JEE Main 2022 July Session 2 Shift-1 (DT 26-07-2022) Chemistry

JEE (Main)
PAPER-1 (B.E./B. TECH.)
2022
COMPUTER BASED TEST (CBT)
Memory Based Questions & Solutions
Date: 26 July, 2022 (SHIFT-1) | TIME : (9.00 a.m. to 12.00 p.m)
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Duration: 3 Hours | Max. Marks: 300
SUBJECT: CHEMISTRY
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| JEE MAIN-2022 | DATE : 26-07-2022 (SHIFT-1) | PAPER-1 | MEMORY BASED | CHEMISTRY
PART : CHEMISTRY
1. In the reaction
2BeCl2 + LiAlH4
Product formed among the following are :
(a) LiH (b) BeH2 (c) LiCl (d) LiH2
(e) AlCl3
(1) b, c, e only (2) a, b, c only (3) c, d, e only (4) b, e only
Ans. (1)
Sol. 2BeCl2 + LiAlH4  2BeH2 + LiCl + AlCl3
2. List-1 List-2
(I) PCl5 (a) Square pyramidal
(II) [CoCl6]3– (b) Trigonal bipyramidal
(III) O3 (c) Octahedral
(IV) BrF5 (d) Angular/Bent
Identify correct match :
I II III IV
(1) b c d a
(2) a a c d
(3) c b d a
(4) b c a d
Ans. (1)
Cl
Cl
Sol. (I) PCl5  P Cl Trigonal bipyramid

Cl
Cl
–
Cl
Cl Cl
Co
(II) [CoCl6]3–  Cl Cl Octahedral
Cl
O
(III) O3  Bent or angular
O O
F
F F
(IV) BrF5  Br Square pyramid
F F
3. In 2 Lit solution concentration of Mg is 42 ppm, then concentration of Mg in solution in molarity is

x × 10–5 M then value of x is :
Ans. (175)

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WMg
Sol. ppm(w/v) = × 106
Volum e of s olution
WMg
42 = × 106
2  103
42  2  103
W mg = = 84 × 10–3 gram
10 6
 84  10–3 
Molarity =   = 1.75 × 10–3 M = 175 × 10–5 M
 24  2 
4. For the reaction

2Ag+(aq) + Cu(s) 2Ag(s) + Cu2+ (aq) K = 2×1015 and for reaction
1 2 1
Cu + 2Ag(s) Ag+(aq) + Cu(s) K = [x] × 10–8
2 2
then value of x is :
[Report your answer to nearest integer]
Ans. (2)
Sol. 2Ag+(aq) + Cu(s) 2Ag(s) + Cu2+ (aq) K = 2×1016
1/ 2
1 2 1  1
Cu + 2Ag(s) Ag+ + Cu(s) K' =  
2 2 k 
1/ 2 1/ 2
 1  1 
K' =   =   10–15 
 2  1015  2 
K' = 5 × 10–8 = 2.24 × 10–8
5. Liquiation process is used for purification of

(1) Metal which have lower melting point than each impurities.
(2) Metal which have high melting point than each impurities.
(3) Metal which have low boiling point than each impurities.
(4) Metal which have high boiling point than each impurities.
Ans. (1)
Sol. Liquation process : This process is used for the purification of the metal, which itself is readily fusible,
but the impurities present in it are not, i.e., the impurities are infusible. In other words, we can say that
the melting point of the metal to be purified should be lower than that of each of the impurities associated
with the metal.
6. For the reaction

A  2B + C
If initial concentration of A is 0.5 M then half life is 100 sec and if initial concentration of A is 1 M then half
life is 50 sec, find order of the reaction.
Ans. (2)

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1n
Sol.
T1/ 2    C1 
C 
(T1/ 2 )  2
1n
 100   0.5 
  =  
 50   1 
(2) = (2)–1
1 – n = –1
n=2
7. In hydrogen-oxygen mixture mass percentage of hydrogen is 40% and total pressure of mixture is 2.2
pascal, then portial pressure of hydrogen is _______ pascal.
Ans. (2)
Sol. Let total mass of mixture = 100 gram
mass of oxygen = 60 gram
Hydrogen Oxygen
 40   60 
mole    
 2   32 
 15 
= 20 mole  
 8 
20 20 20 8 160
XH2 = = = = = 0.914
 15   160  15  175 175
 20    
 8   8 
160
PH2 = [PTotal] XH2 = 2.2 ×  2 pascal.
175
8. Borazine is known as inorganic benzene it is formed by 3 equivalent of X and 6 equivalent of Y, then X

and Y are respectively.
(1) B2H6, NH3 (2) NH3, B2H6 (3) B2O3, NH3 (4) B2O3, NH3
Ans. (1)
r
Sol. B2H6 + NH3    B3N3H6 [Borazine]
High Temp
T  200 C
ratio 1 : 2
9. To prevent explosive decomposition of H2O2 following compound are added.

