.

Title: Residual Primario Selva - Assay Report

Client: PetroPeru

Report No.: 120-19-18155

Date of Issue: 10 December 2019

Sample Description:
Amspec Reference
Sample ID: Residual Primario Selva
Lab ID: 120-19-18155
Date Received: 01 October 2019
Date(s) Tested: 10 October - 10 December 2019
Per Sample Label
Sample ID: Residual Primario Selva
Sample Date: September 2019
Sample Type: Submitted to Amspec HTC Laboratory

Reported by:

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Table of Contents

Section Page

1. Properties of Crude …………………………………………………………………………………… 3

2. Distillation Yield Data and Curves

2.1 Distillation %mass Yield and %volume Yield Data ………………………………. 4
2.2 Graph of Cumulative % yield against Temperature, °F AET …………………. 5

3. Assay Summary …………………………………………………………………………………………… 6

4. Properties of Cuts
4.1 IBP - 77°F …................................................................................ 7
4.2 77 - 200°F ` …................................................................................ 8
4.3 200 - 300°F …................................................................................ 9
4.4 300 - 400°F …................................................................................ 10
4.5 400 - 500°F …................................................................................ 11
4.6 500 - 650°F …................................................................................ 12
4.7 650 - 750°F …................................................................................ 13
4.8 750 - 850°F …................................................................................ 14
4.9 850 - 1000°F …................................................................................ 15
4.10 650°F+ …................................................................................ 16
4.11 1000°F+ …................................................................................ 17

5. Distillation Reports
5.1 Atmospheric Distillation (D86) ………………………………………… 18
5.2 Simulated Distillation (D7169) ………………………………………… 19
5.3 Light Ends in Crude Oil ( D7900) ………………………………………… 20

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Properties of Crude

Sample ID Residual Primario Selva

Lab ID 120-19-18155
Client ID PetroPeru
Date 10 December 2019
Test Method Unit Result
API @ 15.56°C °API 21.2
Specific Gravity @ 15.56/15.56°C D5002 0.9267
Density @15°C kg/l 0.926
Total Sulfur D4294 Wt% 0.59
Acid Number (Total) D664 mg KOH/g 0.58
Pour Point D97 °C 12
Viscosity @ 77°F (25°C) D445 cSt 680.5
Viscosity @ 122°F (50°C) D445 cSt 110.5
Viscosity @ 140°F (60°C) D445 cSt 71.950
Light Ends Analysis D7900 Vol% Page 20
UOP K Factor UOP 375 11.8
Metals ICP - Iron IP501 ppm (wt) 20
Nickel IP501 ppm (wt) 15
Vanadium IP501 ppm (wt) 30
Asphaltenes (c7 Insolubles) D6560 Wt % 4.1
Water & Sediment D4007 Vol% 0.5
Salt Content D3230 PTB 7.3
Aniline Point D611 °C *N.A.
H2S content UOP 163 ppm (wt) <1
Mercury UOP 938 ppb (wt) 1.8
Benzene D7900 Vol% 0.03
Vapor Pressure D323 psi 1.6
Total Nitrogen D5762 ppm (wt) 1553
Basic Nitrogen UOP 269 Wt % 0.031

*N.A. = Not Applicable to run Analysis per Method

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Distillation % Mass Yield and % Volume Yield

Cut Range Mass Yield Cumulative Volume Yield Cumulative

°F Wt. % Wt. % Vol. % Vol. %
IBP - 77 0.26 0.26 0.38 0.38
77 - 200 1.37 1.63 1.85 2.23
200 - 300 2.61 4.24 3.29 5.52
300 - 400 1.29 5.53 1.51 7.03
400 - 500 1.84 7.37 2.04 9.07
500 - 650 7.75 15.12 8.24 17.31
650 - 750 6.71 21.83 6.97 24.28
750 - 850 18.24 40.07 18.78 43.06
850 - 1000 21.02 61.09 21.28 64.34
1000+ 38.91 100.00 35.66 100.00

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Graph of Cumulative % yield against Temperature, °F AET

1050

1000
Temperature,
Graph of
Graph
AET°F
Cumulative
of Cumulative
%mass %volume
against AET,°F
against AET,°F
0 0 0
950
77 0.26 0.38
900 200 1.63 2.23
850 300 4.24 5.52
800 400 5.53 7.03
500 7.37 9.07
750
650 15.12 17.31
700 750 21.83 24.28
650 850 40.07 43.06
Temperature , °F AET

600 1000 61.09 64.34

550

500

450

400

350

300

250

200

150

100

50

0
0 10 20 30 40 50 60 70 80
Cumulative % Yield

Graph of Cumulative %mass against AET,°F Graph of Cumulative %volume against AET,°F

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Assay Summary

Sample ID Residual Primario Selva Cut Range

Lab ID 120-19-18155
Client ID PetroPeru
Whole IBP - 77 - 200 - 300 - 400 - 500 - 650 - 750 - 850 -
Date 10 December 2019 650+°F 1000+°F
Crude 77°F 200°F 300°F 400°F 500°F 650°F 750°F 850°F 1000°F
Test Methods Units

