3

SEC: INC.
JR_*CO-SC(MODEL-A) Date: 14-08-22

Time: 3 Hrs Max. Marks: 180
14-08-22_INC.JR.IIT_STAR CO-SC(MODEL-A) _JEE ADV_WAT-7_SYLLABUS
PHYSICS: PRESENT WEEK (80%): Work ,Power, Energy: Work, Kinetic energy,
work - enegry theorem, conservative and non conservative forces,
potential energy, conservation of energy
(EXCLUDE: Problems related to power, Problems related to types of
equilibria, vertical circular motion, Spring problems)
PREVIOUS WEEK (20%): Circular motion: Kinematics of Circular

Motion, Angular Velocity, Angular Acceleration, Dynamics of Circular
Motion, Banking Of Road, Radius of Curvature, Centrifugal Force
(Exclude: Vertical Circular Motion)
CHEMISTRY: PRESENT WEEK (80%): Thermochemistry: Enthalpy change and

Internal energy change of a reaction, Enthalpy of formation, Enthalpy
of combustion, Hess law, Bomb calorimeter, Enthalpy of atomisation,
Neutrlisation, hydrogenation, Enthalpy of phase transition, Enthalpy
of solution, Bond enthalpy, Resonance energy
PREVIOUS WEEK (20%): Limitations of first law of thermodynamics;
Second law of Thermodynamics; Carnot cycle, efficiency of
thermodynamic system, Entropy -physical significance , expressions
in all types of processes, Gibb's free energy - physical significance,
spontneity of processes
MATHEMATICS: PRESENT WEEK (80%): Graphs of Trigonometric Functions,
Periodicity and extreme values
PREVIOUS WEEK (20%): Conditional Identities, Summation of
Trigonometric series, Miscellaneous problems on Transformation
Narayana IIT Academy 14-08-22_INC.JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-7_Q’P
Time: 3:00Hour’s IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Questions with Multiple Correct Choice
Sec – I(Q.N : 1 – 6) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Numerical Value Type
Sec – II(Q.N : 7 – 14) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Questions with Comprehension Type
Sec – III(Q.N : 15-18) +3 -1 4 12
(2 Comprehensions – 2 +2 = 4Q)
Total 18 60
CHEMISTRY:
+Ve - Ve
Marks Marks
Sec – I(Q.N :19 – 24) +4 -2 6 24
Sec – II(Q.N : 25 –32) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Sec – III(Q.N : 33-36) +3 -1 4 12
Total 18 60
MATHEMATICS:
+Ve - Ve
Marks Marks
Sec – I(Q.N:37 – 42) +4 -2 6 24
Sec – II(Q.N :43–50) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Sec –III(Q.N : 51-54) +3 -1 4 12
Total 18 60
INC.Jr.IIT_*CO SC Page No: 2

PHYSICS MAX.MARKS: 60
SECTION- I
(Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
1. A particle moves on a circular path of radius R, so that its angular velocity about a
fixed point on the circumference of the circular path is constant and is equal to  . Then
A) the acceleration of the particle is variable
B) the acceleration of the particle is constant in magnitude and is equal to 4R 2
C) the acceleration of the particle varies in magnitude
D) acceleration of the particle may be zero
2. A block of mass 2 kg is hanging over a smooth and light pulley through a light string.
The other end of the string is pulled by a constant force F = 40 N. The kinetic energy of
the particle increase 40J in a given interval of time. Then : (g = 10 m/s2)
2kg F  40 N
A) tension in the string is 40N
B) displacement of the block in the given interval of time is 2m
C) Work done by gravity is -20J
D) work done by tension on the block is 80J

3. A circular road of radius r is banked for a speed v = 40 km/hr. A car of mass m
attempts to go on the circular road. The friction coefficient between the tyre and the
road is negligible.
A) The car cannot make a turn without skidding
B) If the car turns at a speed less than 40 km/hr, it will slip down.
C) If the car turns at the correct speed of 40 km/hr, the force by the road on the car is
mv 2
equal to .
r
D) If the car turns at the correct speed of 40 km/hr, the force by the road on the car is
mv 2
greater than mg as well as greater than .
r
4. A block of mass 10 kg is moving on a horizontal rough surface by applying a force of

