UNIT TEST II 2021-22

CLASS : XII
SUBJECT: CHEMISTRY (043)
TIME: 90 min. M.M: 35
General Instructions:
1. The Question Paper contains three sections.
2. Section A has 25 questions. Attempt any 20 questions
3. Section B has 24 questions. Attempt any 20 questions.
4. Section C has 6 questions. Attempt any 5 questions.
5. All questions carry equal marks.
6. There is no negative marking
SECTION A
This section consists of 25multiple choice questions with overall choice to attempt any 20
questions. In case more than desirable number of questions are attempted, ONLY first 20
will be considered for evaluation.

1.Which of the following crystals does not exhibit Frenkel defect?

(a) AgBr (b) AgCl (c) KBr d) ZnS

2.In which pair most efficient packing is present?

(a) hep and bcc (b) hep and ccp
(c) bcc and ccp (d) bcc and simple cubic cell

3. The system that forms maximum boiling azeotrope is

(a) Acetone-chloroform (b) ethanol-acetone
(c) n-hexane-n-heptane (d) carbon disulphide-acetone

4.For carrying reverse osmosis for desalination of water the material used for making
semipermeable membrane is
(a) potassium nitrate (b) parchment membrane
(c) cellulose acetate (d) cell membrane

5.Which oxide of nitrogen is obtained on heating ammonium nitrate at 250°C ?

(a) Nitric oxide (b) Nitrous oxide (c) Nitrogen dioxide (d) Dinitrogen Tetraoxide

6.Arrange the following hydrides of group 16 elements in order of increasing stability

(a) H2S < H2O < H2Te > H2Se
(b) H2O < H2Te < H2Se < H2S
(c) H2O < H2S < H2Se < H2Te
(d) H2Te < H2Se < H2S < H2O
7.Which of the following compounds has the highest boiling point?
(a) CH3CH2CH2Cl (b) CH3CH2CH2CH2Cl
(c) CH3CH(CH3)2 (d) (CH3)3CCl
8.Which of the following molecules has highest dipole moment?
(a) CH3Cl (b) CH2Cl2 (c) CHCl3 (d) CCl4

9.Which of the following alcohols will give the most stable carbocation during dehydration?
(a) 2-methyl-1-propanol
(b) 2-methyl-2-propanol
(c) 1-Butanol
(d) 2-Butanol

10.The Product formed when hot NaOH reacts with Cl2 is

(a) NaClO (b) NaClO3 (c) NaClO4 (d) NaClO2

11. An unknown alcohol is treated with “Lucas reagent” to determine whether the alcohol is
primary, secondary or tertiary. Which alcohol reacts fastest and by what mechanism?
(a) Tertiary alcohol by S N2
(b) Secondary alcohol by SN1
(c) Tertiary alcohol by SN1
(d) Secondary alcohol by SN2

12.Conversion of phenol to salicylic acid and to salicyldehyde are known as (respectively)

(a) Reimer-Tiemann reaction and Kolbe’s reaction
(b) Williamson’s synthesis and Hydrobration-oxidation
(c) Kolbe’s reaction and Williamson’s synthesis
(d) Kolbe’s reaction and Reimer-Tiemann reaction

13. Denaturation of protein leads to loss of its biological activity by

(a) formation of amino acids
(b) loss of primary structure
(c) loss of both primary and secondary structure
(d) loss of both secondary and tertiary structures

14. Fluorine differs from rest of the halogens in some of its properties. This is due to
(a) its smaller size and high electronegativity.
(b) lack of d-orbitals.
(c) low bond dissociation energy.
(d) All of the these.

15. Which of the following will have metal deficiency defect?

(a) NaCl (b) FeO (c) KCl (d) ZnO
16. Which of the statement is incorrect for XeO4 ?
(a) Four p -d bonds are present
(b) Four sp3 – p bonds are present
(c) It has a tetrahedral shape
(d) It has a square planar shape
17. If 0.1M solution of Glucose and 0.1 M solution of Urea are placed on to sides of the
semipermeable membrane to equal heights , then it will be correct to say that
(a) There will be no net movement across the membrane
(b) Glucose will flow towards urea solution
(c) Urea will flow towards glucose solution
(d) Water will flow from urea solution to glucose .

18. .Which of the following reagents can not, be used to oxidise primary alcohols to aldehydes?
(a) CrO3 in anhydrous medium
(b) KMnO4 in acidic medium
(c) Pyridinium chloro chromate
(d) Heat in the presence of Cu at 573 K

19. Which of the following reactions of glucose can be explained only by its cyclic structure.
(a) Glucose forms pentaacetate
(b) Glucose reacts with hydroxylamine to form an oxime
(c) Pentaacetate of glucose does not react with hydroxylamine.
(d) Glucose is oxidized by nitric acid to gluconic acid.

