Final JEE-Main Exam July, 2022/25-07-2022/Evening Session

FINAL JEE–MAIN EXAMINATION – JULY, 2022

(Held On Monday 25th July, 2022) TIME : 3 : 00 PM to 06 : 00 PM
CHEMISTRY TEST PAPER WITH SOLUTION
SECTION-A 2. Two solutions A and B are prepared by
1. Match List I with List II : dissolving 1 g of non-volatile solutes X and Y.
List-I List-II respectively in 1 kg of water. The ratio of
(molecule) (hybridization; shape) depression in freezing points for A and B is
A. XeO3 I. sp3d ; linear found to be 1 : 4. The ratio of molar masses of
B. XeF2 II. sp3; pyramidal X and Y is :
C. XeOF4 III. sp3d3; distorted octahedral (A) 1 : 4
D. XeF6 IV. sp3d2 ;square pyramidal
(B) 1 : 0.25
Choose the correct answer from the options
(C) 1 : 0.20
given below:

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(A) A-II, B-I, C-IV, D-III (D) 1 : 5
(B) A-II, B-IV, C-III, D-I Official Ans. by NTA (B)
(C) A-IV, B-II, C-III, D-I Allen Ans. (B)
(D) A-IV, B-II, C-I, D-III
Official Ans. by NTA (A) 1
Allen Ans. (A) Mx
DTfx k f × m x 1
Sol. = =
DTfy k f × m y 1
My
Xe 1
Sol. (A) – sp3 – pyramidal
O O O Þ
1 My
=
4 Mx
F
Þ M x : M y = 1 : 0.25
Xe
3. Ka1, Ka2 and Ka3 are the respective ionization
(B) – sp3d – linear constants for the following reactions (a),(b),
and (c).
F
(a) H 2 C 2 O 4 ƒ H + + HC2 O4-
O (b) HC2 O-4 ƒ H + + HC2 O24-
F F
(c) H 2 C 2 O 4 ƒ 2H + + C2 O24-
(C) Xe –sp d –square pyramidal
3 2
The relationship between K a1 ,K a2 and K a3 is
F F given as
F (A) K a3 = K a1 + K a 2 (B) K a3 = K a1 - K a 2
F F
(C) K a3 = K a1 / K a 2 (D) K a3 = K a1 ´ K a 2
Xe Official Ans. by NTA (D)
(D) sp d –distorted octahedral
3 3
Allen Ans. (D)
F F
Sol. H 2 C 2 O 4 ƒ H + + HC 2 O 4- K a1
F
H 2 C 2 O -4 ƒ H + + C 2 O 24 - K a2
H 2 C 2 O 4 ƒ 2H + + C 2 O 24 - K a3 =K a1 ´ K a 2

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Final JEE-Main Exam July, 2022/25-07-2022/Evening Session
4. The molar conductivity of a conductivity cell filled 7. Given below are two statements.
with 10 moles of 20 mL NaCl solution is L m1 and Statement I : Pig iron is obtained by heating
that of 20 moles another identical cell heaving 80 cast iron with scrap iron.
mL NaCl solution is L m 2 , The conductivities Statement II: Pig iron has a relatively lower
exhibited by these two cells are same. carbon content than that of cast iron. In the
The relationship between L m 2 and L m1 is light of the above statements, choose the correct
(A) L m 2 = 2 L m1 (B) L m 2 = L m1 / 2 answer from the options given below.
(A) Both Statement I and Statement II are
(C) L m 2 = L m1 (D) L m 2 = 4 L m1 correct.
Official Ans. by NTA (A) (B) Both Statement I and Statement II are not
Allen Ans. (A) correct.
1000 (C) Statement I is correct but Statement II is
Sol. L m = k ´
M not correct
(D) Statement I is not correct but Statement II