10N along the surface. The block is moving with a constant velocity. Then
A) the work done by frictional force on the block is – 100 J for displacement of 10m
B) the network done on the block for a given displacement is zero
C) the network done on the block for a given displacement is non-zero
D) None of the above
5. A heavy stone is thrown from a cliff of height h in a given direction. The speed with
which it hits the ground (ignore air friction)
A) must depend on the speed of projection
B) must be larger than the speed of projection
C) must be independent of the speed of projection
D) may be smaller than the speed of projection

6. The triangular block is moving horizontally with constant velocity v0 as shown in the
figure. The block A always remain stationary with respect to triangular block. In time t,
mg
A) the work done by normal reaction on triangular block is W1   v0t sin 2
2
B) the work done by normal reaction on triangular block is zero

mg
C) the work done by normal reaction on block A is W2  v0t sin 2
2
D) the work done by normal reaction (between block A and the triangular block) is
zero on the system (triangular block + block A) in any frame of reference.
SECTION - II
This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the second
decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) designated to enter the answer.
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
7. A particle of mass 1 kg moves with a constant speed v = 1 m/s along the curve ACB in
2 x
vertical plane whose equation is y  0.5cos , where x and y are in metre and l  1m .
l
The normal reaction on particle at lowest point B is 5n N (take  2  g ). Find the value
of n.
C x

b
8. A radical force F = br, r < a ; F  , r  a is acting on a particle at distance r from
r2
origin. The work done by the force when particle is moving from r = 0 to r =  is
a 2b b
 . Find the value of n.
n a
9. The work done by a force F  2  x  4 y  iˆ  8 xjˆ N on a particle moving from the origin to
(4m, 2m, 0) along path x 2  8 y is 10nJ . Find the value of n.

10. The work done on a particle of mass m by a force
 
x y
k iˆ  ˆj  N
  x2  y 2  3/2
 x 2
 y 
2 3/2 
 
(k is a constant of appropriate dimensions), when the particle is taken from the point (a,
0) to the point (0, a) along a circular path of radius a about the origin in the XY-plane is
11. A force F   x 2iˆ  y 2 ˆj  z 2 kˆ  N is acting on a particle. The particle displaces from
(0, 0, 0) to (1m, 1m, 1m). Find the work done by the force.
12. A particle of mass 1kg is moving on a circular path of radius 1m. Its kinetic energy is
K  bt 4 , where b = 1 J/s. The force acting on the particle at t = 1s is  2 x  m / s 2 . Find
1/ 2
the value of x.
13. A block of mass 1kg starts with velocity 5m/s. Its acceleration-time graph is shown in
figure.
The kinetic energy of the particle at t = 2s is 1682  10 n . Find the value of n.

14. The two blocks in an Atwood machine have masses 2.0 kg and 3.0 kg. Find the work
done by gravity during the fourth second after the system is released from rest.
 g  10 m / s 
2
SECTION – III
(COMPREHENSIN TYPE)
This section contains 2Paragraphs. Based on each paragraph, there are 2 questions. Each question has 4
options (A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases
Paragraph for Question Nos. 15 to 16:
Consider the situation shown in the figure. The system is released from rest and the
block A travels a Distance 5m in downward direction (take, g = 10m/s2)
15. Find the total work done by the tension on the system (block A+ block B)
A) zero B) 116.67 J C) 375 J D) – 375 J
16. Find net work done on the system
A) Zero B) 116.67 J C) 375 J D) – 116.67 J

A block of mass m is initially at x  0 pulled along X-axis by applying the force
F  b  cx , where b and c are positive constants.
F
X
O
17. The maximum value of x is
b b 2b b
A) B) C) D)
c 2c c 3c
18. The maximum speed of the block during motion of the block is
b 2b 3b 4b
A) B) C) D)
mc mc mc mc

CHEMISTRY MAX.MARKS: 60
SECTION- I
correct options.
option.
19. The normal boiling point of a liquid ‘X’ is 400K. Which of the following statement is
true about the process X  l   X  g  ?
A) At 400K and 1 atm pressure G  0

