FINAL JEE–MAIN EXAMINATION – JUNE, 2022

(Held On Friday 24 June 2022)

th
TIME : 9 : 00 AM to 12 : 00 PM

CHEMISTRY TEST PAPER WITH ANSWER

SECTION-A
1. If a rocket runs on a fuel (C15 H30) and liquid 4. For a reaction at equilibrium
oxygen, the weight of oxygen required and CO2 1
A(g) B(g)  C(g)
released for every litre of fuel respectively are: 2
(Given: density of the fuel is 0.756 g/mL) the relation between dissociation constant (K),
(A) 1188 g and 1296 g (B) 2376 g and 2592 g degree of dissociation () and equilibrium pressure
(C) 2592g and 2376 g (D) 3429 g and 3142 g (p) is given by :
Official Ans. by NTA (C) 1 3
Allen Ans. (C)  p 2 2
(A) K  1
 3 2
2. Consider the following pairs of electrons  1  2  1   
1
(A) (a) n = 3, 1 = 1, m1 = 1, ms = + 3 1
2  2 p2
1 (B) K  1
(b) n = 3, 1 = 2, m1 = 1, ms = +
2
EN  2    2 1   
1 3
(B) (a) n = 3, 1 = 2, m1 = – 2, ms = – ( p) 2
2 (C) K  1
1  3 2
(b) n = 3, 1 = 2, m1 = –1, ms = –  1  2  1   
2
1 3
(C) (a) n = 4, 1 = 2, m1 = 2, ms = + ( p) 2
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2 (D) K  1

1 1   1    2
(b) n = 3, 1 = 2, m1 = 2, ms = +
2 Official Ans. by NTA (B)
The pairs of electron present in degenerate orbitals Allen Ans. (B)
is/are:
A

(A) Only A (B) Only B 5. Given below are two statements :

(C) Only C (D) (B) and (C) Statement I : Emulsions of oil in water are unstable
Official Ans. by NTA (B)
and sometimes they separate into two layers on
Allen Ans. ( B)
standing.
Statement II :For stabilisation of an emulsion,
3. Match List – I with List - II
excess of electrolyte is added.
List – I List – II
(A)  PtCl4 2 (I) sp3d In the light of the above statements, choose the
most appropriate answer from the options
(B) BrF5 (II) d2sp3 given below :
(C) PCl5 (III) dsp2 (A) Both Statement I and Statement II are correct.
(D) (IV) sp3d2 (B) Both Statement I and Statement II are
Co  NH 3  
3

 6 incorrect.
(A) (A)(II), (B)(IV), (C)(I), (D)(III) (C) Statement I is correct but Statement II is
(B) (A)(III), (B)(IV), (C)(I), (D)(II) incorrect.
(C) (A)(III), (B)(I), (C)(IV), (D)(II) (D) Statement I is incorrect but Statement II is
(D) (A)(II), (B)(I), (C)(IV), (D)(III)s correct.
Official Ans. by NTA (B) Official Ans. by NTA (C)
Allen Ans. (B) Allen Ans. (C)

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6. Given below are the oxides: 10. Identify the correct statement for B2H6 from those
Na 2 O,As2 O3 ,N2 O, NO and Cl2O7 given below.
Number of amphoteric oxides is: (A) In B2H6, all B-H bonds are equivalent.
(A) 0 (B) 1 (B) In B2H6 there are four 3-centre-2-electron
(C) 2 (D) 3 bonds.
Official Ans. by NTA (B) (C) B2H6 is a Lewis acid.
Allen Ans. (B) (D) B2H6 can be synthesized from both BF3 and
NaBH4.
7. Match List – I with List – II (E) B2H6 is a planar molecule.
List - I List - II Choose the most appropriate answer from the
(A) Sphalerite (I) FeCO3 options given below :
(B) Calamine (II) PbS (A) (A) and (E) only
(C) Galena (III) ZnCO3 (B) (B), (C) and (E) only
(D) Siderite (IV) ZnS (C) (C) and (D) only
Choose the most appropriate answer from the (D) (C) and (E) only
options given below: Official Ans. by NTA (C)
(A) (A) - (IV), (B) – (III), (C) – (II), (D) – (I) Allen Ans. (C)
(B) (A) - (IV), (B) – (I), (C) – (II), (D) – (III)
EN
(C) (A) - (II), (B) – (III), (C) – (I), (D) – (IV) 11. The most stable trihalide of nitrogen is:
(D) (A) - (III), (B) – (IV), (C) – (II), (D) – (I) (A) NF3 (B) NCl3
Official Ans. by NTA (A) (C) NBr3 (D) NI3
Allen Ans. (A) Official Ans. by NTA (A)
Allen Ans. (A)
8. The highest industrial consumption of molecular
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hydrogen is to produce compounds of element: 12. Which one of the following elemental forms is not
(A) Carbon (B) Nitrogen present in the enamel of the teeth?
(C) Oxygen (D) Chlorine (A) Ca2+ (B) P3+
Official Ans. by NTA (B) (C) F– (D) P5+
Allen Ans. (B) Official Ans. by NTA (B)
A

Allen Ans. (B)

9. Which of the following statements are correct ?
(A) Both LiCl and MgCl2 are soluble in ethanol. 13. In the given reactions sequence, the major product
(B) The oxides Li2O and MgO combine with ‘C’ is :
excess of oxygen to give superoxide.
(C) LiF is less soluble in water than other alkali
metal fluorides.
(D) Li2O is more soluble in water than other alkali (A)
metal oxides.
(B)
Choose the most appropriate answer from the
options given below: (C)
(A) (A) and (C) only
(B) (A), (C) and (D) only
(C) (B) and (C) only (D)
(D) (A) and (C) only
Official Ans. by NTA (A) Official Ans. by NTA (B)
Allen Ans. (A) Allen Ans. (B)

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14. Two statements are given below :

Statement I: The melting point of monocarboxylic

16.
acid with even number of carbon atoms

is higher than that of with odd number of carbon

atoms acid immediately

The major product of the above reaction is
below and above it in the series.

