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SEC: INC.

JR_*CO-SC(MODEL-A) Date: 14-08-22


Time: 3 Hrs Max. Marks: 180
14-08-22_INC.JR.IIT_STAR CO-SC(MODEL-A) _JEE ADV_CAT-1_SYLLABUS
PHYSICS: (100% CUMULATIVE)

SYLLABUS COVERED FROM 06-06-22 TO 13-08-22

CHEMISTRY: (100% CUMULATIVE)

SYLLABUS COVERED FROM 06-06-22 TO 13-08-22

MATHEMATICS: (100% CUMULATIVE)

SYLLABUS COVERED FROM 06-06-22 TO 13-08-22


Narayana IIT Academy 14-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-1_Q’P
Time: 3:00Hour’s IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Questions with Multiple Correct Choice
Sec – I(Q.N :1– 6) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Numerical Value Type
Sec – II(Q.N:7 –14) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Sec – III(Q.N :15-18) Matrix Matching Type +3 -1 4 12
Total 18 60

CHEMISTRY:
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Questions with Multiple Correct Choice
Sec – I(Q.N :19– 24) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Numerical Value Type
Sec – II(Q.N:25 –32) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Sec – III(Q.N :33-36) Matrix Matching Type +3 -1 4 12
Total 18 60

MATHEMATICS:
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Questions with Multiple Correct Choice
Sec – I(Q.N :37– 42) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Numerical Value Type
Sec – II(Q.N:43 –50) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Sec – III(Q.N :51-54) Matrix Matching Type +3 -1 4 12
Total 18 60

INC.Jr.IIT_*CO SC Page No: 2


Narayana IIT Academy 14-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-1_Q’P
PHYSICS MAX.MARKS: 60
SECTION- I
(Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which
are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
1. A 10 km long straight road connects two towns A and B. Two cyclists start
simultaneously, one from town A and the other from town B. On reaching the opposite
town a cyclist immediately returns to his starting town whereas the other cyclist takes
some rest and then returns to his starting town. Both of them can ride at a speed 20
km/h in absence of wind but during their whole journey uniform wind from town A to
B increases speed of a cyclist going with the wind by the same amount as it decreases
the speed of the cyclist going against the wind. Both the cyclists meet twice, first 2 km
and then 6 km away from one of the towns
A) One of the cyclist takes rests in town B
B) One of the cyclist takes rests in town A
C) Speed of wind is 12kmph
D) The time of rest of one of cyclist in a town B is 18.75 minutes
2. There is a narrow bridge somewhere on a road connecting two towns. Two cars travel
from one of the towns to the other with a constant speed u1 everywhere on the road,
except on the bridge, where they travel with another constant speed u2 . How the
separation s between the cars varies with time t is shown in the following graph

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Narayana IIT Academy 14-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-1_Q’P
A) The speed u1 of the cars on the road is 25 m/s

B) The speed u2 of the cars on the bridge is 10 m/s

C) Length of the bridge is 700m

D) Length of bridge is 600m

3. A train passes a platform with a uniform speed. A boy standing on the platform decides
to estimate length of a coach and speed of the train. For this purpose, he first runs with
a constant speed of u  10 km/h in the direction of the motion of the train and passes by
a coach in n1  30 steps. Then he turns back, runs at the same constant speed and passes
by a coach in n2  20 steps. If the boy covers a distance l  1.0 m in each step, answer the
following questions

A) The speed of the train is 2 kmph B) The length of each coach is 24m

C) The speed of the train is 3 kmph D) The length of each coach is 20m

4. The system shown in figure is in equilibrium. Surface PQ of wedge A, having mass M,


is horizontal. Block B, having mass 2M, rests on wedge A and is supported by a
vertical spring. The spring balance S is showing a reading of 2Mg . There is no
friction anywhere and the thread QS is parallel to the incline surface. The thread QS is
cut. Then, just after thread QS is cut,