B) At 400K and 2 atm pressure G   ve
C) At 400K and 0.1 atm pressure G   ve
D) At 410K and 1 atm pressure G   ve
20. Select the incorrect statements about the plot of ln K vs 1/T
G 0
A) Linear with slope equal to and intercept H
R
B) Plot of ln K vs 1/T is a curve
H 0 S 0
C) Linear with slope and intercept
R R
S 0 H 0
D) Linear with slope and intercept
R R
21. Which of the following statement is (are) correct?
A) for an exothermic reactions, H 0f (products) < H 0f (reactants)
B) H 0f of CO 2  g  is same as the H comb of carbon graphite
C) all exothermic reactions have a free energy change negative

D) for a reaction N 2 g   O2 g   2NO g  , the heat at constant pressure and the heat at
constant volume at a given temperature are same

22. XY , X 2 and Y2 are diatomic molecule if H X  X , H Y Y and H X Y are in the ratio
of 2:1:2 and enthalpy of formation of XY from X 2 and Y2 is -100 kJ/mol. The value
of H X  X in kJ/mol is
A) 200 B) 400 C) 250 D) 500
23. In the reaction: 2 H 2 g   O2 g   2 H 2O l  ; H   xkJ then which of the following
is correct
A)  xkJ is the heat of reaction
B) xkJ is the heat of formation of H 2O
C) x kJ is the heat of combustion of H 2
D)   x / 2  kJ is the heat of formation of H 2O
24. The enthalpy change for a reaction depends upon:

A) physical state of the reactants and products
B) use of different reactants for the same products
C) nature of intermediate reaction steps
D) internal energies of reactants and products
SECTION - II
25. 
Three moles of an ideal gas Cv ,m  12.5 JK mol
1 1
 at 300K and 5dm . If the gas is
3
heated to 320K and the volume changed to 10dm 3 , calculate the entropy change.
 log 2  0.3,log3  0.48

1
26. The heat of neutralization of oxalic acid is -25.4 kcal mol using strong base, NaOH.
Hence, the enthalpy of ionization of oxalic acid is
1
(given  n H S . Avs S . B  13.7 K .cal mol )

27. The polymerization of propene to linear polypropene is represented by the reaction

n CH
CH 3
CH 2  CH 3
CH CH 2 
n
Where n has large integral value, the average enthalpies of bond dissociation for
(C = C) and (C – C) at 298K are +590 and +331 kJ mol 1 , respectively. The enthalpy
1
of polymerisation is -360 kJ mol . Find the value of n.
28. In the reaction AB2  l   3 X 2  g   AX 2  g   2 BX 2  g  H  270 kcal per
mole of AB2  l  . The enthalpies of formation of AX 2  g  & BX 2  g  are in the ratio
of 4:3 and have opposite sign. The value of  f H
0
 AB  l    30 kcal/mol. Then
2
 f H 0  AX 2  is
1
29. The heat of dissociation of H 2 is 435 kJ mol .
1
If C s   C g  ; H  720 kJ mol , calculate the bond energy per mole of the
C  H bond in CH 4 molecule.  f H for CH 4  75kJ mol 1 .
30. A monobasic acid is dissociated to 25% in 0.1N solution. When 100 mL of the acid is
neutralized by 0.1N KOH solution, heat evolved was 120 cal. Calculate heat of
dissociation per mol of acid. (in K cal)
31. The molar enthalpies of combustion of C2 H 2  g  , C  graphite  and H 2  g 
are – 1300, -394, and -286 kJ mol 1 , respectively. The standard enthalpy of formation
of C2 H 2  g  is
0
32. 1.00 litre sample of a mixture of CH 4 g  and O2 g  measured at 25 C and 740 torr
was allowed to react at constant pressure in a calorimeter which together with its
contents had a heat capacity of 1260 cal/K. The complete combustion of the methane to
CO2 and H 2O caused a temperature rise in the calorimeter of 0.667 K. What was the
mole per cent of CH 4 in the original mixture? H Co  CH 4   215 kcal mol 1 .

