SAFIETY DATA SHEET Sica This saiety data sheet is prepared in accordance with EU directive 91/155/EC ammended by eSeiNGs: rection 2001/88/EC. |SIGMADUR 520 (HB FINISH) BASE (LEAD FREE COLOURS) MSDS NL 01 / EN Version 7.5 Print Date 7/14/2005 Revision date 08-07-05 11. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product information Trace name ‘SIGMADUR 520 (HB FINISH) BASE (LEAD FREE Reccmmended use solvent based, two component coating base Registration number (Denmark) , PR-1015192, Company ‘Sigma Costings BV ‘Amsterdameeweg 14 1822 AD Vithoom Telephone 431297541911 Telefax + 431297841050 Emergency telephone number ¥31204075210 12. COMPOSITIONIINFORMATION ON INGREDIENTS For consponents with an occupational treshivold limit value see chapter 8 Uf multigle components with identical identifiers appear, these have different hazardous properties, eg. flashpoint Companies EINECS ]CASNa. [Symbol [R-phasctay [Concanvaton —] No Tahir TISSIST | 1530307 [Xe RG, RIOT, | 1000-25.00% RE Solvent raph (pave gh arom, | 365-199.0 | EATATIS-S | Xe, N | RIO. RSIS, [10.60 5.00% 6S, R37, 6s, R6? eye masa [oat Ri1_R20__[250- 10.00%, mtn: ea 203-503-9 1108-65-6 RIO. RIG 2.50-10.00% amide wax R20, RS} — [0.00-250% Bis? 3 6S pemtmliyAp peAByD ehacas [25547 | AUSSEIET | N___|ReB_ RIOT ]0.00-2:50% Metyt12.266pentmetytpipendyl | 280-0604] 2919-97-7] Xi. N] RAD, RSHS3 OOO 2.50% sebacats 3. HAZARDS IDENTIFICATION Harurdous components ylene Rephrase(s) : FLAMMABLE. HARMFUL BY INHALATION AND IN CONTACT WITH SKIN, HARMFUL TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATIC ENVIRONMENT. P-phrase(s) v8SAFETY DATA SHEET This saiety date sheat is prepared in accordance with EU directive S1/1S5/EC ommended by Girectivs 200V8BEC. SIGMADUR 520 (HB FINISH) BASE (LEAD FREE COLOURS) MSOS HL 01 /EN Version 7.5 Print Date 7/14/2005 Revision date 08-07-05 Con ains: Bix(1.2,2,6,6-pentamethyl-4-piperidyl) sebacate Meth! 1,2.2,6,6-pentamethy|-4-piperidyl sebacate May produce an allergic reaction. |4. FIRST AID MEASURES Gen zeal advice ‘When symptoms persist or in all eases of doubt seck medical advice. Never tive anything by mouth to an unconscious person Bye contact Inrigate copiously with clean, fresh water for atleast 10 minutes, holding the cyclids apart. Remove contact lenses. Seck medical advice. Skin contact ‘Take offall contaminated clothing immediately. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or ‘thinners Inhsdation Remove to fresh air. Keep patient warm and at rst. I beeathing is ivegular or stopped, administer anificial respiration. If unconscious place in recovery position and seek medical advice. ngestion : Ifaccidently swallowed obtain immediate medical atention. Keep at rest. Do rot induce vomiting Burs If spills on clothing catch fire, wash with plenty of water. Remove toose clothing. Do not remove clothing that has melted tothe skin Obtain medical attention IS. FIRE-FIGHTING MEASURES Specific hazards during fire ‘As the product contains combustible organic components, ie will produce fiph ing dense black smoke containing hazardous products of combustion (see section 10). Exposure to decomposition products may be a hazard to health. Coot closed containers exposed to fie with water spray. Do not allow run-off from fire fighting to enter drains or water courses. ‘Special protective equipment Inthe event of fire, wear self-contained breathing apparatus. for fire-fighters Suitable extinguishing media Use water spray, alcohol-esistant foam, dry chemical or eazbon dioxide. Keep containers and surroundings cool with water spray. Extinguishing media which 2 DoNOT use waterjet. ‘must not be used for safety reasons | '6, ACCIDENTAL RELEASE MEASURES Personal precautions Use personal protective equipment. Ventilate the area. Refer to protective ‘measures listed in sections 7 and 8. Wear respiratory protection, Beware of ‘vapours accumulating to form explosive concentrations. Vopours can accamulate in low areas, Remove all sourees of ignition. Environmental precautions ‘Try to prevent the