1.

Solid
State
Shortcut Methods
and
ImportantFormulae definite shape. o
volume and
which it has definite
substance in arrangement.
State: The state of the particles have orderly
Solid constituent

n
The substances in which
Crystalline Solids:
Crystalline Solids:

o
Classification of Network Crystals

is
ii. Covalent
i. lonic
Crystals Crystals
iv. Metallic arrangement,
Molecular Crystals have orderly
ii. constituent particles do not

s
substances in which
Amorphous Solids: The
points. This depicts
the relative

e
arrangement of identical
three dimensional orderly

s
Space Lattice: A
particles in the crystal.
arrangement of constituent
crystalline solid is called unit cel.

t
a
repeating structural unit of
Unit Cell: The smallest

u b
um

D o to goiul sroits ed
(A)EE

.Crystal
Unit cell parameters

systems:

2
Cubic
1 o
sbibor fgiel

2 0 Orthorhombic

Tetragonal

E T
Crystal systems Monoclinic
Rhombohedral 3-HO-
C
S19-r
Triclinic

T
Hexagonal
(S)2
sle &fi Isbeh:olqeaxo 101

H
.Types of Cubic Unit Cells: Simple, body centred (bcc) and face centred (fec).

Total No. of Atoms per Unit Cell:

M Simple cubic

8x=1
bec

8x+1-2 8x+6x-4o
fcc

nozoto 10slo
 otween radius (r) of an atom and
elation between
Rela
Solld Stato (85)
edge length (a)
of cubic unit cell:
Simple cubic | bee

3 a

Coordination Number and Packing Efficiency

o n
Type Simple
cubic
bcc
is
Coordination

e s
s
tive number

Packing etticiency 52.4%68%

Number of
Number
tetrahedral voids = 2x No. of atoms
of octahedral voids = No. of atoms
l 1gitgriveo

b t
u
9222101slebul
.Density related to edge length and atomic mass (formula mass) by the formula:
of the crystal is

o
nXMM
p=
PaxNA
Point defects
Iregularities exist around a point or an atom.
D
i. Vacancy defect: Non-ionic solids
some of the lattice 1
a. Stoichiometric defects (intrinsic or thermodynamic defects)

2 sites are
0
vacant.

0
Arises when
decrease in density of the substance.
Results in

ii.

Arises when some

2
Interstitial defect : Non-ionic solids
constituent particles occupy and
the substance.
interstitial site.

T
Results in increase in density of

E
i. Frenkel defect: Ionic solids cation) from its normal site
delocalization of smaller ion (usually
Arises due to site.

C
to an interstitial
defect.
Also called as dislocation
of the substance.
Does not affect the density u and anions from their lattice
T
oidto busta
DCnottky defect: Ilonic solids h number oflscations

H
equal
Characterized by missing of
neutrality. the substance.
Site to maintain electrical decrease in density of
in vacancy
defect and

M
ESults (substitutional
hoOSt atoms
D.
Impurity defects place of
lattice site in
Arises when atoms are
a present at the (interstitial impurity defect).
foreign
eign interstitial sites
purity defect) orat the vacant gaewgoflol ari g
oidos 2S)
La
LoL3LoL3
TI x

MHT-CET 2
Questlons
MHT-CET Exam
(86) o Which an
8.

n
Non-Stoichiometric defects (A) NaCl
c.
defect

o
i. Metal excess vacancies maintaining electrical Which an
to anionic thus 9.

is
arises due electron
defect an (A) NaN
Metal excess a hole which is occupiedandbyimpart colour to crystals. (C) K2SC
Leaving called F-centres
balance. Sites are

s
Schottky defects. interstitial sites. 10. The
perc
Similar to presence of extra cations at interstitial (A)52.40
present in another

e
arises due to
Metal excess defect maintained by an electron
neutrality is 11. How ma

s
Electrical
site. (A) 1
defects

t
Similar to Frenkel
12. If a met
deficiency defect transition metal at

b
i. Metal when metal shows variable valency 1.e., in
Metal deficiency
defect arises (A) 1.86
presence of the

u
metals. a cation from its
lattice site and the
The defect occurs due to missing of 13. Which a
the adjacent lattice site.

o
cation having high charge in (A)In th
Multiple Choice Questions (B) In th

D
(C) Forr
MHT-CET 2004
D)In t

1
1. Silicon is (C)conductor (D)none of these 14. Which
(A) semiconductor (B) insulator
(A) Vali

2
MHT-CET 2006 (B) The
2. A metallic element has a cubic lattice. Each edge of the unit cell is 2 A. The density of the metal (C) The

0
is 2.5 g cm.The unit cells in 200 gof metal are D)The
C)1x 1022io (D) 105
(A)1x10 (B)1x 10 1x

2
15. In body
MHT-CET 2013 (A) 38°
1s
3. A metal has a fcc lattice. The edge length unit cell is 404 pm. The density of the metal

T
2.72 g cm. The molar mass of the metal is (NA, Avogadro's constant 6.02 x 10 mol") 16. If thee c
(A)40 g mol (B)30 g mol (C)27 g mol (D)20 g mol FCC ty
MHT-CET 2015

(A)Dioxygen
(C) Benzene
CE
*4. Select a ferromagnetic material from the followings.
(B) Chromium (TV) oxide
(D)Dihydrogen monoxide
(A) 2
17. Arrang
(A) bec
(C) fec

HT
MHT-CET 2016
*5. In face centred cubic unit cell, what is the volume occupied?

(A) B) T
)
3
18. Which
(A)Sch
C) Inte
MHT-CE

M 6. Which among the following solids is a nonpolar solid?

33 19. Calcula
(A) Hydrogen chloride (B) Sulphur volume
dioxide chsegpe
(C) Water p g D) Carbon dioxide (A)3.2
MHT-CET 2018
ra89 20. Sodiun
7. In which among the following solids, Schottky defect is
NOT observed? sodium
(A)ZnS (B) NaCl (C)KCI
(D)CsCl (A)5.2
 aBte

os21
Solld State (87)
MHT-CET 2019

Which among the tollowing solids shows Frenkel defect?

(A) NaCl
(B) CsCI

n
(C)AgCl
, Which following nain
mong the following
among pairs of compounds
(D) KCI

o
CaCO is NOT
(A) NaNOs and
isomorphous ?

is
K;SeO4 (B) NaF and MgO
(C) K SO, and (D) NaCl and KCI
nercentage ofunoccupied volume in simple cubic
cell is

s
(A)52.40% (B) 32.00%
(C)68.04%
(D)47.60%

e
1 How total constituent particles are present
many
in simple cubic unit cell?
(A)I (B)3

s
(C)4 (D)2
1f a metal crystallizes in bcc structure with edge length of unit cell 4.29x 10 cm, the radius of

t
metal atom is
(A) 1.86 x 10 cm (B) 1.07 x 107 cm (C) 3.2x 10
cm (D) 1.07 x 10 cm

13. Which among the following statements is true about Schottky defect?
(A)In this regular cation is replaced by different cation.
(B) this cation or anion moves from regular site to place between lattice site.
u b
o
In

(C)Formation of metal alloy is example of this defect.

D) this defect cation and anion are lacking in stoichiometric proportion.
In

14. Which among the following statements is NOT true about amorphous solids?
(A) Values of physical properties change with direction of measurement
D
1
(B)
These are pseudo solids
(C)These are super cooled liquids

2
(D) These
behave like fluids

0
15. In body-centred cubic cell the space occupied by constituent particles
C)74% (D)
is
68%
o die
(A) 38% (B) 62%

2 then total particles present in

10, if the constituent particles of crystal lattice are of identical size
FCC type unit is equal to
(D) 4

T
(A) 2 (B) 3 (C)1
decreasing order of packing efficiency.
trange following type of unit cells according to their
17. A

E
cubic
(A) bec> fcc> simple cubic (B) fcc> bcc > simple
(D) Simple cubic bcc > fcc
>
0 091

C
(C) fcc > simple cubic> bec
the following defects is
observed in Brass?
Aamong (B) Substitution
impurity
A)Schottky

T
g D) Frenkel
C)Interstitial impurity lot
MHT-CET

H
2020
density 19.3 g cm and
19. Calculate
38.6 g of noble metal having
the 1number of unit cells in
volum the 10cm. (D)6.236 x 100

M
of one unit cell is 6.18 x
(A)3.236 10 (C)6.180 x 10
x 10 (B) 3.236 x
20. Sodium cm. What is the length of unit cell of
crysta structure with radius 1.86 X 10
sodium? allizes in bcc
(D)4.3 x 10 cm
A)5.26x (C) 7,44 x 10 cm
10 cm(B)3.272 x cm 10
 37. An
MHT-CET Exam Questions cell? Cal
(88) space in bcc type of in unit (D)68%
percentage of void (C)26% (A)
21. What is the
(C)
an element is 6 x 104
(B) 74% g?
(A)32% one atom of
mass of
mass of an fec
unit cell if
10g (D)2.4 x 10g 38. Wh
22. What is the (C)2.4 x
(B)24 x 10"g

n
102g its
(A)4 x molecular solid? (A)
NOT a polar
is 1

o
the following (D) SO20
23. Which among HCI (C)
OC)
is
(B) CHa
(A)HS
crystal structure? 39. Dr
the packing efficiency of fec (D)52.4%
(A
24. What is
(B)47.6% (C) 74.0%

s
(A) 68.04 % havine (C
present in 100 g of an element with fec crystal
unit cells are

e
25. How many number of pm? 40. Th
density 10g/cm and edge length 100 x 1025
D)1
(C)2x 105 (A

26.
(A)4x 105 (B)3x10
Nickel crystallizes in a fec
nickel atom.
type of unit cell, edge length

t s
is 0.3524 nm. Calculate the
radius of
41. W
ca

b
(D)0.1246 nm (A
(B)0.1426 nm (C)0.2164 nm
(A)0.1624 nm
unit cell is 4 g cm 42.
unit cell, the density and edge length of

u
27. An element crystallizes bcc type of
an element?
and 500 pm respectively. What is the atomic mass of

o
(C)125.5 (D)250.0
(A) 100.1 (B) 150.0 olleba
cm, the edge length of unit 43. A

D
28. An element crystallizes in bcc type having atomic radius 1.33
x 10
cell will be (
(A)4.08 x 10 cm B)2.17x 10 cm C)2.66x 10 cm (D)3.07x 10 cm

(A)4 (B)1
1
29. What is the number of atoms present per unit cell of aluminium having edge length 4 A?

2 (C)8 (D)2
44. A
d

0
30. Lithium crystallizes into body centered cubic structure. What is the radius of lithium if edge
length of it's unit cell is 351 pm?

2
45. A
(A)75.50 pm (B) 240.80 pm (C)300.50 pm (D) 151.98 pm
*31. The edge length of fcc type unit cell of copper having atomic radius 127.6 pm equal to
is

T
(A)331 pm (B) 378 pm C) 295 pmn (D)361 pmn *46. S

E
32. An element crystallizes in fcc lattice with cell edge 250
pm. Calculate the density of
element. (At. Mass = 90.3)

C
(A) 19.20 g cm (B) 38.40 g cm C)48.40 g cm cm
(D)23.12 g 47. A
33. An element with density 2.8 g cm forms fcc unit cell having

T
Calculate molar mass of the element edge length 4 x 10
(A)22.0 g mol (B)27.0 g mol (C)33.0 g mol

H
(D)36.0 gmol
34. Molar mass of an element is 60.22 g mol. What is the
mass of fcc type unit cell of an elemeu 48.
(A) 1.0x 10g (B) 4.0 x 10 g
C)2.0x 10g x
M
D) 4.0 10 g8
*35. Aluminium crystallizes in a face centred cubic structure,
its atomic radius 125
the edge length of unit cell? is pm. What 1s
*49.
(A)335.5 pm B) 288.6 pm (C) 280 pm
o 36. Sodium crystallizes in bcc structure with radius 1.86 x
D)353.5 pm
10* cm. Calculate the edge lenguh 50. F
unit cell.
(A) 6.20 x 10 cm (B) 4.29 x 10 cm (C) 3.72 x
10 cm (D) 8.05 x 10 cm
 eleme ent crystallizes in bcC type Solld State (89)
37. An crystal structure
Calculate radius of element. with edge length
of unit cell 300 pm.
(A) 1.299 x 10 cm
(C) 1.440 x 10 cm
ibor oimo ii6) 6.920 x 10 cm

n
(D) 2.299 x 10
That cm
is the volume of
I

o
mole of a crystalline
its unit cell contains 24 molecules? e
solid having unit

is
unit cell
oat edge
length 16x 10 cm, it
(A) 159.3 cm mol
(B) 404.0 cm' mol
(C) 102.7 cm mol
D) 142.1 cm mol

s
39. Dry ice i18 an example of
(A) ionic solid

e
(B) covalent solid
(C) metallic solid
ng

s
(D) molecular solid
The coordination number of
40 the sphere in cubic close packed
(ccp) structure is

t
(A) 8 (B) 4 C)6 (D) 12
of 41, What the coordination number of cation in ionic

b
is
compound if the type of hole occupied by
cation is cubic?

u
(A) 4 (B) 6
poC)3 (D)8
42. Xenon crystallizes in fec lattice and the edge length of unit cell is 620 pm. What is the radius of

o
Xe atom?
(A) 536.9 pm (B) 438.5 pm () 265.5 pm D) 219.2 pm
it 43.A compound has fcc structure.
unit cell? (Molar mass = 98.99))
D
If density of unit cell is 3.4 g cm', what is the edge length of

1
(A)8.780Å (B) 6.083 A C)7.783 A D) 5.783 A
metallic element crystallizes in simple cubic lattice. If edge length of the unit cell is 3A, with

2
4. A

density 8 g/cc, what is the number of unit cells in 108 g of the metal? (Molar mass of metal =

0
100g/mol)
ge A) 2x 104 (B) 5 x 1023 (C)2.7 x 102 D) 1.33 x 100

2
has a bcc structure with cell edge of 288 pm, the density of element is 7.2 g cm.
AnWhatelement
the an
is atomic mass of element?
(C) 62.43 (D) 51.81

T
(A) 77.68 (B) 25.89
is 316.5 pm, what is the radius of
ver atom?
crystallizes in foc structure. If edge length of unit cell

E
an silver
D) 158.25 pmn
(A) 121.91 (C) 137.04 pm
pm (B) 111.91 pm

C edge of 500 pm. The density of the

47. A element is
ement crystallizes in a bcc lattice with cell
Cn 5 g cm. How manyatoms are present in 300 g of metal?

T
atoms
(A)3.2 x 10" (B) 6.4 x 10
atoms
C)1.6x 103 atoms (D)12.8 x 10 atoms
asgo

H
type of hole occupied by
ent? What ionic compound if the
is the coordination number of cation in
c coord
cation is octahedral?
(D)4

M
A)6
49.Which (B)3
C)8 be
amorphous solid?
among the following 18 an example of (D) Magnesium
(A)Diamond (C) Glass
th of S0. (B) Camphor cel1?
Howmuch
each corner of bcc unit (D) 1/2
(A)1/8 art of an atom upies (C) 1/6
(B) 1/4
 65.
Exam Questions fec unit cell?
(90)MHT-CET unoccupied space in (D)74% oreloofe
percentage of (C)68% edoe1
S1. What is the (B) 32%
radius 17.32 nm. What is the
(A) 26%
bec structure with atomic
crystallizes with 66
52. An element (D) 40 nm E
cell? (C)29 nm
of unit is 24.99x 10-24

n
(B) 64 nm cm
(A) 33 nm cell. The volume of one unit cell n 67.
crystallizes in fcc type of
unit
number of unit cells in 36 g
ofpure
53. An element

o
cm. Calculate the

is
the element is 7.2 g
and density of 08
1021
sample of element. C)2.0 x 1023 (D) 1.25 x
(B) 2.0 x 10 68

s
(A)2.0 x 10 sodium i
cell of sodium if mass of one atom of
mass of bcc type unit

e
54. What is the

s
3.819 x 10g? (D)7.638 x 10g 69
(B) 7.038 x 108 C)1.5276 x 10g
(A)3.819 x 10g

t
ferromagnetic in nature?
55. Which among the following is
(D)Iron2 toi

b
(A)Oxygen (B) Benzene (C)Water
70
amorphous solid?
56. Which among the following is NOT an
(A)Tar

(A) Gadolinium
(B) Camphor

(B) Oxygen
(C)Butter0 91 (D)Rubber
57. Which of the following is ferromagnetic in nature?
(C) Water
o u (D)Benzene
2 (A) 71

(A) Sb (B) Bi
D
58. Which among the following elements when added to silicon forms P- type semiconductor?
(C) As D) B

radius of one atom?

(A) End - centred orthorhombic 1
59. Which among the following crystal structures the edge length of unit cell is equal to twice the

2 (B) Simple cubic yiecsb

omg 007
72

0
(C) Body centred cubic D) Face centred cubic
0 73

2
60. Which is the number of atoms in 12.08 x
10 unit cells if an element crystallizes in bee
structure?
(A) 4.838 x 104 (B) 2.416x 1024 (C) 2.08x 10

T
(D) 1.208 x 1023 74
3o e61. Sodium crystallizes in bcc type of crystal
lattice. If the edge length

E
the radius of sodium atom? of unit cell is 4.29 A, what s
(A) 2.15 A (B) 2.94 A

C
C) 4.29 A D) 1.86 A
aieo 62. How many unit cells are present in 1.00 cm' of aluminum A 7
3.54 x 10 cm? crystal, if edge length
of unit cell3

T
(A) 4.508 x 102 (B) 6.022 x 103 C)1.126 x 102 (D) 2.254 x 102
63 What is the density of iron crystalwhich crystallizes

H
in body centred
gd beiq length 287 pm? (At. mass of Fe 56 amu) cubic structure with edge
=
(A)7.87 g/cm (B) 6.07 g/cm C)7.07 g/cm
(D)6.87 g/cm

M
77
64. Which is the radius of sodium tom if it crystallizes in
bcc structure with
4.29 x 10 cm? un cell
(A) 1.61 x 10 cm
bilo uotigoreto s
(B) 1.85x 10 cm
edge length ofunit

(C) 6.19 x 10 cm (D) 2.30 x 10 cm ireiA 7

 age
Date No.

65. What is t mass of unit

of cell
(At mass of gold= 197 g mol) gold if it crystallises
edgelength (A) 130.85 x 1023 neto in fcc structure? Solid State
(91)
(C) 32.71 x 103g Y (B)
98.14 x

n
102 g
66. Gold crystallizes in fcc
fecc structure soD)
with edge
65.42 x 102

o
(A) 198 pm
10 cm (B) 162 pm length 396

is
g of pure r chloride
crystallizes )(C)714pmpm, find atomic radius dius of gold.
the edge ngth of unit in to fec type (D)
c ell of
will be (Given crystal system. 140 pm
(A) 9.889 Å

s
(B) 7.426 A At. Mass If density of
of Cu- unit cell is 3.4 g
An element
crystallizes as (C) 5.783 A 63, CI-36) cm

e
odium is S

simple
of an element? cubic having D) 3.642 A
celledge length 5

s
(A) 261.5 pm A.
(B) 176.8 pm What is the radius
of atom
59.The edge length y(C) 216.5 pm

t
of bcc type of (D) 250.0 pm
cell.(Molar mass of an unit cell
element = 100 of an element is 400 pm.

b
(A) 2.144 g cm g mol Calculate the
density of unit
(B) 10.378 g cm
70. The number C) 7.289 g cm

u
of atoms in 100 g (D) 5.189 g cm
200 pm is equal of an fec crystal with
to density 10g cm

o
and unit cell edge
(A)1x104 (B) 3 x 1034
length
71. What is the edge length xe(C)2x 104

D
of D) 5x 104
or? 60 g respectively? fcc type of unit cell having density
and atomic mass 6.22
(A) 6.83 x 10 g cm and
cm (B) 4.0x 10 cm

1
ice the 72. metallic element
A
C)3.47 x 10cm (D) 8.0x 10 cm
crystallizes to bcc type

2
Calculate radius
of its atom.oriod of crystal lattice, having
edge length of unit
(A)250.0 pm cell 5 AA.
B) 176.8 pmi

0
8, An ()261.5 pm (D)216.5 pm
element (atomic
in bcc the density mass = 100 g/mol)
having bcc structure has

2
of the unit cell edge 400 pm.
(A) 2.144 g/cm element?goE What is
B) 10.376 g/cm C)1.289 g/cm
A metallic element aD) 5.188 g'cm

T
has a cubic lattice with edge length ofunit cell 2 A. Calculate
hat i unit cells in
200 g the number of
(A) of the metal, if density of metal is 2.5 g cm
10.0x 1025 7

E
(B) 6.25 x 105 (C) 6.40 x 1025 (D) 1.0x 1025
ne radius of a
sphere in simple cubic lattice is 3 nm. What will be the edge

C
ell is cell? length of an unit
(A)
9x 10 m
76. Silver
(B) 6x 10m (C)3x 10m (D) 1.5x 10 m

T Crystallizes in
edge face centred cubic structure, if radius of silver atom is 144.5 pm.
the edge What is
length of unit cell'?

H
pm
(B) 289.0 pm bait o (C)428.6 pmot gavol (D)333.7 pm
tcell
7.Mass of unit
What cell offan
an element is 415 x 10 g. If edge length of unit cell is 3.50 x 10 cm.
m,

M
(A)7.32the density of element
is

Cmo(B)9.67
78.Metallic
g/cm ox (C)1.18 gcml a D)4.67 g/cm

oT 1ts
(A)113.2 nent crystallizes FCC type crystal lattice. What is the radius of atomi edge length
unit cell if
pm is 405 pm? ny aul 1o (D) 202.5 pm
(B)143.2 pm (C)175.3 pm
 XloL3
length of unitcel m
(92)MHT-CET Exam
Questions having edge 94. How
type of crystal lattice 0.53 g
crystallizes in bcc
79. An element radius of atom of an
element?
(D) 1.905 x 10
cm (A) one
4.4 x 10 cm. What is the
(C) 4.72 x 10 cm

n
(B) 3.72 x 10 cm Element A ocCupy edg
(A) 2.22 x 10 cm form a molecule.
y 23 95. The
crystallize in hep lattice to density

o
elements A and B (A) 246
80. Atoms of molecule is (D) AB3

is
the formula of
of tetrahedral voids, (B) AB (C)AB ma
(A) AB mass of gold is 197 g mol, the mass
structure. If atomic
face centred cubic
81. Gold crystallizes in

(A)6.5 x 10kg
is
of unit cell of gold (B) 3.25 x 10 kg (C) 1.3 x 10 kg
fec lattice. If edge
length of the unit
(D) 3.9x 10 kg
cell is 4.07 x 10

e s
cm and densiity 1. (A)
Si and

s
82. An element crystallizes in element. condu
the atomic mass of
is 10.5 g cm". Calculate (C)64.33 g mol D) 106.6 gmol

t
mol (B) 10.66 g mol D)
(A)67.41 g pm, calculate the 2.
unit cell. If the radius of copper atom is 127.8
fec Numb

b
83. Copper crystallises with = 63.55 g mol")
density of copper? (At. mass: Cu
cm (C)4.4 g cm D) cm
8.9 g

u
(A)9.5 g cm (B) 1.89 g Given
Mass
84. Fullerene is an example of

o
(C) lonic Solid (D) Metallic solid Volur
(A) Covalent solid (B) Molecular solid
g. What is the mass of one atom of copper? Mass
of copper is 419 x 10

D
85. The mass of fec type unit cell
(A) 1.047 x 10 g atomb gitvsd flos (B) 2.09 x 10g atombo silf
(D) 4.19 x 10 g atomitooias102
s 3
Nu
(C) 1.048 x 10 g atom

86. Which among the following types

and 'b'?
(A) Tetragonal (B) Hexagonl

2 1
of unit cells has bond angle equal to 120° between edges 'a'

(C) Orthothombic D) Monoclinic

3. (C)
For f
Edge

0
87. Copper crystallizes as face centered cubic lattice, with edge length of unit cell 361 pm.
Dens
Calculate the radius of copper atom.
ive (C)157.600e8
fom imote) tesmele nA.a

2
(A) 108.6 pm (B) 127.6 pm
NA
pmoroD) 181.6 pmn
Mol
88. An element crystallizes in bc structure. The number of unit cells of an element
in 4 g of it s

T
(Given: At mass = 40)
rdus s2stl eotmois 3km A B Wel
toit
fstorm to
1(C) 9.1xNA n
E
(A)2x0.1 Na (B)0.2 xNA c D)0.1 NA
89. Aluminium crystallizes in face centred cubic structure, having
o(e

C
J length of the unit cell of aluminium is
atomic radius 125 pm. The edge
4. B)
(A)250.0 pm (B) 353.5 pm (C) 465.0 pm D)253.5 pm Chr

T
*90. Which among the following is NOT paramagnetic mag
in nature?
(A) Benzene (B) Fe
C)Cu

H
(D)Oxygen 5. (C)
91. Which ofthe following formulae is used
to find edge length bcc
of unit cell?0(A
(A) B)3 Vol

M
(C) nue
4r
3
opl (D) V8r M.tt 6. (D)
92. Bcc type of crystal lattice contains 1.208
x 10 unit cells. Howlo
stoe
present in these unit cells ? many atoms of the elemenare Car
pl p (A) 6.04 x 10 (B) 3.618 x 7. (A)
*93. The edge length of fcc unit cell
10c(C)1.208 x 103e
(D) 2.416 x 10 Na
of xenon is 620 pm. What
(A) 235.166 pm (B) 189.37 pm is the radius of Xe atom?
(C) 209.87 pm
8. (C
D) 219.23 pm
 AGe
(Date
No.

ogl2
th of unit many 1ithium atoms are
cell 94. How present
0.53 g cm (At mass of Li = 6.94) in a unit
0 cm
(A) one atom (B) four nebr
atomsu leo cell with
edge length
Solid State (93)

(C) two 3.5 A and density

A occupy

n
nt length of bce type
2/3 95. Theedge of unit cell atomso(D)
density is 2 g/cc ? of metal is six atomso
5 A. What

o
(A) 246.5 pm (B) 232.5 pm is the radius

is
of metal atom if it' s
mol, the mass (C)176.8
pm
D) 216.5 pm
kg

s
SOLUTIONS
m
and density I. (A)

e
Ge are semiconductors
which are bad conductors
nductor

s
at high temperature.
Hence, Si and Ge of electricity
are semiconductors at room temperature but a

t
calculate the (D)

Number of unit cells mass of metal

b
mass of one unit cell
edge length of unit cell = 2A =
Given, a of auh 9pub
srt

u
belob
Mass of metal = 200 g, Density
2x 10 cm
id of metal = 2.5 g cm
Volume of unit cell =

o
(edge length = (2 x 10 = (A).
m of copper? Mass of one unit cell = volume 8x 10 cm
x density = 8 x
10x 2.5 = 20 x 1024

D
Number of unit cells in 200
g metal= mass of metal 200
Js9m 1o Jov ass of one unit cell 20x10-2410x 10-1.0x 1035
pen edges 'a

1
3. C)
For fcc
o inu sno to fov ldon to g080 iallso tu to o
cell, n = 4

2
Edge length, a = 404 pm
ell 361 pm. = 4.04 x
Density
10 cm

0
of metal, d = 2.72 g cm
NA=6.02 x
10 mol

2.NA
Molar mass
4 g of it is ofthe metal, M =?
Weknow
that density, (P) nxM

n.Theedge . (B)
M=

E T P-a NA2.72x(4.04x10x6.02>x10-27 gmolrl

n

C
Ch
ma
magnetised.V)oxide i.e. CrO exhibit very strong magnetic property. It can be permanently
It ontains larg number of unpaired electrons.

T
S. (C)

Volume od e tisg zinu to ogg pod u ougge bioy jo omlog beigucon

H
occupied
by face centred cubic unit cell is
6 (D)
element are arbon dioxide

M 1.(A)

C
aCl,KCI,
CsCl
a
is non-polar solid.

show Schottky defect.

glo yigo bviog
to oiavge on it oont,Hoal
(8).
Sol Lal]
Exam Questions formula
(94) MHT-CET
They have similar chemical aeand
identical. comparable.
is almost
9. (D) isomorphous substances cation radii are generally
Crystal of anion and

n
polarizability i.e. ratio of

o
10. (D) simple cubic cell-52.4%

is
Volume occupied in
unoccupied47.6%
Volumeremains

s
11.()
12.(A)
ForBCC,
.av34.29*10"*-1.86 x 10* cm

s e
t
4

cations in the crystal

b
13. (D)
The defect produces due to
vacancies caused by absence of anions and
lattice is called as Schottky defect.

(A)
19.(B)
Mass
15. (D) 16. (D) 17. (B)

38.6g - 2 cm
o u
18. (B)

D
Vol. of metalensity
Density 19.3g cm
Total vol. of metal

1
No. of unit cells in 38.6g of noble metal =.
Vol. of one unit cell

2
2 cm 1022
6.18x10" cm
3.236 x
20. (D)

T1.86
=2
x 10

2 0 cm

T
For bcc structure, r =

V3a=4r

CE
21.(A)
r4x1.86x10 cm
a 4.3 x 10 cm

T
Packing efficiency in bcc type
of unit cell
Unoccupied volume or void space in 68%.
bec type of unit cell

H
22. (D) is about 32 %.
InFCC, No, of atoms per unit cell -4

M
Mass ofunit cell
Mass of 4
atoms4 x 6 x 10 g
-24x 10"g-2.4x 10 g
23. (B)
In CH4, there is no
separation of positive
and negative charges.
24. (C)
 eoup moxT Solid
25. (D) State (95)
mulae =(100 pm)
and Vol. of unit cell = (100 x 100 cm) Mx
10 cm
Vol. of 100 g of an element Mass 100g
Density 10g cm
= 10 cm

No. of unit cells in 100 g of an element = Total volume

Volume of one unit cell
MX
o n
26.( oniheto
10 cm
10 cm x10 unit cels
is
For a fec type of unit cell,
0.3524 nm
=0.1246 nm
e s
s
2.828 istoo fog &.09 aesnio
the crystal

t
27.(B)
n= 2, p = 4 g cm

b
In bec,

a 500 pm = 500 x 107 cm 5 x 10 cm (C).2e

Volume of unit cell,
pxaxN
a = (5 x 10 cm)

o
=

4x125x10 X6.022 X10-150.5 g mol

125

u
x 104 cm

28. (D)

D
1
For bec crystal,. r-
os i od so

2
a =
4X1.33 x10% cm

0
1.732
a 3.07 x 10 cm.
A
29. (A)
a4Å = 4x 10
2 cm, p
=
2.7 g cm,

T
M 27, n=?

E
n Pxa'XN 2.7x(4x10 x6.022X I =3.85 =4oLxExDE
M 27

C
30. (D)
For bcc unit cell, O)8E

HT VS
31.(D)
For foc type
YSXS

unit cel
-151.98pm
dolom 3o armuie

-361 pm
M 32.(B)
a
22
250 pm
M 90.3
a

m
2.5x 10 cm
r(2/2) - 127.6 (2/2)=360.85
oesailleteCoho olamo prmulo

(C.8
mol, (for fec cell)
 Questions 42. (D)
(96)MHT-CET Exam a
4x90.3
nxM (2.5x10*' x6.022 x 10 Fo
axN,
3840 g cm
709001 Joya

n
p

o
33. (B)
cm, a-4x 10 cm,

is
p2.8g
(for foc), M-2
43. (D
n-4 PXa"XN
nXM
M

s
p-
a'xN
2.8x(4x10 )x6.022x10-26.97-27g mol

34. (B)
M

s e
t
6.022 x 10 particles
Molar mass 60.22 g mol contains
44. (E
element contains 4 particles (FCC)

b
xgof
60.22x4 40 x 1023=4.0 x 10 8
.0-39d
u
6.022x103
Ox00E q 09 M

o
35.(D)
For fcc unit cell, r= 2
a-r(2/2) 125(2/2) = 353.5 pm
D Mwo

1
45.
36. (B)

For bec unit cell,

:. a= -4x1.86x10
r
cm

0 = 2
4.29 x 10 cm

2
1.732

37.(A) 46. (1
a
T
300 pm =3x 10 cm
For bcc unit cell, r = YSa

E 4 F
1.732x3x10 cm

C 4
1.299 x 10 cm

T
38. (C) 47. 1
leg i03d 302
a 16x 10 cm a

H
Volume of one unit cell = a =(16 x 10
4096x 10 cm
Volume of 24 molecules

M
4096 x 10 cm
. Volume of 1 molecule 4096x104 e
90t 24 170.67x 102 cm
Volume of I mole of a crystalline solid
170.67x 1024 x 6.022 x 10
1027.77 x 10
39. (D) 40. (D) 102.7 cm mol
41. (D)
 DateNo.
elb
b os
42.(D)
pmn
21
a620
fec unit cell, r= oklicylobedago Solid State(97)
For
noo19durnosboeea
620

n
2x1.414 219.2 pmn

43.(D)
n4,p3.4
a nXM
g cm , M-98.99,
4x98.99 a=?
is o
s
pxN 3.4x6.022x103
cm

e
193.4 x 10
a - 5.783 x 10 cm (Ce

.(B)
a5.783
a=3A =3x 10 cm
A

t s
b
SE.DE
Volume ofthe unit cell
(a) = (3 x cm =27
=27 x 10" cm° x10

u
Mass of unit cell x 104 cm
8 g cm
=
216x 107g

o
216x 10 g=l unit cell 3 le 1o loV
108
108 g to alqmse oug to g ot i
D
1023 unit
216x10- 5x cells. allessioto
of
45.(D)

1
a 288 pm = 2.88 x 10 cm
a (2.88 x 10

2
cm =
p 2.39x10 cmn
7.2 g cm", n = U9 7ia 1osqg9dsq amois 1o
2 (for bcc cell) o

46. (B)
M

a=316.5 pm
PXa' xN 7.2x2.39x10x6.022x103
n 51.81

2 0
g adto 2M
2800.
For fcc unit

r316.5pm = 111.91
cel,

E T
r/
ousrgorol-o1

C
2x1.414 pm
47.(B) (E)08
S00pm =5x (6).e

T
a 10 cm 913910g4010ret uiloba)
(5 x 10 cm)= 125 10 cm
x oitongaitiet ogyAO
cm, m 300 g,n=2 (for bcc cell)

H aN
7.5g
aiiorgemerCitsd jsteW
P nMM
M - Pxa'xN
a'N

M
n

M-25x125x10 x6.022x10-282.3 g mol 9g0n l0eoy 3om

282.3 2
gofmetal 10 atoms bgnol ogb 0oal otdiy olgrale a
ntains 6.022 x
300 g of
metalcontains 6.022x10x3006.399 x 10 atoms = 6.4 x 10 atoms
282.3
 MHT-CET Exam
Questions 60. (B
(98) In
48. (A) octahedral void is 6.
coordination number of an N
The

n
49. (C) 12

50. (A)

o
2

is
51. (A) = 74 %
Packing efficiency
For fec unit cell, 61.
Unoccupied space 26% F
52. (D)
For BCC,

e s
17.32 0.4330 x a
t s (E)
62.

b
17.32
a 40 s01 6A8-
0.433
53. (C)

Vol. of element
Mass
Density
368 5 cm
7.2 g cm

o u 63.

D
Total Vol. of element 01
No. of unit cells in 36 g of pure sample of element
Vol. of one unit cell 901

54.(D)
2 1 5 cm
24.99 x10-Cm2.0
n 0tx 28.)
x 1023

0 98
No. of atoms per bec type of unit cell, n= 2
Mass of bcc unit cell Mass of two atoms
. Mass of boce unit cell of Na 3.819x
27.638 x 10
1023 x 2
g
Mxa M
55. (D)
O-Paramagnetic

E T (EO3
mg &o1t
64.

C
Benzene, water Diamagnetic sinu oo1 10
3lso
Fe- Ferromagnetic

T
56. (B)
57. (A) 65.
(81.4

H
Gadolinium- ferromagnetic
Oxygen- Paramagnetic
01x mg
00s

M
Water, Benzene Diamagnetic
58.(D)
When a trivalent impurity (B, Ga, In, Al) are M
added to a pure semiconductor mall
amount results in p-type semiconductor, (Si, Ge) in s a
59. (B) 66.
In a simple cubic lattice, edge length (a)= 2r ttoooioc oc
 o0.(B) cach unit cell has 2 atoms.
In bee, Solld State(99)
No. of atoms
No. of unit cells
No. of atoms
per unit cell
No. of atoms
12.08x 1023
x 1023

n
=
24.16 No. of atoms-
2.416 x 104
61.(D)
For bee

3xa-
structure, 4r 3 a
2 x4.291.857
is o
s
1.86 A
62.(D)
a
--3.54 10
(3.54 x 10
x cm
= 4.436 x 10-2 cm
ig 002A2e

s e
No. of unit cells= Ol. of Aluminium
Vol.of unit cell
I cm

Cm
4.436x103

b
2.254 x
t
102

u
63.(4)
nXM 001eS
DensityN,xa

For BCC,
287 x 10

n=2
m 287x 10 cm

D o 005
FO1SS0.0xotxko

1
2x56 112
6.022x103 x (287x 10-10 1.423x10' x10

64. (B)
112
1.423x1014.23
112 7.87 g/cm

0 2 Mx
otxox 01x005)
In

4r
BCC structure,
=
3 a
2
65.(A)

E T
1.732x4.29x101.85x10 cm
S

C
S I
of mole of Gold atoms 197 g/mol
(6.022 x 10 atoms)
Mass 197
of 1 atom of gold. 6.022x103

nall

HT FCC cell

So mass
has 4 atoms.

of gold in unit cell

197 X4
6.022x10
1.3085 x 10 g 130.85 x 10g

M
66.
D) ORESO
In fcc
structure
4r-2a
414x396 139.98-140 p
 (100)MHT-CET Exam Questions 12
67. (C)
Density (d) nxM
N on to.o

n
o
3.4
4x99
x6.02x10
[CuCl 63 +36 99) 0
396
3.4x6.022x10
a193.47 10x 1024 uto is
opd o4 o 7

s
cm
a -5.78x
Edge length (a) = 5.78A
68. (D)
For simple cubic unit cell; edge
Edge length (a) = 5 A= 500 pm
length (a) = 2r

s e
r- 500pm
2
250 pm

b t allsa inu to so

u
69. (D)
Edge length of bcc type cell 400 pm
(A)

o
M=100 g mol
nxM 2x100
Density (P) (400x100} x6.022x 103
200
64x10 x6.022x10 D
- 5.189 g/cm 0xT8s
70.(D)
Density= nXM
Density
a xNo
2 1
O101&60A O8)O1x SSo.

10
(200x10)yx6x103
10X8x100 x6x103
4xM

2 0 01x661
1ulouzie 908

T
M = 12 g/mol

E g will contain
6x10 x100 x 103= 5 x 10
100 =
12
atoms

71. (B)

C turo0KSS00) 1orae tRi 2mo1a bloD10 slom 1

(A) 2

T
Density= nxM to22d
aXN

H 6.22 4x60
ax6.023x10

M ri blon to ay g
240 2400 xCc03 9u
6.22x6.023x10 6.22x 6.023 x10
-64.06 x 104
-4x 10 cm
 ate

72.(D) TSolld State (101)

o or iFor BCC, 3 a =
4rnolb lotep roy bodosor ow

n
3x5x10-10 o

o
4
e0.c

is
2.165 x 100=r
r- 216.5 x 10* m=216.5 pm
73. (D)
Density p
=
XM
axN
e s
s
For bcc; n=2 sAat oluoolontougo
2x100 200

t
(400x1010y x6.022x10 64x6.022 x10
= 5.188 g/cm

b
74.(D)
200

u
Number of unit cells in 200 g of the metal
2.5(2x10 cm)

o
200 -200104 = 1.0x10
(A).a
2.5x8x10* 20
75. (B)
For simple cubic lattice,
D O30.20xot0 20
r
I=3 nmn
a-2
a= 2(3)=6 nm = 6x

2
10 m1 Tomg 2.0013

76. (A)

For FCC,r

.
=

2 0 -0.3535 a

T
144.5 0.3535 a
a = 408.7 pm

E
77.(B)

C
Density
Mass of unit cell
Volume of unit cell i.e.
a
SS
0

T
415x104 415x10 - 9.67 g/cm AA
(3.5x10 42.875 x104

H
78.(B)
For FCC,
moo3oaosM
143.167 pm
ls
M
=0.3535 x 405-
0.3535 xa
79.(D) epg inaogroH
of ip ofg bered asf alfey acs lo
DCC Crystal, wsd 0Ci
10
x 4.4 x 10=1.905 x
433 x a 0.433
g i
e(102) MHT-CET Exam Questlons
tetrahedral.
88.
atom. Since A OCCupy vo
80. (C) associated with each
voids
nere are two tetrahedral
the ratio of A and B is,

n
2A B

2x 1
M
is o 89
4:3
Ratio of A: B = 4:3
Formula of molecule is
A4B3

e s
81. (C)
Since, 197g of gold =
xgof FCC crystal of
6.022 x 10 particles
gold = 4 particles
t s 90

b
10kg= 1.3 x 10 kg 91
197x4 x 10" g= 0.1308 x
X 130.8
u
6.022x10
82.(D)

o
nM
P 91
a'N
10.5
4xM
(4.07x10yx6.022x10
D
426.29 = M=106.57 g mol

2 1 9

0
83. (D)
nM

2
a'N,
2E9

T
2820.02
4x1.278x10 cm 20

E
a
2

C
3.615 x 10 cm
47.25 x 10 cm
4x63.55 25 -8.934 g cm-3oV
T
P 47.25x10x6.022x10 28.451

H
84. (A) O1&218
85. (C)

M
Since it is FCC type unit cell, n = 4
419x104
Mass of one atom of Cu 4
- 1.0475 x 10 g atom
86. (B) (a).e
Hexagonal types of unit cells has bond angle equal
to 120° between edges 'a' and D
87.(B)
EEEOsECO
For FCC crystal, r= 361-127.6 pm
 88.(C)
.4XNA particles anoitulos
4gof metal contains 4XN
voids, Solld State (103)
40
Particlesoso5iuo
=0.1 x NAA particles.
For bcc
crystal,
particles El
n-2 hem
2 unitcell
=X
n
0.1 xNA particles unit cells.

o
olredb lebieo

is
9.(B)
oitnloefabioloo
For FCC, a =
21.414*125 s touoeguosgo1915

s
353.6 pm.

e
90.((A)

s
Benzene is diamagnetic while
others are paramagnetic
in nature. 0 02 nt

t
91.(A)
Relation between edge length

b
(a) and radius (T) in
4r BCC is given .252.
by
io
a

u
biupis

o
1838
92.(D) onoolA g.3 bipil e
biupt

Crystal lattice contains 1.208 x 10 unit cells.

Type
ofcrystal is BCCn=2
No. of atoms
D toiulo2 biloe

1
present in BCC unit cellsg larus muihoe g.s 5iloe
nt bipe
2x1.208 x 10=2.416 x 1023
atomseyolle istoM 39 biloz ai biloe
93.(D)
For FCC unit cell,

0 2
I2 4
x620-219.20
4
2 0uloe oul ovode 20g sr to qweeie
0 2

T
94.(C)

E
= nM
N,a
-PN,a
C teoi9gpr srizagile
0.53x 6.022x102 x (3.5x10 )" Aonytulos a viogorg o
T
M 6.94 allsp a olotsg okoa to teoiteogno
25.81x0.53 13.68

nH
= 1.97iou 30 oue1 20096 19 2tool sotsiss
6.94 6.94
2
e soga
M -1.752500
For
BCC crystal
structure, to-giee
T
om=0.433 x 500
5.D) pm10.Piopil odt 1e

imoitoh fop
O000to
 2. Solutions
Shortcut Methods
ImportantFormulae and of the particlesof
components. Depending on the sizes
two or more
Solutions are the mixture of mixtures are classified into three types
components of the solution, the
1. A coarse mixture
2. A colloidal dispersion

o n
is
3. A true solution sugar
solution: e.g. a solution of NaCl or
Homogenous starch
colloidal solution of
Heterogenous solution: e.g. a
Different Types of Solutions
Gaseous solution
e s
i. Gas in gas e.g. air
ii. Liquid in gas e.g. CHCl
i. Solid in gas. e.g.
mixed with Na gas
fumes, smoke

t s onule
Liquid Solution
i. Gas in liquid e.g. CO2 in
ii. Liquid in liquid e.g.
ii. Solid in liquid e.g.
water
Alcohol in water
NaCl or sugar in water
u b
Solid Solution:
Gas in Solid e.g. H2 gas in palladium
ii. Liquid in solid e.g. sodium amalgam
ii. Solid in solid e.g. Metal alloys
metal

D o
such as brass, bronze

Solubility of Gases in Liquids:

2 1
Henry's law The solubility of gas in a liquid at constant
a

pressure of the gas above the solution.

temperature is proportional to the

Where,
SocP or S=Ku

P
S =
xP
Pressure in bar
2
KH= Henry's law constant
0
Solubility of a gas in mol dm

T
Colligative Properties:

E
The property of a solution which depends on the total number of particles of the solute
(molecules, ions) present in the solution and does not depend on the nature
or chemical

C
composition of solute particles is called colligative property of the solution.
e.g. (a) lowering of
relative lowering of vapour pressure of a solution (b) elevation
in the boiling point (C)
depression in the freezing point (d) osmotic pressure.

HT L.
Lowering of Vapour Pressure
.Vapour pressure The pressure exerted by the vapour
equilibrium with the liquid phase at
of the liquid.
of a liquid when it 1s
a constant temperature is called
the vapour presSu

M Lowering of vapour pressure

Raoult's law: PsolnXPo,
X1
AP:
Po=vapour pressure of pure
mole fraction of component
P--W,M
Po wM
in the solution
solvent (C20

Thus, the relative lowering

of vapour pressure is
equal to the mole fraction
of the so
 Elevation of Boiling Point Solutions (105)
i. he elevation in the
The boiling point of a
hoiling point of the solution
souttonand the pure solvent is defined as the difference between e
. If To and T are the boiling at a given pressure.
points of a pure solvent
boiling point, AT,= T-To and a solution, then the elevauon
of "
ATb Kb.m
Where, Kb
ATb
Ebullioscopic constant, m
KxX1000 molality

o n
is
WxM,
Units of Ka-K kg mol

s
ii. Depression of Freezing Point
The depression in the freezing point of a solution

e
is defined as the difference between the
freezing points of a pure solvent and that of the
solution. o

s
AT To-T (T<To)
AT Kr. m
Where, K

AT
Cryoscopic constant, m = molality
KxW
KWxM2
x1000

b t
u
Units of K= K kg mol b0 8
iv. Osmotic Pressure

Isotonic Solutions:
solutions.
MRT, D o
The solutions having same osmotic pressure are called isotonic

1
T1 M2RT
T2
Since ti = Tt2, M = M2

0 2
If the solutes are present in equal volumes of the solutions, then, sribero

2
Vi V2

n n2

T
having equal volumes, the number
Hence isotonic solutions at same temperature and
must be equal.
moles or number of molecules of two solutes

CE
Hypotonic Solution: Among two solutions,
to be hypotonic to another.
n n2.pn
one having a lower osmotic pressure is said
Hence if concentrations are Mi and
nbebrtog
M2 then, Mi < M2 or

HT Hypertonic Solution
said to be hypertonic to
Among two solutions, one having
:
another. Hence, M1> M2 or nj>
n2.
higher osmotic pressures is

othe obsle

M
of Solution
Osmotic Pressure and Concentration wl&ooiA)
(Where, M = Molarity)
ot av (0)
MRT M2 Molar mass of solute)
WRT (Where, W2 - Mass of solute,
RT M,V ovatelolo2.01
vrgilas
 11
Questions Questions
MHT-CET Exam
(106) Multiple Choice
12
non-electrolyte in water is
MHT-CET 2004 molal solution of a (D)0.093°C
point ofa
0.05 (C)0.93°C
1. The freezing (B) 1.86°C

n
(A)-0.093°C
is 1sotonic with 10 cane
aqueous solution
MHT-CET 2006

o
per litre, if
urea dissolved

is
amount of (D) 16.7 g/L
2. What is
the
(mol. wt. of urea- 60)? (C)17.54 g/L
sugar solution (B) 19.2 g/L
(A) 200 g/L
MHT-CET 2007
3. Which of the
following is not a
colligative property7
(B) Lowering of
vapour pressure

e s
s
boiling point (D) Freezing point
(A) Elevation in
(C)Osmotic pressure
MHT-CET 2008
4. Maximum
depression in freezing point is
caused by
(B) sodium sulphate
b t
u
(A)potassium chloride (D)magnesium carbonate
(C) magnesium sulphate
MHT-CET 2010
5. Dissolution of 1.5 g of

point by 0.01°C. Find the

D o
a non-volatile solute (mol. wt.= 60) in 250 gof
molal depression constant of the solvent.
a solvent reduces its freezing

D)0.1

1
(B)0.001 (C)0.0001
(A)0.01

2
MHT-CET 2015
litres
of solute, mass of solute and volume of solution in

0
6. If M, W and V represent molar mass
respectively, which among following equations is true?

