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Fiitjee: Solutions To JEE (Main) - 2021
Fiitjee: Solutions To JEE (Main) - 2021
Please read the instructions carefully. You are allotted 5 minutes specifically for this
purpose.
Important Instructions:
1. The test is of 3 hours duration.
2. This test paper consists of 90 questions. Each subject (PCM) has 30 questions. The
maximum marks are 300.
3. This question paper contains Three Parts. Part-A is Physics, Part-B is Chemistry and
Part-C is Mathematics. Each part has only two sections: Section-A and Section-B.
4. Section – A : Attempt all questions.
6. Section-A (01 – 20) contains 20 multiple choice questions which have only one correct
answer. Each question carries +4 marks for correct answer and –1 mark for wrong
answer.
7. Section-B (01 – 10) contains 10 Numerical based questions with answer as numerical
value. Each question carries +4 marks for correct answer. There is no negative marking.
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JEE-MAIN-2021 (31st August-First Shift)-PCM-2
PART – A (PHYSICS)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
V V
+3 +3
(A) t (B) t
-3 -3
V V
+3 +3
(C) t (D)
t
-3 -3
Q2. A coil having N turns is would tightly in the form of a spiral with inner and outer radii ‘a’ and ‘b’
respectively. Find the magnetic field at centre, when a current I passes through coil:
I a b 0IN b
(A) 0 (B) loge
8 a b 2 b a a
0I 1 1 0I a b
(C) (D)
4 a b a b 8 ab
Q3. In an ac circuit, an inductor, a capacitor and a resistor are connected in series with XL = R = XC.
Impedance of this circuit is:
(A) 2R2 (B) Zero
(C) R 2 (D) R
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JEE-MAIN-2021 (31st August-First Shift)-PCM-3
Q5. A uniform heavy rod of weight 10 kg ms–2, cross-sectional area 100 cm2f and length 20 cm is
hanging from a fixed support. Young modulus of the material of the rod is 2 1011 Nm–2.
Neglecting the lateral contraction, find the elongation of rod due to its own weight:
–9 –10
(A) 2 10 m (B) 5 10 m
-8
(C) 4 10 m (D) 5 10–8 m
Q6. A small square look offside ‘a’ and one turn is placed inside a larger square loop of side b and
one turn (b >> a). The two loops are coplanar with their centres coinciding. If a current I is passed
in the square loop offside ‘b’, then the coefficient of mutual inductance between the two loops is:
8 2 b2
(A) 0 (B) 0 8 2
4 b 4 a
0 8 2 0 a2
(C) (D) 8 2
4 a 4 b
Q7. A helicopter is flying horizontally with a speed ‘v’ at an altitude ‘h’ has to drop a food packet for a
man on the ground. What is the distance of helicopter from the man when the food packet is
dropped?
2v 2h
(A) 2ghv 2 h2 (B) h2
g
2gh 2ghv 2 1
(C) h2 (D)
v2 h2
Q8. The masses and radii of the earth and moon are (M1, R1) and (M2, R2) respectively. Their centres
are at a distance ‘r’ apart. Find the minimum escape velocity for a particle of mass ‘m’ to be
projected from the middle of these two masses:
1 4G M1 M2 4G M1 M2
(A) V (B) V
2 r r
2G M1 M2 1 2G M1 M2
(C) V (D) V
r 2 r
M2
1
Q10. A reversible engine has an efficiency of . If the temperature of the sink is reduced by 58°C, its
4
efficiency becomes double. Calculate the temperature of the sink :
(A) 280°C (B) 382°C
(C) 180.4°C (D) 174°C
Q11. A moving proton and electron have the same de-Broglie wavelength. If K and P denote the K.E.
and momentum respectively. Then choose the correct option :
(A) Kp = Ke and Pp = Pe (B) Kp < Ke and Pp < Pe
(C) Kp < Ke and Pp = Pe (D) Kp > Ke and Pp = Pe
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JEE-MAIN-2021 (31st August-First Shift)-PCM-4
Q12. Consider a galvanometer shunted with 5 resistance and 2% of current passes through it. What
is the resistance of the given galvanometer?
(A) 300 (B) 344
(C) 226 (D) 245
Q13. A body of mass M moving at speed V0 collides elastically with a mass 'm' at rest. After the
collision, the two masses move at angles 1 and 2 with respect to the initial direction of motion of
the body of mass M. The largest possible value of the ratio M/m, for which the angles 1 and 2
will be equal, is :
(A) 3 (B) 1
(C) 2 (D) 4
time time
time time
Q16. An object is placed at the focus of concave lens having focal length f. What is the magnification
and distance of the image from the optical centre of the lens?