SECTION – III
(COMPREHENSIN TYPE)
The thermodynamic property that measures the extent of molecular disorder is called
entropy. Entropy change of phase transformation can be calculated using Trouton’s
formula  S  H / T  . In the reversible adiabatic process, S will be zero. The rise
in temperature in isobaric and isochoric conditions is found to increase the randomness
 Tf 
or entropy of the system, S  nCln  .
 Ti 
1
33. The melting point of a solid is 200 K and its enthalpy of fusion is 400 cal mol . The
entropy change for the fusion of 1 mole of the solid (in cal K 1 ) at the same
temperature would be
A) 800 B) 2 C) 0.2 D) 80
34. When 1 mol of an ideal gas is compressed to half of its volume, its temperature
becomes double. Then the change in entropy  S  would be
A) CV ln 4 B) CP ln 2 C) CV R ln 4 D)  CV  R  ln 2

The integral enthalpy of solution in kJ of one mole of H 2 SO4 dissolved in n mole of
75.6  n
water is given by H s 
n  1.8
35. When 1 mole of H 2 SO4 dissolved in 7 mole of H 2O, then H is
A) 55.59kJ B) 70.14kJ C) 70.14kJ D) 60.14kJ
36. When 1 mole of H 2 SO4 dissolved in excess of H 2O, then H is
A) 39.79kJ B) 60.14kJ C) 75.60kJ D) 75.60kJ

MATHEMATICS MAX.MARKS: 60
SECTION- I
correct options.
option.
37. If sec A tan B  tan A sec B  28, then the value of sec A sec B  tan A tan B is
A) 785 B)  783 C) 783 D)  785
38. If A, B, C, D are acute angles such that cotAcotB=tanC tanD, then the maximum value
of cosAcosBcosC cosD is
1 1 1
A) 1 B) C) D)
2 4 16
Let    0,  / 4  and t1   tan   , t2   tan   , t3   cot   and t4   cot  

tan  cot  tan  cot 
39. ,
then
A) t1  t2  t3  t4 B) t4  t3  t1  t2 C) t3  t1  t2  t4 D) t2  t3  t1  t2
 3  5  7  
40. Let f n    2sin sin  2sin sin  2sin sin  ...  2sin sin  2 n  1 , n  N ,
2 2 2 2 2 2 2 2
Then which value of the following is / are correct ?
  1  2 
A) f9    B) f n    0, n  N
4 2  n 
 2    1
C) f5  0 D) f9    
 7  4 2

41. If A  sin 440  cos 440 , B  sin 450  cos 450 and C  sin 460  cos 460 , then correct
option(s) is/are
A) A  B  C B) C  B  A C) B  A D) A  C
42. Let f  x   ab sin x  b 1  a 2 cos x  c, where a  1,b  0 then
A) Maximum value of f  x  is b if c  0
B) Difference of maximum and minimum values f  x  is 2b
C) Fundamental period of f  x  is 2
D) Fundamental period of f  x  is 
SECTION - II
43. If f  x   2  7cos x  24sin x  7sin x  24cos x  , for every x  R, then maximum value
1
of  f  x   4 is
44. The minimum value of  3sin x  4cos x  10  3sin x  4cos x  10  is
 x x
45. The fundamental period of sin      is ____(where [.] denotes G.I.F)
 2 2
3
46. If the fundamental period of cos  cos x   cos  sin x  is , then k is
k
7  6 tan   tan 2  
47. If maximum and minimum values of for all values of    2n  1
1  tan 
2
2
are  and  are respectively, then    is

   
48. If maximum and minimum values 1  sin      2cos     for all real values of
4  4 
 are  and  respectively, then    is
k
49. The ratio of greatest value of 2  cos x  sin 2 x to its least value is , then k =
4
50. If sin x  cos( x   )  cos( x   )  2 , has a real solution for x , then the minimum value
of sin is
SECTION – III
(COMPREHENSIN TYPE)
Minimum and maximum values of a cos  b sin   c are c  a 2  b 2 and
c  a 2  b 2 respectively
5 x  12 y  7 xy
51. If x 2  y 2  x 2 y 2 then the complete range of is
xy
A) 3, 20 B)  6, 20 C)  6, 3 D)  7, 20
52. The range of 3cos   300   3sin   2 is
A)  1, 4 B) 3, 5 C)  1, 5 D) 1, 3