2
MWR (B) TIMR (C) n=-
TWR
(D)
RTRV
(A) T=
TV wV VM WM
*7. van't Hoff factor

(A)33.33

E T of centimolal solution of Ka[Fe(CN)%] is 3.333. Calculate the percent

dissociation of K3[Fe(CN)6].
(B)0.78 (C) 78
ateatt
(D)23.33
MHT-CET 2016

C
8. Identify the compound amongst the following

T
of which 0.1 M aqueous solution has higne
boiling point.
(A) Glucose (B) Sodium chloride (C) Calcium chloride

H
(D) Ferric chloride
9. The relation between
solubility ofa gas in liquid at constant
stated by which law? temperature and external pressu

M
(A)Raoult's law
(C)van't Hoff Charles' (B)van't Hoff Boyle's law
law
fs
MHT-CET 2017
(D)Henry's law

10. Solubility of which

(A) KNO
among the following
solids in water changes
(B) NaNO slightly with temperauu
ure?
(C) KBr
(D) NaBr
 osmou nressure of solution
t 20° Cis (Given,containing 34.2 g of cane
11. 1 fsolution at Solutions (107)
IL atm (B)3.6 atm R= 0.082 L atm sugar (molar
mass 342g mol
(A)2.40
(C)24 Kmol)
atm
For
which among the following equimolar (D)0.0024
12.Value? aqueous solutions atm
(A)Aluminiumchloride van't Hoff factor has the
o lowest

n
(C)Ammoniumchloride (B) Potassium
sulphate
(D)Urea

o
MHT-CET 2018
% cane
13. The com et

(A)M =Ah.
W
relation between elevation

(B)Ma=K,.W
ofboiling point and molar
mass of solute is
is
,K
s
AT, W AT.W2 (C)Ma (D)M, AT,
W
WW

e
K,.Wa
MHT-CET2019

s
oda fosmo TO
alenlate van't Hoff factor for 0.2 m aqueous solution
of KCI which freezes at-0.680°C.

t
(K = 1.86 K kg mol) q Yomg
(A) 1.86 (B) 6.8alke s (C)3.72wnodufo

b
(D) 1.83
15. KH is Henry's constant and has the unitloe

u
(A) atm mol dm (B) mol dm atm (C) atm mol dm D) mol dm' atm

o
of components form homogeneous mixture?
16. Which of the following sets
(A)Silver chloride + Water (B) Sugar+Benzene

D
ezing (C)Ethyl alcohol+ Water (D) Phenol + Water

17. If the van't Hoff factorfor 0.1M Ba(NO3)2 solution is 2.74, the degree of dissociation is

1
(A)0.91 (B)0.87 (C)0.74ouutoa lal(D) 87

2
18.9 gram anhydrous oxalic acid (Mol. Wt = 90) was dissolved in 9.9 moles of water. If vapour
pressure of pure water is Pi', the vapour pressure of solution is

0
litres
(A) 1.1P (B) 0.99P 0.8d) (C) 0.90Ps T(D) 0.1P

2
urea (mol. mass. 60 g mol") and sucrose (mol. mass.
19. of the following sets of solutions of
Which
342 g mol) is isotonic ?
(B)3.0 gL urea and 3.0 gL sucroseo

T
cent (A)3.0 gL urea and 17.1 gL sucrose
(C)9.1 gL" urea and 6.0 gL sucrose (D) 6.0 gL urea and 9.0 gL sucroseCA)

(A) E
20. Relationship between vant Hoff factor

C
a-i
n-1
(B) i=1-n
(i) and degree of
(C)i=
dissociation (a) is

n-1
(D)a-
n-1
ate
T
hest water at 300 K. If R 0.0821
180) is dissolved in 100 ml of
1 18 gram glucose (Molar massosmotic pressure of solution'?
21.1

H.
-atm mol K', what is the (D) 0.821 atm
(C) 24.63 atm
e is (A) 2.463 atm (B) 8.21 atm
aqueous solution of a
substance is

M
0.25 molal
elevation in boiling point of
The
(D)0.15 Kpenog
(K0.52 K kg mol") C)0.50 K a80(8
(A)0.13 K (B)2.08 K0800 solute is
point and molar mass of the A1,W
23. Relation depression of freezing (D) M-
Detween
W,
K,WL (C)Ar M,Wi KW
(A)AT M, Ma
(B)Ma TW2
KW2
 (108)MHT-CET Exam Questions 34. Osm
colligative property among the
followings. pressure
Vapour a
of solvent
(A)1
24. Identify the
a solvent
(B)
Osmotic pressure of a solution
35. Whi
(A) Boiling point of (D)
(C)Freezing point of a solvent is isotonic L
with 6.6 g ofurea? (A)i
1L solution
which
mass of sucrose in its (B)

n
25. What is the 12, N = 14, O-
16) D) 34.2 g A)
(Atomic mass: H 1, C- (C) 68.2 g C)
(B)30.1g

o
(A) 37.62 g solution2 (D)
molal aqueous
value in its 0.05

is
highest
Which of the following solutes has m 36. Va
26. (B) Gluco0se dre
chloride
(D) Aluminium
Potassium sulphatee

s
(A) (A
chloride
(C) Ammonium
37. W
MHT-CET 2020
27. Which of the
following statement is NOT
heterogenous
correct about solution?
mixture of two or more
s e
substances with fixed composition
fr

t
(A) True solution is a
may play the role of
either solute or solvent
matter solid, liquid and gas
(B) The three states of solute 38..A
constitute smaller part is called

b
(C)The component of solution which
as hydration
process of solvation is known
(D)When water is solvent, the

u
cause increase in vapour
pressure of l molal aqueous K
following changes will 39.
28. Which of the

o
solution at same temperature?
obyoto19y 12 (A
(A)addition of 0.1 molal solution of NaCl

D
(B) addition of I molal KI solution 40.
C) addition of water
NazSO4 AOCA)

1
(D) addition of 0.5 molal solution of
29. Which of the following pairs of solution is isotonic?
41

0
(A)0.3 gLurea and 17.19 gL sucrose
(C)3.0 gL urea and 1.719 gL sucrose 2
(Molar mass: urea = 60, sucrose= 342 g mol)
(B)3.0 gLurea and 17.19 gL sucrose
(D)30 gL urea and 17.19 gL sucrose
42

2
30. According to Raoult's law, relative lowering of vapour pressure for a solution containing a nat
volatile solute is equal to

T
(A)moles of solute (B) mole fraction of solute Jge0)
D)mole fraction of solvent gideaousfs05

E
(C) moles of solvent
4
31. The Henry's law constant for oxygen is 1.3 x 10 mol dm atm. If partial pressure of oxygen

C
is 0.46 atmosphere, what is the concentration of dissolved oxygen at 25°C and
CeD (A)2.82 x 10 mol dm (B)5.98 x 10 mol dm
1 atm pressure

T ()3.53 x 10 mol dm D)5.98 mol dm

H
32. 38.4 g of unknown substance (molar mass 384 g mol") and 116 g of acetone is used to prepa
a solution at 313 K. If vapour pressure of pure acetone (molar mass
58 g mol) is 0.
atmosphere, what is the vapour pressure of solution?

M
(A)0.7999 atm (B)0.880 atm (C)0.650 atm (D)0.958 atm
33. 0.5 molal aqueous solution a weak
of acid (HX) is 20% Ionized. If Kr of water is 1.30 *
mol, the lowering in freezing point of solution is
(A)0.56 K
(B)1.12 K (C)-1.12 K D)-0.56 K
 Osmotic pressure of lar solutionat
34. C 27°C is Solutions (109)
(A) 12.1 atm (B) 1.21 atm (R 0.082)
ong following is true (C)2.46 atm
35.
Wh for the value (D)24.6 atm
(A)is same for all gases of Henry's law
constant
(B)is greater for gases with higher solubilities K?e
(C) increases with increase in temperature
(D) first creases and then decreases

n
with increase
aour pressure of solvent "A in temperature

o
ns is 0.90 atm, when
a non-volatile solute

is
iroj to 0.60 atm. What is mole fraction is added, vapour pres sure
(A)0.500 of A in solution?
(B)0.667
(C)0.300
hat is the value of Ke if 30 g urea (D)0.333

s
(molar mass 60)
freezing point by 0. 15 K? dissolved in 0.5 dm of water decreases

e
(A)0.30 K kg mol
(B)0.030 K kg mol
(C)0.15 K kg mol
18. An amalgam of mercury with sodium is
(A) liquid in liquid solution
(D)0.015 K kg
an example of
moltoatlotel

t
(B) solid in liquid solution s
b
(C) solid in solid solution
(D)
liquid in solid solution
Solution of chloroform in nitrogen is an example

u
39.
of
(A) liquid in solid
(B) liquid in gas

o
(gas in liquid ios (D) liquid in liquid
40. Which of following 0.1 m aqueous solution exhibits highest

D
osmotic pressure at 25°C?
(A) urea (B) CoClh (C)glucose (D) KCI
41. Identify the correct relation between depression in freezing point and freezing point of pure
solvent.
(A) T° = T - ATr (B) T° AT-T

2 1 (C)T°= AT+T(D) T° = Tx AT

0
42. If a centimolal aqueous solution of Ka[Fe(CN)6] has degree of dissociation 0.78, what is the
value of van't Hoff factor?

2
go
(A) 3.34 (B) 2.5 C)12ogeelo 4.0

43. What is osmotic pressure of a semi molar solutionat 27°C? (R=0.082)

T
(A)4.96 atm (B) 2.46 atm (C)12.3 atm (D)20.5 atm
0.10 M NaCl, 0.05 M BaClh and 0.05 M

E
44. Solutions A, B, C and D are respectively 0.2 M urea,
except
AlCl3. All solutions are isotonic with each other
upil nr D)B

C
(C)A dato2.t2
(A)C (B)D
b
45.
Henry's law is a relation between

T (A)temperature and pressure

D23qi (B)pressure and solubility
TUsogd (D)volume and solubility
(C)pressure and volume

H a solution
olatile solute is the ratio of
containing non-voli
46. Relative lowering
in vapour pressure of
of moles of solution
of solute to total number
number of moles

M
moles of solute
of moles of solvent to number of
number solvent total number of moles of
solution
to
number of moles of number of moles of
solvent
of moles of solute to
number
OE (112) MHT-CET Exam Questions with a 6.840
cm of water is found to be isotonic
3.42 g of it in 100
72. Solution of 'A' containing H- 1, 0- 16) (A)
(At. wt: C- 12,
sucrose, what is the molar mass of 'A'?
1
For

n
solutionof
(D)342
(C)171

o
(A)68 (B) 180 Fre
freezing point depression urea

is
will have highest (D)I M
the following solution (C)1 M glucose (C
73.Which ofsucrose (B)I MKC
(A)1 M K3[Fe(CN)6] is 3.333.
What is it's percentag Is
solution of

s
factor () for centimolal
*74. van't Hoff (D)77.7%
dissociation?

e
(B) 33.33% C) 80% non-electrol
(A) 70% isotonic with % solution of
1

s
mass 342) is
cane sugar (molar
75. A 5 % solution of substance X is (D)68.4 g mol
substance X, the molar mass of

t
171.2 g mol (C)136.8 g mol
(A)34.2 g mol (B)

b
statement from the following: is always less than
vapour
76. Identify the correct containing a non-volatile solute
solution
(A)Vapour pressure of a

pressure of pure solvent.
solvent
(B) Boiling point of pure
non-volatile solute.
(C)Liquids having greater intermolecular
(D)Vapour pressure of a solution
pressure of pure solvent.
u
solution containing a
is always greater than boiling point of it's
D o
forces have lower boiling
containing a non-volatile solute
points.
is always greater than vapour

1
water?
77. What is the value of Ky if 6g of
urea is dissolved in 0.1 dm' of
urea = 60)
(AT= 0.15° C and molar mass of augey

2
(B)0.15 K kg molua otl
(A)0.030 K kg mol0
sal (D)0.30 K kg mol ato o
0
(C)0.015 K kg mol
Hot
to determine osmotic pressure using van't
78. Which of the following equation is correct
equation?
(A) rV=
W,RT
2 (B) TC= VRT
sule

T
M 6

RT
E
(C)T (D) rV k
M
79.30x 10
C
kg urea dissolved in water to make 500 mL aqueous solution and it is isotonic win
cane sugar solution. What quantity of cane sugar is present in it's 1 lit. solution?

T (Atmass: H=1,N= 14, O=16, C 12)

(A)171 g (B) 17.1 g (C)3.42 g (D) 34.2 g

H80. What is freezing point of a solution containing 1.8 g ghucose dissolved in 1000 g of water?
(Kofwater= 1.86 K kg mol and at. mass C H=1,0
12, 16)

M
(A)-0.0093°C (B)-0.0372°C
(C)-0.0186°C D)0.0186C
notie
1 1T 10 g each of glucose,
urea and sucrose is dissolved in 250 mL of water having oSmo
pressure nsis
(A)T 2 T3
t,
T2 and
ts respectively, the decreasing order of osmotic pressure of these solutions
(B) 72T>Ta
(C)12TT31 (D) T312
84 SOLUTIONS Solutions (113)

I.(A)non-electrolyte AT Kr x m
For
AT 1.86 x 0.05
Freezing point of
0.093° c
solution=0-AT=0-0.093-0.093°C

2.
Isotonie solutions have same osmotic
pressure.

o n
yte
Molecular weight x V W2
Molecular weight x V, one
is
s
WL 10 60x1011.54
342 x0.1 WI
60x1 342x0117.54 g/L

ur e
(D)
3.enression in freezing point is a colligative property
o

s e
but freezing point is not a colligative property
4 (B)
Na:SO produces maximum number particles.otulo2 lo vankMnlok
Na,SO2Na +S)
of

b t
3 particles

Thus, it causes maximum

D)
depression in freezing point.

o u
D
5.
Weight of solute x 1000 1.5x1000 =
Molality
Molecular weight of solute x wt. of solvent 60x 250 0.1 molal
Depression in freezing point,
ATr Kxm
2 1
0
= =0.1
0.01 Ksx 0.1 Kr 0.1 o1weesyt b lon) eiidulog

2
feae plho tial
6. (C)
The osmotic pressure follows the equation,

T
W
n
RT But,
M

7. (C)
CE WRT
VM
T80

T 4)
(n-
K3 [Fe(CN),] 3K+[Fe(CN)6P

H a l3.555-1=0.78
n-1 4-1
percentage dissociation= 0.78 x
100= 78 %
25lo .0910oio

M
8. (D)

L They all are having same

concentration, the one that
highest boiling point. Ionic compounds
will ionize.
B 2
Will break into the m0st

parts (I Na, 1CI)

2ll4
parts has

part (covalent, does not ionize) 4 parts (1 Fe, C)

3
a I
D
C parts (1 Ca, 2 C)
 Exam Questions 19. (A)

n
(114) MHT-CET constant temn
liquid at onstant temperatute Ure
between solubility of gas in Mas
D)

o
9. the relation
Henry's Law states Mo

is
external pressure. Mo
10. (D)

s
11. (A)
x0.082 x 293 2.40 atm 20. (D)

e
T MRT= 342x1L
21. (C)

s
12. (D)
dissociate into its ions.
Urea does not
13. (A)

T
AT K, x m (m is molality) Wt.

b
of solvent in kg
W
-K MxW
t 22. (A

u
Where nz No. of mole of solute A
W Wt of solute in solution

o
M2 Molar Mass of Solute
W
Ma
M2 X 02 23.

D
AT,x W
25.
14. (D) 75209h,adt
K= 1.86 K kg moll

1
17, m=0.2, Tr0.680°C,
AT=im K

2
0.68 ix 0.2 x 1.866 slolM
0.68 1.827

0
1.83
0.2x1.86 26.

2
15. (B)
S P 29
Solubility (mol dm) Pressure (atm)
192 10.0
.

T
Unit of Ky = mol dm atm

E
16. (C)
17.(B)

Ca
Ba(NO3)h Ba +2Nog
Total ions after dissociation, n = 3

HT 18. (B)
2.124-087
Mass= 9 g, molecular mass =
Moles of water 9.9
moles
90g

M oles ofsolute

:. Moles of water
Mole fraction
(n,)=0.1
90
(n) = 99
of solvent (x)=
-0 99 jnol nmog seifiods
P=P xx . P=0.99xP
D +n 10
 Solutions (115)
perature 19.(A)
Urea Sucrose
an Mass-3 Mass 17.1
Molar mass 60 Molar mass
342

n
0.05 Moles-
342 0.05
Moles 0.05
60
no. of moles are same then solutions

o
When are isotonic.

20. (D)
21.(C) mass is
s
Mass of glucose 18 g, Molar 180 g

Moles-=0.1, Volume - 100ml =

e
180
0,1 L, Molarity==1L
0.1

s
T = MRT=1 x0,0821 x 300 24.63 atm

t
22. (A) Ky = 0.52 K kg mol'
AT ?, m= 0.25m,
Ks = 0.25 x 0.52 0.13 K.

b
AT m
24. (D)

u
23.(C)

o
25. (A) mol
Sucrose (molar weight)= 342 g
of urea = 60 0.11

D
Moles 00.0
with 6.6 g/L of urea =0.11 x 342 -37.62 g
Mass of sucrose in 1L isotonic

26. (D)
29. (B)
27. (A)

1
28. (C)

2 ot
0
For isotonic solution, Turea7Tsucrose 0
Dureansucrose
3.0
6.0
17.19-0.05mol
343
2
30. (B)
31. (B)

E T KHxP
noilo xeor
09

C
Ku S 10 mol dm
= 5.98
atm x 0.46 atm
x 10 mol dm
S=1.3

HT
32.(A)
n2
38.4
384
= 0.1 mol solute

(acetone)
TT

eog gonoft toreubyf

M
116 mol solvent
O2
58
2 2+0.
2+0.1
= 0.95
Mole fraction; X1 n, +n is given by
pressure of the solution
vapour -0.7999 atm
Dy Kaoult's law, the 0.842 atm
P = X1 x Po =0.95 x
 Questions
MHT-CETExam 43. (C)
For a semim
(116) MRT
n =

n
(B)
HX H +X electrolyte, 44. (A)
dissociation ofan Osmotic pr
i-
o
For (A) TUrea
:0.2
a-
i-1-0.2 is (B) TNaC
(C) Tpucly

s
1.12 K TAIC,
i-0.2+1 1.2 x 0.5- D)
1.2 x 1.86
ikm= Allso
e
Now, AT
ook

s
24.6 atm 45. (B)
x 300K=
34.(D)
(M-
Molarity)
mol By Henr
MRT dmx0.082 dm'
atm K'

t
Where,
-I mol
46. (A)

b
35.(C)

u
36. (B)

0.9-0.6 0.333
0.9
Now, X +X2
1

D o loiew 1slo) anoou

47.(A)
Po-P
Po ?
Accor

1 P-P
= 0.667
-X2 =1- 0.333
=1

2
Po
37. (C)
dm 0.5 kg P
Mass of water 0.5
(

0
(

Moles of urea= 0.5mole (6 48. (C)

2
50
0.5mol Imol/
Due
Molality ofurea = kg O
0.5kg 49.(D)

T
AT Kx m ATb
ore 20 0
Ka

E
K= 0.15K0.15K mol kg
Imol/ kg AT
38.(D)
40.(B)
C 39. (B)

HT Due to more number of ions in solution.

41. (C)
AT T-
T-AT+T
T
50. (D)
p
W

M
T-freezing point of pure solvent
T freezing point of
solution suloe lorm E09 M
AT depression
in freezing point
42. (A) (osoe) a9zloelore
K[Fe(CN)%)
3K'+ (Fe(CN),J
n =4
van'tHofffactor
oot loM
(i)1+a (n-1) =1+0.78 (4 100q8
1)=3.34
 43.(C) mimolar solution, Solutions (117)
Fora Molarity (M) =
0.5
MRT 0.5 mol x 0.082 L atm
K mol x 300 K 12.3 atm
44. (A)
Osmotic pressure, t= iMRT
= x 0.2 RT = 0.2 RT
1

(A) TUrea

n
B) ENaCI 2 x0.I RT= 0.2 RT
C) TgaCl3 xO.05 RT=0.15 RT
D)
.
TAIC

All
4 x 0.05 RT=0.2 RT
solutions are 1Sotonic with each
other except C.
0009240 H000

is o
s
45. (B)
=
By Henry's Law, S Ka xP

46.(A)
Where, S Solubility of gas, P = Pressure of gas, KH=

s e
Henry's law constant
a2
n, +n2

b t
ovloe)5ruprooe

u
47.(A)
10 mm of Hg
Po-P X20.2 22

P
Po-?
According to Raoult's Law

2
10 mm of HE
Po
= 0.2
D o 9119oiq vigilo
02
Po=50
48. (C)
mm of Hg

2 1
Due to more

49.(D)
AT
number of ions in solution.

=
(100.18 +273) -(100 +273) 0.18 K
2 0
T
Ks = 0.512 Kkg mol', m=?
AT

E
AT, K^ xm m

m
C 0.18 K
0.512 K kg mol
= 0.35 mol kg

T
50. (D)

H xP
450mm Hg, P=400 mm Hg,
W 30 g, W2= 1.5 g, M2=?
Mi = 78 g mol (molar
mass of benzene),

M Ma

M-1578
W PP)
(450-400)
450 = 35.1 gmol
HOsd
OTA
M200-a
M C0.0
MED-
30
(118) MHT-CET Exam Questions A and
Mf
51. (D) ix
Thei
AT

,
Kam -Ks MW
M,W
XM, xWM
n
K
52. (D)
W
is o 59. (C)
The
Hoff

s
i-1.076, a-? H' (A)
CHFCOOH CH,FCO0 +

e
(B)
(C)

s
n-2 (2 (D)
1076-11.076-= 0.076

t
2-1 60. (B)

b
53. (B) va

u
54. (A) 61. (A
Benzoic acid Solid

o
Benzene liquid (solvent) th
A)
It is solid in liquid type.
62.

D
lowering of
55. (A)
number of solute particles on the surface. Relative pressure are
Colligative property depends on osmotic
point, depression in freezing point,
vapour pressure, elevation in boiling
colligative properties.

56. (A)
i=3.33
2 1 63.(

0
Ka[Fe(CN)s).
[Fe(CN)6]
Ka[Fe(CN)6] 3K+

2
0 0
1-o 3a a oi te Tde 9T05 or oud
Total no. of Particles =1-a+3a+a

1+3a
3a=
E T
3.33
2.33
= 1+3a

C
2.33 n x TA
64

T a%- x100 77.7%

H 57. (D)
Solubility of a gas in liquid decreases with increase in temperature and increases
with incre

M
in pressure.

58. (D) M.W

A - 0.1 MM CgH1206 i= 1) M
B 0.05 M NaCl i- 2)
C 0.05 M
D 0.1 MM
BaCl2
AICl
i 3)
i-4)
o 008-02
 B are isotonic as they give
A and
M factor
same number
of particles per Solutlons (119)
ix per unit volume
which is given by
The i x M actor for A -Ix0.1-0.1

n
B -2x 0.05-0.1
C -3x0.05-0.15

o
D -4x0.1-0.4

(CE
59.(C)
The salts which dissociate to give same number
off factor for Ka[Fe(CN)%]- 5 of ions and concentrations
have same Van
is
s
(A) MgSO42 ions
(B)Na;SO4= 3= ions

e
(C) Al:(SO4)3 5 ions
(D) Al(NO:)s 4 ions
60.(B)
van't Hoff factor (i)
TheoriticalColligative Property
Observed Colligative Property

t s
Observed molar mass

b
Theoritical molar mass
61. (A)
cetic acid molecules in benzene undergoes association,

u
so its observed molar mass is greater
than actual molar mass.

o
lowering of 62.(D)
An aqueous solution of non-electrolyte does not produce
pressure are any ions.
van't Hoff factor (i) =

D
1
So, its

63.(A)
kg mol
K= 0.52K
xm
ATr-Kr
Molality= 0.186
1.86
AT

2
0.186°C
1
0 o
m 0.1
002 rüiw oiroto ai tojtuloe eu Meco0
AT Kyx mo = ulg

AT
=0.52 x 0.1 0.052
T-T,
2
= 0.052
T, -100 0.052

T
Boiling point of solution T, = 100.052°C 0

E
64.(B)
AT Kxm
Kg=41
C
ith increas

HT K = molal elevation constant

Al = Increase in boiling
nmolality of solution.
65.(D)
point
o 90m
sue to 9eegoog
vloestuloe lo oiber lot
Jvioe 1020otlo dua

M
TA()sucrose constant.
(CRT)A =(CRT)Sucrose R&Tare
1.73 1000 3.42 1000 ,
ra enoc
to edmoro
M
MA
100
x 100 173
342 100
ouvalo ens Bie potufo
1.73
 Questions
MHT-CET Exam
(120) 11
66. (C) 12
nA
V 100 ml, d 1.58
Po-143,
Mass 100 x 1.58 158

143-P 0.5 154

143 65 158
x 143- 1.07
o n
is
143-P =0.007
141.42 mm Hg
-143-1.07
P

s
67. (A)
m, r'-kPa, V=?
n XkPa, V 10.5

-RT
s e
i X
10.5
x8.314x300;
By dividing equation () by (i)
i x8.314x 300

b t
u
x8.314x 300
10.5
X/10

10
V'
10.5
1/V'x8.314x300
V = 105 m
D o AE

1
68.(D)
mass of urea (g)
Molarity of Urea

2
molar mass of urea x volume of solution (L)
1.5 0.025 M
60 x1

2 0
Now, 0.025 M urea solution is isotonic with 500 mL glucose solution.
Molarity of glucose = 0.025 M
Molar mass of glucose = 180 g

T
M> 1000 cm glucose 180 g
1

180x0.025x500 ouloz to oq geili

E
O.025 M- 500 cm glucose= 2.25 g
1000

C
69. (C)
Relative lowering in vapour pressure,

PP
T
AP
po 2 -
n,+D

H
Where, P vapour pressure of pure solvent, P =
vapour pressure of solution,
X2 mole fraction of solute,
n2= number of moles of solute,
n number of moles of solvent.

M 70.(C)
MgSO4, KCI, NaCl gives 2 ions (particles)
(particles) on
Al,(SO),
dissociation
2AP
on dissociation whereas

+3So
Al,(SO,), gves io
More number of ions in solution
will have maximum elevation
in boiling point.
 71.(A)
Solutlons (121)
72. (C)
Molecular mass of Sucrose
CiHa:O-342gmolT
Molarity ot Sucrose Solution Wx1000
MxVm 6.84x1000
Molarity of 'A
342x100 -0.2 M
molarity

n
of sucrosesolution
Molarity of 'A" solution Wx1000 0.2 M

0.2
Mx 100
3.42x 1000
Mx100
is o
s
M 34.2
171 g mol

e
0.2

s
73. (B)
KCl K* +CI

t
SinceKCl undergoes dissociation to give ions,
it means produces more particles
Colligative property depends upon number of solute particles. in solution.

b
Depression of freezing point will
be high for KC1.

74.(D)
K,[Fe(CN),l
i-
K+[Fe(CN),PF n

5.555- 255 =0.7766

-4

o u
D
a
n-1 4-1 3
%
dissociation = 0.7766 x 100 = 77.66 % 08
75. (D)

2 1
Solution of non-electrolyte is isotonic with solution of cane
Molarity of cane sugar solution = Molarity of non-clectrolyte
sugar
solution
5

342x0.1L
= 0.4162

2 0 810.0-
0210.0-
noitlpa lo roe giioee
8

T
Molar mass of non-electrolytee Molarity x 0.1 0.1462x0.1

E
68.399 g mol » 68.4 g mol
0.01462
76. (A)

C
uppose, Po = Vapour pressure of
pure solvent, P=
solvent, it covers the
Vapour pressure of solution
surface are of the pure

T
added to the pure between of which vapour
when nonvolatile solute is vapour phase decreases
going in
DOvent, mumber of molecules compare to pure solvent.

H Pressure of solution is lowered as

Lowering of vapour pressure,
con fo tu o

M
APPo- P efoinq lo
77.B)
60-000X6xK
Ma 1000 K,W. 60 0.15x0.1
AT,W

K = 60x0.15x 0.1
0.15 K kg mol
6000
 Exam Questions
(122)MHT-CET
78. (A) follows the equation,
Osmotic pressure orosloM
=n,RT
T
V T

n
solute)
n2 (moles of M, o gialoM

o
rV-RT
79. (D)
M
Molarity of urea solution
= Molarity of cane
sugar solution
is
Because they are isotonic.
Molar mass of urea =CONH)2
=12+16+(14 x 2) +(2x 2)

e s
s
60 g
cane sugar = Ci2H2011
Molar mass of

t
- (12 x 12) +22 +(16 x 11)
342 g

b
Molarity of urea Molarity of cane sugar egu bgagob yhego1G 9gito
A0Xot 1gd sd

u
3g W
60gx0.5 L 342gx1L
342x5= W
60x0.5
W2
1026
30
34.2 S
D o
1
80. (C)
AT Kg. m (0) 2

2
1.8
AT = W
K M,W,8 = 1.86x-
180x1000x103
olo-2on to roitulo8

1.86 x 0.01

0
0.0186°C
=

AT 0.0186°CC sotogooie
.
81. (B)
2
Freezing point of solution = 0°C- AT- -0.0186°C

E T
Molar mass of glucose = CsH1206 180 g
Moles of glucose
180
10-0.056

C
Molar mass of urea cO(NHa)h = 60 g
=

10
oug s Moles of urea= 0.167 yloe euig si of bobbo e stuioe aitslovnog 13
60

T
Molar
Molar mass of sucrose CpHO1-342
=Ci2H220 542 09tpa to admu gnavioe
ooa boeo coulo to
Moles of Sucrose 10 = 0.029

H
342
No. of moles o no. of particles

M
Decreasing order of osmotic pressure
of solution is
glucose sucrose 000
WTA

000
 3.lonic Equilibria
ImportantFormulae and Shortcut ww
Methods
Types ofelectrolytes

n
electrolytes-strong acids, strong bases and
:Strong
salts
Weak electrolytes-weak acids, weak bases
Degree of dissociation (oc):
oc
number of moles dissociated
total number of moles
iso
Percent dissociation=

Acids and Bases:

oc x 100

e s
s
Arrhenius Theory OH-10H HO,H04

t
Acid It is a substance which contains hydrogen and on dissolving in water produces
hydrogen ions, (H). e.g. HCI
HCla)H)+Cl)

u b
Base It is a substance which contains OH group and on dissolving in water produces
hydroxyl ions (OH). e.g. NaOH
NaOH(aq) = Na" (aq) + OH (aq)

Bronsted Lowry Theory:

HC1+H,O =H,0' +CI
D o p

1
Acid
NH +H,O=NH; +OH sizsa tolos slT

2
Base

0
Lewis Theory: 0 pa) (pe g
ACId can accept a pair of
electrons.
e.g. BF3, AICl

2
Base can donate a pair of electrons.
e.g. NHs, CaHsNH2

T
Ostwald's dilution law:

E K,V
bocot eesd is be bron

C
For weak acids, a enuutotlludho eogyt

HT For weak base,

Where, c centration of an acid or a

V=Volume of an acid or a
base in mol dm
base in dm' mol
dm

O hoisato otiee

M Autoionization of water:
-H,o OH 1, at 25°C K.-
1.0x 10
 Questions
(124) MHT-CET Exam
Relationship between pH and
pOH ol
= 14
pH+pOH
pOH=-logio[OHJ
pH--logio[H'],

Hydrolysis of salts:
Salts:

o n
is
a and a strong base:
1. Salt of strong acid
NaCl+ H,O
NaCl: NaOH+ HCI
S.B S.A. Sat

a strong base CH,COONa +H,O

s
:

2. Salt of a weak acid and NaOH

e
CHCOONa: CH,COOH+
Salt
S.B.
ses

s
W.A.
b cbisA

3. Salt of a strong acid

and a weak base
oalTauinsd
t
NH,OH+HCl=NH,CI+H,O
NHCI: S.A. Salt

b
WB

a weak acid and a weak base: eonfeggED

4. Salt of NH,OHCH,COONH, +HO
CH COONH4: CH,COOH+

Salt Hydrolysis
W.A.
Salt WB.

o u
i Salt of strong acid and strong base
Na (aq)+Cr (aq) + H,O ()=Nat (aq)
+OH (aq)
D
(aq) + CI (aq)
+H

1
In this solution [H"] = [OH], hence the
solution is neutral.

ii. Salt of weak acid and strong base

0 2
CH,CO0aq) + Na* (aq)+H,O()= CH,COOH (ag)+ Na (aq) +OH
(aq9

2
The solution is basic.

ii. Salt of a strong acid and a weak base

T
NH (ag)+ CI (ag) + H,0()=NH,OH (aq) + H (aq) +Cl (aq) s0sdTo
b

E
The solution is acidic.

C
iv. Salt of a weak acid and a weak base
CH,COO(aq) + NHZ (a2) +H,O(0=CH,COOH(aq) + NH,OH(aq)
blavt0 wes

HT The solution may be acidic, basic or neutral depending on the relative strength of
acid and weak base formed in the hydrolysis.

Types of buffer solutions:

M i. Acidic buffer solution: pH

u
= pK, +log10
[salt]
[acid]
Lwhere, pK, = -logo K,]

ii. Basic buffer solution: pOH=pK, + lo810

salt)
[base] where, pK,=- logio Ksl
 lonic Equilibrium (125)
Relationship between solubility and solubility
product:

n
Molar solubility (mol/L)-so lubility in g/L
molar mass in g/ mol

o
Solubility product (K):
B,Ay xB)+yAR)
is
s
K-B"TA

e
If S is the molar solubility of the compound, the equilibrium concentrations of the 1ons in
the saturated solution will be

B-xS mol/L, Ays

K =[xS[ysy" = x*y>sa+y)
mol/L

t s
Common
b
ion effect : The common ion effect states that the ionization of a weak

u
electrolyte is suppressed in presence of a strong electrolyte containing an ion common to the

o
weak electrolyte
e.g, CH COOH and CHCOONa have common ion CH,COO

D
Multiple Choice Questions

1
This topic has been included in the CET syllabus for the first time for CET 2021. Find sample
questions below:

(A) KC
1
dd(B) CIK,
0 2
1. According to Ostwald's dilution law, the degree of dissociation of weak acid given by

C) K,7V D)K,C

(A)pH/pOH 14(B)
2
2. The relation between pH and pOH is
14-pH pOH (C)pH x pOH= 14 (D)14/p0H- pH

(A)[Ca j2F

E T
3. The solubility product of CaF2 is
(B)[Ca"](2FT
4. According to Lowry-Bronsted concept, base is a
(C[Ca"IFT
substance which acts as
(D)[Ca"IF]

C
(A) a proton donor
(C) a proton acceptor
(B) an electron donor
(D) an electron acceptor

T Pbla is related to its solubility

product by the equation
at
Cngtá S. The solubility of (C)Kp= 27s (D)K 4S
(A)K S (B)Kp = 4S E
Hne
6. The solution
(A)KNO (B) NaCN
be
of a salt is basic. The salt must (C)CH,CH0ONH (D) NH,NO

M
potassium acetate will be
pH of the mixture of acetic acid and (C) less than 7 (D)more than 7
(A)0 (B)7
= 4.7. The pH of the
in NHOH. For NH4OH, pks
A solution is 2 M each in NH,CI and
solution will be (D)9
(C) 5.8
(A)4.7 (B)9.3
 M

(B)
MHT-CET Exam Questions hydroxyl 1ons, its pH. will 6. NaCN
(126) concentrations of hydrogen ion and
sa
solution contains equal
o It is a b

n
9. When (D) 0 When
around 10
(C)7
(B)

o
(A) 14 would be
25°C, its solubility 7. (C) mi

is
1.6 x 10 mol dm at
dm The
10. If Kp of Agl is (B) 4x10 mol
(A)4x10moldm (D) 0.8x10
g dm 8. (B)
(C)0.8x10 gdm Accor

11. The pH of
a solution is correctly defined
as

o adt boon (B)

pH 1 afont odt 211

e s
s
(A)pH-log.[H] logiolH Joa be oth Here,
p =

t
(D) pH log1o[H*]
(pH=log10H1 9. (C)

b
relationship of its solubility
product (L,) with IfE
soluble salt ApBq the

u
12. For a sparingly ol zoree) 10. (A)
solubility (S) is (B)Ls SP*4.p.qp nionsolo Ag

o
(A)Ls = SP.pP.q (D)Ls = SP. (pq)P*4
=
r(C)Ls S. pP.q the pa
the acid and the salt. If Ka1x 10,

D
contains equal concentrations of
13. A buffer solution
of the buffer is (C)6 (D)7
(B)4

1
(A)2
11. (C
14. BF is a
ol esd (B) Lewis baseahalsi
19sd eed iqo ld

2
(A) Lewis acid at Electrolyte
p
(C)Amphoteric compound D)

15. Na2CO is a salt of

(A) strong acid and strong base
(C)weak acid and strong base
2 0 (B) strong acid and weak base
D)weak acid and weak base
gibtoouk 12. (
13.(

T
SOLUTIONS

1. (A)

CE
For weak acid,

aKc
e3o tbose oilidoloe ott
od- grrod orgaibsooo/ 14.

HT
2. (B)

3. (C)
pHpOH =14 14-p-Ptyioe ot bonibn
ot tocs p 15.

M 4.
CaF
Solubility
Ca

productCa
(C)uhotem(
+2F d t2a ise 9d

5. (B)
Pbla Pb+2
Here, x 1, y =2.
y-(n? sl2=4S3
 (B)
GVbermentioimodo lonleEquilibrlum (127)
will NaCN
Na +CN
be NaCof
is a
strong base (NaOH) and weak
acid (HCN). vog
It is strong, solution is basic.
Vhenbase

7.
(C)
The
mixture is an acidic buffer, hence the pH would
be less than 7.

o n
(B)
According to Henderson Hasselbalch equation,

o- pK +lo810 salt]
is
s
[base]
[salt][base] p-pK,-4.7 t oeof

e
tp
Here,
- 14-p= 14-4.7 9.3

ith 9.
10.(A)
-[OH), then solution will be neutral and its pH will he around 7.a

t s
b
AglAg+T
S-

u
thepH sothl
= v16x10-l6
V1.6x10
S=

o
mol dm3
S= 4x10
1. (C)

D
1
pH-log1olH pH log0;
ienob
H o: 2otogort arienstnt

1
12.(4) anio9ubod bns gaiism

2
13. (C)
K =1x 10 pK6
Now, according to Henderson
Hasselbalch equanion,s sgogovied
pH

Here,
pk,
[salt
+log10se
ase]
[salt)-lacid)n
pH= pK, = 6
-TH
2 0 e tetaoa 1A 0011 ag 191 2ee

14.

15.(C)
(A)
BF

E T
is electron pair aceptor hence it 1s Lewis acido
raee

breqol caiiw aotmeyot

ittdaihi
anoltanut

C
hon
Na,CO 2Na +cO strong base
(NaOfH).gbovuollo iheg od
(H2CO3) and
1s a salt of weak acid

HT o abowotor ug
selapa0gab ote
enoiaua
oiotgon

M
 W
Thermodynamics W
4. Chemical Wo
Methods
Important Formulae and Shortcut Wo

Thermodynamic Terms: Heat

forms of energy and the quantitati
tative
deals with the study of different

n
Mode
Branch of science which
relationships between them. differe

o
universe which is under
investigation He
System: Specified part of the

is
system.
universe which can interact with the He
Surrounding: Remaining part of the
matter and energy.
Open system: Can exchange both
energy but not matter. First
Closed system: Can exchange
Isolated system : Neither matter nor
energy can be exchanged.

e s F
F

Matter
Bnergy Energyzg
Insulator

t s Inter

b
Whe
Energy Motter zz
u
Open ayatem Closed ayatem Laolated ayatem Entt
()

o
(a) (b)

Properties of System

D
upon the quantity or size of matter present in
the
i. Intensive Properties: Do not depend heat,
tension, viscosity, specific
system. e.g, pressure, temperature, density, surface

1
melting and boiling points, etc.
matter present in the system.
Properties: Depend upon the quantity or size of

2
ii. Extensive
e.g., mass, volume, internal energy, entropy, enthalpy, etc.
Extensive properties are additive but intensive properties are not.

Thermodynamic Processes

2 0
Isothermal Process : At constant temperature, AT = 0 and AU =0
i. Isobaric Process: At constant pressure, AP = 0

E T
ii. Isochoric Process: At constant volume, AV = 0
iv. Adiabatic Process : Completely insulated, AQ =0
State Functions
g aop Th
.

C
Properties which depend only on the initial and final states of a system i.e., do not
the path followed. e.8, pressure, volume, temperature, entropy, enthalpy,
depend on
internal energ

HT etc.
Path Functions ODDD
Properties which depend upon the path followed, e.g, work, heat.
ii

iv.

M
Work presssure
the system and the surroundings as a result of
Mode of energy exchanged between
difference between them.
 .W--Pext(V2- V) Chemical Thermodynamics (129)

2.303 nRT logor 2.303 nRT log

Work done by the system is -ve.
Work done on the system is +ve.
titative

n
at
e
Mode 0f energy exchanged between the

o
system and the surroundings
difference between them. as a result of temperature
.Heat given out by the system is -ve.
Heat absorbed by the system is +ve.
is
First Law of Thermodynamics: AU= Q+ W
For isothermal process, AU = 0 W -Q

e s
For adiabatic change, AU = W as Q= 0
For isochoric change, AU = Q, as AV = 0

t s
b
internal Energy Change (AU):
U-U

u
Where, U and U are internal energies of initial and final
states, respectively.

o
Enthalpy change (AH):0el-
Heat absorbed or evolved by the system at constant pressure.

inthe
AH Qp, AH -AU+PAV or AU+An,RT

D
1
Work done in chemical reaction
heat, W=-An RT

stem.
2
Enthalpy Change during Phase Transformation : Enthalpy change accompanying the

0
conversion of 1 mole of a substance from one state to another.

Solid
A He

2 Liquid Gas

T Hrter
Asub

E
Thermochemistry:

C
Reaction Enthalpy: Enthalpy change accompanying a
AH= 2Hproducts2Hreactants
reaction.

d on
ergy

HT
i. Standard Enthalpy of Reaction (A,H°): Enthalpy change of
participating substances are in their standard
states.
a reaction when all the

Enthalpy change accompanying

Enthalpy of Formation (A,H°): in their standard states.
the formation of

M
dard
one1
mole from its constituents
of a substance
bond enthalples
thalpPy change for a reaction from
Ssure A,H bonds)
2 AH reactant bonds)-2AH product
 Exam Questions MHT
(130) MHT-CET Summation
v. Hess's Law
of Constant Heat a reaction is equal to sum of enthalpy changes ofindividu
in. W
Overall the enthalpy change for 9 (A
steps in the reaction.
AH 10. H
(A

AH AH2 AH
o n
11. F
AH AH + AH2 + AH;

is
Entropy (S):
Measure of randomness or disorder of the system.

e s 12. F

s
AS = 2rey Solld Liquld
Entropy increses
T
13.
Multiple Choice Questions

b t
u
MH
MHT-CET 2004
1. If the heat of formation of CO2 is -393 kJ. The amount of heat evolved in the formation of 14.
0.176 kg of CO2 is
(A)-1357.9 kJ
2. Enthalpy (H) is equal to
(B)-1275.9 kJ

D o
C)-1572.0 kJ D)-1165.5 k

(B) product of pressure (P) and volume (V) of gas

M
15.

1
(A) internal energy (U)
(C)internal energy (U)+ PV D)work (W) done by a system

3. For the reaction, PCl,(g)

(A)AH AU

0
(B)AH>ottonm
AU
2
PC1, (8)+Cl, (8)

olste
(C)AH< AU (D)None of these 16.

2
MHT-CET 2005 energy of
4. Bond energy of hydrogen gas is433 kJ. How much is the bond dissociation
17
0.5 mole of hydrogen gas?
(A)-433 k

E T (B)+433 k (C)-216kJ (D)+216 k

5. Heat of formation of SO2 is-298 kJ. What is the heat of combustion of 4 g of S?
(B)-37.15 kJ (C)+298 kJ (D) 18.6 kJ
18

C
(A)+37 kJ
1 dm
6. 2 moles of helium gas expanded isothermally and irreversibly at 27°C from volume M
Im at constant pressure of 100 kPa. Calculate the work done.

HT(A)99900 k

MHT-CET 2006
(B)99900 J

7. The standard molar heat of formation

C) 34464.65 kJ D) 34464.65 J

of ethane, CO and water () are -21.1,94.1 and

-683
19

M
kcal respectively. The standard molar heat of combustion of ethane will be 2
(A)-372 kcal (B) 162 kcal (C)-240 kcal gl D) 183.5 kcal
the
8. In a closed container, a liquid is stirred with a paddle to increase the temperature. WhiCh
of
following is true?
(A)AU W#0,Q=0 (B) AU = W= Q #0
yolertind
da 2
A
(C)AU = 0, W = Q#0 (D)W 0, AU Q#0
ndividua MHT-CET 2007 Chemical Thermodynamics
(131)2

9.
Whichof the owing is a path function?
(A) Internal energy (B) Enthalpy
(C)Work
Hess's law is based on (D)Entropy A

n
10.
r
(A) Law of conservation of mass
(C)First law of thermodynamics (B)Law of conservation

o
(D)None of these of energy

is
.Eor an ideal gas, the heat of reaction at constant
pressure and constant volume
(A)H +U=PV are related as
(B)U H+PAV
(C),Q+AnRT

s
(D)None of these
12. For the reaction, 2Ha(8)+O:(8)2H,0(g).
The heat of decompoSition of water per mole AH--573.2

e
kJ
is
(A)286.6 kJ

s
(B) 573.2 kJ (C)-28.66 kJ (D)zero
13. The bond energy 1s the energy required to

t
(A) dissociate one mole of the substance (B) dissociate bond in 1 kg of the substance
(C) break one mole of similar bonds (D)break bonds in one mole of substance

1ation of
MHT-CET 2008
14. If AU is the heat of reaction for C2H,OH() +302(g)

u b
2C0:(g) +3H20) at constant volume,
the AH (heat of reaction at constant pressure), at constant temperature is

o
(A)AH= AU + RT (B)AH= AU- RT (C)AH= AU -2 RT (D)AH = AU+2RT
MHT-CET 2009

D
of gas 15. Heat of combustion of methane is 800 kJ. What is the heat of combustion for 4 x 10kg of
methane?
x 10* kJ (D)-1600k

1
(A)-800kJ (B)-3.2 (C)-20kJ
16. 16 g of oxygen gas expands isothermally and reversibly at 300 K from 10 dm to 100 dm. The

2
work done is (in J)
(A)zero (B)-2875J (C)+2875 J D)infinite

0
ergy of is maximum for which
17. At the same conditions of pressure, volume and temperature, work done

18. In .
(A)NH3 (B)N
2
gas if all gases have equal masses?
(C)Ch
process, work is done at the expense of internal
energy
(D)H;S

T
C) adiabatic (D) isobaric
(A)isothermal (B) isochoric
dm' to

E
MHT-CET 2010
decomposed by 130 kJ of heat?
How much H;O is
19The heat of formation of water is 260 kJ.

C
(C)0.5 mol (D)2 mol
(A)0.25 mol (B)1 mol
TIBT0-TRM
nd-683 MHT-CET 2011

T
released upon the formation of
is-393.5 kJ/mol. The heat
ne
20.1 heat of combustion of carbon
oxygen gas 1s (D)+31.5 kJ
.2g of CO2 from carbon and kJ

H
(C)-315 k
the (A)+315 kJ (B)-31.5
chof 21. law, the heat of reaction depends upon
final condition of reactants
ccording to Hess's (B) initial and

M
reactants
A) initial condition of reactants D) end conditions of
intermediate path of the reaction

ww
www.T
 wwww

it
A www
D
wNN1 etmsen
N i

law of
The first
35. (A)Q--w
Exam Questions

n
(132)MHT-CET
Identify the IN
MHT-CET 2014 36.(A)AH 22H
22. Find the correct

(C)H-H
equation.
(A)U-U-H2+H n,RT-nRT
niRT
-U2 +U1 n2RT-
(B)U2-Ui- H2- H
(D)H- H -U2+Ui
combustion of hydrogen at 273 K is
n>RT + n^RT
n2RT + nRT

-286 kJ and enthalpy of fusion of ice

is C) o
(B)AH=
AU+
AH(reaction)

(D)AH AU

s
of 100 g of
23. Assuming enthalpy
be +6.0 kJ, calculate enthalpy change during formation of
at the same
temperature to

e
ice. (C)+292 kJ (D)-292 kJ MHT-CET 2018
(B)-1622 kJ

s
(A)+ 1622kJ Which among
a volume of Sm to 1dm at
when two moles of an ideal gas is compressed from 37.
condition?
24. The work done

t
100 kPa is
300 K, under a pressure of D)42495 kJ
(A)499.9 kJ (B)-499.9 kJ C)-99.5 k (A) AU=

MHT-CET 2015
25. For which among the following reactions, change in entropy is less
(B) Dissociation of Hydrogen
u b
than zero?
C) AU= W
38. Two moles
against a pre

o
(A) Sublimation of Iodine (D)Thermal decomposition of Calcium
Carbonate (A)-201.6k
(C)Formation of water
combustion of 0.090 kg of ethane 39. Calculate th

D
the work done during
26. Given R 8.314 JK mol,
=
Given: R
(Molarmass 30) at 300 K is (C)6.234 kJ (D)-6.234 kJ (A)-7482J
(B) 18.7 kJ

1
(A)-18.7k
following is a feature of adiabatic
expansion? MHT-CET 20
27. Which among the (D)AT 0

2
(B)AU<0 (C)AU>0 40. For a proce
(A)AV<0 from a volume of
two moles of ideal gas is compressed

0
when
28. What is the amount of work done
a pressure of 100 kPa?
(A) T
I m to 10 dm' at 300 K against (D)-114.9 k
(C)114.9 kJ

2
(A)99 kJ (B)-99 kJJ 41. Calculate
pressure a
MHT-CET 2016
thermodynamics for isochoric process is

T
(A)27 cal
first law of
29. Mathematical equation of (C)Q=-W D) AU=W
(B)-AU=Q 42. Three mo
(A)AU-Q
(A) AG> 0

CE
*30. The criterion for a

31. Identify an extensive

spontaneous process is
(B)

(B)
AG < 0 (C)AG =0

property amongst the following.