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1
Þ Lm µ is correct.
M
Official Ans. by NTA (B)
20
L m1 M2 1 2 1 Allen Ans. (B)
= = 80 = ´ = Sol. Statement –I is incorrect because cast iron is
Lm2 M 10 4 1 2
1
20 obtained by heating pig iron with scrap iron
Þ L m = 2L m Statement–II is also incorrect because pig iron
2 1
5. For micelle formation, which of the following has more carbon content (:4%) than cast iron
statements are correct? (:3%)
(A) Micelle formation is an exothermic 8. High purity (>99.95%) dihydrogen is obtained by
process. (A) reaction of zinc with aqueous alkali.
(B) Micelle formation is an endothermic (B) electrolysis of acidified water using
process. platinum electrodes.
(C) The entropy change is positive. (C) electrolysis of warm aqueous barium
(D) The entropy change is negative. hydroxide solution between nickel
(A) A and D only (B) A and C only electrodes.
(C) B and C only (D) B and D only (D) reaction of zinc with dilute acid.
Official Ans. by NTA (A) Official Ans. by NTA (C)
Allen Ans. (C) Allen Ans. (C)
Sol. For micelle formation, DS > 0 (hydrophobic Sol. High purity (>99.95%) dihydrogen is obtained
effect) This is possible because, the decrease by electrolysis of warm aqueous Ba(OH) 2
in entropy due to clustering is offset by increase solution between Ni-electrodes
in entropy due to desolvation of the surfactant, 9. The correct order of density is
Also DH > 0 (A) Be > Mg > Ca > Sr
6. The first ionization enthalpies of Be, B, N and (B) Sr > Ca > Mg > Be
O follow the order (C) Sr > Be > Mg > Ca
(A) O < N < B < Be (B) Be < B < N < O (D) Be > Sr > Mg > Ca
(C) B < Be < N < O (D) B < Be < O < N Official Ans. by NTA (C )
Official Ans. by NTA (D) Allen Ans. (C)
Allen Ans. (D) Sol. In II'A' group density decreases down the
group till Ca and after that it increases.
N > O > Be > B Correct order of density is
Sol. 1st I.E. (2p3 ) (2p4 ) (2s2 ) (2p1 )
Sr > Be > Mg > Ca

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 Final JEE-Main Exam July, 2022/25-07-2022/Evening Session
10. The total number of acidic oxides from the 13. Major product of the following reaction is
following list is : NO, N 2O, B2O3, N2O5, CO,
SO3, P4O10
O
2 HBr
(A) 3 (B) 4
O
(C) 5 (D) 6
Official Ans. by NTA (B)
Allen Ans. (B) Br
O Br
Sol. Neutral Oxides — N2O, NO, CO
(A)
Acidic Oxides — B2O3, N2O5, SO3, P4O10
O
11. The correct order of energy of absorption for
the following metal complexes is
A: [Ni(en)3]2+, B: [Ni(NH3)6]2+, C: [Ni(H2O)6]2+
Br

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Br
(A) C < B < A
O
(B) B < C < A (B)
(C) C < A < B O
(D) A < C < B
Official Ans. by NTA (A)
Allen Ans. (A) (C) Br O Br
Sol. Stronger the ligand, larger the splitting & higher
the energy of absorption. O

[ Ni(en)3 ] > [ Ni(NH 3 ) 6 ] > [ Ni(H 2 O) 6 ]

+2 +2 +2

(A) (B) (C) Br

12. Match List I with List II. Br O
(D)
List–I List–II
A. Sulphate I. Pesticide O
B. Fluoride II. Bending of bones
C. Nicotine III. Laxative effect Official Ans. by NTA (D)
D. Sodium IV. Herbicide
arsinite Allen Ans. (D)
Choose the correct answer from the options
given below:
Br
(A) A-II, B-III. C-IV, D-I O O
(B) A-IV, B-III, C-II, D-I + H–Br ®
Sol.
O O
(C) A-III, B-II, C-I, D-IV HBr
(D) A-III, B-II, C-IV, D-I
Official Ans. by NTA (C)
Br
Allen Ans. (C)
Br O
Sol. A-Sulphate – III (Laxative effect)
B-Fluoride – II (Bending of bones)
O
C-Nictoine – I (pesticides)
D-Sodium Arsinite – IV (herbicide)