Mass Yield Wt% 0.26 1.37 2.61 1.29 1.84 7.75 6.71 18.24 21.02 84.88 38.91
D2892 /D5236
Volume Yield Vol% 0.38 1.85 3.29 1.51 2.04 8.24 6.97 18.78 21.28 82.69 35.66
API @ 15.56°C °API 21.2 76.1 60.7 47.9 37.7 30.9 27.3 25.9 23.3 17.4 8.6
Specific Gravity @ 15.56/15.56°C D4052 / D5002 / D70 0.9267 0.6817 0.7362 0.7888 0.8364 0.8714 0.8911 0.8990 0.9141 0.9503 1.0100
Density @15°C kg/l 0.926 0.6814 0.7359 0.7884 0.8360 0.8709 0.8907 0.8986 0.9136 0.9498 1.0094
Total Sulfur D4294 Wt% 0.590 0.304 0.403 0.411 0.486 0.666 0.951
Total Sulfur D2622 Wt% 0.0040 0.0031 0.0249 0.1219
Acid Number (Total) D664 mg KOH/g 0.58 <0.1 <0.1 <0.1 <0.1 0.1 0.33 0.45 0.7 0.59
Pour Point D97 °C 12 <-33 <-33 -15 18 27 42 21 84
Viscosity @ 77°F (25°C) D445 cSt 680.5
Viscosity @ 104°F (40°C) D445 cSt 1.156 1.845 5.248 19.98
Viscosity @ 122°F (50°C) D445 cSt 110.5 1.002 1.574 4.108 13.73
Viscosity @ 140°F (60°C) D445 cSt 71.950
Viscosity @ 212°F (100°C) D445 cSt 3.756 5.636 13.210 48.56 11107
Viscosity @ 248°F (120°C) D445 cSt 2.701 3.626 8.092 26.28 2201
Light Ends Analysis D7900 Vol% Page 20
PONA Analysis -Paraffins D5443 Vol% 95.38 79.15 59.14 49.28
Olefins D5443 Vol% 3.64 3.00 0.70 0.38
Naphthenes D5443 Vol% 0.21 16.11 35.36 24.62
Aromatics D5443 Vol% <0.05 1.75 4.76 13.93
>200°C D5443 Vol% 0.78 <0.05 <0.05 11.78
Aromatics by UV HPLC- Mono Aromatics D6591 Wt% 12.2 13.7 13.2
Di-Aromatics D6591 Wt% 4.0 5.5 5.1
Tri+ Aromatics D6591 Wt% <0.1 0.6 2.7
Total Aromatics D6591 Wt% 16.2 19.7 21.0
Freeze Point D5972 °C -75 -44 -8
Distillation D86 °C Page 18 Page 18 Page 18 Page 18 Page 18
UOP K Factor UOP 375 11.8 11.9 11.8
Metals ICP - Iron IP501 ppm (wt) 20 <1 <1 <1 24 50
Nickel IP501 ppm (wt) 15 <1 <1 <1 17 35
Vanadium IP501 ppm (wt) 30 <1 <1 1 36 76
Sodium IP 501 ppm (wt) 20
Asphaltenes (c7 Insolubles) D6560 Wt % 4.1 4.8 10.8
Water & Sediment D4007 Vol% 0.50
Salt Content D3230 PTB 7.3
Mercaptan Sulfur D3227 ppm (wt) 16.0 12.0 5.0 39.0
Aniline Point D611 °C *N.A.
Smoke Point D1322 mm 21.0 18.0 15.0
Cetane Index D4737 38.1 42.1 51.0 58.8
Micro Carbon Residue D4530 Wt % <0.1 <0.1 <0.1 <0.1 0.46 10.20 22.1
Penetration at 25°C D5 mm/10 3
RON D2699 67 48
H2S content UOP 163 ppm (wt) <1
Mercury UOP 938 ppb (wt) 1.8
Benzene D7900 Vol% 0.03
Vapor Pressure D323 psi 1.6
Total Nitrogen D5762 ppm (wt) 1553 12.3 54 188 307 681 1773 3282
Basic Nitrogen UOP 269 Wt % 0.031 <0.001 0.002 0.006 0.009 0.019 0.036 0.061
Molecular Weight UOP 375 g/mol 372.1
Notes: Cumulative Volume Yield results are normalized to 100% among fractions in proportion to their Yields
*N.A. = Not Applicable to run Analysis per Method due to the matrix of the sample.

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Sample ID Residual Primario Selva

Lab ID 120-19-18155
Cut Range IBP - 77°F
Date 10 December 2019

Test Method Result Unit

Mass Yield 0.26 Wt%
D2892
Volume Yield 0.38 Vol.%
Methane 3.24
Ethane 6.28
Propane 32.32
i-Butane D6730 21.80 % Wt.
n-Butane 25.62
i-Pentane 2.15
n-Pentane 0.95

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Sample ID Residual Primario Selva

Lab ID 120-19-18155
Client ID PetroPeru
77 -
Date 10 December 2019
200°F
Test Method Unit
Mass Yield Wt. % 1.37
D2892
Volume Yield Vol. % 1.85
API @ 15.56°C °API 76.1
Specific Gravity @ 15.56/15.56°C D4052 0.6817
Density @15°C kg/l 0.6814
Total Sulfur D2622 Wt% 0.0040
Acid Number (Total) D664 mg KOH/g <0.1
PONA Analysis -Paraffins D5443 Vol% 79.15
Olefins D5443 Vol% 3.00
Naphthenes D5443 Vol% 16.11
Aromatics D5443 Vol% 1.75
>200°C D5443 Vol% <0.05
Distillation D86 °C Page 18
Mercaptan Sulfur D3227 ppm (wt) 16
RON D2699 67

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Sample ID Residual Primario Selva

Lab ID 120-19-18155
Client ID PetroPeru
200 -
Date 10 December 2019
300°F
Test Method Unit
Mass Yield Wt. % 2.61
D2892
Volume Yield Vol. % 3.29
API @ 15.56°C °API 60.7
Specific Gravity @ 15.56/15.56°C D4052 0.7362
Density @15°C kg/l 0.7359
Total Sulfur D2622 Wt% 0.0031
Acid Number (Total) D664 mg KOH/g <0.1
PONA Analysis -Paraffins D5443 Vol% 59.14
Olefins D5443 Vol% 0.70
Naphthenes D5443 Vol% 35.36
Aromatics D5443 Vol% 4.76
>200°C D5443 Vol% <0.05
Distillation D86 °C Page 18
Mercaptan Sulfur D3227 ppm (wt) 12
RON D2699 48

