PRACTICE SHEET - 07 (Chemistry)

Basic Concept of Organic Chemistry

121. At conjugated position – NO imparts 125. Which of the following will have weakest indicated
(1) + M and + I effect C—H bond?

(2) – M and – I effect

(1) O2N CH2—H
(3) + M and – I effect
(4) – M and + I effect CH3

Me H3C C
H3C
(2) CH2—H
122. The IUPAC name of the compound H3C

H3C C
Et H3C
(1) 3-methyl-6-ethylcyclohexene
(2) 6-ethyl-3-methyl cyclohexene CH3
CH3
(3) 3-ethyl-6-methyl cyclohexene C
CH3
(4) 6-methyl-3-ethyl cyclohexene
(3) CH2—H
123. Strongest and weakest acid among the following is
CH3
C
CH3 — NO2 CH3 — CHO CH3 — F CH3 — CN
CH3
I II III IV
CH3
(1) I and II (2) III and IV (4) CH3—H
(3) III and II (4) I and III
124. Correct order of acidic strength for the given 126. Which of the following compounds will not dissolve
species in aqueous NaOH?

R O
CH3—C N—H CH3—CH2—CH3 O
O C
I II H
(1) (2) OH
CH3—C C—H CH2—H HO OH

III IV H
S
H
(1) I > II > IV > III (2) II > IV > III > I (3) (4)
OH
(3) III > I > IV > II (4) I > III > IV > II
127. In which of the following all electronic effects
namely inductive, mesomeric and hyperconjugative
SbF5
effects are present? (3)
F
O
(4) CH3 — C C — H 
NaNH2 /NH3

(1) (2)
H3C CH3 133. Out of the given reactive intermediates which will be
attracted towards the magnetic field?
O (1) Carbocation
CH3
(3) (4) (2) Carbanion

(3) Carbon free radial

O
(4) Nitrene
128.Most acidic species among the following is 134. Which will have highest melting point?
O O S S
(1) (2)
(1) (2)
O S

O O (3) (4)
(3) (4)
O O
135. Which of the following species cannot behave as
129. What is the index of hydrogen deficiency in the electrophile?
molecule C12H17NO?
(1) BCl3 (2) AlCl3
(1) 4 (2) 5
(3) 6 (4) 7 (3) NH4+ (4) SO3

130. Which of the following compound cannot have a 

bond? 136. Which of the following is correct about the following
isomers?
(1) C10H21N (2) C7H12
(3) C20H40Cl2O (4) C30H50Br2O2

131. Which of the following experimental techniques can be

used to detect carbon free radicals in a reaction mixture?
(1) Magnetic susceptibility method
(2) Polarimetry
(3) NMR-spectroscopy 137. Which is paramagnetic?
(4) IR-spectroscopy (1) Singlet carbene (2) Nitrene
(3) Free radical (4) Carbonium ion
132. Which of the following reactions will not generate a
carbanion?

O
138. Diphenyl methane is
(1) NaOEt
(1)
Et-OH How many structural isomers are possible when one
O of the hydrogen is replaced by chlorine atom?
(1) 8 (2) 7
NH 2
(2) (3) 4 (4) 2
NO 2
139. In which compound/compounds nitrogen cannot be 141. IUPAC name of given compound is
estimated by Kjeldahl's method?

(1) Hex-2-en-5-yne (2) Hex-3-en-5-yne

(3) Hex-4-en-1-yne (4) Hex-5-en-1-yne

140. Given hydrocarbon compound is

142. Which statement is correct for compound?

(1) Aromatic (2) Non aromatic
(3) Anti aromatic (4) Inorganic
(1) Have five resonating structures
(2) Show – R effect
(3) Have six resonating structures
(4) Show – I effect

143. The most unlikely representation of resonance structures of p-nitro phenoxide ion is

O O O O
N N

(1) (2)

O O

O O O +
O
N N

(3) (4)

O O

144. The most stable free radical among the following is

 
(1) C 6H5 CH2 CH2 (2) C 6H5 CHCH3

 
(3) CH CHCH (4) C 6 H5
3 3

145. Which of the following is not planar structure?

(1) (CH3)3C (2) (CH3)3C

(3) CH3 3 C (4) CH2 CH CH2

146. Which of the following is most stable carbocation?

CH2

(1) (2)

(3) (4)

147. Correct order of stability of carbanion

CH2 CH2 CH2 CH2

NO2
NO2 O CH3
I II III IV
(1) IV > I > III > II (2) III > II > I > IV
(3) II > III > I > IV (4) IV > I > II > III
148. The electron donating nature of –OH group linked to benzene ring can be explained with the help of
(1) Resonance effect (2) Hyperconjugative effect
(3) Inductive effect (4) Electromeric effect
CH3

149. The carbocation CH3 C CH2 stabilizes itself by

CH3
(1) H– shift (2) H+ shift
(3) CH3– shift (4) CH3+ shift

150. Which of the following is incorrect order of stability?

CH2 CH2
(1) C 6H 5CH 2 > CH2 CH CH2 (2) >

(3) CH2 CH > CH3 CH2 (4) CH3 CH2 > CH2 CH2