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Final JEE-Main Exam July, 2022/25-07-2022/Evening Session
14. What is the major product of the following Sol. The correct order of acid strength is
reaction? OH OH OH OH
—
H OH
H2O
NO2 OMe
O NO2 OMe
O
+
CH3MgBr H3O Zn -Hg
16. CH3 - CH2 - CN ¾¾¾¾¾
Ether ® A ¾¾¾® B ¾¾¾¾
HCl
®C
(A) H
The correct structure of C is
(A) CH 3—CH 2—CH 2—CH 3
O OH
O
||
(B) H
(B) CH 3 - CH 2 - C - CH 3

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OH
O O |
(C) CH 3 - CH 2 - CH - CH 3
(C) H
(D) CH3—CH2—CH = CH2
Official Ans. by NTA (A)
Allen Ans. (A)
O
N MgBr
(D) H ||
Sol. CH3MgBr
CH 3CH 2 - C º N ¾¾¾¾¾ ® CH 3 CH 2- C -CH 3
Official Ans. by NTA (B) +
H3O
Allen Ans. (B)
O
H – H H ||
Sol. OH—
CH 3 CH 2 CH 2 CH3 ¬¾¾
Zn / Hg
¾ CH 3 CH 2 - C - CH 3
O O O— HCl

(Clemmensen Reduction)
O —
O O OH 17. Match List I with List II :
H
+ List-I List-II
H + H H Polymer used for items
A. Nylon 6,6 I. Buckets
B. Low density II. Non-stick
Aldol formation takes place. polythene utensils
C. High density III. Bristles of
15. Arrange the following in decreasing acidic
polythene brushes
strength. D. Teflon IV. Toys
OH OH OH OH
Choose the correct answer from the options
given below:
NO2 OCH 3 (A) A–III, B-I, C-IV, D-II
(B) A–III, B-IV, C-I, D-II
NO2 OCH 3
(C) A–II, B-I, C-IV, D-III
(A) (B) (C) (D)
(A) A > B > C > D (B) B > A > C > D (D) A–II, B-IV, C-I, D-III
Official Ans. by NTA (B)
(C) D > C > A > B (D) D > C > B > A
Allen Ans. (B)
Official Ans. by NTA (A)
Sol. LDPE ® Toys
Allen Ans. (A) HDPE ® Buckets (As per NCERT)

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 Final JEE-Main Exam July, 2022/25-07-2022/Evening Session
18. Glycosidic linkage between C1 of a-glucose and 2. A sealed flask with a capacity of 2 dm3 contains
C2 of b-fructose is found in 11 g of propane gas. The flask is so weak that
(A) maltose (B) sucrose it will burst if the pressure becomes 2 MPa.
(C) lactose (D) amylose The minimum temperature at which the flask
Official Ans. by NTA (B) will burst is _______ °C. [Nearest integer]
Allen Ans. (B) (Given: R = 8.3 J K–1 mol–1. Atomic masses of
Sol. Theoretical C and H are 12u and 1u respectively.) (Assume
that propane behaves as an ideal gas.)
Official Ans. by NTA (1655)
Allen Ans. (1655)

11
Sol. Moles of C3 H8 = = 0.25moles
44

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19. Some drugs bind to a site other than, the active PV = nRT
site of an enzyme. This site is known as Þ 2 × 106 × 2 × 10–3 = 0.25 × 8.3 × T
(A) non-active site (B) allosteric site Þ T = 1927.710 K = 1654.56°C
(C) competitive site (D) therapeutic site 3. When the excited electron of a H atom from
Official Ans. by NTA (B) n = 5 drops to the ground state, the maximum
Allen Ans. (B) number of emission lines observed are _____
Sol. Theoretical Official Ans. by NTA (10)
20. In base vs. Acid titration, at the end point methyl Allen Ans. (4)
orange is present as Sol. Since only a single H atom is present,
(A) quinonoid form (B) heterocyclic form maximum number of spectral lines = 4
(C) phenolic form (D) benzenoid form
Official Ans. by NTA (A)
5
Allen Ans. (A)
4
- +
Sol. Me2N N N SO Na
3 3
2
+
H
1