A) The acceleration of wedge A is g / 2 m/s

B) The acceleration of block B is zero

C) The normal contact force between wedge A & and block B is zero

D) The normal contact force between wedge A & and block B is non-zero

INC.Jr.IIT_*CO SC Page No: 4


Narayana IIT Academy 14-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-1_Q’P
5. Six particles are located at the vertices of a regular hexagon of side ‘a’. At t  0 , they
all start moving simultaneously with constant speed ‘v’. The first particle is heading for
second, the second particle is heading for the third and so on, Then choose the correct
option(s)
v

v v

v v

a 2v 2
A) At t  , the acceleration of each particle is
2v 3a

a 3v 2
B) At t  , the acceleration of each particle is
v a

a 3a
C) At t  , the radius of curvature of trajectory of each particle is
2v 2
a a
D) At t  , the radius of curvature of trajectory of each particle is
v 3

6. On a train moving along east with a constant speed V , a boy revolves a bob with string
of length l on smooth surface of a train, with equal constant speed V relative to train.
Mark the correct option(s)

A) Maximum speed of bob is 2V in ground frame.


4mV 2
B) Tension in string connecting bob is at an instant
l

mV 2
C) Tension in string is at all the moments.
l
D) Minimum speed of bob is zero in ground frame

INC.Jr.IIT_*CO SC Page No: 5


Narayana IIT Academy 14-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-1_Q’P
SECTION - II
(Maximum Marks : 24)
This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the second
decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct numerical value is entered as answer.
Zero Marks : 0 In all other cases.
7. One day you were on a picnic with your class. During return journey from the picnic
spot to your school, it began to rain, therefore the driver reduced speed of the bus and
drove with an average speed u1  60 km/h instead of the scheduled average speed u0  70
km/h. After the rain stopped, the driver drove the bus at an average speed u2  75 km/h
and covered the remaining s  40 km exactly in schedule time. The time duration of rain
is_________minutes.
8. In the setup shown, magnitude of the force F exerted on the block A is so adjusted that
the block B and the ball C remain motionless relative to the block A without contact
between A and C. All surfaces in contact are frictionless, masses of these bodies are
mA  12kg mB  5kg and mC  3 kg respectively. Acceleration of free fall is g  10 m / s 2 .
Find the value of necessary force F (newtons)

9. In the figure shown all the surfaces are frictionless, and mass of the block, m  1 kg. The
block and wedge are held initially at rest. Now wedge is given a horizontal acceleration
of 10 m / s 2 by applying a force on the wedge, so that the block does not slip on the
wedge. Then work done (in Joule) by the normal force in ground frame on the block in
3 seconds is

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Narayana IIT Academy 14-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-1_Q’P
10. A small particle initially at point p starts moving from rest. The whole space where
particle will move is divided into three regions as shown in figure. In region (i) particle
accelerates through  5 m / s 2  where direction of acceleration is along the normal of the

screen, while in region (ii) the acceleration acts in such a way that it is always
perpendicular to the direction of motion resulting the particle to move on a circular
20
track having radius m . There is uniform acceleration in region (iii) in such a manner
3

that velocity of particle become thrice (without change in direction) when it just reach
the screen. Find the average speed of a particle (in m/s).

11. AB is an inclined roof and a body is projected from origin towards the roof as shown in
figure. The value of h (in metre) for which body will just touch the roof is

[Given     450 and u  10m / s, g  10 m / s 2 ]


y

h
u

 
x
C B

12. Two points, A and B, are located on the ground at a certain distance d  10 2m apart.
Two rocks are launched simultaneously from points A and B with equal speeds but at
different angles. Each rock lands at the launch point of the other. Knowing that one of
the rocks is launched at an angle   37 0 with the horizontal, what is the minimum
distance (in metre) between the rocks during the flight?