material ffom eatering drains or water ways. Ifthe produet contaminates rivers and lakes or drains inform respective authorities, Clean with detergents. Avoid solvents, Contain and collect spillage with non combustible ebsorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Additional advice 2 Refer to scction 15 for specific national regulation Met rods fort LSAFETY DATA SHEET directive 2001/9HEC. MOS NL 01 / EN Version 7.5 ini auey del seats prepared in acordance wth EU crectve S1/ISSEEC ammended by PP i855 |SIGMADUR 520 (HB FINISH) BASE (LEAD FREE COLOURS) Print Date 7/14/2005 Revision date 08-07-05 17. HANDLING AND STORAGE Handling Safi handling advice Advice on protection against fire and explosion Storage Requirements for storage areas | and containers | Advice on common storage Mi TO REACH TLY TO REACH 10 % LEL TLV of the product Avoid exceeding of the given occupational exposure limits (see section 8). Use only in area provided with appropriate exhaust ventilation, Avoid contact with skin, eyes and clothing. Smoking, cating and drinking should be prohibited in the application area, Avoid inhalation of vapour or mist. For personal protection see section 8. Prevent the creation of flammable or explosive concentrations of vapour in ‘ir and avoid vapour concentration higher than the occupational exposure limits. When transferring from one container to another apply earthing, ‘measures and use conductive hose material. No sparking tools should be uscd. The product should only be used in areas from which all naked lights land other sources of ignition have becn excluded. No smoking, The accumulation of contaminated rags and dry overspray, particularly in spray booth filters, may result in spontancous combustion. Goad housekeeping. standards, regular safe removal of waste materials and regular maintenance of spray booth filters will minimise the risks of spontancous combustion and other fire hazards. ‘Observe label precautions. Prevent unauthorized access, Containers which aze opened must be carefully rescaled and kept upright to prevent leakage. ‘Store betweea 5 and 25°C (41 - 77 F) ina dry, well ventilated place away from sources of heat, ignition and direct sunlight. Solvent vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures ‘with air. Electeical installations / working materials must comply with the technocological safety standards. Keep away from sources of ignition - No smoking. Store in accordance with the particular national regulations (see section 15). Keep away from oxidising agents and strongly acid or alkaline materials. Ib. EXPC'SURE CONTROLS / PERSONAL PROTECTION um ventilated air quantity for 1 liter of product 2,420 m3 Basis: MAC (NL) 103 m3, 179 mg/m3. Basis: MAC (NL) Components on the national MAC list and/or the European TLY list (98/24/EC): Components CASNo. [Value] Value] Basis (rogien")__| fppm) 3/8SAFIETY DATA SHEET irectiv2 20018B/EC. MSDS NL 01/EN Version 7.5 This seaty data sheet is proparad in accordance with EU directive 9Y/15S/EC ammended by |SIGMADUR 520 (HB FINISH) BASE (LEAD FREE COLOURS) Print Date 7/74/2005 Revision date 08-07-05 ayline 1330-20-7 [210.00 [3000 | MAC(N) TWA ‘aan be absorbed through skincan be absorbed 221.00 |s000 | EUELV TWA throwgh skin 442.00 |10000 | EU ELV sTEL. Solvent naphiha (petroleum), ight arom: BATTSSS | 35.00 ESIGTWA eth /Ibenzene T0014 |215.00 30.00 ‘MAC (NL) TWA can be absorbed through skincon be absorbed 442,00 |10000 | EUELV TWA through skin 884.00 |20000 | EUELV STEL | 2-miethoxy-I-methylethy! acetate TO8-65-6 | $50.00 100.00 MAC (NL) TWA | | eam be absorbed through skin 27500 50.00 | EUELV TWA i 50.00 10000 | BUELV STEL Personal protective equipment General advice Respiratory protection Hand protection Eye protection Skin and body protection Adlitional advice Environmental protection Personal protection SigaraKalon Internal Safety Conte (INSACO) Form Cotour Odnur Flash point Autoignition temperature Upper explosion limit Lower explosion limit Dersity Water solubility pH ‘When operators, whether