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Reviewing Textile Wastewater Produced by Industries: Characteristics, Environmental Impacts, and Treatment Strategies
Reviewing Textile Wastewater Produced by Industries: Characteristics, Environmental Impacts, and Treatment Strategies
Reviewing Textile Wastewater Produced by Industries: Characteristics, Environmental Impacts, and Treatment Strategies
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ABSTRACT
The textile industry is one of the most intensive industries in chemical products whose wastewater contains hazardous dyes, pigments, dis-
solved/suspended solids, and heavy metals. Hence, it is important to effectively treat the wastewater generated by this industry before
releasing it into the environment. Although the field of textile wastewater treatment has made tremendous progress, the developed treat-
ment methods should be improved further to make them economically viable and friendly. In this review, characteristics of textile
wastewater are introduced. We have primarily focused on the environmental impact and toxicity of textile wastewater. Toxic and harmful
contaminants must be removed from textile wastewater to reduce the extent of environmental pollution caused when textile wastewater
is released into rivers or reused. Hence, various techniques that are used to treat textile wastewater are discussed. Finally, the challenges
faced, and prospects of the methods have been discussed in detail.
Key words: advanced oxidation process (AOP), aquatic toxicity, dyes, textile wastewater, wastewater treatment
HIGHLIGHTS
This is an Open Access article distributed under the terms of the Creative Commons Attribution Licence (CC BY-NC-ND 4.0), which permits copying and
redistribution for non-commercial purposes with no derivatives, provided the original work is properly cited (http://creativecommons.org/licenses/by-nc-nd/4.0/).
GRAPHICAL ABSTRACT
1. INTRODUCTION
Various scientific fields have made immense progress in the 21st century. Extensive research has been carried out on diverse
topics in the fields of Environmental Science and Engineering research in the last 20 years. Large amounts of wastewater are
generated daily from the textile, cosmetics, paper, rubber, leather, and printing industries (Younis et al. 2021). It is difficult to
treat the toxic and complex textile wastewater produced by industries. Currently, water contamination caused by the waste-
water released from the textile industry poses a threat to economic growth. As highly water-soluble and toxic substances
(microbial pathogens and organic dyes) are present in the discharged water, the wastewater directly contaminates the natural
ecosystem and reduces the availability of clean and fresh water that can be utilized for drinking. The complex and stable struc-
ture of the dyes makes the degradation of dyes (present in waste water and other complex substrates) difficult. The
mineralization of dyes, presence of organic compounds, and toxicity of the wastewater released from textile and dye manu-
facturing industries negatively affect the environment. Therefore, it is important to gain practical knowledge and develop
methods to effectively treat textile wastewater to save the environment (Holkar et al. 2016).
In recent years, extensive research has been carried out in the field of treating dyeing and weaving wastewater (Figure 1). To
date, considerable efforts have been made to remove organic dyes/pollutants from wastewater using various methods (chemi-
cal, physical, and biological). It has been reported that it is difficult to remove color following traditional treatment methods
(e.g., ozonation-, bleaching-, hydrogen peroxide/ultraviolet (UV)-, and electrochemistry-based) as most textile dyes have com-
plex aromatic molecular structures that make their degradation difficult (Akbari et al. 2002). These dyes are stable in the
presence of light and oxidants. They can also withstand conditions of aerobic digestion. Therefore, it is important to develop
a green and sustainable method to effectively treat textile wastewater. Environmental scientists and engineers have focused
on developing economically viable treatment methods.
To date, various review articles on the properties and applications of the most important approaches used for removing
dyes from wastewater have been reported (Brillas & Martínez-Huitle 2015). However, the introduction of synthetic fibers
has led to the emergence of some current markets that need to use other dye categories, becoming a recent major environ-
mental problem. The aim of this review article is to provide extensive knowledge on the recent methods (such as chemical,
physical, biological, and eco-friendly) that are used to remove dyes from wastewater produced by the textile industry. The
latest and exhaustive data on the treatment processes used to treat textile wastewater have been presented here.
Figure 1 | Number of papers reported per annum (keywords used: ‘textile wastewater treatment’) indexed in the core collection of Web of
Science (spanning the years from 2010 to 2020 (inclusive); June 2021).