Heat capacity (C) Density
D) ASwtal
<0

(D) Surface tension

300 K ag
(A)-4.18
43.Identifyt
(A)N2

T
(A) Viscosity combustion
work done when 0.5 mole of methane, CH4g), is subjected to (C) 2H0
32. What is the amount of
J K mol)

H
at 300 K ? (Given, R -8.314 (D)+2494J 44.If Co+
(A)-2494J (B)-4988J )C)+4988 J

formatio

M
MHT-CET 2017 (A)Y-X
kg of ethane, CaHs (g) at 300 K is
33. The work done during combustion of 9 x 10 45. "The ma
mass: C=12, H= 1)
(Given: R =8.314 J Kmol, Atomic (A) Mod
(C)18.71 kJ (D)-18.71 k
(A)6.236 kJ (B)-6.236 kJ to (C) Firs
an gas from a volume of Im
i
34. Calculate the work done during compression of mol
2 of ideal 46. Based
10 dm at 300 K against a pressure of 100 kPa.
o
(D)-22.98 k (A)For
(A)-99 kJ (B)+99 kJ C) +22.98 k (C)For
 . The first law of thermodynamics
for isothermal Chemlcal Thermodynamies
(A)Q- (B)AU-w process is (133)
36. Identify the INVALID
(C)AU-Q
equation. (D)AU0.
(A)AH2prodocts2t
00g (B)AH AU+ PAV

n
(C) AHemction)2Pmotect
bomdk)2(
n
o
(D)AH AU + AnRT
MHT-CET 2018
7.Which among the following is
s
equations represents
condition? the first law ofthermodymamics

e
under isobaric
(A) AU-Q-Pen. AV

s
(C) AU-W (B)Q,-AU
(D)W--Q

t
38.Two moles of an ideal gas
are allowed to expand
Onate against a pressure of 101.325 kPa. Calculate from a volume of 10 dm'
to 2m at 300

b
(A)-201.6 k the work done. K
(B)13.22kJ (C)-810.6 J D)-18.96

u
39.Calculate the work done during combustion of
Given: R-8.314 J K 0.138 kg of ethanol, CH,OH
mol, molar mass of ethanol 46 g at 300 K

o
(A)-7482 J (B) 7482 J mol.
(C)-2494 J (D)2494

D
MHT-CET 2019
me o 40. For a process, entropy change of a system is expressed
as
(A)

41. Caiculate the

(B)Orev x T

2 1 C)H-TS

difference between heat of combustion of carbon monoxide gas at

0
constant
pressure and at constant volume at 27°C ? (R -2 cal K mol'
(A)27 cal (B)-300cal C)54 cal

2
(D)-600cal
2.Three moles of an ideal gas are expanded isothermally from a volume of 300cm' to 2.5 L a
300 K against a pressure of 1.9 atm. The work done in joules is
(A)-4.18J

E T (B)+423.56J (C) +4.8J (D)-423.563

43. Identify the equation in which change in enthalpy is equal to change in internal energy
(A)Na+3Hag2NHs ud(B)Co)+OgCO

C
ISU C) 2H-020+2H;0g+ Oo (D)PCls PCb+Clh
COAH =-Y, calculate al for

T
-X, CO+;0 CcO
4. If C+ Ozp COp AH

formation

H
(C)-Y-X (D)X-Y
(A)Y-X (B)X+Y
an isolated system", is the statement of
mass and energy both are conserved in thermodynamics

M
he of thermodynamics (B) Second law ofthermodynamics
Modified first law (D) Third law of
(C)First law of thermodynamics
is correct?
46. Bas on first law of thermodynamics which of the following
an process, AU-w
(A)For an isochoric process, AU-Q (B)For adiabatic process, Q+W
C) For an isobaric process, Q,-AU+ W
(D)Foran isothermal
 ALA
(134)MHT-CET Exam Questions Which ofth
absorbs 120 J of heat from the surroundin. 60.
47. A gas performs 0.320 kJ work on surrounding and
Ang

Hence change in internal energy is

(A) Ha
(B) 120.32 J (C) 200 J D)-200J 2CO%

n
(A)440 J (C)
kcal. Calculate heat of formatio
Harg)+ Clap >2HCl + 44
48. Consider the following reaction When 2 m

o
61.
against co

is
for 36.5 g of HCl. (D)11 kcal
kcal (B)-88 kcal (C)-22 kcal (A)-1924
(A)-44 condition with liberation
ot
elements under standard
from its
*49. One mole methanol is formed Which of
value of ASmu.?

s
62.
238.9 kJ of heat energy. What theis
(C)472.8 J (D)238.9 J (A) Surfa

e
(A)711.7 J (B) 801.7J
AH and AS respectively are a re
all temperatures, values of 63. For

s
be non-spontaneous at (D) positive, negative
50. For a reaction to
positive, positive (C) negative, positive spontane
(A)negative, negative (B)

t
C(diamond) +Oztg)CO2(g, AH=-395.4 (A)666.
C(gaphite) + O2g) CO2g), AH = -393.5 kJ.
51.If ?

b
What is enthalpy of transformation of
C(gphit)(dianmond) 64. Which
(C) 1.9 kJ D) 589.5 k pressure
(B) 788.9 kJ

u
(A)-1.9 k
is enthalpy of (A) CaC
kJ of heat is required. What
gaseous sodium is ionized, 49.4

o
52. When 2.3 g of
ionization of sodium? mol (D) 404 kJ mol 65. Averag
(B)494 kJ mol C) 48.4 kJ bond is
(A)49.0 k mol

D
on its surrounding
absorbs 6 kJ of heat and does 1.5 kJ of work (A)929
system
53. For a particular reaction, system?
What is enthalpy change of D)- 1.5 kJ 66. In an

1
(B) +6.0 kJ (C)+4.5 kJ
(A)+7.5 kJ AcH'(CsH6)»=- 3267 kJ, 300 K
formation of benzene if,

2
enthalpy of
54. Calculate standard (H20)=-285.8kJ mol. (A)-5
AH(CO2)=-393.5 kJ mol and AH" (C)48.6 kJ mol (D) +32.67 kJ mol

0
B) -38.6 kJ mol 67. For th
(A)-679.3 kJ mol
pressu

2
following properties is extensive? Melting point D) Boiling Point
55. Which of the Density (C) (R
(B) to 10L
(A) Volume reversibly at 300 K from 1L
an ideal gas is expanded
isothermally and (A)

T
56. Two moles of sem
is
D)4.8 kJom 68. For
The enthalpy change in kJ
f&

C)Zero kJ

E
(A)11.4 kJ (B)-11.4 kJ ntage0 280
1-0A)

C
an (A)A
MHT-CET 2020 are 6.01 kJ mol
enthalpy of vaporization for water respectively (C)
and
57. Enthalpy of fusion sublimation at 0°C?

T
What is enthalpy of 69. Heat
45.07 kJ mol at 0°C. mol (C)27.50 kJ mol D)39.06 kJ mol
(B) 51.08 kJ form
(A)48.07 kJ mol

H va
(A)
reaction
58. For the following AS° 15 JK. What is the
+3CO2(g) ;AH°=-29.8 kJ and
= 70. Ene
>2Fe

M
Fe,O10)+3CO O=
of ASiotal) at 298 K? C)100.0 JK D)115.0 JK"
(A)29.8 J K (B) 298.0 J K (A)
sublimation? 71. Wh
equations is correct for heat of
59. Which of the following
(B)AvapHAubH +AruHwatsi) (A)
(A)AubH- AnuH+AvapH
(C) AaH- AnabH x AvapH
ed
D)AubH AtuH-AvapH re (C)
yunding Wh of the following equationshas ChemicalThermodynamics
60. AH and AH° same? (135)
(A)Hau0za) H,O0
OB) Nac +Ox N,ON
Tmation
) 2Co%+O2) 2C02()
D)CHA+20Cl
moles of
61.When 2moles o an ideal gas are
expanded isothermally
ternal pressure of 760
st constant exter
CH,Clh+2o
froma volume of 12.5

o n
is
ttion mm Hg. Calculate the L to 15.0 L
of (A)-1924.0J (B)-25.325J amount of work done in joule?
C)-253.25J
Which of the following1s NOT an intensive (D)-190.0J

s
(A) Surface tension (B) Density property?
y are (C)Heat capacity

e
reaction AH -30 (D)Refractive index
Eor a kJ and As=-45 J
K", at what temperature reaction
5.4

s
spontaneous to non-spontaneous? changes from
k. (A)666.6 K (B) 375.0 K

t
C)675.0 K (D)777.0 K
Which of the following compounds is Not present in its standard

b
4.
state at 25°C and 1
atmosphere
py of pressure?

u
(A) CaCOs) (B) CHOHo (C)HO (D)COp

o
65. Average bond enthalpy of water is 464.5 kJ mol. If the energy
required to break first O-H
nding bond is 502 kJ mol", then how much energy per
mol is required to break second O-H bond?

D
(A)929 kJ (B) 678 kJ (C) 427
66. In
ko3-(0(D)251 k
isothermal and reversible process, 1.6 x 10 kg Oz expands from 10 dm' to 100 dm' at
an
300 K,

(A)-5744 J (B)-1436 JH
2 1
work done in the process is (R =8.314 JK mol)
(C)-2872 J (D)-4308J

0
67. For the combustion of mole of liquid benzene at 298 K, the heat of reaction at constant
1

pressure is-3268 kJ mol'. What is heat of combustion at constant volume?

10 L (R8.314 x 10 kJK mol

(4)-6728 mol
k
2
kJ mol
(B)-672.8 (C)-3264.2 kJ mol (D)-1632 kJ mol
%, For

230g+Ozg) T
following reaction, relation between AH and AU 1s

E 250,
(B)AH-AU+RT
er
C
and (A)AH = AU-2RT
C)AH AU - RT
D)AH-AU +2RT
respectively. Hence heat of

T
69. Heat are -K and-Xg
of
Ccombustion
o of Co, Hag and CaHeo -Xi,

(D)-2x1 - 3x2+X
formation
of CaH) is

H
value (C)x tX2-X3
4)-+2x1+3x2 (B)-X-Xt3 is x kJ. The value of
bond enthalpy of
70.Energy Oztp) into free atoms
to dissociate 16 g

M
quired
1
0-0bond i
D
(A)4x (C) 16x kJ
kJ (B)2x kJ
1. ch is true for heat and nperature? extensive properties
respectively
e Intensive and respectively
(A)Both B) intensive properties
areiintensiveproperties Extensive and
C)Both
are extensive oroperties diue (D)
 Equilibriur
Questions 2S0+O2(g) is 83. (A)-7.191
MHT-CET Exam reaction, 250
(136) for the entropy
AH and AU -RT
72. Relation
between
(B)AH +AU== RT 84. If absolu
(A)

n
(A)AH+AU = RT (D)AH-AU
sulphur to Standard
(C)AH-AU= 2RT combines with

o
carbon 85.
when 6 g
heat evolved from its C

is
the quantity of (A)2.861
73. What is reaction
according to the kJ mol (D)22 kJ
C+SCS, AH--92 (C)32 kJ 86. From
the

s
kJ (B)46
(A)11 kJ is spontancous? N2(g)+3
indicates the reaction

e
the following conditions (A)-92.
*74. Which of temperature

s
AH <0, AG<0 at all
(A)AS>0,
87. If 2 kJo
temperature
(B)AS <0, AH>0,
AG>0 at low

t
at high
temperature change
(C)AS <0, AH>0, AG>0 (A)-2k
at all temperature

b
(D)AS<0, AH>0, AG>0 300 K?
AS(coa) for following reaction at 88. For the
What is the value of AH°=-25kJ, AS° =15JK")

u
75. +3C02)
Fe,O3+3CO2Fe D)-10.0 JK- (A)AU
(C) 68.2 JK-

o
(B)98.3 JK
(A) 8.32 JK a volume of 4 89. Whatis
work done during isothermal expansion of a gas from
76. Calculate the amount of

D
external pressure of 3 atmosphere? N
dm to 6 dm against a constant (C)-30.4 J (D)-6.0J
(A)-607.8 J (B)-60.8J odaidAHH-
water from

1
for the formation of ethanol from ethene gas and liquid (A)23
77. What is the value of AH

2
following data? 90. When
AH =-1368kJJ
) CHOH +302()2C02(p)+3H,O0 What i

0 -
AH° =1410kJ
(i) CHAg+302g)2CO2() +2H,0 (A)

2
(A) +2778.0 kJ (B)-1326.0 kJ (C)+42.0kJ (D)-4188.0kJ
extems
91. When
78. An ideal gas expands from x 1
10 m to 1 x 10 m' at 300 K against a constant follow

T
pressure of 1 x 10° N m,
work done is
(A)W
(A)-0.7 x 10 J (B)-9x 10 J C)-9 x 10J (D)-1 x 10

E
the (C)A
calculaic
79. When a system absorbs 8 kJ of heat and does 2.2 kJ of work on surrounding,
92. What

C
internal energy change
(A) 5.8 k (B) 10.8 kJ (C)-10.2 kJ (D) 8.0 kJ from
(A)

T
80. If 38.55 kJ of heat is absorbed when 6.0 g of O, react with CIF according to reaction
iRsra 93. The
2CIF+Oz)CL+OF

H
What is the standard enthalpy of reaction? Calc
(A) 205.6 kJ (B) 102.8 kJ (C) 72.28 kJ D) 49.80 kJ (At.1
(A)1

M
Wha
Sample,
81. A sample of gas absorbs 4000 kJ of heat and surrounding does 2000 J of work on samp *94. Whe
is the value of AU?
(A) 4002 kJ (B) 4000 k (A)A
2000(C) 6000 k
kJbes(D)
82. An ideal gas expands isothermally and reversibly from 10 m to (B)
20 m at 300 K, P
5.187 kJ of work on surrounding. Calculate number of moles
of gas used.
C)4
(A) 3 (B) 2 (C)1.5
eR (D)
(D) 1
 Equilib anstant for a reaction is 20. What the Chemical Thermodynamies
0t k mol (B)
A)-7.191 kJ moll (B)-2.763 kJ mol" is value of AG at 300
K? (R-8x 10 kJ)
(137)
(C)-5.527kJ mol
of a solid is greater than zero, (D) 16.63 kJ mol
84 Ife at T 0, it

n
A)ahsohute entropy (B) formal entro is called
form (C)residual entropy (D)standard
CS Standard enthalpy of fomation

o
of water is-286 kJ mol entropy
8

is
fromits constituen
ent elements in their standard
states
When 1800 mg
of water is formed
(A)2.86 kJ (B) 57.2 kJ the amount of energy liberated
(C)5.72 kJ is
the given reaction, (D)28.6 kJ

s
s6. From

3Hael 2NH() AH=-92.6 kJ,

e
the enthalpy offormation NH,
(A)-92.6 kJ (B)-46.3 kJ of is

s
(C)-185.2 k (D)-138.9 k
1f2 kJ of heat
released from system and kJ
is
6 of work

t
change of system? is done on the system, what enthalpy
is
(A)-2k (B) +8 kJ (C)-8

b
k (D)+6 k
For the reaction, N2(g)+ 3H2g) 2NH(), AH is equal to

me of 4
(A)AU-RT
89. What

N3H 2NH
is
B)AU+2RT (C)AU+RT

o
standard N =sN bond enthalpy from following reaction?
u (D)AU -2RT

D
AH°-83kJ
er from AH-435 k, AHH) 389 kJ

1
(A)2334 k (B) 435 kJ (C)946 kJ (D) 1305 k
90. When 6.0 g of graphite reacts with dihydrogen to give methane gas, 37.4 kJ of heat

2
is liberated.
What is standard enthalpy of formation of CH42
(A)-74.8 kJ mol
91. When 1

following is correct?

2 0
(B)-112.2 kJ mol (C)-37.4 kJ mol (D)112.2 k mol
mole of gas is heated at constant volume and heat supplied is 500 J then which of the

(B)Q-500 J, W- 0

T
(A)W 500 J, AU =0
C)AU -0.5 -500 J (D)Q=-500 J, AU 0
ate the J, Q =
RAC

E
92.1
the work done when 2 mole of an ideal gas is expanded isothermally and reversibly
what 1s

C
rom 5 m to 10 =
m' at 300 K? (R 8.314 JK mol")
(A)-34.58 k C) 3.458 k D)-1.725 k
(B)-3.458 kJ
and water is -1172 kl mol

T
31The acetaldehyde to carbon dioxide
of combustion of acetaldehyde were completely oxidized.
amount of heat liberated when 66 g of
ate
H
AL Mass C = 12, H 1, 0 = 16) (D) 1758 k
(A)1172 kJ (C) 2344 k
What (B) 6600 kJ
94.Whe temperatures?

M
spontaneous at all
the reaction becomes
be
A)AH+ve, AS=+ve, A
orming B)AH
+ve, AS-ve, AG- +ve
C) AH -ve, AS--ve, AG--ve
D)AH-ve, AS=+ve, AG--ve
 w
108. He
(138) MHT-CET Exam Questions -395
20 m at 300 K performine
ideal gas expands isothermally and reversibly from 10 m° to expansion.
ming
(A)
95. An gas undergoing
Calculate number of moles of
5.187 kJ of work on surrounding. WH
109.
(R 8.314JK mol (C)1.5 (D)1 (A)
(B) 3

n
(A)2
175.8 JK mol respectively (B)
*96. If AH and AS° for the reaction
N,O4()2NO2() is 57.24 kJ and (C)

o (D)
at 298 K?
What is the value of AG° for this reaction

is
(C) 4.85 kJ
(D)-4.85 kJ
(A) 57.24 kJ (B) -17.58 kJ
110. F
property? o (A)
97. Which of the following is an extensive (D) Volume

s
Specific heat
(A) Density (B) Surface tension (C)
111. F

e
+302() 2C02)+3H;O0% eth
98. For the reaction, CH,OH

Rh(A)
Which among the following is true?
AH AU+2 RT (B)

99. Work done when 2 moles of

AH = AU + RT

an ideal gas
(C) AH- AU-2 RT (D) AH= AU-
is compressed
RT

t s
from a volume of 5 m to dm at
1

(A
300K, under a pressure of 100 kPa

b 00(A
is ao 22
(B)-99.5kJ (C) 424.95 kJ D) 499.9 kJd

u
(A)-409.9 kJ

100. In which of the following reactions,

AH is not equal to AU?a 112. V

o
(B) Na+Oac) >2NO(
(A) SO+ NO >SOi +NO (A
(D) 2S02) +Ocg) 2S0)
2H
H+
D
C)
combustion (B
101. If heat of combustion of methane is -800
kJ mol, calculate enthalpy change for
(C
of 4 x 10 kg of methane.
(A)-800 k (B)-3.2
102. Thermodynamics deals with
x 10 kJ

2 1
(C)-280 kJ (D)-20 kJ

ooieml 1o gglirtno basbote ef isrt 113.

0
(A) microscopic properties of system
(B) macroscopic properties of the system

2
(C) rates at which physical and chemical processes
system OCcuo gto alomt psi
(D) the path between the two states of the 114.
indicte spontaneity of rection at all temperatures?

T
*103. Which of the following set of parameters
(B) AH +ve, AS = -ve, AG = +ve
(A) AH = +ve, AS = +v e, AG =-ve

E
(D) AH =-ve, AS =-ve, AG =+ve
(C) AH=-ve, AS = +ve, AG = -ve
are 191.5, 130.5 and 192.6 J Kmol
*104.The standard entropies ofN2()H2p and NH(

C c
cota
respectively. The values of AS° for formation of NH, is

T
(A)-98.9JK"mol (B) Zero 115.1
molirnos taod sd
K' mol fo D)- 29.4 JK- DH a
latso

H
105. For an isothermal process
(A) Q< W (B) Q=- W (C)Q= W 000(6) (D) Q> w

M
H2 and
106. Heat of formation of water is -272 kJ mol. What quantity of water is converted to
by 750 kJ of heat?
(A) 7.5 mol (B) 2.75 mol (C) 5.5 mol (D) 0.275 mol l16.
of AG, AS and AH
*107. At what temperature, a chemical reaction will have following values
AG -5.2 KJ mol, AH = 145.6 kJ mol, AS=-216 kJ mol
HAC
(B) 650.0 KK
(C) 823.0 K (D) 425.0K
(A) 698.1 K
 K performing Chemical Thermodynamics
pansion of formation of ethane, ethylene
at
(139)
kJ) acetylene and
395 (all in respectively most stable carbon dioxide are
among them -136, 66, -228 and
(A) Carbon dioxide (B) Acetylene is

n
(C)Ethylene
respectively 109. Which of following is residual entropy
(D)Ethane
of a substance?

o
A)entropy of solid equal to 0 at T-0

is
B)entropy of solid equal to 0 at T-273 K
entropy of solid greater than 0 at
T-273 K
D)entropy of solid greater than 0 at T 0 K
110 For a reaction,
(A)+ 10 kJ
AH=-50 kJ, AS-150JK"
(B)-110 kJ
at 400 K. What is
(C)-10 kJ

e s
the value of AG ?

s
(D)-50.15 k
1 From the following reaction, calculate the
amount of heat liberated
RT ethane during formation of 75 g

to I dm C,H+H)
(At mass C= 12, H 1)
CHs)iAH--124 k mol

b t
112.
(A) 248 kJ (B) 310 kJ

Which of the following reactions is NOT exothermic?

(C) 372 kJ

o u (D) 284 k

Ha0to
D
(A)
2
H,Oo +286 kJ
combustion (B) 2KCIO,s)
2KCI +302(+78 kJ
(C) Na+202)

D) CHp +202)
2NO2(- 66.4 kJub botoed
CO0+2H,0 +890 k
2 1
0
113. For combustion of I mole of liquid benzene at 298 K, the heat of reaction at constant volume is
-3264.2 kJ. What is the heat of combustion at constant pressure? (R = 8.314 JKmolr')

114.
2
(A)-3267.9 k mol (B)-816.9 kJ mol
Standard entropies of N2(g), Ha) and
(C)-2439.2 kJ mol (D)-1633.9 kJ molr
NH3) are a, a, and as JK mol respectively. What

T
is
itures? value of AS° for formation of NHs(?

-1 E
(A)a,-a+ (B)a
H
C
Kmo
(D)a,-

T
to react at 2 atmosphere pressure
200 mL of ethylene gas and 200 mL of HCI gas are allowed
as per given reaction,

H C,Ha+HCl CHCl o
M
pressure volume work in Joule.
HandO
ate
40.52 J (D) 26.20 J
(A) 20.26 J
(B) 54.40 J dC) decomposition of water is
116.How decomposed by 429 kJ of heat it heat of
gram of water is
AH ? 286Lany
kJ moll? 22.5 g t
(A) 27
g (B) 40 g
vroo (C) 36g
308 0(D)
)
 Whe
Questions
129.
(140) MNT-CET Exam (A)AH

n
following
reaction from
117. ldentify endothemic (B)AH
2KC+30,+78kJ

o
(A) 2KCIO

is
2NO66.4kJ C)AH
(B) Na+20
CO+2H,O,+890k (D)AF
)CH+20
D) H+ H,0,+286k)
chemical reaction will have
following values?

e s 130. Heat
of SO

s
118.At what temperature, a J (A)
AG-4k, AH--60 k), AS-160 (C) 350 K
(D)400 K

t
K(B) 250
(A) 300 K 131. Ider
119. Standard molar entropy is (A)J

b
a pure substance at atm
I and 25 °C
(A) the absolute entropy of one mole of pure substance at 1 atm and 298 °C
nmole

(B) the absolute entropy of one

a
of

u
one mole of a pure substance at 700 mm
pressure and 25 °C 132.The
(C)the absolute entropy of
substance at atm and 298 °C
1
(A)
(D)the absolute entropy of one gram of a pure

o
reversibly from 10 m' to 20 m at 300
K
ideal gas expand isothermally and
120. Three mole of an 133. He

D
calculate the work done. (R- 8.314 JK mol) heat
(B)-2593.5 kJ (C)-51.87 k (D)-5.187 k
(A)-1037.4kJ (A)
on surrounding, calculate

1
10 kJ work
121.A system releases 15 kJ of energy as heat and does
nternal energy change. 134.Wh

2
(A) 5 k (B)-5 k (C-25 kJ (D) 25 k
(A)
of water if heat of formation

0
122.Calculate the amount of heat liberated during formation of 2.7 kg (B)
ofwater is-284.5 kJ mol. (C)

2
(A) 4.267x 10° kJ (B)4.267 x 10 k (C) 1.896 x 10 kJ (D) 2.896 x 10kJ
(D
123. For which of the following reaction, AH AU?

T
(B) HOu H,O 135. A
(A)2 CO+Ox 2 COp
(C)Ha+Bra 2 HBr (D) PCls ist
PCl+ Clh

E
124. Which of the following equations shows the relationship between heat of reaction at constant
(A

C
pressure and heat of reaction at constant volume if the temperature is not constant? 136. V
(A)AH-An- AURT (B)AH AU RT -

(A
C)AH AnRT (D)AH AU AnRT

T
(B
125.If Co+ OoCOo AH--396 kJ mol", calculate heat liberated during formation of (C
0.154 kg of CO (D

H(A)1386.0 kJ (B)346.5 k
126. The H-H bond energy is 430 kJ mol
(C)693.0 kJ
and CHCI bond energy is 240 kJ mol
(D) 1039.5 k 137.

M
AH for HC
-90 kJ, then H-Cl bond energy is
(A)213 kJ mol (B) 180 kJ mol (C) 360 kJ mol (D)425 kJ mol 2
127. Heat of combustion of liquid benzene to carbon dioxide and water
is-3266 kJ
the amount of heat liberated when 780 mg of benzene is fully oxidised?
mol. Wha
(At mass of C- 12, H-1)
(A)65.32 kJ (B) 326.6 kJ (C)16.33 kJ (D)32.66 k
128. Which of the following is an intensive property?
138.2
(A) Internal energy (B) Mass (C)Volume (D) Melting point
 11l change
he change in Gibb's free
will be Chemical Thermodynamics
129. When energy always (141)
negative?
A)AH and AS both positiv at low temperature.
negative, AS positive, at all temperatures.
(B)AH
(C)AH positive, AS = negative at all
ratures.

o n
is
(D)AH and AS th negative at high temperature

130.
formation of SO2 is
Heat of format -298 kJ mol". Calculate

s
enthalpy change during formation
of SO2. of 4 g
A)-32.8 k (B) -18.6 kJ

e
(C)-37 kJ
(D)-20.4 kJ

s
Identify the unit used for measurement
1 of energy according to
(A)J K mol (B)kg s2 m international system of units?

t
(C)kgm's2 (D)kg m s
25 °C
112.The equilibrium constant for a reaction is 10, value

b
of AG" at 300 K is (R = 8 x 10 kJ)
(A) 11.054 kJ mol (B) 2.763 kJ mol (C)5.527kJ mol
O m at 300 K, (D)-5.527 kJ mol

ding, calculate
133. Heat of formation
heat?
(A) 45 g (B) 33 g
o
C) 40 g u
of H;0 is -270 kJ mol". How much water can be decomposed

(D) 27 g
by 675 kJ of

D
134.When will be the reaction becomes spontaneous at all temperatures?

1
it of formation
(A) AH=+ve or -ve, AS = 0, AG =0
(B)AH=-ve, AS = +ve, AG =-ve 05hmol hrod-

2 togoibgo to yno brod sio

(C) AH= +ve, AS = -ve, AG = +ve
10 kJ EE
(D) AH=-ve, AS = -ve, AG =-ve or tve olom
so
10 gro cotuooeeih beo

on at constant
135. A
is
(A) 4000 kJ
2
AU? 0
sample of gas absorbs 4000 kJ of heat and surrounding does 2000 J of work on sample, what
the value of
(B) 6000 k (C) 2000 kJ (D) 4002 kJ(
136

E T he
ne
Which of the following statements does not represent first law of thermodynamics?
spontaneous flow of heat is always unidirectional from high to low temperature.
total internal energy of an isolated system is constant. co
formation of

C Total energy of universe is constant.

when one form of energy disappears, exactly equivalent
amount of other form must appear.

T
137. Given
is that,
H for HCI Co+O2g)CO2 AH--Xk

H -2
formation of carbon monoxide is
20
)+O2e) >2C0, AH=-YkJ, then standard enthalpy of
aol
(B) 2X- Yk

Ma
What 1s (A)Y-2X k
ol.
l HA
What is the change in
138.2.5
kJ of and it releases 1500 J of heat.
done on the system
internal energy? is (D)2500 J
point (A)4000 (C)1500 J
J (B)1000 J
 (142) MHT-CET Exam Questions
SOLUTIONS

1. (C) 1
mole of substance is ormed
for
absorbed or evolved when
Heat of formation is amount of heat
from its elements.

n
Given, mass of CO - 0.176 kg = 176 g
Molecular weight of CO; = mole of CO;44 g
I

CO-393
o
kJ
C+O
is
12 g 2 x 16g 44g om
kJ
Heat evolved when 44 g of CO; is produced =-393
393
produced=-x176=-1572 kJ
Heat evolved when 176 g of C0, is 44

e s
s
2. (C)
Enthalpy is total heat content of system.
tPv 0Lt nou
t
H Uinternal energy)
om

b
3. (B)
AH =AU+PAV=AU +An RT

u
PCls(g) PCl(g) +Ch(g)
=
P ),2-1
1
Ang

AH>
4. (D)
AH= AU+1x RT
AU

D o odoisr orh sd lbw nalWEr

1
Bond dissociation energy=- bond formation energy
Given, bond energy of hydrogen =-433 kJ

0 2
. Bond dissociation energy of one mole of H = 433 kJ

Bond dissociation energy of 0.5 mole of H2=

433
+216.5 kJt afque A2E

5. (B) C06(C
Heat of combustion is
2
total
009S 10)
heat changes
0003 (8
accompanying when one mole of substance undergocs

T
complete combustion in excess of oxygen.s
S+O2 SO2, AH= 298 kJ

E
Heat of formation of SO; heat=
of combustion of
tso
a td
to
SO,
asoosltoq sd'f (A)
Atomic
oll
mass of S 32 g

C
Combustion of 32g of S (= mole of S) gives heat =-298 kJ
1

-298
Combustion of 4 g of S gives heat =
32
x4=-37.25 kJ

H
or T
6. (B)
W -PAV
Given, P = 100 kPa= 10° Pa, Vi
W 10x (1- 10) J=99900 J
= 1dm' = 10m', V2= 1m00
00 0+0

M 7. (A)
AHeaction -2
AH CaH=-21.1 kcal,
AH of products 2 AH of reactants
AHCO-94.1 kcal, AH H0=-68.3 kcal

CaHs+02 200+3H,0
 AHpombustion [2 AHCO,+ 3AH Chemical Thermodynamics
(143)
H,0)-|AH,CH,+AHO
- (2x(-941)+3(-68.3)--21.1x
ve is
formed (-188.2-204.9)
+21.1-393.1+21.1

n
-372 kcal
8.(A
AU Q+w
0 C: temperaure
Q+W 0+
W0, Q-0
W
is to De increased, no
AU W=
heat should enter
or leave the system)
is o
9.(C)
Taternal energy, enthalpy
and entropy are state functions

e s
s
but work and heat are path functions
.(B)

t
Hess's law is based upon law of conservation of energy.

b
11.(C)
The
heat of reaction for ideal gas, at constant pressure and volume

u
i15,
AnRT bar
Q-Qt
o

o
12. (A)

Heat of decomposition of water is o,(.

D
H,O(g)H(g) +

AH= T 88.2=286.6kJ/ mol001og a00-

10 noliaonot ort aoau boenoln

13. (C)
The bond

2 1
00103 3ooeot elt nce

energy is the energy required to break one mole of similar bonds.

boere

0
14.B)

2
We know that, AH = AU+AnRTisqal
undergoes number of moles of gaseous reactants
Where, An = number of moles of gaseous products

So,

E T AH
-2-3--1
AU-RT
rU- H-R 10 (T T 0-

C
15.(C)

CH4+20>CO2+2H20; AH,-800kJ 0

T
16g
kJ
10 kg CH-800
Heat of combustion of 16 x 800x 4x10
-=-20kJ

H Heat of combustion of 4 x 10 kg
CH will be 16x103
(90
ounslnc

M
16.(B) 100

W= 2.303 nRT
log2-2.303xx8.314x 300log 0

2872 J-2875 J
 E
(144)MHT-CET Exam Questions
24. (A)
Work d
17. (A)
is also same, work done
depends only upon molecular
When P, V and T are same and mass Here,

n
M molecular mass)
W (Where,
lowest molecular mass, so work done
1s maximum for i
Among the given gases, NH, has

18. (C)
We know that, AU- Q+ W. Ifheat
supplied from the surrounding, Q0
is o 25. (C)

s
For th
AU- W Q 0 for adiabatic process 2
of only internal energy and

e
i.e. Work is done at the expense m

s
Three
19. (C) beco
water is as

t
The reaction for the formation of
AH 260 kJ ) 93o facn
On reversing Equation (), we get

H0- H,+o. AH=-260 kJ .(i)

u b 26. (B)

o
1 mol
= 1 mol
W
By 260 kJ heat water decomposed
=.1x130 0.5 mol No

D
130 kJ heat will decompose water 260
Ca

1
20. (C)
AH -393.5 kJ/mol
C+OcO
2
. Heat released upon the formation of 44 g of CO% =-393.5 kJ
393.5
CO2
Heat released upon the formation oflgof

0
44 27. (B
-395.35.2 -315 n

2
kJ
Heat released upon the formation of 35.2 g of CO2 44
28.(
21. (B)

T
conditions of reacta
According to Hess's law, the heat of reaction depends upon the initial & final
29.

E
22. (C)
We know that, AH = AU + AngRT

C
= n>RT - nRT 30.
H2-H U-Ui + (n2RT- niRT) or Ha- Hi -U,+U1

22
T
23. (B) 31.
Hg)+;0-(8) H;0(0; AH--286 kJ 0SC3e089
H
32.
(I) HO(9)H,O(); AusH=+ 6
18 g
U00 k oiadco to lill

M odeadmoo to 1
On subtracting (1) from () to

Hag)+0,(g) H,O0) AH--286-6--292 kJ

On formation of 18 g ice, change in enthalpy-292 kJ
o
: On formation of 100 g ice, change in enthalpy=-410-1622
18
kJ

S
 (A)
24.rk W=-Pext (V2- Vi) Chemical Thermodynamics
ass done,
100 kPa
(145)
Here, Pext
Vi Sm=5= x 10 L
V2 1
dm' 1
L

n
W
-100 x (l -500)=
=499900 J = 499.9 kJ499900kPa L

o
1
kPaL

is
1 kJ)
25. (C)
For the reaction
2H:(g)+Oz(g)

s
2 HO() AS negative
more ordered state less disorderd sate (

e
Three gas-phase moles are
hecomes less disordered converted into two moles

s
state. The entropy of liquid. The more disorderd state
of the system decreases because
I:8) disorder decreases.
AS positive
Hg)
CaCOs (8)
>2H(8)
CaO+CO2 (g)
AS positive
AS positive
reb t
u
26. (B)
W -AnRT

o
0.090
No. of mole = =3
30x10
CHa)+7;(g)2
- n 2-4.5 -2.5
COg+3H,0() for 1

D
mole

1
=
An= n2 30010
W --2.5 x 8.314 x 10x 300 x 3) = 18.7
kJ0-UA 0
27.(E
In adiabatic expansion, AT *0, AU # 0.

0 2 (A8E
1240101 o122E.10f-9

2
28. (A) (VA)
ants. W - PAV = - 100 (1- 0.01) =- 100 (-0.99) = 99 k 9s2sc101-
)s00E101-)

T
29. (A)
thermodynamics for isochoric process.
AUQv is the mathematical equation of first law of
30. (B)

CE
AG<0 is the criteria for spontaneous
31.(B)
process.

property out of the given

options.

T
t capacity is the only extensive
LCOAC006PIC (0)
32.(D)

H CH4)+202g)CO2zg+2H,O0 orob bow locas 8 g

1 moles of
CO2
Amount of work done = -AnRT oxygen to produce

M
I mole of methane reacts with 2 moles of O% to produce l
mole of CO
1 mole of
Hence with
mole of CH4 reacts
0.
Dmoles of reactants= 1.5
nmoles of product =l
An =n2-nj = 1 -1.5=-0.5SJKmol=+2494 J
0.5) x 300 x 8.314
 Questions
(146)MHT-CET Exam
33. (C) reaction is
Work done in chemical

n
W--An RT
3H;O(
IC,H(8)+0; (8)> 2C0,(8)+
An-2-4.5-2.5
W-+2.5 x 8.314 x 300
6.2355 kJ
is o
s
= 6.2355 kJ
For 30 g=1 mole
18.71 kJ
For90 g=3 moles=
34. (B)
W--PeaxAV, AV= (0.01
m - Im) = - 0.99 m'=-100 kPa
(-0.99) m'=

s e
99 kJJ

35. (A)
First law of
thermodynamics is, AU
isothermal process, AU = 0
=
Q-w
Q+w
wralpetb

b t
xesl8s0995

u
For
product

o
36. (C)
bonds energy necessary to break
AHreaction) energy necessary to break reactant

D
bonds
AHrEaction)2AH(reactant bonde)2AH(product bonds)
00.0 olom 10 of
37. (A)
First law of thermodynamics is
AU Q+P. AV
2 1
When P is constant i.e. isobaric process

38. (A)
Q- Q AU= Qp-Pex. AV

2 0 0x0EE82- W

T
=
P 101.325 k Pa 101325 Pa
Vi 10 dm' = 10x 10m' = 10 m', V2= 2 m
W -P (AV)

CE
= -101325 x (2-0.01)
=(-101325) x (+1.99) J=-201.636 kJ

HT
39. (B)

CgH,OH

An =
+ 302(g)

2-3--1
2002) +3H00 vnaitonanol arotosb0 0E

M .
138
W=-An RT
W=+(1) x 8.314 x300 2494.2 J
For 46 g ethanol work done 2494.2 J
gethanol work donexJ
138x24942 7482.6J
46
40. (A)
 Chemical Thermodynamics (147)2
41.(8)
co+ CO
An,
-1-1.5-0.5

n
AHAU+An,RT
AU = AnRT =-0.5) x 2x 300-300 cal
42.(D)
V300cm', V,=2.5L, T=300 K, P=1.9
gas expands against constant external
atm,n-3
is o
s
As pressure,
W -PAV= -1.9(2.5 -0.3)= -1.9(2.2)
99 kJ
=4.18
e
L atmx 101.3 -423.43 J
6

s
atm
43.
AH AU+ PAV or AH= AU + AnRT 0 01 ei0.16

t
.. AH= AU at An = 0
reaction, Co) + Og)>CO),

b
In the A, =0
to break product 4.(A)
45. (A)

o u
According to modified first law of thermodynamics mass and energy
mass decreases, energy increases in some process.
are interconvertible when

D
46. (C)
AU =Q+ W
For isochoric process, AV =0 Q AUU

1
W
For adiabatic process, Q =0 AU=
For isobaric process AP =0 . Q- AU+ W

2 vontood bos Ra eo
oun
For isothermal process AU=0 Q--W
Ato.000 orods oouog

0
47. (D)
W=-0.320 kJ = -320 J

2
Q 120 J
AU=Q+W 120-320-200 J
O

T
48.(C)
49.(B)

ca).1e
CE AS=
50. (D)
AH= TAS
AH 238.9x10-801.7J
298 K
53. (B) 54. (C) 55. (A)

T
51. (C) 52. (B)
56. (C)
enthalpy change zero.

H
For isothermal reaction of ideal gas
57.(B)
x001 b 01V

M
AruH
6.01 kJ mol
ApubH = 7
kJ mol,
45.07
For sublimation at 0°C,
,0 HO H,O»
AsabH 6.01+45.07 51.08 kJ mol
 (148) MHT-CET Exam Questions For
58. (D) the entropy
system loses heat to surrounding. Hence y of
o the
Since the reaction is exothermic,
surrounding increáses.

n
AHgur+29.8 kJ = 29800 J
29800
100 JK
ASu A 67. (C

o
=
T 298

is
115 JK
ASTotal = AS,ys + ASur = 15 +100 C
59.(A) 60. (A)

s
Q
61. (C)
10 m,

e
n2 mol, Vi = 12.5L= 12.5 x 10 m, V2 = 15.0 L = 15.0 x

s
P 760 mm of Hg 1.013 x 10° Nm
-Pext (V2-Vi)= -1.013 x 10 (15.0 - 12.5)10

t
W
= -2.5325 x 10x 103 HA
el nt

b
J
roiteror
W -253.25

u
62. (C)
matter present in the system)
i.Extensive property - heat capacity (depends on the amount of

o
refractive index (independent of the amount of
sd old i. Intensive property - surface tension, density,
matter present in the system)

D
68.
63. (A)
AH--30 kJ, AS = -45 JK= -0.045 kJ K

Since
AS
AH
AH -30 kJ
-0.045 kJ K
=

1
666.67 K

2
and AS are both negative, the reaction is
0-9 er0o1 9pdsiba t01
GA 0014 sdoero
temperature and non
spontaneous at low

64. (C)
spontaneous above 666.67 K.

2 0
Water at 25° C is present in liquid state.
t0C-
toE-0-04
().
0E.0--W
L0S1
69.

65. (C)

H,O H T
Average bond enthalpy of H0 is 464.5 kJ molr

E +OHo AH 502 kJ mol (a1.e

C
OH
2ATH
H +O AH-?
+AH

T
Average bond enthalpy = AH
2
x 2 502+AH2

H
464.5
AH2= 929 502-427 70.
moluo vglaiteeg lsabiogots l ion 1e
12.

M
66. (C)
Vi 10 dm ,V=100 dm, T 300 K,
R 8.314 JK mol, mo.- 1.6 x 10 kg= 16g o T2
me
n Mo 32
-0.5mol
 For
isothermal and reversible process.
Chemical Thermodynamics
ofthe (149)
Wa -2.303 nRT logto

- 2.303x 0.5 x 8.314

x

o n
is
300 xlog1o
67. (C)
-2872J

CH O >6CO20+3H,O

Q-3268kJ mol, Ang-1.5

e s
s
T 298 K, R=8.314 x 10 kJK molr,

t
Q =?
Now,
-Q+An RT

b
Qp
-

u
Q, QpAn RT
tem)
- -3268-[-1.5) x 8.314 x 10 x 298]

o
unt of --3268 +3.716
Q, -3264.284 kJ mol
68. (C)
AH AU+ AngRT
D
2S02 +O2)
An
2S0
=np-n= 2-3 =-1
AHAU RT
2 1 (E)

0
non -

69.

2
i.
C+0, CO, AH-X
i H,+0,H,O
T
AH2-X2

E
CH,+o,200,+3H,0
ii. AH-X3

C
3 equation (i1)
ultiply equation (i) by 2+multiply equation (i) by
-

2C+3H, CH wrw

HT
70. (B)

72.(D)
AH
AH
2AH +3AH2 -AH
-2x-3x2 +X3
71. (D)

M SOs
An
Now, AH
3-2=1
AU+AnRT
AH-AU =RT
2S020+O)
 Questions
MHT-CET Exam
(150) 300
T
73. (B) W=
CS,
C+S, (Endothermic reaction)
mol
AH--92 kJ evolved = 92 kJ

n
heat
For 12 g C,
heat evolved - 46
kJ
.
o
For 6 g C,

74. (A)

75. (B) oe 203- is n

s
exothermic,
The reaction the = 25000 J
83. (A)
AHu=+25 kJ K=2

e
AHuT 25000 83.33 JK AG°

s
ASsur 300 K
T
ASys t+ASqu

t
AStotal
+83.33 JK
= 15 JK
84. (C)

b
AStotal =98.33 J K
85. (D)
PIEC211-2
u
76. (A) atm
4 dm, V2=6dm',V1) =3 4)
Pex
V
=
H

o
Now, W= -Pex (V2- =-3(6-
L. atm=-6 x 101.3 J
-6

D
W 607.8 J

7. (C)

1
Subtract equation (1) from equation (ii)
AH = 1410 - 1368 = 42 kJ 86. (B)

78.(B)
V= 1x 10
V =1x 10 m' = 0.01 m
m =
0.001 m

0 2 Na

Pex1x 10 Nm2
W =-PeV2-Vi)=-1x 10° (0.01 -0.001)
2 004 87. (A)

T
-0.009 x 10° 0H Q=
W -9x 10J
79. (A)
Q +8 kJ,
AU= Q+W
CE W -2.2 kJ
8-2.2 5.8 kJ
O. 00R 0 No
88. (D)
Na

T
80. (A)
2CIF+O21 Cl,0+OFg) -AEHAS
H ar-H4 89. (C)
For 6.0g of O2 AH +38.55 kJ
AH°= 38.55x32 = 205.6 (a) at N
M
For 32.0g of O2 kJ
6
81. (A)
Q=+4000 kJ, W = +2000 J= +2 kJ
AU Q+ W= 4000+2 4002 kJ

82. (A)
VI= 10 m' = 10 x 10' dm
V2 20 m = 20 x 10 dm
 A
Chemical Thermodynamics (1531)
300 K, W=-5.187 kJ= -5187
T

W--2.303 nRTlog

5187-2.303 x n x 8.314 x 300 x logi

0
20x10
10x10

o n
is
5187
2.303x8.314 x 300 x 0.301
3 moles alo 00

s
n

e
83.(A)
K 20, T= 300 K, R 8x
10 kJ K mol

s
= -2.303 RT logio K
AG
:-2.303 x 8 x 10 x 300 x logio(20))

t
AG-7.191 kJ mol

b
84.(C)

u
85.(D)

H,O AH =-286 kJ mol

For 18 g

: For 1.8 g of H,O, amount of

18g

energy liberated=

D o
of H0, amount of energy liberated = 286 kJ mol
286
18
28.6 kJ+O0 H

86. (B)

Natg)+3H2g 2NH3()

2 1 AH=-92.6 kJ
ar t faote a
0
-92.6 kJ
Enthalpy of formation of NH, = =46.3

87.(A)
Q--2 kJ,
2
W +6 kJ

H.2

E T AU=Q+W=-2 +6=4 kJ
Now, AH =AU- W = 4-6=-2
88. (D)
kJ

C
Na1p)+3H2 2NH)
= gol0 E2ntoE
An 2-4 -2
a
T AH= AU + An RT = AU 2RT
-

89.C)
007

H
AH°=-83kJ Jos
N+3H2 2NH3p (product bonds)
AH (reactant bonds)-AH

M
AH N-H
(N=N) +3AHH-]-[6AH
AH
-83 AH'NN)+3(435)-6(389)
HA -83 AHNNI + 1305-2334
KJ
an NN) =-83 1305 +2334 = 946
 tie

Exam Questions
(152)MHT-CET 97.

n
(A)
CH)
Co+2H kJ

o
graphite, AH-37.4 98.
For 6.0 g of -37.4 x12=-74.8 kJ mol

is
AH
For 12.0g of graphite, 6

s
91. (B)
Q500 J, At constant
volume, AV=0 lor
92. (B)
W--PAV =0

Vi=5 m', V2= 10

m

s e 99.

t
mole,
n-2 0.-
T 300 K, R 8.314 JK mol
WmAx2.303 nRT log10

u b
o
. WmAx =-2.303 x 2 x 8.314 x 300 log1o 10
=-3457.97J
Wmax -3.458 kJ

D
1
93. (D)
CH,CHO+2.50, 2co, +2H,0 AH-1172 kJ mol OHto 20
For 44 g of CH,CHO, AH=-1172 kJ mol

g
66 of CH CHO,
AH==1172x66

0
44 2
--1758 kJ mol 1

2
: The amount of heat liberated when 66 g of acetaldehyde were completely oxidis
1758 kJ mol

94. (D)
95. (B)
VI

E T
m', V2 = 20 m', T = 300 K
= 10
W0
C
Wmax-5.187 kJ = -5187 J, n=?
Wmax-2.303 nRT log1o2

HT -5187 =-2.303 xnx

n
5187
8.314 x 300 log10
10
5187

M
2.303x8.314x 300 xlog102
2.303x8.314x300x0.3010
n 3mol
96. (C)
N,O4g)2NO AH 57.24 kJ
AS 0.1758 kJ K" mol
AG AH TAS
= 57.24-298 (0.1758)
- 4.8516 k
 Chemical Thermodynamics
97. (D) (153)
Propertyof atter that depends on the amount
of matter in the
Volume is an xtensive property. system.

98.(1
C.H OHo +
302(g) 2C02g+

n
3H;O
2-3
= -1
Ang
0
o
AH AU + An, RT aro

is
AH AU- RT

99.( (D)

s
No. of moles = 2
Initial volume Vi = 5
m

e
=
Final volume V2=l dm 102m

s
Pressure= 100 kPa = 10° Pa

=-PAV =-P (V2 - Vi)

t
W

= 10 (10-5)

b
W =499.9 kJ on 2

u
100.(D)
AH AU+ An RT

o
If An, = 0, then AH = AU
250, +Oat 2S0
An,-1
AH AU
D
1
In all other reactions An, = 0AH AU

2
101.(D) 006x8.0
CH,+20 >CO, +2H,O

0
xidised is 16 gm
of methane=-800 kJ/mol.
Given Heat of combustion of 16 x 10 kg

2
Enthalpy change for combustion of 4 x 10 kg of
methane =? A80
-800x 4x10-20 kJ mol.

T
16x10
102.

E
(B) macroscopic systems involving a large
number
Ther
eTmodynamics deals with energy changes of
containing a few molecules.
ofrOlecules rather than microscopic systems
103. (C)

C
T
AG
AH-TAS
For spontaneity,
AG-Vve

H l AH -ve,
AG -ve
AS = +ve then
at all temperatures.

M
104.
(A)

NHg
As (AS)products(AS )reactants
 ww mm

w
axa

Exam Questions 112. (C)

(154) MHT-CET Nz()
As°-192.6-x191.5+x130.5 The ab

n
2
= 192.6-291.5
192.6-(95.75 + 195.75) 113. (A)
AS--98.9 J/mol
105. (B)
For an isothermal
-
process AT 0 AU =0
is o C,H
Qp
A

s
AU Q+W
0 Q+W Q
Q--W
106. (B)
AH-272 kJ
s e 114.(B)

H,0H,O
t
N2c
H,0-272 kJ

b
I mole of
? 750 kJ

u
-2.75 moles. Stan
272

o
O2
2.75 mole of H2O is converted to H2 and ASO

D
107.(A)
4G =AHTAS 115.(C)
T 216 C,
145.6- 1000

1
-5.2
200
145.6 =1O

2
-5.2 1000

0
150.8x1000
T
216

2
T =698.1 K
108.(A)

T
More the energy released (exothermic) during the formation, more stable it is. So CO% 15 m
stable among them. 116.(A

E
Fo
109. (D)
Residual entropy is the difference in entropy between a non-equilibrium state and crystal s

Entropy
C
of substance close to absolute zero.
of solid> 0 at T 0K

T
117.1
110. (A)
AG AH TAS n

H = -50-400) 1D=-50+60
1000 10 kJ 118. (

M 111.(B)
C,H+H C.Hds
For mole of formation of ethane =30 g=-124 kJ
1

For 75 g ethane =?
AH--124kJ mol
A

=-75 x 124-310 kJ 119.