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Narayana IIT Academy 14-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-1_Q’P
13. A particle P is moving on a circle under the action of only one force acting always
d 2  d 
2

towards fixed point O on the circumeference. Find ration of &  at an instant


dt 2  dt 
  450

14. In the shown figure inside a fixed hollow cylinder with vertical axis a pendulum is
rotating in a conical path with its axis same as that of the cylinder with uniform angular
velocity. Radius of cylinder is 30 cm, length of string is 50 cm and mass of bob is 400
gm. The bob makes contact with the inner frictionless wall of the cylinder while
moving the minimum value of angular velocity of the bob, so that it does not leave
contact is_____rad/s

SECTION - III
(Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has TWO (02) matching lists: LIST-I and LIST-II.
FOUR options are given representing matching of elements from LIST-I and LIST-II. ONLY ONE of these four
options corresponds to a correct matching.
For each question, choose the option corresponding to the correct matching.
For each question, choose the option corresponding to the correct matching.
Full Marks : +3 If ONLY the option corresponding to the correct matching is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –1 In all other cases.
15. A block of mass m is stationary with respect to a rough wedge as shown in figure.
Starting from rest, in time t work done on the block: ( m  1kg ,  300 , a  2m / s 2 , t  4s )

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Narayana IIT Academy 14-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-1_Q’P
Column-I Column-II
A By gravity p 144 J
B By normal reaction q 32 J
C By friction r 56 J
D By all the forces s 48 J
t None
A) A  t ; B  p; C  s; D  q B) A  p; B  s; C  q; D  t

C) A  t ; B  p; C  s; D  r D) A  t ; B  s; C  p; D  q

16. A block of mass m lies on wedge of mass M. The wedge in turn lies on smooth
horizontal surface. Friction is absent everywhere. The wedge block system is released
from rest. All situation given in column-I are to be estimated in duration the block
undergoes a vertical displacement ‘h’ starting from rest (assume the block to be still on
the wedge, g is acceleration due to gravity)

Column-I Column-II
Work done by normal reaction acting
A p Positive
on the block is
Work done by normal reaction
B q Negative
(exerted by block) acting on wedge is
The sum of work done by normal
reaction on block and work done by
C r Zero
normal reaction (exerted by block) on
wedge is
Net work done by all forces on block Less than mgh in
D s
is magnitude
A) A  q; B  p, s; C  r , s; D  p B) A  q, s; B  p, s; C  r , s; D  p, s

C) A  q, s; B  p; C  r , s; D  p, s D) A  q, s; B  p, s; C  r ; D  p, s

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Narayana IIT Academy 14-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-1_Q’P
17. Match the columns

Column-I Column-II
(Situation)
  
A p F2  F2  F3

is centripetal force

Front view of a car rounding a curve with constant


speed

B q F1 is static friction

Passengers in a rotor not sliding relative to rotor


wall, cylindrical rotor is rotating with constant
angular velocity about its symmetry axis

C r F1 can be in direction
opposite to that shown
in figure

Particle kept on rough surface of a bowl, no


relative motion of particle w.r.t bowl and bowl has
constant angular velocity
  
D s F1  F2  0

Car moving on a banked road with constant speed,


no sideways skidding
   
t F1  F2  F3  0

INC.Jr.IIT_*CO SC Page No: 10


Narayana IIT Academy 14-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-1_Q’P
A) A  p; B  q, p, s; C  p, q, r ; D  p, q, r

B) A  p, q; B  p, q; C  p, q, r ; D  p, q, r

C) A  p, q; B  p, q, s; C  p, q, r ; D  p, q, r

D) A  p, q; B  p, q, s; C  p, q; D  p, q, r

18. A boat is being rowed in a river. Air is also blowing. Direction of velocity vectors of
boat, water and air in ground frame are as shown in diagram


Vwater

Vboat


Vair

Column-II
Column-I
(Possible directions)

A Direction in which boat is being steered p

B Direction in which a flag on the boat may flutter q

C Direction of velocity of water relative to boat r

Direction of velocity of air relative to a piece of


D s
wood floating on river

A) A  p; B  q, s; C  s; D  p, r B) A  q; B  q, s; C  s; D  p, r

C) A  p; B  q, s; C  s, r ; D  p, r D) A  p, q; B  q, s; C  s; D  p, r

INC.Jr.IIT_*CO SC Page No: 11


Narayana IIT Academy 14-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-1_Q’P
CHEMISTRY MAX.MARKS: 60
SECTION- I
(Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which
are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
19. Consider the following reversible processes being performed on 5 moles of argon

Select the correct choice(s)

A) SX  Y  95.7 JK 1 B) SZ  Y  95.7 JK 1

C) SX  Y  SX  Z  SZ  Y  95.7 JK 1 D) SXZY  0

20. Which of the following statements is/are incorrect

A)When the entropy change of the system and the entropy change of the
surroundingsare added, the sum is always positive.