1 f
(A) Very high, (B) ,
4 4
1 f
(C) , (D) 1,
2 2
Q17. For an ideal gas the instantaneous change in pressure 'p' with volume 'v' is given by the equation
dp
= –ap. If p = p0 at v = 0 is the given boundary condition, then the maximum temperature one
dv
mole of gas can attain is :
(Here R is the gas constant)
ap0
(A) 0°C (B)
eR
p0
(C) (D) infinity
a eR
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JEE-MAIN-2021 (31st August-First Shift)-PCM-5
Q18. Angular momentum of a single particle moving with constant speed along circular path :
(A) remains same in magnitude but changes in the direction
(B) changes in magnitude but remains same in the direction
(C) remains same in magnitude and direction
(D) is zero
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JEE-MAIN-2021 (31st August-First Shift)-PCM-6
SECTION - B
(Numerical Answer Type)
This section contains 10 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded-off to the second
decimal place).
12V 1
Q2. A square shaped wire with resistance of each side 3 is bent to form a complete circle. The
resistance between two diametrically opposite points of the circle in unit of will be ______.
Q3. A car is moving on a plane inclined at 30º to the horizontal with an acceleration of 10ms–2 parallel
to the plane upward. A bob is suspended by a string from the roof of the car. The angle in
degrees which the string makes with the vertical is______. (Take g=10ms–2)
2k
C 50F
Q5. A wire having a linear mass density 9.0 × 10–4 kg/m is stretched between two rigid supports with a
tension of 900 N. The wire resonates at a frequency of 500 Hz. The next higher frequency at
which the same wire resonates is 550 Hz. The length of the wire is ______m.
Q6. When a rubber ball is taken to a depth of __________m in deep sea, its volume decreases by
0.5%.
(The bulk modulus of rubber = 9.8 × 108 Nm –2
Density of sea water = 103 kgm–3
g = 9.8 m/s2)
Q7. A particle of mass 1 kg is hanging from a spring of force constant 100 Nm –1. The mass is pulled
slightly downward and released so that it executes free simple harmonic motion with time period
T. The time when the kinetic energy and potential energy of the system will become equal, is
T
.The value of x is ________.
x
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JEE-MAIN-2021 (31st August-First Shift)-PCM-7
Q8. A block moving horizontally on a smooth surface with a speed of 40 ms–1 splits into two equal
–1
parts. If one of the parts moves at 60 ms in the same direction, then the fractional change in the
kinetic energy will be x : 4 where x =__________.
–1
Q9. The electric field in an electromagnetic wave is given by E = (50 NC ) sin (t–x/c)
–12
The energy contained in a cylinder of volume V is 5.5 × 10 J. The value of V is
3
__________cm .
(given by 0 = 8.8 10–12 C2N–1m–2)
Q10. If the sum of the heights of transmitting and receiving antennas in the line of sight of
communication is fixed at 160 m, then the maximum range of LOS communication is _____km.
(Take radius of Earth = 6400 km)
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JEE-MAIN-2021 (31st August-First Shift)-PCM-8
PART – B (CHEMISTRY)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
Q1. Given below are two statements : one is labelled as Assertion (A) and the other is labelled as
Reason (R).
Assertion (A) : Metallic character decreases and non-metallic character increases on moving
from left to right in a period.
Reason (R) : It is due to increase in ionisation enthalpy and decrease in electron gain enthalpy,
when one moves from left to right in a period.
In the light of the above statements, choose the most appropriate answer from the options given
below:
(A) (A) is false but (R) is true.
(B) Both (A) and (R) are correct and (R) is the correct explanation of (A)
(C) Both (A) and (R) are correct but (R) is not the correct explanation of (A)
(D) (A) is true but (R) is false
CN
CH2 CH2CN OH
(A) (B) CH3
H O
COOH
C
(C) CH3 (D) CH3
CN
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JEE-MAIN-2021 (31st August-First Shift)-PCM-9
Br
Q5. Select the graph that correctly describes the adsorption isotherms at two temperatures T1 and T2
(T1 > T2) for a gas :
(x – mass of the gas adsorbed ; m – mass of adsorbent ; P – pressure)
x x T1
m T2 m
(A) T1 (B) T2
P P
x x T1
m T2 m
(C) T1 (D) T2
P P
Q6. Given below are two statements: one is labelled as Assertion (A) and the other is labelled as
Reason (R).
Assertion (A) : Aluminium is extracted from bauxite by the electrolysis of molten mixture of Al 2O3
with cryolite.
Reason (R) : The oxidation state of Al in cryolite is +3.
In the light of the above statements, choose the most appropriate answer from the options given
below :
(A) Both (A) and (R) are correct but (R) is not the correct explanation of (A)
(B) Both (A) and (R) are correct and (R) is the correct explanation of (A)
(C) (A) is true but (R) is false
(D) (A) is false but (R) is true.
Q9. BOD values (in ppm) for clean water (A) and polluted water (B) are expected respectively
(A) A < 5, B > 17 (B) A > 15, B > 47
(C) A > 25, B < 17 (D) A > 50, B < 27
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JEE-MAIN-2021 (31st August-First Shift)-PCM-10
Q10. The correct order of reactivity of the given chlorides with acetate in acetic acid is :
CH3
Cl Cl Cl CH3 CH2Cl
CH3
CH3
Cl Cl CH2Cl Cl CH3
CH3
CH3
Cl CH2Cl Cl CH3 Cl
CH3
CH3
CH2Cl Cl Cl Cl CH3
CH3
Q12. Which one of the following lanthanides exhibits +2 oxidation state with diamagnetic nature?