20. Which of the following is not the characteristic of ionic solids?

(a) Very low value of electrical conductivity in the molten state.
(b) Brittle nature.
(c) Very strong forces of interactions.
(d) Anisotropic nature

21. Fitting reaction can be used to prepare

(a) Toluene (b) Acetophenone
(c) Diphenyl (d) Chlorobenzene
.
22. p-dichlorobenzene has higher melting point than its o- and m- isomers because
(a) p-dichlorobenzene is more polar than o- and m- isomer.
(b) p-isomer has a symmetrical crystalline structure.
(c) boiling point of p-isomer is more than o- and m-isomer.
(d) All of these are correct reasons.

23.. Which is the correct order of decreasing bond dissociation enthalpy?

(a) F2 > Cl2 > Br2 > I2
(b) I2 > Br2 > Cl2 > F2
(c) Cl2 > Br2 > F2 > I2
(d) Br2 > I2 > F2 > Cl2

24. The mole fraction of the solute in one molal aqueous solution is
a. 0.009 b) 0.018 c) 0.027 d) 0.036
25. The helical structure of protein is stabilized by:
(a) Peptide bond (b) Dipeptide bond
(c) Hydrogen bonds (d) vander Waal’s forces

SECTION B
This section consists of 24multiple choice questions with overall choice to attempt any 20
questions. In case more than desirable number of questions are attempted, ONLY first 20 will
be considered for evaluation.

26.. Acetone reacts with Grignard reagent to form

(a) 3° alcohol (b) 2° alcohol
(c) ether (d) 1°alcohol

27. A mixture of 1-chloropropane and 2-chloropropane when treated with alcoholic KOH gives
(a) prop-1-ene (b) prop-2-ene
(c) a mixture of prop-1 -ene and prop-2-ene (d) propanol

Q.28. Edge length of unit cell of chromium metal is 287 pm with bcc arrangement. The atomic
radius is of the order
(a) 287 pm (b) 574 pm (c) 124.27 pm (d) 143.5 pm

29.. The density of a solution prepared by dissolving 129g of urea in 1000g of water is 1.15g/ml.
The molarity of this solution is
a. 1.78M b)1.02M c) 2.05M d) 0.50M

30. Strength of acidity is in order:

(a) II > I > III > IV (b) III > IV > I > II
(c) I > IV > III > II (d) III > IV > II> I

31. The most common secondary structure of proteins is

a. β-pleated sheet c) β-pleated sheet non-parallel
b. β-pleated sheet parallel d) α-helix
32. Which of the following statement is incorrect for group 15 elements ?
(a) Order of ionization enthalpies is ΔiH1 < ΔiH2 < ΔiH3
(b) The boiling point and melting point increases from top to bottom in the group
(c) Dinitrogen is a gas while all others are solids
(d) All statements are correct.

33. Identify the end product (C) in the following sequence:

34. The set with correct order of acidity is

(a) HClO < HClO2 < HClO3 < HClO4
(b) HClO4 < HClO3 < HClO2 < HClO
(c) HClO < HClO4 < HClO3 < HClO2
(d) HClO4 < HClO2 < HClO3 < HClO

35. What is the correct order of reactivity of group 16 elements?

a) O > Se > S > Te > Po
b) S > O > Te > Po > Se
c) S > O > Se > Te > Po
d) O > S > Se > Te > Po

36. XeF2 is isostructural with

a) ICl-2 b) SbCl3 c)BaCl2 d) TeF2

37. . The increasing order of reducing power of the halogen acids is

(a) HF < HCl < HBr < HI
(b) HI < HBr < HCl < HF
(c) HBr < HCl < HF < HI
(d) HCl < HBr < HF < HI

38. 2- Methoxy – 2- methyl propane on heating with HI would produce

a) Methyl alcohol and sec-propyl iodide. b) Methyl iodide and tert-butyl alcohol.
c)- Methyl iodide and isobutene. d) Methyl alcohol and tert- butyl iodide.

39. In the following reaction C6H5CH2Br --------------------X , the product X‖ is

Mg, Ether & H2O,

a) C6H5CH2OCH2C6H5 b) C6H5CH3 c) C6H5CH2CH2C6H5 d) C6H5CH2OH

40.. Which of the following alkyl halides will undergo SN1 reaction most readily?
(a) (CH3)3 C—F (b) (CH3)3 C—Cl
(c) (CH3)3 C—Br (d) (CH3)3 C—I

41. What weight of glycerol should be added to 600 g of water in order to lower its freezing
point by 10°C ?
(a) 496 g (b) 297 g (c) 310 g (d) 426 g

42. Each polypeptide in a protein has amino acids linked with each other in a specific sequence.
This sequence of amino acids is said to be–
(a) primary structure of proteins. (c) tertiary structure of proteins.
(b) secondary structure of proteins. (d) quaternary structure of proteins .