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Sample ID Residual Primario Selva

Lab ID 120-19-18155
Client ID PetroPeru
300 -
Date 10 December 2019
400°F
Test Method Unit
Mass Yield Wt. % 1.29
D2892
Volume Yield Vol. % 1.51
API @ 15.56°C °API 47.9
Specific Gravity @ 15.56/15.56°C D4052 0.7888
Density @15°C kg/l 0.7884
Total Sulfur D2622 Wt% 0.0249
Acid Number (Total) D664 mg KOH/g <0.1
Pour Point D97 °C <-33
Viscosity @ 104°F (40°C) D445 cSt 1.156
Viscosity @ 122°F (50°C) D445 cSt 1.002
PONA Analysis -Paraffins D5443 Vol% 49.28
Olefins D5443 Vol% 0.38
Naphthenes D5443 Vol% 24.62
Aromatics D5443 Vol% 13.93
>200°C D5443 Vol% 11.78
Freeze Point D5972 °C -75
Distillation D86 °C Page 18
Mercaptan Sulfur D3227 ppm (wt) 5
Smoke Point D1322 mm 21
Cetane Index D4737 38.1

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Sample ID Residual Primario Selva

Lab ID 120-19-18155
Client ID PetroPeru
400 -
Date 10 December 2019
500°F
Test Method Unit
Mass Yield Wt. % 1.84
D2892
Volume Yield Vol. % 2.04
API @ 15.56°C °API 37.7
Specific Gravity @ 15.56/15.56°C D4052 0.8364
Density @15°C kg/l 0.836
Total Sulfur D2622 Wt% 0.1219
Acid Number (Total) D664 mg KOH/g <0.1
Pour Point D97 °C <-33
Viscosity @ 104°F (40°C) D445 cSt 1.845
Viscosity @ 122°F (50°C) D445 cSt 1.574
Aromatics by UV HPLC- Mono Aromatics D6591 Wt% 12.2
Di-Aromatics D6591 Wt% 4
Tri+ Aromatics D6591 Wt% <0.1
Total Aromatics D6591 Wt% 16.2
Freeze Point D5972 °C -44
Distillation D86 °C Page 18
Mercaptan Sulfur D3227 ppm (wt) 39
Smoke Point D1322 mm 18
Cetane Index D4737 42.1
Micro Carbon Residue D4530 Wt % <0.1
Total Nitrogen D5762 ppm (wt) 12.3
Basic Nitrogen UOP 269 Wt % <0.001

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Sample ID Residual Primario Selva

Lab ID 120-19-18155
Client ID PetroPeru
500 -
Date 10 December 2019
650°F
Test Method Unit
Mass Yield Wt. % 7.75
D2892
Volume Yield Vol. % 8.24
API @ 15.56°C °API 30.9
Specific Gravity @ 15.56/15.56°C D4052 0.8714
Density @15°C kg/l 0.8709
Total Sulfur D4294 Wt% 0.304
Acid Number (Total) D664 mg KOH/g 0.1
Pour Point D97 °C -15
Viscosity @ 104°F (40°C) D445 cSt 5.248
Viscosity @ 122°F (50°C) D445 cSt 4.108
Aromatics by UV HPLC- Mono Aromatics D6591 Wt% 13.7
Di-Aromatics D6591 Wt% 5.5
Tri+ Aromatics D6591 Wt% 0.6
Total Aromatics D6591 Wt% 19.7
Freeze Point D5972 °C -8
Distillation D86 °C Page 18
Smoke Point D1322 mm 15
Cetane Index D4737 51
Micro Carbon Residue D4530 Wt % <0.1
Total Nitrogen D5762 ppm (wt) 54
Basic Nitrogen UOP 269 Wt % 0.002

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Sample ID Residual Primario Selva

Lab ID 120-19-18155
Client ID PetroPeru
650 -
Date 10 December 2019
750°F
Test Method Unit
Mass Yield Wt. % 6.71
D5236
Volume Yield Vol. % 6.97
API @ 15.56°C °API 27.3
Specific Gravity @ 15.56/15.56°C D4052 0.8911
Density @15°C kg/l 0.8907
Total Sulfur D4294 Wt% 0.403
Acid Number (Total) D664 mg KOH/g 0.33
Pour Point D97 °C 18
Viscosity @ 104°F (40°C) D445 cSt 19.98
Viscosity @ 122°F (50°C) D445 cSt 13.73
Viscosity @ 212°F (100°C) D445 cSt 3.756
Viscosity @ 248°F (120°C) D445 cSt 2.701
Aromatics by UV HPLC- Mono Aromatics D6591 Wt% 13.2
Di-Aromatics D6591 Wt% 5.1
Tri+ Aromatics D6591 Wt% 2.7
Total Aromatics D6591 Wt% 21
Metals ICP - Iron IP501 ppm (wt) <1
Nickel IP501 ppm (wt) <1
Vanadium IP501 ppm (wt) <1
Cetane Index D4737 0 58.8
Micro Carbon Residue D4530 Wt % <0.1
Total Nitrogen D5762 ppm (wt) 188
Basic Nitrogen UOP 269 Wt % 0.006

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Sample ID Residual Primario Selva

