Ps2s2 CHEMISTRY Paper 2 July/August 2shours eI Tip ex cr 1 a (Principal Subject) Paper 2 2hours 30 minutes ’ INSTRUCTIONS TO CANDIDAT ions Answer five questions including three questions Irom section A and any two que from section B. Write the answers in the answer bookleUsheets provided, Begin cach question on n fresh page. are provided. h papers Mathematical tables and g Non programmable, silent scientific electronic calculators may be used, Mustrate your answers with equations where applicable. ary use (CO 12.0% 16 I= IN 14 Br 80,1 = 965000) | © Where neces |W AKDSSTL Join Moa Laminin > Turn Over GeanscanverAn organic compound P. vi + Ieforms a yellow precipitate with both Brady’s # SECTION © Attempt onty three questions from ts seat 10: has the following properties —_ ooo ui eagent ana soution in presence of sodium hydroxide solution = burns with yellow non sooty flame, toric enirated hydrochloric acid in Itforms cloudy solution immediately when tated with concentrated Hy roel presence of anhydrous zine chloride @) © @) ©) © @ w (by © 12 mark Write structural formula and IUPAC name of Ps (Oe maar) Write equation and suggest a mechanism forthe reaction between P and i) concentrated hydrochloric aeid in presence of anhydrous zine chloride.(3/amarks) Gi) Hot concentrated orthophosphoric acid at 160°C (4% marks) (ii) Potassium eyanide in the presence of dilute sulphuric acid at the temperature less Mean 20°C (03 marks) (iv) Brady's reagent (05 marks) equations only, show how P ean be synthesized from propat ol (02 marks) Distinguish between order of reaction and activation eneryy (02 marks) The table below shows the concentration of iodine varying with time during the acid catalysed iodination of propanone. ‘OCHS + bay CHRCOCH shy + Hy Ce oT 2 4 é _10 | Oo 210 [0.199 | o166 | 0.150 0.110 | 0.090 - ‘graph of iodine against time and use it to deter (37s marks) i) units Ys matks Gi) the order of reaction, acme Describe an experiment to show how the results in (b) ean be determine reas to the following equation. ¢ according CHiCHOy—* Clays + COg Standard enthalpy of formation areQHP(CI:CHO)~-1664 Imo", ‘UI? (Clay) =-75k3mot" andi? (CO) =-1 10K mot “The activation energy. Es=+190k} mot Draw the reaction profile forthe reaction indi wg the values OF E Define the following werms, (@ Panttion coefficient Gi) Solvent extraction. (05 marks) (O1 marky (Ol mark Describe an experim of butane: ‘that can be used to determine the dis A-dioie (succinic) acid between trichloromethane bution eve and water, 50 cin of iodine solution in 0.16M potassium iodide w hloromethane in a separating funnel until ex temperature. Th ty sha:en with Som’ of librium wats at ture sat allowed Stara ie the queots layer required 21.30 em’ of 013M sodium thio. inicator.20em" ofthe trivhloromethane layer seid 26 70k! ut U TSM fe solution using starch indicator. (KD oF iodine between thine s 85 al room temperature) Calculate Senate jolar concentration of fice iodine in triehloromethane layer MINIS dort Mack Ee nel at ram Aer to separate 20cm Nulphate solution (0 marksy Beimscuoner(ii) the molar concent Ain) the Molar cone, on ‘eine Gv) the equitibrium eo ia a ation ot 1 compleved (ive) i onstant Ke fr the ve rein aquenns Layer, (2) marks) vi con action (@) State {69 * Faq) == tay, sina (one application of . tion of partition coetice Gi one eason why sie eet ee sn wan wy a {an indeator in tation involving 4. The boilin (01 marky points of hydrides of group (IV raph of Hag OUP (IV) and roup Vt) are shown the raph stow , Ny ints of hydrides of group (IV) and group (VI) elements is! Peril Woe (@) Explain why; era (i) the graph for the hydrides of group(IV) is almost linea. (ii) the boiling point of the hydride of Muorine is abnormally high com ‘of the hydride of earbon Giiy the boiling points of other hydrides of group seven elements inerease with increase in period number. (2 marks) (b) Describe the reactions of: the hydrides of proup( Vl) elements with concentrated sulphuric acid (3% marks) 1) the ivdrides of group(lV) elements with sodium hydroxide. (08 marks) — (©) Write equatiog forthe reaction between: {iy TIydeogen Mhuoride with sificon (IV) oxide (imarks) (ii) Methane with bot copper(I) oxi. (15marks) — (Gin) Mydeogen Chloride gas with aqueous potassium manganat (VID soution, (1Ymatks) SECTION B “Autemp only two questions from this section. 5. The graph below shows the pH changes that occur when 25em” of O.1M weak asi 1A was tiated against sodium hy droxide solution. ‘A graph of pil agaios tum Id ne B ura Over CamScanner6 \ Ss (a) Use the graph to determine: (08 marks) (i) the Ka ofthe weak acid). (02 marks) (ii) the pl and volume at the end point {by Cirteulate the eaniion (03 marks) (moby aan te decd, (Oh (©) Explain the shape of the graph, mam (4) Which of the indicators methyl orange nd phenolphthalein would be oars) suitable for this titration, Give the reason for your answer. - versions can be effected. Without using equations, describe how the following conv roa mary {a) Phenyl methanol from benzene (3% marks) (b) Benzene from calcium oxide. (05 marks) (©) Phenol from nitrobenzene, ; {@)__ 2hydroxypropanoic acid from ethanol. ses mame) (e) phenyl ethyne from phenyl ethane. (03 marks) Explain each of the following observations: 7 (a) Anaqueous solution of sodium sulphate iy neutral to Fitmus while aqueous solution of sodium sulphite turns red litmus paper blue. (04 marks) (b) When excess carbon dioxide gas was separately bubbled through sodium aluminate solution and sodium carbonate solution both form white precipitate. (04 marks) (©) When warm concentrated nitric acid was added to sulphur, the yellow solid dissolved with effervescence of reddish brown gas and colorless solution was formed. (03 marks) (d) The shapes of the molecules BF) and PCI; are different. (5 marks) (e) The melting point of sodium is 98°C where as that of magnesium is 650'C, (04 marks) One of the ores of copper is copper pyrites (CuFeS:). () Ghats meant by the term ore? i) Name and write the formulae of two other ores of copper. o marks (b) Copper pyrites ean be voncenteated by froth flotation, Describe briefly | the process is carried out. eet or eee 2 marks) (©) The concentrated ore in (b) above is roasted in a limited supply of air, The roasted juct is mixed with silicon (IV) oxide and the mi ed i eats ey ¥¢ mixture heated in the absence of ait. (i) the concentrated ore is roasted in limited supply of aie. (ii) the roasted product is heated with silicon(IV) oxide in the absence of a. absence of air Pn . seo (02 marks) (impure copper can be obiained from roasted produc i) impurities inthe copper can be removed. oat (eh me) (03 marks (@)__ State what would be observed and write equation for t pure copper is added to: (i) moderately concentrated nitric wid silver nitrate solution, (02 marks? E a marks) {OW ARISSILA Jor Mock Es the reaction that took place wher