spraying or not, have fo work inside the spray booth, ventilation is unlikly to be sufficient to contol particulates and solvent ‘vopour in all cases. In such circumstances they should wear a compressed air- fed respirator during the spraying process and until such time as the pasticulates and solvent vapour concentration has fallen below the exposure nts For prolonged or repeated contact use protective gloves. Barrier creams may Irelp to protect the exposed areas of skin, they should however not be applied ‘once exposure has occurred, Skin should be washed after contact. (Chemical resistant goggles must be wor. Personnel should wear protective clothing. Skin should be washed after contact. Working clothes must not consist of textiles, which show a dangerous melting behaviour incase of fire. Workers should wear antistatic footwear, Refer to national regulations in chapter 15 for regulations on environmental protection Bnclosing glasses, safety gloves and P2A2 half:face combi mask Please contact your personal protection equipment supplier for further advice 9. PHYSICAL AND CHEMICAL PROPERTIES slight aromatic 300°C Note: Calculated >3s08C TIT HV) 0.94 mV) ca. 1.3 plem3 insoluble 48 1SAFETY DATA SHEET THis sively data sheet is prepered in accordance with EU directive 91/1S9/EC ammended by directive 2001/90EC. MSDS NL 01/ EN Version 7.5 , dynamnic Flow time | SIGMADUR 520 (HB FINISH) BASE (LEAD FREE COLOURS) Print Date 7/14/2005 Revision date 08-07-05 700 maPa.s at 23 °C >= 608 ‘Transversal section: 6 mm Method: ISO 2431 (EN 535) 6 mam CUP 110, STABILITY AND REACTIVITY Conditions to avoi Hazardous reactions Hazardous decomposition products 14. TOXICOLOGICAL INFORMATION ‘cate oral toxicity Acute inhalation toxicity Skin iita Ey? contact : Further information Ac te Toxicity Data for Components ETHYLBENZENE (100-41-4) Acute inhalation toxicity Avoid temperatures above 60°C (140 F), direct sunlight and contact with sources of heat. Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid exothermic reactions. Incase of fire hazardous decomposition products may be produced such as: Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOX), dense black smoke. ‘May cause nausea, abdominal spasms and imitation of the mucous membranes. Exposure to component solvent vapours concentration in excess ofthe stated ‘occupational expomure limit may rexult in adverse health effect, Such as ‘mucous membrane irritation. respiratory system iritation, adverse effects on kidney, liver and central nervous system. Symptoms and signs: headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact withthe preparation may cause removal of natural fat from the skin resulting in desiccation of the skin. The product may bbe absorbed through the skin ‘The liquid splashed in the eyes may cause imitation and reversibte damage. ‘There is no data available for this product. LC50: 100 ppm (lo) (mouse, 4h) 4 2. ECOLOGICAL INFORMATION Fuvther information “The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/4S/EC and is classified for ecotoxieological properties accordingly. See sections 2 and 15 for details 4 3. DISPOSAL CONSIDERATIONS Preduct Waste key for the unused ‘The product should not be allowed to enter drains, water courses or the sol Disposal together with normal waste isnot allowed. Special disposat required according to local regulations. 08 01 11: waste paint and varnish containing organic solvents or other dangerous substances. 8SAFETY DATA SHEET Ts sufly deta sheet prepared in accordance wih EU directive S11SS/EC ommended by Giective 2001/88/EC. |SIGMADUR 520 (HB FINISH) BASE (LEAD FREE COLOURS) MSDS NL 01/EN Version 7.5 Print Date 7/14/2005 Revision date 0807-05. | 114, TRANSPORT INFORMATION ‘Trcnsport to be in accordance with ADR for road, IMDG for sea and TATA for air transport UN-No 1263 Proper shipping name PAINT Clas 3 | Packing group m Lael 3 Ma ine Poltutaat (IMDG)P.PP,-) Pe Ma ine Pollutant component (IMDG) Dibutyltin bis C8-C18 carboxylates Em3 (IMDG) FESE | Limited quantity (ADR) ‘Max. per inner pack. : 5,00 L | Max. per outer pack. : 30.00 KG Limited quantity (IMDG) Max. per inner pack, :$.00 L Max. per outer pack. : 30.00 KG Note ‘yack sizes less than 450L, under the terms of 2.23.1.5, this product isnot subject tothe provisions of ADR. 115, REGULATORY INFORMATION Harmful Havardous components which must be listed on the label: | + xylene Rephrase(s) R10 Flammable, 2021 Harmful by inhalation and in contact with skin, 5253 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment, Sphrase(s) $23 Do not breathe spray. 