Lab ID 120-19-18155
Client ID PetroPeru
750 -
Date 10 December 2019
850°F
Test Method Unit
Mass Yield Wt. % 18.24
D5236
Volume Yield Vol. % 18.78
API @ 15.56°C °API 25.9
Specific Gravity @ 15.56/15.56°C D4052 0.899
Density @15°C kg/l 0.8986
Total Sulfur D4294 Wt% 0.411
Acid Number (Total) D664 mg KOH/g 0.45
Pour Point D97 °C 27
Viscosity @ 212°F (100°C) D445 cSt 5.636
Viscosity @ 248°F (120°C) D445 cSt 3.626
UOP K Factor UOP 375 11.9
Metals ICP - Iron IP501 ppm (wt) <1
Nickel IP501 ppm (wt) <1
Vanadium IP501 ppm (wt) <1
Micro Carbon Residue D4530 Wt % <0.1
Total Nitrogen D5762 ppm (wt) 307
Basic Nitrogen UOP 269 Wt % 0.009
Molecular Weight UOP 375 g/mol 372.1

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Sample ID Residual Primario Selva

Lab ID 120-19-18155
Client ID PetroPeru
850 -
Date 10 December 2019
1000°F
Test Method Unit
Mass Yield Wt. % 21.02
D5236
Volume Yield Vol. % 21.28
API @ 15.56°C °API 23.3
Specific Gravity @ 15.56/15.56°C D4052 0.9141
Density @15°C kg/l 0.9136
Total Sulfur D4294 Wt% 0.486
Acid Number (Total) D664 mg KOH/g 0.7
Pour Point D97 °C 42
Viscosity @ 212°F (100°C) D445 cSt 13.21
Viscosity @ 248°F (120°C) D445 cSt 8.092
Metals ICP - Iron IP501 ppm (wt) <1
Nickel IP501 ppm (wt) <1
Vanadium IP501 ppm (wt) 1
Micro Carbon Residue D4530 Wt % 0.46
Total Nitrogen D5762 ppm (wt) 681
Basic Nitrogen UOP 269 Wt % 0.019

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Sample ID Residual Primario Selva

Lab ID 120-19-18155
Client ID PetroPeru
Date 10 December 2019 650+°F

Test Method Unit

Mass Yield Wt. % 84.88
D5236
Volume Yield Vol. % 82.69
API @ 15.56°C °API 17.4
Specific Gravity @ 15.56/15.56°C D4052 0.9503
Density @15°C kg/l 0.9498
Total Sulfur D4294 Wt% 0.666
Acid Number (Total) D664 mg KOH/g 0.59
Pour Point D97 °C 21
Viscosity @ 212°F (100°C) D445 cSt 48.56
Viscosity @ 248°F (120°C) D445 cSt 26.28
UOP K Factor UOP 375 0 11.8
Metals ICP - Iron IP501 ppm (wt) 24
Nickel IP501 ppm (wt) 17
Vanadium IP501 ppm (wt) 36
Asphaltenes (c7 Insolubles) D6560 Wt % 4.8
Micro Carbon Residue D4530 Wt % 10.2
Total Nitrogen D5762 ppm (wt) 1773
Basic Nitrogen UOP 269 Wt % 0.036

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Sample ID Residual Primario Selva

Lab ID 120-19-18155
Client ID PetroPeru
Date 10 December 2019 1000+°F

Test Method Unit

Mass Yield Wt. % 38.91
D5236
Volume Yield Vol. % 35.66
API @ 15.56°C °API 8.6
Specific Gravity @ 15.56/15.56°C D70 1.01
Density @15°C kg/l 1.0094
Total Sulfur D4294 Wt% 0.951
Pour Point D97 °C 84
Viscosity @ 212°F (100°C) D445 cSt 11107
Viscosity @ 248°F (120°C) D445 cSt 2201
Metals ICP - Iron IP501 ppm (wt) 50
Nickel IP501 ppm (wt) 35
Vanadium IP501 ppm (wt) 76
Sodium IP 501 ppm (wt) 20
Asphaltenes (c7 Insolubles) D6560 Wt % 10.8
Micro Carbon Residue D4530 Wt % 22.1
Penetration at 25°C D5 mm/10 3
Total Nitrogen D5762 ppm (wt) 3282
Basic Nitrogen UOP 269 Wt % 0.061

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Distillation Report (ASTM D86)

Sample ID Residual Primario Selva

Lab ID 120-19-18155
Client ID PetroPeru
Date 10 December 2019

77 - 200 - 300 - 400 - 500 -

Cut Range
200°F 300°F 400°F 500°F 650°F

Description °C °C °C °C °C
IBP 42.8 101.6 154.4 210.1 274.5
Recovery @ 5% 55.7 105.9 159.7 220.0 286.8
Recovery @ 10% 58.1 106.9 161.0 221.5 289.4
Recovery @ 20% 60.7 108.8 163.0 223.6 293.2
Recovery @ 30% 63.4 110.4 164.8 225.8 296.3
Recovery @ 40% 66.2 112.4 167.0 228.4 299.7
Recovery @ 50% 69.1 114.3 169.5 230.8 303.1
Recovery @ 60% 72.1 116.9 172.3 233.7 307.2
Recovery @ 70% 75.4 120.1 176.2 237.0 311.5
Recovery @ 80% 79.1 124.1 181.0 241.0 316.4
Recovery @ 90% 85.3 129.9 188.2 246.5 322.6
Recovery @ 95% 89.9 134.9 194.0 251.2 327.4
FBP 100.3 146.3 203.2 255.8 329.4

% vol % vol % vol % vol % vol

Recovery 98.4 97.0 97.5 98.1 97.5
Residue 0.9 1.0 1.1 1.2 1.4
Loss 0.7 1.0 1.4 0.7 1.1

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Simulated Distillation Report (D7169)