Figure 2 | Possible pollutants present and the nature of effluents discharged at each step of the industrial process; reprinted with permission
from Ref. (Mani et al. 2019).
industry wastewater are presented in Table 1. Data analysis reveals that the COD value corresponding to mixed wastewater is
significantly high.
Notably, the major contaminants present in textile wastewater are produced during the processes of dyeing and finishing.
Currently, aromatic hydrocarbons and heterocyclic dyes are commonly used in the textile industry (Holkar et al. 2016). A dye
molecule consists of two parts: the dye group and the dye auxiliary pigment (Liang et al. 2014). When the dye molecules are
exposed to light, the structure containing double bonds (C ¼ C) oscillates to absorb light and produce visible colors (Akbari
et al. 2002). Dye at low concentrations can also exhibit highly intense color (Nigam et al. 2000; Liang et al. 2014). The
Table 1 | Characteristics of conventional textile industry wastewater (Al-Kdasi et al. 2004, Mani et al. 2019)
1 pH 6–10
2 Temperature (°C) 35–45
3 Biochemical oxygen demand (mg/L) 80–6,000
4 Chemical oxygen demand (mg/L) 150–12,000
5 Oil and grease (mg/L) 10–30
6 Total suspended solids (mg/L) 15–8,000
7 Free ammonia ,10
8 Total dissolved solids (mg/L) 2,900–3,100
9 Chloride (mg/L) 1,000–1,600
10 Sodium (mg/L) 70
11 Trace elements (mg/L) ,10
12 Silica (mg/L) ,15
13 Total Kjeldahl nitrogen (mg/L) 70–80
14 Color (Pt-Co) 50–2,500
complex and stable structures exist not only in textile wastewater but also in any kind of complex substances. Dyes can be
classified into various categories based on their characteristics. They are primarily classified as ionic and non-ionic dyes
(Robinson et al. 2001). Ionic dyes are direct, reactive, and acidic dyes. Non-ionic dyes remain dispersed as they do not
ionize in a water-borne medium (Deive et al. 2010). Methyl orange, acid red-B, rhodamine-B, Prussian red, alizarin red,
Congo red, orange green, rose Bengal, and basic yellow 28 are examples of ionic dyes (Islam et al. 2019). Textile dyes are
classified as acidic, alkaline, direct, disperse, active, sulfur, or reducing dyes (Table 2) (Akbari et al. 2002). Acidic dyes are
negatively charged, and alkaline dyes are positively charged. The dyes are active if anionic dyes are used in the textile indus-
try, medium if metal ions are present, reduced if they are derived from natural indigo, and disperse if non-ionic (Brillas &
Martínez-Huitle 2015). Direct dyes are the most popular class of dyes, as they are easy to use, exhibit a wide range of
colors, and are economically friendly. The structures of most direct dyes contain di-azo and tri-azo moieties. The maximum
range of colors can be observed for the azo dye (percentage of dyes belonging to this class: 60–70%) (Deive et al. 2010).
Table 2 | Dye classification and methods of application (Akbari et al. 2002, Verma et al. 2012, Pang & Abdullah 2013)
Dye-fiber
Substrate attachment
Dye class Characteristics (fiber) Metals in dyes mechanism Method of application Dyeing method
Acid Anionic, water- Nylon, wool, Copper, lead, Ionic bond, Suitable for neutral to Fiber is placed in an acidified
soluble silk zinc, Van der acidic dye baths. aqueous medium (pH: 2.5–
chromium, Waals 7; dye temperature: 100–
cobalt 110 °C).
Basic Cationic, water- Acrylic, Copper, zinc, Ionic bond Suitable for acidic Fiber is placed in an acidified
soluble nylon, silk lead, dyebaths. aqueous dye bath (pH: 5–
cotton, chromium 6.5; temperature 105 °C).
wool
Direct Anionic, water- Cotton Copper, lead, H-bond Application from neutral Fibers are placed in a slightly
soluble zinc, or micro-alkaline baths alkaline medium; the
chromium containing additional electrolyte is used at 100 °
electrolytes. C.
Disperse Colloidal Polyester, None Solid solution Fine water dispersions are Fiber is placed in an acidified
dispersion, nylon, formation often applied by high dye bath (pH: 5.5;
very low acetate, temperature–pressure or temperature: 130–210 °C).
water cellulose, using lower temperature
solubility acrylic carrier methods.