43. Which of the following is not correctly matched?

(a) Acidic oxides-P2O5 NO2, Cl2O7
(b) Basic oxides-Na2O, CaO, MgO
(c) Neutral oxides-CO2, CO, BeO
(d) Amphoteric oxides-ZnO, SnO,Al2O3
.
44.Which of the following reactions will give the major and minor products?

(a) (a) is major product and (b) is minor product

(b) (a) is minor product and (b) is major product
(c) Both (a) and (b) are major products
(d) Only (b) is formed and (a) is not formed

45. Given below are two statements labelled as Assertion (A) and Reason (R)

Assertion : When a metal is treated with conc. HNO3 it generally yields a nitrate,NO2 and H2O.
Reason : Conc. HNO3 reacts with metal and first produces a metal nitrate and nascent
hydrogen. The nascent hydrogen then further reduces HNO3 to NO2

Select the most appropriate answer from the options given below:
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true but R is not the correct explanation of A.
(c ) A is true but R is false.
(d) A is false but R is true.
46. Given below are two statements labelled as Assertion (A) and Reason (R)

Assertion : SN2 reaction of an optically active aryl halide with an aqueous solution of KOH
always gives an alcohol with opposite sign of rotation.
Reason : SN2 reactions always proceed with inversion of configuration

Select the most appropriate answer from the options given below:

(a) Both A and R are true and R is the correct explanation of A

(b) Both A and R are true but R is not the correct explanation of A.
(c )A is true but R is false.
(d) A is false but R is true

47.Given below are two statements labelled as Assertion (A) and Reason (R)

Assertion : If a liquid solute more volatile than the solvent is added to the solvent, the vapour
pressure of the solution may increase i.e., ps > po.
Reason : In the presence of a more volatile liquid solute, only the solute will form the vapours
and solvent will not.

Select the most appropriate answer from the options given below:
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true but R is not the correct explanation of A.
(c )A is true but R is false.
(d) A is false but R is true

48. Given below are two statements labelled as Assertion (A) and Reason (R)

Assertion : Bond angle of H2S is smaller than H2O.

Reason : Electronegativity of the central atom increases, bond angle decreases.

Select the most appropriate answer from the options given below:
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true but R is not the correct explanation of A.
(c )A is true but R is false.
(d) A is false but R is true.

49. Given below are two statements labelled as Assertion (A) and Reason (R)

Assertion : When NaCl is added to water a depression in freezing point is observed.

Reason : The lowering of vapour pressure of a solution causes depression in the freezing point.

Select the most appropriate answer from the options given below:
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true but R is not the correct explanation of A.
(c )A is true but R is false.
(d) A is false but R is true
SECTION C
This section consists of 6multiple choice questions with an overall choice to attempt any5. In
case more than desirable number of questions are attempted, ONLY first 5 will be considered
for evaluation

50. Match the items given in Column I and Column II in the following question.

Column I Column II
(i) SN1 reaction (A) vic dibromide
(ii) Bromination of alkene ( B) Saytzeff rule
(iii) Alkylidene halide ( C) Racemisation
(iv) Elimination of HX from alkyl halide (D) gem dihalide

a) iC , ii-A , iii--D , iv--- B

b) iB , ii-C , iii--A , iv--- D
c) iC , ii-D, iii--A, iv--- B
d) iD , ii-A , iii--B , iv--- C

51 . Which compound can exist in a dipolar (zwitter ion) structure?

(a) C6H5CH2CH (N = CH2) COOH
(b) (CH3)2CHCH (NH2) COOH
(c) C6H5CONHCH2COOH
(d) HOOCCH2CH2COCOOH

52.A solution containing 10.2 g glycerine per litre is isotonic with a 2% solution of glucose. What
is the molecular mass of glycerine?
(a) 91.8 g (b) 1198 g (c) 83.9 g (d) 890.3 g

Case : Read the following passage and answer the questions that follow:

Solids may be classified as amorphous and crystalline. Amorphous solids are isotropic where as
crystalline solids are anisotropic. Solids can also be classified on the basis of type of forces of
attraction as ionic, covalent, metallic and molecular solids. Unit cells represent crystal lattice.
Types of crystal lattice-bcc, fcc, simple cubic, end centred cubic are most common in seven
crystal systems and 14 bravais lattices. The constituent particles arrange in square close
packing, bcc, fcc, hcp. Packing efficiency of hcp and fcc is 74%, bcc 68% and simple cubic
packing (52%). The vacant sites in packing are called voids, tetrahedral and octahedral being
most common. Density of solids can be calculated by using d = Z M/ a3N0 . There are defects in
crystal lattice, point defects like Frenkel and Schottky. Non-stoichiometric defects are metal
excess type and metal deficient type and impurity defects. These defects affects properties of
solids..

53.Which type of defects are shown by ZnS?

54. A compound is formed by cation ‘C’ which occupy 75% of octahedral voids and anion ‘A’
form hcp. What is formula of compound?

55. What happens when ZnO is heated and why?

.