(1) Urea (2) Formaldehyde (3) Formic acid (4) Lime stone
Ans. (1)
Sol. H2O2 is not kept in Glass container because traces of alkali metal ion from glass can catalysed explosive
decomposition of H2O2. So it is stored in plastic or wax lined glass container with some urea or glycerol
(which acts as negative catalyst).
10. Difference in Magnetic moment (spin only) of [Co(H2O)6]Cl2 and [Cr(H2O)6]Cl3 is

(1) 0 (2) 4 (3) 2 (4) 3
Ans. (1)

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Sol. (spin only) = n (n  2) BM

n = number of unpaired e–
[Co(H2O)6]Cl2  Co2+  3d7  t 22,g2,1 , e1g, 1 unpaired e– = 3
[Cr(H2O)6]Cl3  Cr3+  3d3  t 12,1g,1 , e 0g, 0 unpaired e– = 3

so difference in magnetic moment = 0
11. List – I List – II

(Reaction / process) (Catalyst)
(I) N2 + 3H2  2NH3 (a) Fe
(II) 4NH3(g) + 5O2(g)  4NO + 6H2O (b) Ni
(III) Vegetable oil + H2  Vegetable ghee (c) V2O5
(IV) 2SO2 + O2  2SO3 (d) Pt
I II III IV
(1) a d b c
(2) a b c d
(3) d a b c
(4) a d c b
Ans. (1)
Sol. Catalyst
(I) N2 + 3H2  2NH3 Fe
(II) 4NH3 + 5O2  4NO + 6H2O Platinised asbestos
(III) Vegetable oil + H2   Vegetable ghee
Ni ( Catalyst )
Ni
Cu (Pr omotor )
Platinised asbestos [ Catalyst ]

(IV) 2SO2 + O2    2SO3 V2O5
As 2 S 3 ( Catalysic poisons ) V2 O 5
12. Statement I : Ionic radius of Cl– ion is double than parent atom.
Statement II : Anion radius is always greater than parent atom.
(1) Both Statement I & Statement II are true (2) Statement I is true & Statement II is false.
(3) Statement I is false & Statement II is true (4) Both Statement I & Statement II are false.
Ans. (1)
Sol. Ionic Radius of Cl– = 167 pm
Covalent Radius of Cl = 99 pm
13. KMnO4 is used as oxidising agent in acidic medium then difference in oxidation state of Mn in KMnO 4
and product is :
(1) 2 (2) 3 (3) 4 (4) 5
Ans. (4)
7 2
Sol. MnO 4– + 8H+ + 5e–  Mn 2  + 4H2O
difference in oxidation state of Mn = 5

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14. 0.5 M, 800 ml HNO3 solution on heating volume become half and 11. 2 gram HNO 3 also evaporate, then
find molarity of resulting HNO3 solution.
[Molar amass of HNO3 = 63 gram/mole]
(1) 0.56 M (2) 1.12 M (3) 0.23 M (4) 1 M
Ans. (1)
Sol. Mole of HNO3 = 0.5 × 0.8 = 0.4
Mass of HNO3 = 0.4 × 63 = 25.2 gram
After heating volume of solution = 400 ml
mass of HNO3 = 25.2 – 11.2 = 14
14  1000 
Molarity (M) =   = 0.56 M
 63  400 
15. How many faraday's charge is required to deposit 1 mole of Fe from Fe 3O4
[Report your answer to nearest integer]
Ans. (3)
2 3
Sol. Fe3O4  FeO + Fe 2 O 3
Fe3O4 + 8H+ + 8e–  3Fe + 4H2O
8
mole 1 mole
3
8
charge =   F = 2.67 F
3
16. Among the following in which disproportionation is not occur