33637 ‘Wear suitable protective clothing and gloves, $38 In case of insufticient ventilation, wear suitable respiratory equipment 61 Avoid release to the environment. Refer to special instructionvsafery date sheet, Pep rrase(s) P99) Contains : Bis(1,2,2,6,6-pentamethyl-4-piperidy!) sebacate, Methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate May produce an allergic reaction, ‘National legistation‘Ths suety dota sheet is prepared in accordance wih EU directive 91/15S/EC emmended by Giroctve 2001/987EC. |SIGMADUR 520 (HB FINISH) BASE (LEAD FREE COLOURS) MSDS NL 01 /EN Version 7.5, Print Date 7/74/2005, Revision dale 08-07-05 SAFETY DATA SHEET Ses Registration number (Denmark) , PR-1015192, | Mincem 2 P2,Xq | CFR Classification : K3Xn NER Classification NER Class 0.1: 0 (mn) NER Class 0.2: 36.9 %(en) NER Class 03: 1.1 %(m) MAL code (1993) 43 116, OTHER INFORMATION “Ths product contains a complex mixtare of bydrocarbons. Detailed information can be obtained by the producer. jon of R-phrases mentioned in section 2 | RI0 Flammabte. | R2021 ‘Harmful by inhalation and in contact with skin. R38 Invtating to skin. So.vent naphtha (petroleum), light arom. R10 Flammable, R513 Toxic to aguatie organisms, may cause long-term adverse «effects in the aquatic environment. Ros armnfl: may cause lung damage if swallowed, R37 levitating to respiratory system. R66 Repeated exposure may cause skin dryness or cracking, R67 \Vapours may cause drowsiness and dizziness ethylbenzene RI Highly flammable. R20 Harmful by inhalation, 2-methoxy-I-methylethy! acetate RIO Flammable, R36 Lrvitating to eyes. am de wax R20 Harmful by inhalation. RS May cause long-term adverse effects in the aquatic Bis(1,2.2,6,6-pentamethyl-4-piperidyl) R43 ‘May cause sensitization by skin contact, sebicate 50/53. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Mehl 1,2,2,6,6-pentamethyl-4-piperidy! R43 May cause sensitization by skin contact, sebicate 51/83 Toxic to aquatic organisms, may cause long-term adverse clfects in the aquatic environment. Version: 7.5 Revision date 08.07.2005, ‘The information contained in this safety data sheet is based on the present state of knowledge and current European and | National tegisation at the date of issue. The supplier reserves the right to modify data on the safety data sheet without fanher notice. Any change in data will normally be followed by the issue of a new safety data sheet, The uscr should chezk the date of issue and if more than 12 months have clapsed, then the data should only be used after checking with the nearest sales office of the supplier to establish that the data is still valid. As the specific conditions of use of the product are outside the suppliers control the supplier is not reponsible forthe (negative) consequences of these specific ontitions of use, which are outside ofthe suppliers. control and which are act compliant with the handling, storage and other instructions inthis safety data sheet. 718SAFETY DATA SHEET Fa antl tt ant proper ls ccorhce wih EU dace S1SSEC med by IMA cs ete |SIGMADUR 520 (HB FINISH) BASE (LEAD FREE COLOURS) MSDS NL 01/ EN Version 7.5 Print Date 7/14/2005 Revision date 0807-05 | ‘Afer al component(s) stated on the relevant Technical Data Sheet have been mixed the safety precautions mentioned fon etch of the component(e) safety data sheets and Inbels should be used in assessing the safety precautions of the | iced product For further information see technical data sheet number: 7524 8B