B)The entropy in isolated system, with P – V work only, is always maximized


atequilibrium.

C)During a spontaneous process, gibbs free energy change will always


decreaseirrespective of the changes in temperature and pressure.

D) Phase change of a substance at a constant temperature is an isoentropic process.

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Narayana IIT Academy 14-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-1_Q’P
21. For an ideal gas select correct relationships.

1
A) Z1  [constant P] B) Z1  P [ constant V]
T

1 1
C) Z11  2 u avg N*2 D) Z11  [constant P]
2 T 32

22. Which of the following is / are correct for a gas obeying vanderwall’s equation?
A) A gas having negligible size and reasonable intermolecular force will follow
 a 
P  2  Vm  RT
 Vm 

B) A gas having negligible intermolecular force and reasonable size will follow
Pb
Z 1
RT

C) TA gas having negligible size and negligible intermolecular force will follow
PVm  RT

D) At Boyle’s temperature gas will follow PVm  RT at all pressure


23. The standard enthalpies of formation of CO 2 g  and HCOOH  l  are 393.7 kJ mol 1 and
409.2 kJ mol 1 respectively at standard condition. Which of the following statementsare
correct?
A) 393.7 kjmol 1 is the enthalpy change for the reaction, Cgraphite  O2g  
 CO2 g 

B) The enthalpy change for the reaction, CO2g   H2g  


 HCOOH l would be 15.5 kjmol 1

C) The enthalpy change for the reaction, is 409.2 kJ mol1


D) The enthalpy change for the reaction, H 2 g   CO2 g  
 H 2 Ol   CO g  is 409.2 kJ mol 1

24. Which of the following represent(s) H o atomization , H O s  ? 2

A) H o sub lim ation, H O s   2H o BE ,O  H


2

B) H o fusion, H O s   H o vapourisation, H Ol 


2 2

H o BE ,O O
C) H o formation , H O s   H o BE , H  H 
2
2

D) H o fusion, H O s   H o atomization, H Ol 


2 2

INC.Jr.IIT_*CO SC Page No: 13


Narayana IIT Academy 14-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-1_Q’P
SECTION - II
(Maximum Marks : 24)
This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the second
decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct numerical value is entered as answer.
Zero Marks : 0 In all other cases.
25. For a Vander waal gas having Critical Temperature 400K and Critical Pressure 160atm,
 1 
the reciprocal of slope   of Z vs P curve at a very high pressure and 300KT
 slope 
X
emperature is found to be X. Find out the value of ?
192

Given : R = 0.08 atm litre / mole-K.


26. The cyclic unsaturated hydrocarbon, naphthalene  C10 H8  which maybe written as

, absorbs 5 mol of hydrogen per mole of hydrocarbon on complete


hydrogenation, the accompanying enthalpy change H o  345 kJ / mol of naphthalene.
The average enthalpy of hydrogenation of a (C = C) in a ring is –120 kJ/mol. Using this
data calculate resonance energy (in kJ/mol).
(Report your answer by dividing it by 85.)
27. A certain mass of anhydrous oxalic acid is converted into H2O, CO2 and CO, on
heating in the presence of H2SO4. The CO formed reacts completely with iodine
pentoxide to liberate iodine. The iodine thus liberated required 200 ml of 0.2 N
thiosulphate. The mass (in g) of oxalic acid taken was
28. When ammonium vanadate is heated with oxalic acid solution, a substance Z is formed.
A sample of Z was treated with KMnO4 solution in hot acidic solution. The resulting
liquid was reduced with SO2, the excess SO2 boiled off and the liquid again titrated
with same KMnO4. The ratio of the volumes of KMnO4 used in the two titrations was 5
: 1. What is the oxidation state of vanadium in substance Z? Given that KMnO4
oxidizes all oxidation state of vanadium to vanadium (+5) andSO2 reduces V (+5) to V
(+4).
29. A quantity of 1.6 g of pyrolusite ore was treated with 50 ml of 1.0 N-oxalic acid and
some sulphuric acid. The oxalic acid left un decomposed was raised to 250 ml in a
flask. A volume of 25 ml of this solution when titrated with 0.1 N-KMnO4 required32
ml of the solution. The percentage of available oxygen in the ore is