(1) 3MnO42– + 4H+  2MnO4– + MnO2 + 2H2O
(2) H2O2  H2O + O2
(3) KMnO4  
 K2MnO4 + MnO2 + O2
750 K
–
(4) ClO3–  ClO4– + Cl
Ans. (3)
Sol. In disproportionation reaction an element from one particular oxidation state oxidise & reduce.
17. Total number of Mn–Mn bond and Mn–CO bond in Mn2(CO)10 is…….
Ans. (11)
Sol.
Number of Mn–Mn bond = 1

Number of Mn–CO bond = 10

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18. For 7 mole of monoatomic ideal gas calculate U If T = 40 K

[Given R = 8.3 J]
(1) 3492 J (2) 5820 J (3) 8148 J (4) 2328 J
Ans. (1)
F
Sol. U = nRT
2
3
= × 7 × 8.3 × 40 = 3491.88 J
2
19. Chlorophyll is a complex of _______

(1) Mg (2) Ca (3) P (4) C
Ans. (1)
Sol. Chlorophyll, is a complex compound of magnesium.
20. Which is more stable

N2+Cl– N2+Cl– N2+Cl– N2+Cl–
(a) (b) (c) (d)
NO2 CN OCH3

(1) d > c > b > a (2) b > c > d > a (3) c > d > a > b (4) c > b > d > a
Ans. (1)
[ Ag (NH ) ]  NaBH
21.    
3 2
 A 
4
 B
CHO
O OH OH O
(1) A = ;B= (2) A = ;B=
COO– COO– COO– COO–

O OH O OH
(3) A = ;B= (4) A = ;B=
CH2OH CH2OH O OH
Ans. (1)

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h
22. + 3Cl2  No. of hydrogen in Product.
500 K
(1) 6 (2) 4 (3) 12 (4) 3

Ans. (1)
Cl
Cl Cl
h
Sol. + 3Cl2 
Cl Cl
Cl
(BHC)
Benzene Hexachloride
23. Which compound is non-aromatic
(1) (2)
 
(3) (4)
Ans. (3)
Aromatic Aromatic
Sol.
 
Non-Aromatic Aromatic
24. Clº + CH4  A + B

(1) CH3• + HCl (2) CH3Cl + HCl (3) CH2Cl2 + HCl (4) CH3Cl + Cl2
Ans. (1)
•
Sol. Cl– + CH4  C H3 + HCl
25. Stearic acid + Polyethylene glycol A

A is -
(1) Anionic detergent (2) Cationic Detergent
(3) Nonionic Detergent (4) Soop
Ans. (3)
Sol. fact

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Ph
26. PhMgBr + x  Ph–C–CH3
OH
What is x -
Ph CH3 Ph Ph
(1) C=O (2) C=O (3) C=O (4) C=O
H3C H3C Ph C2H5
Ans. (1)
Ph Ph
 Ph
H+
Sol. PhMgBr + C=O Ph–C–O Ph–C–OH
H3C
OH CH3

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JEE (Main)

PAPER-1 (B.E./B. TECH.)

Duration: 3 Hours | Max. Marks: 300

Resonance Eduventures Ltd.

Sol. (I) PCl5  P Cl Trigonal bipyramid

3. In 2 Lit solution concentration of Mg is 42 ppm, then concentration of Mg in solution in molarity is

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4. For the reaction

5. Liquiation process is used for purification of

6. For the reaction

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8. Borazine is known as inorganic benzene it is formed by 3 equivalent of X and 6 equivalent of Y, then X

9. To prevent explosive decomposition of H2O2 following compound are added.

10. Difference in Magnetic moment (spin only) of [Co(H2O)6]Cl2 and [Cr(H2O)6]Cl3 is

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Sol. (spin only) = n (n  2) BM

[Cr(H2O)6]Cl3  Cr3+  3d3  t 12,1g,1 , e 0g, 0 unpaired e– = 3

11. List – I List – II

Platinised asbestos [ Catalyst ]

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16. Among the following in which disproportionation is not occur

Number of Mn–Mn bond = 1

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18. For 7 mole of monoatomic ideal gas calculate U If T = 40 K

19. Chlorophyll is a complex of _______

20. Which is more stable

(a) (b) (c) (d)

NO2 CN OCH3

(1) A = ;B= (2) A = ;B=

COO– COO– COO– COO–

(3) A = ;B= (4) A = ;B=

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(1) 6 (2) 4 (3) 12 (4) 3

23. Which compound is non-aromatic

24. Clº + CH4  A + B

25. Stearic acid + Polyethylene glycol A

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26. PhMgBr + x  Ph–C–CH3

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