Sulfur Colloidal, cotton – Dye Aromatic substrate adds Fiber is placed in a bath; dye
insoluble precipitated sodium sulfide and re- is dissolved in alkaline
fiber oxidizes the fibers into sulfur, which is replaced by
insoluble sulfur- the electrolyte and
containing products. deposited in air or peroxide
central site.
Reactive Anionic, water- Cotton, silk, Copper, Covalent Reactive sites present on Fiber placed in dye bath; salt
soluble nylon, chromium, bond the dyes react with the added to displace dye;
wool lead functional groups alkali added to induce
present in the fiber and reaction between dye and
bind the dye covalent fiber.
bonds under the
influence of heat and
pH (alkaline).
Vat As sulfur dye Cotton None As sulfur dye Water-insoluble dyes are As sulfur dye.
dissolved by reducing
them using sodium
hydrosulfite, then
exhausted on fiber and
re-oxidized.
In addition to harmful dyes, wastewater produced by the textile industry also contains various pigments, heavy metals, sul-
fates, oils, surfactants, and chlorides (Wei et al. 2020) (Figure 2). These contaminants can adversely affect aquatic life and
water quality. Heavy metals have often been used during the process of dye fixation and also in dyes. It has been reported
that the metal units present in dyes help impart color so that the dues can be used as textile colorants. Textile wastewater
contains trace amounts of metals such as Cu, Cr, As, and Zn, which harm the environment (Table 2) (Mirghani et al.
2008; Mani et al. 2019). These metals can bind with organic dyes and/or fibers (Khan & Malik 2014). The major contami-
nants present in textile wastewater are high suspended substances, COD, acidity, heat, color, and other soluble substances
(Al-Kdasi et al. 2004). In general, textile wastewater exhibits intense color and is characterized by high BOD/COD values
and high saline loading (Holkar et al. 2016). The BOD/COD ratio for composite textile wastewater is approximately 0.25.
This indicates that wastewater contains a large amount of non-biodegradable organic substances. (Al-Kdasi et al. 2004). As
reported by Paździor et al. (2019), industrial textile wastewater treatment methods are studied using various effluents gener-
ated during the execution of different processes within the dye-house. These effluents are collected under conditions of
equilibrium or in neutralization pools. The pollutions at a lower concentration may be present in the effluents.
Mathur et al. (2006) assessed the mutation-causing ability of textile dyes from Pali (Rajasthan) by conducting an Ames
bioassay. In their study, a total of seven dyes were conducted for their mutagenicity by Ames assay, using strain TA 100 of
Salmonella typhimurium (Mathur et al. 2006). The results indicated that only one dye, Violet, exhibited no mutational
activity. The use of the remaining six dyes resulted in mutation (Mathur et al. 2006). It has also been reported that bioassays
are sensitive and reliable methods that can be conducted to determine the toxicity of industrial wastewater. Hence, they can
be used to assess the efficiency of emerging tools (Rosa et al. 2001). The relative sensitivity of biological assays toward textile
wastewater is arranged in descending order: plant enzymes . bacteria . algae ≈ daphnids ≈ plant biomass ≈ germination rate
. fish. Significant effects on genetic toxicity were not observed (Rosa et al. 2001). The aquatic toxicity of a series of unique
direct dyes containing benzidine congeners, 2,20 -dimethyl-5,50 -dipropoxybenzidine, and 5,50 -dipropoxybenzidine, and the tox-
icity of a commercial dye (C.I. Direct Blue 218) were assessed by conducting acute toxicity studies in the presence of Daphnia
magna (Bae & Freeman 2007). The results revealed that C.I. Direct Blue 218 was highly toxic toward daphnids. It was more
toxic than the unmetallized direct dyes. In addition, the results also revealed that the assay conducted with D. magna could be
effectively used to assess the aquatic toxicity of dyes (Bae & Freeman 2007). Villegas-Navarro et al. (1999) used the crus-
tacean Daphnia magna as a sensor organism and 50% lethal concentrations (LC50) as the standard for measuring the
toxicity of textile effluents (treated and non-treated). The results indicated that all the five textile industries could produce
toxic non-treated water (ATU: 2.1–25.4). The treated water was also toxic (ATU: 1.5–7.2). This suggested that the treatment
plants and methods used by the five textile industries to remove toxic water were not highly efficient (Villegas-Navarro et al.
