Variant: U.S.A.-EN
Material Safety Data Sheet Version No: 2.2
07/19/2007
Validation Date:
State Reporting
This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins under California
Proposition 65 at levels which would be subject to the proposition.
Massachusetts Substances List (MSL) - Hazardous substances on the MSL must be identified when present in materials
at levels greater than state specified criterion. The criterion is: >= 1%. Components with CAS numbers present in this
material at a level which could require reporting under the statute are:
Environmentally Hazardous Substances listed by the State of Pennsylvania must be identified when present in materials at
levels greater than the state specified criterion. The criterion is >= 1%. Components with CAS numbers in this material at a
level which could require reporting under the statute are:
A Volatile Organic Compound (VOC) is any volatile compound of carbon excluding methane, carbon monoxide, carbonic
acid, metallic carbides or carbonates, ammonium carbonate, 1,1 -trichloromethane, methylene chloride, (FC-23),
(CFC-113), (CFC-22), (CFC-114), and (CFC-115). By this definition, this is a (VOC) material.
Latest Revision(s)
Revised Section(s): 2 3 8 11 12 15 Date of Revision: March 14 2007 Document regeneration error: Date of Revision:
July 19 2007
DISCLAIMER OF RESPONSIBILITY
This document is generated for the purpose of distributing health, safety, and environmental data. It is not a specification
sheet nor should any displayed data be construed as a specification. The information on this MSDS was obtained from
sources which we believe are reliable. However, the information is provided without any warranty, expressed or implied,
regarding its correctness. Some information presented and conclusions drawn herein are from sources other than direct
test data on the substance itself. The conditions or methods of handling, storage, use and disposal of the product are
beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and
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MSDS No.: BE9041
Variant: U.S.A.-EN
Material Safety Data Sheet Version No: 2.2
07/19/2007
Validation Date:
Language Translations
This document may be available in languages other than English.
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