(Given Z for Nd = 60, Yb = 70, La = 57, Ce = 58)
(A) La (B) Yb
(C) Nd (D) Ce
Q13. Given below are two statements : one is labelled as Assertion (A) and the other is labelled as
Reason (R) :
Assertion (A) : A simple distillation can be used to separate a mixture of propanol and
propanone.
Reason (R) : Two liquids with a difference of more than 20°C in their boiling points can be
separated by simple distillations.
In the light of the above statements, choose the most appropriate answer from the options given
below :
(A) Both (A) and (R) are correct and (R) is the correct explanation of (A)
(B) (A) is false but (R) is true.
(C) (A) is true but (R) is false
(D) Both (A) and (R) are correct but (R) is not the correct explanation of (A)
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JEE-MAIN-2021 (31st August-First Shift)-PCM-11
Q15. Which one of the following compounds contains -C1-C4 glycosidic linkage?
(A) Maltose (B) Lactose
(C) Amylose (D) Sucrose
Q17. Which one of the following 0.10 M aqueous solutions will exhibit the largest freezing point
depression?
(A) glucose (B) hydrazine
(C) glycine (D) KHSO4
Q18. The major products A and B in the following set of reactions are :
OH H O+
LiAlH4 3
A H B
H3O +
CN 2SO4
OH OH OH
(A) A= (B) A= COOH
, B= , B=
CHO CO 2H NH2
OH OH OH OH
(C) A = , B= (D) A = , B=
NH2 CHO OH CHO
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JEE-MAIN-2021 (31st August-First Shift)-PCM-12
Q19. Which one of the following is the correct PV vs P plot at constant temperature for an ideal gas? (P
and V stand for pressure and volume of the gas respectively)
PV PV
(A) (B)
P P
PV PV
(C) (D)
P P
Q20. Given below are two statements : one is labelled as Assertion (A) and the other is labelled as
Reason (R).
Assertion (A) : Treatment of bromine water with propene yields 1-bromopropan-2-ol.
Reason (R) : Attack of water on bromonium ion follows Markovnikov rule and results in 1-
bromopropan-2-ol.
In the light of the above statements, choose the most appropriate answer from the options given
below :
(A) Both (A) and (R) are true but (R) is NOT the correct explanation of (A)
(B) (A) is true but (R) is false.
(C) Both (A) and (R) are true and (R) is the correct explanation of (A)
(D) (A) is false but (R) is true.
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JEE-MAIN-2021 (31st August-First Shift)-PCM-13
SECTION - B
(Numerical Answer Type)
This section contains 10 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded-off to the second
decimal place).
-1 -1
Q1. A3B2 is a sparingly soluble salt of molar mass M (g mol ) and solubility x g L . The solubility
5
x
product satisfies Ksp = a . The value of a is ________. (Integer answer)
M
Q2. The total number of reagents from those given below, that can convert nitrobenzene into aniline is
______. (Integer answer)
I. Sn – HCl
II. Sn – NH4OH
III. Fe – HCl
IV. Zn – HCl
V. H2 – Pd
VI. H2 – Raney Nickel
Q3. The molarity of the solution prepared by dissolving 6.3 g of oxalic acid (H2C2O4 2H2O) in 250 mL
of water in mol L–1 is x × 10–2. The value of x is ________. (Nearest integer)
[Atomic mass : H : 1.0, C : 12.0, O : 16.0]
Q5. Consider the sulphides HgS, PbS, CuS, Sb2S3, As2S3 and CdS. Number of these sulphides
soluble in 50% HNO3 is _______.
Q6. For a first order reaction, the ratio of the time for 75% completion of a reaction to the time for 50%
completion is _______. (Integer answer)
Q7. According to the following figure, the magnitude of the enthalpy change of the reaction
A B M N in kJ mol1
is equal to _________. (Integer answer)
x x =20kJ mol1
A+B
y =45kJ mol1
z =15kJ mol1
y
M+N
Energy
Reaction Coordinate
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JEE-MAIN-2021 (31st August-First Shift)-PCM-14
Q9. The number of hydrogen bonded water molecule(s) associated with stoichiometry CuSO45H2O is
_______
Q10. Ge(Z = 32) in its ground state electronic configuration has x completely filled orbitals with m l =
0. The value of x is _______.
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JEE-MAIN-2021 (31st August-First Shift)-PCM-15
PART – C (MATHEMATICS)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
Q1. Let *, , v be such that the Boolean expression p* ~ q p q is a tautology. Then :
(A) * , (B) * ,
(C) * , (D) * ,
Q2. Let the equation of the plane, that passes through the point (1, 4, –3) and contains the line of
intersection of the planes 3x 2y 4z 7 0 and x 5y 2z 9 0, be x y z 3 0, then
is equal to:
(A) 23 (B) 15
(C) –15 (D) –23
9x 2 12 x 4
Q4. The function f x x 2 2x 3 e is not differentiable at exactly:
(A) three points (B) four points
(C) two points (D) one point
Q5. If p and q are the lengths of the perpendiculars from the origin on the lines.