1999). Sharma et al. (2007) used Swiss Albino rats to assess the toxicity of the wastewater generated from the textile industry.
Table 3 presents information on the toxicity of some commonly used azo dyes.
The discharge of untreated or semi-treated colored sewage into the nearby water affects the extent of penetration of light
and oxygen, and this ultimately affects the aquatic ecosystem. These toxic and harmful contaminants must be removed from
textile wastewater to minimize the extent of pollution caused (or avoid causing pollution) when wastewater mixes with river
water or is reused for other industrial or agricultural processes (Abdel-Karim et al. 2021). Hence, different textile wastewater
treatment processes are discussed in the subsequent sections of this manuscript.
Table 3 | Most commonly used azo dyes and the health hazards caused by them (Ali et al. 2019; Watari et al. 2021)
Figure 3 | Treatment methods used for the degradation of dyes present in textile wastewater.
The annual global market growth rate has been reported to be 8.13%. Hence, it is estimated that large amounts of effluents
consisting of approximately 280,000 tons of refractory textile dyes will be produced by the textile industry (Zhou et al. 2021).
The choice of appropriate treatment method depends on the production process and the chemicals used in the textile plant.
The choice is also influenced by the composition of wastewater, discharge rule, location, business costs, operational costs,
availability of land, selection, and availability of reuse/recycling of treated effluents, process, and expertise (Jegatheesan
et al. 2016). The cost of treating river water that can be used for drinking should be reduced, and drinking water should
be colorless and devoid of toxic compounds. Thus, numerous treatment processes (such as physical, chemical, and biological)
have been developed to treat wastewater before the wastewater is released into river bodies. A combination of these treatment
methods has also been used to treat textile wastewater in an economically effective manner. It has been reported that these
techniques can be effectively used for textile wastewater treatment (Holkar et al. 2016).
4.1.1. Adsorption
It is environmentally important to remove dyes from colored effluents (especially from the effluents produced by the textile
industries). The process of adsorption is one of the diverse methods that has been favorably used to treat dye-containing
wastewater. A large number of materials, such as activated carbon (the most commonly used and expensive adsorbent), poly-
meric resins, and numerous economical adsorbents (agricultural and industrial by-products, such as peat, bentonite, chitin,
silica, other clays, and fly ash) have been used as appropriate sorbents to realize the decolorization of industrial wastewater
(Suteu et al. 2009). Activated carbon is the most well-known adsorbent. It is usually produced following the processes of phys-
ical or chemical activation. Although activated carbon can be effectively used to adsorb dyes, its application is limited as it is
expensive. Hence, there is an increasing demand for the production of an adsorbent that is as efficient as activated carbon but
cheaper than activated carbon. Several economically viable treatment methods for the treatment of dyes have been reported.
The execution of these methods requires the use of various adsorbents such as rice husk, cotton, bark, hair, coal, perlite,
sewage sludge-based activated carbon, apple pomace, wheat straw, banana peel, orange peel, organobentonite, pearl millet
husk, peat particles, wood, fly ash, and coal (Khan et al. 2004). The removal ability of activated carbon processed from
coir pith was studied in the presence of three strikingly applied reactive dyes in the textile industry (Santhy & Selvapathy
2006). It was reported that the activated carbon obtained from the coir pith not only effectively removed the color but
also significantly reduced the COD levels of textile effluents. Recently, Suleman et al. (2021) used castor biomass-based
biochar to realize the adsorption of safranin. The results revealed that the biochar could be used to realize a high adsorption
capacity (4.98 mg/L). Approximately 99.6% of the safranin dye could be removed (99.6%). Oke & Mohan (2022) reported
that textile sludge-based activated carbon could be used as an adsorbent to adsorb reactive yellow 145, methylene blue,
and reactive red 198. The adsorption capacities were recorded to be 75.1 mg/L, 101.8 mg/L, and 76.6 mg/L, respectively.