Sample ID Residual Primario Selva

Lab ID 120-19-18155
Client ID PetroPeru
Date 10 December 2019
Cut Range Whole Crude

% Off BP(F) % Off BP(F) % Off BP(F) % Off BP(F) % Off BP(F) % Off BP(F) % Off BP(F)

IBP 156.7 16.00% 662.7 32.00% 798.1 48.00% 911.8 64.00% 1063.2 80.00% 1285.3

1.00% 179.1 17.00% 674.0 33.00% 804.8 49.00% 919.8 65.00% 1074.5 81.00% 1302.2

2.00% 213.4 18.00% 684.9 34.00% 811.0 50.00% 927.6 66.00% 1086.3 82.00% 1319.4

3.00% 259.5 19.00% 695.4 35.00% 817.7 51.00% 935.2 67.00% 1098.5

4.00% 303.3 20.00% 704.6 36.00% 824.5 52.00% 943.0 68.00% 1110.6 FBP >1328

5.00% 378.6 21.00% 714.3 37.00% 831.0 53.00% 951.2 69.00% 1123.4 Recovery 82.50

6.00% 442.8 22.00% 722.5 38.00% 838.1 54.00% 960.2 70.00% 1136.1 Residue 17.5

7.00% 489.0 23.00% 731.7 39.00% 844.9 55.00% 969.4 71.00% 1149.5

8.00% 522.6 24.00% 739.5 40.00% 852.3 56.00% 978.8 72.00% 1162.7

9.00% 552.3 25.00% 748.3 41.00% 859.4 57.00% 988.6 73.00% 1175.2

10.00% 575.2 26.00% 756.1 42.00% 867.0 58.00% 998.3 74.00% 1188.6

11.00% 592.5 27.00% 763.9 43.00% 874.2 59.00% 1008.4 75.00% 1202.8

12.00% 607.7 28.00% 771.7 44.00% 881.5 60.00% 1019.1 76.00% 1216.4

13.00% 623.9 29.00% 778.3 45.00% 888.8 61.00% 1030.2 77.00% 1233.8

14.00% 637.2 30.00% 785.2 46.00% 896.3 62.00% 1041.1 78.00% 1251.0

15.00% 650.7 31.00% 791.8 47.00% 903.9 63.00% 1052.3 79.00% 1269.42

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Light Ends In Crude Oil (D7900)

Components Listed in Chromatographic Order

Minutes Index Group Component Mass % Volume % Mole % BP(F) BP( C)

1.3598 198.74 unknown 0.0008 0.0011 0.004 BPF BPC
1.381 200 P2 ethane 0.0012 0.0032 0.0036 -127.48 -88.6
1.4353 300 P3 propane 0.0093 0.0172 0.0197 -43.672 -42.04
1.5179 357.58 I4 i-butane 0.0164 0.0273 0.0264 10.904 -11.72
1.5659 387 unknown 0.0013 0.0017 0.0021 10.904 -11.72
1.5885 400 P4 n-butane 0.0481 0.077 0.0775 31.1 -0.5
1.615 408.53 I5 2,2-dimethylpropane 0.0005 0.0008 0.0006 49.1 9.5
1.653 420.14 unknown 0.0014 0.0018 0.0018 49.1 9.5
1.7657 451 unknown 0.0008 0.0011 0.0011 49.1 9.5
1.8464 470.45 I5 i-pentane 0.1211 0.181 0.1569 82.112 27.84
1.9183 486.28 unknown 0.0031 0.0041 0.0041 82.112 27.84
1.9567 494.22 unknown 0.0042 0.0056 0.0054 82.112 27.84
1.9855 500 P5 n-pentane 0.1334 0.1973 0.1729 96.908 36.06
2.03 506.41 unknown 0.0069 0.0092 0.009 96.908 36.06
2.085 513.96 unknown 0.0033 0.0043 0.0042 96.908 36.06
2.1217 518.8 unknown 0.0083 0.011 0.0108 96.908 36.06
2.2312 532.34 I5 Carbondisulfide(Diluent) 0 0 0 113 45
2.257 535.36 I6 2,2-dimethylbutane 0.0081 0.0116 0.0088 121.514 49.73
2.415 552.58 unknown 0.0016 0.0022 0.0018 121.514 49.73
2.46 557.13 unknown 0.0012 0.0016 0.0013 121.514 49.73
2.5325 564.18 N5 cyclopentane 0.0078 0.0096 0.0103 120.65 49.25
2.5421 565.09 I6 2,3-dimethylbutane 0.0252 0.0353 0.0273 136.364 57.98
2.5865 569.22 I6 2-methylpentane 0.1495 0.212 0.1623 140.468 60.26
2.7553 583.93 I6 3-methylpentane 0.0902 0.1257 0.0979 145.886 63.27
2.9601 600 P6 n-hexane 0.371 0.5211 0.4027 155.714 68.73
3.0208 604.34 unknown 0.0047 0.0062 0.0051 155.714 68.73
3.0525 606.55 unknown 0.0014 0.0018 0.0015 155.714 68.73
3.0995 609.77 unknown 0.0043 0.0057 0.0046 155.714 68.73
3.1528 613.33 unknown 0.0068 0.0091 0.0074 155.714 68.73
3.2442 619.24 unknown 0.0141 0.0186 0.0153 155.714 68.73
3.3108 623.4 I7 2,2-dimethylpentane 0.0122 0.0167 0.0114 174.542 79.19

PETROPERU
.