x cosec – y sec = k cot 2 and x sin + y cos = k sin 2 respectively, then k2 is equal to:
(A) p2 + 2q2 (B) 4p2 + q2
2 2
(C) p + 4q (D) 2p2 + q2
Q6. lim
sin2 cos 4 x is equal to:
4
x 0 x
2 2
(A) 2 (B) 4
(C) 2 (D) 4
a1 a2 a3
2r 2r
Q7. If ar cos isin ,r 1,2,3...,i 1, then the determinant a4 a5 a6 is equal to:
9 9
a7 a8 a9
(A) a2a6 – a4a8 (B) a9
(C) a1a9 – a3a7 (D) a5
Q8. The length of the latus rectum of a parabola, whose vertex and focus are on the positive x-axis at
a distance R and S (>R) respectively from the origin, is :
(A) 4(S + R) (B) 2(S + R)
(C) 2(S – R) (D) 4(S – R)
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JEE-MAIN-2021 (31st August-First Shift)-PCM-16
Q9. Three numbers are in an increasing geometric progression with common ratio r. If the middle
number is doubled, then the new numbers are in an arithmetic progression with common
2 2
difference d. If the fourth term of GP is 3 r , then r – d is equal to:
(A) 7 + 3 (B) 7 – 3
(C) 7 + 3 3 (D) 7 – 7 3
Q10. The line 12x cos + 5y sin = 60 is tangent to which of the following curves?
2 2 2 2
(A) 144x + 25y = 3600 (B) x + y = 60
2 2 2 2
(C) x + y = 169 (D) 25x + 12y = 3600
x
1 1 a
logx , x0
x 1 x
b
Q11. If the function f(x) = k , x 0
cos2 x sin2 x 1
, x0
x2 1 1
1 1 4
is continuous at x = 0, then is equal to:
a b k
(A) 4 (B) –5
(C) 5 (D) –4
1
Q12. The integral dx is equal to: (where C is a constant of integration)
3 5
4
x 1 x 2
5 5
4 x 1 4 3 x 2 4
(A) C (B) C
3x2 4 x 1
1 1
4 x 1 4 3 x 2 4
(C) C (D) C
3x2 4 x 1
Q14. Which of the following is not correct for relation R on the set of real numbers?
(A) (x, y) R 0 < |x| – |y| 1 is neither transitive nor symmetric.
(A) (x, y) R < |x – y| 1 is reflexive and symmetric.
(C) (x, y) R < |x| – |y| 1 is reflexive but not symmetric.
(D) (x, y) R 0 < |x – y| 1 is symmetric and transitive.
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JEE-MAIN-2021 (31st August-First Shift)-PCM-17
dy 2x y 2x
Q15. If ,y 0 1, then y 1 is equal to:
dx 2y
2
(A) log2(1 + e) (B) log2(1 + e )
(C) log2(2 + e) (D) log2(2e)
Q16. Let f be a non-negative function in [0, 1] and twice differentiable in (0, 1). If
x 2 x 1 x
0 1 f t dt 0 f t dt,0 x 1 and f 0 0, then lim
x 0 x 2 0
f t dt :
(A) does not exist (B) equals 1
1
(C) equals (D) equals 0
2
Q17. Let a and b be two vectors such that 2a 3b 3a b and the angle between a and b is 60°. If
1
a is a unit vector, then b is equal to:
8
(A) 6 (B) 5
(C) 8 (D) 4
Q19. A vertical pole fixed to the horizontal ground is divided in the ratio 3 : 7 by a mark on it with lower
part shorter than the upper part. If the two parts subtend equal angles at a point on the ground 18
m away from the base of the pole, then the height of the pole (in meters) is :
(A) 8 10 (B) 12 15
(C) 12 10 (D) 6 10
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JEE-MAIN-2021 (31st August-First Shift)-PCM-18
SECTION - B
(Numerical Answer Type)
This section contains 10 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded-off to the second
decimal place).
Q1. If 'R' is the least value of 'a' such that the function f(x) = x2 + ax + 1 is increasing on [1, 2] and 'S'
2
is the greatest value of 'a' such that the function f(x) = x + ax + 1 is decreasing on [1, 2], then the
value of |R – S| is _________.
1
Q2. Let [t] denote the greatest integer t. Then the value of 8 [2x] x dx is _______.
1
2
2 2
Q3. If the variable line 3x + 4y = lies between the two circles x 1 y 1 1 and
2 2
x 9 y 1 4, without intercepting a chord on either circle, then the sum of all the integral
values of is ________.
Q4. The number of six letter words (with or without meaning), formed using all the letters of the word
'VOWELS', so that all the consonants never come together, is _________.
x 1 y 2 z 1
Q5. The square of the distance of the point of intersection of the line and the
2 3 6
plane 2x – y + z = 6 from the point (–1, –1, 2) is _________.
12
36 x 12
Q6. If 4 k is the term, independent of x, in the binomial expansion of 2 , then k is equal to
4
4 x
_________.
z 2
Q7. A point z moves in the complex plane such that arg , then the minimum value of
z 2 4
2
z 9 2 2i is equal to _________.