For 75 g of ethane formation, 310 kJ of heat is liberated.
 Chemical Thermodynamics
112. (C) (155
Na +20) Oc-66.4 kJ AH-+66.4kJ
above reaction is endothermic as AH++ve.
13.(A)
6CO) +3H,O

o n
Q, Q+An,RT
An 6-7.5-1.5
is
s
-3264.2+-15x 8.314 x 10 x 298)
3264.2-3.716-3267.9 kJ mol
114(B)
Nag+3H) 2NH)
s e
Standard entropies
Na)tHa NH

b t
AS Asndt-2As
o u
D
115.(C)

CHp+HCl C,H,Cl
200 mL 200 mL 200 mL
AV
= 200-400
-200 mL= -0.2 L

2 1
=Volume of Product (V2)- Volume of reactant (Vi)

0
W -P.AV
-2x (-0.2) 0.4L atmbg aoas
is most
116.A)
0.4x
2
101.32540.53 J
required.o5 0o

T
ror of H,0 = 286 kJ of heat is
18 g

Xg of H20= 429 kJ of heat is required.sed Liolt

stal state

E
X
429x18=27g
286
117.B)

C
dOthermic reaction heat is absorbed, In
the following
reaction 66.4 kJ of heat is
absorbed

T Nau)+2024 2NO0)-66.4 kJ

H
118.(D)
AG AH-TAS
4000
60000-T(-160)

M
64000
160 T
T = 64000 400 K
119.(A) 160 and 25°C.
substance at I atm
mole of a
Theabsolute entropy pure
 Questions
(156)MHT-CET Exam
120. (D)

W-2.303 n RT logIo
20
x 3 x 8.314 x 300 10
-2.303
x 3 x 8.314 x 300 x 0.3010
-2.303
W=-5187.027 J
=-5.187 kJ

o n
121. (C)
According to first law of
thermodynamicS
is
s
AU Q+ W
=-15+(-10)
AU=-25 kJ
energy-25 kJ
Intermal

s e
t
122. (A)
Since, 18 x10 kg of H,0 =-284.5 kJ
-284.5 x 27
2.7 kg of HO
18x 10
42.675 x 10 = 4.2675

u b
x 10* kJ

o
123. (C)
Since, AH= AU+ An RT

D
For the reaction,
H2g+Brag) 2 HBr(g)
2o a
An 2-2 0 1nse o 9mlo oubor'l
124. D)
AH AU

2 1 VA

0
AH AU+AnRT
Where, An = No. of moles of gaseous product -no. of moles of gaseous reactant.

125. (A)
For formation of I mol
2
CO% = 396 kJ heat is liberated3o Lo6 s 0830g
154
mol
4

E T 96x154
44
= 1386 kJ heat is liberated. d
o Ouoa7

C
126. (D)

Ch HC

HT AHHCID:O H-H BE.of CI-CI -[B.E.of

2 H-CI]

-BE
M
-90 -(B.E. ofH-C 081-10008-
00
-90 215 + 120-[B.E. of H -CI]
-90 335 [B.E. of
. B.E. ofH- Cl 335H-
Cl]
+ 90 425 kJ mol
ostomso
 Chemical Thermodynamics
127.(D) (157
6CO)+3H,O
CH AH-3266kJ
Molar
mass of CGH6 78 g mol ! RmeJnohao
780 x 10
Moles of
benzene = 0.01
mol
78
mole of benzene liberates 3266 kJ of heat
1

0.01 of benzene liberat 3266 x 0.01=32.66

kJ of heat

o n
118.
Melting noint does not depend on the amount substance,
of it is an intensive property.
is
s
129.(B)
AHTAS

e
AG
-ve-ve +ve .at all temperatures.
bo
s
130(B)
t

t
I
mole of SO; =-298 kJ mol
4

b
of
64
SO-298 x 64
-18.625 kJ
oobto awrge

u
131.(B)

o
132.(D)
AG -2.303 RT logioK=-2.303 x 0.008x 300 logio10 = -5.527 kJ mol

D
133. (A)
I
mol of H,0 = 18 g 270 kJ mol
615x18
= 075x18 laomo (oialo)
-45 tavlao
=675 kJ

1
X
270

2
134. (B)
AG AH TAS

0
-ve) -ve) +ve)
135. (D)

2
4002 kJ
Q+W= (4000 kJ) + (2000x 10 kJ) =
AU=
13etoota01301s lo ztga sitbh
136. (A)
137. (C)

E T
Multiply equation (1) by (2)
2C+2019 2C02p10 AH=-2X kJhog
to tolo. ()ogtoeal

2C0
C
Reverse equation (2)

2C0+O
3o
AH Y kJ si(i)
& (ii)]

T
Eq. ()
2C+O2tp) 2C0 AH Y-2X kJltiAdd
mation of l mole of CO io

H
Forthe
formation-
ard enthalpy of
o
M
138.
.(B)
=
W2.5 kJ 2500 J, Q = -150oJ
aU=Q+W=-1500 +2500 1000
 5.
Electrochemistry
Shortcut Methods
ImportantFormulae and
or S
Electrical conductance (G)0

. Cell constantcm
a
(or m)
Cell constant

o n
is
.Conductivity (K)=- Resistance

Molar conductivity (Am)(K in Qmand Cin mol m)OR

Am- (K in Q' em and C in mol dm)
ATRAOL

e s
s
C
.Kohlrausch's Law :Ao a +

Degree of dissociation (a) = n

Ao

b t
u
Electrochemical cell: (8).1E

o
Type Energy change Anode Cathode
Electrical energy chemical

D
Electrolytic cell
energy
Galvanic (voltaic) Chemical energy Electrical
cell
1
energy
Cell representation:
Anode
X()x(aa)
Cathode
0 2 HA
(v-) (v
04

2
|I (aa)IY)
LOxidation J Reduction

T
Quantitative aspects of electrochemistry:
a.The mass of reactant consumed or the

E
mass of product formed at an electrode
electrolysis can be calculated by knowing
stoichiometry of the half reaction at the elecu

C
Mass of product moles
I(A)x t(s)
of product x molar mass of product

T
W
x
96500(C/ mole") mole ratio x molar mass of product po ee

H b. Suppose two cells

containing different electrolytes
quantity of electricity is are connected in series
sane
erateda a
M
passed through them
the electrodes ofthe then the masses of the substances
two cells are related as
W dayol 3o valaio busbae
mole ratio) x M W2
(mole ratio)2 xM2
(M and Ma are the molar masses 0et-o
of substances produced
10026 ec
es of
at the electrodes
cells 1 and
2)
 Electrochemistry (159)
EMF of cell

standard reduction electrode

(In terms of potential)

.Nernstequation

n
X()+Y(aq) - xn- (aq) + Y(8)

Foell Fell
n
og

is o
.Thermodynamics of Galvanic cells:
AG--nFEoell
e s
ii) AG-RT tn K

ii) Eel
O.0591og oK
at 25°C
CK= Equilibrium constant)

t s
b
n

.Standard hydrogen electrode (SHE):

EE(It
H (IM) |Ha(g, atm) |Pt
1
EH, -0.00OV

is primary reference electrode)

o u
nson ionouber bol
Electrochemical Series
i. Metals having higher positive Eed Values,
D
undergo reduction more readily and are good
oxidizing agents.

ii.
2 1
Metals having higher negative Eed Values, undergo
-H
oxidation more readily and are good

reducing agents.

2 0 Multiple Choice Questions

uring
Ode
MHT-CET 2004
1. Standard

E T
electrode potential of cell H2 |H"| Ag|Ag
is (EAt IAg = 0.80V)

C
D)1.2V
(A)0.8 V
a(0) (B)-0.8 V oC)-1.2Va

T
MHT-CET 2005
V, 0.34 V and -2.37 V respectively.
D are 0.8 V, 0.79
4 Reduction potentials of A, B, C and
three elements?

H
Which element displaces all the other (D)C
edst (A) B (B)A
(C)D od

M
S Na is used in reduction of Zn salt because <ENa(red)
(B) EZn(red)
(A) EZa(oxi) > ENa(Oxi)
(D) Both (A) and (B)
(C) Eza(oni) < Eša(oni)
 (160) MHT-CET Exam Questions

MHT-CET 2006
4. The reduction electrode potential, E of 0.1 M solution of M ions (ERp=-2.36 V. MHT

n
VV
V) is
(A)-4.82 V (B)-2.41 12. At

o
(C)+2.41 V (D) None of these 9.
5. The ionic conductance of Ba
and Cr are respectively 127 and 76 ohm Cm
dilution. The equivalent conductance (in ohm cm) of BaClh at infinite dilution will
At

is de
(A

s
(A) 139.5 (B) 203 be MHT
C) 279

e
(D) 101.5 13. H

s
MHT-CET 2007 cC
6. The standard Ered values of A, B (A
and C are +0.68 V, -2.54 V,

t
-0.50 V respectively. Then
heorte
of their reducing power is MHT
(A)A> B>C

b
(B)A>C>B (C)C>B>A (D)B>C>A
7. EMF of hydrogen electrode 14. W

u T-on
in tem of pH is (at 1 atm pressure) (A
(A)Es,xpH RT
RT 1 s 15. T

(C) E

MHT-CET 2009
2.305 RT pH
F (D) EH,
(d)
D
=
o -0.591 pH
sbo3els msgezbyd bysbust?
su
(A

1
16. W
8. The standard reduction (A
potential for Mg*"/Mg

2
Ecel for is -2.37 V
the following reaction is and for Cu/ Cu is 0.337. The MHT
Mg+Cu>Mg*+Cu

0
Boog (A)+2.03 17. H
VE (B)-2.03 V
C)-2.7 Vgt298
luoirmorioo12o1

2
ch
MHT-CET 2010 iD)+ 2.7.VM (A
9. Given, for Sn
/Sn, standard reduction potential

T
reductionpotential 18. In
is 1.5 V. Forthe is 0.15 (A
reaction, 3Sn°+2Au" V and for
the value of Ecell is; Au/
E
-> 3Sn4* +2Au. 3000 Au,
standau
*19. In
(A)+1.35 (B)+2.55

C
C)-1.35 (A
MHT-CET 2011 (D)-2.55 (C
MHT

T
10. According to Faraday's
first law
x
(A) w=6500 E (B) W=xtxE
ETs6 20. Id

H
Ixt 96500 (C) E=Xtx96500 (A
11. A button cell used in w
watches functions as
following:
W (D) E=Ix 21.
W

M
Zn(s)+ Ag:0(6) + H:O0)=2Ag(6)
+ Zn
tx 965000
(A
(aq) + 20H (ag)
If half-cell potentials are, 22. W
Zn (ag)+2e" Zn(s); acc
Ag:O(8)+HO)+2e2Ag()+2OH E-0.76V (A
(aq); MHT
The cell potential will be E-0.34
(A)1.10 V
v 23.
(B)0.42 Vv
(C)0.84 V Th
(D)1.34 ele
V (A
 MHT-CET 2013
Electrochemistry
(161)
25°C mol
25° lar conductance
12.At ohm cm mol and of 0.l molar
9.54 at infinite dilution aqueous solution
aisation ammor of ammonium hydroxide
degree of 1onisation of ammonium hydroxide its molar conductance
at
Tbe infinite
(A)2.080 % (B) 20.80 % at the same is 238 ohm cm
(C)4.008% concentration
m mol.
The
and temperature
MHT-CET 2014 (D)40.80% 1s

n
electrical conductand
13. How is electrical conductance of a conductor
conductor? related with length

o
and area of cross-section
(A)G 1.a.k of the

is
(B)G-k.l.a ornu(C)G -k.a.l
.Theorder
MHT-CET 2015 (D)G kl.a

s
Which of the follov
lowing complexes has
4 COCl.3NH lowest molar conductance?

e
(A) B) CoCl.4NH (C)CoClh.5NH
(D)CoCl.6NH

s
The overall reaction taking place at anode during
suitable electrode is electrolysis of fused
sodium chloride using

t
(A)Oxidation of chloride
(B) Reduction of sodium
(C) Reduction of chlorine ions biete d

b
(D)Oxidation of sodium
atoms
16 Which among the following solutions is NOT
used in determination of the cell

u
(A) 10 M KCI (B) 10 M KCI constant?
(C)1 M KCI (D) Saturated KCI

o
337. The MHT-CET 2016
sbrollo tutbos aluoo
17. How many faradays of electricity are required

D
to deposit 10 g of calcium from molten
chloride using inert electrodes? (Molar mass calcium
of calcium = 40 g mol) bns ay
(A)0.5 F (B)1F (C)0.25
Folto
1
(0)2F siuols)56
18In the cell represented by Pb)| Pb (IM) l| Ag (IM)l the reducing agent is
go),

2
standard
(A) Pb
O(B)Pb* (C)Ag020.8)D)Ag aeso.cCA

0
19. In dry cell, what acts as negative electrode?
(A)Zine (B)Graphite
lop

2
(C)Ammonium chloride (D) Manganese dioxidetb
stinni de bios
MHT-CET 2017 lorm 2 o2.08c(A)
20. Identify
(A)Li

E T
the weakest oxidising agent among the following.

21. What is the SI

(B) Na (C)Cd2
iwollot ori gnoms tior
De(D)1
oboiliso is bo
A
E

C
unit of conductivity
(A)Sm (B)Sm (C)Sm20.0 piv D)S m2om dft t

T
Which among the following equations represents the reduction reaction taking place in lead
aCcumulator at as
positive electrode, while it is being used a source of electrical energy?
(A)Pb D)Pb Pb
Pb Pb

H
(B)Pb Pb (C)Pb
MHT-CET
2018
3.Thenumb

M
1s passed through an solution of
Ciectrolyte
moles of electrons passed when current of 2 A
(A)4.1
for 20 minutes 1s
mol e" (D) 2.487 x 10 mole
24.Whatmol
x e (B) 1.24 x 10 mol e" (C) 2.487 x 10
accumulator?
is the density acid used as an electrolyte in lead
(A)] sdensity of solution of sulphuric
(A)1.5 (D)2.0 g mL"
g mL (B) 1.2 g mL (C)1.8 g mL
 Questions
(162)MHT-CET Exam
MHT-CET 2019
37. Fo
CusO4 solution and if
connected in series containing An
25. Two electrolytic
cells are
deposited on cathode of first cell, the numben A
'Cu' are
If in electrolysis 0.4 moles ofthe second cell is
on cathode of (D)0.18 moles
Al' deposited (B)0.4 moles (C)0.27 moles
38.If

n
(A)0.6 moles to
an electrolytic solution decreases on dilution due (A
conductivity of

o
26. The
unit volume
(A)increase in number of ions per

is
39. Si
(B) increase in percentage ionization V
(C) increase in ionic mobility of ions
volume
(D) decrease in number of ions per unit

27. The resistance ofM

10
solution is 2.5 x 10 ohm. What is the molar conductivity
s
of soluti

e
on
40. F

(Cell constant 1.25 cm)

(A)2.5 ohm cm mol
(C)2.0 ohm cm mol
(B)5.0 ohm cm mol
(D) 3.5 ohm cm mol

t s
19/0 9dT 2
41.

b
oT0919 9louniu
28. Standard Hydrogen Electrode (SHE) is a 42.
(B) Metal-Sparingly soluble salt electrode

u
(A)Metal-Metal ion electrodebor)
(C) Primary reference electrode (D) Secondary reference electrode

o
29. Which of the following acts as oxidizing agent in hydrogen-
oxygen fuel cell? MH
(A)O (B)C (C) KOH D)H 43.

anode and cathode respectively areobe

D
30. In the electrolysis of aqueous sodium chloride with inert electrodes the products obtainei
olo to

1
(A) Na and Clh (B) Ch and H C)O, and Nal(D) Ch and Na 44.

2
Cu
31. Calculate EMF. of following cell at 298 K, Zn,ZnSO%(0.01M)| Cuso%(1.0 M)
E2.0V.

0
(A)2.0296 V B) 1.0508 V 45.
(C) 2.0592V (D)2.0 V

2
32. The molar conductivities at infinite dilution for sodium acetate,
HCl and NaCl are 91 S
mol, 425.9 S cm mol and 126.4 S cm mol respectively.
acid at infinite dilution is
The molar conductivity of a

T
(A)530.9 S cm mol" (B) 390.5 S cm mol
(C)930.5 S cm mol (D) 300.5 S cm mol

E
33. Which among the following is
correct for electrolysis of brine solution? 46.
(A)Ch gas is liberated at cathode
(B) H2 gas is liberated at cathode

C cm
(C)O2 gas is liberated at cathode
(D) Sodium metal is collected at anode
34. T he molar conductivity of 0.05M HCI
solution is 163.3 Q em? moll is
conductivity of the solution at at 298K. WDat

T
bed the same temperature?
(A)0.08165 Ncm
(C)0.008165 pee(B) 0.81652 cm gapn 47.I
sd
H
(D)8.165 Q cm og
35. The standard emf
of Cu Cu
e101 e
|Agm)Ag cell is 0.463V. If the standard electrode potential 48.
Cu' electrode is 0.337 V, what

M (A)-0.126V is the standard electrode potential

g(B)-0.860 V of 'Ag' electrode
56. In Ha-02 fuel
(C)0.626 V
cell, reaction taking (D)0.800 V
place at negative electrode
(A) 2H20+ 40H
C)2H+20H
4H,O +4e
(B) 40H
is o
0tp) + 2H,O +4e
49.F
2H,O+2 b
D) O0+ 2H,040H)
 B*
17.For tho - 0.403V, ca (1M)
thecorrectprediction
fE'cd H about AG (IM)1Halg) (1
Electrochemistry
(16
Ch (A)AGve, E"cell--ve 0e0 and
and E" atm) Pt,
+ve, E'cell = (B) AG -ve,cell is
esof )4G (D) AG=+ve,E'cel +ve
'of Zn "(aq)+2e
+ 2e Zn(S)
is-0.763 V then
E" of 2
E'cell +ve
3V (B)+ 1.026V Zns)2Zn()+2e will be
(C)-0.703V
oduction potentials elements
Standard redu (D)-1.506V
of

n
9, respectively. Which element A, B, C and
displaces D are
V
other three elements0.799 V, 0.690v, 0.34V and-2.37

o
(B) A
4) C C)B from their salt?

40. How
many
chloride? (At.
coulomb of electricity
mass Mg = 24)
is required to produce
5 g
(D) D

is
of magnesium from magnesium

s
(A) 41.66 C (B)4166.0C C)4020.2 C

e
(D) 40202.0Dc
EMF of
what is a cell having AllAP" (E"=1.66V) and Ag'lAg (E°-0.80VY

42.
(A) 2.46 V (B)-0.86v
How many Faraday of electricity 1S required
(A) 4 Faraday (B)8 Faraday
(C) 0.86 V
(D)-2.46V
for the reduction of 3 moles Zn22
of
t s
b
(C)6 Faraday D) Faraday
2

u
MHT-CET 2020

o
43. What is the common unit of conductivity if the dimensions are expressed in centimeter?
(A).2 cm (B)N cm (C) cm
at
D
D) cm
4. What is the molar conductivity of 0.1 M NaCl if it's conductivity is 1.06 x 10 Q cm'?
cm mol

1
cm mol
(A)1.06 x 10
2 sds B) 5.3 x 10'2
d les
C) 1.06 x 10 Q cm mol D)9.4 x 10 Q cm mol

m
45.
Which
A)Oxidation occurs at negative electrode 2
of the following statements is true for electrolytic cell?

0
2
5) Reduction occurs at positive electrode
lotteoloqbscltoesogaweot
etic
C)Oxidation occurs at positive electrode
A
T
D)Anode is negative and cathode is positive electrode a
constant of NaCl

E
solution if resistance and cell
Wnat 18 the conductivity of 0.01 M NaCl
cm respectively at 298 K?

C cm
301ution are 375 ohms and 0.5
em (B)7.50 x 10 o
the
(A)1.333 x
10a x 10 Qem

T 91875x 10 O(D D) 1.333

41.During 2cm aqueous sodium chloride the
product obtained at anode is

H
e electrolysis of (C)Cla
(D) Na
(A)02
(B) Hg)
1 of l|Cu"M)Cu?

M is Standard potential of cell, Ni | Ni

What

IfECu V. (D)0.573 V
(A)-0.753
.337 V and E°Ni--0.236 (C)0.101 V
one mole of A"
V (B)-0.136 V to Al?
reduction of
.How much for the D)1.930 x 10'c
charge in coulombs is required (C)2.895 x 10'C
(A)1.930x
10'C (B)2.895 x 10'C
 Questions 484 Q and conduc
(164)MHT-CET Exam gives a resistance of TH
with 0.01 M KCl 62.
filled 1.
50. Conductivity cell is constant?
cm 25°C. What is cell cm (D)0.341 cm
0.00141 Q at
(C)0.510 (A

n
(B)0.751 cm
(A)0.682 cm W
conductivity and resistance of
e of 63.

o
solution at 25°C, if asolutiga
ofKCI

is
51. What is the cell constant
10
em and 55.0 Q respectively? 64. H
is 0.0112 Q
cm (C)0,491 cm (D)2.0 cm

s
cm (B)0.2
(A)0.616 conductivity of ca
conductivity at infinite dilution of CaCh, if the molar

e
52. What is the molar
andC ion infinite dilution is 119 and
71
2 cm mol'? 65. N

s
at
(B)261.0 Qcm mol
(A)126.0 Qem' mol
(D)431.0 cm molr

t
(C)341.0 Q em mol
53. How many electrons flow when a current of 5 amp is passed through a cell for 200 sec? 66.

b
(A)9.65 x 10 (B) 1.60 x 10 (C)6.24 x 10 (D)3.12 x 10

u
54. If the conductivity of 0.08 M KCI solution is 2x 10 N, what is the molar conductivity of te

o
solution?
cm mol 67.
(A)350 Q cm mol (B) 25.0 2
D)0.25 Q cm mol 01a0-TH
D
C)250 cm mol

55. What is the relation between cell constant, conductivity and electrical resistance?

(A)k (B) k= R.b

2 1 (C)k-
avbubao
(D)k = Rb
56. What is the standard free energy change for the cell, having following cell reaction?
68.

0
2Ag)Cd 2Ag Caa), Fel =1.20V 0U.FO) 69.
(A)-260.8 k e

2
(B)-115.8 kJ (C)-231.6 kJ (D)-160.8 kJd
57. For the following cell, standard potential
of copper electrode is 0.337 V and standard cel 70.
potential is 0463 V.

T obotosls svdteoe nn anuoso no

Cu Cu(IM)|| Ag'(IM) 1Ag albixO0
os
E
What 15 the standard potential of silver electrode?boa ritigapar obork(0
(A)-0.463V (B)-0.126v (C)0.126 V (D)
0.800 Vol a 71
C
58. What will be the concentration
of NaCl solution, if the molar conductivity and conductviy
NaCI solution is 124.32 cm
mol and 1.243x 10 Q cm* respectively?
(A) 0.01 mol L

T
B) 0.02 molL (C) 0.1 mol
59. How many electrons are involved
Lmo
(D) 0.001 mol L
72
in the reaction when 0.40 F

H
electrolytic solution? of electricity is passed throu
(A) 6.022x 103 (B) 1.505 104x (C) 2.4088 x 10 D) 6.642 x 10

M
60. If resistivity of 0.8 M KCI
solution is 2.5 x 10 Q cm. Caleulate olution
(A)5 x 10 em mol molar conductivity ors
N (B)4 x 10°Q cm 73
C)2x 10 cm mol
cm
moly A
61. A solution CusSO4 is
of
D)3 x
electrolyzed using a current
10°
2 mol"
elo doua mass
of Cu is deposited at cathode? (At. of 1.5 amperes for 10 minutes
(A)0.150 g
Mass of Cu - 63.7) 74
(B)0.395 g
(C)0.637 g8 (D)0.297 g
 activh
tance between electrodes of a conductivity Electrochemistry (165))
62. The cell is 0.98 cm and area
1.960cm?. What is the cell constant? of cross section is
cm (B) 1.5 cm
ofa (A)2 (C)0.5 cm
(D)1 cm
sului 63. What is the SI unit for rochemical equivalent?
(A)Kg C (B)JS- C)JC-
tlaw many faradays of electricity 1s required to
(D) Kg C1 6

n
ectrolysis of molten MgCl,? (Molar mass of produce 4.8 g of Mg at cathode in
ofCa Mg- 24 g/mol)
the

o
(A)0.4 F (B)1 F
(C) 10 F

is
(D)4 F
65. Number of electrons involved in the reaction when 1
faraday of electricity is passed through an
electrolytic solution is

s
1046
(A)12 x (B) 96500 (C)8 x 106d (D)6.022x 1023

vity
ofte
h6. During discharging the change taking place at cathode in
(A) Pbo) is oxidized to Pb(aq) (B) Pb
e
lead accumulator is

s
is oxidized to PbO20)

t
(C) Pbg is reduced to
Pbo80o) (D)PbO20) is reduced to Pba)

b
67.Molar conductivity of 0.01 M HCI solution is 400.0 Q cm
mol. Calculate the conductivity
of HCl solution.
(A)2.5x 10
(C)8.0 x 10
Q cm
Q cm
oreoR()
68. Conductivity of a conductor is
(B)4.0x 10

o
(D)4.0x 10
u o cm
em

2 m
(A) inverse of resistance
(C)inverse of resistivity
ot(B)
D inverse of conductance
(D) equal to resistivity

(A)2.75 x 10 (B)0.524 x 1035

1
69.E'cellis 1.040 V and involves transfer of 2 electrons, calculate equilibrium constant of cell.

2
(C)2.75 x 1035 (D)2.098 x 100

0
dard cell 70. In 2 hours, a certain current liberates 0.504 g hydrogen. How many grams of copper can be
deposited by the same current flowing for the same time in a CuSO4 solution?

(A) 63.5 gg zdc(B) 16.0

2
(Molar mass of Cu = 63.5 g mol, Ha =2.0 g mol
go (C) 31.8 g (D) 32 g

tivityof

E T
71. When dry cell is in use the change taking place at cathode is
(A) Zn is reduced
C) MnO is oxidized
(B) NH ions are reduced
(D) Zn is oxidized

an
C
2. Consider the following half-cell reaction: Au" +3e Au

T
ough is required to deposits 0.394 g of Au. (Given Molar mass
How many coulombs of electricity
ofAu 197 g mol)

H
(A) 289.5 C (B) 579.0 C0 C) 386.0 C(e (D) 193.0 C
DIuion
3
What
resistivity is 2.5 x 10
is the molar conductivity of 0.4 M solution of KCI10*if it's em mol
Q cm ?
a
M (A)2.1x10 cm mol (B) 1.0 x
em* mol
mas
)1.0x 10 o cm mol IAO)(D) 2.1 x 10'2
74.The standard What is the maximum electrical work obtained
at ndard emf of Daniel cell is 1.10 volt.
m Daniel
(A) 106.15 cell? (F
kJ
= 96500 C) 0S(8)
(B)212.3 kJ (C)175.4 kJ (D) 57.07 kJ
tEA)
 Exam Questions solution?
(166)MHT-CET does NOT displace zinc from it's 8
metals (D) Na
Which of the following (C) Al
75. (B) K undergo ovi.
(A) Fe relative tendency of metals to idation
fron
correct decreasing of
76. Identify the
Fe
following (B) Cr> Al> Mg>
Mg > Mg
(A) AI> Fe> Cr> (D) Fe>Cr> Al
) Mg> AI> Cr> Fe
the molar
conductivity of 0.1 M NaCl solution of
its condsae
ctivity

o n
is
77. What is
10Nem?em'mol cm'mol
1.01 x
107 Q
(B) 1.01 x 102 cmmol
(A) 1.01 x D) 1.01x 10 2

s
cmmol
(C)1.01 x 10° 2 out by passing 0.01 A currentnt.Wita
solution of NaCl was carried

e
Electrolysis of dilute aqueous
78.
0.01 moles of H2(g) at the
cathode?
is the time required to liberate

s
19.3 x 10 sec (D) 9.65 x 10' sec
(A) 38.6 x 10° sec (B) 28.95 x 10" sec (C)
the conductivity

t
conductivity cell dipped in 0.5 M KC1 gives a resistance of 250 ohms. If
79. A
cell constant?
KClsolution is 6.68 x 10 S cm, what is the
(A) 1.67 cm (B) 0.364 cm (C)0.810 cm

80. A conductivity cell dipped in 0.01 M AgNO; solution

u b
gives a resistance
D) 0.270 cm
of 3160 ohms. If cel

2
(A)6.723 x 10
(C)1.487x 10acm
cm

D o
constant is 0.47 cm, what is the conductivity of AgNO3 solution?
(B) 1.487 x 10
D) 7.10x 10
Qcm

Q cm

1
81. What is the equilibrium constant of the reaction involving two electrons if the standard emf d
the cell is found to be 0.296 V at 25°C?

2
(A) 1x 10 (B) 2.95 x 10 (C)1x 10 (D) 2.95 x 1010

0
82. Emf of cell having following cell reaction at 298 K is 0.059 V.
Zno+2H Zn" +H2

2 0 003500
What is the value of AG?
(A) -5.7 kJ (B)-14.1 k C)-8.3 kJ (D)-11.4 kJ

(A)10 sec.
E T
83. What is the time required to deposit one millimole of aluminium
through aqueous solution of aluminium ions?
(B) 300 sec.
by passage of 9.65 amy

C
(C) 30 sec. D) 100 sec.A
84. For the following cell, bep
Zn Zn (1IM) ||H' (1M) |H2g(latm)

T
Cell potential is 0.763 V. What is the potential
(A)-0.763V
of Zn"|Zn electrode?
(B) 0.242 V

H
()0.3815 V (D) 0.0 V
85. During the electrolysis of molten sodium
chloride, the product obtained cathode 15
(A) Hap (B) Na at

M
(C) Clh D) O
86. Which element among the following three
is used as reducing
elements from their oxides? agent for reduction of re
(A) Mg (B) Zn
87.If theresistivity of 0.1 M KCl solution
is
(C)
Al
50 2 cm, what is
ro(D) Hg
(A) 160 2 cm mol ity?
its molar conductiviy
(C) 290 2 cm mol (B) 240 Q cm molr
(D)200 Q cm? mol 1
lo iso 00
 oquired to deposit one
millimole of Electrochemistry (167)
88. The aqueous lution of metal ion monovalent metal
throug is by the passage of 9.65 amperes
ation sec. (B) 10 sec.
(A) 100 (C) 300 sec.
from
lar Conductivity at infinite (D)30 sec.
the enectively, dilution
9.If the molar conductivity for NaCl, KCI and KBr are 126, 150

n
moascm? cm mol (B) 176 at infinite dilution for NaBr and 152 S cm
(A) 303 S S cm' mol
(C) 128 S cm mol is

o
uctivity (D) 278 S cm mol
the valu
value of cell constant conductance

is
What is if
is 90.
(A) 10.0
cm (B) 1.0 cm and conductivity of a solution is same?
(C)0.5 cm
(D) 0.1 cm
hich among the following electrical properties

s
has SI unit Siemens per meter?
(A) Conductance (B) Resistivity
(C)Resistance
Tent.What

e
(D)Conductivity
Ca O2 () CO2 (
92.1f +
AH=-396 kJ mol", calculate heat liberated

s
sec 0.154 kg of CO2 . during formation of
(A) 1386.0 kJ (B) 346.5 kJ (C)693.0 kJ
uctivity

t
(D) 1039.5 k
of the standard emf of following cel1?
93. What is

b
Ni) Nia)llAu)lAu 0A10 JBitei
IM IM

u
ms.
Ifcell ifE-0.25v, Eu 1.50V.

o
(A)1.75 V (B)-1.75 V i (C)1.25 V to tato(D)-1.25 V
conductivity of Nal solution is 6.0 x 10 ncm

D
94. The and molar conductivity is
rd emf of
120cm'mol". Calculate the concentration of Nal solution.
(A)0.05 M (B)7.2x 10 M C)0.005 M orfoi(D)2 x 10 M
95. Which
(A)Mg

96. During
(B) Ag

2 1
metal from following has highest tendency to undergo oxidation?aosbro
(C)Fe
electrolysis of aqueous NaCl, the product obtained at cathode
(D)AI0
is

ampere
7.
(A)H2(
The
(B) Ch

2 0 C)H-Og (D)O2(
standard electrode potential of Zn and Ni are -0.76 V and -0.25 V respectively. If the
reaction takes place in the cell constructed between these two electrodes
is spontaneous. What is

T
the standard emf of the cell?
C)5.1 V (D) 1.01 V
(A) 0.101 V (B) 0.51 V

E
.Ihe resistance of 0.01 M solution of
an electrolyte is 100 N at 298 K. What is the conductivity

C
of solution? (Given: b =l cm')
(B) 10 ohm
cm
(A) 10 ohm cm
(D) 10 ohm
cm
(C) 10ohm cm

T
conductivity cell is 300 ohm and conductivity is
AESIStance of 0.1 M KCI solution in a
0.013 S cm What is cell constant (D) 3.9 cm

H
(C)4.5 cm
three
(A) 3.0 cm (B) 1.5 cm
1s molar conductivity of
1.061 x 10 S cm. What
ung
0.01 solution is

M
e Conductivity of M salt
the solution? cm mol
(A) 10.61 cm (B) 1.061 2
cm' mol
(C)106.1 Q cm
Q' mol
mol
at (D) 1.061 x 10 2
101.What
(A is tthe unit of electrical conductance (C) Siemens -1 (D) Volt
(A) Ohm (B) Siemens
 (168) MHT-CET Exam Questions
containing 0.01 M CusSo
102. What is the electrode
potential of Cu)Cu) electrode, solutien

298 K ? (E 0,34 V at 298 K)

(C) 0.399 V (D) 0.170 V
(A)0.2808BV (B) 0.222 V

n
SOLUTIONS

1. (A)
Given, EtA=0.80 V, H H
Hydrogen is anode and silver is cathode.
Ag |Ag
teolotai anogddw is o
Eell Ecathode-EAnode
0.80-0.00 (EH0.00 V)

e s
2 (C)
0.80 V

t s
The element having lower reduction potential can displace metal having higher reduction potential

b
Reduction potential of A = 0.8 V
Reduction potential of B = 0.79 V

u
Reduction potential ofC = 0.34 V
Reduction potential of D= -2.37 V

o
Reduction potential of D is least among given elements.
It can displace all other metals.
3. (C)
Metals having higher oxidation potential (or
D
1
lesser Eyed) can replace metals having lesse
oxidation potential.

2
: Oxidation potential of Na is more than that dgoreolof motfare
of Zn.
Na is used to reduce Zn salts.
4. (B)
E Ep+

2 0 n
log [M*
ngieog boiools bosbnse odt

T
Given, ERP
-2.36V, (M)-0.1 M
n 1
(for M> M)
E
VE0(8 rO0(A)
E Ep+ log[M*] =-2.36+ log 0.1=-2.36+0.0591 x(-)

C
n
-2.36-0.0591-2.419V
5. (A)

HT Equivalent conductance
equivalent of electrolyte
is defined as conducting

The equivalent weight of BaClh =molecular weight

power of all the ions produced
by onc
gra

M
2
A for BaCl, Ba" 2CT
Agfor BaClh
6. D)
Ba"+C- 127
76-139.5ohm lem?1o.0
Reducing character is based upon
higner
Order of reducing character is B>C>A.negative value of reduction electrode potential
 Electrochemistry (169)
7.(
2H+2eH bnoonalorn
According to Nernst equation, bvo vlobalo oho slort
=E°+2.303
RT oboobobM mo

n
E
nF
1
[H*1
2.303 RT
2xF
-log[H*)-2.303 RT.
pH
is o
s
(D)
anode E

e
Fcathode cu2
E

Cu)EM2Mo 0.337--2.37) V =2.7 V

9. (A)

EeEcathodeanode15-0.15=1.35 V
t s
(B)
According to

=
Faraday's first law,M
ZIt and Z96500
E
1.0,4 gieve be

u b a3nalen

o
W

Elt
iolsso slom I 2eogob ot boTpet o

D
W
96500 olao to esM
Where, I= current, t = time, E = equivalent weight, w = weight deposited oalo
11. (A)
Anode is always the

2 1
site of oxidation thus anode half cell is
onI
fon to off
101 boztpon a6

e 2r
0
V poo
Zn"(aq) +2e Zn(s), rurolso E 1
-0.76
2.0

2
Cathode half-cell is

Ag:O($) + H,O(1) +2e2 Ag(s)+20H (aq); E = 0.34 V

12.(C)
Fcell

E T
Ecathode-Eanode 0.34--0.76)= +1.10 V gnieol bnuograog sd

Given, molar

C
conductance at 0.1 M concentration,
Ac= 9.54 Qcm mol bs

HTMolar conductance at infinite dilution,

A=238 Q cm mol
c Know that, degree of
ionisation, a =

A
x100=
Ag x100
238
x100 = 4.008 % ()

M
13.(C)
Conductance is given by, G =k.a.l where, k is specific

iemob aa
conductance.ooM

oglonooloasoet otoloa0ee

betizogsb 92 1tw
 Exam Questions
(170)MHT-CET
produced by
power of all the ions prododissoh
14. (A) is the conducting ions soving
Molar conductance molar conductance oc number of huced.
mole of an
electrolyte. Therefore,
lg lonisation
Modern-Notation
Werner Complex [Co(NH):Cl](No ionisation)
CoCl.3NH [Co(NH)Cli] [Co(NH).Cl] + CI(2 ions)
[Co(NH)C1,]CI

n
COCl4NH [Co(NH:)5CI) Clh[Co(NH:):CIJ"+2C1
(3 ions)
CoCl.5NH [Co(NH)6+3Cr(4 ions)

o
[Co(NH)%JCl

is
COCl.6NH complexes will be in the falrowin
From the above table it is clear
that, molar conduction of the
order a < b<e<d.
15. (A)
The overall reaction taking place at anode during
suitable electrode is oxidation of CI ions to Cl; (g).

e s
electrolysis of fused sodium chloride.
eusing

2 CT()

16. (D)
Clh (g)+ 2e (overall oxidation at anode)

t s
b
The cell constant is determined by using 1M, 0.1 M, or 0.01 M KCl solution. ou/

u
17. (A)
Ca+2e Ca

Mass of calcium deposited = 10 g

Molar mass of calcium= 40 g moltaior oleviups
No. of moles =.
10
D o
2 moles of electrons are required to deposit I mole of calcium.

3 ah
0023e
oul

1
= 0.25 mol
40g mol
2 F are required for 1 mole of calcium url ao

x=0.25 x 2 0.5 F

0 2
x F are required for 0.25 mole of calcium.
a(pa)
Bao-sd oboru

2
18. (A)
PboPbim)|Agim)|Ago)

T
The compound losinge is called reducing
agent.
PbPb" +2e

E
19. (A)

C
In a dry cell, zinc acts as negative electrode.
20. (A)
1itnt3e sonatoubico1sl0

T
It is strongest reducing agent.
21. (B) 22. (D)

H -
23. (C)
No. of molesofe"- 2x96500
20x60 =2.487

M
x 10 mol e
24. (B)
HSO4 solution used as electrolyte has
density 1.2 gL-1
25. (B)
Moles of Cu deposited=0.4,
as botn the olyte
will get deposited. cell are in series,
same moles of both tne
issolvinq
(D) #v of electrolytic solution Electrochemistry (171)
depends on no.
of ions per unit
17.(B) volume.
R-2.5 x 10' Q
C-0.1, b = 1.25 cm

-?

n
1.25
R 2.5x10

o
lowing
10x1.25

is
1000k
A
C 0.1x10 x2.5 -50 cm mol

s
USing 28.(C)
Electrode potential of
SHE 1sarbitrarily taken as

ther several electrodes is
e
calculated thus SHE
zero and by using
SHE, electrode potential of
is called as primary

s
29.(A) reference electrode

t
30.(B)
In electrolysis of aq. NaCl

b
Atcathode: Na)+e Na

2H,0+2e

u
H2
+20H)
At anode: 2C+2eCl +2e

Ch
31.(C)
2H,0 O2g+4H +4e°
gas is evolved at anode and H2 gas
evolved at cathode.

D o orele

1
Zn ZnSO, CuSo, | Cu, I

E2V

2
Eo-0.0592 Zn*
log
2

32.(B)
= 2-O.0592lo

2 0 -2+0.0592 2.0592 V

T
AHCI= 425.9, A CHcOONa = 91, A NaCl= 126.4, A CH cOOH =?
ACH,C0OH A CH,COONa+ AHC1- ANaCI =425.9+91-126.4
33.(B)

C
In electrolysis
E of aq. NaCl
218100
390.5 S cm mol

T +e
At cathode: Na Na)
2H,O,+2e>H2 +20H

H 2H,00+4H+
At anode: 2C1+2e>Cl +2e
4e

M gas
4.(C)
41.(A)
is evolved at anode and
35. (D)
42. (C)
36. (A)
H2 gas evolved at cathode.

37. (B) 38. (A) 39. (D) 40. (D)

 (172)MHT-CET Exam Questions
43. (C)
resistivity andx is conductivity or
specific conductance, then
Ifp is a

p-Rx
am (OR ohm m or Sm')

o n
is
a
(In C.G.S. system, the units of K are Qcm or S cm which are used commonlv

s
44. (A)
k=1.06x 10 o cm,C=0.1 M
Molar conductivity, Am =A*100
C
1.06x10x10001.06 x 10 a cm mol
s e
t
siAm 0.1

45. (C)

u b
The anode of electrolytic cell is positive on which oxidation takes place.

o
46. (D)

Conductivity, k= ell constant0.5

cm
abodo
k
R
=1.333x 10 Q cm
3752

D
1
47. (C)

2
During the electrolysis of aqueous NaC1,
i. Hz is liberated at
cathode

0
ii. Clh gas is released
at anode

2
48. (D)
Eel EahodeE E- E

T
=0.337 V--0.236 V) = 0.573 V
49. (B)

CE
Al +3e
1

3e=
mole of electron = 1F
3F
Al
= 96500 coulombs
3x96500-2,89,500
2.895 x 10 coulombs 21DHA

T
50. (A) o000A
C 0.01 M, R=484 Q, k=0.00141
Q cm

H
Cell constant, b b?
kxR
0.00141 cmx 484 Q 2 ieyiooie

M
b 0.682 cm
51. (A)
k 0.01122 cm,R 55.0 Q
Cell constant, b kxR
0.0112 2 cm x 5.0 Q
b 0.616 cm
 52.(B)Kohlrausch Law Electrochemistry (173)
of independent migration
By of ions,
Ao(cC) +2
-119+2(71)
261.0 2 cm mol

53.(C) 200= 1000 C

=Ixt=5 x

The charge ofone electron is

No. of electrons passed
1.602 x 10-1C
1000 C

o n
is
1.602 x 10"C 6.24 x 101

54.(C)

s
1000 k 1000x 2 x102
250 2 cm mol 0000
0.08

e
C

s
55. (A)

t
56. (C)

2Ag+Cd 2Ag +Cd 0

b
d Joeno

u
n=2
AG--nFE-2x 96500 x 1.20 -231600J-231.6 kJ
57.(D)
Eel0.463V
EE-Eo
Eo 0.337 V

D o (olbolto te) sM
edoto oluco

1
oioeelslo7 CegtMtoat
EA
Ee +E 0.463 +0.337 0.800 V
58.(D)
A = 124.3 Q cm

0
mol,k= 2
1.243x 10 2cm

2
C=?
1000 k 1000 k
= C =

T
C

C 1000x1.243x10 = 0,001 mol L-tomo9000 100-0

E
124.3

C
59.(C)
O001
1F=96500C

T 0.4 38600 C 10.0%00

F= 96500 x 0.4
no201x0 000

H
NOw, 96500 C = 6.022x 10 electrons
x 38600
38600 C 6.022x10 ivoboo)

M = 2.4088
96500
x 10 electrons
 (174) MHT-CET Exam Questions
60. (A)
= 0.4 x 10 Q cm
Conductivity (k) resistivity 2.5x10 2 cm
1000k 1000cm L'x0.4x10 Qcm
Molar conductivity (Am)= 0.8 mol LC
C
-5x 10n cm mol
o n
is
61. (D)
The half reaction at cathode is
Cu+2e Cu
Mole ratio=, t- 10 min = 600 s

e s
s
Ixt ratio x molar mass of Cu
Mass of Cu deposited Xmole
96500 0001
1.5x600
96500x 63.7 = 0.297 g
b t
u
62. (C)
0.98 cr

o
Cell constant, b- cmn
a 1.96 cm2 0.5

D
63. (D)
Electrochemical equivalent is the mass of substance deposited or liberated
on an electrode pe

1
coulomb of charge.

2
64. (A) (
Mg +2e Mg

0
(at cathode)
24 g of Mg = 2 F of electricity

4.8 24
2
g of Mg 4.8X2 =0.4 F of electricity.

T
65. (D)

E
1 Faraday
is the electric charge on one mole of electrons (6.022 x 104 electrons).
66. (D)
67. (B)
C
T
C 0.01 M, cm mol
A= 400.0 2
k-?

H A
1000 k
C
k = xC
A1000

M k

68. (C)
=
400.0x0.01 =
1000
4.0 x 10 Qcm
20020o
Conductivity =
o00
resistivity
 69.( Electrochemistry (175)
- 1.049 V, n= 2, K=? v
Feell
0.0592
log K
Eel
Eel Xn 1.049 x 2
: logioK
0.0592 0.0592
ot
35.439

n
logioK
- Antilog (35.439)

70.(B)
=2.75 x 1035
Mass of HydrogenEquivalent mass is o
s
of hydrogen
Mass of Copper Equivalent mass

e
of copper
0.504 1
Mass of copper

Amount of copper deposited

63.5/2
= 0.504 x = 16
sonebo
t s
71. (D)
In dry cell

u b
o
Anode: Zn Zn+2e
rode per Cathode: 2MnO, +2NH)+2e Mn,0, +2NH, +H,O
MnO; is reduced.

72.(B)
D
Au+3e Au)

2
Charge required to produce 197 gm of Au = 3F.
Charge required to produce 0.394 gm of Au =?
1 oubro

3.(C)
O.594X SF
197

2 0 = 0.006 F
=
0.006 x 96500 C=579 C

E T
Specific conductance (K) =
Resisitivity

C K 25x10
Kx1000 Ix1000

T
Molar conductivity Am
M 2.5x10 x 0.4
cm* mol
1.0x 10°2

H
=
74.(B)
Eell1.10volt

M For Daniel
Electrica
15.(A)
cell, n
work done
=2
nFE2 x 96500 x
1.10 -212.3 kJ

Zn> Fe
The K>Na >Al>
ctivity series of metals given above: metals above from respective salt
solutions.
The the
etals placed below cannot displace
 neseest

(176)MHT-CET Exam Questions

76. (C)
The metal placed above in the reactivity series undergoes oxidation easily.
77. (D)
Kx1000 1.01x10x1000

o n
is
Am
C(Molarity) 0.1
Molar conductivity Am 1.01x 10 cm'mol"

78.(C)
0.01 moles of H2 will requires 0.02 moles of electrons or 0.02 F.

e s
s
Ixt =0.02
96500

t
10
xt
1000

b
= 0.02
96500
t= 19.3x 10" sec. 00
79. (A)
Conductivity=Conductance x cell constant
K Cx cell constant
o u
K x cell constant

D
1
6.68 x 10 bou
250 cel constant

2
Cell constant =6.68 x 10 x 250 = 1670 x cm beouboz ai On
10= 1.67

0
80. (C)
Conductivity =Conductance x cell constant

2 x cell constant
R
3160
x0.47 ng or botper egu

T
0.0001487Qm =1.487 x 10 Q'm
81. (A)

CEE
0.295 =
2.303RT log
nF

log Ke
K, =
0.0591
n
logK
ongtbuod oihiog

HT logKc
Kc
=2x0,295

= 1
0.0591
x 1010
10
009

M
82. (D)
AG-nFEcell
AG--2 x 96500 x 0.059

=-11387J
=-11.387 kJ -11.4 kJ
 Electrochemistry (177)2
83. formed=xt
oles of product
Mole
96500 mole ratio
Al+3e Al

Mole ratio 0.33

9.65xt0.3

n
0.001 mol =
96500

o
0.001x96500

is
=t
9.65 x0.33
t 30.30 sec.
batiedilatad bioRei
84.(A)
Eell = Ecathode
Eanode

=0-0.763 V C Ep,

e s
s
= 0.000 V)
Eell -0.763 V
85.0
During the electrolysis of molten sodium chloride pale green Clh
molten silvery white sodium is formed at cathode.

b t
gas is released at anode and

u
obonA 86. (A)
EM-2.37, E2-0.763
isOn
EM
E-1.66, EH+0.79

D o
is very small it undergo oxidation, it means it acts as a reducing agent.
9dto or he qrmoo a wol
gev.ei sMto latastog yito

1
87.(D)
0- eer.0r TE
Conductivity (k) 1

2
Resistivity
itbibooe

0
k 0.02
50

2
1000 k 1000x0.02 =
2002 cm mol
(O). Molar Conductivity
C 0.1

T e beniosde pbeoot
88. (B)
It x mole ratio sbore
Moles of Product deposited

E
96500
9.65xt1 (. For monovalent metal, mole ratio
= 1)

C
0.001
96500
alol 10 sec.