Minutes Index Group Component Mass % Volume % Mole % BP(F) BP( C)

3.3577 626.26 N6 methylcyclopentane 0.0913 0.1129 0.1015 161.24 71.8
3.4108 629.43 I7 2,4-dimethylpentane 0.032 0.0441 0.0299 176.882 80.49
3.5065 634.96 I7 2,2,3-trimethylbutane 0.0021 0.0028 0.0019 177.584 80.88
3.7517 648.24 unknown 0.0012 0.0016 0.0011 177.584 80.88
3.7714 649.25 A6 benzene 0.0262 0.0277 0.0314 176.162 80.09
3.8717 654.31 I7 3,3-dimethylpentane 0.0063 0.0084 0.0058 186.908 86.06
3.9569 658.47 N6 cyclohexane 0.0787 0.0936 0.0874 177.296 80.72
4.1325 666.68 I7 2-methylhexane 0.124 0.1692 0.1157 194.09 90.05
4.1733 668.52 I7 2,3-dimethylpentane 0.0375 0.05 0.035 193.604 89.78
4.2417 671.55 N7 1,1-dimethylcyclopentane 0.0198 0.0243 0.0189 189.464 87.48
4.33 675.37 I7 3-methylhexane 0.1357 0.183 0.1267 197.33 91.85
4.49 682.05 N7 1c,3-dimethylcyclopentane 0.0368 0.0457 0.035 195.386 90.77
4.5581 684.8 N7 1t,3-dimethylcyclopentane 0.0365 0.0452 0.0348 197.096 91.72
4.5761 685.52 I7 3-ethylpentane 0.0091 0.012 0.0085 200.246 93.47
4.6267 687.52 N7 1t,2-dimethylcyclopentane 0.0641 0.079 0.0611 197.366 91.87
4.9589 700 P7 n-heptane 0.4067 0.5509 0.3796 209.156 98.42
5.2559 711.03 unknown 0.0012 0.0015 0.0011 209.156 98.42
5.5677 721.82 N7 methylcyclohexane 0.2792 0.3362 0.266 213.674 100.93
5.6658 725.07 N8 1,1,3-trimethylcyclopentane 0.0428 0.053 0.0357 220.802 104.89
5.9603 734.41 N7 ethylcyclopentane 0.0173 0.0209 0.0165 218.246 103.47
5.9971 735.54 I8 2,5-dimethylhexane 0.0203 0.0271 0.0166 228.398 109.11
6.066 737.63 I8 2,4-dimethylhexane 0.0249 0.0329 0.0204 228.974 109.43
6.2668 743.56 N8 1c,2t,4-trimethylcyclopentane 0.0249 0.0303 0.0208 242.132 116.74
6.312 744.86 I8 3,3-dimethylhexane 0.0068 0.0089 0.0056 233.546 111.97
6.5301 751 I8 2,3,3-trimethylpentane 0.0275 0.035 0.0225 238.586 114.77
6.6292 753.72 I8 2,3,4-trimethylpentane 0.005 0.0064 0.0041 236.246 113.47
6.7688 757.46 A7 toluene 0.0542 0.0579 0.055 231.134 110.63
7.0454 764.6 I8 2,3-dimethylhexane 0.028 0.0364 0.0229 240.098 115.61
7.0884 765.69 I8 2-methyl-3-ethylpentane 0.0032 0.0041 0.0026 240.098 115.61
7.175 767.84 unknown 0.001 0.0014 0.0008 240.098 115.61
7.2769 770.34 I8 2-methylheptane 0.1543 0.2048 0.1264 243.77 117.65

PETROPERU
.

Minutes Index Group Component Mass % Volume % Mole % BP(F) BP( C)

7.3342 771.73 I8 4-methylheptane 0.0453 0.0596 0.0371 243.878 117.71
7.3792 772.81 I8 3-methyl-3-ethylpentane 0.0105 0.0136 0.0086 240.098 115.61
7.4875 775.38 N8 1c,2c,4-trimethylcyclopentane 0.0053 0.0065 0.0045 242.168 116.76
7.5656 777.21 I8 3-methylheptane 0.0946 0.1241 0.0775 246.074 118.93
7.6121 778.28 N8 1c,2t,3-trimethylcyclopentane 0.1162 0.1397 0.0969 243.5 117.5
7.6858 779.98 N8 1t,4-dimethylcyclohexane 0.0499 0.0606 0.0416 246.848 119.36
7.8975 784.73 N8 1,1-dimethylcyclohexane 0.0171 0.0203 0.0142 247.19 119.55
7.9908 786.79 I9 2,2,5-trimethylhexane 0.003 0.0039 0.0022 255.362 124.09
8.0408 787.87 N8 3c-ethylmethylcyclopentane 0.0098 0.0118 0.0081 249.98 121.1
8.1275 789.74 N8 3t-ethylmethylcyclopentane 0.0084 0.0101 0.007 249.98 121.1
8.1775 790.81 N8 2t-ethylmethylcyclopentane 0.0182 0.0219 0.0152 250.16 121.2
8.2558 792.47 N8 1,1-methylethylcyclopentane 0.0031 0.0036 0.0025 250.754 121.53
8.3641 794.73 N8 1t,2-dimethylcyclohexane 0.0442 0.0527 0.0368 254.174 123.43
8.6226 800 P8 n-octane 0.3837 0.5059 0.3142 258.224 125.68
8.8508 805.91 unknown 0.0026 0.0034 0.0075 258.224 125.68
8.9393 808.15 N8 i-propylcyclopentane 0.0063 0.0075 0.0053 259.574 126.43
9.0364 810.59 I9 2,4,4-trimethylhexane 0.0006 0.0007 0.0004 32 0
9.0852 811.8 unknown 0.0006 0.0008 0.0004 32 0
9.1882 814.34 N8 N8-[1] 0.0039 0.0046 0.0032 32 0
9.2844 816.68 I9 2,2,3,4-tetramethylpentane 0.0027 0.0034 0.002 271.454 133.03
9.3567 818.42 I9 2,3,4-trimethylhexane 0.0029 0.0036 0.0021 282.308 139.06
9.441 820.43 N8 N8-[2] 0.0057 0.0067 0.0047 282.308 139.06
9.6177 824.58 N8 1c,2-dimethylcyclohexane 0.0202 0.0235 0.0168 265.532 129.74
9.6447 825.21 I9 2,3,5-trimethylhexane 0.003 0.0038 0.0022 268.43 131.35
9.6747 825.9 unknown 0.0016 0.0021 0.0011 268.43 131.35
9.7417 827.44 I9 2,2-dimethylheptane 0.0009 0.0012 0.0007 270.86 132.7
9.8505 829.92 N9 1,1,4-trimethylcyclohexane 0.0748 0.0897 0.0554 275 135
9.918 831.45 I9 2,2,3-trimethylhexane 0.0461 0.0596 0.0336 271.22 132.9
10.0003 833.29 I9 2,4-dimethylheptane 0.0029 0.0037 0.0021 271.22 132.9
10.0974 835.44 I9 4,4-dimethylheptane 0.0486 0.0629 0.0354 271.22 132.9
10.2258 838.25 I9 2,5-dimethylheptane 0.035 0.0452 0.0255 276.8 136