Q9. An electric instrument consists of two units. Each unit must function independently for the
instrument to operate. The probability that the first unit functions is 0.9 and that of the second unit
is 0.8. The instrument is switched on and it fails to operate. If the probability that only the first unit
failed and second unit is functioning is p, then 98 p is equal to _________.
x
3t
2
Q10. If x (x) = 2 ' t dt,x 2, and 0 4, then (2) is _________.
5
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JEE-MAIN-2021 (31st August-First Shift)-PCM-19
FIITJEE
KEYS to JEE (Main)-2021
PART – A (PHYSICS)
SECTION - A
1. B 2. B 3. D 4. C
5. B 6. D 7. B 8. B
9. C 10. D 11. C 12. D
13. A 14. B 15. B 16. C
17. C 18. C 19. C 20. D
SECTION - B
1. 6 2. 3 3. 30 4. 100
5. 10 6. 500 7. 8 8. 1
9. 500 10. 64
PART – B (CHEMISTRY)
SECTION - A
1. D 2. B 3. A 4. C
5. A 6. A 7. A 8. C
9. A 10. A 11. B 12. B
13. A 14. A 15. B 16. C
17. D 18. B 19. A 20. C
SECTION - B
1. 108 2. 5 3. 20 4. 25
5. 4 6. 2 7. 45 8. 3
9. 1 10. 7
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JEE-MAIN-2021 (31st August-First Shift)-PCM-20
PART – C (MATHEMATICS)
SECTION - A
1. A 2. D 3. C 4. C
5. B 6. B 7. C 8. D
9. A 10. A 11. B 12. C
13. D 14. D 15. A 16. C
17. B 18. D 19. C 20. C
SECTION – B
1. 2 2. 5 3. 165 4. 576
5. 61 6. 55 7. 98 8. 398
9. 28 10. 4
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JEE-MAIN-2021 (31st August-First Shift)-PCM-21
FIITJEE
Solutions to JEE (Main)-2021
PART – A (PHYSICS)
SECTION – A
2
Sol3. Z R 2 XC XL
2
Z R 2 R R XL XC R Given
ZR
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JEE-MAIN-2021 (31st August-First Shift)-PCM-22
Sol5. W 10kg m / s2
A 100cm2
20cm x
Y 2 1011 N / m2 dx
F F
Y
A AY
For elemental mass of length, dx
Change in its length
w
x .dx
d
AY
d
w
x dx
0 Ay
1 w
2 AY
On putting values we get
5 1010 m
Sol6. MI b
Also
B. A BA cos0
a
I 1 1
0 2
4 . a
b
4 2 2
2
I
4 0 2 a2
2b
And on comparing with
MI
0I 2 a 2
4 MI
2b
0 a2
8 2 M
4 b
1 2
Sol7. h gt v
2
2h
or t
g h
So, x vt
2h
or, x v
g x
So, dist of man from helicopter is
2h 2v 2h
h2 x 2 h2 v 2 h2
g g
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JEE-MAIN-2021 (31st August-First Shift)-PCM-23
Sol9. dist I1 I2 2 5a
2 2.3a
I1 a P
4.6a
5a 2a
5a
I2
1
Sol10. or 25%
4
Tsink 58 C (ie decreased)
1
' or 50%
2
Tsink ?
As we know, the efficiency for a reversible engine is given by :
T
1 2 T2 sink temperature
T1
1 T 1
1 2 & 1
T2 58
4 T1 2 T1
On comparing both, we get
3 T
T2 T1 & T2 58 C 1
4 2
3 T
T2
4 T2 174 C
1
T2 58 C T1
2
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JEE-MAIN-2021 (31st August-First Shift)-PCM-24
P2
As we know KE
2m
Also, de-broglie wavelength, is given by
h h
or
2mK
same for both
KP K e
h
Again
P
P same for both
PP Pe
0.98i 5
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JEE-MAIN-2021 (31st August-First Shift)-PCM-25
M
1 4
m
M
3
m max
Sol15. A A
B B
C
NB
Amount of B,
A NA 0
NB e A t e B t
B A
or NB K e A t eB t
A
t
Where K NA
B A 0
f f 1
Sol16. m
f u f f 2
uf f f f2 f
v v
uf f f 2f 2 F
f
dist of image from optical centre
2
dP
Sol17. aP, at V V0 , P P0
dV
Tmax ? for n 1
dP
aP (Given)
dV
dP
adV
P
On integrating, we get
P v
dP
P P a0 dV
0
P
n a V P P0 e aV
P0
Also, we know, PV nRT
P0 e aV V nRT
P0 VeaV
T
nR
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JEE-MAIN-2021 (31st August-First Shift)-PCM-26
dT
0 for Tmax
dV
P d
0
nR dV
V.eaV 0
d
dV
V eaV 0
V eaV a e aV .1 0
aV 1 e aV 0
1
V or V = 0
a
P 1
Tmax 0 e
nR a
P0
e 1
naR
P
Tmax 0 n 1
aeR
Sol18. L r p L mvr kˆ
Direction & magnitude both remain
same for particle moving with
constant speed.