It is noteworthy that it is difficult to remove activated carbon from the solution, and thus, it can be released into the environ-
ment along with the processed sludge used to treat wastewater. This can result in secondary contamination (Singh & Arora
2011). Recently, the adsorption of titanium dioxide (TiO2) is a highly regarded advanced photocatalyst that constitutes a new
growing branch of activated carbon composites to improve the adsorption rate and discoloration ability, causing serious con-
sideration and support around the world (Foo & Hameed 2010). Liu et al. fabricated a highly active TiO2/activated carbon
photocatalyst following a hydrothermal method. This system could be readily isolated from the treatment system and could be
used to effectively adsorb methyl orange (Liu et al. 2007). Activated carbon present in the TiO2/activated carbon catalysts can
potentially act as organic-molecule-adsorbing centers. Subsequently, the adsorbed molecules get transferred to the
Figure 4 | Role of activated carbon in improving the activity of TiO2; reproduced with permission from Ref. (Liu et al. 2007).
decomposition center and the TiO2 units present on the surface of activated carbon get illuminated. This can be attributed to
the concentration differences (Figure 4). It is important to understand the conditions affecting the adsorption capability of
such compounds. It is believed that the adsorption ability is influenced by various factors such as the hardness of water
and time of processing (Siddique et al. 2017).
Table 4 | Nanofiltration techniques used to treat textile wastewater (Othman et al. 2021)
Everzol red
Reactive black Concentration: 0.4–2 ppm 60–97
Pressure: 0.3–1.7 bars
Safranine orange Initial concentration: 50 ppm 86
Pressure: 5 bars
Eriochrome black Initial concentration: 1 ppm .99
Pressure: 4 bars
Sunset yellow Initial concentration: 100 ppm 82.2
Pressure: 6.2–6.9 bars
pH: 6.8
The dimensions of the aperture of the MF membrane lie in the range of 0.2–0.5 μm. This membrane is primarily used to
remove particulate suspensions and colloidal dyes from the load-running dye baths and out-of-date rinsing bath (Dasgupta
et al. 2015). MF supports unconsumed auxiliary chemicals, dissolved organic pollutants, ions, and other soluble pollutions
to pass through the membrane together with the permeability (Couto et al. 2017). Amaral et al. (2014) studied the use and
operating parameters of the MF system to recover insoluble indigo blue present in the cotton yarn dye bath to realize pigment
reuse and water washing. The results suggested that the MF process can be potentially used to recover insoluble indigo blue
presents in synthetic wastewater systems (Amaral et al. 2014). It has been recently reported that coal is a good carbon
material that can be used as a carbon source for the fabrication of asymmetric microfiltration carbon membranes character-
ized by high porosity, controllable aperture, and narrow pore size (Song et al. 2006). A tubular carbon microfiltration
membrane was fabricated by mixing mineral coal (average particle size: 100 μm) with a solution of phenolic resin and organic
additive (Tahri et al. 2013). The fabricated membrane exhibits interesting properties in terms of mechanical and chemical
tolerance. In addition, high permeability flux and removal efficiency could be achieved. The extents of retention of COD
values and salinity were 50 and 30%, respectively. Turbidity and color could be removed efficiently (Tahri et al. 2013).
and human health. Environmentally friendly substances that can be used as alternatives to these toxic coagulants have
attracted the attention of scientists worldwide. Various biodegradable, non-toxic, and widely available compounds (Elkady
et al. 2011) such as chitosan, Moringa oleifera seeds, tannins, and Jatropha curcas seeds are being increasingly studied as
alternatives (Hameed et al. 2018).
M þ H2 O ! M(OH ) þ Hþ þ e (2)
þ
O2 þ 2H þ 2e ! H2 O2 (3)
Figure 5 | AOPs based on zero-valent aluminum for treating textile wastewater; reproduced with permission from Ref. (Khatri et al. 2018).
