Batch-1 Major Test - 2 : Chemistry (Paper - 1)

PART (B) : CHEMISTRY

SECTION-1 : (Maximum Marks : 12)

 This section contains FOUR (04) questions.

 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.

20. If IFxn types species are planar and non-polar, then which of the following match is correct -
(Where X is number of F atoms and n is charge on species)
(A) x = 2 and n = +1
(B) x = 3 and n = 0
(C) x = 2 and n = –1
(D) x = 5 and n = 0

21. The correct IUPAC name of following compound is

(A) Methyl-5-bromo-2-ethyl cyclohexane carboxylate

(B) 5-bromo-2-ethyl methyl cyclohexane carboxylate
(C) Methyl-3-bromo-5-ethyl cyclohexane carboxylate
(D) None of these

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 Batch-1 Major Test - 2 : Chemistry (Paper - 1)

22. Formic acid is considered as a resonance hybrid of the four structure -

Which of the following order is correct for the stability of the four contributing structures?
(A) I > II > III > IV
(B) I > I > IV > III
(C) I < III < II < IV
(D) I > IV > III > II

23.

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 Batch-1 Major Test - 2 : Chemistry (Paper - 1)

SECTION-2 : (Maximum Marks : 12)

 This section contains THREE (03) question stems.

 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value corresponding to the answer in the designated
place using the mouse and the on-screen virtual numeric keypad.
 If the numerical value has more than two decimal places, truncate/round-off the value to TWO
decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.

Question stem for Questions 24 & 25

Question Stem

Suppose an orbital of H atom whose radial wave function is represented as

  r   k1  e r/k 2  r 2  5k 3r  6k 32 

24. No. of angular nodes of the orbital is/are ___

25. Radial distance of the spherical node which is farthest from the nucleus (Assuming k3 = 1 Å) is __ Å

Question stem for Questions 26 & 27

Question Stem

A balloon containing 1 mole air at 1 atm initially is filled further with air till pressure increases to
3 atm. The initial diameter of the balloon is 1 m and the pressure at each state is proportion to
diameter of the balloon

26. No. of moles of air added to change the pressure from 1 atm to 3 atm

27. Balloon will burst if either pressure increases to 7 atm or volume increases to 36 π m3. Calculate the
number of moles of air that must be added after initial condition to burst the balloon

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 Batch-1 Major Test - 2 : Chemistry (Paper - 1)

Question stem for Questions 28 & 29

Question Stem

3
Two moles of an ideal gas ( C V, m  R ) is subjected to following change of state
2

28. The pressure at B is __ bar

29. The temperature at D is __ K

SECTION-3 : (Maximum Marks : 24)

 This section contains SIX (06) questions.

 Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct
answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both
of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chose (i.e. the question is unanswered);
Negative Marks : –2 In all other cases

30. Select the correct statement(s).

(A) In a reversible process, G is always zero in a closed system.
(B) In a reversible process, Suniv is always zero in a closed system.
(C) In a reversible process, Ssys is always zero in a closed system.
(D) In a reversible process, Ssvs is always zero in an isolated system.

31. Identify the processes for which at least one of S, w, U, H are zero.
(A) Melting of ice of 1 atm and 0oC
(B) Irreversible adiabatic expansion of one mole of ideal gas
(C) Reversible Isothermal expansion of a Vander Waal’s gas
(D) Adiabatic free expansion of a Vander Waal’s gas

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 Batch-1 Major Test - 2 : Chemistry (Paper - 1)

32. Which of the following do(es) not represent Ho formation of the product?
(A) H 2 (g)  I 2 (s) 
 2HI(g)
2
(B) O3 (g)   O 2 (g)
3
(C) NH 4 (g)  Cl  (g)  NH 4Cl(g)
(D) P4 (black)  5O 2 (g) 
 P4O10 (s)

33. Which of the following aromatic rings have greater electron density than

(A)

(B)

(C)

(D)

34. Which of the following statements would be false about this compound?

(A) All three C–N bonds are of same length.

(B) C1–N and C3–N bonds are of same length but shorter than C5–N bond.
(C) C1–N and C3–N bonds are of same length but longer than C5–N bond.
(D) C1–N and C3–N bonds are of different length but both are longer than C5–N bond.
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 Batch-1 Major Test - 2 : Chemistry (Paper - 1)

35. Which of the following groups can either donate as well as withdraw a pair of electrons in resonance
depending upon situation?
(A) –NO
(B) –CH=CH2
(C) –CHO
(D) –N=NH

SECTION-4 : (Maximum Marks : 12)

 This section contains THREE (03) question stems.

 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer using the mouse and the on-
screen virtual numeric keypad in the place designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.

36. A mixture of Ferric oxide (Fe2O3) and Al is used as a solid rocket fuel which reacts to give Al2O3
and Fe. No other reactants and products are involved. On complete reaction of 1 mole of Fe2O3, 200
units of energy is released. If the ratio of masses of Fe2O3 and Al taken so that maximum energy per
unit mass of fuel is released is y : 1 then value of y is (Round off to nearest integer)

37. The sum of the number of bond pairs of electrons on each central atom in the following species
[TeBr6 ]2  , [BrF2 ] , SNF3 and [XeF3 ]
[Atomic number : N = 7, F = 9, S = 16, Br = 35, Te = 52, Xe = 54]

38. Two flasks A and B have equal volumes. A is maintained at 300 K and B at 600 K. While A contains
H2 gas, B has an equal mass of CH4 gas. Assuming ideal behaviour for the both gases the ratio of
(uav)A : (uav)B = x : 1 . Find x.

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