‘XI’ Chemistry Examination 2022

01-June-2022
Section ‘A’ (Multiple Choice Questions)
Q 1. Choose the correct answer for each from the given options:

1. Limiting reactant is the one which:

(a) Is taken in lesser quantity in grams as compare to other reactants.
(b) Is taken in lesser quantity in volume as compare to other reactants.
(c) Gives the maximum amount of the product which is required.
(d) Gives the minimum amount of product under consideration.
2. Which of the following is false for gases?
(a) They diffuse easily (b) They have mass
(c) They are highly compressible (d) They do not mix well.
3. At constant temperature if the pressure is doubled, the volume of the gas will be:
(a) Doubled (b) Reduced by half (c) Increased four times (d) No change
4. If a graph is plotted between temperature on x-axis and volume of the one mole of gas on y-axis at
constant pressure, then a straight line is obtained which cuts a temperature axis at;
(a) 0 oC (b) -273.16 K (c) -273.16 0C (d) 300K
5. 3.01 x 1023 molecules of oxygen gas at S.T.P occupy a volume of:
(a) 22.4 dm3 (b) 224 dm3 (c) 11.2 dm3 (d) 2.24 dm3
6. The number of moles in 58.5 gm of NaCl is:
(a) 58.5 moles (b) 35.5 moles (c) 23 moles (d) 1 mole
7. A breaker containing 180 gm of water contains:
(a) 6.02x1023 moles (b) 6.02x1024 molecules
(c) 10.02x1023 molecules (d) 12.01x1023 molecules
8. The process, in which a solid directly changes into vapor without passing through liquid phase, is
called:
(a) Evaporation (b) Condensation (c) Sublimation (d) Neutralization
9. On kelvin scale, absolute zero is equal to:
(a) 273.16oC (b) 0oC (c) 20K (d) -273.16oC
10. Real gases are nearer to identity at:
(a) High temperature and low pressure (b) High temperature and high pressure
(c) Low temperature and high pressure (d) low temperature and low pressure
11. The particles having a mass 1836 times that of the electrons is:
(a) Neutron (b) Proton (c) Meson (d) Hyperon
12. An electron is said to be excited when it:
(a) Loses energy (b) Jumps to a higher orbit
(c) Jumps to a lower orbit (d) Enters the atom
13. Quantum number value for 2p are:
(a) n=2 , l=1 (b) n=1 , l=1 (c) n=1 , l=0 (d) n=2 , l=0
14. Two solids, having the same crystal structure, are called:
(a) Isomorphous (b) Polymorphous (c) Isotopes (d) Allotropes
15. Cathode rays are deflected by:
(a) Neither electric nor magnetic field (b) An electric field only
(c) Both electric and magnetic field (d) A magnetic field only
16. When alpha particle are sent through a thin metal foil most of them go straight through the foil
because:
(a) Alpha particle moves high velocity (b) alpha particle are positively charged
(c) most of the space is empty (d) all of the above
17. Most of penetrating radiation of radioactive element is:
(a) Alpha rays (b) Beta rays (c) Gamma rays (d) x-rays
18. The energy released when an electron is added to an atom is the gaseous state is called
(a) Ionization energy (b) Electron affinity (c) Electronegativity (d) Electro positivity
19. The angular momentum of an electron revolving around the nucleus of an atom is:
(a) (b) (c) (d)
20. The color of the light depends upon its:
(a) Wavelength (b) Source (c) Velocity (d) none of these
21. The octet rule is not followed in the formulation of:
(a) (b) (c) (d)
22. Which of the hydrogen halides has the highest percentage of ionic character?
(a) (b) (c) (d)
23. Fluorine molecule is formed by the overlap of:
(a) s-s orbital (b) p-p orbital (c) s-p orbital (d) none
24. The molecule BeCl2 is linear because Be is:
(a) Sp hybridized (b) Sp3 hybridized (c) Sp2 hybridized (d) all of the above
25. For the reaction: the , the change in enthalpy is called:
(a) Heat of reaction (b) Heat of sublimation
(c) Heat of neutralization (d) Heat of combustion
26. The properties of the system that depends upon the amount of material concerned are:
(a) Intensive properties (b) Extensive properties
(c) Physical properties (d) Chemical properties
 27. when:
(a) is zero (b) is zero (c) is zero (d) none of these
28. Hess’s law, may be used to calculate:
(a) (b) (c) (d) K
29. The heat content of a system is called:
(a) Internal energy (b) Entropy (c) Enthalpy (d) Potential energy
30. For the reaction
(a) Kp=Kc (b) Kp is less than Kc (c) Kp is greater than Kc (d) none of these
31. The color of universal indicator in neutral solution is:
(a) Red (b) Green (c) Blue (d) Pink
32. In electrolytic cell, the anode is the electrode where:
(a) Oxidation occurs (b) Reduction occurs (c) Both a&b Occurs (d) Neutralization occurs
33. Oxidation number of Cl in KClO3 is equal to:
(a) -1 (b) -5 (c) +5 (d) -6

Section ‘B’ (Short Answers Questions)

Q.2 Attempt Eight questions from this section. Each question carries 4 marks.

1. Write the rate expression and calculate value of rate constant and order of reaction:
, using following data:

2. Differentiate in any two of the followings:

(a) Activation energy and threshold energy (b) Positive catalyst and Negative catalyst
(c) Crystalline solids and Amorphous Solids (d) Hydration and Hydrolysis
3. Combustion of 0.5 gm of hydrocarbon produced 1.515 gm of CO2 and 0.77 gm of H2O, if molecular
mass of the compound is 58 a.m.u. Determine its molecular formula.
4. Balance the equation by ion electron method: (any one)
(a) ( ) ( )
(b) ( )
5. Find the pH of 0.004 mol/dm3 of HCl when it is 70% ionized at 25oC.
6. When the equilibrium was attained for the reaction , the concentration of [A] = [B] was
4 moles/dm3 and that of [C] was 6 moles/dm3 , calculate Kc and the initial concentration of A and B.
 7. What is the solubility of lead iodide in g/dm3 at 25oC? Ksp for PbI2 is 1x109.
8. Draw and shortly explain the shapes of given molecules according to VSEPR theory:
(a) CH4 (b) H2O (c) NH3 (d) BF3
9. Write the electronic configuration of the following:
(a) Cr (Z=24) (b) Cu (Z=29) (c) Mg+2 (Z=12) (d) Cl-1 (Z=17)
10. Write a short note on the following : Surface tension , Vapour Pressure
11. In an experiment 76.2 gms of Fe are allowed to react with 86.7 gms of S. Which of the two is
limiting reactant? Calculate the mass of FeS obtained.
12. A certain mass of nitrogen gas at 20oC and at 740 torr pressure occupies12.345 dm3. Calculate the
volume that will occupy at S.T.P.
13. State and explain 1st law of thermodynamics, prove W=PΔV.

Section ‘C’ (Detailed Answers Questions)

Note: Attempt any two questions from this section. Each question carries 10 marks.

Q.3 (a) What is hybridization discuss the types of hybridization with reference of Carbon compounds.
(b) Find the heat of formation of acetic acid at 25oC.
I.
II.

III.

IV.

Q.4 (a) Derive general gas equation by combining gas laws . Calculate the values of R in two different
system of units.
(b) State and explain Le Chatelier’s principle with refrence to the formation of NH3 by Haber’s process
as follows
Q.5 (a) Describe Bohr’s atomic model in detail.
(b) Describe discharge tube experiment.