The removal of color has been widely achieved using H2O2, sodium hypochlorite (NaClO), and other chemical agents in
the textile industry. Argun and Karastas et al. (Argun & Karatas 2011) used 2,000 mg/L of H2O2 to degrade synthetic dyes
(concentration: 200 mg/L). However, the polishing operations associated with these chemicals are cost ineffective (Lin &
Chen 1997). It has been recently reported that the process of ozonation can be a potential alternative to established methods
that are used for decoloration. According to Hassaan & El Nemr (2017), the removal of COD, ozone is much less efficient. It
was observed that the process of ozonation could not be used to reduce COD effectively. The results revealed that it could be
used to realize one-step decolorization and partial oxidation to improve biodegradability. The increased BOD/COD ratio fol-
lowing ozonation could be potentially attributed to the increased biodegradability of toxic substances (Hassaan & El Nemr
2017). In addition, it has been suggested that O3 should be used in combination with other technologies for effective waste-
water treatment. According to Destaillats et al. (2000), 30% mineralization of methyl orange can be achieved in the presence
of O3. When the process is conducted in combination with the ultrasound-based treatment methods, the cumulative extent of
mineralization achieved is .80% in the pH range of 5.5–6.5. According to Vecitis et al. (2010), the generation of the syner-
getic effect can be attributed to the fact that the decomposition of one O3 molecule results in the production of two OH·
radicals under conditions of sonolysis.
Table 5 | Diverse aerobic bacteria that can be used to achieve dye decolorization
(.99%). It was also observed that P. aeruginosa could be used to remove commercially used tannery and textile dye. Navitan
Fast blue S5R is an example of such a dye that can be removed from wastewater systems in the presence of glucose under
aerobic conditions (Pandey et al. 2007). In addition, an anaerobic (facultative anaerobic bacterial culture)–aerobic sequence
system was used to remove the color from a pilot-scale actual textile wastewater system and reduce COD of the wastewater
system under study (Kapdan & Alparslan 2005).
The effect of microbial decolorization is influenced by the adaptability and activity of the chosen microorganisms (Nor
et al. 2021). From this point of view, in microbial decolorization, the bacteria have the ability to decolorize, which is assumed
to be associated with the production of a different enzyme (Nor et al. 2021). Aeromonas veronii GRI (KF964486) was isolated
from domestic textile effluents after selective enrichment on azo dye to evaluate the biodegradation effectiveness of methyl
orange (Mnif et al. 2016). It was observed that when the system was vaccinated with an initial light density of approximately
0.5, sucrose (0.25%), yeast extracts (0.125%), and Bacillus subtilis SPB1 biosurfactant (0.01%), bacteria could effectively
decolorize azo dyes. The stirring stage was initiated approximately 24 h after the stage of static incubation (Nor et al.
2021). The researchers also reported that the removal of methyl orange could be potentially attributed to intracellular
enzyme activities (Nor et al. 2021). Furthermore, the textile dye-decolorization effect achieved in the presence of microorgan-
isms could be improved by producing biological surfactants. Mnif et al. (2015) reported that lipopeptides derived from
Bacillus subtilis SPB1 maximize the decolorization efficiency and accelerate the decolorization rate when the optimal con-
centrations of biosurfactants are approximately 0.075%. It is essential to summarize the influence of each parameter
associated with biodegradation to develop a more effective and faster bacterial degradation method. Table 6 summarizes
the possible ranges of the staffing parameters to achieve better biodegradation effects (Mani et al. 2019).
Azo dyes are electron-deficient compounds containing the -N ¼ N- chromophore group. These dyes may also contain sev-
eral other electron-withdrawing groups in their skeletal structure. The production of electronic defects makes the compounds
less susceptible to the degradation process. Bacteria can effectively degrade dyes as diverse, and well-constructed enzyme sys-
tems are present in these organisms (Sarkar et al. 2017). It has been reported that azo dye-decolorizing microorganisms
produce various enzymes, such as azo reductase, laccase, peroxidases, NADH-DCIP reductase, tyrosinase, MG reductase,
and aminopyrine N-demethylase. Azoreductases, laccases, and peroxidases are the major enzymes that are responsible for
the decolorization of azo dyes (Imran et al. 2015).
Table 6 | Differing factors that affect the dye degradation and decolorization efficiencies (Mani & Bharagava 2016, Mani et al. 2019)
Factors Descriptions
pH The pH value has an important effect on the dye-decolorization efficiency. The optimal pH range for color
removal using bacteria is 6.0–10.0. Tolerance toward high pH conditions is particularly important for
industrial applications where reactive azo dyes are used. The processes of decolorization (for these types of
dyes) are usually conducted under alkaline conditions.
Temperature Temperature significantly influences all processes associated with microbial vitality. Water and soil repair
processes are also affected by a change in temperature. The azo dye-decolorization rate increases until the
optimal temperature is reached. Following this, the decolorization activity decreases slightly.