T
89. (C)
According to Kohlrausch Law,

H aNaBr) Ao(NaCI) + Ao(KBr)

- Ao(KCI)

M
150
=126+ 152
olNaBr) = 128 S cm mol
 eee
AÄS
Exam Questions
(178)MHT-CET
constant
90. (B)
= Conductance x cell
Conductivity (k)
Conductivity
Cell constant
Conductance
When, Conductivity=
conductance

o n
is
Cell constant=
I

91. (D)
or S m
of conductivity Qm"

s
=
S. I. unit

e
92. (A)
CO% = 396 kJ heat is liberated
For formation of I mol
396 *I54 = 1386 kJ heat is liberated.

s
154
mol 44

t
44

93. (A)

b
Ee = Fatode-Em EAu- EN
anode
=

u
= 1.50-(-0.25) 1.75 V

94. (C)
Molar conductivity ()=

120 1000 x6.0 x 10

C
1000 K
C

D o
1
0.6
C =0.005 M
120

2
95. (A)
Reduction potential of Mg is very low

0
as compared to other given elements.
EM-2.37, E+0.799, E, -0.440,
E=-1.66

2
96. (A)
At anode, Oxidation
2C) Clhg +2e

E T At cathode, Reduction
2H,0+2
2C+2H0 Cl0
H2 +20H

C Hence, Hg obtained +Hp +20H

at cathode.
97. (B)

HT E
E
-0.76 V,

-
E -E
E-E
E-0.25 V

M -0.25--0.76)
-0.25+0.76
0.51 VV
 98.(C) Electrochemistry (179)2
R

-xb
100

K 10ohm cml

9..(D)
n
constan
Conductivity, k = Cell

o
R

Cell
0.013=Clconstant
constant= 3.9 cm
300
is
100.(A)
conductivity 1000 k

e s
s
Molar
C

t
1000x1.061x104
0.01
10.61

b
= SQ cm* mol

u
101. (B)
of electrical conductance =

o
Unit Q =S (Siemens)
Electrical conductance =
=Q

102.(A)
D
Eoell

For reaction
log.Product]
1
[Reactant]

2
Cu+2
Ecell 34-
Cu

2 0
1
l0g10TO.011
n- 2

E T
0.34-0.0296 logio 100
0.34 0.0296 x 2

C
0.34 0.0592
0.2808 V

HT
M
 eren

6. Chemical Kinetics
Important Formulae and Shortcut Methods
Rate of Reaction

o n
is
For a reaction, aA + bB >cC+dD
d[B]_ 1 d[C]_1 d[D]
Average rate of reaction dA]1
Idt b dt c dt d dt

s
Rate law:

e
For a reaction, a A +bB C+dD

s
Rate of reaction o [A}'[B}' Ratek[AJ" [B]' 00
Where, k is the rate constant which is independent of concentration and

t
varies with temperatre
The powers x and y may be simple whole numbers, zero or fraction
which are experimentalh

b
determinedd
rvcosbr09.2al
Order of the reaction:
For a reaction, a A+ bB
Rate k[AJ" [B}'
cC+dD
Overall order of reaction= x +y
OLxO0.I0001

o
100
toro mo0 16.01 u
Molecularity of reaction:
It is the number of reactant molecules
D
taking part in an elementary
(Eyt01

1
For Example: i. O3g) +Og)202g)
reaction. It is an integer.
(Molecularity 2)itool

2
ii. C,Hs H4g) +Hl) (Molecularity 1) MH
(A).301

0
Integrated rate law: 1.
1. Integrated rate law for the first order

2
reaction in solution:
Consider first order reaction, A > Product
k 250ogAlo

T
10
t [A MH
[A]o-The initial concentration of the reactant A,
2. V

E
[A]= The concentration of A that remains unreacted
at time t
The units of k will be will be s,

C
min or (hour) because
logoAlo
2. Half-life of the first order reaction:
[AJ, 1S unitless quantity.
seeo.o-bEO

T 693 3.
k/2
F

H
The half-life of the first order reaction is independent of initial
reactant concentration. MHT
3. Integrated rate law for gas phase reaction:

M
For the gas phase reaction, 4
Ag) B)+C A
k25108102P-P 5.
t T
Where, P = Initial pressure of A A
P Total pressure of the reaction mixture at time t.

C
 Integrated rate law for zero
4. order reaction: Chemical Kinetics (181)
For zero order reaction, A-P
K A
The units of K will be mol dm

Half-life of zero order reaction:

n
[Alo
t/a 2k

o
a half-life of zero
order reaction

is
is proportional
to the initial concentration
6. Pseudo-first order reaction: of reactant.
Consider hydrolysis of methyl
acetate,

mperature.
rimentally
CH,COOCH+H,O
The reaction was expected to follow
CH,COOHaq) +
CH,OH(9)
the second order kinetics,

e s
s
because the solvent water 1s
arder however, obeys the first
present in such large
concentration is negligible compared excess that the change in its
to initial one or concentration

t
Hence this is a pseudo-first order reaction. its remains constant.

b
Effect of catalyst on Rates of Reaction :
catalyst is a substance that increases the rate
of the reaction without being itself consumed
A

u
the reaction. It functions by providing on altermative mechanism of lower in

the reaction to occur.

activation energy for

eger.

MHT-CET 2008
Multiple

CO8.&(O1
D o
Choice Questions

LO(E

1
how many seconds will the concentration of the reactant in a first order reaction be halved
1. After

10s

2
the rate constant is 1.155 x
if
(A)600 (B) 100 (C)60owato (D) 10 sT t
MHT-CET 2009
2. Which is a

(A)k= .303,
log 2 0
correct integrated rate equation?

82oi1oo11(B) log kk=

ME)
-2.302
jog

T
-

t = equations (
C)-d (a-x) k dt d Ceo0/0) (D)All are integrated rate

E
quantity.
order reaction, the unit of rate constant time?
is
hich
C
order (D)Third
(A)Zero order (B) First order (C) Second order

T
MHT-CET
2010
4. The are
on. units ofrate constant for first order reaction mols D)Lmols

H
(A)mol L s (C)L 168
(B)s oe(6) n0q0goteg
integrated rate equation isdgog or
Thef
uer

M
log
A)k= iros na(B) k=- a-x
(O
(Ck-in (D)
ka(a-X)
-x
 ww

Exam Questions
(182)MHT-CET rate c
17. The
MHT-CET 2011 the 0.080M,
is equal to

n
overall rate of reaction s
multistep reaction, the fastest steP (A) 990
6. In a (B) rate of
MHT-CET 2

o
(A)rate of slowest step
(C) average rate of various steps
(D)the rate of last stcpP16 nu or
is
certain
18. A
1) 2SO2
MHT-CET 2013
*7. What is the activation energy for
a reaction if its rate doubles when
the temperature is
is
raise . In the rea
from 20°C to 35°C ? (R 8.314 mol'
(A)342 kJ mol
J
(B) 269 kJ mol
K)
(C) 34.7 kJ mol (D) 15.1 kJ mol

e s (A) NO2
C) NO
Slope oft

s
MHT-CET 2014 19. (A)-Ea
product is rate k [AJ B). What is the rate nstat
=

t
8. Rate law for the reaction A + B ,
the rate of reaction at a given temperature is 0.22 Ms when [A]=IM
and [B]=0.25 M? MHT-CET2
if Ms D)0.05 M's

b
(B)0.88 Ms (C)1.136
(A)3.52 Ms 20. For theeel
MHT-CET 2015 relations
For the reaction if the rate law expression is, rate

u [0] t +d[S
9. Os(g) +Og20:(g) k [O;]
(A)-

o
molecularity and order of the reaction are respectively
(A)2 and 2 (B)2 and 1.33 (C)2 and 1 oa
(D)1 and2
(C)
+1 d

D
10. The relationship between rate constant and half-life period of zero order reaction is given by
0.693 (D)t=4A%
(A) t =[Alo2k (B) ,

k 2k
21. Which ar

1
k
2
(A) 2NH
11. Half-life period of a first order reaction, A > product is 6.93
hour. What is the value of rae

2
constant? (B) Ci2H
(A)1.596 h (B)0.1 h C)4.802 h (C) H2g)
D)10 h

0
MHT-CET 2016 won teA (D) 2HC

2
12. The reaction takes place in two steps as 22. The acti
o08(A
i) NO,Cl NO2) +Cl i) NO,Clg) constant
Identify the reaction intermediate.
+Clg NO2) +Cla (A)1.6 x
(A)NO2Cl

E T (B) NO0
13. The rate constant and half-life of a first order
(A)tia
2=
0693 B)tu 0.693 k
(C)Cho
reaction are related
(D)Cl
to each other as
dedl
23. For
a cht
of reactic
(A)incre

C
k (C)k = 0.695 tun
(D)ktin0.693
(C) incre
14. Average rate of reaction 2SO2)t Og) >2 SOs is 24. For
written as
(A) 1S0,]
the e
(B)-0, C)aso, followin

T 2 At
At At
(D) AS0,]sA
MHT-CET 2017 At
(A)3d

H 15. Which among the following reactions is an example of 0-188

(A)Inversion of cane sugar pseudo first
(B) Decomposition order reaction?
C)Conversion of cyclopropane to propene (D)Decomposition of H2O2 C)2d

M ofNOs 3
*16. Which among the following equations represents Arhenius 25.The
equation? e integ
(A) k=Ae,/RT (B) k=A eRT/E, (C)k RT
(A)k=2
(D)kTE
C)k=2
 constant for aa first order reaction
nt for Chemical Kinetics (183)
The rae is 7.0 x 10
s.
17.0.080 M, what is the half-life of reaction? If initial concentration reactant
(B) 79.2 s of 1s
(A)990 s (C)12375 s
MHT-CET2018 (D)10.10 x 10s

n
certain
reaction occurs in two steps as
2s02g)+2NO2(g)> s03()+2NO()

o
ii) 2NO( +O,(8)>2NO2)
ature

is
is raised the
reaction,
In
1S intermediate
(A) NOg) (B) NO is intermediate
(C)NO) is catalyst (D) Ozg is intermediate

s
the straight line obtained by plotting
logiok against 1/T
19. Stop represents what term?

e
rate constant (B)-2.303 E/R
(A)-E (C)-E/2.303 R (D)-E,/R

s
25 M? MHT-CET 2019

20. Forthe
the elementary reaction

t
2sO t
Og) 2S0(g)», identify the correct among the following
relations

b
[Os] [O]the -djsO3g»l-2d|02(g)
(4) dt
(B) +d[SO(g-d02
t

u
t dt
+1 dSOg d[sO2(g
(C) D)s2g)dO2g)

o
given by 2 dt dt dt dt
21. Which among the following reaction is an example of azero order reaction?

D
Pt
(A) 2NH3()
value of ate (B)CpHz2O11()+ H,OgCHI20s4 +CoHi2Osaq)
T (C) Hag tIag)> 2Hlg
D)2H;02002H;00 + Og)

2 1
activation energy of a reaction is zero. Its rate constant at 280 K
is 1.6 x 10 s", the rate

0
The
2. constant at 300 K is
(B) 1.6x 10 s
s s

2
(A)1.6x 10' (C)3.2 x 10 D)Zero
2)
constant [B], the rate
25. For
chemical reaction rate law is, rate = k [A]' [B]. If [A] is doubled at
a

T
of reaction
(A)increases by a factor of 4 (B) increases by a factor of 3
(D)increases by a factor of 2

E
(C
increases by a factor of 8
the elementary reaction, 3 H2e) +Narg >2 NH3) identify
the correct relation among the

C
rOr
following relations.
A)3dH d NH .-1dH
T
(B) 3 dt
2 dt
dt dt
oD)HdNH]
H 2dHd NH dt dt
dt
reaction, A> Product,
15
dt

M
Their
aled rate equation for first order

A (A)k=2.303
tlog1oA], a B) k=-.

C)k i 1el k=;

+ A log1o D)
 (184)MHT-CET Exam Questions
26.Order which among the
of
(A)2H;0202H,O
following reactions is NOT one?
+Oztg) (B) Cyclopropane> CH3- CH=CH

o n 37

is
+HCI
(C)2N;Osg)2NOg) +Ozg D(D)CHC) t Chg)>CClug
27. Consider the reaction 2A+B-> product.
When conc. of °B alone was doubled, the hales
alf-life
the rate inCreases by two times, order

s
38.
not change. When conc. of "A" alone was doubled,
reaction is

e
(A)2 (B) 1.5 (C)1 (D)0

s
28. Consider the reaction 2A +2B C+2D, concentration of A is doubled at constant [B) z
if 39
increases by a factor 4. If concentration B is doubled at constant [A] the rate is doubled p.

t
law of the reaction is
(A)rate-k[A (B] B)rate= k{A] [B (Crate [A
[B}* (Drate k[A]B)

(A)9.605 x 10 min
(C)1.374 x 10 min

u b
29. If the half-life period of a first order reaction is 200 minutes,
(B)3.465x 10
(D) 288.6 min
the rate constant will be
min
40

30. If the rate of reaction is expressed as, -

(A)3A +2B » C
31. A>B
(B)2B3A +C

D o
1d[AII2 dB| -q,
is first order reaction with rate equal
constant of the reaction is
dt
(C) 2B + C>
to 6.6 x 10
dt
3A
M
the reaction is

s.
(D) 3A2B +C
When [A] is 0.6 M,
41

1
42
(A) 9x 10s (B)9x 10s (C) 1.1 x 10 slwol (D) 1.1 x 10 s

2
MHT-CET 2020
32. Which of the following is a character

0
of catalyst?
(A)It increases the rates of both forward
and backward reactions
(B) It increases the activation energy of equally in reversible reaction 43

2
reactants
(C)It affects the energies of reactants and
products of the reaction
(D)It changes the position of equilibrium

T
33. In the reaction, N, +3H,
2NH3, the rate of disappearance 44
appearance of NH, is of H2 is 0.02 M/s. The rate

E
(A) 0.0133 M/s (B)0.004 M/s (C)0.032 M/s

C
*34. Which among the following 1s correct (D)0.023 M/s
decreases at constant temperature and
when energy of activation,
for same concentration? Ea of the catalyzed reactou
(A)eaRTdecreases (B)/RT decreases

T
(C)K decreases
35. Half-life of first order reaction is 20 minutes. (D)/RT decreases
What is
the time 6

H
concentration of the reactant taken to reduce
toth? initial
the
(A)66.56 min (B)6.6 min (C) 150 min

M
36. The rate law for the reaction (D)79.68 min 47
2NO)+Og) 2NO
among the following statement is correct? is rate -k[NOJ which
(A)The reaction is first order in 02, first order in NO [O:] then
,
and cond 48
(B)The reaction is second order in NO, zero order in O2 and order overall
(C)The reaction is second order in NO, first order in in O second
(
and third order overall
(D)The reaction is zero order overall order overall
49
 www e

e ae
tws

er reaction 87.5%
In a first order of reactant
87.59% of Chemical Kinetics (185)
37 constant for the reaction is given by is converted into
28) product in 15 minutes. The ra
(B) 0.693 min

n
A)6O3min 15 (C)0.693 x 5 min
e half-lifedid D) min

o
5
mes, half-life of a first order

is
38. The
I reaction is 6.0 hour, How
order long will it take for the concentration ot
reactant to decrease from 0.4 M to 0.12 M?
(A) 10.42 h B)9.51 h (C) 30.36 h
D)4.25

s
stant[B),
rate
ioubled.Rate
ar the first order reaction A B, the rate constant is 0.25 s,
h

if the concentration of A is

e
reduced to half, the value of rate constant will be oae 00
(A)0.25 s (B)0.30 s
d

s
B] (C)2.25 s()(D)0.075 s
Eorthe reaction 4NH3+502 4NO + 6H;0, the rate of disappearance NH
e 40. of

t
is 3.6 x 10 M/s.
What is the rate of formation of water?
(A)6.0 x 10M/s (B)54x 10 M/s

b
(C)3.6 x 10 M/s (D)4.0x 10 M/s
41.The rate law for the reaction A +B+C- Product is expressed as Rate- k{AS [BY' (CP. What

s0.6 M, rate 42. The

(A)3
is the overall order of the reaction?

reaction N,O, -
(B)1
2NO +0,
(C)2

o u (D)0
is first order in N.Os having rate constant 6.2x10s

(A)
What is
7.75
the value of rate
x 10 mol L s
olot D
of reaction when concentration of N-O, is 1.25 mol L"?
(B) 8.15 x 10 mol Ls h at
sed0

1
(C)4.96 x 10 mol L-1 s-1 (D)2.01 x 10 mol Ls
for 75%
first order reaction is 0.02232 min. Calculate the time required

2
43. The rate constant for
le reaction completion of the reaction.

0
(C)48.12 min (D)12.77 min
(A)62.12 min (B)38.31 min
zero order reaction?

2
44. Which among the following is an example of
(A) Hydrolysis of CH3COOCH3
s. The rate of (B) Inversion of Ci2Hz2O11

T
(
Decomposition of N,O in presence of catalyst TO
(D) Decomposition of N0s

E
tna
reaction the of rate constant for the zero order reaction?a.Fat (D) mol dmt
yzed .What is unit (C)mol dmr

C 0B)-ke
(A) (B) mol dm't
slope of the graph of logio[A].
Vs. time is equal to A
ases rOr first order reaction the
(D) k
(C)03 2303mb

T
initial (A)k 1ooto 2.303
ce the acetaldehyde? 0: 6A)
gaseous

H
decomposition of loiufW
gnivollo D)
1
47. What
is the order oof reaction for
(A) 0 (B) 2 obuseg to s(91.i
times, the rate of reaction becomes 100 times.
which by 10

M
then
48. If concent
Whontration of reactant 'A' rate is increased = k[AJ?
law is, rate (D) 4
(A)2
is the order of reaction
if (C)3
take for 20 g of
reactant to
(B) 1 What time will it
49. A 1 x 10s.
first order reaction has rate
reduce
rat constant
t
D) 346.5 S
to 5 g? (C) 693.0 SoH
(A) 138.6
s (B) 238.6 s
 (186)MHT-CET Exam Questions
50. What is the value of rate constant of first order reaction, if
minutes for
it takes 15 minutes for consum
e

o n
is
of 20% of reactants? -1
(A) 1.07 x 10 min (B) 1.48 x 10 min
(C)1.84 x 10 min (D)1.38 x 10 min

too51. A first order reaction has a rate constant 0.00813 min,

completion?
s
how long will it take

e
D)98.7 min
r

s
(A)112.7 min B) 56.35 min (C) 62.77 min

52. Half-life of first order reaction X Y+Z is 3 minutes. What is the time required toreduce
red

the concentration of X° by 90 % of it's initial concentration?lsv odt

(A)9.969 minutes (B) 4.12 minutes (C)9.105 minutes

b t
(D) 12.05 minutes
53. A first order reaction is 25% completed in 40 minutes. What is the rate constant
ei

t
u
k for
reaction?
2.303 2.303x log 1.33 log 4
C)303x
(A)xlogE

o
40
B) (D) 2.303x log
40 40x3
54. For first order reaction the concentration of reactant

D
decreases form 0.2 to 0.1 M in 100 minuts
What is the rate constant of the reaction?
(A) 144.3 min (B)6.93 min (C)69.3 min

1
D)6.93 x 10 min
55. A first order reaction is 75% completed in
60 minutes, the time required
(A)30 min for it's 50% completion s

2
(B) 60 min (C)120
56. What is the molecularity and order mins
of the following reaction
D)40 min

0
respectively? if rate law is, rate k [Os]10
otberOg+O 2021

2
ebno jed 101
(A)3 and 1
(B)3 and 2 (C)4 and 2
57. For a first order reaction, AB, D)2 and 2

T
1t LAJ I M and rate
is
constant of the reaction? 4x 102 M s What is the rae
(A) 4 x 10s

E
(B) 0.4 x 10s
C) 2x 10s
(D) 2.5 x 10 s
58. For the reaction, 2NOB)>2NO)+

C
B) Tate law is
=k [NOBr?, r
If rate constant is 1.62 M sand concentration
of NOBr
oG)
reaction? is 2.00
o A6 10 10 M, what is therate

T
x
Ms (B)5.24 x 10 Ms
(6.48x 10 Ms
59. In the reaction 2S02 +0 2S0 the rate of appearance (D)4.05 x 1o-S Ms

H disappearance of O is
(A) 1.0 x 10 M/s (B)4,0 x 10 M/s (C)2.0x
of SOg is
10 M/s
4 x 10 M/s, rate o
the

M
of
60. Which among the following is an example of pseudo
pseudo first (D) 6.0x
order reaction? . 10 M/s
00 (A)2 N,Osg) 4NO) Oa) t

(8) CH,
-H, CH, -CH-CH,
(C)H2Oco2H200+ Oxo
(D) CHCOOCHs) + H,O CH,COOH) +CH,OH
esfor hat is the
What erage rate of reaction
average
when the change
Chemical Kinetics (187)
consumption 61. seconds? in concentration
of product is 0.05 M in 20
(B) 0.05 M/s
(A) 4.0 M/s

n
(C)0.0025 M/s
(D) 1.0 M/s
the reaction A+B,
In AB+B,
the rate of reaction

o
it take ntration
concen of A and independent on the is directly proportional to the

is
for 60% concentration of
(A) rate-
k[A] (B) rate k[B;] B. What is the rate law expression
in
(C)rate- k[A] [B,] (D) rate- k[A)TBa)
63. The
rate for the reaction is r-
k[AJBJ'. If the concentration
of A is doubled and that of B is

s
required halved, the new rate is ra then what is the ratio of
toreduce 20-b)
r2/?

e
(A) (B) a -
b (C)a+b
ninutes (D)

s
The reaction 2NO;Cl 2NO2) + Clh takes place in two steps
onstant k for th
64.
+ Cl
as
NO;Cl NOg)
log
M in 100 minutes.
() NO;Cl+Ckp
Identify the reaction intermediate.
(A) NO:(g)
NO)+Clh
(B) NO,Clo
(8
b
(C)Clo0ot0.o(D) Clap t
2S0+O2S0SO3?
u
65. In the reaction the rate of disappearance of SO is 1.28 x 10 Ms.
appearance of

o
What is the rate of
0 min (B) 1.25 x 10 M/s (C) 0.64 10 M/s (D) 0.32 10 M/s
(A) 2.56 x 10 M/s x x

% completion

D
is
66.
A reaction takes 40 minutes for 30% decomposition. What is the half-life of reaction?
first order
(A) 59.5 min (B) 77.8 min (C)67.8 min D) 82.2 min
rate k 10 minutes. What percentage does the

1
[O-][0] 67. Acertain zero order reaction is 50% completed in
reaction completes after 15 minutes?
(D)60%

2
(A) 65% (B)25% (C)75%
of N2 is 2.6 x 10 M/s,
2NH), if the rate of disappearance

0
68. In a reaction Na(g)+3H2)
in M/s is
rate
the rate of disappearance of Hz (C)2.6 x 10 M/s (D) 7.8 x 10 M/s
What is the (B) 5.2 x 10 M/s

2
(A) 8.6 x 10 M/s
time is expressed in seconds?
69. Which is the unit of rate constant
for the first order reaction if
mol dm"s (D) mol dm's
s (C)

T
(A) mol dm's (B)
+O2
. order kinetics: 2 N024NO2
Keaction given below follows first M and rate of reaction is
0.05

E
N;O2 is
Calculate rate constant of reaction if concentration of
rate of
vhat is the Ls? s D)2.0x 10s

C
1.5x 10 mol (C) 1.5 x 10
(A)2.5x 10 s (B)3.0x 10s will be the concentration of
0 Ms constant 0.025 M s What
rate
certain zero order reaction has

T
rate of concentration is 0.50 M?
M/s, the " Adctant'A'after 15 seconds, if
initial
(C)0,375 MM
(D)0.060 M
(B)0.125 M the rate law for
(A)0.50 M in B. What is

H
and first order
0 M/s order in A
eaction A +B P, is second (D) Rate k[A] [B
=
the reaction? Rate-k[A]"[B]
Rate=k[AP B]'" (C)

M (B) constant ofthe reaction?

Kate =k[A] [B] minutes. What is the rate
73. A first completed in 50 10min
orde reaction is 50 % (B) 3.465 x
Order
(A)7.215x 10 min (D) 1.386 x 10 min
the half-life of
reaction.
completion. Calculate (D)57.8 min
(C)1.386x 10 min
minutes for 30% (C)42.7 min
caction takes 40
first order reac
(A)77.7 min (B)23.1 min
 w
ecers
ww

(188) MHT-CET Exam Questions

75. Rate constant for zero order reaction is 2 x 10 mol
after 25 sec. is 0.5 M, what is the initial concentration
Ls. If the concentration
of reactant?
ionofoftheTeact

o n
is
(A)0.125 M (B)0.5 M (C)1.25 M (D)1.0 M
76. The slope of a graph, log [A] versus t for a first order reaction is-2.S 1. (A)
constant for the reaction is
x 10- Therae Rate co
(A)-25x 10 s(B) 2.5 x 10s (C)1.086x 10s
77. The slope of a graph, log [A]: versus t' for a first order reaction
is 2.5 x
(D) 5.757 x

10sT s
10s

e
s
constant for the reaction is Therae a
(A)-2.5 x 10 s(B) 2.5 x 10 s (C) 1.086 x 10 s
(D) 5.757x 10 s

t
78. A first order reaction, A ti/2
>B takes 100 minutes for it's 90o completion.
constant of reaction? What is the r

b
ate
(A) 0.0460 min (B) 0.0230 min ti/2
(C)0.2303 min2 (D) 0.4606 min

u
79.0.0210 M solution of N,Os is 2. (B)
allowed to decompose at 43°C. How
0.0150M ? (Given k = 6.0 x long will it take to reducet For first
10 sec)

o
(A)3364 sec (B) 360.0 sec (C)560.0 sec (D) 5600 sec k
80. The rate of first order reaction A

D
constant of the reaction? > B is 6.3 x 10 Ms', if [A] = 0.3 M, what is the rate
(A)1.3x 10 s
3. (B)
(B) 2.1 x 10S s
C)1.2x 10 s- 5. (C)
81. For zero order reaction, when (D)1.6x 10s

1
obtained is equal to [AJ is plotted against For first
time (t), the slope
eso of
the straight line

2
(A)-k (B)-kt (C)k Rate
82. A first order reaction D)[A] A
is 50 % completed

0
in 32 minutes is in 16 minutes. The
percentage On integ
(A)75 % of reactant that will reat
(B)12-5% dE

2
(C)25%
83. Consider the reaction; (D) 100%
2N,Os) 4NO,)+O2g What
concentration of NO2 increases is the rate of reaction, when
In[R]

T
to 5.2 x 10 M Att 0,
(A) 2 x 10 M/s (B) 7.6 x 10 M/s in 100 sec.?
(C) 5 x [Where,
84. For the reaction 2A +B 10M/sto

E
3C+ D, which among D) 1.3 x 10 M/s In [R
expression? the
n coitoas following
is NOT the correct rate On puttin
d[A]

C
R)dB la
In[R]
2 dt
dt C) dD 0
85. The time required to decompose dt
D)dc =

T
rate constant for this first ordeT Cl2 to half 3 dt kt
reaction. of it's initial 6. (A)
(A) 4.158x10 min amount is 60 min
ninutes. Calculate

H
(C)1.155 x 10 min (B) 2.651x Rate of re
10 min
86. The rate constant for the first order
(D)1.551x
reaction is 1.15
10 min 1080
M0200
. equal to t
(C)

M
take to reduce to 3 g? x 10
(A) 414 sec (B) 444 sec Given,
(C) 424 sec long will 5g ofthe eactan
Final in
*87. When the temperature of first order
reaction
tem
which among the following is corect? increases (D)
then according 434 sec Since,
dol (A) e decreases (B) Ea/RT increases to Arrhenius equation rate
RT (C)Ea
RT creasesiro
(D) k decreases
As rate
co
 Chemical Kinetics (189)
thereactant SOLUTIONS

(A) onstant k= 1.155 x 10 s

.Therate Rate
2.303log a
k O (a-x)
0s
1.The
rate
a,(a-x)=

o n
is the rate
ti/2

600s
klog=2.303 2-2.303
1.155x 10-3 O8 155x10-3 X0,3010 =
O.693x 103
1.155
is
s
ti/2

e
in (B)
For first order reaction is

s
to reduce
to =
k

t
t a
4. (B)

b
(B)
t1s the rate
. (C)

ue
For first order,
=kIR: d[R

o
traight line Rate or kdt ter
dt B ODa8 [R

D
On integrating equation (1)

at will react
dR) kdt otstnsonos ibiiniofAlbogtt
R
, when the
Att=0,
In[R]

Where, R =
=-
R] =
final
kt +C
[Ro]
concentration,
2
i.e. 1
a - x and Ro is the initial
i)
O
concentration, i.e. a].

M/s
ect rate law
On
In [Ro] = C

In[R] = -kt + In [Ro] 0

putting the value of C in equation (i),

2
we get

or
k-n n
T
kt In[Ro]- In[R]
- kt =
In[R]- In[Ro] and
.
E
a multistep reaction is
(A)
slowest step; hence the overall rate of
the
Of reaction depends upon

C
Calculate dc
s. cqual to the rate of slowest step.

1. (C)

T
20+273 293 = K
Initial temperature, Ti
Cn,temperature T, =35+273 =308 K
inal

H
reactant
the J mol' K R 8.314 temperature,
nce, rate becomes double on raising
Since
aoue

M
equation 2 2r or 2 2a
Ius
AS
rate constant,
ka-2
k Cr Ki
ses
 (190) MHT-CET Exam Questions
From Arrhenius equation, we know that
16
log ET-T
2.303 R TT2

n
E 293-308 17
log2 2303 8.314 293x308
0.3010 E, -15
2.303x8.314 293x 308
0.3010x 2.303 x 8.314x 293 x 308 is o 18

s
E 34673.48 J mol- 34.7 kJ mof
15

e
1
8. (B)

s
Forreaction, A + B product
-kAB]
dt

0.22k (0.25) k 0.22

0.25
=0.88 Ms-1

b t
u
9. (A)
The rate for the reaction, Os(g) + O(g)

o
bimolecular and its order is 2. 2 O:(g) is rate = k [O3] [O]. The reaction

D
10. (C)
The relationship between half-life of zero order reaction
and its rate constant is given by

2k

2 1
Where, tun - half-life period; [A]o = initial concentration
and k = rate constant.

0
11. (B)
For first order reaction A > product

2
0.693 0.693 0.693
tan = 0.1h-l
k 1/2 6.93

T
12. (D)
NOCI NO2)+ Cl

E
(free radical)

NO, Co+Co NO)+Ca

C
The intermediate generated is CI".

T
13. (A)
The half-life of 1" order reaction is given as tin-693

H
k
14. (B)
Reaction is 2502+ O0280s
M Avg rate of reaction-S02-AO]1A[So,)
2 At At
Out of four options, only (B) option is correct.
15. (A)
2 At
2
2
 (C) Chemical Kinetics (191)
J6Arrheniusequation isk =Ae Ea/RT A
eEa/RT

17.(4) 0.693
t/2 0.693
k
1/2 4990 sec
7.0x104

18.(B)
As. NO is formed during reaction and
again consumed

o n
is
it is intermediate.
bo
19.(C)
Ea

s
Ink=nA RT

e
Ea -Ea
ngin k = log10A 2.303RT logA slope= -Ea

s
2.303R 2.303R
logiok

t
y= mx +C=logiok logioA (C

b
T
n n is

u
C-logioA
-Ea 1/T
m-slop2.303R
(A)
For the reaction
250,+O2 2SO
D o
1
(8) 6)-an,ai coitocst od not waloi

so,]--[0,1-20, iM0olaM01 xdo

2
Rate
01LI-
--0,1so,]
0
Rate=-

2
21.(A)
Lero
<rate of reaction does not depend on concentration of reactant.
order reaction

T
eg 2NH
N2 +3H2
(8)
oto
to ste

E
2.(A)

C
Ea
-0, K 1.6 x 10, T = 280, T 300K, Ka=?0

log Ea_-
o8K2.303RTTJ

HT log K,
1.6x10 =0 log
Ka=1.6 x
K2 = log 1.6x 10

10
m ORED 0

M
3.()
4.(C)
For the
reaction
3H,+N,
>2NH,
 Exam Questions
(192)MHT-CET
d[H,d[N,]1 dNH, so06ape
Rate 3 1 dt dt
dt
d[NH,]
1 dH.1
dt
3
dt 2
d|NH,J
2 d[H dt
dt

25. (B)
Integrated rate equation for
first order
reaction A >P is mus bom
o n
is
2.303A
k= t

e s
26. (D) 27. (A)o28. (A)

t sorgof

b
29. (B)
For first order reaction,

u
=
0.693 3.465 x 10 min
= k=93 HE0E
qp

o
/2

30. (A) noilane sd wi

31. (C)
Rate law for the reaction is, Rate =k [A]
D
1
6.6 x 10 Ms =kx 0.6 M
. k=1.1 x 10 s 00
32.(A)

0 2
-
33. (A)

2
N2 +3H 2NHonoo tto broob ion esob not asst to s181e otoos 00 9
Rate of reaction=- d(NH, )
)=_I d(H,)_1

T
From rate expression,

E
dNH,) - 2d,)
dt

=
3

x0.02
dt

= 0.0133 M/s 08
01 0d
C
dt
34. (D)

T
35. (A)
For first order reaction,
0-
H
=0.693 0.693
k 0.0346 min
/2 20

M if [A]o= 1, [A]= no ?
Here,
10
k -2.303ogA
t [A],
. ti/10 2.303
0.0346 log 10=66.56 min
 J6(C
Rate -k[NO]
x 2,y=1
[O:]
Chemical Kinetics
(193)
Here,
Overall order of reaction
x+y=3 001
37.(D) actant is
87.5 % of reactant i converted
into
[AJo- 100, [A]= 100 87.5 product in 15 minutes,
12.5 means 12.5
2.303 o0[Ah

n
% remains unreacted.

)e
k
15
A
2.303
15

2.505log
100
go12.5
10d

0.693
Oto n
is o
s
k
15
8 =
min
rblom blora
e
38.(A)

s
For first order reaction,
0.693 0.693

t
k =0.1155 h
6.0 h

b
Here, [A]o=0.4 M, [A] = 0.12 M bfobistoos euo6 to ooideogpmoon

u
2.5051o Ah- 2.303 xlog 0.42.305 0.5224 OF
t
[A]} 0.1155h 0.12 0.11550.5224

39. (A)
Rate
t10.42 h
constant for first order reaction is
D o A0-1001
independent of initial concentration.

1
Thus, k 0.25 s
. (B)
4NH+502>4NO + 6H20
Rate of reaction

0
=-1 2
d[NH,] -1dO,] 1 d{NO]
noitoasto 1obiu ds
1 d[H,O]

2 o
dt 5 dt 4 dtg6 dt
Rate of formation of water, dLH,0- 6 d[NH] 0130831 2o0 3eih o

T
(A dt 4 dt

-x3.6x10=5.4 x 103 M/s

41.(A)
42(A)
CE 0.8E101 x 08.0 t0E.C

T N,O,
()0e
2NO,+0, 001nstane7 1o Jsome lecrgiO
zso
H
2 0botossznu gniismen
For first
order reaction,
0 0
A 0E

M
Rate
k[N,Os] A)
6.2 x 10sx 1.25 mol L
innB100- 0l-
te=7.75x10 molL"s
 Questions
MHT-CETExam
(194)
100-7525
43. (A)
If[A]%= 100,
[AJ=
t=7
0.02232 min, -2.5051og 100

n
k 2.303ogAh
23010sA 0.02232 25

o
t
-001A00
is
62.12min MA
t reaction rat
catalyst surface react, the isindependeu
44.( molecules on the
Because only the N,O
the total
concentration of N,O.
Therefore, the reaction
follows zero order
kinetics. 001 got00

e s
45. (C)
For zero order reaction,
kA-[A)_ mol dm
= mol
dm'r
oo08a202
E0E

t s
b
t
odoss 19010 3eul 10

u
46. (C)
02.0ceo:0
47. (C)
0.2

o
Decomposition of gaseous acetaldehyde,
CH,CHO CHg +cO MSIO-A M0oA
Rate k[CH,CHO?
The order of the reaction is 1.5
D
48. (A)
r=k[A,
1
100 r = k[10

2
AJ
si 1 te anobnoquan Roaae10610 ta 101 estanou sta

0
100

2
x=2
The order of reaction = 2
49.(A) O-R0-OMA0

E T k=1x 10,
For first order reaction,
2.5008[A
[AJo= 20 g
.[A]=5g

797w t0
noitoset h

noitsoot10 916

C
k

t 2.3031o0
1x107020

HT 50. (B)
[AJo
[A
t 2.303x0.602 x 10= 138.6
Original amount
of reactant
Reactantremaining 100
s

M
For first order unreacted=
reaction,
100-20 80
2.303oA
k 2.303
15 min 08 =0.0148 min
.k 1.48x 10 80
min otCa
4lom02S
 Chemical Kinetics (195)
S1.(A) Original amount of reactant=
100
(A =Reactant aining unreacted
(Ak order reaction 100-6040
For first LA
2.301og
[A
2.303
0.00813 min
ogio
40
100
= 112.7 min

o n
is
ependent
of 52.(A)
minn
=3

s
1/2
0.693 0.693
0.231 min

e
=
3
/2
rAl=Original amount of reactant = 100
FAL=Reactant remainingunreacted =100-90
For first order reaction,
10

t s
logTAL 2.303
0.231 min
100
109.969 minv

u b
o
53.(B)
[A 100, [A]) =100 25 75,t-40 min

D
-logAL O2c002

1
.
k =
2.30log 100 2.303x log 1.33

2
40 40
54.(D)

.
(For
0.695=6.93 2
min-
6.93 x 10 min
0
first order reaction)3020 broooe s

etaW ioiiv ii
ai rotose1 bro teit

ae
obuoe

T
k
100 min
oo0.M0

E
%.(A)

i 100, 20 [A]= 100 75 =25, t= 60 min

C
AJo
For first order reaction, oruit at egr

T
k 250 1og
t

H
.303108 100
k 25
60 min
A
M 1. The
time
tun
k2.303x0.6020 0.0231 min
60 min
required for 50 % completion
0.693 - 30 min
of reaction is,

0.0231 min
 Questions
MHT-CET Exam
(196)
56. (D) 2028)
Oe)+O) [O] reaction) =2
= k[O3]
rate reaction=2 taking part in
Orderof reactantmolecules
Molecularity (No. of

n
ii. 64
57. (A)

o
reaction,
For a first order
A
Rate k[A]
B
Ro.0 is
Rate
[A]
4x10-4x 10s C0

e s
s
58. (C)
2NOB 2NO( +Br()
k=
Now,
1.62 M's,[NOBr] =
r=1.62k[NOBr]
Msx
2.00 x 10 M

(2.00 x 10 M
b t tortosor olbnodeih
E0E

59. (C)
6.48 x 10Ms

o u 00 AT 00
D
2S02+O 2S03
Rate of appearance of SO=
A
=4 x 103 M/s

1
dt
1 dSO,] -4[0,] 1dSO,]
dO-x4x10
2
-
=2x 10 M/s
2 dt dt 2 dt dt
60. (D)

which one of the reactant is present

2
Pseudo first order reaction is a second
0 order than is made
in excess.
Eg.: Ester hydrolysis in which water is
to behave like a first order reacau

T
taken in excess.
CH,COOCH,)+H,O
CH,CoOH

E
+CH,OH
61. (C) i091

C
Average reaction rate =.
Changein concentration
Change in time
of products0.05
0.0025

HT 62. (A)
A+B,
Given Rate oc [A]
Rate depends on
AB + B
and not on [B]
1o 20
298.

M
concentration 001
Rate-k[A) of reactants.
63. (A)
k [AJ [B ti 1eso.0 O00.002.
IfA is doubledand oitoontocoitolpoo
B is halved
pot amitafl
e02 301 besiape
n-k [2A
ciun 0 Ee0.0
0.0
tin 1ec0.0
 wwwww

[B Chemical Kinetics
kA -2*k[Ar [B
...(1)
(197)

2K[AJ (B- 2a-b

k[AJ [B]°

64.(C)
NO;Cl RDSNOg)+ Ck (1)

o n
is
NO;Cl+Cle) NO(g)+ Cl2 ..(2)
2NO,C 2NO +Cl

s
Rate -
k[NO;CI]
reaction intermediate is formed and gets

e
The consumed in the reaction.
Reaction intermediate = Clg)

s
olons tobro Jenh ho
65.(B)

t
2s0, +0,2S03
I d$O,
dtthe above reaction,
In
Rate
dt

of disappearance of SO2 = Rate of formation of SO3

u b
gobs91sb1oorS
0
yot

o
1.28 x 10 M/s = 1.25 x 10
66.(B)
MWs0 et
C0.0

D
First order reaction,
t= 40 min
2.0108100 A 2505 log-0.00892 min
Ag -2.303og

1
k-2501og
40 A 30A 40 70
70 Ao
AJ

2
100 200.0
0.693 0.693 =

0
tp = 77.8 min
ler reaction in k 0.00892 A-020 2

2780-020

2
67.(C)
MESI0
For zero order reaction

T
A Ap- kt
bos bnoooa A 1o zsbno arf
For 50% completion Ao nil ai Eio b0 21

E
A =
(aAon
(O) E
-Ag-k(10 10k- -
C After 15 mins
200
A
A

HTAA--AA
OfOE.0

a0x
OE
o8EIReF00
A

M ance left after 15 min = Ap- A

Completion
x100
3Ag
75% 0
C0E
O
Al
e0.0 80tJorgoi tere.0

800
 Questions
MHT-CETExam
(198) A
68. (D) 2NH)d[NH,]
3Hr) d[H,]
Na)+
dN,)._1 12 dt
dt dt
1 dH]
n
dN,)
dt dt
3

2.6x

q-3x
10-dH,]
3

2.6 x
dt
10-7.8 x 10 M/s
is o
s
dt

e
69. (B)
For first order reaction

k
-o-
The units of rate constant is time"
= sec.
t s ORSe

70. (B)
For the
2 NO
1

4NO
order reaction
+O208 1o nobamoliooia
u b
rate

k
1.5 x
k[N Os]
10kx
5X10-= 3.0 x 10s
0.05
0.05

D o
1
71.(B)
For zero order reaction,
k =

0.3750.50-[A]
A-[A)
15

0 20.025=.0-A]
15
00
Ce0.0 000

2
[A = 0.50-0.375 eaoo.0
[AJ = 0.125 M

T
72. (C)
The order of A is second

E
and order of B is
Rate-k [AJB] first, therefore the rate
law become

C
73. (C)
2.303
k- log LAla-2,303 -01

T t [A
100 (O19-
- 2.303 500 50

H log,2-
50
22303 x0.3010
- 0.01386 50
1.386 x
10min
M 74.(A)
2.303og
k 2.303
0.05757
8A 2.303
A0810
0
100
70
logiol.428
in 0.693 0.05757x0.1547
0.0089 77.865 min 0.0089 min
noiralg
 (D) Chemical Kinetics
15 For zero order reaction. (199)
k Ah-[A]
t
[A,-0.5
2x 102

n
25
0.5+0.5 [AJo

o
[A 1.0M

Thesslo of a graph, log[AJ. versus

't for a first order
is
s
reaction is given
Slope by

e
2.303
2.5x 10x 2.303
=5.757 x10s k o
s
k E pplethae

t
.(D)
The slope of graph, lo8LAJ a
Versus t' for a first order

b
reaction is given by
Slope k
001

u
2.303
-2.5 x 103x 2.303= -k

o
k 5.757 x 10s
78.(
d0
For first

k
order reaction,
logA 2.303100
D
k
k
=
=
0.02303 x 1
0.02303 min
[A

2 1
0
19.(C)

2
t 2501og A 2.303 0.021]
6.0x100 (0.015]
3838 logio 1.4 3838 x 0.1461 =560 sec
80.(B)
For first
Rate-k[AA]
E T
order reaction,
LALICCOxot00 0
6.3x10 k[0.3]
=
C
.5X 10-21 x 104-2.1x 10$

T
k
81.(A) 0.3 Aaoisupe uiasA

H
For zero
order reaction [Ao
k -A[A Slope-k

M Alp-[A)- kt
A
Y
-kt
mx
t

+ [AJo

C
[A

Time(t)
 MHT-CET Exam
Questions
e(200)
82. (A) reaction
order
For the first
2.3030gA) 2,30
t
1og
A
[A)
100
10A
n
100
log 32 A)

o
16
logio100-logio[A] MO

is
0.0188 x 32
0.0188 x 32 2-logiolA]
0.602 2- logio[A] yAol tm
to
oferta
logro[A] = 2-0.602 1.398
By taking antilog
[A 25.00
ogole

e s
s
after 32 minutes = 100-25 75%
% reactant that will react
of
83. (D)
2N,Os 4NO2(¢) +O2()
ety
1 d[NO,] - x5.2x10- 13 x 10 M/s
b t
Alaof digse a to snpls

u
Rate
dt 4x100 sgole
84. D)
2A+B
Rate
3C+D
-_dB)_ dD)_ dC]
D o
1
2dt dt dt 3dt
85. (C) C08.S
tin
0.693

0.693
0 2 gol
IxE0EC00

2
= 1.155 x 10 min
60

T
86. (B)
2.3051og0 E0ES

E
k 1210.01
t 01x0.0

C
1.15x 10 2.303
log,, 1.66
t

T
2.303
tT.15x10
L.15x103X0,2218 = 2002.6 x 0.2218 = 444.17 sec.

H 87.(C)
Arrhenius equation,
o1xIS-0Lx
E.0-0
otkEe
M
k = Ae E,/RT
IS
sqole
LA-LA
 7.Elements
Important Formulae
ofGroups 16,
17 and 18
andShortcut
Group 16
Elem (Oxygen Family) OH Methods
.ns np"O (0,to Po S, Se, Te, Po)
From Atomic size,
M.P.,
lonisation enthalpy,B.P., Densityincreasesobaobg

o n
is
Hydrides electronegativity
(HX): Bond angle, decreases
Reducing power bondenergy
increases decrease
Oxides (EO2, EO,) (E -S,
Halides (EX6, EX4, Se, Te, Po)
EX;) (E = S, Se,

e s
s
Te)inliu mo
Reacts with metals to formcompoundsoed00

t
Allotropes
O: Oz, O

b
S: rhombic, monoclinic obiign
Se: red,greyon
ti

Group 17 Elements (Halogen family)

Te: crystalline, amorphous

o
Po:c, B (both metallic)
u 2

D
2oit1oqot faoigodO
ns np (F, CI, Br, I, At)
From F to I (At)

1
Atomic size, Density increases wtouose
Ionisation enthalpy, electronegativity decreases

2
> (Haloacids, HX): Acidity, reducing character increases, stability
decreases

0
Oxides of halogens (most of them are unstable)

2
Interhalogen compounds
Metal halides
HOaM d roitoeoi

T
Group 18 Elements (Noble gases)
ns
np' (He, Ne, Ar, Kr, Xe, Rn) O0

E
From He to Xe (Rn)

C
Atomic
lonisation
size, density, M.P., B.P., increases
enthalpy decreases

Chemically inert towards

hydrogen, oxygen

Krypton and Xenon form fluorides00b

T
to sopeog50
HA02
H Oxoacids
of Sulphur
ii. Sulphuric acid
- H2SO4

M
Sulphurous acid- HS0s monosulphuric acid-HSOs
ii. Di or yrosulphur acid- HS07 iv. Peroxy
HS,03
v. Peroxy vi. Thiosulphuric acid-
disulphuric acid- HS2Os
 Questions
(202)MHT-CET Exam
of chlorine
Oxoacids
Oxyacids of chlorine

HCIO HCIO4
HOCI HCIO

increases
Thermal stability, Acid strength

Sulphur dioxide (SO)

o n
is
a. Preparation
i. From sulphur

So+Ozg)
ii. From sulphite
SOg)

e s
Na,sOg +H,sOa(09) Na,SO, + H,0
ii. From sulphides (Industrial method)
+SO2(p)

t s
2ZnS+302(g) 2ZnO( +2S02(6

4FeS20+11020)2Fe,Os(o) +8S02
u b
b. Chemical Properties:

i. Reaction with Cl2

D o
1
Charcoal enesC osie
SO2)+Clhg) S0,Cl2(
ii. Reaction with
O
2s02g) +O2cg)

0 2 ergolsrl to 2obix0

2
ii. Reaction with NaOH
2obiad lasrov

T
2NaOH+S0,
NaSOg +H,0
iv. Reaction

E
with Na,SO3
Na,SO,+ otot
C
H,0 +S0 2NaHSO,codseo
V. Reducingproperty-

T
SO2 acts
as a reducing
e.g. 1. 2Fe*
+SO2 +2H,0 agent in the presence
ofmo1isture

H
2Fe
2. 2KMnO4 +S0Ž +4H*
+ 5S02 +2H,0
KSO4 +2MnSO4 la1o alblaaor0

M
Sulphuric
acid (H,SO) +2H2SO4d
a. Preparation:
O.2.H-biceonudglteuneg
It is manufactured
by Contact
process;
in presence
ofcatalyst V205
 h.
Chemical properties Elements of Groups
C+2H,SO 16 17 and 18 (203)

$+ 2H,SO
Co, +24,0+2S0,
3S0,+2H,0
Cu+2H,SO
CuSO,+SO, +
2HX 2H,0
+H,SO,

n
HSO XBr, 1) X, +S0, +
2H,0
cone

o
CH,O ,S0, 12C+11H,0
NaCl+H,SO
KNO,
NaHSO, +HCI
+H,So,KHSo, +HNO, is
Chlorine (C1)
CaF, + H,SO CaSO, +2HF

e s
a. Preparation:

i. By the oxidation of HCl with

MnO +4HC1
MnO

t s
b
MnClh +Cl, +2H,0
ii. By the oxidation of HCI with KMnO4

ii.
2KMnO4 + 16HCI 2KCl+2MnClh +8H,0+5Clh
action of conc. HSO4 on NaCl and MnO2
By the

o u
D
4NaCl+MnO, +4H,SO, 4NaHSO + MnCl, +2H,0 +Cl2
iv. By Deacon's process
o
4HCI+O

1
2Cl2 +2H,0
723K

b.
V.