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Narayana IIT Academy 14-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-1_Q’P
30. The average life time for then n = 3 excited state of a hydrogen-like atom is 4.8 × 10–8s
and that for the n = 2 state is 1.28× 10–7s. Ratio of the average number of revolutions
made in the n = 3 state to the average number of revolutions made in the n=2 state
before any transitions can take place from these states is 1 :x. The value of x is
31. A sample of hydrogen atoms containing all the atoms in a particular excited state
absorb radiations of a particular wavelength by which the atoms get excited to another
excited state. When the atoms finally de-excite to the ground state, they emit the
radiations of 10 different wave lengths. Out of these 10 radiations, 7 have wave lengths
shorter than the absorbed radiation and 2 have wavelength longer than the absorbed
radiation. The orbit number for the initial excited state of atoms is
32. An  –particle of momentum 3.2 × 10–20kgms–1 is projected towards the nucleus of an
atom of an element. If the distance of closest approach of  – particle is 1.5 × 10–13 m,
then the atomic number of element is (Mass of  – particle = 4 amu, chargeon electron
= 1.6 × 10–19 coulomb, NA = 6 × 1023)

SECTION - III
(Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has TWO (02) matching lists: LIST-I and LIST-II.
FOUR options are given representing matching of elements from LIST-I and LIST-II. ONLY ONE of these four
options corresponds to a correct matching.
For each question, choose the option corresponding to the correct matching.
For each question, choose the option corresponding to the correct matching.
Full Marks : +3 If ONLY the option corresponding to the correct matching is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –1 In all other cases.
33. One mole of a monoatomic ideal gas is taken through a cycle ABCDA as shown in
theP-V diagram. Column-II gives the characteristics involved in the cycle. Match
thewith each of the processes given in Column-I.

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Narayana IIT Academy 14-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-1_Q’P
List – I List – II
A) Process AB P) Internal energy decreases
B) Process B  C Q) Internal energy increases
C) Process C  D R) Heat is lost
D) Process D  A S) Heat is gained
T) Work is done on the gas
A) A-PR, B-PTR, C-QS, D-RT B) A-PTR, B-PR, C-QS, D-RT

C) A-PT, B-PR, C-QS, D-QRT D) A-PTR, B-PR, C-QST, D-RST

34. Match the following.

List – I List – II

A) P) 4s

B) Q) Any of the 5porbital.

Angular wave function independent


C) R) 3s
from  and 
D) At least one angular node. S) any of the 6d orbitals

Match each process given in List – I with one or more effect(s) in List – II. The correct
option is

A) A – PR; B –PS: C – PR; D – QS B) A – P; B –PQS: C – PR; D – QS

C) A – PQS; B –PR: C – PR; D – QS D) A – PR; B –PQ: C – PRS; D – QS

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Narayana IIT Academy 14-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-1_Q’P
35. Column I contains some chemical reactions and Column II contains some  H values
(in kJ). Match the correct  H in Column II for the chemical reaction in Column I with
the help of the following thermo chemical equations given.
H   aq   OH   aq   H 2O  l  ; H  57.3 kJ

H Solution of HA (g) = –70.7 kJ/mol

H Solution of BOH (g) = 20 kJ/mol

H Ionization of HA = 15 kJ/mol and BOH is a strong base.