1 4
2
2
x 5 x
2
5x 2
2
x
5x
2
x
x 5cm
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JEE-MAIN-2021 (31st August-First Shift)-PCM-27
SECTION - B
Sol1. Re q 6
12v
i 2A (through battery)
6
v15 6V
Sol2. Re q 3 3 6
3 3
3 6
60
Sol3. 30
2 wrt car frame
a 10 / s2
30 60
10m / s2
10m / s2
30
Sol4. Q CV
50 F 2V
100 106 C
Q 100C (on upper plate)
Sol5. 9 10 4 kg / m
T 900N ;
f0 500Hz resonance frequency
f0' 550Hz Next higher frequency
n (for wire fixed at both ends)
2
T 900N
v 1000m / s
9 104
v f
v nv
or f f0
2
f'
n 1 v
2
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JEE-MAIN-2021 (31st August-First Shift)-PCM-28
n 1000
500Hz 2
550Hz n 1 1000
2
10 n
n 10
11 n 1
10 1000
500Hz
2
10m
v
Sol6. P B
v
P
or B
v
v
gh
B
0.5% of V0
V0
gh 908 108 0.005
B h
0.005 V0 103 9.8
V0
h 500m
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JEE-MAIN-2021 (31st August-First Shift)-PCM-29
Pi Pf m m m
Sol8. v ' 60
m 40 2 2
v ' 20m / s 40m / s
1m ' 2
kEf v 602
2 2
1 2
1m KEi m 40
22
202 602 2
1
m 2000 m/2
2 m/2
v'
1 1
KE 2
m 2000 m 1600 60m/s
2
KE 1
m 1600
2
1
m 400
2 1 x
1 4 4
m 1600
2
x 1
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JEE-MAIN-2021 (31st August-First Shift)-PCM-30
hT 160 hT
hT 80m
dM 2 6400000 80 2 6400000 80
2 16 64 106
2 4 8 103
dM 64km
PART – B (CHEMISTRY)
SECTION - A
Sol1. Assertion (A) is correct & Reason (R) is incorrect
Metallic character decreases from left to right & non metallic character increases from left to
right
I. E. increases & electron gain enthalpy also increases from left to right.
Sol2.
O O
H3C C OH + SOCl 2 H3C C Cl + SO 2 + HCl
(A)
AlCl 3
OH O
C CH3 C CH3
KCN
+ HCl
CN OH
(B)
(C)
Sol3. Synthetic gas is a syn-gas which is also called water gas i.e mixture of (CO + H2)
C + H2O CO + H2
(Red hot) (1:1) mixture
Sol6. In electrolytic reduction of Al2O3, cryolite (Na3AlF6) is used to increase conductivity & decrease
melting point. Oxidation state of Al in cryolite (Na3AlF6) is (+3).
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JEE-MAIN-2021 (31st August-First Shift)-PCM-31
Sol8. Biuret is
O O
C C
H2N NH NH2
Denticity is 2 of terminal –NH2 only, because middle -NH will undergo in cross conjugation.
Sol9. B.O.D value < 5 ppm for clean water and B.O.D value of polluted water 17 ppm.
Sol10. Compound react with SN1 mechanism in presence of polar protic solvent, which follows
carbocation forming path.
Hence correct order is.
CH3
Cl Cl Cl CH3
CH2 Cl
> > >
CH3
Sol11.
O O
Cr Cr
O O O
O O
Sol13. Simple distillation can be applied for the separation of two liquids has boiling point difference
greater than 20oC.
Boiling point of propanol > boiling point of propanone (due to H- bonding effect)
o-hydroxymethylphenol Novolac
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JEE-MAIN-2021 (31st August-First Shift)-PCM-32
Sol15.
6 6
CH2OH HOH2C
5 5
OH O H OH
4 OHH 1 O H 1
H 4
OH H
H 3 2 H 2H
H OH 3
H OH
Lactose is polymer contain glycosidic linkage between C1 of - galactose & C4 of - glucose.
Sol16.
CH3 CH3
Conc. H2SO4
H3C C CH CH3 H3C C CH CH3
a few drops
CH3 OH H CH3 OH 2
-H2O
CH3 CH3
Rearangment
H3C C CH CH3 H3C C CH CH3
migration of
CH3 CH3
CH3 group
-H
H3C C C CH3
CH3 CH3
Sol17. Tf iK f m
Higher the value of i, more be Tf .
Glucose i =1
Hydrazine i =1
Glycine i =1
KHSO4 i =3 K H SO
4
Sol18.
OH OH
(1) Li AlH4
+
(2) H3O CH2NH2
C N
(A)
Reduction of –CN group, gives –CH2-NH2
OH
OH +
H3O / H2SO4
C OH
C N
O
H / -H2O
O
C OH
(B)
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JEE-MAIN-2021 (31st August-First Shift)-PCM-33
PV
P
Pressure increases & volume decreases , PV remains constant at constant T.
Sol20.