If f  x  and g  x  are two periodic functions with fundamental period T1 and T2
f  x
respectively, then the fundamental period of f  x   g  x  , f  x  g  x  , may be
g  x
the LCM of T1 and T2 or the submultiple of the LCM or does not exists.

x  2x
53. The fundamental period of the function sin    cos   is
 3   4 
A) 12 B) 24 C) 24 D) 12
54. How many of the following function is periodic ?
I) sin  x   cos  2x 
II) sin  
 3 1 
2  1 x  cos 
 4

2
x

 22 
III) sin  x   cos  x 
 7 
 1 3 
IV) sin 
 1  2 

x   cos 1  2  3  6 x 
A) 0 B) 1 C) 2 D) 3

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SEC: INC.

JR_*CO-SC(MODEL-A) Date: 14-08-22

PREVIOUS WEEK (20%): Circular motion: Kinematics of Circular

CHEMISTRY: PRESENT WEEK (80%): Thermochemistry: Enthalpy change and

INC.Jr.IIT_*CO SC Page No: 2

A) tension in the string is 40N

B) displacement of the block in the given interval of time is 2m

C) Work done by gravity is -20J

D) work done by tension on the block is 80J

INC.Jr.IIT_*CO SC Page No: 3

A) The car cannot make a turn without skidding

4. A block of mass 10 kg is moving on a horizontal rough surface by applying a force of

B) the network done on the block for a given displacement is zero

C) the network done on the block for a given displacement is non-zero

D) None of the above

A) must depend on the speed of projection

B) must be larger than the speed of projection

C) must be independent of the speed of projection

D) may be smaller than the speed of projection

INC.Jr.IIT_*CO SC Page No: 4

B) the work done by normal reaction on triangular block is zero

INC.Jr.IIT_*CO SC Page No: 5

(4m, 2m, 0) along path x 2  8 y is 10nJ . Find the value of n.

11. A force F   x 2iˆ  y 2 ˆj  z 2 kˆ  N is acting on a particle. The particle displaces from

The kinetic energy of the particle at t = 2s is 1682  10 n . Find the value of n.

A) zero B) 116.67 J C) 375 J D) – 375 J

16. Find net work done on the system

A) Zero B) 116.67 J C) 375 J D) – 116.67 J

Paragraph for Question Nos. 17 to 18:

17. The maximum value of x is

INC.Jr.IIT_*CO SC Page No: 7

A) At 400K and 1 atm pressure G  0

B) H 0f of CO 2  g  is same as the H comb of carbon graphite

C) all exothermic reactions have a free energy change negative

INC.Jr.IIT_*CO SC Page No: 8

C) x kJ is the heat of combustion of H 2

D)   x / 2  kJ is the heat of formation of H 2O

24. The enthalpy change for a reaction depends upon:

 log 2  0.3,log3  0.48

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C  H bond in CH 4 molecule.  f H for CH 4  75kJ mol 1 .

31. The molar enthalpies of combustion of C2 H 2  g  , C  graphite  and H 2  g 

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Paragraph for Question Nos. 35 to 36:

A) 55.59kJ B) 70.14kJ C) 70.14kJ D) 60.14kJ

36. When 1 mole of H 2 SO4 dissolved in excess of H 2O, then H is

A) 39.79kJ B) 60.14kJ C) 75.60kJ D) 75.60kJ

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A) 785 B)  783 C) 783 D)  785

Let    0,  / 4  and t1   tan   , t2   tan   , t3   cot   and t4   cot  

Then which value of the following is / are correct ?

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42. Let f  x   ab sin x  b 1  a 2 cos x  c, where a  1,b  0 then

B) Difference of maximum and minimum values f  x  is 2b

44. The minimum value of  3sin x  4cos x  10  3sin x  4cos x  10  is

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Minimum and maximum values of a cos  b sin   c are c  a 2  b 2 and

A) 3, 20 B)  6, 20 C)  6, 3 D)  7, 20

52. The range of 3cos   300   3sin   2 is

A)  1, 4 B) 3, 5 C)  1, 5 D) 1, 3

Paragraph for Question Nos. 53 to 54:

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54. How many of the following function is periodic ?