List – I List – II
(Chemical Reactions) ( H values in kJ)
A) HA  aq   BOH  aq   BA  aq   H 2 O P) –42.3
B) HA  g   BOH  g   BA  aq   H 2O Q) –93
C) HA  g   H   aq   A   aq  R) –55.7
D) B  aq   OH   aq   OH  aq  S) 0
The correct option is

A) A – P; B – Q: C – R; D – S B) A – Q; B – S: C – R; D – P

C) A – R; B – S: C – Q; D – P D) A – Q; B – P: C – S; D – R

36. A volume of 6 L H2O is placed in a closed evacuated room of volume 827 L at the
temperature of300 K. The density of liquid water at 300 K is1.0 g/ml. The vapour
pressure of water at 300 K is 22.8 mm Hg. Neglect the change in volume of liquid
water by vaporization.
List – I List - II
A) Mass of water vapour formed (in g) P) 6
B) Moles of water vapour formed Q) 18
C) Approximately mass of liquid water left (in kg) R) 3
D) Total moles of atoms in vapour form S) 1
Match each reaction in List – I with one or more products in List – II and choose the
correct option.
A) A – Q; B – S: C – P; D – P B) A – Q; B – P: C – S; D – R
C) A – S; B – R: C – R; D – P D) A – Q; B – S: C – P; D – R

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Narayana IIT Academy 14-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-1_Q’P
MATHEMATICS MAX.MARKS: 60
SECTION- I
(Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which
are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
37. Choose the incorrect statement(s)?

10 10 10 10
A) sin 82 cos 37 and sin127 sin 97 have the same value.
2 2 2 2

3 3
B) If tan A  & tan B  then tan  A  B  must be irrational.
4 3 4 3

C) The sign of the product sin 2. Sin 3. Sin 5 is positive

D) There exists a value of  between 0 & 2  which satisfies the equation


sin 4   sin 2   1  0 .

38. Which of the following is / are correct?

8 tan x
A) tan x  3 tan 3 x 
1  3 tan 2 x

3 tan 9 9 tan 27


B)   12 tan 9
1  3 tan 9 1  3 tan 2 27
2

3 tan x
C) tan x  2 tan 2 x 
1  tan 2 x

3 tan 9 9 tan 27 27 tan 81 81tan 243


D)     30 tan 9
1  3 tan 9 1  3 tan 27 1  3 tan 81 1  3 tan 2 243
2 2 2

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Narayana IIT Academy 14-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-1_Q’P
39. If f n    cot    tan   2 tan 2  22 tan 22  ...  2 n tan 2 n   , n  N , then identify which of

the following option(s) is (are) correct?

   
A) f5  7   0 B) f5  8   64 C) f9  12   210 D) f9  12   0
2  2  2  2 

40. All the terms of an A.P. are natural numbers and the sum of the first 20 terms is greater
than 1072 and less than 1162. If the sixth term is 32 then

A) first term is 32 B) first terms is 7

C) common difference is 4 D) common difference is 5

41. The equation x2  a 2 x  b2  0 has two roots each of which exceeds a number c, then

A) a 4  4b2 B) c 2  a 2c  b2  0 C) a 2 / 2  c D) None of these

42. If x 2  4 y 2  12 xy, x  1, 4 , y  1, 4 , then

A) the greatest value of log 2  x  2 y  is 4

B) the least value of log 2  x  2 y  is 3

C) the range of values of log 2  x  2 y  is  2, 4

D) the number of integral values of  x, y  is 2 such that log 2  x  2 y  is equal to 3

SECTION - II
(Maximum Marks : 24)
This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the second
decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct numerical value is entered as answer.
Zero Marks : 0 In all other cases.
17 10 r
43. The value of   cos3 .
8 r 0 3

x 2 12
 e log e 4 is
x
44. The product of the solutions of the equation 2

x
45. The value of 0
that satisfies the relation x  1  x  x 2  x3  x 4  x5  .........
sin18

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Narayana IIT Academy 14-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-1_Q’P
22
46. If  1  tan  2    1  tan  45  2     2
 0

then  is :

47. Given x, y  R, x 2  y 2  0 . If the maximum and minimum value of the expression


x2  y 2
are M and m, and A denotes the average value of M and m, then find the
x 2  xy  4 y 2

value of 30 A.