Br2 / H2O
H3C CH CH2 H3C CH CH2 Br
HOBr
OH
(1-Bromopropan-2-ol)
H H
HO Br O Br
H
Br + H2O
Br
H3C CH CH2 H3C CH CH2 Br
H H2O
H3C CH CH2 Br
OH
SECTION – B
Sol1.
3-
A3B2(s) 3A+2
(aq) + 2B (aq)
Solubility x 3x x
M M M
3 2
Ksp A 2 B3
3 2
3x 2x
M M
3 2
x x
27 4
M M
5
x
108
M
5 5
x x
Ksp a 108
M M
Ans. a 108
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JEE-MAIN-2021 (31st August-First Shift)-PCM-34
Sol2.
NO 2 NH2
Reagents
w 1000
Sol3. Molarity (M) =
molecular mass volume of solution(ml)
6.3 1000 4
= 0.2M
126 250 20
Molecular mass of oxalic acid H2 C2O 4 .2H2 O
= 1 2 12 2 16 4 2 18
26 64 36 126
M 2 10 1M
20 102 M
x 102 20 102
x 20
Ans.= 20
Sol4.
Change in oxidaiton number = 2
9 9
Cd(s)+Hg2SO 4(s) + 5 H2O(l) CdSO 4 H O(s)+ 2Hg(l)
5 2
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JEE-MAIN-2021 (31st August-First Shift)-PCM-35
25.1JK 1
Ans. = 25
Sol5. HgS, PbS, CuS, Sb2S3, As2S3, & CdS are given sulphides
CdS, PbS, As2S3 & CuS are soluble in 50% HNO3 but Sb2S3 & HgS are not soluble.
Ans.= 4
Sol6.
2.303 Co 2 2.303
t 75% log log2
K Co / 4 k
2.303 Co 2.303
t 50% log log2
K Co / 2 K
t 75%
2
t 50%
Ans.= 2
Sol8. Cl, Br & I form halic(V) acid i.e HClO3, HBrO3 & HIO3.
Sol9.
H H
H O O H O
H O
O S
+2
Cu H O
H O
O
H O
H H
One water molecule is associated with hydrogen bond.
Ans.= 1
Sol10. Ge ( Z = 32)
= 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p2
m 0 (for 4s, 3s, 2s, 1s) 4 orbital
m 0 (one p orbital of 2p and 3p)
m 0 (one d orbital)
Total orbitals = 7
Ans. = 7
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JEE-MAIN-2021 (31st August-First Shift)-PCM-36
PART – C (MATHEMATICS)
SECTION - A
Sol1. (p q) (p q) is tautology
p q q p q pq (p q) (p q)
T T F F T T
T F T T T T
F T F F T T
F F T F F T
,
Y
Sol3. e 4x 2e3x e x 6 0
e x t 0,
t 4 2t 3 t 6 0
Let f t t 4 2t 3 t 6
X
f ' t 4t 3 6t 2 1 f O
9 x2 12x 4
Sol4. f(x) x 2 2x 3 e
(x2 2x 3)e(3x 2)2 , x 1
2
f(x) (x 2 2x 3)e(3 x 2) , 1 x 3
2 (3x 2)2 x3
(x 2x 3)e ,
3x 2 2 x 1 3 x 2
2e
f ' x
2x 3 3x 2 , x 1, x 3
2
2e 3x 2 x 1 3 x 2
2x 3 3x 2 , 1 x 3
f ' 1 f 1 ,
f ' 3 f 3
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JEE-MAIN-2021 (31st August-First Shift)-PCM-37
k cos 2 k 2p
p kcot2 sin cos . sin 2 cos2 cos2
2 sin 2 2 k
q
and q= ksin2 sin2
k
on solving these two we get 4p2 q2 k 2
2r
i
Sol7. ar e 9
a1,a2 ,a3 ,........ are in G.P.
a1 a1r a1r 2 1 r r
2
x
O (R,0)
(S,0)
a a
Sol9. Let , a, ar are in G.P. ,2a,ar are in A.P.
r r
a 1
2a - = ar – 2a 2 - = r - 2 r2 – 4r + 1 = 0 r = 2 3 .
r r
A/q, ar 2 3r 2 a 3
d ar 2a 3 3
r2 d 7 3
x y x2 y2
Sol10. Since the line cos sin 1 is the equation of tangent to the ellipse 2 2 1 at
5 12 5 12
(5cos ,12sin ). Hence option (A) is correct option.
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JEE-MAIN-2021 (31st August-First Shift)-PCM-38
h h h
1 ln 1 ln 1
1 a a lim b 1 1 …………..(i)
Sol11. LHS = lim f(x) lim ln lim
x 0 h 0 h
1 h h 0
a
h h 0 h
b
a b
b
a b
cos2x 1 2sin2 x
RHS = lim f(x) lim
x 0 x 0 x 2 1 1
x 2 1 1 lim
x 0 x2
2 4 ……………….(ii)
and lim f(x) k …………(iii)
x 0
f 0 f 0
f 0
1 1
4 k
a b
1 1 4 4
From (i) ,(ii) and (iii) we get k 4 1 5
a b k k
dx dx x 1 3
Sol12. x 1 put t dx dt
3 /4
x 1
3/ 4
x2 (x 2)2
x2 (x 2)3 /4 (x 2)5 /4 x2 (x 2)2
1/ 4
1 dt 1 t1/ 4 4 x 1
= . +C +C
3 t3/ 4 3 1 3 x2
4
3 5 7
Sol13. 2 2
2 2
2 ..........