PETROPERU
.

Minutes Index Group Component Mass % Volume % Mole % BP(F) BP( C)

10.2928 839.7 N9 *1c,3c,5-trimethylcyclohexane 0.0066 0.008 0.0049 281.174 138.43
10.3474 840.87 I9 2,6-dimethylheptane 0.0034 0.0044 0.0025 275.396 135.22
10.4074 842.15 N9 1,1,3-trimethylcyclohexane 0.006 0.0071 0.0045 295.862 146.59
10.4874 843.85 N9 1c,2t,4t-trimethylcyclohexane 0.0033 0.0039 0.0024 32 0
10.7128 848.56 A8 ethylbenzene 0.0158 0.0169 0.014 277.16 136.2
10.7674 849.68 unknown 0.0099 0.0132 0.0291 277.16 136.2
10.8513 851.39 N9 1c,3c,5c-trimethylcyclohexane 0.0204 0.0242 0.0151 32 0
10.9538 853.47 unknown 0.0014 0.0018 0.001 32 0
11.0592 855.58 I9 I9-[1] 0.0056 0.0071 0.0041 32 0
11.1681 857.74 A8 1,3-dimethylbenzene 0.044 0.0472 0.0388 282.416 139.12
11.2285 858.92 A8 1,4-dimethylbenzene 0.013 0.014 0.0115 281.048 138.36
11.2909 860.14 unknown 0.0222 0.0293 0.0648 281.048 138.36
11.4 862.26 I9 2,3-dimethylheptane 0.0022 0.0028 0.0016 284.9 140.5
11.4651 863.51 I9 3,5-dimethylheptane 0.008 0.0102 0.0058 276.8 136
11.5735 865.57 N9 N9-[1] 0.0059 0.007 0.0044 276.8 136
11.6052 866.17 I9 I9-[2] 0.0011 0.0014 0.0008 276.8 136
11.7505 868.9 I9 4-methyloctane 0.0301 0.0387 0.022 288.392 142.44
11.8124 870.05 I9 2-methyloctane 0.0415 0.0539 0.0303 289.904 143.28
11.9414 872.43 N9 1c,2t,3c-trimethylcyclohexane 0.0057 0.007 0.0042 304.16 151.2
12.1008 875.32 I9 3-ethylheptane 0.0138 0.0175 0.01 289.4 143
12.1852 876.84 I9 3-methyloctane 0.0475 0.061 0.0346 291.614 144.23
12.2452 877.92 I9 3,3-diethylpentane 0.0024 0.0029 0.0017 270.842 132.69
12.3345 879.5 N9 1c,2t,4c-trimethylcyclohexane 0.0023 0.0028 0.0017 275 135
12.3978 880.62 A8 1,2-dimethylbenzene 0.0286 0.0301 0.0252 291.974 144.43
12.4705 881.89 unknown 0.0045 0.0059 0.0039 291.974 144.43
12.6085 884.29 I9 I9-[3] 0.0015 0.0019 0.0011 291.974 144.43
12.7381 886.51 I9 I9-[4] 0.0082 0.0104 0.006 291.974 144.43
12.7788 887.21 N9 N9-[2] 0.0272 0.0323 0.0202 291.974 144.43
12.8851 889.01 N9 N9-[3] 0.0173 0.0205 0.0128 291.974 144.43
13.0294 891.43 I9 I9-[5] 0.0023 0.0029 0.0017 291.974 144.43
13.0951 892.52 N9 i-butylcyclopentane 0.0043 0.0052 0.0032 298.346 147.97

PETROPERU
.