1
48. If tan A tan B  , then  5  3cos 2 A 5  3cos 2 B  is equal to
2

49. If a, b, c, d are distinct integers in A.P such that d  a 2  b 2  c 2 , then find the value of
abcd

If 4sin 270     then the sum of digits in       2 


4
50.

SECTION - III
(Maximum Marks: 12)
This section contains FOUR (04) questions.
Each question has TWO (02) matching lists: LIST-I and LIST-II.
FOUR options are given representing matching of elements from LIST-I and LIST-II. ONLY ONE of these four
options corresponds to a correct matching.
For each question, choose the option corresponding to the correct matching.
For each question, choose the option corresponding to the correct matching.
Full Marks : +3 If ONLY the option corresponding to the correct matching is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –1 In all other cases.
51. Match the following

Column – I Column – II
7  6 tan   tan 2 
If maximum and minimum Values of
1  tan 2  
P)  1)  2
for all real values of    2n  1 , n  I are  and 
2
respectively, then
If maximum and minimum values of
  
Q) 5cos   3cos    3   3 for all real values of  are  and 2)  6
 
 respectively, then

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Narayana IIT Academy 14-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-1_Q’P
If maximum and minimum values of
    
R) 1  sin  4     2 cos  4    for all real values of  are  3)  6
   
and  respectively, then
If maximum and minimum values of 3cos   4 sin   2
S) 4)     10
for all real values of  are  and  respectively, then

5)     14

A) P  3; Q  3; R  2;S  4 B)P  3; Q  4; R  2;S  1

C) P  1; Q  5; R  2;S  4 D)P  1; Q  3; R  2;S  4

52. Match the following

Column – I Column – II

2 4 8 2 4 8
If A  sin  sin  sin and B  cos  cos  cos ,
7 7 7 7 7 7
P) 1) 1
then A2  B 2 is equal to

cos 20  8sin 70 sin 50 sin10


Q) is equal to 2) 2
sin 2 80

2 cos   1  
If cos   then tan 2 cot 2 has the value equal to
2  cos  2 2
R) 3) 2
where  ,    0,  

S) The value of cos 20  2sin 2 55  2 sin 65 is 4) 3

5) 3

A) P  2; Q  3; R  4;S  1 B) P  2; Q  4; R  5;S  1

C) P  1; Q  3; R  5;S  2 D) P  2; Q  3; R  5;S  1

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Narayana IIT Academy 14-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_CAT-1_Q’P
53. Match the following

Column – I Column – II

2F  n   1
Suppose that F  n  1  for n  1,2,3,…..and
P) 2 1) 42
F 1  2. Then F(101) equals

If a1 , a2 , a3 ...a21 are in A.P. and a3  a5  a11  a17  a19  10 then


Q) 21 2) 1620
the value of  ai is
i 1

R) 10th term of the sequence S  1  5  13  29  ..... is 3) 52

The sum of all two digit numbers which are not divisible
S) 4) 2045
by 2 or 3 is

A) P  3; Q  1; R  4; S  2 B) P  3; Q  2; R  4; S  1

C) P  2; Q  1; R  4; S  3 D) P  4; Q  2; R  1; S  3

54. Match the following

Column – I Column – II


If     , where  and  are positive, then
2
P) 1) 1

 sin   sin   sin   is always less than
4

Q) If sin   sin   a and cos   cos   b, then a 2  b2 cannot exceed 2) 6

R) If 3sin   5cos   5,   0  then the value of 5sin   3cos  is 3) 3

S) If 2cos x  sin x  1, then the value of 7 cos x  6 sin x is equal to 4) 4

A) P  1; Q  2; R  3; S  4 B) P  2; Q  1; R  3; S  4

C) P  1; Q  3; R  2; S  4 D) P  1; Q  4; R  3; S  2

INC.Jr.IIT_*CO SC Page No: 22

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