1 2 2 3 3 42
2r 1 1 1
tr 2 2
2
r (r 1) r (r 1)2
10 10
1 1 1 120
S10 t r 2 1 2
r 1 r 1 r (r 1)2 11 121
Sol14. 0 x y 1 0 y x 1
but 0 x y 1and 0 y z 1 does not necessarily imply that 0 x z 1
as 0 x y 1 1 x y 1 with x y ……….(i)
and 0 y z 1 1 y z 1with y z ……….(i)
(i) + (ii) 2 x z 2
For example (1,2) and (2,3) satisfy 0 x y 1 but (1,3) does not satisfy it.
0 x y 1 is symmetric and but not transitive.
Option (D) is correct option.
dy 2 x y 2 x 2y dy
Sol15. y
y 2x dx put 2y – 1 = t 2y ln2 dy =dt
dx 2 2 1
1 dt x 1 2x C
2 dx ln t put x = 0 and y = 1 we get C = - 1
ln2 t ln 2 ln 2 ln 2
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JEE-MAIN-2021 (31st August-First Shift)-PCM-39
2 2 2 2 2 2
Sol17. 2a 3b 3a b 4 a 9 b 12a.b 9 a b 6a.b
2 2
5 a 8 b 6a.b 0 ….......(i)
a.b 1
cos 60 a.b 4 b and a 8
a b 2
from (i) we get b 5
Sol18. 18 2 3 90 sin3 1 sin2 cos 4sin2 2sin 1 0
cos 0 4 sin 2 sin 1 0 cos ec 18 2 cos ec18 4 0
2 2
x 2 2x 4 0
3x x
Sol19. tan ……(i) and
18 6
7x
10x 5x
tan2 ……..(ii)
18 9
2 tan 5x 72
Solving (i) and (ii) 2
we get x
1 tan 9 5 3x
Height of pole = 10x = 12 10
18m
2 1 1
Sol20. 1 1 1 2(a 1) (1 a) 2 3a 1
1 1 a
2 1 5
3 1 1 3 2( b 1) (3 b) 5 2 3b 7
1 1 b
1 7
For a , b , system has no solution
3 3
SECTION - B
2
Sol1. f(x) = x + ax + 1 f (x) 2x a
for increasing f (x) 0
2x a 0 a 2x a 2 2 a 4 R = - 4
And for decreasing f (x) 0 a 2x a 2 1 S = - 2
|R - S| = 2
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JEE-MAIN-2021 (31st August-First Shift)-PCM-40
1 1
Sol3. Since centres C1(1,1) and C2(9,1) lies opposite sides of the line 3x 4y
( 3 4 ( 27 4- < 0 (7,31) …………(i)
Also length of perpendicular from centre of the circle is greater than radius of the circle .
34
1 2 or 12 ……………….(ii)
5
27 4
and 2 21 or 41 …………..(iii)
5
from (i), (ii) and (iii) we get [12,21]
sum of all integers = 165.
Sol4. VOWELS
vowels – 2 , constants – 4
all the consonants never come together 6! 3!4! = 720 – 144 = 576
x 1 y 2 z 1
Sol5. r (say)
2 3 6
Let P(1 + 2r , 2 + 3r , -1+ 6r) lies on the plane 2x – y + z = 6 r = 1 P 3,5,5
12
x 12
Sol6. 2
4 x
12 r r
x 12
12 (12)r
General term Tr 1 Cr 2 12 Cr 12r .x12 3r
4 x 4
According to question , 12 – 3r = 0 r = 4
( 12)4 36
T5 12 C4 12 4 4 55
4 4
6 6
3 3
4 55 4 k k = 55
4 4
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JEE-MAIN-2021 (31st August-First Shift)-PCM-41
z c 2
i zc 2i
z c 2 4
zc
Radius of the circle 4 4 2 2 C
2 A B 9 2,2
Square off minimum distance AB = 7 2 98
2
2,0 2,0
Sol9. P(E1 ) 0.9 , P(E1 ) 0.1 and P(E2 ) 0.8 , P(E2 ) 0.2
0.8 0.1 0.8 2
Required probability P
0.8 0.1 0.2 0.1 0.9 0.2 2.8 7
98P = 28
3t
2
Sol10. x(x) 2(t) dt, x 2 , By Leibniz theorem
5
(x) 3x2
(x) x(x) 3x 2 2(x) (x) ...............(i)
x2 x2
dx
I.F. e x 2 x 2
Multiplying (i) by I.F. we get ,
(x)(x 2) x3 C put x = 0 and (x) 4 we get C = 8
x3 8
(x)
x2
(2) 4
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