Me2N+ N NH SO-3 Na + 4. While performing a thermodynamics experiment,

a student made the following observations,
(QUINONOID FORM)
HCl + NaOH ® NaCl + H2O DH = –57.3 kJ mol–1
SECTION-B
CH3COOH + NaOH ® CH3COONa + H2O
1. 56.0 L of nitrogen gas is mixed with excess of
DH = –55.3 kJ mol–1.
hydrogen gas and it is found that 20 L of
The enthalpy of ionization of CH 3COOH as
ammonia gas is produced. The volume of
calculated by the student is ______ kJ mol–1.
unused nitrogen gas is found to be____ L.
(nearest integer)
Official Ans. by NTA (46)
Official Ans. by NTA (2)
Allen Ans. (46)
Allen Ans. (2)
N2 + 3H 2 ® 2NH 3 Sol. DH ionisation of CH 3 COOH = -57.3 - ( -55.3)
Sol. 56L excess O
-10L -30L +20L = 2 KJ/mol
46L 20L

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Final JEE-Main Exam July, 2022/25-07-2022/Evening Session

5. For the decomposition of azomethane. 7. The spin-only magnetic moment value of M3+ ion
CH3N2CH3(g) ® CH3CH3(g)+N2(g) a first order (in gaseous state) from the pairs Cr3+/Cr 2+,
reaction, the variation in partial pressure with Mn 3+/Mn 2, Fe 3+/Fe 2+ and Co 3+/Co 2+ that has
time at 600 K is given as negative standard electrode potential, is B.M.

Slope = –3.465×10
4 [Nearest integer]

æ p ö Official Ans. by NTA (4)

ln ç 0 ÷
èp ø Allen Ans. (4)

Sol.
0
ECr +3 Cr +2
= -0.41V
t/s
The half life of the reaction is _____ × 10–5s.
[Nearest integer] [Cr +3 ] = 4s0 3d 3

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Official Ans. by NTA (2)
Allen Ans. (2) m= n(n + 2) B.M
Sol. For first order reaction
1 æP ö = 15 B.M : 4 B.M
k = ln ç 0 ÷
t è Pø
æP ö 8. A sample of 4.5 mg of an unknown monohydric
ln ç 0 ÷ = kt alcohol, R–OH was added to methylmagnesium
è P ø
iodide. A gas is evolved and is collected and its
ln 2 0.693
t1/2 = = = 2 ´ 10 -5 volume measured to be 3.1 mL. The molecular
k 3.465 ´ 10 4
weight of the unknown alcohol is ____ g/mol.
6. The sum of number of lone pairs of electrons [Nearest integer]
present on the central atoms of
Official Ans. by NTA (33)
XeO3, XeOF4 and XeF6 is _____________
Official Ans. by NTA (3) Allen Ans. (33)
Allen Ans. (3)
Sol. ROH + CH3MgI ® ROMgI + CH4(g)

moles of CH4 = moles of ROH

Xe
Sol. - one lone pair on central atom
O O O Þ
V
=
m
(Assuming NTP Condition)
22400 M.M
O
F F
3.1 4.5 ´ 10 -3
Xe - one lone pair on central atom Þ =
22400 M.M
F F
Þ MM = 32.51

Nearest Integer = 33
F
F F
Xe
- one lone pair on central atom
F F
F

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 Final JEE-Main Exam July, 2022/25-07-2022/Evening Session

9. The separation of two coloured substances was 10. The total number of monobromo derivatives
done by paper chromatography. The distances formed by the alkanes with molecular formula
C5H12 is (excluding stereo isomers)_____
travelled by solvent front, substance A and
Official Ans. by NTA (8)
substance B from the base line are 3.25 cm. 2.08 Allen Ans. (8)
cm and 1.05 cm. respectively. The ratio of Rf Sol. The Alkanes and their monobromodervative are
values of A to B is ______
Br
Official Ans. by NTA (2) Br, ,
1.
Allen Ans. (2)
Br
2.08
R FA 2.08 Br
= 3.25 = ;2

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Sol. R FB 1.05 1.05 2. , , , Br
3.25 Br Br

3. Br