Minutes Index Group Component Mass % Volume % Mole % BP(F) BP( C)

13.3258 896.31 N9 N9-[4] 0.0033 0.0039 0.0024 298.346 147.97
13.4441 898.22 N9 N9-[5] 0.002 0.0024 0.0015 298.346 147.97
13.5548 900 P9 n-nonane 0.1498 0.1933 0.1092 303.476 150.82
13.6378 902.69 N9 1,1-methylethylcyclohexane 0.0178 0.0205 0.0132 305.924 152.18
13.7307 905.7 unknown 0.0045 0.006 0.0034 305.924 152.18
13.752 906.38 N9 N9-[6] 0.003 0.0035 0.0022 305.924 152.18
13.8229 908.65 N9 N9-[7] 0.001 0.0012 0.0008 305.924 152.18
13.9464 912.58 A9 i-propylbenzene 0.0036 0.0038 0.0028 306.338 152.41
14.0678 916.4 N9 N9-[8] 0.0138 0.0162 0.0102 306.338 152.41
14.1618 919.34 N9 i-propylcyclohexane 0.0065 0.0075 0.0048 310.622 154.79
14.2651 922.54 I10 2,4-dimethyloctane 0.0038 0.0048 0.0025 312.62 155.9
14.3514 925.2 I10 2,2-dimethyloctane 0.0114 0.0145 0.0075 314.42 156.9
14.3891 926.35 N9 N9-[9] 0.0026 0.0031 0.002 314.42 156.9
14.503 929.83 N9 N9-[10] 0.0025 0.003 0.0019 314.42 156.9
14.59 932.46 I10 2,6-dimethyloctane 0.0212 0.0269 0.0139 320.738 160.41
14.6251 933.51 I10 2,5-dimethyloctane 0.0098 0.0124 0.0064 317.3 158.5
14.6864 935.35 unknown 0.0002 0.0003 0.0006 317.3 158.5
14.7646 937.69 N10 N10-[1] 0.0087 0.01 0.0058 317.3 158.5
14.8205 939.35 unknown 0.0041 0.0054 0.0027 317.3 158.5
14.887 941.32 I10 I10-[1] 0.0029 0.0037 0.0019 317.3 158.5
14.9528 943.25 I10 3,3-dimethyloctane 0.0296 0.0371 0.0195 322.16 161.2
15.0159 945.1 N10 N10-[2] 0.0055 0.007 0.0036 322.16 161.2
15.0819 947.03 A9 n-propylbenzene 0.0104 0.0111 0.0081 318.632 159.24
15.1503 949.01 I10 3,6-dimethyloctane 0.0054 0.0068 0.0036 321.44 160.8
15.201 950.48 I10 3-methyl-5-ethylheptane 0.0117 0.0149 0.0077 316.76 158.2
15.2857 952.92 N10 N10-[3] 0.0039 0.0045 0.0026 316.76 158.2
15.3534 954.85 A9 1,3-methylethylbenzene 0.0187 0.02 0.0146 322.394 161.33
15.3849 955.75 unknown 0.0022 0.003 0.0017 322.394 161.33
15.4212 956.78 A9 1,4-methylethylbenzene 0.0082 0.0089 0.0064 323.618 162.01
15.472 958.22 N10 N10-[4] 0.0005 0.0006 0.0003 323.618 162.01
15.5388 960.11 unknown 0.0116 0.0154 0.0078 323.618 162.01

PETROPERU
.

Minutes Index Group Component Mass % Volume % Mole % BP(F) BP( C)

15.6166 962.3 A9 1,3,5-trimethylbenzene 0.0124 0.0133 0.0097 328.532 164.74
15.6494 963.21 unknown 0.0058 0.0077 0.0045 328.532 164.74
15.6929 964.43 I10 I10-[2] 0.0069 0.0087 0.0046 328.532 164.74
15.7624 966.36 N10 N10-[5] 0.0035 0.0041 0.0024 328.532 164.74
15.7801 966.86 I10 I10-[3] 0.001 0.0013 0.0007 328.532 164.74
15.8392 968.49 I10 5-methylnonane 0.0051 0.0064 0.0033 329.18 165.1
15.8945 970.01 I10 4-methylnonane 0.0188 0.0236 0.0124 32 0
15.914 970.55 A9 1,2-methylethylbenzene 0.0069 0.0073 0.0054 329.324 165.18
15.9787 972.32 I10 2-methylnonane 0.0183 0.0234 0.012 332.654 167.03
16.0298 973.72 unknown 0.0034 0.0045 0.0023 332.654 167.03
16.077 975 I10 3-ethyloctane 0.0049 0.0061 0.0032 331.7 166.5
16.1222 976.23 N10 N10-[6] 0.0046 0.0053 0.0031 331.7 166.5
16.18 977.79 I10 3-methylnonane 0.0164 0.0207 0.0108 334.04 167.8
16.2148 978.73 I10 I10-[4] 0.0055 0.0069 0.0036 334.04 167.8
16.2997 981.01 I10 I10-[5] 0.0013 0.0016 0.0008 334.04 167.8
16.3956 983.57 A9 1,2,4-trimethylbenzene 0.0342 0.0362 0.0266 336.884 169.38
16.454 985.13 unknown 0.0114 0.0151 0.0089 336.884 169.38
16.5341 987.24 N10 i-butylcyclohexane 0.0126 0.0147 0.0084 340.34 171.3
16.574 988.29 unknown 0.0027 0.0035 0.0018 340.34 171.3
16.5989 988.95 I10 I10-[6] 0.0022 0.0027 0.0014 340.34 171.3
16.6492 990.27 I10 I10-[7] 0.0038 0.0047 0.0025 340.34 171.3
16.6895 991.32 I10 I10-[8] 0.0023 0.0029 0.0015 340.34 171.3
16.7253 992.25 N10 N10-[7] 0.0007 0.0008 0.0004 340.34 171.3
16.8018 994.24 N10 1t-methyl-2-n-propylcyclohexane 0.0028 0.0032 0.0019 339.8 171
16.8504 995.5 A10 i-butylbenzene 0.0071 0.0077 0.005 343.022 172.79
16.9564 998.23 A10 sec-butylbenzene 0.0034 0.0037 0.0024 344.012 173.34
16.9741 998.69 unknown 0.003 0.004 0.0021 344.012 173.34
17.0252 1000 P10 n-decane 0.0895 0.1135 0.0588 345.47 174.15

PETROPERU