Chemical properties

0 2
By electrolysis of brine (concentrated NaCl solution)

2
2Al+3C1, 2AICl

P +6Ci, 4PCI

T
+Cl, 2HC
H2
8NH +3Cl 6NH,CI+N

E
(Excess)
brote
Cl Ca(OC), +CaCI, +2H,0

C
2Ca(OH), +2C1
CH,C1+ HCI
CH, +CI,

T
Methylchloride
Methane
Fe,(S0,) +2HC1
2FesO, + H,sO, +Cl

H Interhalogen compounds
Clh+H,O HCI+ HOCI

M Structure
linear
Interhalogencompounds

trigonal
XX's (IF5)
StructureX (ICI) XX'3 (BrF3) Square
XX, (IF)
pentagonal
bipyramidal
bipyramidal pyramidal
(or T-shaped)
 Questions Questions
MHT-CET Exam
(204) Multiple Choice
16

is
MHT-CET 2005
unpaired electrons in sulphur (C)8 (D)1 M
Number of
1. (B)6
(A)2
MHT-CET 2006
2. Apatite is an
ore of
(B) chlorine
(C)bromine (D)iodine

o n
is
(A) fluorine
MHT-CET 2011 not correspond to the orderr Hl<
Hl < HBr < H <HP
<HCI 1
following property does
3. Which of the (B) Reducing power
(A) Themal stability
(C)lonic character
(D)Dipole moment

e s 2

MHT-CET 2012
4Which of the following compound
(A)XeF (B) XeF4
of Xenon does not exists?
(C) XeFs

t s
(D) XeF2

MHT-CET 2013
5. Which is the strongest acid in the following?
(A)HSO4 (B) HCIO3 (C)HCI04

u b (D) HSO3
MHT-CET 2015
6. Electronic configuration of only one P block element
element consists of how many atoms of it?
(A)One (B) Two C)Three
o
D to
is exceptional. One molecule

toD)Four
of s

1
7. Which is the most abundant element
on earth?
,02,

2
(A)Hydrogen (B) Nitrogen (C)Oxygen (D)Silicon
Identify a metalloid from the following

0
list of elements. O-1DHE
(A)Carbon (B) Neon (C) Sodium

2
9. Which halogen forms
(D)Tellurium
an oxyacid that contains
(A)Fluorine the halogen atom in tripositive oxidationSaie
(B) Chlorine (C) Bromine

T
MHT-CET 2016 (D)Iodine
10. The element that

E
does NOT form
(A) Carbon acidic oxide is
(B) Phosphorus

C
11. Which halide magnesium (C)Chlorine
of has highest ionic
(D)Barium
(A) Chloride character?
(B) Bromide

T
12. The most abundant (C)lodide
(A) Neon
noble gas in
atmosphere D)Fluoride
is

H
(B) Argon
13. What is the highest (C) Xenon
oxidation state (D) Krypton
(A)+1 exhibited

M
(B)+3 by group 17 elements?
MHT-CET 2017 (C) +5
14. Whichamong
the following (D)+7
(A)H,O compounds
HS (B) does not
15. Which halogen act as
(A)Fluorine has the highest (C)HSe a reducing agent
value (D)HTe
(B) Chlorine of negative
electron
(C) Brominegainenthalpy
(D)lodine
 Which element among the following
Elements
16.
(A) Argon 0B) Oxygen does NOTform diatomic of Groups 16 17 and 18(205)
(C)Nitrogen molecule
MHT-CET2018 ules?
Tdentify element that forms 8(D)Bromine
17. Carbon amphoteric
(B) Zinc oxide.
(A)
(C) Calcium
MHT-CET 2019
(D) Sulphur

n
umber of sulphur in
oxidation numt
18. The Sg molecule

o(C)6a 2t o w D)3
(A)0 (B)2 is

IF ? 19. The
(A)+4
xidation state of sulphur in HaS207
(B)+6
among the following does
is
(C)+5 OH (
OHA is o
s
20. Which
not form polyhalide (D)+7
(A) Bromine (B) Iodine ion? woH

e
(C)Fluorine
21. Which mixture is sed for respiration (D)Chlorine

s
(A)Kr+O;
by deep sea divers?
(B)
He +O,
(C)Ar+O2 O0H D)Ne +O

t
Amange the following in the increasing
order of their acidic strength.
(A) HBr < Hl< HF < HCl

b
< (B) HCl< HBr <Hl <HF
(C) Hl < HBr HCI< HF
(D) HF <HCI< HBr
<HI

u
23 Which substance is used to
bleach wood pulp into white
(A) H:02 paper?

o
of that (C) Chlorine gas
(B) NaOI
D) H,SO4 /KMnO4

D
24. Which of the following
oxides is amphoteric in nature? oligt ert guoine
(A) Ca0
(B)Na,007 C)AlLO30efE)(D) SO,
doiIE.

1
25. The shape of BrFs molecule
isoeggd aireo
(A)Trigonal bipyramidal
(B) Square planar

2
C)Trigonal pyramidal (D) Square pyramidal

0
26. Which
tate? of the following oxyacid of sulphur contains S =S linkage?
(A)H,S05

2
(B) HS02 (C)HSO3 D)HS04
MHT-CET 2020
uiloH(

T
1, In resonance
hybrid of ozone molecule, O-O bond length is
(A)148 pmn
a)(B)134.5 pm C121 pm (D) 128 pm

E
28. Which
of the following oxyacid of sulphur contain both S-S and S-O bonds?
1

C
A)H,S;03 B)H,S;04
29.
)(C)HS02 (D)H;S;0s(A
0W many lone pair of electrons are present on chlorine atom in chlorus acid?

T
A)3 ()D)1
(B)4 OOC)2
hich of the following
oxyacid of chlorine has highest thermal stability?

H (A)HCIO
31.Chlorine
(B) HCIO 00)(C) HCIO4 (D)HCIO,

M
is manufacture by ebe
(A)Haber process to 2oditUEA
(B) Ostwald's process
C)Deacon
process (D) Contact process
32.Which to 2ocon )
among does not form polyhalide ion'?o
A)CI the followin halogen
(C) Br oRag (D)I a 02
(B)F
 Questions
(206)
MHT-CET Exam bleaching and oxidizing agent2
following is powerful (D) HI
(C)Clh
33. Which among the
(B) SO
(A)PH amphoteric in nature?
following oxides is (D)Clh0
34. Which among
the (C)BO
(B) CaO
(A)SnO mineral of chlorine?

n
following is NOT a (D)Cryolite
35. Which among the (C)Horn silver
(B) Sylvine

o
(A) Carnallite not contain lone pair of elee.
ectron

is
the following
oxyacids of chlorine does onchlor
36. Which of
atom? (C) HOCIo (D) HOCI
(B) HOCIO

s
(A) HOCIO hypochlorous aci
37. How many lone pair of electrons
are present on chlorine atom in cid?

e
(B) 2 (C) 3 D) 1

(A) 4

s
power.
38. Identify correct decreasing order of oxidizing
(A) HCIO> HCI0, > HCI03 (B) HCIO > HCIO >HCIO3dn

t
(C) HCIO> HCIO3> HCIO2 (D) HCI0 > HCIO > HCIO

b
39. What is the oxidation state of chlorine atom in chloric acid?
(A)+1 (B) +5 C)-1 (D) +3
40. Which among the following pairs
XX,? u
of halogen forms the interhalogen compound of the

o
D
(A) Br and F (B) I and CI (C) Cl and F (D) I and F
41. Which among the following is used as an oxidizing
agent to bleach wood pulp into white pae

1
(A)Mn(OH (B) H02 (C) NaOCl (D)C
42. What is the oxidation state chlorine

2
of atom in hypochlorous acid?
(A)-1
(B)+2su2(

0
C)+1 abi (D)+3g
43. What is the oxidation
state of sulphur in oil
of vitriol? lsbi

2
(A)+3
(B)+2
(C)+6
44. Identify the inert gas
used for filling balloons?
D)-3ode

T
(A)Krypton
(B) Helium
45. Which of the following oxyacid (C)Argon

E
D)Neon T0-1
(A) HS.0 of sulphur contain
(B) HS;0s S-O-S linkage?

C
46. Which of the following C) HSO3
noble gas molecules (D) H;S,0
(A) Helium is more
(B) Neon polarized by water?

T
47. Which among (C) Argon 6
the following (D) Krypton
(A) F2 is pale yellow
gas?

H
(B) Br
48. How many lone (C)Ch
pair of electrons
(A) 3 are present (D) 1

M
49. The oxidation (B) 1 on each oxygen
state of chlorine (C) 0 atom in any
any oxy acids of ch
(A) number in its oxyacid
of lone pair electrons (D) 2oOHA
(B) oxidation
state of oxygen on oxygen depends upon
(C) number
of in molecule atom 6
(D) number chlorine atoms per
of oxygen atoms molecule
50. What is the colour per molecule
(A) Yellowish of gaseous
white (B) ozone?
Blue black
(C) Blue
 ndbond angle and hybridization of Sulphur Elements of Groups 16 17 and 18(207)
TheO-S-0
a
sp
119°, (B) 134, sp in SOg molecule is respectively
(A) (C) 105°,sp'd
Highest
negative electron enthalpy in halogens (D) 1170,sp
(B)F is possessed by
(A) C (C)I
dioxide combines (D) Br

n
sulphurur dioxide with chlorine in the atol
Uhen presence of charcoal
formed is catalyst, the product

ron on
chlorine
(A) S,C
C
Colloidal Sulphur

ich of the
follow
(B) SOClh
(D) SO,Clh
oble gases is least soluble
(B) Ar in water?
iso
s
(4)Ne (C) Kr
id? eaeD) He

e
What the ratio of volumes of gases involved
r dioxide and dioxygen respectively
in the preparation
of sulphur trioxide
under similar conditions of temperature from

s
sulph
pressure? and
(B) 2:1:2

t
(A)1:3: 1 (C)1:1:1 (D)
hybridiza
ne of hybridization is observed in interhalogen compounds
1:2:1
56. What type

b
(B) sp of the type XX'3?
(A)sp (C)sp'd (D)sp'd

u
d of the type hich among the following gases is used to produce and sustain
powerful super conducting
magnets for NMR and MRI systems?

o
odgud e (C) Heun noitsbi (D) Ne eonie
(A) Kr (B) Ar

8. Which of the following oxyacid of chlorine is thermally least stable?

D
white paper? (A) HCI0O (B) HCI03 (C) HCI02 (D) HCIO
59. The oxidizing power of oxyacids of chlorine depend upon
oold-q a
(A) number of oxygen atoms per molecule
B)number of chlorine atoms per molecule
C)Oxidation state of oxygen in molecule

2 1 slo emolo loold-qo hoom

0
(D)number of lone pair of electrons on each oxygen atom

the lowest oxidtion state possessed by chlorine in it's oxyacids?s o2aa

2
60. Which is
(A)+1 (B) +5 (C)+3 (D)
-2H1 61. Which among the following catalysts is used in manufacture of sulphuric acid by contact

E
A)Ni
T
process?
(B)Fe with Mo
. The maximum positive oxidation state shown by halogen is
C)MnO (D)V,0ssnod

C ao
xo (D) +3 sinene
(A)+5
(B) +1otabizo t (C)+7
type OX;? (X = halogen)
3 among the following halogens does not form the oxide of
"Ch
T
(A)F
(B) CI (C) Br (D)I muis
chlorine?
of highest oxidation state possessed by chlorine in
its oxyacids?

H
(Athe part (D) +3 ateosald
)+5 (B)+1 130 (C) +7oagti
65.Inthe heating

M
labora rogen chloride is prepared by ont ogu
concentrated sulphuric acid.o0 obovdteom
A)bleaching
(B) powdera and
s dium chloride and concentrated sulphuric acid.
C) bleac
(D) Dotag powder and ammonia
solution.
sulphuric acid.
chlorate and ncentrated A
 Questions
MHT-CETExam SOLUTIONS
(208)
15. (B)
16. (A)
Not
1. (A)
3p
=16
Atomic number of S3s, 3p 17. (B)
16S1s,2s, 2p°, Ca

n
electrons.
It has 2 unpaired Ca
fluorine with calcium.

o
(A) It is an ore of
Zn

is
2.
CaF2.3Ca;(P01)2
Apatite is
18. (A
.
3. (B) in the order as H-X
bond length increases from HR 19. (B

s
Reducing power increases In
HF < HCl< HBr < HI

e
A

XeF2, XeF4 and XeF6. It does not exist as Xe.

s
4. (C)
Xenon forms following fluorides
20. (C

t
5. (C) F
The strength of oxyacids can also
be decided with the help of the oxidation number n ce of

b
atom. Higher the oxidation number of
central atom, more aCidic is the oxyacid. 21.
1

u
25.
H,SO ,HCI0, HC10, H,SO,

o
HCIo, oxidation number of Cl is highest, so HCIO, is the strongest acid amg
Since, in mong

given.

D
o
6. (A)
Helium (He) is a p-block element but its electronic configuration does not follow the arnm

7
atom of it.

(C)
2 1
trend of p-block element electronic configuration. Since it is monoatomic it consists cf
26.

8. D)
mass of earth crust.

Tellurium is metalloid.
2n0
Oxygen is the most abundant of all the elements
on the earth. Oxygen forms about 46.0
a1e (tosibxo biow
(83

T
beat al etavissng gon
9. (B) iollol

E
Fluorine forms oxyacids in +1
oxidation state.
Chlorine forms oxyacids

C
in +1, +3, +5, +7 oxidation
Bromine and lodine forms states.
oxyacids in +5, +7
10. (D)
oxidation state. 27.

T
Barium does not form
acidic
11. (D)
oxide.(

H
Magnesium fluoride
has highest ionic
character.
12. (B) 28.

M
Argon
isthe most abundant noble gas
13. (D) in atmosphere.
The highest oxidation 0 bs 1olwo
14. (A)
state by group
17 elements nog bas ebiroiaabo 0
Except H20, all
is +7,
e.g.e.g. IF,
IF7 oq gtoas0
hydrides of group
16 act as
reducing agent.
 ie

15.(B) lements of Groups

16 17 and 18 (209)
16.0(A) Noble gases are monoatomic.

17.(B)
and S form acidic oxide

n
C

Ca forms basic oxide,

o
Zn forms amphoteric oxide.

HI.
18.(A)
19.(B)
is
s
In the pyroSulphurie acid, all oxygen
Oxygen atoms atom show
attached to S atom, O.S is-2.

e
As 4

O.S of S = +6

s
.

20. (C)

t
F mdo not have vacant d-orbitals,
ber of central hence does not
form polyhalide ion.
21.(B) 22. (D)

b
23. (C)
24. (C)
25.(D)

id among the

o u
snioto

D
F

the nomal

1
sists of one 26. (B)

2
HS02 contains S = S linkage.

46.6% by
(A)
HO-Š-0-Š-OH
(H,S,0)
2 0 (B) HO-Š-OH
(H,S,O,)
cooo

C)

E T HO-Š-OH
(H,SO,)
anoosle 1lo iag
(D) HO1.0.
-

(H,S,0)
- OH

27.D)

C
HT 0%
28.(A)

M Ihiosulphuric

HO
acid, H2S,03
CO

OH
 Exam Questions
(210)MHT-CET
29. (C)
42. (C)
H
Hy
Oxi
Chlorous Acid (HCIO;)

n
30. (C) state of chlorine,
43. (C)
increase in oxidation
Thermal stability increases with Oil
1+ 3+
HCIO<HCIO, <HCIO,
5+
<
7t+

HCIO,

is o44. (B)
45. No

s
31. (C)
i. Haber process NH ii. Ostwald's process HNO H

e
ii. Deacon process Cl iv. Contact process- HSO

s
32. (B)
Due to absence of d-orbital.
33. (C)
34. (A)
SnO Amphoteric, CaO Basic,
b
B,03, Cl%0;> Acidic t Ha

35.0

36. B)
Cryolite is a mineral of fluorine.

o u
D
46. (D
X

1
47. (A
F

37. (C)
:0:
(HOCIO,)

0 2
OH
CI
BI

H C: 2 48. (I

T
3 lone pair Al
of electrons
(Hypochlorous acid) on chlorine atom
49. (
38. (A)
1+
HCIO>HCIO,

CE S+
> HC10,
Oxidizing power
T
m
50. (C

T
of oxyacids of chlorine O
39. (B) decreases as
the oxidation no. of chlorineine reases 51. (A

H HOCIO,
Chloric acid

M
40. (D)
The only known
interhalogen
compound
41. (D) of the type XX,
is IF7. 52.(A
Ne
 www

e
Elements of Groups
Hypochlorus acid> HOCI
16 17 and 18 (211)
Oxidation state of Cl =+1

(
Oil of
vitriol> H,SOb,

o n
is
4.(B)
answer
45. No
HS,O, -Throsulphurous acid

s
H,S,0s-Disulphurous
acid

HO-S-OH HO-S-S-OH

s e
t
0
HS0-Thiosulphuric acid
HSO-Dithionous acid

HO-S -OH HO-S-S-OH

u b
46.(D)
Xenon is the

47. (A)

D o
most polarized noble gas due to its large size.

v-bOH

1
Fluorine (F2) is a
pale yellow highly toxic diatomic gas.
Clh-Yellowish green gas

2
Br-Reddishbrown liquid
h Purple solid
-

48.(D)
Oxyacids of
All

49.(D)
2 0
chlorine HOCI, HCIO2, HCI03, HCIO4
oxygen atoms in each acid have 2 lone pairs.

50.(C)

E T
Ihe oxidation state
molecule. More the
of chlorine in its oxyacid depends upon number of oxygen atoms per
number of electronegative atoms more are the oxidation state of chlorine.

eases.
C
Uzone (Os) is
S1.(A)
pale blue gas with distinctively pungent smell.

HT 1.431A
sp2 hybridisation with 2 bond
pairs and I lone pair

M
119
52.(A)
Negative the following order:
electron n enthalpy decreases in
Cl>F>Br>I
 Questions
MHT-CET Exam
(212)
53. (D) Charcoal
(Catalyst) sO,Clh
Chloride
SO, +Cl Sulphuryl

water and solubility increases from 1 elium t

54. (D) sparingly soluble in Kryps
Noble gases are

Kr>Ar> Ne> He

o n
is
55. (B)
2S0, +0, 2sO,
21:2
s
Ratio:

e
56. (C)
XX'%(T-Shaped) sp'd-hybridized.
O
57.(C)
He gas is used to produce & sustain

t
powerful superconducting magnets for NMR
s & 1

58. (A)
Order of thermal stability of oxyacid of chlorine is,
HCIOHCIO, <HCI0 <HCI04
u b
o
59. (A)
Acid strength of halogen oxoacids increases with the increasing oxidation state of

D
Oxygen atom increases oxidation number of halogen.
60. (A)
besnalo
1
HOCI-Hypochlorus acid
O.S. of Cl=+1
61. (D)
Preparation of H,SO4 by contact
trioxide. In this conversion
0 2
process involves
led wollogolig
conversion of sulphur dioxide to s

2
catalyst V2Os is used.

250+0s V,O2SOu
720 K
250

62. (C)

E T
Halogens have 7 electrons
2 bar

63. (D)
C in their outermost shel

T
OF2,ClhO and Br:O
formed. are
10-Very unstable, cannot

H
be ormed.
64.(C)
oeb wesuld algarcO
M
38
Outer E.C. 3p
of CI

Since Cl has
7 outer electrons
65. (B) it's maximum ALEN
oxidation
H,SO+NaCl state is +7.
K
NaSO, +2HCI
Na,SO,+2HCIeeo
 Transition andInner
Transition
ImportantFormulae Elements
and ShortcutMethods
(d-block elements)
Trans ition elements
pton
I The
.ietion elements
transition
are
elements are placed
in the periods
and 6d series. 4 to 7 and groups
4d, Sd 3 to 12 those constitute

n
3d,

General eledsctronic configuration of four series

o
of d-block elements
Ar] 3d-l0 4s-2

is
3d series: ii. 4d series: (Kr]
4d-10 5-2
Sd series: [Xe]
Sd-106s-2
ii. iv, 6d Series: [Xr] 6d10

s
7s
aofronic configuration of d-block elements:
I systems
Series Elements Symbol Atomic Electronic

s e
t
Number Configuration
3-d Series Scandium Sc 21
[Ar] 3d' 4s

b
Titaniumn Ti 3d 4s
halogen. Vanadium Ar
Ar] 3d' 4s
Chromium
Manganese
Iron
Cr
Mn
Fe 26 u
[Ar) 3d' 4s

o
|[Ar] 3d 4s
L[Ar] 3d° 4s

D
Cobalt Co 27 Ar] 3d' 4s
Nickel Ni 28 Ar] 3d*4s
Copper Cu 29 [Ar] 3d 4s

1
sulphur
| Zinc Zn 30 [Ar] 3d4s*

2
4-d Series Yettreium 39 [Kr) 4d'5s
Zivconium Zr 40 [Kr] 4d 5s

0 5s
Niobium [Kr 4d
Nb
[Kr 4d 5s

2
Molybdenium Mo 42

Tcllueerium Tc [Kr] 4d° 5s

Ruthenium Ru 44 [Kr] 4d' Ss

T Kr] 4d 5s
Rhodium Rh 45
[Kr] 4d 5s

E
46
Palladium Pd [Kr] 4d5s
Ag 47
Silver

C Cadmium Cd 48 (Kr) 4d 5s
5-dSeries Lanthanum La 57 [Xe] 5d'6s
(Xe] 4f 5d 6s

T
72
Hafnium Hf [Xe] 4f" S5d' 6s
Tantalumn Ta Xe] 4f*5d'6s

H Tungston W
|(Xe]4f* 5d 6s
Rhenium Re
76 (Xe] 4f" 6s 5d

M
Osmium Os (Xe] 4r sd 6s
ridium (Xe] 4r 5d 6s
Platinumn Pt
4 5d 6s
Gold Au 9 (Xe] 4f"5d 6s
80 |(Xe]
Mercury Hg
 Questions Atomic Electronic
MHT-CET Exam
(214)
Elements
Symbol Number Configuration
Series 89 [Rn] 6d 7s I1.
Actinium Ac 104 [Rn] 5f 6d 7s
6-dSeries Rutherfordium Rf
[Rn]5f 6d' 7s
Db 105
Dubnium 106 [Rn] 5f" 6d' 7s
Seaborgium Sg [Rn] 5f 6d 7s
107

n
Bh
Bohrium
Hs 108 | [Rn] 5f 6d 7s

o
Hassium 109 [Rn] 5f 6d 7s

is
Mt
Meitnerum
Ds 110 [Rn) 5f 6d 7s
Darmstadtium
Roentgenium Rg
111 [Rn] 5f
6d' 7s

s
112 [Rn] 5f 6d"7s
Copernicium Cn

Trends in properties of the first

transition series:

s e
t
An atomic radius decreases with
increase in atomic number.

b
Having hep, ccp or bec metallic characters.

u
I.E. increases with increase in atomic number.

o
Show variable oxidation states [except first and last member of the series].

Most common oxidation state of the first series is +2 [except Sc].

Most
D
of the metals exhibit paramagnetism (contains unpaired es).

1
They form coloured compounds both in solid as well
in aqueous solution due to d

2
transition (i.e., incomplete d-subshell).
[except Se 3d'), Tif (3d'), Cu'(3d),zn
(3d] are colourless].

2
e.g., Brass is an alloy of Cu
0
They form complexes, interstitial
compounds and alloys.
(60-80%) + Zn (40-20%)
Bronze is an alloy of Cu
(75-90%) +Sn (25-10%)

T
They also act as catalyst.

E
The spin-only formula
for magnetic moment
= yn(n+2) BM is

C
Where, n is the number
Bohr Magneton (BM). of unpaired electrons and

T
moment expr
u is the magnetic mo
Some

H
useful facts :
. Most abundant transition
metal - Fe

M Wonder metal
Ferrous metals-
Zinc metals -
Ti
Fe, Co and
Zn, Cd and
Hg
Ni
Lightest metal

Coinage metals
-

leaviest metals -Os and

-
Se
Ir

andAu
Cu, Ag
Ag
 ansition elements
Trans
Inner (f-block elements) ransition and
Inner transition
elements are placed
placed separately
separ Elements
periods. at the bottom (21)
and 7 of the periodic
inner-transition table. They
i. First series (Lanthanoid are a subset of
series) 6
Name of the Atomie
Symbol
element ldeal Electronie
number

n
Lanthanum Configuratlon Observed Electronie
57
Cerium (Xe" Configuration

o
58
Xe]4f id 68 Xe
Praseodymium Sa'
6

is
d' Xe] 4f
Neodymium
Nd
XeJ4r
60 d 68 Xe] 4F
Promethium Xe] 4
Pm 68
(Xe] 4r Xej 4

s
Samarium 5d
Sm 68 (Xe)4
Europium
(Xe4

e
Eu 5d' 6s2
Xe) 4f
Gadolinium
3 [Xe]
4
Gd 5d 682
Xej 4f

s
4 (Xe]4 6s
Terbium Tb 5d 6s Xe] 4f
Xe]
4 5d 6s
Sd

t
Dysprosium Dy b6 6s(Xe 4
Holmium Ho
Xe] 4f sd' 6s2
(Xe] 4
57

b
Erbium
Xe] 4f0 Sd 6s2 (Xe] 4
Er 68
Xe] 4f
Sd 6s Xe]4f

u
Thulium Tm 59
Ytterbium
Xe] 4f 5d 6s Xe]4f
Yb
Xe] 4f3 sd'6s
o
Lutetium Lu Xe]4f 6s
Xe] 4f sd' 6s Xe]
Trends and Properties of Lanthanoids:
4fsd 6s

d-d Show common stable oxidation state +3.

Regular decrease in atomic
D
1
and ionic radii with increase in atomic number is called
lanthanide contraction.

2
They have low I.E. and high b.p. and m.p.
They form coloured compounds due to f-f transitions

2 0
La(4f), Gd* (4f'), Lu (4f) colourless
Ce(4f) & Yb*" (4f*) -> Colourless despite of having unpaired electrons (exceptions).
Good conductors of heat and electricity

T
'Except Promethium (Pm), all are non-radioactive in naure.
'The Lanthanoids are strongly paramagnetic.
expressedin

CE
All the lanthanoids from hydroxides of the general formula Ln(OH)3.
(Ln represents any element of lanthanoid series).
unce the ionic size decreases from La" to Lu", the basicity of hydroxides decreases.
while, Lu(OH)3 is the weakest
base.

T
s1S the strongest base
i. Second
-transition series (Actinoid series)
inner-tr:

H
Electronie
Name of Atomic Expected Electronic(Observed)
Configuration
Symbolol Number Configuration
Element
7s [Rn]| 6d 7s

M
ad Au Actinium [Rn] 6d
89 [Rn 5f 6d 7s |[Rn]| 5tf6d7sS
Thorium Ac
7s
6d"| 7s |Rn| 5tf6d 7s
Th 0
Protactinium [Rn] 5f
Uranium Pa 91
92 [Rn]
5f6d
5f6d7sRn St6d7s
Neptunium
Np 93 [Rn]5f6d| 7s |[Rn]| 5f6d| 7s
7s*|Rn]|
Plutonium
Pu 94 [Rn] 5f 6d|
 Exam Questions 6d 7s[Rn]|
(216)MHT-CET 95 [Rn] 5f 5f
Am [Rn] 5f 6d 7s[Rn]| 5f6
Americium 96 7s[Rn]| 9. Ce
Curium Cm 97 [Rn] 5f 5f T (A
Berkelium Bk 98
5f
[Rn] 5fO
6d 7s|[Rn]| 5f C
Californium Cf 99 [Rn]| 7s 5fT
[Rn]|
MHT
Einsteinium Es 100 IRn]| 5f 6d 7s [Rn] 5fT
10.1M
Fermium Fm 101 Rn]|
5f 6d' 7s Rn] 5fT

n
(A
Mendelevium Md
102 Rn] 5f6d 7s|[Rn] 5fT
Nobelium No [Rn]| 5f 6d 7s[Rn] 5f MHT

o
103
Lawrencium | Lr

is
and from 92U, the further
elements are synthetice 11. W
All actinides are radioactive, ly prepey (
called transuranic elements.
artificial transmutation hence
12.1
Trends and properties of Actinoids
All actinides show +3 oxidation
state.

e s 13. V

s
They are highly reactive metals
.All the metals are radioactive.
Cm" (5f) and Lr" (5fs) are coloiesci

t
Ac"(5f), MH
.They are generally coloured [except rless)
14.

MHT-CET 2004
Multiple Choice Questions

u b MH

o
15.
1. Oxidation state of iron in Fe;O4 is
(A
D ou6bpro sldeta nowieeo ete
ME

1
MHT-CET 2008 *16.

2
2. Which of the following ions is colourless in solution? Dirtsdins
(A)V3* C)Co2
(B)C (D)Sc

0
3. The general electronic configuration of the transition elements is 17.
n-
2
(A) 1)d", (n +1)s* (B) (n- 1)d'-0, (n+ 1)s2
(C)n- 1)d, np', ns -
(D)(n 1)d-10 ns!-2 MI

T
4. The point of dissimilarity between lanthanides
and actinides is *18.
(A) three outermost shells are partially filled. obiro boo0

E is outoro1
(B) they show oxidation state of
+3 (common). tqpod
(C)they are called inner transition elements.

C
D)they are radioactive in nature.
5. Calamine is
bpibyot abioeineh iA

HT (A)CaCO
MHT-CET 2009
a(B)
6. Most basic hydroxide among
MgCO3 O

the following is
(C) ZnCOs geo(D)CaCO +Ca0
19

M
(A)Lu(OH) (B) Eu(OH)
7. The maximum number (C)Yb(OH)» (D)Ce(OH)» 20
of unpaired electrons is
(A)Fe (B) Cu present in
(C) Co
MHT-CET 2010 D)Ni
8. Which gives +7 oxidation Uindonio 21
(A)Mn(25) state?
(B) Cr(24)
C)Cu(29) (D)Fe(26)
 stable. This is because of ransition and Inner
Ce is
A)half-filled d-orbital transition Elements (217)
empty orbital (B) all paired
(C)
(D)fully filledelectrons in d-orbital
MHT-CET 2011 d-orbital
common Oxidation states shown
10.1Most by cerium are
(A)+2, +4 (B)+3, +4
(C)+3, +5
MHT-CET 2012 (D)+2, +3

11.
Which of the
(A)Mn
follo
owing species shows
(B) Ni2*
the maximum
magnetic moment

o n
is
epared C)Fe
by (D)Ag
12. The oxidation fCr in KCr,0 i
(A)+4 (B) +3
en44
s
(C)+6 (D)+5
Which of the folowing is not an iron
ore?

e
13.
(A) Malachite (B) Haematite
(C) Siderite

s
(D)Limonite
MHT-CET 2013
14 Which of the following lanthanoid ions is diamagnetic?
(Atomicno. of Ce = 58, Sm =62, Eu = 63, Yb = 70)
(A)Ce*
MHT-CET 2014
(B) Sm2 (C)Eu2
201wolio

b t
(D) Yb

15. Select the coloured compound amongst the following.

Cu- 29, Zn = 30)

(A) TICl4
srdmee (8
(B) CrClybyd (d
o
(C) ZnClt 01021(D) u
(Atomic no. of Ti = 22, Cr

(O CuCIb
24,

MHT-CET 2015

D sbixo t
"16. Potassium dichromate is a good oxidizing agent, in acidic medium the
oxidation state of

1
chromium changes by
(A)2 (B) (C)4 D)5 mtt
17. The only radioactive
(A) Gadolinium

0
(B) Holmium
2
element among the lanthanoids is
(C) Promethium D)Neodymium

2
MHT-CET 2016

18. How is sodium chromate converted into sodium dichromate in the manufacture of potassium

T
dichromate from chromite ore? tsollie aonot bes bas
(A)By the action of concentrated sulphuric aigniwollot or geore doi,2g
acido

E
B) By roasting with soda ash
C) By the action of sodium hydroxide

C
(D)By the action of lime stone
19.Identify
o
the metal that forms colourless
O(0
ailove(
compounds. rp-THA cos

T
Chromium (Z = 24)
(A) Iron (Z (B) geos ifoi
(D) Scandium (Z 21)u
26)
rob gao

H
anadium (Z 23)
rogqoO (o
MHT-CET
2018 llol ortgoo .85

M
20.The
most basic hydroxide from following is 62)
(A)Pr(OH) (B) Sm(OH)» (Z-
La(OH)» (Z=57)
C)Ho(OH)3 (Z=
59)
(Z=67)
anos srl Je
lo u(D) their colourless
and copper (Z 29) in
41 Identify (Z 22)
the oxidation states of titanium (D)Ti", Cu
Compounds. Cu
A)TP", (C) T, i240
Cu B) TI", Cu
 Exam Questions
(218)MHT-CET respectively is
dichromate 1on 40
MHT-CET 2019 ion and
ionic charges on chromate (C)-2,-4 potassisum
D)-4,-2
The
*22. (B)-3,-2
(A)-2,-2 potassium hydroxide and chlorate
manganese dioxide, is
mixture of
23. When a obtained is (C)K2Mn04 D)K2SO4 fu
the product (B)KMnO permanganate 1on are respectively
(A)KMnO manganate and 41
*24. The ionic charges of (C)-1,-1 (D)-2,-2
(A)-1,-2
25. Select the ion which
(B)-2,-1
hasmaximum effective magnetic
(B)V"(Z23)
moment
(C)Cu(Z-29) (D)Fe"(Z-26)

o n
is
(A)Mn "(Z=25) transition series?
following elements belongs to the first inner
26. Which of the (C)Protactinium (D) Promethium
(B) Americium

s
(A)Curium
ionization enthalpy?
27. Which of the following
elements has highest second

e
(C) Co-2 (D) Fe-26)
(A) Cu-29) (B) Zn-30)

28. Which among the following elements

(A) Tm(Z= 69) (B)Ho(Z= 67)
has completely filled 4f subshel1?
C)Yb(Z = 70)

t
following substances is used as a catalyst for thermal
s
(D)Gd(Z=64)
decompos
position
4

b
29.Which among the
potassium chlorate?

u
(A) MnO; (B) CuClh (C) Fe (D) V,0s

30. Cobalt- Thorium alloy is used as catalyst in the process of mo beioloo ori pols
(A) manufacture of H,SO4
) decomposition of KC10, to Og

31. The highest oxidation state in plutonium (At. No

D o
(B) synthesis of gasoline
(D) hydrogenation of oils
= 94) is
ea
20 TU0-9

1
(A)+7
eho (B)+6 (C)+5gg (D)+4i
*32. Limestone is used as a flux in the extraction

2
of
(A)Zinc (B) Iron C)Copper D)Aluminium

0
33. Which of the following is NOT the mineral of iron?
(A)Magnetite (B) Limonite

2
(C) Haematite (D) Corundum
34. Identify the pair of flux and the slag respectively in
the extraction process of iron.
(A)Lime stone and calcium silicate
e
T
(B) Calcium silicate and lime stone
(C) Sand and ferrous silicate
35. Which among the following is an (D)Ferrous silicate and sand

E
ore of iron? te b
(A)FeS2 (B) Fe20
(C)FeCO3esaboe (D) Fe,O4 i
C
36. The mineral of iron is
(A) Limonite (B) Cryolite
(C) Calamine oml
MHT-CET 2020 (D) Epsum salt

HT 37. Which among the following

(A) Scandium
elements has lowest
(B) Cobalt
38. Which among the following
density and is lightest?
(C)Copper
elements is a soft
(D) Iron

M
(A)Zn (B) Mo element as compared
(C)W to others
39. Which among the following bizo Co ofn
by blast furnace? reactions Occurs extraction
at the zone
luoloe(A) of slag formation l
Co
(C) CaO+SiO
CO (
(8) Fe,O, +3C
2Fe+3COo
bt
CaSiO,
(D) Fe,O,+3CO 2Fe+3CO2
 correct statement ransition and
Identit from following.
40. ids have greater tendency
Lantnacontraction
Inner transition
Elements(219)
Actionoid contraction is
is greater
to form complexes
B) than lanthanoid than
rate is )Binding
energy of
4f orbitals is lower contraction.actinoids.
fused, D)Hydroxides of tinoids are less than
basic than 5f-orbitals.
a nosition of elements
Lathanoid
hydroxides.
41.
What La (Z = 57) and
table? Ce (Z- 58)

n
periodic respectively
(A)La Group-4,
Period-7 in the long form of

o
Ce-Group-5, Period-7 (B)La-Group-3,
Period-6

is
Ce-Group-3, Period-6
C)La-Group-3, Period-7 (D)La- Group-3, Period-6
Ce-Group-3, Period-6

s
lement from followingforms colourless Ce Group-3, Period-7
compounds in +2
(A)Zn(Z 30) (B)Cu(Z 29)

e
oxidation state7
(C)Mn(Z - 25)
(D)Co(Z- 27)

s
which among following processes
occurs at 1500 K in
43 blast furnace for
(A)Slag formation (B) Combustion of coke extraction of iron?

t
(C)Reduction ore
position of D)Ore loses moisture
of

b
4Which among the following lanthanoids has smallest atomic
size?
(A)Pm (B)Ce

u
C)Sm D)Pr
5. What is the formula of calamine?

o
MgCOs, CaCOs (B) Fe2O3
(A)

0C)ZnCO D)FeCO

D
46. Identify
correct decreasing order of ionic radii of lanthanoids.
(A)Sm> Gd> Ce> Pm (B)Ce> Pm> Sm> Gd

1
C)Pm> Sm> Ce> Gd
cosu (D)Gd> Pm> Ce> Sm
47. Which of the following elements exhibits oxidation states other than +3?
(A)Gd hdto(B) La

0 2 (C)Ce
48. What is the role of tuyers used in blast furnace for extraction
(A)To blowa blast of preheated air in to the furnace
(D)Lu
of iron?

2
B)It enables the even distribution of charge.
C)It is used to remove molten slag and iron.

T
D)It prevents loss of hot gases

E
49. What is the
formula of pyrolusite ore?
(A)MnO (C)CuO (D) Cr-O
(B) PbCrO4

C50 hi in the blast furnace for extraction of iron?

C reaction from following occurs at 2000 K
(A)CaCOs>CaO (B) CaO+ SiO > CaSio
+CO2bino 2Fe+3CO

T (C)2C+O2 2C0 (D)Fe203+3C0

1. form its oxide?
rom following elements has lowest tendency to

H
(D) Cr
(A) AL (C) Hg
(B) Fe is used as reactant in next
step for
52.Which first step and
of the following is a product of

M iron manufacture
K2Cr20, from concentrated chromite ore sulphate
n of (A) Sodium of (B) Sodium chromate
dichromate Potassium
(C) Sodium
53.What
chromate ued(D) found in t3 oxidation state of
Chromium
moment
is th of effective magnetic
(Z 24)?
(A) 1.73
Value (C)2.84 BM
(D) 3.87 BM
BM (B) 4.90 BM
 MHT-CET Exam
Questions +3 oxidation state9
(220) lanthanoids, shows only (D) Neodymium
among the
following
Gadolinium (C) Terbium
Which 71.
54.
(A) Cerium
(B)
enthalpy of atomization from followino g
highest (Z=21) (D) Zn (Z-30)
element having C) Sc
55. Identify the (B) Fe (Z = 26)
(A) Cu (Z= 29) transition series?

n
elements belongs to first inner V
Which the following (C)Bk (D)Pr 72.
of

o
56.
(B) Fm

is
(A)Pu oxidation state?
exhibits only +3
following actinoids (Z=92) (D)Pa (Z= 91) 73.1
57. Which of the
90) (B)Lr (Z= 103) (C)U
(A)Th (Z- among allo
exhibited by any transition element

s
oxidation state
58. What is thehighest
C)+7 D)+5 74

e
(A)+8 (B) +6
exhibited by actinoids?

s
state
59. What is the highest oxidation
(A)+6 (B)+3 (C)+4 o(E(D) +7 15.

t
four S = O bonds?
60. Which of the following oxyacids of sulphur contain

b
(B) HS04 (C)HS06 (D)H2SOs 76.
(A)H;SO4
of densities of d-block elements.

u
61. Identify the correct decreasing order
(A)Ni> Fe> Cr>Vse 3mole (B)Cr> Fe>V> Nio al *77.
(C)Fe> Ni> V> Cr
62. Which among the following sets
(A)AI, O (B) Fe, S

D o
(D)V>Cr> Fe > Ni
of elements is present in chalcopyrite?
(C) Cu, Fe, S (D)AI, Fe, O
*78

1
63. Which among the following elements is radioactive?lno geieneroob toomoe vitns
(A) Eu (B) Nd (C) Pm D)Lu
(A)Cd B)Co

0
65. Which among the following elements 2
64. Identify the element if it's expected electronic configuration
bt
is [Ar]
(C) Znetrormols zn (D)Hg
3d"4s. 79.

2
possesses one electron in 4s orbital in observed elecam 80.
configuration?
(A)Cu(Z = 29) (B)Ni(Z=28)
o (D)Mn(Z=25)
T
(C)V(Z=23)
66. Identify the mineral iron
of from following.

E
(A) Magnesite (B) Calamine
C) Siderite Willemite *81.
67. Which cation from following sodaD)

C
does NOT form
(Atomic number colourless compound?
Cu= 29, Ti = 22, Zn =
(A) Ti 30, Sc = 21)
(B) Cu
(

T
(C) Sc3* 82.
68. Which mineral among
following contains (D) Zn
(A) Willemite
(B) Malachite zinc? atwollot oo
H
69. Which among the (C)Corundum 83.
(A) Pu
following actinoids D) Azurite
exhibits highest
70.Which element )B)Lr
oxidation state +7?

M among to(C) Cf
oxidation state? the following
exhibits electronic ((D) Th
in
(A) Dysprosium configurationa Xej4t o
(C)Neodymium (Z 66) boe i (B) Praseodymium 9Tutots
84
(Z60)aeet(c(D) Cerium (Z 59)
(Z=58) 85
 among 1g the followino
following pairs ransition and Inner
m Which
1. value ofeffective magnetic moment? of clements in their transition Elements
(221)
nber: Sc=21, respective oxidation
(Ator Ti= 22, Cr-24, Co states will have same
) and Cr* (B) Ni and Ti 27,Ni
(C) Sc" and-28,
(A) Zn Zn-30)
Which ofthe following compound is used
T
(D) Cr and Co
72 (B) FeCO as an ore of iron?

n
(A) FeO4
is generally employed for ores
t (C) Fe,O, (D) 2Fe,O, 3H,O

o
Roa
3. containing

is
(A) Oxide (B) carbonates
(C) nitrates
ch of the following elements possesses
one
t D) sulphides
electronic configuration? unpaired electron in 5d orbital

s
in observed
(A) Eu (Z=63) (B) Gd (Z-64)
(C) Nd(Z=60)

e
(D) Yb (Z=70)
Which among the following elements belongs to
second

s
(A) Nd (B) Er inner transition series?
(C) Np
Which among the following hydroxides is most ionic in
o m(D) Lu

t
(A) Eu(OH) (B) Ce(OH nature?
(C) Lu(OH
(D) La(OH)s
77 which zone of blast furnace used to extract iron, reduces MnO2
(A)Zone of reduction
(C) Zone of slag formation

u b
(B) Zone of combustion
(D) Zone of fusion
and Ca (POs)z to Mn and P?

o
78. Which zone of blast furnace in extraction of iron works
out the following reaction?
Fe,O, +3CO 2Fe+3CO,

D
(A) Zone of reduction (B) Zone of slag formation
C) Zone of combustion eg (D) Zone of fusion ot odh to ce
oi

1
79. Identify the soft element from following.
(A) W (B) Cr s g gpivrollol o(D) Cd

2
(C) Mo
80. Which
d electronic element among the following has highest number of unpaired electrons in observed

0
electronic configuration?
(B) Copper (Z = 29)olor ott to doid2e

2
(A) Scandium (Z 21)
C) Titanium (Z 22) (D) Chromium (Z 24)
soll dio136
es cA

T
OLWhich among the following hydrides have low bond dissociation energy of M-H bond
(M=Central atom)?

E
(A)H;0 (B) H:Se (C)HS (D)HT
. Which among
the following elements belongs to second inner transition series?
02
C
(A) Sm (D)Lu
(B) Am (C) Dy 0
Which of the following properties is NOT of actinoids? gmvoil

in + 4

HT
4.
hese have reater tendency to form complexes.
nding energy of 5f orbitals is lower than 4f orbitals.
ydroxides
(D)Some of of theseare
more basic in nature
the ions of these are fairly coloured.
than lanthanoids.
toaoieup

electronic configuration

M
Which ?
element mong the following has empty 5d-orbital in observed
(A) Lu (D) Gd (Z-64)
(Z= 71) (B) La (Z=57) C) Yb (Z=70)
5 W'hichamor lanthanoid? 0S
A) Smong the following elements is NOT a (D) Pu
Pr
(B)Cee3i)C)
 formati.
MHT-CET Exam
Questions
occurs at zone of slag ation in
the
(222) following reactions prote
among the furnace?
*86. Which by blast (B)C*,02>co
iron
extraction of 1. (A
4Ca AlO; + 30
(A)
12CaO+2A1,0;
(D)2C002+2Cote
2Fe + 3CO; lanthanoids?
(C)FeO +3C0 is NOT of

n
properties
*87. Which of the
following 2. (
orbitals is higher.
(A)Binding energy of 4f electron enters in 4f-orbitals.

o
differentiating

is
(B) In these form oxOcations. prepared in laborato
atory
(C)These elements can't these do not occur in nature but
(D)Most of the elements of
NOT form oxocation?

s
following elements does
88. Which among the (C) Pu D)Np

e
(B) Lu
(A)U compounds?
following forms colourless

s
89. Which cation from
24, Ni = 28, Fe = 26) olled o(D) CP*
(Atomic No.: Ti = 22, Cr= (C) Ni2

t
T (B) Fes
(A)
elements exhibits oxidation states
from +1 to + 6?

b
90. Which from following D) Cu (Z=29) 3.
(B) Cr (Z-24) (C) Fe (Z 26)
=
(A) Mn (Z=25)

91. Which of the following metals reacts

(A)u (B)Hg
92. What is the melting point of zinc?
with dilute H,SO4?
(C) Fe

o u D)Bi

D
(A)473 K (B)692 K (C) 423 K D)1193 K
observed electronic configurnti 5.
93. Which of the following elements has six unpaired electrons in
(A)Cu (Z= 29) (B) Cr (Z= 24)
*94. Which among the following pairs
(A)4.0 % C, hard and brittle
2 1(C) Mn (Z = 25) D)Fe (Z-26)
of percentage of carbon and the property of cast iron is t
(B) Less than 0.2 % C, very soft
6.

(C)0.2 to 2.0% C, very soft

2 0 (D)0.2 to 2.0 % C, forms steel alloy

95. Which of the following methods is used for concentration of iron ore?
(A) Washing in current of water
ibus2
Simttnef

T
(B) Froth floatation
(C) Dissolving the ore in water solution of NaOH
or Na,CO3iot st noe
of

E
D) Electromagnetic separation 7.
*96. What is the temperature needed exta:

C
for decomposition of lime stone in blast (Or
of iron? furnac
(A) 2000 K (B) 1200K
(C)500 K (D) 1500 K

T
*97. Which among the following firon
changes occurs at
(A)Limestone decomposes 900K in blast furnace for exura n

H
C)Reduction of ore by (B) Reduction of ore by C
CO
98. Identify the formula (D)Ore loses moisture yab
of lanthanoid

M
(A) Ln2O oxide formed when
(B) LnO lanthanoid (Ln) is burn
99. Which element among the (C)Ln,O (D) LnO
following exhibits
state? electronic configuration as
(A) Neodymium
(Z= 60)
(C)Praseodymium
(Z= 59)
bet (B) Terbium (Z= 65)
(D) Cerium (Z 58)
he process Transition
and Inner transition
SOLUTIONS Elements (Zz0)
of
(A) oxidation number
1. Let x be the
of Fe in Fes04.
Therefore,
3x +4 x-2) = 0
or 3x 8 in Fe,O
or x=
(D) 3

n
V23) [Ar] 3d', 4s
=[Ar] 3d, 4s0

o
(two unpaired
Cr24) [Ar] 3d', 4s electrons)
C [Ar] 3d,

is
4s (three unpaired
Co(27) 3d, [Ar] 4s2 electrons)
Co [Ar] 3d', 4s

s
(three unpaired
Sc(21)= [Ar] 3d', 4s2 electrons)

e
Se
huis.
Ar]
3d", 4s
(no unpaired electrons)
Thus in Sc no unpaired d-electron

s
is present. Hence,
colourless 10n. no d-d transition
is possible and it is

t
(D)
29) 3. Generally, d-block elements are called

b
d-subshell. Thus, their transition elements as
general electronic configuration they contain inner partially
is
filled
1)d-0, ns2

u
(n -

4 (D)
Lanthanides and actinides
both are not radioactive. Except

o
radioactive while all actinides promethium, all lanthanides are
are radioactive. non-
. C)

D
nfiguration?
6) Calamine is the carbonate ore of zinc (ZnCO).
6. (D)

1
on is true?
Due to lanthanide contraction, the size of M" ions
(i.e., Lu", Eu", Yb*" and Ce) decreases

2
and thus, the basic
strength of their hydroxides decreases.
The order of size
of given M ions is

0
Ce>Eu*>Yb* > Lu"
The order of basic strength of hydroxides is

2
Ce(OH); > Eu(OH)3> Yb (OH)3> Lu(OH)3
1. (A)
eotab
aFe[Ar)
T
rextraction 3d4s2

firon?
29Cu=[Ar]
CE 4 unpaired electrons

3d4s (one unpaired electron)

A)E

T
Co [Ar] 3d'4s2
gen.
1111 1 11
4
oxidation
H sNi=[Ar) 3
3d 4s
unpaired electrons

M 2
1unpaired11|1
ece
boio
b 2
(aoaelo boisgr
 Exam Questions
(224)MHT-CET (Unne 63
+ (n-1)delectrons npaired)
8. (A) state ns electron
d-block elements, oxidation 70
For = [Ar] 3d'
4s
(a) Mn(25)
5+23d 74s'

n
O.S.
(b) Cr(24)
[Ar) 15. (B)
5+1 = 6

o
O.S
[Ar] 3d4s

is
(c)Cu(29)
O.S. 0+1=1
[Ar] 3d° 4s
241
(d) Fe (25)
+2 and +3 among the given elements (T
s
O.S.
exhibits + 7 oxidation state
Thus, only Mn
. (C)
The electronic
Cess
configuration of Ce is
Xe] 4f Sd" 6s
(observed)

s e
t
Ce= (Xe] 4f sa" 6s are empty and Ce gains th
all 4f, 5d and 6s orbitals the
sta
Since, in +4 oxidation state,

b
inert gas. Hence, Ce is most stable.
configuration of nearest (A
Si
10. (B)
The electronic configuration of
Ce is as Ce: [Xe] 4f*sd'6s
The most common oxidation states shown by

o
cerium are +3 and +4.
u 16. B
P
d

D
11. (C) bf
No. of unpaired Magnetic moment
No.
Outer-most
S. lon
configuration electrons H=yn(n+2) BM

1
D
(a) Mn [Ar]3d 1.73

2
b) Ni [Ar] 3d 2.83 17. (C
(c)Fe |[Ar] 3dP 5.91

0
d)Ag [Kr] 4d 18. (
Thus, Fe will show maximum magnetic moment.