Dye concentration It has been previously reported that an increase in the dye concentration can result in a gradual decrease in the
decolorization rate. This can be potentially attributed to the toxic effect of dyes exerted on the bacteria,
inadequate biomass concentration, and/or blockage of azo reductase active sites in the presence of different
dye molecules.
Electron donor It has been observed that the addition of electron donors, such as glucose or acetate ions, can induce reduction
cracking in azo bonds. The type and availability of electron donors significantly influence the color removal
efficiency achieved using bioreactors operated under anaerobic conditions.
Oxygen and agitation Environmental conditions can directly affect the degradation and decolorization process of azo dyes. The
environmental reduction or oxidation states indirectly affect the process of microbial metabolism. It is
assumed that under anaerobic conditions, reductive enzyme activities are high. The oxidative enzymes
involved with the process of azo dyes degradation require the presence of a small amount of oxygen.
Carbon and nitrogen Dyes lack carbon and nitrogen sources. In the absence of a complementary source, it is difficult to biodegrade
sources these dyes. For effective activity, microbial cultures often require the presence of complex organic sources
and carbohydrates for efficient dye decolorization and degradation.
Dye structure High rates of color removal were observed for dyes characterized by simple structures and low molecular
weights. This could be attributed to the presence of electron-withdrawing groups (such as SO3H and
-SO2NH2) in the para position of the phenyl ring (relative to the azo bond) and high-molecular-weight dyes.
Redox mediator Redox mediators (RM) can promote various reductive processes (including azo dye reduction) under anaerobic
conditions.
The CF and NF methods and a combination of the two methods (CF–NF) have been used to treat wastewater systems con-
taining synthetic dyes (Liang et al. 2014). Liang et al. (2014) reported that the CF process could be used to achieve almost 90%
dye removal efficiency under conditions of optimal dosage (polyaluminum chloride (PAC)/polydiallyldimethyl ammonium
chloride (PDDA) ¼ 400/200 ppm; pH of the mixed dye wastewater .3). In addition, they found that the CF and NF methods
could complement each other’s strengths. The problems faced when each method was used individually could be addressed
using the CF–NF method. Riera-Torres et al. (2010) reported that NF removed except 40 and 80% of color for the five dyes,
while CF reached 85–95% color removal rates of the four dyes except polyurethane resin for RB5. The color removal effi-
ciency for RB5 reached 90%. When the combination techniques were used, the efficiency reached .98% for all dyes.
Aouni et al. (2009) reported that the color removal efficiency was .99% when the NF technique was used following
electrocoagulation.
López-López et al. (2016) improved the efficiency of AOPs by introducing CF as a pretreatment method (to reduce the tur-
bidity observed in the textile effluents). The experiments were conducted with five different concentrations of industrial
coagulants. The coagulants (FLOCUSOL-PA/18) were used to reduce turbidity (approximately 99% of the turbidity could
be removed). In addition, the color removal rate for all AOPs was nearly 100%. Ozone combinations are the most widely
used advanced oxidation methods before biological treatment to improve biodegradability and color removal efficiency. It
has been reported that an increase in the BOD/COD ratio (following ozonation) can be attributed to the increased biodegrad-
ability of toxic substances (Sevimli & Sarikaya 2002). According to Ledakowicz et al. (Ledakowicz & Gonera 1999), AOPs
should be conducted before subjecting the water systems to conditions of degradation. The results revealed that the combi-
nation of O3 and UV radiation processes or the O3/UV/H2O2 process were the highly efficient AOPs. The AOPs suppressed
only 10% of the microbial growth (during the subsequent biodegradation process), while untreated wastewater exhibited 47%
inhibition.
Microbial fuel cells (MFCs) have received immense attention as they can be efficiently used for power generation. These
can also be used to conduct sustainable wastewater treatment methods (Li et al. 2021b). Electrochemically active bacteria
(present at the anode) can produce electrons and reach the cathode via an external circuit. The formed protons and electrons
bind with oxygen (in the cathode chamber) to produce water. Recently, MFCs have been used to treat textile wastewater. Log-
roño et al. (2017) designed an air-exposed single-chamber MFC with microalgal biocathodes to treat real-dye textile
wastewater and generate bioelectricity. They reported high COD removal efficiencies (92–98%) using MFCs. Wu et al.