Statement II : The solubility of monocarboxylic

acids in water decreases with increase in molar (A) (B)

mass.

Choose the most appropriate option:

(A) Both Statement I and Statement II are correct.

(B)Both Statement I and Statement II are incorrect.

(C) Statement I is correct but Statement II is EN (C) (D)

incorrect.

(D) Statement I is incorrect but Statement II is

Official Ans. by NTA (D)
correct. Allen Ans. (D)
Official Ans. by NTA (A)
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Allen Ans. (A) 17. Which of the following is an example of polyester?

(A) Butadiene-styrene copolymer
(B) Melamine polymer
15. Which of the following is an example of
(C) Neoprene
A

conjugated diketone?
(D) Poly--hydroxybutyrate-co--hydroxy valerate
Official Ans. by NTA (D)
(A)
Allen Ans. (D)

(B) 18. A polysaccharide 'X' on boiling with dil H2SO4 at

393 K under 2-3 atm pressure yields 'Y'.

(C) 'Y' on treatment with bromine water gives gluconic

acid. 'X' contains -glycosidic linkages only.
Compound 'X' is :
(D) (A) starch (B) cellulose
(C) amylose (D) amylopectin
Official Ans. by NTA (C)
Official Ans. by NTA (B)
Allen Ans. (C) Allen Ans. (B)

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19. Which of the following is not a broad spectrum 3. The osmotic pressure of blood is 7.47 bar at 300 K.
antibiotic? To inject glucose to a patient intravenously, it has
(A) Vancomycin (B) Ampicillin to be isotonic with blood. The concentration of
(C) Ofloxacin (D) Penicillin G glucose solution in gL–1 is _____(Molar mass of
Official Ans. by NTA (D) glucose = 180 g mol–1
Allen Ans. (D) R = 0.083 L bar K–1 mol–1) (Nearest integer)
Official Ans. by NTA (54)
20. During the qualitative analysis of salt with cation Allen Ans. (54)
2+
y , addition of a reagent (X) to alkaline solution
of the salt gives a bright red precipitate. The 4. The cell potential for the following cell
reagent (X) and the cation (y2+) present Pt | H2 (g) | H (aq) || Cu 2 (0.01M) | Cu(s)
respectively are: is 0.576 V at 298 K. The pH of the solution is ___.
2+
(A) Dimethylglyoxime and Ni (Nearest integer)
(B) Dimethylglyoxime and Co2+ Official Ans. by NTA (5)
(C) Nessler’s reagent and Hg2+ Allen Ans. (5)
(D) Nessler’s reagent and Ni2+
Official Ans. by NTA (A)
EN 5. The rate constants for decomposition of
Allen Ans. (A) acetaldehyde have been measured over the
temperature range 700 –1000 K. The data has been
SECTION-B
10 3
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1. Atoms of element X form hcp lattice and those of analysed by plotting In k vs graph.The value of
T
2 activation energy for the reaction is___ kJ mol–1.
element Y occupy of its tetrahedral voids. The
3
(Nearest integer) (Given : R = 8.31 J K–1 mol–1)
percentage of element X in the lattice is_________
A

(Nearest integer)
Official Ans. by NTA (43)
Allen Ans. (43)

2. 2O3 (g) 3O2 (g)

At 300 K, ozone is fifty percent dissociated. The Official Ans. by NTA (154)
standard free energy change at this Allen Ans. (154)
–1
temperature and 1 atm pressure is (–) __J mol
(Nearest integer) 6. The difference in oxidation state of chromium in
–1 –1
[Given: ln 1.35 = 0.3 and R = 8.3 J K mol ] chromate and dichromate salts is _______
Official Ans. by NTA (747) Official Ans. by NTA (0)
Allen Ans. (747) Allen Ans. (0)

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7. In the cobalt-carbonyl complex: [Co2(CO)8], 9. Number of electrophilic centre in the given
number of Co-Co bonds is "X" and terminal compound is ____
CO ligands is "Y". X + Y =____
Official Ans. by NTA (7)
Allen Ans. (7)

8. A 0.166 g sample of an organic compound was

Official Ans. by NTA (3)
digested with cone. H2SO4 and then distilled
Allen Ans. (3)
with NaOH. The ammonia gas evolved was passed
through 50.0 mL of 0.5 N H2SO4. The 10. The major product 'A' of the following given
used acid required 30.0 mL of 0.25 N NaOH for reaction has _____ sp2 hybridized carbon atoms.
complete neutralization. The mass percentage 2,7 – Dimethyl1 – 2, 6 – octadiene

of nitrogen in the organic compound is____. 
H
 A
Mojor Pr oduct
Official Ans. by NTA (63) Official Ans. by NTA (2)
Allen Ans. (Bonus) EN Allen Ans. (2)
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A