2
S
12. (C)
KCr:O

T
Let the oxidation state of Cr is x. 19.
=
2(+1)+2x+7-2) 0 O

E
=
+2+2x- 14 0
2x 12 0

C
x=+6
20.0
L
13. (A) 21.(

T
Sr. No. Ore Formula
(a) Malachite CuCO.Cu(OH)

H
(b) Haematitee
(C) Siderite
Fe:0
FeCO C
(d) Limonite | 2Fe,03.3H,O

M
Thus, malachite is not an ore of iron.
14. (D) bi
Lanthanoid ion with 22.
no unpaired electron
ssCe is diamagnetic
Ce
Xe]4f 5d 6s in nature. C
4f
(2 unpaired
62Sm Xe] 4f° sd 6s electrons)
Sm =
4f
(6 unpaired
electrons)
 Xe] 4f sd 6s? ransition and
Inner transition
63Eu 4f Elements
Eu (7 unpaired (22)
[Xe] 4r6s electrons)
Yb
Yb
4ft4
No unpaired ODHO OnMt
electron
hencediamagnetic
(6
(B) [Ar] 3d 4s Ti-[Ar] 3d 4
Ti unpaired electron)

n
(No
C
Ar] 3d 4s CP-[Ar] 3d

(Three unpaired
Zn=[Ar]3d 4s2
11
electrons)
Zn Ar) 3d0
is o
(All electrons paired)
Qu=[Ar] 3d4s Cu' [Ar] 3d

e s
s
ns the
stable
1 1 10 1 11

t
(All electrons paired)
Cr ion has 3 unpaired electrons, therefore its

b
Since
salt, i.e. CrCl, will be coloured.
16.(B)

u
Potassium dichromate 1s good oxidising agent in acidic
medium. In this process potassium
dichromate (OXidation number

o
of Cr=+6) is reduced to chromium sulphate (oxidation number
ofCr=+3)
Cr,0+14H* +6e 2C+7H,0
Dichromate i1on

D
gain six electrons and hence act as an oxidising agent.

1
17.(C)
Only Promethium is radioactive.
.(A)
Sodium chromate

0
conc. H,SO4
2
Sodium dichromate
2Na,CrO4 +H,SO (conc.) > Na^CrO, +Na,SO4 +H,0mtoluoloz
ncrzo

19.(D)

2
options chromium, vanadium and scandium
are d-block elements which form

T
ut of given
coloured compounds. Iron forms colourless compound.
20.0

CE
Ln(OH): Basic strength decreases from La(OH)s to Lu(OH).
21.(C)

HT aTi1s
C1s
Cu
fno
22p 3s'3p 4s3d
1s2s'2p°3s*3p°4s'3d'
2s'2p 3s3p 4s'3d
ls 2s 2p°3s3p°4s°3d (No
(No unpaired electron

aired
orbital
in d orbital)

electron in d orbital)
of the transition
metal or ion then its
(O)
solution

M
electron is present in d
Decomes cdcolourless.
12.(A) ()1e
Chromate
ion CrO , Dichromateion C,0
 Exam Questions
(226)MHT-CET
23. (C) >3K2MnO4 +KC+3H,O
3MnO2 +6KOH
+KClO 52. (C)
1.

24. (B) Permanganate ion MnOg

Manganate ion MnO,

n
28. (C) 29. (A) 30.(B)
27. (A)
25. (D) 26. (D) ii.

31. (A)
Pu exhibits +7 oxidation

32. (B)
state.

iso ii.
33. (D)
Corundum is crystallized alumina while all others
are mineral of iron. A

e s
s
34. (A) 103 t0ools ilA 53. (D
C

t
35. (B)
Fe203 (Haematite) is an ore of iron.
36. (A)
Limonite 2Fe,0g 3H,0

u b (bozing anoosls
54. (E
G
T

o
37. (A) (8A
In 3d-series elements, across the series density and mass increases from Sc to The
Zn. 55. E

D
Scandium has lowest density and is lightest.
th
38. (A)

1
All transition elements (with the exception of Zn, Cd and Hg) are very hard. 56.
. Here, Zn is a soft element as compared P
to others.
39. (C)
42. (A)
Zn 3d
40. (B)

0 2
41. (B)
9vitoscibt at moidiounofd
57. 1

2
(No unpaired d-electron)
Zn forms colourless compounds in +2
oxidation
bo204i buos
enodo pbe 58.
state.oc0)02 8+00 60.

T
43. (A)
44. (C)

45. (C) E
Atomic siZe decreases across the series
Ce> Pr> Pm> Sm

C
from left to right 07l 2bogo0 t

T
46. (B)
Along the lanthanoid series,
there is a decrease

H
47. (C) in ionic radii.
Ce Xe]4f sd° 6s?
3tsl stag o
M
Ce exhibits +4 oxidation
state.
48. (A) 49.(A)
50.(C)
51. (C)
61.(
201
0
 ransition andInner
(C)Convers transition Elements
of chromite«ore into sodium (220
chromate
4FeCrO, 8Na,CO, 70,
2Fe,0,+8C0, +8Na,CrO.
Chromite ore
rsion of sodium chromate into
usotovo
Sodium chromate
2Na,CrO, +H,SO
sodium dichromate attort
Na,Cr,0, +Na,SO,

n
Sodium chromate Sodium dichromate
+B,ObehA
anversion of sodium dichromate to
Na,Cr0,
Sod. dichromate
+2KC1-
potassium dichromate
K,CrO,
Pot. dichromate
+2NaCl
is o
3.(D)
3d (3 unpaired electrons)
ti oousole ao

e s
s
C

n(n +2) 33+2) 3.87 BM

54..(B)
Gadolinium(Xe] 4f 5d'6s?
The extra stability of

b
Gd ion is due to their half-filled f-subshells. t -olimebie
herefore, 55.(B)
The greater number of unpaired electrons, greater is
the enthalpy of atomization.

o u otSomoll
interatomic interaction and greater will be

D)

D
56.
Pr belongs to first inner transition series, i.e. Lanthanoids
series elements.

1
57.(B)
Lr(Z [Rn] 5f4 6d' 7s2

2
103) =
Due to completely filled 5f- orbital, Lr exhibits only +3 oxidation state.
o T

0
58.(A)
59. (D)

2
60.(C)

T
)
D)uD00s0-sidasisM
HO-S-OH

E
(ii) HO-S-S-OH

C
(H,SO,) (H,S,O,)

T
H.
ii) HO-S-S-OH

O 0
(iv) HO-0-$-OH o aeoge

M
dbos
(H,S,O,) (H,SO,)(00)
61.(A)HSO6contain four S O bonds

the 3d- series, density of the elements increases.

Oss
Ni> Fe>
Cr>V
 (228) MHT-CET Exam
uuesuune

62. (C)
Chalcopyrite CuFeS2 onoinsn
63. (C)
980
lanthanide.
Promethium (Pm) is the only radioactive
64. (C)
[Ar]3d4sZ=30 (Zn)
65. (A)
3s 3p°4s' 3d0

o n
is
(A) Cu(Z = 29) 1s 2s 2p
(B) Ni(Z = 28) = Is 2s 2p° 3s 3p°4s 3d
(C)V(Z 23) = 1s* 2s? 2p 3s 3p° 4s 3d utib.boe

s
=
(D) Mn(Z = 25)- 1s 2s 2p° 3s 3p° 4s* 3d

66. (C) M& 2. e

Cu(Z -29) possesses one electron in 4s orbital in observed electronic confieas.

s
ration

t
Magnesite - MgCO3
Calamine- ZnCO
Siderite FeCO3
lsitdue-1 bollit-pd niod os oub 2itot
Willemite-Zn2SiO4

u b o
bi vilidety s

o
67. (A)
Ti3 7

D
=4s 3d
Cu 4s 3dl0

1
Sc3 4s 3d

2
Zn2*
=4s 3d10

0
Ti forms colored compounds as
it has unpaired
electrons.
74

toigeaeg

2
68. (A)
Willemite- ZnSi04 (C)ee
7

T
Malachite- CuCO, Cu(OH),

E
Corundum- Al203
O-2-OH
76

C
Azurite-2CuCO, Cu(OH)
69. (A)

T
Highest oxidation state
of +7 is exhibited
70. (D) by Pu and Np.

H i. Dysprosium (66) DXe] 4f°6s?

M
78.
ii. Praseodymium
(59) =[Xe] 4f 6s? 0
ii. Neodymium (60)
[Xe] 4f 6s?
iv. Cerium (58)-[Xe]
4f sd' 6s 79.
Cerium exhibits
+4 oxidation
state with
configuration
4f.
 ansition and Inner
11.(D) transition Elements
Contiguration (229)
No. ofunpaired
3d electrons
Se-4s
Cr-4s°3d |L1
3
T-4s°3d'

o n
N-4s 3d RVViono2 0d o
is
Co-48 3' 1 11 1 3

e s (d).c9

s
Caecies having same number of unpaired electrons
have same dipole moment

t
C&Co have 3 unpaired electrons. bouoloo ghiat oo seorh
1o anoi odt to oreo

b
yn(n+2) = V15 =3.9

72. (C)
Haematite is an ore of iron: Fe203

o ao be
uX

D
3. (D)
Roasting is carried out for sulphide ores which on heating in presence of excess of air releases

1
gases like SO2 etc. from the ore. bionlas2i (6e S oui9 ut
74.(B) (B).08
It has one

0 2
Gadolinium: Gd (6u): Xe4f sd' 6s gale usiom iamot
unpaired electron in d orbital.
OlAD
or 3ugnng ddi
Oiee0
zonidoo

O
OACOsDSt
Or

OO

2
75. (C)

Neptunium= Np(93) = [Rn] 5f *6d' 7s belongs to 5f series. C).78

orft to taoM
1350 20r ob 92303 to elnorrelo

T
76. (D)
bo18qorg d
dsl at stst is more ionic in nature.
LOH)s is the most basic of given hydroxides. It (8)28

E sis
200b (ul)
7.(D) abiomsdinsl on 9a19ed nots3oxo mol vot

C
blast furnace
In
zone of fusion: 800° 1200°C
MnO,
+2C Mn+2CO

HT T8.(A)
4,(PO,)
Sio,+C
3CaO+ P,0,
Si+CO,
Diuoqo0 tesluolo2
ammot it.nodoolo boinqu on and T soni2

M
Lone of
reduction or top zonc
re,O,+3Co 3K 2Fe+3CO
19.(D)
Aetals
like Ag Cd, In, Auetc. are soft in nature.
o asd 10 soti2
laonimaltoni anotonla
pbizo wode
nos ote
 Exam Questions
(230)MHT-CET electrons
80. (D)
No. of unpaired 91. (C)
Fe+
4s2
21Sc [Ar]3d' 2
=[Ar]3d2 4s2
22 Ti 92. (B)
4s Melt
24 Cr [Ar]3d'
4s'

n
29
Cu =[Ar]3d0 93. (B)
24Cr
e

o
H and Te is not much
81. (D) the bond between
itrm
is
electronegative, 94. (A)
Since Te is less Cast
dissociate.
low energy to
electronegativity is as follows:
Order of increase in 95. (A)

82. (B)
Te< Se< S<0

second inner transition series.

e s Was
awa

s
Americium (Am) belongs to 96. (B)

t
83. (D) C
Some of the ions of these are
fairly coloured. Lim

b
All actinides are coloured ions. Thi

u
84. (C) 97. (C)
E.C. of 71Lu = [Xe] 4f"sd'6s In z

o
E.C. of s7La =[Xe] 4f'5d'6s
E.C. of 7oYb = [Xe] 4f sd'6s

D
E.C. of sGd =[Xe]4f' sd'6s 98. (A)
85. (D) oidwo sbideiua not tpo bormso, 21 gecenol

1
Pu (Plutonium, Z = 94) is actinoid.

2
86. (A) 99. (B)
Ca0 combines with gangue to form molten slag of calcium silicate and calcium alumina
E.C

0
CaO+SiO, CaSiO, o
b ai mozools
4CaA103 +30O2

2
12Ca0+2Al,03
87. (D)
Most of the elements of these do not occur in nature but prepared in laboratory.
88. (B)

E T
Lutetium (Lu) does not form oxocation, because
no lanthanoids form oxocations.
muit tanld al

C
89. (A) 00S 008
2Ti[Ar] O0+M -20-0a

T
26 Fe Ar] 3d
0.9-0Of
aNi"[Ar] 3d"
00+1
H
Since Ti has no unpaired electron,
it forms colourless compound.
90. (B)

M 2aCr [Ar)
4s

Since Cr has 6 electrons

3d5

O0000D
in outermost
shell, it can show oxidation states +1 to +ó.
sta
 Transition
1. (0) and Inner
Fe+H,SO FeSO, +H, t noitenibnoo0.0 transition Elements
(231)
(dilute)

92(B)

n
Melting point of Zn = 419.5°C =
692.5 K

o
84,B)22s 2p° 3s 3p°

is
4s' 3d
equires
eh G
arhoo boo/
contains 4.0 % carbon

s
Cast iron and it is hard and
brittle.

e
9%(A)
g in current of water Odinun obanibro

s
is gravity
with current of water concentration
and heavier (ore) method,
particles collected where lighter particles washea

t
96.(B) at the bottom. o
Oftz HO
19)bneubono

b
CaCO CaO +CO
1200 K (oto
Limestone Quick limme ) otobre (u
occurs in zone of slag formation

u
(reib) s3lobieT0
This

o
97.(C) (aoi ateobsmeTo
In zone of reduction the temperature is (ATd) ostsibgoH(
around 900 K.

D
Fe,0, +3C0 2Fe +3CO, 29alqno lo 29qp
HA (0)coreiqmos oitgslormoli (A)
98.(A)
Ln

4Ln+30
forms

2Ln03
2 1 2925lqero9 oi geloosi (E)
Ln" ions; they form Ln2O3 when it burnt in oxygen.

0
.(B) Y PAB
E.C. of 6sTb
Jatstn io 29dimor ofrmolAS.2rd

2
=[Xe] 4f 6s tmol os les vd 1201 enou alo he 290(g
Tb4 = [Xe] 4f 6s
s vafotinobhenemsis toocied=y

T
:29NoRuu) ti egi90el
aoroaiosnote(A
OO0O0

CE soioroar mot6uns 0teemoatleusouie ()

T
ioat.aoiionib1002
0graco vloe)

H yolgno0 ni anibno
Dood sonslaV ()
(ne oel

M d
ol ert o1eborteesos os2tioro
bpethrd gnot00qD
(i079/grnog sl
geb

(A)
bear Ition lo aaro b
 w
i

3rono bre roe

2S)
Coordination Compounds T
n
9. SP
Formulae and Shortcut Methods Sp

.A
Important
co-ordination compound or a complex
consists ofa metal atom or 1on surroundedh
by co-ordinate bonds, e.g.
[Cu(NHs)4]SO,
is o Sp

s
molecules or anions called ligands bonded
or ion in the complex has primary valence.

e
According to Werner's theory, metal atom

s
sphere) and secondary valence (inner sphere). AP
s
The number of (monodentate) ligands directly bonded th

t
.Co-ordination number (CN): 11

central metal atom or ion by co-ordination bonds is co-ordination

number (CN). A) 20 iii.

b
b V.
Ligands:olod s
Monodentate ligands (Cr, OH, NH3, H;O, etc.)
i) Bidentate (en, c,of etc.)
ii)Tridentate (dien)
o
ormil
Os
ioiOu 00Ss01Pu
00CI
MHT

D
1. Wh
iv)Tetradentate (trien) sotnol gsle lo anos ai euooo 2d
(v) Hexadentate (EDTA) (A)

1
Types of Complexes: 000 bauoms s oqenes orh
toilouiber 30 sra MHT
(A) Homoleptic complexes Ni(CO)4. [Co(NH,)«]Clh O407 0080,91

2
2. [Cu
(B) Heteroleptic complexes [Co(NH;).ClhH;0]CI (A)
(A) 80

0 eno
Opl cmot ysdl anrot nd
Effective atomic number: 3. An

2
EAN Z-X+Y (A)
Where,Z= Atomic number of metal. C)
X = Number of electrons lost by metal to form
Y= Number of electrons donated by ligands. the ion.

T
5k MHT
Isomerism in Complexes: 4. Sel

CE
(A)Stereoisomerism ) Geometrical isomerism

(B) Structural isomerism

(ii) Optical isomerism
:() lonisation isomerism
(ii) Linkage isomerism
(At
(A)
MHT-

T
(iii)Coordination 5. The
isomerism
(iv)Solvate isomerism (A)

H Bonding in Complexes
Valence bond theory (VBT)
6.
C)
[Cr

M
) i) Crystal field
theory (CFT) of is
Valence bond theory (VBT):A central metal ato (A)
dsp, d'sp, etc. forming hybridised orbitals to accommodaundergoes C)
ligands.
hybridisation
from lik MHT
(A)Inner complex: (n- 1) d orbitals of metal are used
(B) Outer complex: nd orbitals of metal are used. Whi
A)
MHT-
8. The
 Typesof
hybridizationn
Geometry Coordination
sphybridisation
hybridisatic Linear Compounds (233)
Sphybridisation Triangular
Sp hybridisation Tetrahedral
yunded
dsp hybridisation Squareplanar
w
n
4]SO4 by neutral dsp Trigonal
bipyramidal
d'sp hybridisation Octahedral
y valence

y bonded
(outer
&'sp hybridisation

Applicatio of the coordin

Biological importance
Pentagonal
compounds
bipyramidal

is o
ideeW
to the ii. In medicine
ii. For estimation of hardness of water
iv. In electroplating
e s
s
er0 T30-T
Multiple Choice

t
Questions

b
MHT-CET 2006

Which ofthe following is diamagnetic in nature?

(O)Te
(A)Fe(CN)
MHT-CET 2013
(B) NiCI

olqmo
(C)Ni(CO)]

o u D)MnCl

D
2. [Cu(NHs)4J" shows which erolo oilgnogoa loutE
of the following hybridisation?
(A) 8e A) dsp (B)sp'd (C) dsp (D)sp

1
3. A
moment of 1.73 BM will be shown by one among
magnetic
the following.nun(
ooh
(A)[Cu(NH)4*

2
(C)TiCl
(B)[Ni(CN)J ng add rrost dno(E0
(8).00 ge nt pe(D)[CoCl] oteog ort no1 vloe

0
MHT-CET 2014

2
Select the diamagnetic complex ion amongst the following complexes.
(At. No.: Fe =
26, Co =27)
(A)K,[Fe(CN)%]

T
B)[Co(NH;),]Ch C)K[FeF] (D)K[CoF6)
MHT-CET
2015

E
ogomunoroldboneT (0
Ihe correct IUPAC
name of [Co(NH)s(NO:%]

C
(A)Triamminetrinitrito-N-cobalt(1) (B)
Triamminetrinitrito-N-cobalt(I)
C)Triamminecobalt(I)nitrite (D)Triamminetrinitrito-N-cobaltate(III)

T
6. CrNH
)] [Cr(SCN)6)
Ds] and [Cr(NH;)2(SCN)4] [Cr{NH;)4(SCN);] are the examples of what type
ofisomerism?

H
A)lonisation (B) Linkage isomerism
isomerism
sp ordination isomerism ovso-Ho0D)Solvate isomerism
sation like the MHT-CET

M
ctrons fom 2016
opiirono(
Which
ofthe following is a neutral complex?
(&)TPHNHS)Clh) Ving isa (C)[Ni(NHs)6]Ch D) K.[Fe(CN)6]
MHT-CET (B)[Co(NH:)%]Clh
2017 oio (8) algosoidobouatsnib0
loib (C) Vj
K[Fe(CN)6] is
ATect charge on and coord on number of 'Fe' in (D)+3, 3
2,4 (C)+2,6
(B)+3, 6
 Exam Questions
(234) MHT-CET
coordinate complexes is an exception
to EAN rule? t 1o
22. 7
following
9. Which of Zn = 30, Cu =29)
Pt = 78, Fe = 26,
(Given: At. No. DCu(NH,).
D)[Cu(NH,),
(A)P(NH,),(B)Fe(CN)," ()|Zn(NH;),J 23.

MHT-CET 2018

o nMH

is
in the complex
[AuCl4]' ? 24.
oxidation number of gold
10. What is the (C)+2 D)+1
(A)+4 (B)+3

s
in dimethylglyoximato ligand? ootgg
11. What is the number of donor atoms (D)420/8

e
(B)2 (C)3 25.
(A)1

MHT-CET 2019
12. Which complex among the following gives a white

t s
aques
precipitate on treatment with an uea 26.

b
solution of barium chloride? (B)[Co(NH,)sNO:;]SO4
(A)[Pt(NHs)%ClE]Br2
27

u
D)[CO(NH,),SO,]NO;
(C)[PNH,).Br,]Cl2
0T -TE

o
13. Which among the following is used in the treatment of cancer? lot od todoit
(A) trans-P(NH;);ClL] (B) cis-[PtClL(NHs)2]
28.

D
(C) trans-[Pt(en);Clh] (D)cis-[P(en);Cl,]
14. Which among the following is a neutral complex?
ErOS T9O-THR

1
(A)[Ni(NH:)%]Ch (B)[Fe(H,0)%]Cl) CK[Ag(CN):] D)[Pt(NH)%Cl]
29

2
15. According to Werner's theory, the geometry of the complex is determined by
(A)number and position of the primary valences in space. er

0
(B) only from the primary valence in space.
C) only from the position of secondary valence in space.

2
(D)number and position of the secondary valences in space.
Aroc Tup-R
30.

T
16. The effective atomic number of Iron (Z- 26) in [Fe(CN)6]3 is
(A)35 (B) 34 (C) 33
(D)
a soslod
36
31
o
E
17. IUPAC name of the complex Ba[CuCl4] is GOOOJ( A
(A) Bariumtetrachlorocuprate(11)D

C
(B) Tetrachlorobariumcuprate(l) 32.
(C) Tetrachlorobariumcopper(11) (D) Bariumtetrachlorocuprate(I) TR
Which among the following ligands

T
18. 1s usca Tor the estimation
of hardness of water ?
(A)Ammonia (B) Ethylene diamine
C) Diethylene triamine (D)Ethylene diamine

H
tetra-acetate
33.
19. What is the denticity of Ethylene diamine tetra-acetate ion?2
(B)2 E)(C)1 to
(A)4
9rost
M
(D)6
(D)6 cetnol
20. The complex ions [Co(H;0)(ONO)and [Co(H,) NO,1+
34.
(A) linkage isomers (B) geometrical nolbxoo ()
(C) coordination isomers (D) ionization isomers
isomers s 1892
coordinate complex [Pt(NH,);Cl.l 35.
21. The IUPAC name of i
(A)
diamminedichloroplatinum(11) (B) dichlorodiammineplatinum(IV)
(C) diamminedichloroplatinum(TV)
(D)dichlorodiammineplatinum(II)
 number of Co (Z
effective atomic
B) 34 27) in [CoNH:)61" Coordination Compounds(235)
(A)27 is
(C)35
coordination number of Pt
11,
The ion in [Pt ChNH)h] (D) 36
(A)4 (B)8 complex
(C)2 is
HT-CET 2020 (D)6
ng the following

n
folle
hich among
Whi coordination
24. compounds

o
number of ligands? does not have
coordination number

is
to
(A)Co(NH)6** (B)[Cu(NH)AP* equal
(C)[Co(en)»}"
effective atomic number (D)[PLNH,)
hat is of Fe in [Fe(CN)%1

s
(A)26 B)34 ? (At. No. of Fe -
(C) 36 26)

e
the value of primary valence of Co CoCli? (D)35
26.what is in
(A)4
. What is
(B)3
the type of hybridization and the
(A)sp'd' and octahedral
(C)1
geometry respectively
HO
found in [CoF6?
(D)2

t s
b
(B)d'sp and pentagonal bipyramidal
(C)dsp' and pentagonal bipyramidal (D) dsp and trigonal bipyramidal
8 Which among the following is a correct formula
(A)[Co(H;OXNH;)]I
C[CoNH)s(H;O)]l
(B) [Co(NHs)s1JH,O

o u
of Pentammineaquacobalt(11I iodide?

D
(D)[Co(H,O) (NH;):1]
9. Which of the following types of valences, according to Wermer's theory is also called as primary
valence?
(A)

(C)
Subsidiary valence
Auxiliary valence
2tAoS)(B)

2 1 Residual valence
(D)Ionisable valence

0
30
the formula of potassiumtrioxalatoaluminate(11I).
Identify
A)Ks[AI(CO.)»] B)[K,AI(C;04)»] C)K4AI(Cz02)3](D)Al[Ks(C:04)]
31. Which among
(A)KAg(CN)»]
the
(B)[Fe(CO)%]
2
following complexes is a homoleptic and cationic in nature?
(C)[C%Cl(en)a]C1 D)[Fe(H;0),]Ch

T
hexaminecobalt(11I)chloride?
from following is true for a complex
.Which statement 1
o
E
A)It is an anionic
complex
5 In this coordination number of cobalt is
In
t
C
this oxidation state of cobalt is +3
D) is a heteroleptic complex
wollot not bauoo stabroeo
zobo(i)lodop oni boo

T
láentify [Cr(C;04»]
the Oxidation state of Cr in Ky
(A)-
A)+5 (C)+6lsou
(D)+3 oC
(B)+2

H
in nature?
4.Which a heteroleptic and cationic
complexes
nong the following com is
n(B)[Pt(NH;)Ch]
A)KAFe(CN)%)

M
CCoNH,)4Cl]Cl (D)[Ni(CO)]
%.7hich EAN rule?
metal ion does NOT obey
complexes, the central
from following complexe
Atomic
number: Pt Fe = 26)
= 29, Zn = 30, C[Cu(NH,)4*
D[Fe(CN)o
A)PNH)% 78, Cu
(B) [Zn(NH)4*"
 Questions
(236)MHT-CET Exam [CoCl(en)»]?
What is IUPAC name of (I) ion L(
36. (A)Bis(ethylenediammine)dichlorocobalt

(B) Ethylene diamine

(C) Ethylene diamine
cobalt () dichloride0
cobalt chloride
y100d
bosaT
ehtylenediamine cobalt (1)
(D) Dichloro K3[Fe(CN)6]?
oxidation number of Fe in iodt(D)-3to
37. What is the
roo e(C) +3

n
(B) +6
R Te(A)-6
behavior and geometry respectively in Cuproamm. nium

o
38. What is the type of magnetic
sl
is
(Atomic number of Cu = 29)?
(A)Paramagnetic and
square planar B) Paramagnetic and tetrahedral
(D) Diamagnetic and tetrahedral
(C) Diamagnetic and pyramidal
*39. Which ligand among the following has highest
(A) NCS (B) OH
splitting power
(C) CO (D)

e s
of d-orbitals of central.metal
s

Cu(H,0), so H,0?nste' ( s
40. How many water molecules are hydrogen bonded in following molecular formula

t
Lenbodetoo bus
b'a

b
3 mecgcd tonogi
A) 5 (B)4 b
ab ) (C) (D) 1
bo

u
41. Which among the following is a correct formula of Bariumtetrachlorocuprate(11)?
(A) Ba[CuClL] (B) Cu[BaCl] (C) Ba[CuCL]Clh(D) Cu[BaCIkjC
42. What is oxidation number of Ru in
(A)+2
ag
(B)+5
43. What is the effective atomic number of Zn in
o
Ru (NH,), H,o Cl?

D (C)+1
[Zn(NH3)4]SO4?sor
(D) +6oaW.e

1
(A) 27 eibiede2
(B) 36 (C) 30 ooms (D) 28

2
44. Identify the tetradentate ligand from
the following.
(A) Triethylene tetramine

0
(C) Dimethyl glyoximato
(B) Ethylene diamine tetracetato
D) Oxalato

2
45. What is the number of =N-OH
groups present in dimethyl
glyoximato?
(A)1
(B)4
3
AA

T
46. What is the secondary valence
of Co" ion according to Werner's
moP)2
(A)4 Ch?
theory in [Co(NH;]4u
(B) 3

E (C)6dout
47. Which coordinate compound none (D)5
from following

C
(A)Tris(ethylenediammine)cobalt([III)chloridehas a net negative
charge on complex n?
(B) Diamminesilver(I)chloride
C) Potassiumtrioxalatoaluminate(III)

T
(D)Tetracarbonyinickel(o)
onqoloseron 2(
48. What is the oxidation s ar

H
state and coordination toxolono9 srivvollotodi
(A)+6 and6 (B)+4 and 4 number of platinum gt
respectively in P:NHs
49. Which among the C)+6 and 4

M
following is an
ambidentate (D)+4 and6
(A)H0 ligand?looou agnwolol
u (B) NH, oo
(C) COo- 19
(D) NO
COO
 ldenti f donorgroupspresent
number ofd
0 (A)Six Coordination
(B) Three inEDTA. Compounds
tal number ofligandspresent (C)Two 3oose eog (237)
What
51.
(B)2 in [CoClH(NH:).]CI (D)Four
(A)6
-T3114 Which 1g the following C)4
52. is a monodentate (D)1 biT(A

n
(A) Oxalato (B) Water ligand?do-
of O obalt in [Co(NHs)%]Cl, (C)Ethylenediamine

o
What is EAN (D)Dimethylglyoximato
ium sulphate

is
(At. No. of
(B) Co
(A)

54. How
36
many donor groups are
28
c
(C)27
present in diethylene
27)?
(D) 30 pbi ta

s
(A)6 (B)4 triamine?2
al metal ion? (C)3
tofltod D)2

e
among the following
h oidW28
complexes carries
(A) [Pt(NH)%Ch] (B) [Fe(H0)]Clh not net charge?

s
(C) K:[Hgl4]
1dentify the coordinate complex (D) Ni(NH),]Ch

t
having ambidentate ligand
(A) Tetraaquadichlorochromium(I)chloride from following.ove
Bariumtetrachlorocuprate(II)D

b
(B)

C) Sodiumhexanitrito-N-cobaltate(III) 000A)
noo nemsta geiio.
t st
to doid W.0r

u
D)Diamminesilver(OChloride
10 2nttaligasog H0.l00D dbocs
Jch 57. Identify the increasing order of odge
effective notEbo

o
9
magnetic moment :(AT
Oxidation state. of following elements in their + 2
Fe (Z 26), Co (Z = 27), Ni (Z = 28), Cu (Z= 29) oiome bas2mot 10 S(0)
(A) Co< Cu < Fe < Ni
(C) Cu< Co < Fe < Ni

D
(B) Cu < Ni < Co< Fe
(D) Fe < Co< Ni< Cu 9inoias
iobl.It
1
58. What is systematic
name of [Cr(en)3]Clh?

2
(A) Ethylenediamminetrichlorochromate
B) Tri(ethylenediammine)chromium(II)chloride
T19189 ug 10SulbY Sdl ett T
C) A

0
C) Tris(ethylenediammine)chromium(II)chlorideote
990nin 1o edun sai
(D) Ethylenediamminechromium(II)chloride tedEt
(A) +3
2
.What is oxidation state of iron in potassium hexacyano ferrate (1)2

(B)+2iT (4)(C) *6 oine)t4dorurd(A

or vitrsbAT

T
Chl7
dentify the precipitate and it's quantity obtained when
1 mole of aqueous solution of

E
etramminedichloroplatinum([V)bromide is treated with aqueous silver nitrate in excess.
a? (A) Two moles
of silver chloride

C
(0)
5) Two moles of silver bromide
bromide nibnocs dotd W.ar
DOnoles of silver chloride and one mole of silver

T
D One mole of silver bromide
Which complex?oime sid Tr
H)6]"? among the following complexes
c is NOT a heteroleptic

H
(A) [Pt(NH)aBr2]Br2 (B)[Co(NH;)%]Clh
JD0} (e) Oeuojo9O
C)[Co(en):Clh]
2:(60niI) D) [Co(en);Clh]C
(NH:)%]" respectively?

M
D.What
is c0ordination number of Pt in [PtClkNH);] and [Pt (D) 4 and 4
(A) 2 numbe and 6
and 4 (B) 2 and 2 )(C)4 er fatW.er
3. Which complex?o 9dt
among the following compounds is cationic aluminate ()ia
A) Sodiu (B) Lithium hydrido nitrate 0
C) Sodiumthexanitro cobaltate (I) Diammine silver ()
tetrachloroo zincate (II)D ()D)
 Questions dimethyl
(238)MHT-CET Exam ligand dimethyl olua.
in theligand glyoximato ?
attachment are present (D) 4
64. How many
points of )3 WE
(B)1 80.
(A) 2 ()
diethylenetriamine is ?
65. What type of ligand (C) Hexadentate (D)Bidentate (A
(B) Tetradentate
(A) Tridentate

n
d-orbitals of transition metals have slightly higher.energy 81. W
66.Which from following whena (A1

o
?
metal ion forms at compound (D) (A

is
(A) dy (B) dax (C) dyz
d (C
67. Identify cationic complex from following. 82 WI
(C)[Ni(CO (D) [Ni(NH,)ajCI

s
(A) K:[H,la] (B) K4[Fe(CN)%] (A
central (C
*68.Which ligand among the following has lowest splitting power of d-orbitals of
(A) H:0 (B) SCN (C)T (D) EDTA
69. According to Werner's theory based on experiment the formula of coordination

s e 83. WI
(A
(B

t
CoCly 3NH then the molar conductance in mho mol and number of CI ions Dree
(C
AgNO respectively is

b
(A)0,0 (B)0,2 (C)102,0 (D)102, 1
D
84. Ho

u
70. Which of the following statements is correct according to
Werners theory, when excessAgNG (A
is treated with CoCl.6NH, precipitating three moles
of AgC1? Ao

o
(A)5 NH3 and 1 Cl atom are in coordination sphere 85. WI
(B)3 'Cl' atoms are in ionization sphere (A

D
(C)2 Cl atoms and 4 NH; molecules are
(D)2'Cl' atoms are in coordination sphere
in coordination sphere (B
(C
71. Identify anionic complex
(D

1
from following.
(A) Pt(NH;)>Ch] (B) K[Ag(CN};]| C)[Co(NH)«]Cl (D) [Ni(CO) 86. W

2
72. What is the value
of primary valence of copper chloride (A
(A) 3 according to Werner's theory?

0
(B)2
(C)4 (D)1
73. What is the number
of nitrogen atoms

2
(A)3,2 (B)2,2
and-CO0 groups respectively present 1. (C)
(C)2,4 in EDTAT
74. Identify monodentate (D)4,4
ligand from following. 2. (A)
(A)Dimethylglyoximato

T
so C)Diethylenetriamine (B) Ethylenediamine 29
Cu

E
75. What is the oxidation (D)Ammonia
number of central
(A)+2 metal atom

C
(B)+6 in [Cr(NH:)6]0NOs)s? af
76. Which coordinate (C)+4 G
complex from (D) +3
(A) Ka[H,l4] following
(B) K4[Fe(CN)%] has a complex

T
ion
17. Which among
the following C)[Pi(NHS)hCh]with postive charge
(A)[PH(NH)hClh] is NOT an
octahedral
(D) [Ni(NH;)61C

H
(C[Co(en)0NO,); complex?
(B)[CoCl2(en)al
78. What is oxidation
state of iron (D)[r(C0,)hClh} 3. (A)

M
(A)+2( (B)+4
in potassium
ferrate? May
79.What is the
number (C)+3
nitrate is treated of moles
(A)4.0 mole with of silver
[Co(NH,)4Ch]Cl? chloride D)+6 Sihe
e (B)3.0 mole precipitated
when excess
Cn exces5 of
aqueou
Thu
1.73
(C)1.0 mole
(D)2.0 mole In
 isomerism is p resent between Coordination Compounds
what
0[CrHO).ICl3 and (i) [Cr(H;O);CIJCL.H,0? (239)
(A)Coordination (B)Linkage
(C)lonisation
geometry
What type of
af and magnetic (D)Hydrate
behaviour is found

n
Ni = 28)
No. of in compound [NiCu}°?
(At
hen a A)Tetrahedral and paramagnetic

o
free (B) Square planar
O Pyramidal and diamagnetic and paramagnetic

is
(D)Square planar
systematic name of [Co(NH).Cl,]C1? and paramagnetic
hat is
82
(A) Teraammoniumcobaltchloride (B)Tetramninedichlorocobalt(II)chloride

s
C) Tetraamninecobalt(Wchloride (D)Dichlorotetraamminecobalt(II)

e
chloride
al ion? . Which among the following pair of compounds
A) Co(NHs)sNO2]SO4 and [Co(NHs)%SO,]NO;
is an example of linkage isomerism?

pound is
itatedby
B) Co(NH)sNO:]Cl; and [Co(NH,)ONOJC;k
CrHO),]Clh and [Cr(H,0):CI]ChH,0
D)Co(NHs)sSO,]Br and [Co(NH,)sBr|So O o0)ho omun
t s
AgNO
u How

(A) Two
many donor

following
groups are present in dimethyl glyoximato ?
(B) Four (C)Three D) One

u b
o
K.Which of the is a property of coordination compound and not of double salt?
(A) Aqueous solution of these gives the tests of all constituent ions
B)These show entirely different properties from their constituent ions.
These lose their identity in aqueous solution.
(D)

D
(C)These dissociate into their constituent ions when dissolved in water.

86. What is
(A) 35
the effective atomic number
(B) 36

2 1
of Cu in [Cu(NH:)4]* ? (At. No. of Cu 29)
(C) 29 (D) 34

0
SOLUTIONS

2
(C)

A)

T
sCu [Ar] 3d4s
Cu
[Ar] 3d'

E
3d

C
Ground state

HT
3.
(A)
NHs NH NH NHs
ds-nyortdisation

electrons as 2olgnoo al

M
Magnet unpaired
moment,
iS related with number of
n(n+2) BM Spfkoe05ta magnetic moment of
silver (n +2). On solving, n=
S .73=n
the complex/com having one unpaired electron
exhibits
1.73 ompound
BM.
In
uNH Cu-[Ar] 3d
1 1
11
 Questions
(240)MHT-CET Exam
1s paramagnetic in
n sture while
4. (B) having unpaired electron
Coordination compound/ion it
paired, it is
diamagnetic.
all the electrons
[Co(NH)%] Cl, i.e. [Co(NH:),]1on

27Co [Ar] 3d 4s

n
Co [Ar) 3d° 4s
3d

abirolio1egittogbm
sbioldoiedocounoou is o
Therefore, [Co(NH:)%] Cly is diamagnetic in natureobn s02

e s
o9 bas
s
5. (A)
UPAC name of [Co(NH,)hNO;)»] is Triammine trinitrito-N-cobalt (II)
6. (C)
In coordination isomerism same ligand

b
attached to different metal
t ion in coordination sphe

u
7 (A)
Neutral complex is the co-ordination compound with no
charge. Hence option (A) is corec

o
Pt (1), NH,= neutral
or 0 charge and Cl, i.e., [Pt (NH3)2 2
Cl2]toisioz
auo9tp
8. (B)

D
1913 otnt osi00eatb s2sd13
K,[Fe(CN).J=[Fe(CN).J
ottiioe a0p ni goobi iofsseoloesdT C
X+6-1)=-3 X= +3

1
Coordination number of Fe is
6 as 6 CN are attached.

2
9. (D)

29 2+(2x 4)JJ0235
For [Cu(NH).*, EAN
10. (B)
[AuCL
X+4(-1)-1
2 0 X=+3 ABE A)-10

T
11. (B)

E
HO
OH

C Bidentate Ligand

T
HC 28
12. (B)

Ho
In complex [Co(NH3)SNO;JSO4,
BaClh it will
give white ppt. SO, ions are in 29
of BaSOA ionization Treactionw

M
co(NH3) NO2 sphere. Therefore o 30
nepp JS04 +BaCh
-co(NH,)5NO,
13. (B)
B00 jcl+
BaSo
14. (D) GteitbnuoWhite 31
The complexes
ppt Ppt l up
which carry
n0 net
Ma ST
charge are
called as
neutral complexes.
 I5(D) Coordination Compounds
ture while (241)
if it has (A)
16. Atomic number = 26
Z-Complex [Fe (CN)%]3
o.N. of Fe X-6=-3

n
X=+3 =
AN Z- X+Y 26-3 +12

o
35

is
17(4)
IUPACname of Ba [CuCl is bariumtetrachlorocuprate(11).
19. (D) 20. (A)

s
I& (D) 21. (A)
22. (D) 23.(A)
. (C)

e
Ethvlenediamine (en) is bidentate ligand.

s
Co(en)] No. ofligands= 3,
Coordination number = 6

t
2%(C)
nation sphere. Z-26, X = 2, Y = 12

Z-X+ Y 26-2+12 36
b
EAN =

A) is corect OgH.02hfiuo-o1ariqluz muitoteno

u
26.(B)
Primary valence= Oxidation state of Co = +3.
27.(A)
Formation of [CoFs1
It is an example

D o
of sp d hybridisation . An octahedral complex shows paramagnetic
It utilizes outer 4d orbital in
behaviour.

1
sp'd' hybridisation. It is therefore called outer orbital or high spin
or spin free complex.

Orbitals of Co ion

0 2
Since F is weak ligand, there is no spin pairing effect and Co possesses 4 unpaired

2
electrons.

Co" undergoing sp d hybridisation 1 |Ta N L0

T
sporbital
CoF

E (Outer orbital spld hybrid orbitals

or High spin complex) six pairsof electrons from six P ions

C
28.(C)

of Co is +3. Hence correct

NHs) and aqua (H;O) are neutral ligands. Oxidation state

T
formula is (Co(NH;)5 (H20)]l3
zbsgil ioow 1o sas3 m baa s lo
29.0 sulay 39gs Van abasg1 geoele
(A with D)
30 Bo abnsgrt zomeoo

H
n reaction 30.(A) eorosb ziort to 1obro 3dt f cor9e ni bogee eeollot
Bidentate ligand, Oxidation state of Al +3 ARH<4 snoO09

M 3 Formula is K3[AI(C,04)3]
31(D)

,C1,=[Fe(H,0).J"
i i. Omoleptic Fe is linked to only one type of
-
+3CT
ligand, H20.
ion. complex
() 0

tionic
Complex- due to positive charge on
 (242) MHT-CET Exam Questions
32. (C)
[Co(NH)6]Cl >Hexamminecobalt (III) chloride
It is an cationic complex.

n
Coordination number of Co 6, Oxidation state of Co = +3
It is a homoleptic complex.

o
oM.O

is
33. (D)
Oxalate C,0

s
K [Cr(CO)] >(1 3)+Cr+ (-2x 3) = 0
x
3+Cr-6 =0
34. (C)
[Co(NH).Clh]Cl
' Cr = +3

[Co(NH,), CL,I +CI

s e
35. (C)
[Cu(NH)4]>EAN =Z-X+Y =
29 -2+8 =35

b t
u
36. (A) 37. (C) (O12
38. (A)
Cuproammonium sulphate
[Cu(NH)4]*">Oxidation state of
[Cu(NH3)4]S04. H20

3d
Cu = +2

D o 4p
iTsbix0
Y+SAS

-4 21
Cu(Z 29)

0 2 4dsp'hybrid orbitals

E T 3d
4p

C 4 electron pairs

HT dsp-Square planar, Paramagnetic- One unpaired

39. (C)
Strong ligands have larger vaue
or ag
electron.

n
from 4NH to latidnoro3)

M
igands can be arranged in a and case of weak ligands Ao aluoto
Series in the order values are smaller. 1
follows. of their decreasing
field strength, *
cO>CN> en>NH> EDTA>NCS>H0> C05
>OH>F>s*>ar>
40. (D) SCN> Br >I
Four water molecules are coordinated with Cu and one
is hydrogen bonded with SO
41. (A)
 Coordination Compounds
and H,O are neutral molecules. (243).
NH Oxidation number of Ru= +2

EAN= =30 -2+8 36

44.(A)

o n
is
(D)
HO OH
H,C-C-C-CH,
dimethyl glyoximato

e s
The number of=

(C)
N- OH groups - 2)

- Coordination number
t s
b
Secondary valence 6

u
47.(C)
K,[AIC,0,),1 3K° +[AI(C,O,)P-

o
D)
PuNHs)6 i. Oxidation state of Pt= +4

D
ii. Coordination number of Pt ==6
(D)
group has two donor atoms (N and O). Out of the two only one donor atom is linked to the

1
NO,

metal as M-ONO or M-NO2.

(A)
EDTA is hexadentate ligand.

0 2
eiu) 0erom aitsreur lo toiro gate serant
O182

2
51.(A)
[COC%(NH)4]CI
Co is linked to 4 NH3 molecules and 2 CI ions in coordination sphere.

52.(B)
Total

Water is

E Tnumber of ligands =6

a monodentate 1ligand while others are

bidentate ligands.
to ot potebo0

53.(A)

C
EANof CoZ-X+Y 27-3+ 12= 36

T
S4.(C)
aller. The
as
trength,

H
/10
Xolqmoo golomoh
ÇH, gg eu lro sof

M Diethylen

dien)
donor groups)
-CH

bns eiiO) nt 10todatun O 9

 MHT-CET Exam Questions
(244)
55. (A) Net charge: +2 + 1(-2)=0lon loo
(A) [Pt (NH:);Clh] 63. (D
Net charge: +3 So
(B) [Fe(H;0)%*
Net charge:-2 Li
()[HL]
[Ni(NH,)%1 Net charge: +2
(D) D
ana 64. (A
N

n
56. (C)
ligand where the donor
atom can be
-NO2 group is ambidentate : Na;[Co(NO;)%]
sodiumhexanitro-N-cobaltate (III)

o
present in

57. (B)
Fe 4s 3d
is
n4
Vn n+2)

e s
s
4(4+2) 4.89 65.

t
3d
Co4
n=3
Jua noitebop3009107 pabooos
-3(3+2)
Ni4s 3d
3.87
TG091A12
u b ,0.0A

o
n -2 o Gise mitubixo
= 2.82
-22+2) 66.

tor Cu>4s 3d' ano

D
bes ) anois 1onob owt 2at quorg
0

1
n=1
H I1+2) = 1.73 O-M10 OM0-M antee
Increasing order of magnetic moment:
58. (C)

0 2
Cu< Ni < Co< Fe nagil ottnabaoda ATd
A 67.(

2
[Cr(en)]Ch: Tris (ethylene diammine) chromium (A
(III) chloride.
59. (B)
1OM
0

T
Potassium hexacyano ferrate
(II): KA[Fe(CN)%]
Oxidation state of iron = +2 ebnssil to tonu luto

E
60. (B) 2g alsdn sbrd ow
8 68.
2150 oiafw besgil sresnobonon el

C
[Pt(NH3)4Ci,] + AgNO,
Br 2AgBr+[Pt(NH,),
Tetrammine dichloro Cl21*
Platinum (IV) bromide
69.

HT 61. (B)
Heteroleptic complex :
[Co(NHs)%1Clh-
Complex with metal
Homoleptic complex
All other complexes are
species having more than one
as it has only
one type
tyPe
70.

M . heteroleptic in
nature. of ligand.
62 (C)
Both Cl and NH3 are
unidentate ligands.
The coordination number
of Pt in [PtCh(NH)a]
= 4 and
[PLNH,).* =6.
in [Pt 71.
 (D) hexanitro cobaltate (III): Coordination
odium Na,[Co(NO)%]- Compounds (245)
hydrido aluminate ( : LiAIH4- Anionic
Sadium tetrachloro zincate (1I) Na2[ZnClu] AnionicComplexComplex
Diammine
lver () nitrate : [Ag(NH32JNO,- Anionic
Complex
rele rua fo 10dme-Cationic Complex
64.(4) evo
ONO).
It is
HO
N
OH 2

o n
H,C-C-C-CH,
is
s
dimethyl glyoximato
donor atoms per each ligand.

e
Tvo

(ATG)

s
(4)
triamine- dien is a tridentate ligand.

t
Diethyl

000-t0d

b
H
NH,

6.(D)
Boyle's Law

o u
dy, dyz, dx have same energy

D brte elsobonoM

1
While d2 have lightly higher energy.

2
67.(D)

0 10 9guur

0
(A)KaHg L)= [Hgluj - Anionic Complex

2
B)KFe(CN)6) [Fe(CN)%61*-Anionic Complex
=
(Cat
Neutral ldton aioHA S C3)
beganelo vovingon zatesoc
()NiCO)- ai noi

6.(C)

E T
DNi(NH)6]Clh = [Ni(NH)6** = Cationic Complex.
ote
strength, lower will be its splitting power of
2rafqsoo isnborliro0

d-orbitals of central metal ion.

C
the ligand
Ker
nas lowest splitting power ofd-orbitals of central metal ion.
69.(A)

HT According
secon
valency.
neutral
T0.B)
s
to Werner's theory, in CoCl3.3NH3, three
Therefore, no
chloride ions satisty
CI will be precipitated.
non-conductive molecule.
Therefore compound behaves as
primary as well as

M .) can be precipitated
Atoms satisfy primary valency and
are present in ionization sphere are in ionization
ng Ap precipitated, all three Cl atoms
are
sphere. Dince three moles of AgCl
lsmool lnbstalo0
charged.
Since be negatively
counter
positively charged, complex will
a)1s
 Questionss
(246) MHT-CET Exam
72. (D)
Copper chloride - CuCI 78. (D)
Potas

. O.S. of Cu = +1
According to Werner's theory
oxidation number of an element is the
primar

o n
73. (C)

HOOC-CHj-CH, -CH, CH, -C0OH is

HOOC-CH,
-N
CH, -COOH

e s 79. (C)
[Co

s
Ethylenediamminetetraacetic acid
Sin

t
(EDTA) Ag

b
Number of nitrogen atoms= 2
80. (D)
Number of-CO0 groups = 4
[Cr
74.(D)

o u In
sph

H-N
D 81. (A)
Fo

1
t
Monodentate ligand Ox

75. (D)
[Cr(NHs)6]ONO;)»
Charge of NH =0,
0 2 Orl

2
As
Charge of NO, = -1
On
76. (D)

T
ort
Since, counter ion is negatively charged hy
(CI) & NH3 is neutral, the complex is positivelyu

E
77. (A) Ni
Octahedral complexes are formed

C
with coordination
The coordination of Pt in [Pt[NH3)>Clh] number 6.
is 4.
Ea

T
cO
1302ige19ol

H Central Metal

M
lon

eletig L
82.(B)
Ligands
Octahedral Geometry 3o lo ss p Ox
 (D) Coordination
Potass n ferrate K2FeO4,
78.( is
dation state Compounds (247)2
of Fe is +6.

2K
OR
K-O
0 i
Structure
O-K
o n
is
of potassium ferrate
T9.(C)
Co(NH) 1:).ClL]Cl=[Co(NH,),CLI +CIr

s
Since only
one CI
I is in the ionization
sphere only one

e
AgNO. mole of AgCl precipitated with
excess of

D)
Cr[H:O)%]Cl3 and [Cr(H;0),CI]Ch. HO
(II)

t s
b
above structure () and (11) number of water
molecule in and outside
re
sphe are different so it 18 an example of the coordination
hydrate isomerism.

u
biduob sonie
81.(A) Jot ob rsoeraoopotsbeo
Formation of [NICI
is an example
t

oxidation state.