(2020) developed an innovative device that combined dual MFC for the continuous removal of Victoria Blue R and power
production. Analysis of the results revealed that when artificial wastewater containing 1,000 mg/L of Victoria Blue R was
continuously injected into the system, the Victoria Blue R removal rate reached 98.7%.
Table 7 | Factors to be considered while choosing the treatment techniques for treating textile wastewater (Pang & Abdullah 2013)
Physical • Adsorption • Efficient removal of various types • Requires the use of regenerable or disposable
method of dyes. adsorbents.
• Membrane filtration • Efficient removal of all types of • Production of concentrated sludge. Execution and
dyes. running costs to be considered. Large volumes of
waste cannot be treated.
Chemical • Chemical coagulation • Short detention time and high • High cost of chemicals and reagents. pH needs to be
method and flocculation removal efficiencies for various adjusted. Large amounts of produced. Problems faced
types of dyes during handling and disposal of wastes.
• Fenton oxidation • Efficient removal for various • Costly chemical reagents used. Large amounts of
types of dyes within a short sludge produced. Problems faced during handling and
period of time. disposal of wastes.
• Ozonation • Efficient removal for various • Not suitable for dispersed dyes. Short half-life
types of dyes. (20 min).
• Sludge not produced.
• Photocatalytic or • Efficient removal for various • Relatively new methods. Formation of by-products
sonocatalytic oxidation types of dyes. observed. The penetrability of UV light (recorded or
an aqueous medium) is often less than that of ultra-
sound irradiation.
• Radiolysis • Complete mineralization achieved • Suitable for high concentrations of dyes. Relatively
in a short time. Sludge not new method.
produced.
• Efficient removal for various
types of dyes (at low volumes).
Biological • Aerobic process • Efficient removal of azo dyes. • Long detention times. Sensitive toward toxic organic
method • Low operating cost. Sludge can dye.
be recycled.
• Anaerobic process • Low operating costs and biogas • Cell reproduction stays longer. Sensitive to toxic
produced can be used as a fuel organic dyes and the production of aromatic amines.
source.
applications of these methods. The microbial decolorization method is economical and environmentally friendly. It is being
increasingly used to treat textile wastewater. It is difficult to decolorize systems that contain complex and synthetic dyes. In
summary, each method has its advantages and disadvantages (Table 7).
Further studies should be conducted to develop ways of treating textile wastewater (Holkar et al. 2016). Combinations of
various processes (such as AOP and biological combination processes) should be considered. The cost of the wastewater
treatment method should be borne in mind while treating large amounts of wastewater. When the integrated processes
(chemical and biological oxidation) were used for wastewater treatment, the costs increased when the reagent doses were
increased at the Fenton reaction stage (Rodrigues et al. 2014). According to Holkar et al. (2016) and Rodrigues et al.
(2014), mineralization rates should be minimized during the pretreatment or post-treatment phase to reduce the usage and
production of unnecessary compounds and energy consumption. This will eventually help reduce the operation cost of the
treatment processes.
6. CONCLUSIONS
Textile wastewater contains color and is characterized by high TDS, BOD, COD, and total suspended solids (TSS). The textile
wastewater system also contains mixtures of various dyes. Hence, it is difficult to treat textile wastewater. The discharge of
colored and untreated (or partially treated) sewage into the nearby water bodies hinders the penetration of light and
oxygen. This eventually affects the aquatic ecosystem negatively. Hence, it is important to treat textile wastewater. Various
methods (such as physical and chemical) are commonly used to treat textile wastewater. However, the operational costs
are high. Biological treatment processes are considered to be the best alternatives to these methods. These processes are
eco-friendly and cost-effective. Most of the organic matter present in textile wastewater is non-biodegradable. Hence, it is dif-
ficult to degrade these compounds following biotreatment methods. Different combinations of treatment methods that can be
used to treat wastewater produced by the textile industry have been suggested. Combinations of CF–NF, AOPs, and MFCs
have been used to treat textile wastewater. In general, in the textile industry, choosing the most effective and cheapest treat-
ment processes or their combinations based on the dyestuffs and dyeing methods utilized during the production.
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First received 11 October 2021; accepted in revised form 25 February 2022. Available online 11 March 2022