CPP-SANKALP_ST-03-PH-I

CPP
STOICHIOMETRY- SHEET : 3
(n-factor, Equivalent Mass, Molar Mass, Dulong-petit Relations)
LEVEL - 1
–2
1. A hydrated sulphate of metal contained 8.1% metal and 43.2% SO 4 by weight. The specific heat
of metal is 0.24 cal/g. What is hydrated sulphate?

2. Find the milli equivalent of:

a) Ca(OH)2 in 74g.
b) NaOH in 20g
c) H2SO 4 in 2.45g.

3. Find the weight of NaOH in its 50 milli equivalents.

4. 1.0g of metal nitrate gave 0.86 g of metal sulphate. Calculate equivalent weight of metal.

5. 1.35g of pure Ca meal was quantitatively converted into 1.88g of pure CaO. What is atomic weight
of Ca?

6. 1.60g of a metal were dissolved in HNO 3 to prepare its nitrate. The nitrate was strongly heated
to give 2g oxide. Calculate equivalent weight of metal.

7. Calculate the no. of mole of water in 488g BaCl 2 . 2H2O.

8. What is the molecular weight of a substance, each molecule of which contains 9 carbon atoms,
13 hydrogen atoms and 2.33 × 10−23 g of other component?

9. What volume of 75% alcohol by weight (d=0.80g/mL) must be used to prepare 150mL of 30% alcohol
by mass(d=0.90g/mL) ?

10. The vapour density of a mixture containing NO 2 and N2O 4 is 38.3 at 27°C. Calculate the mole of
NO 2 in 100 mole mixture.

LEVEL - 2
11. Find out equivalent weight of H3PO 4 in the reaction Ca(OH)2 + H3PO 4 → CaHPO 4 + 2H2O
(A) 98 (B) 49 (C) 24.5 (D) 12.25

12. Equivalent weight of crystaline oxalic acid (H2C2O 4 . 2H2O) is –

(A) 90 (B) 63 (C) 53 (D) 45

13. Which statement is correct for equivalent mass of KMnO 4

(A) E.W. is 1/3 of molecular mass in neutral medium
(B) It is 1/5 of molecular mass in basic medium
(C) It is equal to molecular mass is acidic medium
(D) It is 1/3 of molecular mass in acidic medium

14. Equivalent weight of NH3 in the change N2 → NH3 is :–

(A) 17/6 (B) 17 (C) 17/2 (D) 17/3

15. Number of moles of electrons taken up when 1 mole of NO 3− ions is reduced to 1 mole of NH2OH is
(A) 2 (B) 4 (C) 5 (D) 6
–
16. What is the equivalent weight of nitrogen in the process NO 3 → N2 ?
(A) 14 (B) 4 (C) 2.8 (D) 7
CPP-SANKALP_ST-03-PH-I

17. 1 mol BaF2 + 2mol H2SO4 resulting mixture will be neutralised by :

(A) 1 mol of KOH (B) 2 mol of Ca(OH)2
(C) 4 mol KOH (D) 3 mol of KOH
18. The equivalent weight of divalent metal is W. The molecular weight of its chloride is :
(A) W+35.5 (B) W+71
(C) 2W+71 (D) 2W+35.5

19. Which of the following expressions is correct ( n = no. of moles of the gas, NA = Avogadro
constant, m = mass of molecule of the gas, N= no. of molecules of the gas)
(A) n = mNA (B) m = nNA (C) N = nNA (D) M = mn/NA

20. Copper forms two oxides. For the same amount of copper, twice as much oxygen was used to form
first oxide than to form second one. What is the ratio of the valencies of copper in first and second
oxides?
(A) 2 : 1 (B) 2 : 3 (C) 5 : 2 (D) 3 : 2

ANSWER KEY
1. M2(SO 4)3 . 18H2O
2. a) 2000
b) 500
c) 50
3. 2g
4. 38
5. 40.75
6. 32
7. 4 mole H2O
8. 135.04 amu, Mol. weight = 135.04g
9. 67.5 mL
10. 33.48 mole
11. B
12. B
13. A
14. D
15. D
16. C
17. B, C
18. C
19. C
20. A