Ni ion
ot

D o
sp hybricdisaton and has tetrahedral geometry. Nickel is in +2

1
Orbitals of
3d

2
As Cr is a weak ligand, 2 unpaired electrons in Ni remain undisturtbed.

0
One 4s and three
orbitals undergoingg sp

2
hybridisation orbitals of N
d
harged. NICL high spin complex

T
sphybrid orbitals
4C
Four pairs of electrons from

E
donates a pair of electrons. The compound is paramagnetio since
it
1on
0ontains two unpaired
electrons.

C
HT
.B)
Structure of [NICIJ

M 0.S.of Co
Name
state of Co is given by -
1- [(O. S. of 4x+2-+3
=1-[0-2] 1
[Co(NH3)4C12]' C1
NH) + (O.S. of
Tetramninedichlorocobalt(1)chloride
2x CI)]
 t

N eeeee

(AS(248) MHT-CET Exam Questions

o n
is
83. (B)
(Co(NH)SNO,JCl; and [Co(NH),ONOJCL

In structure (1) ligand NO, is linked through 'N' whereas in

e s
structure (11), NO; ligand is bond.
onded

s
through 0' atom, so it represents the linkage isomer.

t
84.(A)
a muteapog to outoie

b
It is bidentate ligand.

u
OH (O)e
HO

H.C-c-C-CH
dimethyl glyoximato
D o ()08
85. (B)

2 1 hDiD(OF)1O
These show entirely different properties from their constituent
brus.1OOHh91
ions.te
(
svods odt nl

0
Since double salt is when dissolved in water, it dissociates into its constituent ions whereas
coordination compounds do not.

86. (A)
2 aloj to nobamo
(A) 18

EAN

E T
=Z-X+Y
29-2+(2 x4)
stele nofabaxo

C
27+8 35
enotoels bsvsora brisgt ew
sel0 A

HT s91 bes
iogrobru elslictho
Mo aeido noitseibvo
ero

M
altidso tud

eesg ebogo 9Gcoe fo 86ieoob o 10 oe3

 10. Halogen Derivatives
ImportantFormulae
bonded
and Shortcut Methods
lerivatives are the organic
Halogen deriv compounds obtained
hydrocarbonsby halogen atoms by replacing one or more
H atoms of

n
According to
ing the
to the number ofhalogen atoms they are
classified as:
Monohalogen derivatives

o
R-X e.g. CHBr
Dihalogen derivatives
Trihalogen derivatives
CHCl
CHCl, CHI gosto
is
Tetrahalogen derivative CCl
Monohalogen derivatives are classified as
e s
.Alkyl halides (may be primary, secondary, tertiary)
Allylic halides
Haloalkyne
Benzylic halide
.Aryl halides
Vinylic halides

t s
whereas
Preparation of alkyl halides:
1. From alkenes:

u b anc

o
oalog

-
D
+HX

1
s Alkene slor a Alkyl halide

2
(Addition of HX takes place according to Markownikoff's Rule in Unsymmetrical alkenes)
Kharasch (peroxide) effect: zde eoratororasl Bina esoalo-oze
CH3-CH= CH2
2. From alcohols:
+HBr

2 0
Peroxide
1edue evro2 ip9ug0 5
BenzoyiCH,-CH2-CHBr-0123/30 af oB
301 rd botob ban otoowssl aj ebie ba

3R-OH+PCl

E
R-OH+PCl5 T 3R -Cl+H,PO3

>R-Cl+POCl3 + HClvan n9val

tio wol ol beriosi iote oaA
t2u 031tde

tDR0a 9sudozol
seatos

C
K-OH +SOCI, AR-CI+HCIt +so,
Thionyl

T
chloride

H+HCInyrousR-CI+H,O 20 etedt ajuos itg

H R-OH+HBr- NaBr/H,SO4R-Br+H0

M R-OH +HI HPO4>R-I+H,0

Nal eu
 NE
Halo
Reactionsof Subs
Nucleophilic
Alky
(250) MHT-CET Exam Questions 1. No.
: Sr. R-X
3. Halogen exchange
i. Finkelstein reaction
+Nal
acetome
R-I
+NaX

o
2 n R-3

is
R-X
Alkyl halide
AIkyl iodide
Br)
(Where, R-X>R-CI, R- or broe
heating alkyl chorides oromides R-
prepared by 3.
Alkyl fluorides are AsF3, SbF3, etc.
Swartz reaction

s
such as AgF, HgaF2,
ii.
with metal fluorides R-

e
R-Cl+AgF R-F+AgCI eeviveb rogolait

s
(Electrophilic substitution) R
Preparation of haloarenes 5

X
X
hch nogoiedoso

b t 6.

7.

u
Fe/ dark ebiisd otvilA
a olsois

o
8.

Activity:

D
Optical
Plane polarized light :
passed through a Nicol prism, the
transmitted light has Sn2 Reac

1
when
A monochromatic light Alkaline
plane polarized light.
vibrations only in one plane giving a

2
CH
Optical activity: an optically active
a plane polarized light by This is a

0
rotating a plane of
The phenomenon of
R=
substance is optical activity. ast XH lo othbb)

Dextro-rotatory and laevorotatory substances

The optically active substance
which rotates
2 e (ofitoop dozedz light on
the plane of a plane polarized
nght
Hence it
This in

T
which rotates on len
dextro-rotatory and denoted by d or (+) and the substance which d
hand side is
denoted by I or (-.

E
hand side is laevorotatory and
SN2 Me

C
Asymmetric carbon atom: and opua
to four different groups is an asymmetric carbon atom Rate o
A carbon atom attached
asymmetric carbon atom. Second
active substance must have an

HTe.g.2-Chlorobutane or lactic acid

Optical isomerism:

The optical active substances

having same molecular formula but different opticalo
2180-4
activity
The ra

M
HO
are optical isomers or enantiomers.
e.g. d and / lactic acids.

Racemic form: Uxturedue0

is a racemic nu
A mixture containing equimolar amount of two optical isomers SNl
external compensation, denoted by (dl) or (£)
Alka
 Reactions of
Haloalkanes: Halogen Derivatives (251)
eophilic Substitution reactions of
alkyl halides
Sr.No. Alylhaltde Rengent
R-X NaOH(aq)-A Substitution produet

n
(or KOH) R- OH + NaX
otbromide (alcohol) rKX)
NaOR'

o
R-X
R-0-R'+NoX

is
(sodium alkoxide)
(ether)
R-X R8Ag
(silver corboxylate) R-C-OR + Agx

s
NH (alo.) (ester)
R-X

e
(excess) R NH, HX
primary amine)

s
R-X KCN (ale.)-A R-CN RX
(nitrile Xalkyl cyanide)

t
R-X AgCN (alo.) A R-NaC +AgX
(isocyanide)

b
R-X KO-N=O R-0-N=O KX
potassiunm nitrito) (alkyl nitrite)

R-X Ag-0-N= 0-
(silver nitrite)

o
-
u(nitroalkane)
+AgX

D
d light ha
.SN2Reaction:

1
Alkaline hydrolysis of CH3Br is a Nucleophilic Substitution (SN) reaction.
CH,Br+OHCH,OH+Br olsnsgoiato sbyitsG

2
cally active
This is a bimolecular second order reaction. For this rate determining step, by rate law,

0
R=K [CHBr] x [OH]
Hence it is represented as Sy2.
tht on ngh
lates on let
2
This involves back side attack of a nucleophile on carbon atom forming a transition state
which decomposes giving CH3OH with 100% inversion.

opticaly T
S2 Mechanism)roamimo
E
Rate oc [Reactant] [Nu]
-ngerinils4bofkes ar oidseer etu
(okuz hoxtge o

C
a aistos 2viaa rive noitoant
Second order reaction
Sy2 path is CH3X >2° >3°
Therate of hydrolysis of alkyl halides by

1cal
actv

HT HO
H - Br Ho-CB
H

Kure
dueM Sw1
Reaction:
Transition state

hydrolysis of (CH3);C-Br is a
Nucleophilic
Walden Inversion

Substitution (SN) reaction.

AIne
(252)MHT-CET Exam Questions
It takes place in two steps.
slow C* +Br
Step I (CH,), C-Br=(CH,),
Step II (CH),C*+OH (CH3), C-OH
rate determining step. He the
heterolytic fission is slow, it is a
Since the first step of
first order reaction.

n
reaction is unimolecular and
inversion as well as retaininethe
OH are formed by

o
(CH3):C
The product molecules of inversion and forming a racemic mixture.
original structure giving 50%

is
s
Snl Mechanism

e
Rate o [RCX]
First order Reaction
The rate of hydrolysis of
alkyl halides by Syl

t s
path is Allyl, Benzyl >
3°>2°>1°> CHx

Me
Me-C-Br Slow
Me-C +Br
Me

(1)
u b
o
Me M-0-p
UMe

Me-c
Me
OH
FstMe--OH.
Me
(i)
D arolis
Me (e) nouMe
Elimination reaction: Dehydrohalogenation
2 1
-20
2.
180991
alc.KOH +KX + H,O
HO8eHDI29
A

T o Alkene
Alkyl halide

E
This reaction is called
to Saytzeff rule)

C
B - elimination or 1, 2- elimination. (Elimination takes place accor

T
3. Reaction with active metals

H
i. Reaction with magnesium

+ Mg R-Mg-X

M
R-X
Alkyl halide Alkyl magnesium halide
(Grignard reagent)

ii. Wurtz reaction

2R-X +2Nay R-R+2NaX

Allkyl halide Allkane hoitos
etaolol
 Haloarenee.
Reaction of Halogen Derivatives (253)
1. tions of haloarenes with
metals:
a. Wurtz-Fittig reaction

x 2Na +
X-Rdether
o n
is
Alkyl halide R+2NaX
Aryl halide
(Substituted

s
aromatic
compound)
b. Fittig reaction

-X + 2Na dry ether

s e
t
CH +2NaX
Aryl halide

b
Biphenyl

u
2. Nucleophilic substitution of haloarenes:

o
The presence of electron withdrawing group at ortho and/or para
position greatly increases
the reactivity of haloarenes towards substitution of halogen atom.

QHonoriloloci
D
(iyNoOH433

2 1
NO,
(p-nitrochlorobenzene)

2 0 NO,
(p-nitrophenol)

T
ii. CI QH
NO, NO
rd

CE
NO
haq.Na, CO, 403 K

NO olin gniepo o boiban te

T
(2,4-dinitrochlorobenzene) O
(2,4- dinitrophenol) 002ONA
01-80R(O
O-HOR
H i. OH
NO, ROS P-THM
NO NO, NO

M NO,
warm
H,O
NO
(2,4,6-trinitrophenol)
e ogooue a baed
ort abrbd19V
2-9
(2,4,6-trinitrochlorobenzene) ooiavoa oroe heod-20
0-0(0
 MHT-CET
(254) MHT-CET Exam Questions 1-Chlo
in Haloarenes: but-
3. Electrophilic Substitution 4. A)
Reactions of Chlorobenzene
MHT-CE
C Which

n
1,2-dichlorobenzene
5. (A)1-
(C)1-

o
1,4-dichlorobenzene

MHT-C

2HNO/ comc. H,SO

NO
nosaot g d is 6.
(A)de
Ethan

s
conc
1-chloro-2-nitro
NO
C)d
Denzene

e
I-chloro-4-mtro
benzene
MHT-C

s 7. Xi
majo

t
conc. H,50

b
2-charooenaeae
sulphonic acid SOH (A)
19 4-chiorobenzene 3e dtest pigosionM
salphonic acid

goe sgoisl to n
CH,C
anhyd. AlCI
CH

o u (C

D
1-Chlorotoluene CH
4-Chlorotoluene

1
(D
COCH,
0
2
CH,COC 8. Ide
anhyd. AICl
2-chloroacetophenone 0D2olinot o-g

0
COCH,0
4-chloroacetophenone
C

2 Multiple Choice Questions

A

MHT-CET 2004

E T
1. Best method of preparing alkyl chloride is

C
(A)ROH+ SOCIh (lousdgoutinih (B) ROH +PCls ooziib
(C)ROH+PCl3 (D) ROH+HCIAnhy ZnClh

HT MHT-CET 2005
2. 2-propanol+ NaBr
Re fiuxX. What is X?
(A)2-Bromopropane (B) Propane (C)Propene
OM

(D) Propanone

M 3. C-CI bond is stronger than C-I bond, because

(A)C-Cl bond is more ionic than C-I
(C)C-Cl bond is more covalent than
(B) C-Cl bond is polar covalent bond
C-I (D)C-Cl bond length is longer than C-
9.
 Halogen Derivatives (255)
MHT-CET 2006
Chlorobutane on reaction with alcoholic potash gives
(A)but-1-ene (B)butan-1-ol (C)but-2-ene (D)butan-2-ol

MHT-CET 2008

Which of the following compounds is not chiral?

(A)1-chloro-2-methylpentane (B)2-chloropentane

o n
is
(C)1-chlonropentane (D)3-chloro-2-methylpentane
MHT-CET 2010 d

s
Ethanolic KOH gives
6.
(A) dehalogenation reactions (B) dehydrogenation reactions

e
(C) dehydrohalogenation reactions (D)substitution reactions

s
MHT-CET 2014
the
is an opticaly active alkane having lowest molecular mass, predict the structure of

t
7. X on monochlorination 'X*.
major product obtained of
CH
b
CH
(A) CH-CH-CH--CH-CH (B) CH-CH-CH-CH-CHCH

C)CH-CH-CH-CH-CH-Ch-C
CI
CH
fo e3o
hof

o u C

etocrp-10

D
1
D) C-CHh-CH-CH-CH-CH-CH
n els
2
8. Identify the compound °D in the following series of reactions.
CH3 T CE
to oniog srtodto 18be 1o

0 alc. KOH
alfir
CH-CH CH-CH2-Br
A 0Conc.H,S04
H20,4
i)
'B' + C
Major
product
2 Minor
product wot oiilosor leoi ole fotv beuo
B
T
-H20

E
D
(Major product)
+ E
(Minor product)

CH-C-CH-CH

C
(B)
(A) CH-CH-CH-CH

HT CH
(9CH-CH-CH-CH--I
(D)CH-CH-CH-CH-
CH

compounds leads to the

aelooe

formation of a

M
Popanar the following
hydrolysis of which among
Alkaline 1-chloro-3-methylbutane od-e (
racemate? ond- (B)
(A)1-bromo-1-phenylethane (D)1-chloropropane
thar (C)Bromoethane
zger
 The
21.dry
(256) MHT-CET Exam
Questions T0-TH CA)
MHT-CET 2015 prism?
doil-A (C
chemical composition of Nicol's (D) Na,AlF
10. What is the (C) CaCOj MHT-
(B) CaSO4 30-130M
(A)AlLO
22. W

n
MHT-CET 2016 the possible number
of asymmetric carbon atoms in a compound, nie
am
total number
11. If 'n' represents

o
compound is (D)2n+ 2
optical isomers of the

is
of (B)n C)2
(A) 2n
a mixture of n-butyl
bromide and ethyl bromid.e
formed when (A
12. The compound
which is NOT ilons

s
presence of dry ether is
treated with sodium metal in (C) Hexane (D)Ethaneb

e
(A)Butane (B) Octane
oogolao

s
MHT-CET 2017 dry acetone, this
bromide to ethyl iodide using sodium iodide and

t
13. The conversion of ethyl
lsotgo o
reaction is known as
(B) Finkelstein reactiono borg 3oun

b
(A) Swarts reaction (D) Stephen reaction 23.
(C) Sandmeyer reaction
o
MHT-CET 2018
14. With which halogen the reactions of
(B) Chlorine
o
alkanes are explosive?
(C) Bromine
u (D)Iodine
24.1

D
(A)Fluorine
MHT-CET 2019 prism?
form is used for making Nicol's

1
following compounds in crystalline
15. Which among the (C) NazAlF (D) CaCO
(A) CaSO4 (B) A1,0

16. Which reaction is useful in exchange of

(A)Reimer-Tiemann reaction
reaction
0 2
halogen in alkyl chloride by iodide?
(B) Williamson synthesis
D)Wurtz reaction
0(
urogmoo sis hieobt 25.

2
(C)Finkelstein
alkyl halides is
17. The correct order of boiling points of
(A)RI> RBr> RF> RCI (B)RI> RCI> RBr>RF D- R9-2 26

18. The compound

E T
(C)RF> RBr> RCI >RI
which shows highest reactivity
(D)RI> RBr> RCI>RF
towards nucleophilic displacement reaction
1s

C
27
O,N
NO NO
NO,

T
(B) (C) (D)
(A) 28

H NO NO
2

M 19. Nicol's prism is made of

(A)CaSO4

20. An alkyl halide having

(B) CaSiO
molecular formula
(C) CaCO3
CaHgBr
ether gives 2,5-dimethylhexane. The alkyl halide is
on reaction

(B) iso-butyl bromide

with
(D)Cas(PO4)2

Na metal
ln
presenceof
in prescu
3
(A) sec-butyl bromide
(C) n-butyl bromide (D) tert-butyl bromide
ood
6gogelfs-1(0
 Halogen Derivatives (257)
reaction in which 2 molecules of chlorobenzene
forming diphenyl is an example of reacts with metallic sodium in presence or
dry ether
(A)Rosenmund reaction (B) Balz-Schiemann reaction
(C) Wurtz reaction (D)Fittig reaction
MHT-CET 2020

o n
is
22. Which of the tollowing compounds is obtained when t-butyl bromide is treated with alcoholic
ammonia'?

CH3
(A)CH--CH2-NH2 -0ca (B) CH-f=CH2

e s
s
Br

t
CH, CH
(C)CH--CH oD) CH--CH

23. Calcite
NH2

crystals used in Nicol's prism are formed of

NHBr

u b AO2
boe

o
(A) CaC2 (B) CaClh (C) CaCOs D)CaO
bromination of following
many isomers of monobromoderivaties are obtained on

D
24. How
compoundd? obitoliamtet roo 3 diem o70u hib o1oldoiE (o
T0eiabodom griwoliot olignoss dotlWo

1
nolqo2g orli tol ldstiuz (A
onolfs of1OH Fo aodibbA

2
6a w elonoole gniteort (E
(B) 5 ulgiinu (C) 3 gu snel(D)4 olo(O

0
(A)2 molecular formula
monohalogen derivatives for the alkyl halide having
25. The number of possible
CaHX is
(A)3
to

2
(B)4lokare
(C)1 poi)2
evAmbru
A)
(O)

T compounds is optically
active?opeeng
following
26. Which one of the (B)3-Chloropentanerollot brl to ottW.c
(A)2-Chloropropaneersd TO oo eobil (D)2-Chloropentane

E
C)2-Chloro-2 methylbutane

C
27. What is molecular formula of
3-bromopropene?
(B) CsHBr
(C)CHBr
Sooustsdie

(D)CHsBr
od X-0 to 1obx0
A)

T
(A)CaH3Br
formula of allyl chlonde
)
48. What is molecular (C)CHClo.B0)sH
H (A)CHCl
49. The IUPAC name of
0
(B) C,HC1
isobutyl bromide is (B)2-bromo-2-methylpropaneg odT.a

M (A)2-bromo-1-methylpropane

Lentify the name

0q-00
C)1-bromo-2-methylpropane contCy
of reaction in
D)2-methyl-1-bromopropane

which
prepared by heating alkyl
alkyl fluorides are
reaction
bromide

-o10109-(6)
with metallic fluorides. B) Swarts reaction
(A) Wurtz reaction ogomoldo 0(D) Sandmeyer
(C)Finkelstein reaction
 e (258) MHT-CET Exam Questions Identiy
31. Identify Z in the following series ofreactions 42.
- +SO
CH-CH, CH, -IKOH(aleo,) XHBr e
Y- KCN Z
peroxide alcohol ab A
(A)Eth

n
(A) CH-CH-CH-CN (B) CH-CH-CH2
(C)CH-CH:-CH;-Br (D) CHÇH-CH, IUPAC

o
43.
CN (A)2-
32. Identifjy 'A' in the following reaction: C,H,OH +HCI C,HCI+ H,O
is C)1
Whichh

s
(A) NaNO, (B) pyridine (C)conc. H,SO4 (D) anhydrous ZnCh 44.
and so

e
33. Identify the neohexyl chloride from the following (A)Di
(A) (CH:),C-CH-CH2-Cl (B) (CH)2CH-CH2-CH2-CH-CIA

s
(C)CH-(CH;)-CH:-C (D) (CH),C-ÇH-CH, Identi
45.
CH
t
Cl
34. Identify 'B' in the following series of reactions (A)C
Ethanol A

(A) Ethyl magnesium bromide

(C) Sodium ethoxide
Dryether

(B) Ethene
(D) Ethyl bromide

u b 46. Whic
(A) C

(A) Dichloromethane
(C) Dichloro difluoro methane

D o
35. Which among the following is used as refrigerants and for air conditioning?
(B) Trichloromethane
(D) Carbon tetrachloride
36. Which among the following methods is NOT suitable for the preparation of alkyl chlorides?
47.
C)
Whi
(A)t

1
(A) Addition of HCl to alkene
(C)
48. The

2
(B) Treating alcohols with Lucas reagent
(C)Chlorination of alkanes in presence of sunlight (A)

0
D) By heating alcohols with thionyl chloride
*49. Hov

2
37. The reaction 2R-Cl+CoF2 2R-F+CoClh is an example of (A)
(A) Wurtz-fittig reaction (B) Finkelstein reaction 50. Ide
(C) Sandmeyer's reaction D) Swarts reactioniot s

T
(A)
38. Which of the following pairs of aryl halides can NOT be prepared directly by electrophilic C)

E
substitution?
(A)Aryl bromide and aryl iodide (B) Aryl chloride and aryl bromide 51. Wh
D)Aryl iodide and aryl fluoride sd e
C
(C)Aryl fluoride and aryl chloride (A)
(C)
39. What is correct order of C-X bond strength in CH3x- X?

T
(A) CHI > CH,Br > CH,Cl> CH,F (B) CH,CI> CH,Br > CH,I> CH,F
C)CH,F> CH,Br> CH,Cl> CH,I D) CHF> CH,CI> CH,Br > CH,I 52. Th

H
40. The common name of 1-Chloro-2, 2-dimethylpropane is
(A)isopentyl chlorided-1-yli-Cr (B)n-pentyl chloride o-C (A

M C) isopropyl chloride

(A)3-Chloro-2-methylpentane
(C)2-Chloropentane cabasd
D)neo-pentyl chloride
obi 41. Which among the following compound is NOT optically active?
(B)2-Chloro-3-methylpentane
(D)3-Chloropentane
53.
W
su
(A
54.T
(A
 Identify 'A' in the following reaction. Halogen Derivatives (259)
42.

sOCl,PneB KCN(alco)
reflux A
propane nitrile
(A)Ethanol (B) Propan-1-ol
. (C)1-Chloropropane
(D) Propane

n
JUPAC name of isobutyl chloride is
(A)2-chloro-2-methylpropane

o
(B)2-chlorobutane

is
C)1-chloro-2-methylpropane (D)2-chloropropane
Which among the following is
NOT obtained when bromobenzene
and sodium in presence of dry ether? treated with bromoethane
(A)Dipheny (B)n-butane
45. ldentify "B' in the following reaction.
(C)Toluene (D) Ethylbenzene

e s
CH
(A)CHCOOC;Hs
B
(B) CH,COOCH (C)CH,COOC;Hs

t
(D)CH,COOCHs
b
46. Which of the following is least reactive towards SN' reactions?
(A) CH-CH(Br)- CH, orssrofon 6) CH-CH;-Bro

u
bod
(C) CH-Br AOe.0/0) (D)(CH,)^C-Br

hlondes
47. Which
(A) tert-butyl bromide
C)isobutyl bromide 16toigonq lyras ce

D o
among the following has highest boiling point?uwolior a p
(B)n-butyl bromide
(D) sec-butyl bromide

number of optical isomers possible for 3, 4-dichloropentan-2-ol is

-2
otta

1
48. The
(B) Four (C) Sixteen (D)Two
(A)Eight

(A)3 (B)5

0 2
49. How many chlorine atoms are present in a molecule of DDT7
(C)4

the correct decreasing order of reactivity of

S0. 1dentify
(D)2
alkyl halide with ammonia?

2
(B)R-I>R-CI> Br R-
Br>R-I
(A)R-CI>R- - I> R - Br> R-CI (A
(C)R-Br>R-Cl>R-Iod0-()(D)R

T
freons'
S1. Which of the following is NOT an example of Chloro difluoromethane
(A)Diphenyl (B) A

E
difuoromethane
9Irichloro fluoromethane ueato(D) Dichloro

C
Br
HC belongs to
52. The organic compound

T
(D) allylic halide
vinylic halide C) aryl halide
(A) benzylic halide B) sulphonation of chlorobenzene
with concentrated

H
obtained in the
is the major product
what
sulphuric acid?
obiol3-Chlorobenzene sulphonic acid
(B)

M orobenzene sulphonic acid) (D) Benzene

sulphonic acid
(C ene sulphonic
(C)2- Chlorobenzene acid 3-dichloro-4-methylpentane is
present in 2, One
54. The
number of asymmetric
as carbon atoms
(C) Two HDdhD)
(A) Four (B) Three
 Tdentiff
68.(A)R-
Questions
(260)MHT-CET Exam sym-trichlorobenzene? trichlorobenzene ()R-
IUPAC name of (B) 1,2, 4 trichlorobenzene
55. What is 4-trichlorobenzene How D
(A) 1, 3, (D) 1,3,5 69. A)Ze
trichlorobenzene Fittig reaction?
(C)1,2,3- example of Wurtz
the following reactions anis
in presence of anhydrous AICI, form Whic
56. Which
among acetylchloride 70.

n
(A)
Chlorobenzene reacts with (A) 2
4-chloroacetophenone. benzenediazonium chloride. (C)2
-chloro-4-nitroben.

o
form
with NaNO,/HCI to conc.H2S04 to form
(B) Aniline reacts

is
conc.HNO; and sodium and dry ether
ether formi Whic
Chlorobenzene reacts with in presence of 71.
(C) with methylbromide brom
reacts
(D) Bromobenzene
(A) F

s
toluene. sodium metal in Dres.
2,5-dimethylhexane by reacting with ence
Wha
that gives
57. Identifjy the compound

e
72.
of dry ether. tert-butyl bromide (D) sec-butyl bromide (A)

s
isobutyl bromide (C)
(A) n-butyl bromide (B) 16 optical isomers?
carbon atoms are present in a molecule if it has 73. Alky

t
58. How many asymmetric
(B) 5 (C) 2oHO() Wh
(A) 3 (A)

b
SN* reaction for (CH) DIEagoiwolto i a
59. What is the relative rate of
(C) 2.0
(C)
(B) 37

u
(A) 0.0008
chlorobenzene? 14. Idet
60. What is bond length of C- Cl bond
in
C) 0.96 A (D) 1.70 A O

o
(B) 1.77 Å
A) 1.42 Å
61. Identify the product of following reaction geiwofiol od gnoe do
?
D u
CH,-Br+C.H,COOAg obiraord (A
(A) Ethyl ethanoate ned iud-se(C (B) Ethyl propionate bimud idodoal C)

1
(C) Methyl propionate (D) Methyl ethanoate on
oirolb igo to radtna 75. WI

2
62. Identify product B in the following reaction. pla
KON(aleo) A
Bromoethane- B
(A
(A) Acetamide
63. Identify the major product 'B'
Propene
AAKOHB
2 0
(B) Acetic acid
in folowng
(C) Propionic acid (D) Propionamide

reaouonno sGieoránbitoaT03 od
C
76. Id

T
(A)Propan-2-ol B)2-Chloropropane
(C)Propan-1-ol (D)1-Chloropropaneolotetoda
e
A
KCN(alcoholie),

CE
64. Identify A in the following reaction,e

A
Propane nitrile + Potassium bromide toliohro
77.W
(

T
(A) 2-Bromopropane (B) 1- Bromopropane
C)Propan-2-ol (D) Bromoethaneiiogroo

H
65.The boiling points of different alkyl halides having same alkyl group decrease in the order 78.I
(A)R-CI>R-I> R-F>R-Br (B)R-Br> R-Cl>R-I>R-F
botmoo (C) R-F> R-Cl>R-Br>R-I

M
(D)R-I>R-Br>R-Cl>R-F
66. What is UPAC name of neopentyl chloride?
(A)1-Chloro-2,2-dimethylpropane (B) 3-Chloro-2,2-dimethylpropane(A
(C)1-Chloro-3-methylbutane
el)(D)1-Chloropentanerdorof)S 79.1
67. Which of the following compounds has highest C-X bond strength?tedeuse ont
O
(A)CH3-F (B) CH3-Cl (C)CH-Br (D)CH-I
 Halogen Derivatives (261)
correct order of reactivity of alkyl halide
68. Iden with ammonia.
(A)R-I> R-Br> R-CI (B)R-I>R-Cl>R-Br
(C)R-CI>R-Br> R-I
(D)R-Br>R-Cl> R-I
many asymmetric
asyr carbon atoms are present in neopentyl
69. How
(A)Zero (B) Three chloride?
(C)Two (D)One

n
of the following Is an optically
70.Which
hich inactive compound?
(A)
2-Bromo-3-methylbutane (B) 2, 2-dichlorobutane

o
(C) 2-Hydroxypropanoic acid (D) Butan-2-ol
71. Which of
following is NOT formed when a equimolar mixture
the
he 1

hromobenzene is treated with sodium metal in dry ether?

of romomethane and
is
s
(A) Ethane (B) Ethylbenzene (C) Diphenyl (D) Methylbenzene

e
2.What is molecular formula of allyl bromide?
(A)CHBr (B)C,H,Br (C)CHBr (D)CHBr

What is the name of this

(A) Wurtz - Fittig reaction
reaction?
(B)Finkelstein reactionbepo s
73. Alkyl chloride when treated with sodium iodide in presence of dry acetone forms
bro

t
alkyl iodide:

(C) Swarts reaction

b
(D)Wurtz reaction
moo s brs 030

u
74. Identify A and B respectively in the following conversion.

o
Ethene Bromoethane Ethyl propionate er
Drto yogtote brod 1-9
(B) Br/AIBrs, C.H,COOAg

D
(A)HBr, CaH,ONa
C)HBr, CaH,COOAg (D) Br-/AIBr, CH;ONa
preparation of foamed
compounds is used as foaming agents in

1
*75. Which among the following
plastic?

2
(A) Carbon tetrachloride Blpoda Suuto8) Chlororormvibos yllieoitan sd oT
2522og triot- DE tO8
ODamide (C) Dichloromethane-isiro sollao o1s equo(P) Freonso

0
H HH H1O
76. Identify major product 'B' in
following reaction.

But-1- enePeroxide
Br
2 A AgCNB
HHHH

. E T
(A) isobutyl cyanide
HRDH
(C)n- butyl cyanide
ogofit (B) n-butyl isocyanide
D)sec. butyl isocyanide
halides is optically
active?

C
Which among the following alkyl (B) isobutyl chloride
(A) sec. butyl iodide butyl bromide
D) tert.
(C)n butyl bromide

unthe
F
order

HT 78. Tdentify

2-Bromobutane-
in the following reaction.
'B'
KOHaloo A-HB

(B) 2-lodobutane
(C) 1-
oneinoqoofi)-poo
Iodobutane (D) Butan-2-ol

M
(A) But-1-ene o
series of reactions.ero91 BO
19. Identify comp following 3009891 gntstgodotedsh
mpound A in the il ovtg bas
BACNn-butylisocyanide
Aa (C) But-1-ene
(D) Butanal
(A) But-2-ene (B) Butan-2-ol
 3-met
Questions
MHT-CETExam SOLUTIONS
(262) CH3

are gaseous & hence, easy toremove.

choices in which product
1 (A) from given alkyl ch (B)
Finding the
reaction
RCI+SO T +HCI 1 removed easily to get pure ide. 8.
R
OH+SOClh by-products and can be

n
are gaseous alkyl chloride.
sO and HCI method for
preparation of
C
It is best

o
refhw
reacts with NaBr under

is
when alcohol
2. (A) reaction takes place,
Nucleophilic substitution
rore Br

s
QH
NaBr and conc HSO4 CH-CH-CH

e
CH
CH-CH-CH 2-bromopropane

s
2-propanol
as

t
ibor chlorine atom is smaller in size
3. (A) bond length because
C-CIbond length is shorter than C-I
compared to iodine atom.

i) C-Cl bond is
of C and Cl as
more ionic than C-I bond
because of greater
compared to that of carbon and
iodine.rosqpor 6brts b
difference in electronegativities

u Aitebl
(i)More ionic character of bond,

4. (A)
C-Cl
more will be its strength.
bond is stronger than C-I bond

D o
because C-Cl bond is more ionic

-CH=CH, + KCI +H,0

than C-I
9.

1
HC-CH-CH, -CH,-Cl OCHCH,But-l-ene olot s0t 2oene 0W e
ahazo
5. (C)
To be optically active, compound or

0
atom and C-atom posses from different groups are
2
structure should possess a chiral or asymmetric
called chiral-carbon.
carbon

CI H H HH

H-c-c-C---H; 2
H CI H H

H-C-C-C-C-C-H
S o1dbog ojeit iinob/.t
H

HHH HH
E T HHH HH
1-CnioropentaneinusToy-(8Chioropentane
alyeno
o--15d
abinsseo lthudoat (A)

CI CH3

C
HHH H

H-C- c
CH3 Cl H H

C-C-C-HoogoiebiT
sbiseyo lrdn)

T
H-C- -C-C-C-H C-C-C-H
d ietu
bolo
broovadn(3)

H H H HHH
1-Chloro-2-methylpentane
H HHH H
3-Chloro-2-methylpentane
or1a assbl

M
(C asymmetric C-atom)
Hence, 1-Chloropentane is not chiral.
6. (C)
931dolol-(a) -1-18(A
Bthanolic KOH removes hydrogen and halogen atoms from a haloalkane, thus
dehydrohalogenating reagent and gives the same type of reactions.

Janstue33 fo- 8)
 Halogen Derivatives (263)
7. (A)
ethylhexane 1s an optically active alkane having
lowest molecular mass.
H ÇH
CH,-CH2-CH2--CH-CH CH-CH,-CH,--CH, -CH
H
Cl

n
8. (B) O-HDHDROKOJRD
CH3

o
CH
CH3-CH-CH -CH -Br CH, -H-CH=CH + H,O +KBr

is
CH
JESROH

= CH
CH OH
conc.H,SO4CH,-CH-CH-CH,+CH,-H-CH-CH-OH
CH

e s
s
CH-CH-CH ii) H20,A
rorto, Major (B) ou iv ote to Minor (C)
CH3 OH

CH- CH-CH-CH3
HI,
CH -
CH
C -CH,-CH +

b
CH I
t
CH- CH-CH-CH

CH
cos cisaloln ot onalq
eosI biboi(D)iw
2E970n tnioq
Major

o u Minor

sisosiom 2/A
gaiiod.poaninot eastth
(G)

D
7ebzo 190n0
9. (A) at sbilad lolls ganora niog gitod to
Alkaline ROH + KX
RX+KOHhydrolysis

1
OH
soaseong
CH,-C-H+KBrots oilaiosis to
a) CH,-ÇH-Br+ KOH
CH
0 2 1-phenyl ethanol HAHO

2
1-bromo-1-phenyl ethane the
this hydrolysis will lead to
compound having chiral carbon,
Due to the production of
obitmod ud

T
formation of a racemate.
KOH
H0* CH3-CH-CH,-CH,OH+KCI

E
CH-CH,-CH,CI
(6) CH- CH3 ()

C
CH3 3-methyl butanol
1-chloro-3-methyl butane

HT HO
()CH,CH,Br +KOH
Bromo ethane
CH,CH,CI+ KOH
CH,CH,OH+KBr
Ethanol

CH,CH,CH,OH +KCIomod-
Propanol
HO

atom, so these cannot

form a

M
(d) CH carbon
1-chloro propane do not have any chiral
(C) & (d)
Since, products of (b),
racemate. aneudlydom-8-omo8-
10. (C) (CaC03).
crystal
Nicol's prism i made up of calcite
 (B)
Monohaloge
25.
Questions
by 2" where n represent
CH
(264)
MHT-CET Exam
the
compound is given
i.
CH -
(C) of optical isomers of a compound.
11. number atoms in
The possible asymmetric carbon dod
total number of hexane. It
octane andd hexane. It does not fom
butane,
bromide gives
bromide and ethyl
ii. CH,

n
(D)
12.
Mixture of
n-butyl erCHCH,CH;CH,CH;CH;CH;CH +2NaR

o
ethane. CH,CH;Br+2Na- Octane

is
CHCH
2
siNeCH,CH,CH;CH +2NaBr
CHCH,Br+2NaDy
2
Butane
EtherCH,CH,CH;CH;CH;CH3+ 2NaBr 26. (D)
Dry

s
CH,CH,Br+CH,CH,Br+2Na
CHCH Hexane

e
(A)
13. (B)
14. (A)
Reaction of alkane with
fluorine is exothermic
process.

t s 2

15. (D)

b o-D-
(CaCO3).
up of calcite
Nicol prism is made

u
in Finkelstein
reaction
place
16. (C) specifically with iodide takes

o
Halogen exchange
(C)
17.(D) increases.
increases, boiling point

D
R-Cl > R-F.
As molecular mass point among alkyl halide is R-I>R-Br>
.
Correct order of boiling
20. (B) 21. (D)

1
18. (A) 19.(C)
to
elimination (no substitution) (D)

2
22. (B) bromide undergoes 27.
ammonia, t-butyl
In presence of alcoholic
give isobutylene. H,C
CH
CH,-C-CH,
r
+ NH, CH,
(alc.)
2
-=CH,
0 + NH,LBr

isobutylene
inoe lyreilg9t

36169S1- 10 200anot 28.(D)

3- Br

23. (C)

E T
t- butyl bromide CH
Allyl

C
24. (D) 29. (C)
foatvd lerfism- Br

(i) CH,-C-CH, - CH, C

T
() Br-CH,-CH-CH,-CH,
CH CH

Hso 1-Bromo-2- methylbutane

s
2-Bromo-2- methylbutane 30.(B)
1-1

M
(ii) CH, -CH-CH-CH,t iv) CH,-CH-CH, -CH, -Br
CH, Br CH,
2-Bromo-3-methylbutane 1-Bromo -3- methylbutane
 Halogen Derivatives (265)
25. (B)
Monohalo derivatives for CaHoX are

i CH-CH-CH-CH-X ii. CH,-CH,-CH-CH,

CH

o n
is
ii. CH,--X iv,
CH,-CH-CH,
CH
lodoolsCH,-X
26. (D)

e s
(A) CH,-Ç-CH,
H
(B) CH,-CH, -C-CH, -CH,
HDo t s
2-Chloropropane 3- Chloropentane

u b
(C)
Cl

CH,-C-CH,
O.H
-CH,
(D)
ornoorOt H
D o
CH,-Ç-CH,-CH,-CH,
loosb8
CH
2- Chloro -2- methyl butane
(6)

2 1 2- Chloropentane
(chiral carbon)

27.(D)

H,C CH-CH, - Br

2 0
-gM- H0-HO
obimord muiescgs fylt

T
3-Bromopropene (C,H,Br) E)
(O.2e

E onedom otouitb o2olioiCg

46.(D) gier en boatt (C-noT)(0e1)

C
CH,-CH-CH, -Cl
Allyl chloride (C^H,C) to onsroli0
lsoatoozoldoglog

T ouag xolgor spovg. giue loo 39801T 0

29.(C) do Jnqo 3uoithib ohdw

(

H CH,-CH-CH,-Br
CH, oitsuoss saueos

M
edie oiligonois
omo -2-
1-Bromo methylpropane
2- methylpropane
O
30.(B)
(C.e

sona
ea20 X0 itguste brod X03019boal
131D0
 40.(D)

Questions
(266) MHT-CET Exam (3et
31. (A) olatonol
+ KI + H,O
-CH,-I KOHae) CH, CH=CH,-

CH,-CH, A
(X)

n
Peroxide HBr
(D)

o
41.

KCN
CH,-CH,-CH, -CNN- alcohol -CH,
CH, - CH,
(Y)
-
- Br

is CH

s
() A

32. (D)
33. (A)

s e Asit

t
CH 42.(A)

CH,-C-CH, -CH,-Cl
CH,
neohexyl chloride
u b
ofBgoieo1O
CH

34.(A)
NaBr
CH,-CH,-0n H,SO,,ACH,-CH,-Br
Ethanol
Bromoethane
D o
H,O

nothes ise

2 1 (A)

Mg Dry ether nt-gtol

43.(C)
CH

2 0 CH, -CH Mg- Br

Ethyl magnesium bromide
-
-H9-H09

T
(B) IUP
35. (C)

E
44.(C)
Dichloro difluoro methane (CF2Cl;) - (Freon-12) used as refrigerants and for ar

C
conditioning.
36. (C)

T
Chlorination of alkanes in presence of sunlight gives a complex mixture of mono, d
polychloroalkanes which is difiicult to separate.
Di
H
37.(D)
38. (D)
45.(

M
Because aromatic electrophilic substitution with iodine is reversible and with fluorine 1s n
reactive. C
39. (D) (.0 arger Et
The size of halogen atom increases from F to I, which increases the C X bond length. L
the size, greater is the bond length and weaker is the bond formed. 46.(C
Hence the order of C-X bond strength in CHX is, CH,F> CH,Cl> CH,Br> CH3I.
On
 .(D) Halogen Dertvatives (267)
CH
CH,-C-CH, -CI
CH
neo-pentyl chloride

n
(1-Chloro-2,2-dimethylpropane)

o
41.(D)

CH,-CH,--CH,-CH is
H
3-Chloropentane

e s
As it does not contain chiral carbon atom, it is optically inactive.
42.(A)

t s
CH,-CH,-OH +SOC
Bthanol
PyidineCH, -CH, -Cl+ HC11
reflux
Chloroethane

u b
So,
T

sbisd olin 2o dgnents brod X CH,-CH,-CN

D o
AKCN(aco)

KCId

1
otet 1owole 1s 19- b Propane nitrie
43.(C)
CH,-CH-CH, -CI
CH,

0 2
Isobutyl chloride

2
IUPACname 1-Chloro-2-methylpropane

s T
44. (C)

E
B2Na+BCa
Dryetber

C BromobenMene Payd bromide

self-coupling products.
Bybease

T
0n0 Dphenyl and n-butane are
6.(A)

H CH, Br
AIB
CH,BrCH,COOA
CH,COOAg ,CH,COOC,H, +AgBr
4
Ethyl Acetate

M Ethane Ethyl bromide

(bo
(B
46.(C)
bere (A)
towards SN' reaction is
rder of reactivity in alkyl halides
ertiary> Secondary> Primary
 MHT-CET Exam Questions (C)
(268) 54.
H,C-CH-
47..(B)
the boiling point
decreases with branching.
For isomeric haloalkanes,
(A) 2,3-dichloro-4

H-- n
There are

o
two

3,
H
4-dichloropentan- 2- ol
is
55. (D)

Number of chiral carbon atoms (n) = 3

Optical isomers possible
are 2" =2 = 8

e s C1

s
49. (B)
1,3, 5-trich

b t 56. (D) Wurtz-F

50

u
-a

50. (D)
DDT

X bond length increases, the C

D o
X bond strength of alkyl halide decreases
Bromo ben

1
As the C 57. (B)
Therefore, R- I reacts at faster rate with NH3 and R -Cl at slower rate.
H,C-CH
51. (A)

2
Freons are chlorofluoro compounds of methane and ethane.
52. (C)
0
10H399-0 CH

2 eudoal
Br sbisokis
HC
is an aryl halide. odyd tor C-o1oial19nn4901

53.(A)

E T
diMHS

C
It follows
SO,H 58. (D)
+H,SO,

T
(fluming) If the nun
C2 thenthe
So,H

H
Chlorobenzene 1-Chlorobenzene
Sulphonic acid 4-Chlorobenzene 59.(A)
sua minor product) Sulphonic acid

M (major product) 3 alkyl

The relat

baoose ata
 www

Halogen Derivatives (269)

54. (C)
-CH-CH-CH-CH,
o
2.3-dichloro-4-methyl pentane

o n
is
There are two asymmetric carbon atoms.
55. (D)

CI CI
e s
1,3,5 trichlorobenzene is symmetrical.
56. (D)
Wurtz-Fittig reaction:
olidn onocor

t s
-Br +CH,Br + 2Na dry ether ,H QEHO-09
NaBr

u b www

halide ta
Bromo benzene

57.(B)
o9 Toulene

D o
1
H,C-CH-CH, Br+2Na + Br-CH,-ÇH-CH, qo D
- 16H9D
oneiteomot
CH,

2
CH
dry ether
quor fpltoocose sad gsbileliolls nrdii

sboe H.C-CH-CH,
CH,

2 0
-CH, -CH-CH,
CH -4i-9
9gour1021

T
2, 5-dimethylhexane
813-9-9,

E
It follows Wurtz reaction.
58.D)
lf the number of

C
chiral/asymmetric carbon atoms are 4,
then the number of optical
isomers = 2" - 2" =
16 (n =4) qoqigdloub--o60-1

HT
59.(A)

alkyl halides undergo Syl reaction.

The relative rate of Sn2 reaction for (CHs)5C- Br
= 0.0008 10-0 <4H

M
 str
re
orderof
DecreasirngC-Br>
A)
C-Cl> bond
270) MHT-CET Exam
Questions
bond
(M
60. (D)
alk

has partially

n
benzene
TheC-Cl bond in due to resonance forms gamBooibib- 694) CH
double bond nature
HC-C-CH,-C

o
1.70 A.da olstagg
on t

is
length in Chlorobenzene is
Sothe C-Cl bond (C) 22 CH
Chloride
61. (C)

s
CH,-Br+C,H,COOAg CH,COOCH, +AgBr Neopentyl carbon
Methyi propanoate
AsymmetriC

62. (C)
CH,Br C,H,CN (A)
C,H,COOH
(8) Jidomrga at o0sodo toliou-,
s e 70.
(B)

t
(A)- Propane nitrile
H,C-C-CH,C
(B)- Propionic acid. roilatt011-shu

b
CI
63. (A) 2,2-dichlorobut
HC-CH-CH,

u
H,C-CH=CH, H,C-CH-CH, no ch
OH Since it has

o
CI
Propene
2-Chloropropane
Propan-2-old odoned 1.(B)

D
'A B
CH,- Br+ 2Na

1
64. D)
CH,CH,Br CH,CH,CN KB
Potassium d-s+
1d-0-H9-9,

2
Propane nitrile bromide
Bromoethane CH,-CH,t

0
65. (D) increasing atomic
group, the boiling point increases with
Within alkyl halides having same alkyl increase in size and Ethane
van der Waals force increases with
mass of halogen because magnitude of
mass of halogen.
R-I>R-
2
Br> R- Cl> R-F Self-Cc
66. (A)
CH

E
H,C-C-H,-CT 9xodleaitstutb-2S
noitose7 suWaolloh l
12. (C)

C
CH
Saoino2i tiotgo 1odreun sdl aedi
HC=CH-

T
to
1-Chloro-2,2-dimethylpropane ) 3
Allyl b
67.(A) attraction with carbo. 3.B)
is more electronegative, it has strong

H Since size of F atom is small and it

Strength of C- X bond decreases as
H3C-F> CH3- Cl>HC Br>HC-I trH)
follows
zotpo1p7St0
thstt iye0g1shod6u15 9biier lella
iulor sal R-Cl+N

M
Alkyl
Chloride
This
reacti0
 Halogen Derlvatives (271) ww

Oecreasing order of strength ofC- X bond is

C-Cl C-Br > C-I
bond bond bond

n
(More reactive
alkyl halide)

.(A)
CH
italg orrs

o3 iso
s
HC-C-CH, -Cl

e
CH

s
Neopentyl Chloride
Asymmetric carbon atoms = Zero.

70.(B)

b t
u
HC-C-CH,CH,
aoisgo ai it oe ida su at sbiboi lyud opul

o
Cl
2,2-dichlorobutane

D
Since it has no chiral carbon atom
it is optically inactive. OH0-H-9,H
HOX
71.(B) s-S-i8

1
Dry ruaitiuroitoE-S
CH,-Br+2Na+ Br- ether

CH,-CH,+
0 2 O-D-HO-9,
saa
Crease m
Ethane
2
Dipheny! Methyl bezene orns-Rre

T
(Cross Coupling)

E
Self-Coupling Products1a1

C
72.(C)
Allyl 'C -0HONO-9

T
obiangaoeud-
H,C=CH-CH

H Br
Allyl bromide Ceouco

M
73.B)
Dry acetone R-I+ NaCI
R-Cl+Nal or Methanol Alkyl
Alkyl Iodide
Chloride reaction.
This reaction is known as Finkelstein
 Questions
(272) MHT-CET Exam
74. (C)

H,C CH, HBr,H,c-CH,

- Br c.H,COOAE,C.H,C-CH,CH, +Ag
A

o n
is
Ethylpropionate
Ethene Bromoethane Alcohols:
attachedto

s
75. (D) plastic.
in preparation of foamed
Freons are used as foaming agents
76. (B)
CH-CH-CH=
But-1-ene
CH2Peroxide CH-CH2
HBr CH2 -CH2
1-Bromobutane
- CH2 -CH2
- - Br

s e Phenols

t
- NC attached to
AgENCH -CH For
examp
n-butyl isocyanide
77. (A)

u b
o
H,c--CH,CH,
HO-D-98

D
it is optically active.
Since secondary butyl iodide has one chiral 'C' atom,
9csiudaoll Ethers-

1
78. (B)
HC-CH-CH,CH,KOHHC- H,C-CH-CH, -CH,

2
KOH two aryl
But-2-ene
Br

0
A
Prep
2-Bromobutane 2-Iodobutane 1.1
79. (C)

2
T
HBr
H,C=CH-CH, -CH, H,C-CH, -CH, -CH,
Na,O,

E
But-1-ene

C[A]
Br
P1- Bromobutane
2.

T
[B]

H
AgCN,A
H,C-CH,CH, CH, - NC

M
n-butylisocyanide

sbiend lel

13n
2ootiek
ellA
alipol
anota